Titanium Dioxide Patents (Class 423/610)
  • Patent number: 8168145
    Abstract: The present invention provides a porous titanium oxide having improved ultraviolet protection ability, usability, and transparency in the visible region and a process for producing thereof. The porous titanium oxide powder according to the present invention can be obtained by adding an alkali to a titanium salt solution containing a polyalcohol and then thermally hydrolyzing the solution. In addition, it is possible that after the addition of the alkali, an acid is further added to the solution and then the thermal hydrolysis is conducted, or that after thermal hydrolysis, further heat treatment with an acid is conducted. A porous titanium oxide has a mean particle size of 0.01 to 1.0 ?m and a specific surface area of 50 m2/g or more.
    Type: Grant
    Filed: September 21, 2007
    Date of Patent: May 1, 2012
    Assignee: Shiseido Company Ltd.
    Inventors: Masayoshi Wada, Shoichiro Shio
  • Patent number: 8168562
    Abstract: A new method for preparing supported palladium-gold catalysts is disclosed. The method comprises sulfating a titanium dioxide support, calcining the sulfated support, impregnating the calcined support with a palladium salt, a gold salt, and an alkali metal or ammonium compound, calcining the impregnated support, and reducing the calcined support. The resultant supported palladium-gold catalysts have increased activity and stability in the acetoxylation.
    Type: Grant
    Filed: February 2, 2006
    Date of Patent: May 1, 2012
    Assignee: Lyondell Chemical Technology, L.P.
    Inventor: Steven M. Augustine
  • Publication number: 20120097071
    Abstract: This invention pertains to a mesoporous amorphous oxide of titanium and processes of making a mesoporous amorphous oxide of titanium.
    Type: Application
    Filed: December 21, 2011
    Publication date: April 26, 2012
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventor: CARMINE TORARDI
  • Patent number: 8148289
    Abstract: A titanium oxide photocatalyst that is capable of improving a decomposition rate, and a method for producing the same are provided. The titanium oxide photocatalyst of the present invention is a titanium oxide photocatalyst containing at least an anatase-type titanium oxide and fluorine, wherein a content of the fluorine is 2.5 wt % to 3.5 wt %, and 90 wt % or more of the fluorine is chemically bonded to the anatase-type titanium oxide.
    Type: Grant
    Filed: April 18, 2008
    Date of Patent: April 3, 2012
    Assignees: Panasonic Corporation, Sakai Chemical Industry Co., Ltd.
    Inventors: Noboru Taniguchi, Shuzo Tokumitsu, Tomohiro Kuroha, Kenichi Tokuhiro, Akio Nakashima, Keita Kobayashi, Shinji Nakahara
  • Publication number: 20120067405
    Abstract: An anatase-type titania crystal having a one-dimensional structure; a process for producing the crystal; and a dye-sensitized solar cell employing the titania crystal. The titania crystal is excellent in photocatalytic characteristics and photoelectric conversion characteristics. The process for titania crystal production is characterized by comprising: a mixing step in which an aqueous solution containing a block copolymer (A) having a hydrophobic block and a hydrophilic block is mixed with an organic solvent (C) containing a titanium alkoxide (B) dissolved therein to thereby give a liquid mixture; a reaction step in which the temperature of the liquid mixture is set at a value in the range of from 120° C. to 180° C. and the pressure of the atmosphere is set so as to result in the saturated vapor pressure at that set temperature to thereby react the liquid mixture and form a titania sol; and a baking step in which the titania sol is heated to produce baked titania particles having a wire shape.
    Type: Application
    Filed: August 6, 2008
    Publication date: March 22, 2012
    Applicant: ROHM CO., LTD.
    Inventors: Jinting Jiu, Seiji Isoda, Motonari Adachi, Naoki Yoshimoto
  • Publication number: 20120070719
    Abstract: According to one embodiment, a negative electrode active material for nonaqueous electrolyte battery includes a titanium oxide compound having a crystal structure of monoclinic titanium dioxide. When a monoclinic titanium dioxide is used as the active material, the effective capacity is significantly lower than the theoretical capacity though the theoretical capacity was about 330 mAh/g. The invention comprises a titanium oxide compound which has a crystal structure of monoclinic titanium dioxide and a (001) plane spacing of 6.22 ? or more in the powder X-ray diffraction method using a Cu-K? radiation source, thereby making an attempt to improve effective capacity.
    Type: Application
    Filed: September 21, 2011
    Publication date: March 22, 2012
    Applicant: KABUSHIKI KAISHA TOSHIBA
    Inventors: Yasuhiro HARADA, Norio Takami, Hiroki Inagaki, Keigo Hoshina
  • Patent number: 8137647
    Abstract: Provided are processes for the production of titanium dioxide from ilmenite. In these processes, ilmenite is digested with aqueous ammonium hydrogen oxalate. Iron from the ilmenite precipitates as a hydrated iron oxalate and is removed by filtering, leaving a titanium-rich solution. The titanium-rich solution can be further processed to form titanium dioxide.
    Type: Grant
    Filed: December 28, 2006
    Date of Patent: March 20, 2012
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: David Richard Corbin, Thomas Paul Griffin, Keith W. Hutchenson, Sheng Li, Mark Brandon Shiflett, Carmine Torardi, Joseph J. Zaher
  • Publication number: 20120040162
    Abstract: A method of forming a high-k dielectric material including forming at least two portions of titanium dioxide, the at least two portions of titanium dioxide comprising a first portion comprising amorphous titanium dioxide and a second portion comprising rutile titanium dioxide. A method of forming a high-k dielectric material including forming a first portion of titanium dioxide at a temperature of from about 150° C. to about 350° C. and forming a second portion of titanium dioxide at a temperature of from about 350° C. to about 600° C. A high-k dielectric material is also disclosed.
    Type: Application
    Filed: August 11, 2010
    Publication date: February 16, 2012
    Applicant: MICRON TECHNOLOGY, INC.
    Inventors: Tsai-Yu Huang, Ching-Kai Lin
  • Patent number: 8114376
    Abstract: The manufacture of titanium dioxide by oxidation of titanium tetrachloride in a multistage method, where both oxygen and titanium tetrachloride are added in several stages. In the first stage gaseous TiCl4 is introduced into a preheated oxygen-containing gaseous stream in a stoichiometric or hyper-stoichiometric amount to produce a TiO2 containing gas suspension. In the second or further stages liquid TiCl4 and oxygen-containing gas is introduced into the TiO2 containing gas suspension to produce further TiO2.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: February 14, 2012
    Assignee: Kronos International, Inc.
    Inventor: Rainer Gruber
  • Patent number: 8114377
    Abstract: This disclosure relates to process for producing titanium dioxide pigment having reduced chlorides, comprising: a) reacting titanium tetrahalide vapor, rutile-forming agent and at least a stoichiometric amount of oxygen in a reactor to form a gaseous suspension comprising titanium dioxide particles; b) introducing silicon tetrachloride into the reactor at least one point downstream of the point of contact of the titanium tetrahalide, the rutile forming agent and the oxygen, and where at least 97% of the titanium tetrahalide has been converted to titanium dioxide to provide a substantially uniform encapsulation of pyrogenic SiO2 on the titanium dioxide; c) passing the gaseous suspension to a cooling conduit; d) introducing scouring material, typically selected from the group of calcined titanium dioxide and compressed titanium dioxide, and mixtures thereof, into the cooling conduit; wherein the particles of the scouring material have a diameter in the range of about 0.25 mm to about 12.
    Type: Grant
    Filed: November 2, 2006
    Date of Patent: February 14, 2012
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Alan Roger Eaton, Rajeev Lochan Gorowara, Narayanan Sankara Subramanian, Stephen William Taylor
  • Patent number: 8106101
    Abstract: This invention relates to methods of making single phase nanocrystalline titanium dioxide. It is hereby provided a method for preparing single-phase anatase type titanium dioxide photocatalyst having a particle size of nano level at near room temperatures without the need for a sintering process at high temperatures.
    Type: Grant
    Filed: July 13, 2007
    Date of Patent: January 31, 2012
    Assignee: The Hong Kong Polytechnic University
    Inventors: Walid Abdelhamld Daoud, John Haozhong Xin, Kaihong Qi
  • Patent number: 8101152
    Abstract: A titanium halide, preferably titanium tetrachloride, is reacted with suitable reductant, preferably an alkali metal or alkaline earth metal, under ultrasonic excitation in a liquid reaction medium to form nanometer size particles of titanium which may incorporate unreacted reductant. The nanosized titanium particles may be a precursor for nanosized titanium oxide which is formed by oxidizing the titanium, preferably with a low molecular weight alcohol. When the titanium particles incorporate unreacted reductant the oxidation reaction will yield nanometer sized titanates. The nanosized particles, whether titanium oxide or titanates may be extracted by first filtering them from the reaction medium, followed by washing with water to remove any water-soluble reaction products followed by spray drying.
    Type: Grant
    Filed: August 18, 2010
    Date of Patent: January 24, 2012
    Assignee: GM Global Technology Operations LLC
    Inventors: Ion C. Halalay, Michael P. Balogh
  • Patent number: 8097233
    Abstract: The present invention relates to the synthesis of nanoparticles by laser hydrolysis. For this purpose, a precursor interacts with a laser beam (LAS) in a pyrolysis reactor (REAC) for producing nanoparticles (nP), characterized in that the precursor is firstly in the liquid state and is then converted into the vapor phase and in that the flow rate of the precursor is controlled in the liquid phase.
    Type: Grant
    Filed: January 22, 2008
    Date of Patent: January 17, 2012
    Assignee: Commissariat a l'Energie Atomique
    Inventor: Dominique Porterat
  • Publication number: 20110318249
    Abstract: Disclosed is a porous metal oxide obtained by subjecting metal alkoxide and/or a partially hydrolyzed condensate of the metal alkoxide to a sol-gel reaction in the presence of terminally branched copolymer particles represented by the following general formula (1) and having a number average molecular weight of not more than 2.
    Type: Application
    Filed: March 12, 2010
    Publication date: December 29, 2011
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Norio Nakayama, Toshihiko Takaki, Haruhiko Fukumoto, Kaori Matoishi, Shiro Nakatsuka, Naoshi Nagai, Eiichi Takahashi, Yukiko Enomoto
  • Patent number: 8083950
    Abstract: The present invention relates to a method for recovering an organic-inorganic element-doped metal oxide from a hydrolysable metal compound, accompanied with contaminated water treatment. The present invention comprises steps of: a) adding a hydrolysable metal compound as a coagulant to a contaminated water to form a separable floc between the hydrolysable metal compound and contaminants present in contaminated water; b) separating the separable floc and the pre-treated water after flocculation treatment; and c) calcinating the separated floc over 500° C. to produce an organic-inorganic element-doped metal oxide. More preferably, the present invention further comprises subjecting the pre-treated water of the step b) to a microwave treatment to cause a photocatalytic degradation of an organic contaminant that remains in the pre-treated water, with the assistance of the remaining hydrolysable metal compound.
    Type: Grant
    Filed: January 18, 2006
    Date of Patent: December 27, 2011
    Assignees: Photo & Environmental Technology Co., Ltd., University of Technology, Sydney
    Inventors: Hokyong Shon, Vigneswaran Saravanamuthu, Erdei Laszlo, Jong Ho Kim, Jong Beom Kim, Dong Lyun Cho, Byung Chul Choi, Kun Jung Kim, Myung Wan Kim, Sung Jung Song, Hee Ju Park, Jaeweon Cho, In-soo Kim, Seung-hyun Kim
  • Publication number: 20110301270
    Abstract: The invention provides a dispersion of particles of rutile titanium oxide wherein the particles of rutile titanium oxide have a D50 in a range of 1 to 15 nm and a D90 of 40 nm or less in particle size distribution as determined by a dynamic light scattering method; a specific surface area in a range of 120 to 180 m2/g as determined by a BET method; and a rate of weight loss of 5% or less as obtained by heating the particles of rutile titanium oxide from 105° C. to 900° C.
    Type: Application
    Filed: February 15, 2010
    Publication date: December 8, 2011
    Inventors: Atsushi Nomura, Kenichi Nakagawa, Takanori Morita
  • Patent number: 8071070
    Abstract: Provided is a crystalline TiO2 powder in the form of aggregated primary particles having a variable sintering stability at a BET surface area of 70-100 m2/g and a rutile content of greater than 10% but less than or equal to 40%, and a process for preparing the crystalline TiO2 powder, which involves: introducing a TiCl4 vapor and, separately therefrom, H2 and a primary air into a mixing chamber to produce a gaseous mixture; igniting the gaseous mixture in a burner to produce a flame, which is burned into a reaction chamber to produce the crystalline TiO2 powder and gaseous substances; and separating the crystalline TiO2 powder from the gaseous substances, wherein the relative amounts of TiCl4 vapor, H2 and primary air are selected to provide crystalline TiO2 powder having the aforementioned BET surface area and rutile content, with the proviso that factor A has a value of 0.1-0.4 g/m2 in accordance within the following formula: factor A=105{[(TiCl4 vapor×H2)/(amount of air×gaseous mixture)]/BET]}.
    Type: Grant
    Filed: May 24, 2010
    Date of Patent: December 6, 2011
    Assignee: Evonik Degussa GmbH
    Inventors: Christian Schulze-Isfort, Kai Schumacher, Nina Schuhardt, Oswin Klotz, Rainer Golchert
  • Patent number: 8071069
    Abstract: The invention relates to a process for the purification of titania by treating the titania with an aqueous solution having one or more ammonium compounds at elevated temperatures, separating the titania from the aqueous solution, drying the titania and, optionally, calcining the dried titania. More especially the invention relates to the removal of sulphur (mainly present in the form of sulphate compounds) from the titania. The titania purified according to the above process is especially suitable for use as a catalyst carrier.
    Type: Grant
    Filed: August 9, 2002
    Date of Patent: December 6, 2011
    Assignee: Shell Oil Company
    Inventors: Abderrahmane Chettouf, Carolus Matthias Anna Maria Mesters, Gerardus Petrus Lambertus Niesen
  • Publication number: 20110293507
    Abstract: A process includes reacting a titanium compound with an oxalate compound in an acidic medium to form a titanium oxalate complex, where the titanium oxalate complex includes primary and secondary particles. The primary titanium oxalate complex particles may be from about 1 nm to about 200 nm; and the secondary titanium oxalate complex particles may be from about 0.5 ?m to 50 ?m. The titanium oxalate complex may be sintered to prepare a titania-based compound. The titania-based compounds may be used to fabricate electrodes for electrochemical cells.
    Type: Application
    Filed: May 4, 2011
    Publication date: December 1, 2011
    Inventors: Damien Dambournet, Ilias Belharouak, Khalil Amine
  • Patent number: 8062621
    Abstract: A method of manufacturing titanium dioxide particles can produce titanium dioxide particles where a rare earth element is substituted at the titanium sites from which it is possible to highly efficiently take out fluorescence attributable to the rare earth element The method of manufacturing titanium dioxide particles doped with a rare earth element comprises a step of preparing a liquid precursor containing a titanium source and rare earth metal source, the doping ratio of the rare earth element in the liquid precursor being within a range not less than 0 at % and not more than 5.
    Type: Grant
    Filed: June 15, 2006
    Date of Patent: November 22, 2011
    Assignee: National Institute For Materials Science
    Inventors: Jiguang Li, Takamasa Ishigaki
  • Patent number: 8062622
    Abstract: A crystalline titanium dioxide powder, containing aggregated primary particles, wherein a BET surface area of the aggregated primary particles is from 30 to 65 m2/g, and a rutile content of a sum of crystalline modifications in the crystalline titanium dioxide is from of 50-70%.
    Type: Grant
    Filed: December 10, 2009
    Date of Patent: November 22, 2011
    Assignee: Evonik Degussa GmbH
    Inventors: Christian Schulze-Isfort, Oswin Klotz, Rainer Golchert, Uwe Diener, Kai Schumacher
  • Publication number: 20110268956
    Abstract: The invention relates to a process for obtaining ceramic coatings and ceramic coatings obtained. This process allows obtaining coatings of ceramic oxides, such as ZrO2, Al2O3, TiO2, Cr2O3, Y2O3, SiO2, CaO, MgO, CeO2, Sc2O3, MnO, and/or complex mixtures thereof, by means of a high frequency pulse detonation technique in which the relative movement between the combustion stream and the substrate or piece to be coated takes place at a speed that produces an overlap between the successive coating areas exceeding 60% of the surface of a coating area. The allows producing ceramic coatings with a thickness greater than 30 microns in a single pass.
    Type: Application
    Filed: May 12, 2006
    Publication date: November 3, 2011
    Applicant: FUNDACION INASMET
    Inventors: Inaki Fagoaga Altuna, Maria Parco Camacaro, Georgiy Barikyn, Carlos Vaquero Gonzalez
  • Patent number: 8048398
    Abstract: Process for preparing a mixed metal oxide powder, in which oxidizable starting materials are evaporated and oxidized, the reaction mixture is cooled after the reaction and the pulverulent solids are removed from gaseous substances, wherein as starting materials, at least one pulverulent metal and at least one metal compound, the metal and the metal component of the metal compound being different and the proportion of metal being at least 80% by weight based on the sum of metal and metal component from metal compound, together with one or more combustion gases, are fed to an evaporation zone of a reactor, where metal and metal compound are evaporated completely under nonoxidizing conditions, subsequently, the mixture flowing out of the evaporation zone is reacted in the oxidation zone of this reactor with a stream of a supplied oxygen-containing gas whose oxygen content is at least sufficient to oxidize the starting materials and combustion gases completely.
    Type: Grant
    Filed: May 9, 2007
    Date of Patent: November 1, 2011
    Assignee: Evonik Degussa GmbH
    Inventors: Stipan Katusic, Guido Zimmermann, Michael Kraemer, Peter Kress, Horst Miess
  • Patent number: 8048399
    Abstract: It is provided ultrafine particles of a rutile titanium oxide obtained by maintaining the pH of an aqueous solution of a titanium compound having a Ti concentration of from 0.07 to 5 mol/L in the range of ?1 to 3 in the presence of a chelating agent. Such ultrafine particles of a rutile titanium oxide are useful for photocatalysts, high refractive index materials, ultraviolet absorbing materials and the like.
    Type: Grant
    Filed: December 3, 2009
    Date of Patent: November 1, 2011
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Toyoharu Hayashi, Norio Nakayama, Tomonori Iijima
  • Publication number: 20110250126
    Abstract: The present invention is related to a family of Group 4 metal precursors represented by the formula: M(OR1)2(R2C(O)C(R3)C(O)OR1)2 wherein M is a Group 4 metals of Ti, Zr, or Hf; wherein R1 is selected from the group consisting of a linear or branched C1-10 alkyl and a C6-12 aryl, preferably methyl, ethyl or n-propyl; R2 is selected from the group consisting of branched C3-10 alkyls, preferably iso-propyl, tert-butyl, sec-butyl, iso-butyl, or tert-amyl and a C6-12 aryl; R3 is selected from the group consisting of hydrogen, C1-10 alkyls, and a C6-12 aryl, preferably hydrogen. In a preferred embodiment of this invention, the precursor is a liquid or a solid with a melting point below 60° C.
    Type: Application
    Filed: October 14, 2010
    Publication date: October 13, 2011
    Applicant: AIR PRODUCTS AND CHEMICALS, INC.
    Inventors: Sergei Vladimirovich Ivanov, Xinjian Lei, Hansong Cheng, Daniel P. Spence, Moo-Sung Kim
  • Patent number: 8034743
    Abstract: To provide a method of production of an exhaust gas purification catalyst support preventing a drop in the heat resistance of alumina or other catalyst support due to the presence of titania and provided with a sulfur poisoning suppression action by titania and an exhaust gas purification catalyst support produced by the same. A method of production of an exhaust gas purification catalyst support comprising, in a basic solution, making alumina particles adsorb ammonium ions and then bringing titania sol into contact with the alumina particle so as to make the alumina particles adsorb the titania particles. An exhaust gas purification catalyst support where at least base points on the alumina particle surfaces adsorb titania particles and the pH does not rise when immersed in an ammonium nitrate solution.
    Type: Grant
    Filed: June 25, 2008
    Date of Patent: October 11, 2011
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Akio Koyama
  • Patent number: 8029754
    Abstract: The present invention relates to cerium oxide powder and a process for producing the same. The cerium oxide powder of the invention, which is produced by mixing a cerium source such as cerium oxide, cerium hydroxide and cerium carbonate with an alkali metal compound, as flux, and performing high temperature treatment, may have a variety particle size while having spherical shape.
    Type: Grant
    Filed: July 28, 2005
    Date of Patent: October 4, 2011
    Assignee: LG Chem, Ltd.
    Inventors: Jun-seok Nho, Jang-yul Kim, Myoung-hwan Oh, Jong-pil Kim, Seung-beom Cho
  • Patent number: 8029763
    Abstract: The present invention is drawn to a method for removing colloidal titanium dioxide and titanium oxychloride from by-product hydrochloric acid. The method includes adding phosphate ion source and quaternary amine to the by-product acid to cause the titanium dioxide and the titanium oxychloride to form a precipitate. The precipitate can then be separated from the acid, thus producing a decontaminated hydrochloric acid product with reduced levels of titanium.
    Type: Grant
    Filed: March 2, 2010
    Date of Patent: October 4, 2011
    Assignee: Haydock Consulting Services, LC
    Inventor: Frederick Haydock
  • Patent number: 8025861
    Abstract: Titanium oxide (usually titanium dioxide) catalyst support particles are doped for electronic conductivity and formed with surface area-enhancing pores for use, for example, in electro-catalyzed electrodes on proton exchange membrane electrodes in hydrogen/oxygen fuel cells. Suitable compounds of titanium and a dopant are dispersed with pore-forming particles in a liquid medium. The compounds are deposited as a precipitate or sol on the pore-forming particles and heated to transform the deposit into crystals of dopant-containing titanium dioxide. If the heating has not decomposed the pore-forming particles, they are chemically removed from the, now pore-enhanced, the titanium dioxide particles.
    Type: Grant
    Filed: March 3, 2010
    Date of Patent: September 27, 2011
    Assignees: GM Global Technology Operations LLC, Administrators of the Tulane Educational Fund
    Inventors: Mei Cai, Yunfeng Lu, Zhiwang Wu, Lee Lizhong Feng, Martin S. Ruthkosky, John T. Johnson, Frederick T. Wagner
  • Publication number: 20110229793
    Abstract: A metal oxide electrode catalyst which includes a metal oxide (Y) obtained by heat treating a metal compound (X) under an oxygen-containing atmosphere. The valence of the metal in the metal compound (X) is smaller than the valence of the metal in the metal oxide (Y). Further, the metal oxide electrocatalyst has an ionization potential in the range of 4.9 to 5.5 eV.
    Type: Application
    Filed: July 23, 2008
    Publication date: September 22, 2011
    Applicant: SHOWA DENKO K.K.
    Inventors: Tadatoshi Kurozumi, Toshikazu Shishikura, Hiroshi Konuma
  • Patent number: 8021634
    Abstract: A sulfate process for producing titania from a titaniferous material (such as an iron-containing titaniferous material such as ilmenite) is disclosed. The process includes digestion and/or leach steps that form a process solution that includes an acidic solution of titanyl sulfate (TiOSO4) and iron sulfate (FeSO4) from the solid titaniferous material. The process also includes hydrolysis and other steps that form titania from the titanyl sulfate in the process solution. The process is characterised by a ferric ion treatment step of treating the process solution and lowering the concentration of ferric ions from the process solution.
    Type: Grant
    Filed: September 6, 2007
    Date of Patent: September 20, 2011
    Assignee: BHP Billiton Innovation Pty. Ltd.
    Inventors: Eric Girvan Roche, Philip Ernest Grazier, Alan David Stuart
  • Publication number: 20110217222
    Abstract: Aqueous leachant compositions and processes for using the same comprising: (a) providing a metal-containing compound; and (b) subjecting the metal-containing compound to an acid digestion comprising contacting the metal-containing compound with an aqueous leachant; wherein the aqueous leachant comprises a mixture selected from the group consisting of: (i) sulfuric acid and one or more alkanesulfonic acids having alkane moieties selected from the group consisting of propyl, ethyl and methyl groups, at a weight ratio of alkanesulfonic acid to sulfuric acid of 1:1000 to 1:1; (ii) sulfuric acid and one or more salts of alkanesulfonic acids having alkane moieties selected from the group consisting of propyl, ethyl and methyl groups, at a weight ratio of salt of alkanesulfonic acid to sulfuric acid of 1:9 to 1:99.
    Type: Application
    Filed: May 12, 2011
    Publication date: September 8, 2011
    Applicant: BASF SE
    Inventors: Thomas Heidenfelder, Helmut Witteler, Bernd Laubusch, Hans-Peter Seelmann-Eggebert
  • Patent number: 8012451
    Abstract: A highly photosensitivity titanium oxide composition includes a plurality of nanosize particles including titanium dioxide and titanium suboxide. The particles are substantially non-stoichiometric (TiO2-x, wherein 0.1<x<0.3 at a surface of the particles, and in the bulk of the particles x is less than at the surface), provide a magnetic susceptibility value (X) of at least 0.8 10?6 cm3/g at 300 K, and are least 30% by weight rutile. A related method of forming a high photosensitivity titanium oxide composition includes the steps of providing a titanium chloride compound, such as titanium tetrachloride, an oxygen-containing gas and hydrogen, wherein a concentration of the hydrogen is in a stoichiometric excess (H2:O2) from 2.02:1 to 2.61:1. The titanium chloride compound is burned in the presence of oxygen from the oxygen-containing gas and hydrogen to form plurality of ultrafine particles comprising titanium dioxide and titanium suboxide.
    Type: Grant
    Filed: December 13, 2007
    Date of Patent: September 6, 2011
    Assignee: Worthington Technologies, LLC
    Inventors: Ihor M. Kobasa, Wojciech J. Strus, Mykhaylo A. Kovbasa
  • Patent number: 7998453
    Abstract: The disclosure pertains to a process for making a suspension of finely divided titanium (IV) oxide particles, comprising: vigorously mixing (a) a volume of a first component comprising a major proportion of an alcohol, a minor proportion of a titanium alkoxide and a minor proportion of a titanium alkoxide activator selected from the group consisting of water and a first aqueous base, and (b) a volume of a second component selected from the group consisting of water and a second aqueous base, at least one of the first component or the second component having a base therein, the second component being substantially free of alcohol, to form a mixture comprising a suspension of finely divided titanium (IV) oxide particles, the mixture having a water to titanium molar ratio ranging from about 40 to about 1 to about 5000 to about 1, wherein the proportion of the titanium alkoxide, the proportion of the activator, the mixing vigor, and a ratio of the volume of the first component to the volume of the second compo
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: August 16, 2011
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: David M Scott, Carmine Torardi, Vladimir Grushin
  • Patent number: 7998430
    Abstract: A reactor 20 has a plurality of tubular downcomers 32, 34, 36, 38, 40 and risers 42, 44, 46, 48, 50, joined by sections 86, 88 in a continuous serpentine path the tubes dimensioned to provide substantially plug flow conditions for solid and liquid reagents fed into a first downcomer 24 with the products extracted from final riser 52. The reactor 20 is designed for a desired residence time by the number, height and diameter of the tubes. The downcomers 24, 32, 34, 36, 38, 40 may include a bend to improve residence time and to thereby reduce the number of tubes required for a desired overall residence time. The reactor 20 can be used in a leaching operation for producing synthetic rutile, where a pre-treated feedstock including ilmenite, leucoxene or titania slag is leached with hot HCl.
    Type: Grant
    Filed: June 20, 2008
    Date of Patent: August 16, 2011
    Assignee: Austpac Resources N.L.
    Inventor: John Winter
  • Publication number: 20110192322
    Abstract: The invention relates to a method of preparing a well-dispersable, rutile-structured, microcrystalline titanium dioxide product, a product prepared by the method, and an effect paint and a lacquer provided by means of the product. In the method, the titanium dioxide starting material is first treated with a base to have an alkaline pH value, after which it is treated with an acid to have a hydrochloric acid content of 8 to 30 g/l, neutralized, processed, and calcinated. In particular, the preparation method is characterized by the use of a pretreatment chemical before the calcination stage to improve the dispersability.
    Type: Application
    Filed: August 15, 2008
    Publication date: August 11, 2011
    Inventors: Ralf-Johan Lamminmäki, Esa Latva-Nirva, Riitta Linho, Johanna Niinimäki, Visa Vehmanen
  • Publication number: 20110189081
    Abstract: A method for synthesizing high quality crystalline anatase titanium dioxide having a substantial occurrence of (001) facets. Including the steps of combining a source of fluoride anions with a titanium precursor and subjecting the mixture to hydrolysis. A solvent can be combined with the source of fluoride anions and the titanium precursor prior to hydrolysis. The crystalline anatase titanium dioxide can be produced to have the highly reactive (001) facets predominant by area in a variety of crystal structures, such as nanosheets.
    Type: Application
    Filed: March 25, 2009
    Publication date: August 4, 2011
    Inventors: Gao Qing Lu, Shizhang Qiao, Huagui Yang
  • Publication number: 20110189605
    Abstract: The present invention relates to a method of manufacturing titania nanoparticles, and specifically to a method of manufacturing titania nanoparticles wherein the particle size is uniform, it is possible to manufacture monodisperse particles without aggregation among particles, a uniform coating can be applied, that is suitable to large-scale production, and that can obtain high-resolution images by maintaining the toner electric charge and electric charge distribution; and the developer included in said titania nanoparticles.
    Type: Application
    Filed: September 4, 2009
    Publication date: August 4, 2011
    Applicant: Sukgyung AT Co., Ltd.
    Inventors: Hyung Sup Lim, Hyung Joon Lim, Young Cheol Yoo, Osung Kwon
  • Patent number: 7988780
    Abstract: A method of predicting photostability of coatings with various dopants on titanium dioxide pigment particles is disclosed. Calculations of the density of states show that a doped coating which reduces the density of states near the band edge or increases the density of states within the band gap of the pigment particles increases the photostability of the doped pigment.
    Type: Grant
    Filed: July 26, 2010
    Date of Patent: August 2, 2011
    Assignee: Kronos International Inc
    Inventors: Siegfried Bluemel, Lydia Drews-Nicolai
  • Publication number: 20110180769
    Abstract: A method for producing microcrystalline titanium dioxide in the rutile form having a crystal size below 15 nm by an aqueous method, and a titanium dioxide product doped with silicon obtained by the method. The method generally includes adding a silicon containing compound during crystal formation to provide said titanium dioxide product with a small crystal size.
    Type: Application
    Filed: June 30, 2009
    Publication date: July 28, 2011
    Applicant: SACHTLEBEN PIGMENTS OY
    Inventors: Ralf-Johan Lamminmäki, Johanna Niinimäki
  • Publication number: 20110183833
    Abstract: The disclosed subject matter relates to ceramic powders coated with a layer of nanoparticles of multiple crystalline structures and processes for obtaining the same. These coatings can be obtained by means of the introduction of precursors in water in oil emulsions, which upon decomposition during its detonation, form the nanoparticles that adhere to the surface of the ceramic powder intended to coat. The later base ceramic powder can be synthesized during the emulsion detonation (W/O) or simply be directly placed in its composition. The properties of the obtained coating, such as thickness, adhesion, porosity and coated surface percentage, can be adjusted according to the application desired. The ceramic powders coated can applicable to several types of areas of nanotechnology, such as electronics, biomedicine, chemistry, ceramics, energy industries, and the like.
    Type: Application
    Filed: October 13, 2008
    Publication date: July 28, 2011
    Inventors: João Manuel Calado Da Silva, Elsa Marisa Dos Santos Antunes
  • Patent number: 7985389
    Abstract: A method for producing pig iron by direct processing of ferrotitania sands, by the steps of: (a) mixing carbonaceous reductant, a fluxing agent, and a binder with titanium-containing materials selected from iron sands, metallic oxides, and/or iron ore concentrates, to form a mixture; (b) forming agglomerates from the mixture (c) introducing the agglomerates to a melting furnace; (d) melting the agglomerates at a temperature of from 1500 to 1760 C and forming hot metal with a slag thereon; (e) removing the slag; (f) tapping the hot metal; and (g) recovering the titanium and vanadium values.
    Type: Grant
    Filed: August 12, 2008
    Date of Patent: July 26, 2011
    Assignee: Cardero Resource Corporation
    Inventor: Glenn E. Hoffman
  • Publication number: 20110160047
    Abstract: “It has been demanded to produce titanium dioxide having an excellent photocatalytic activity and an excellent super-hydrophilic property by a simple procedure suitable for the production on an industrial scale. Rutile-type titanium dioxide having an excellent photocatalytic activity can be produced by carrying out the anodic oxidization of the surface of a base material comprising titanium or a titanium alloy by applying a voltage (e.g., a high voltage) or carrying out the anodic oxidation of the surface of the base material under high current density conditions. Further, a film is produced on the surface of the base material by the anodic oxidation technique by applying a voltage or the anodic oxidization technique under high current density conditions, and the film is subjected to heat treatment, thereby producing rutile-type titanium dioxide having excellent crystallinity.
    Type: Application
    Filed: May 26, 2009
    Publication date: June 30, 2011
    Inventors: Naoya Masahasshi, Yoshiteru Mizukoshi, Naofumi Ootsu, Yu Matsuda, Satoshi Senboshi
  • Publication number: 20110150752
    Abstract: A method of synthesizing nanoparticles, comprising providing a precursor comprising a titanium alkoxide compound; forming a plasma from oxygen gas at a first location, wherein the plasma comprises plasma products that contain oxygen atoms; causing the plasma products to flow to a second location remote from the first location; contacting the precursor with the plasma products at the second location so as to oxidize the precursor and form nanoparticles; and collecting the nanoparticles with a collector.
    Type: Application
    Filed: December 17, 2010
    Publication date: June 23, 2011
    Inventors: Rajesh K. Katare, Moses M. David
  • Publication number: 20110150753
    Abstract: The present invention relates to a method for preparing anatase-type titanium dioxide (TiO2) nanoparticles, the method comprising the steps of: uniformly mixing titanium n-butoxide and cetyltrimethyl ammonium salt (CTAS) in water; subjecting the mixture to hydrothermal treatment at a temperature of 60˜120° C.; and collecting anatase-type titanium dioxide nanoparticles produced by the hydrothermal treatment and drying the collected nanoparticles. According to the present invention, anatase-type titanium dioxide nanoparticles having excellent crystallinity can be easily prepared in large amounts by a simple process without needing heat treatment.
    Type: Application
    Filed: February 18, 2011
    Publication date: June 23, 2011
    Applicant: Korea Basic Science Institute
    Inventors: Hae jin Kim, Soon Chang Lee, Jin Bae Lee
  • Publication number: 20110144406
    Abstract: The invention provides a catalyst for thermal decomposition of an organic substance having the form of spherical granule having a particle diameter of 0.1 to 1.2 mm, a pore volume of 0.1 to 0.3 mL/g, a tap density of 1.05 to 1.4 g/mL, and a wear rate of 2% by weight or less, the catalyst being obtained by mixing and granulating a pulverized product of an inorganic oxide exemplified by titanium oxide with at least one sol selected from a titania sol, a silica sol, an alumina sol, and a zirconia sol to make spherical granules, calcining the spherical granules at a temperature from 400 to 850° C., and sieving the calcined granules.
    Type: Application
    Filed: August 18, 2009
    Publication date: June 16, 2011
    Inventors: Mitsuru Masatsugu, Toshikatsu Umaba, Itsushi Kashimoto
  • Publication number: 20110143923
    Abstract: The present invention relates to a titanium dioxide composition which comprises titanium dioxide nanoparticles, its preparation and use.
    Type: Application
    Filed: June 2, 2009
    Publication date: June 16, 2011
    Applicant: BASF SE
    Inventors: Virginie Bette, Roelof Balk, Alexandre Terrenoire, Harm Wiese, Ekkehard Jahns, Matthias Ballauff, Yan Lu, Martin Hoffmann
  • Publication number: 20110123409
    Abstract: The invention relates to a chemical reactor with a nanometric superstructure, comprising at least one member wherein at least one reaction chamber is arranged, and said reaction chamber being filled at least partially with a high specific surface area material having a specific surface area greater than 5 m2/g, and characterised in that said high specific surface area material is selected from nanotubes or nanofibres. These nanotubes or nanofibres are preferably selected in the group consisting of carbon nanofibres or nanotubes, ?-SiC nanofibres or nanotubes, TiO2 nanofibres or nanotubes. They may be deposited on an intermediate structure selected in the group consisting of glass fibres, carbon fibres, SiC foams, carbon foams, alveolar ?-SiC foams, said intermediate structure filling the reaction chamber of said reactor at least partially.
    Type: Application
    Filed: November 26, 2008
    Publication date: May 26, 2011
    Inventors: Cuong Phamhuu, Nicolas Keller, Marc Jacques Ledoux, Izabella Janowska, David Edouard, Valérie Keller-Spitzer, Thierry Romero, Liu Yu
  • Patent number: 7947249
    Abstract: The present invention relates to fine hollow powder with a titanium oxide shell, obtained by spray drying an exfoliated titania sol, and thin flaky titanium oxide powder obtained by pulverizing the fine hollow powder, and also to processes for producing the same. The present fine hollow powder and thin flaky titanium oxide powder have a distinguished dispersibility and are useful for additives to cosmetics, pigments, paints, etc., and the present fine hollow powder also has a distinguished flowability and is useful for seed particles for flow measurement.
    Type: Grant
    Filed: June 22, 2007
    Date of Patent: May 24, 2011
    Assignee: Ishihara Sangyo Kaisha, Ltd.
    Inventors: Takayoshi Sasaki, Mamoru Watanabe, Yuichi Michiue, Masaki Iida
  • Patent number: 7943114
    Abstract: The present invention relates to fine hollow powder with a titanium oxide shell, obtained by spray drying an exfoliated titania sol, and thin flaky titanium oxide powder obtained by pulverizing the fine hollow powder, and also to processes for producing the same. The present fine hollow powder and thin flaky titanium oxide powder have a distinguished dispersibility and are useful for additives to cosmetics, pigments, paints, etc., and the present fine hollow powder also has a distinguished flowability and is useful for seed particles for flow measurement.
    Type: Grant
    Filed: June 22, 2007
    Date of Patent: May 17, 2011
    Assignee: Ishihara Sangyo Kaisha, Ltd.
    Inventors: Takayoshi Sasaki, Mamoru Watanabe, Yuichi Michiue, Masaki Iida