Titanium Dioxide Patents (Class 423/610)
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Patent number: 8168145Abstract: The present invention provides a porous titanium oxide having improved ultraviolet protection ability, usability, and transparency in the visible region and a process for producing thereof. The porous titanium oxide powder according to the present invention can be obtained by adding an alkali to a titanium salt solution containing a polyalcohol and then thermally hydrolyzing the solution. In addition, it is possible that after the addition of the alkali, an acid is further added to the solution and then the thermal hydrolysis is conducted, or that after thermal hydrolysis, further heat treatment with an acid is conducted. A porous titanium oxide has a mean particle size of 0.01 to 1.0 ?m and a specific surface area of 50 m2/g or more.Type: GrantFiled: September 21, 2007Date of Patent: May 1, 2012Assignee: Shiseido Company Ltd.Inventors: Masayoshi Wada, Shoichiro Shio
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Patent number: 8168562Abstract: A new method for preparing supported palladium-gold catalysts is disclosed. The method comprises sulfating a titanium dioxide support, calcining the sulfated support, impregnating the calcined support with a palladium salt, a gold salt, and an alkali metal or ammonium compound, calcining the impregnated support, and reducing the calcined support. The resultant supported palladium-gold catalysts have increased activity and stability in the acetoxylation.Type: GrantFiled: February 2, 2006Date of Patent: May 1, 2012Assignee: Lyondell Chemical Technology, L.P.Inventor: Steven M. Augustine
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Publication number: 20120097071Abstract: This invention pertains to a mesoporous amorphous oxide of titanium and processes of making a mesoporous amorphous oxide of titanium.Type: ApplicationFiled: December 21, 2011Publication date: April 26, 2012Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventor: CARMINE TORARDI
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Patent number: 8148289Abstract: A titanium oxide photocatalyst that is capable of improving a decomposition rate, and a method for producing the same are provided. The titanium oxide photocatalyst of the present invention is a titanium oxide photocatalyst containing at least an anatase-type titanium oxide and fluorine, wherein a content of the fluorine is 2.5 wt % to 3.5 wt %, and 90 wt % or more of the fluorine is chemically bonded to the anatase-type titanium oxide.Type: GrantFiled: April 18, 2008Date of Patent: April 3, 2012Assignees: Panasonic Corporation, Sakai Chemical Industry Co., Ltd.Inventors: Noboru Taniguchi, Shuzo Tokumitsu, Tomohiro Kuroha, Kenichi Tokuhiro, Akio Nakashima, Keita Kobayashi, Shinji Nakahara
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Publication number: 20120067405Abstract: An anatase-type titania crystal having a one-dimensional structure; a process for producing the crystal; and a dye-sensitized solar cell employing the titania crystal. The titania crystal is excellent in photocatalytic characteristics and photoelectric conversion characteristics. The process for titania crystal production is characterized by comprising: a mixing step in which an aqueous solution containing a block copolymer (A) having a hydrophobic block and a hydrophilic block is mixed with an organic solvent (C) containing a titanium alkoxide (B) dissolved therein to thereby give a liquid mixture; a reaction step in which the temperature of the liquid mixture is set at a value in the range of from 120° C. to 180° C. and the pressure of the atmosphere is set so as to result in the saturated vapor pressure at that set temperature to thereby react the liquid mixture and form a titania sol; and a baking step in which the titania sol is heated to produce baked titania particles having a wire shape.Type: ApplicationFiled: August 6, 2008Publication date: March 22, 2012Applicant: ROHM CO., LTD.Inventors: Jinting Jiu, Seiji Isoda, Motonari Adachi, Naoki Yoshimoto
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Publication number: 20120070719Abstract: According to one embodiment, a negative electrode active material for nonaqueous electrolyte battery includes a titanium oxide compound having a crystal structure of monoclinic titanium dioxide. When a monoclinic titanium dioxide is used as the active material, the effective capacity is significantly lower than the theoretical capacity though the theoretical capacity was about 330 mAh/g. The invention comprises a titanium oxide compound which has a crystal structure of monoclinic titanium dioxide and a (001) plane spacing of 6.22 ? or more in the powder X-ray diffraction method using a Cu-K? radiation source, thereby making an attempt to improve effective capacity.Type: ApplicationFiled: September 21, 2011Publication date: March 22, 2012Applicant: KABUSHIKI KAISHA TOSHIBAInventors: Yasuhiro HARADA, Norio Takami, Hiroki Inagaki, Keigo Hoshina
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Patent number: 8137647Abstract: Provided are processes for the production of titanium dioxide from ilmenite. In these processes, ilmenite is digested with aqueous ammonium hydrogen oxalate. Iron from the ilmenite precipitates as a hydrated iron oxalate and is removed by filtering, leaving a titanium-rich solution. The titanium-rich solution can be further processed to form titanium dioxide.Type: GrantFiled: December 28, 2006Date of Patent: March 20, 2012Assignee: E. I. du Pont de Nemours and CompanyInventors: David Richard Corbin, Thomas Paul Griffin, Keith W. Hutchenson, Sheng Li, Mark Brandon Shiflett, Carmine Torardi, Joseph J. Zaher
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Publication number: 20120040162Abstract: A method of forming a high-k dielectric material including forming at least two portions of titanium dioxide, the at least two portions of titanium dioxide comprising a first portion comprising amorphous titanium dioxide and a second portion comprising rutile titanium dioxide. A method of forming a high-k dielectric material including forming a first portion of titanium dioxide at a temperature of from about 150° C. to about 350° C. and forming a second portion of titanium dioxide at a temperature of from about 350° C. to about 600° C. A high-k dielectric material is also disclosed.Type: ApplicationFiled: August 11, 2010Publication date: February 16, 2012Applicant: MICRON TECHNOLOGY, INC.Inventors: Tsai-Yu Huang, Ching-Kai Lin
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Patent number: 8114376Abstract: The manufacture of titanium dioxide by oxidation of titanium tetrachloride in a multistage method, where both oxygen and titanium tetrachloride are added in several stages. In the first stage gaseous TiCl4 is introduced into a preheated oxygen-containing gaseous stream in a stoichiometric or hyper-stoichiometric amount to produce a TiO2 containing gas suspension. In the second or further stages liquid TiCl4 and oxygen-containing gas is introduced into the TiO2 containing gas suspension to produce further TiO2.Type: GrantFiled: September 26, 2008Date of Patent: February 14, 2012Assignee: Kronos International, Inc.Inventor: Rainer Gruber
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Patent number: 8114377Abstract: This disclosure relates to process for producing titanium dioxide pigment having reduced chlorides, comprising: a) reacting titanium tetrahalide vapor, rutile-forming agent and at least a stoichiometric amount of oxygen in a reactor to form a gaseous suspension comprising titanium dioxide particles; b) introducing silicon tetrachloride into the reactor at least one point downstream of the point of contact of the titanium tetrahalide, the rutile forming agent and the oxygen, and where at least 97% of the titanium tetrahalide has been converted to titanium dioxide to provide a substantially uniform encapsulation of pyrogenic SiO2 on the titanium dioxide; c) passing the gaseous suspension to a cooling conduit; d) introducing scouring material, typically selected from the group of calcined titanium dioxide and compressed titanium dioxide, and mixtures thereof, into the cooling conduit; wherein the particles of the scouring material have a diameter in the range of about 0.25 mm to about 12.Type: GrantFiled: November 2, 2006Date of Patent: February 14, 2012Assignee: E.I. du Pont de Nemours and CompanyInventors: Alan Roger Eaton, Rajeev Lochan Gorowara, Narayanan Sankara Subramanian, Stephen William Taylor
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Patent number: 8106101Abstract: This invention relates to methods of making single phase nanocrystalline titanium dioxide. It is hereby provided a method for preparing single-phase anatase type titanium dioxide photocatalyst having a particle size of nano level at near room temperatures without the need for a sintering process at high temperatures.Type: GrantFiled: July 13, 2007Date of Patent: January 31, 2012Assignee: The Hong Kong Polytechnic UniversityInventors: Walid Abdelhamld Daoud, John Haozhong Xin, Kaihong Qi
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Patent number: 8101152Abstract: A titanium halide, preferably titanium tetrachloride, is reacted with suitable reductant, preferably an alkali metal or alkaline earth metal, under ultrasonic excitation in a liquid reaction medium to form nanometer size particles of titanium which may incorporate unreacted reductant. The nanosized titanium particles may be a precursor for nanosized titanium oxide which is formed by oxidizing the titanium, preferably with a low molecular weight alcohol. When the titanium particles incorporate unreacted reductant the oxidation reaction will yield nanometer sized titanates. The nanosized particles, whether titanium oxide or titanates may be extracted by first filtering them from the reaction medium, followed by washing with water to remove any water-soluble reaction products followed by spray drying.Type: GrantFiled: August 18, 2010Date of Patent: January 24, 2012Assignee: GM Global Technology Operations LLCInventors: Ion C. Halalay, Michael P. Balogh
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Patent number: 8097233Abstract: The present invention relates to the synthesis of nanoparticles by laser hydrolysis. For this purpose, a precursor interacts with a laser beam (LAS) in a pyrolysis reactor (REAC) for producing nanoparticles (nP), characterized in that the precursor is firstly in the liquid state and is then converted into the vapor phase and in that the flow rate of the precursor is controlled in the liquid phase.Type: GrantFiled: January 22, 2008Date of Patent: January 17, 2012Assignee: Commissariat a l'Energie AtomiqueInventor: Dominique Porterat
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Publication number: 20110318249Abstract: Disclosed is a porous metal oxide obtained by subjecting metal alkoxide and/or a partially hydrolyzed condensate of the metal alkoxide to a sol-gel reaction in the presence of terminally branched copolymer particles represented by the following general formula (1) and having a number average molecular weight of not more than 2.Type: ApplicationFiled: March 12, 2010Publication date: December 29, 2011Applicant: MITSUI CHEMICALS, INC.Inventors: Norio Nakayama, Toshihiko Takaki, Haruhiko Fukumoto, Kaori Matoishi, Shiro Nakatsuka, Naoshi Nagai, Eiichi Takahashi, Yukiko Enomoto
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Patent number: 8083950Abstract: The present invention relates to a method for recovering an organic-inorganic element-doped metal oxide from a hydrolysable metal compound, accompanied with contaminated water treatment. The present invention comprises steps of: a) adding a hydrolysable metal compound as a coagulant to a contaminated water to form a separable floc between the hydrolysable metal compound and contaminants present in contaminated water; b) separating the separable floc and the pre-treated water after flocculation treatment; and c) calcinating the separated floc over 500° C. to produce an organic-inorganic element-doped metal oxide. More preferably, the present invention further comprises subjecting the pre-treated water of the step b) to a microwave treatment to cause a photocatalytic degradation of an organic contaminant that remains in the pre-treated water, with the assistance of the remaining hydrolysable metal compound.Type: GrantFiled: January 18, 2006Date of Patent: December 27, 2011Assignees: Photo & Environmental Technology Co., Ltd., University of Technology, SydneyInventors: Hokyong Shon, Vigneswaran Saravanamuthu, Erdei Laszlo, Jong Ho Kim, Jong Beom Kim, Dong Lyun Cho, Byung Chul Choi, Kun Jung Kim, Myung Wan Kim, Sung Jung Song, Hee Ju Park, Jaeweon Cho, In-soo Kim, Seung-hyun Kim
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Publication number: 20110301270Abstract: The invention provides a dispersion of particles of rutile titanium oxide wherein the particles of rutile titanium oxide have a D50 in a range of 1 to 15 nm and a D90 of 40 nm or less in particle size distribution as determined by a dynamic light scattering method; a specific surface area in a range of 120 to 180 m2/g as determined by a BET method; and a rate of weight loss of 5% or less as obtained by heating the particles of rutile titanium oxide from 105° C. to 900° C.Type: ApplicationFiled: February 15, 2010Publication date: December 8, 2011Inventors: Atsushi Nomura, Kenichi Nakagawa, Takanori Morita
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Patent number: 8071070Abstract: Provided is a crystalline TiO2 powder in the form of aggregated primary particles having a variable sintering stability at a BET surface area of 70-100 m2/g and a rutile content of greater than 10% but less than or equal to 40%, and a process for preparing the crystalline TiO2 powder, which involves: introducing a TiCl4 vapor and, separately therefrom, H2 and a primary air into a mixing chamber to produce a gaseous mixture; igniting the gaseous mixture in a burner to produce a flame, which is burned into a reaction chamber to produce the crystalline TiO2 powder and gaseous substances; and separating the crystalline TiO2 powder from the gaseous substances, wherein the relative amounts of TiCl4 vapor, H2 and primary air are selected to provide crystalline TiO2 powder having the aforementioned BET surface area and rutile content, with the proviso that factor A has a value of 0.1-0.4 g/m2 in accordance within the following formula: factor A=105{[(TiCl4 vapor×H2)/(amount of air×gaseous mixture)]/BET]}.Type: GrantFiled: May 24, 2010Date of Patent: December 6, 2011Assignee: Evonik Degussa GmbHInventors: Christian Schulze-Isfort, Kai Schumacher, Nina Schuhardt, Oswin Klotz, Rainer Golchert
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Patent number: 8071069Abstract: The invention relates to a process for the purification of titania by treating the titania with an aqueous solution having one or more ammonium compounds at elevated temperatures, separating the titania from the aqueous solution, drying the titania and, optionally, calcining the dried titania. More especially the invention relates to the removal of sulphur (mainly present in the form of sulphate compounds) from the titania. The titania purified according to the above process is especially suitable for use as a catalyst carrier.Type: GrantFiled: August 9, 2002Date of Patent: December 6, 2011Assignee: Shell Oil CompanyInventors: Abderrahmane Chettouf, Carolus Matthias Anna Maria Mesters, Gerardus Petrus Lambertus Niesen
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PROCESS OF MAKING NANO-SCALE INTEGRATED TITANIA PARTICLES FOR LITHIUM BATTERY ELECTRODE APPLICATIONS
Publication number: 20110293507Abstract: A process includes reacting a titanium compound with an oxalate compound in an acidic medium to form a titanium oxalate complex, where the titanium oxalate complex includes primary and secondary particles. The primary titanium oxalate complex particles may be from about 1 nm to about 200 nm; and the secondary titanium oxalate complex particles may be from about 0.5 ?m to 50 ?m. The titanium oxalate complex may be sintered to prepare a titania-based compound. The titania-based compounds may be used to fabricate electrodes for electrochemical cells.Type: ApplicationFiled: May 4, 2011Publication date: December 1, 2011Inventors: Damien Dambournet, Ilias Belharouak, Khalil Amine -
Patent number: 8062621Abstract: A method of manufacturing titanium dioxide particles can produce titanium dioxide particles where a rare earth element is substituted at the titanium sites from which it is possible to highly efficiently take out fluorescence attributable to the rare earth element The method of manufacturing titanium dioxide particles doped with a rare earth element comprises a step of preparing a liquid precursor containing a titanium source and rare earth metal source, the doping ratio of the rare earth element in the liquid precursor being within a range not less than 0 at % and not more than 5.Type: GrantFiled: June 15, 2006Date of Patent: November 22, 2011Assignee: National Institute For Materials ScienceInventors: Jiguang Li, Takamasa Ishigaki
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Patent number: 8062622Abstract: A crystalline titanium dioxide powder, containing aggregated primary particles, wherein a BET surface area of the aggregated primary particles is from 30 to 65 m2/g, and a rutile content of a sum of crystalline modifications in the crystalline titanium dioxide is from of 50-70%.Type: GrantFiled: December 10, 2009Date of Patent: November 22, 2011Assignee: Evonik Degussa GmbHInventors: Christian Schulze-Isfort, Oswin Klotz, Rainer Golchert, Uwe Diener, Kai Schumacher
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Publication number: 20110268956Abstract: The invention relates to a process for obtaining ceramic coatings and ceramic coatings obtained. This process allows obtaining coatings of ceramic oxides, such as ZrO2, Al2O3, TiO2, Cr2O3, Y2O3, SiO2, CaO, MgO, CeO2, Sc2O3, MnO, and/or complex mixtures thereof, by means of a high frequency pulse detonation technique in which the relative movement between the combustion stream and the substrate or piece to be coated takes place at a speed that produces an overlap between the successive coating areas exceeding 60% of the surface of a coating area. The allows producing ceramic coatings with a thickness greater than 30 microns in a single pass.Type: ApplicationFiled: May 12, 2006Publication date: November 3, 2011Applicant: FUNDACION INASMETInventors: Inaki Fagoaga Altuna, Maria Parco Camacaro, Georgiy Barikyn, Carlos Vaquero Gonzalez
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Patent number: 8048398Abstract: Process for preparing a mixed metal oxide powder, in which oxidizable starting materials are evaporated and oxidized, the reaction mixture is cooled after the reaction and the pulverulent solids are removed from gaseous substances, wherein as starting materials, at least one pulverulent metal and at least one metal compound, the metal and the metal component of the metal compound being different and the proportion of metal being at least 80% by weight based on the sum of metal and metal component from metal compound, together with one or more combustion gases, are fed to an evaporation zone of a reactor, where metal and metal compound are evaporated completely under nonoxidizing conditions, subsequently, the mixture flowing out of the evaporation zone is reacted in the oxidation zone of this reactor with a stream of a supplied oxygen-containing gas whose oxygen content is at least sufficient to oxidize the starting materials and combustion gases completely.Type: GrantFiled: May 9, 2007Date of Patent: November 1, 2011Assignee: Evonik Degussa GmbHInventors: Stipan Katusic, Guido Zimmermann, Michael Kraemer, Peter Kress, Horst Miess
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Patent number: 8048399Abstract: It is provided ultrafine particles of a rutile titanium oxide obtained by maintaining the pH of an aqueous solution of a titanium compound having a Ti concentration of from 0.07 to 5 mol/L in the range of ?1 to 3 in the presence of a chelating agent. Such ultrafine particles of a rutile titanium oxide are useful for photocatalysts, high refractive index materials, ultraviolet absorbing materials and the like.Type: GrantFiled: December 3, 2009Date of Patent: November 1, 2011Assignee: Mitsui Chemicals, Inc.Inventors: Toyoharu Hayashi, Norio Nakayama, Tomonori Iijima
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Publication number: 20110250126Abstract: The present invention is related to a family of Group 4 metal precursors represented by the formula: M(OR1)2(R2C(O)C(R3)C(O)OR1)2 wherein M is a Group 4 metals of Ti, Zr, or Hf; wherein R1 is selected from the group consisting of a linear or branched C1-10 alkyl and a C6-12 aryl, preferably methyl, ethyl or n-propyl; R2 is selected from the group consisting of branched C3-10 alkyls, preferably iso-propyl, tert-butyl, sec-butyl, iso-butyl, or tert-amyl and a C6-12 aryl; R3 is selected from the group consisting of hydrogen, C1-10 alkyls, and a C6-12 aryl, preferably hydrogen. In a preferred embodiment of this invention, the precursor is a liquid or a solid with a melting point below 60° C.Type: ApplicationFiled: October 14, 2010Publication date: October 13, 2011Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Sergei Vladimirovich Ivanov, Xinjian Lei, Hansong Cheng, Daniel P. Spence, Moo-Sung Kim
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Patent number: 8034743Abstract: To provide a method of production of an exhaust gas purification catalyst support preventing a drop in the heat resistance of alumina or other catalyst support due to the presence of titania and provided with a sulfur poisoning suppression action by titania and an exhaust gas purification catalyst support produced by the same. A method of production of an exhaust gas purification catalyst support comprising, in a basic solution, making alumina particles adsorb ammonium ions and then bringing titania sol into contact with the alumina particle so as to make the alumina particles adsorb the titania particles. An exhaust gas purification catalyst support where at least base points on the alumina particle surfaces adsorb titania particles and the pH does not rise when immersed in an ammonium nitrate solution.Type: GrantFiled: June 25, 2008Date of Patent: October 11, 2011Assignee: Toyota Jidosha Kabushiki KaishaInventors: Shinichi Takeshima, Akio Koyama
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Patent number: 8029754Abstract: The present invention relates to cerium oxide powder and a process for producing the same. The cerium oxide powder of the invention, which is produced by mixing a cerium source such as cerium oxide, cerium hydroxide and cerium carbonate with an alkali metal compound, as flux, and performing high temperature treatment, may have a variety particle size while having spherical shape.Type: GrantFiled: July 28, 2005Date of Patent: October 4, 2011Assignee: LG Chem, Ltd.Inventors: Jun-seok Nho, Jang-yul Kim, Myoung-hwan Oh, Jong-pil Kim, Seung-beom Cho
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Patent number: 8029763Abstract: The present invention is drawn to a method for removing colloidal titanium dioxide and titanium oxychloride from by-product hydrochloric acid. The method includes adding phosphate ion source and quaternary amine to the by-product acid to cause the titanium dioxide and the titanium oxychloride to form a precipitate. The precipitate can then be separated from the acid, thus producing a decontaminated hydrochloric acid product with reduced levels of titanium.Type: GrantFiled: March 2, 2010Date of Patent: October 4, 2011Assignee: Haydock Consulting Services, LCInventor: Frederick Haydock
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Patent number: 8025861Abstract: Titanium oxide (usually titanium dioxide) catalyst support particles are doped for electronic conductivity and formed with surface area-enhancing pores for use, for example, in electro-catalyzed electrodes on proton exchange membrane electrodes in hydrogen/oxygen fuel cells. Suitable compounds of titanium and a dopant are dispersed with pore-forming particles in a liquid medium. The compounds are deposited as a precipitate or sol on the pore-forming particles and heated to transform the deposit into crystals of dopant-containing titanium dioxide. If the heating has not decomposed the pore-forming particles, they are chemically removed from the, now pore-enhanced, the titanium dioxide particles.Type: GrantFiled: March 3, 2010Date of Patent: September 27, 2011Assignees: GM Global Technology Operations LLC, Administrators of the Tulane Educational FundInventors: Mei Cai, Yunfeng Lu, Zhiwang Wu, Lee Lizhong Feng, Martin S. Ruthkosky, John T. Johnson, Frederick T. Wagner
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Publication number: 20110229793Abstract: A metal oxide electrode catalyst which includes a metal oxide (Y) obtained by heat treating a metal compound (X) under an oxygen-containing atmosphere. The valence of the metal in the metal compound (X) is smaller than the valence of the metal in the metal oxide (Y). Further, the metal oxide electrocatalyst has an ionization potential in the range of 4.9 to 5.5 eV.Type: ApplicationFiled: July 23, 2008Publication date: September 22, 2011Applicant: SHOWA DENKO K.K.Inventors: Tadatoshi Kurozumi, Toshikazu Shishikura, Hiroshi Konuma
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Patent number: 8021634Abstract: A sulfate process for producing titania from a titaniferous material (such as an iron-containing titaniferous material such as ilmenite) is disclosed. The process includes digestion and/or leach steps that form a process solution that includes an acidic solution of titanyl sulfate (TiOSO4) and iron sulfate (FeSO4) from the solid titaniferous material. The process also includes hydrolysis and other steps that form titania from the titanyl sulfate in the process solution. The process is characterised by a ferric ion treatment step of treating the process solution and lowering the concentration of ferric ions from the process solution.Type: GrantFiled: September 6, 2007Date of Patent: September 20, 2011Assignee: BHP Billiton Innovation Pty. Ltd.Inventors: Eric Girvan Roche, Philip Ernest Grazier, Alan David Stuart
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Publication number: 20110217222Abstract: Aqueous leachant compositions and processes for using the same comprising: (a) providing a metal-containing compound; and (b) subjecting the metal-containing compound to an acid digestion comprising contacting the metal-containing compound with an aqueous leachant; wherein the aqueous leachant comprises a mixture selected from the group consisting of: (i) sulfuric acid and one or more alkanesulfonic acids having alkane moieties selected from the group consisting of propyl, ethyl and methyl groups, at a weight ratio of alkanesulfonic acid to sulfuric acid of 1:1000 to 1:1; (ii) sulfuric acid and one or more salts of alkanesulfonic acids having alkane moieties selected from the group consisting of propyl, ethyl and methyl groups, at a weight ratio of salt of alkanesulfonic acid to sulfuric acid of 1:9 to 1:99.Type: ApplicationFiled: May 12, 2011Publication date: September 8, 2011Applicant: BASF SEInventors: Thomas Heidenfelder, Helmut Witteler, Bernd Laubusch, Hans-Peter Seelmann-Eggebert
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Patent number: 8012451Abstract: A highly photosensitivity titanium oxide composition includes a plurality of nanosize particles including titanium dioxide and titanium suboxide. The particles are substantially non-stoichiometric (TiO2-x, wherein 0.1<x<0.3 at a surface of the particles, and in the bulk of the particles x is less than at the surface), provide a magnetic susceptibility value (X) of at least 0.8 10?6 cm3/g at 300 K, and are least 30% by weight rutile. A related method of forming a high photosensitivity titanium oxide composition includes the steps of providing a titanium chloride compound, such as titanium tetrachloride, an oxygen-containing gas and hydrogen, wherein a concentration of the hydrogen is in a stoichiometric excess (H2:O2) from 2.02:1 to 2.61:1. The titanium chloride compound is burned in the presence of oxygen from the oxygen-containing gas and hydrogen to form plurality of ultrafine particles comprising titanium dioxide and titanium suboxide.Type: GrantFiled: December 13, 2007Date of Patent: September 6, 2011Assignee: Worthington Technologies, LLCInventors: Ihor M. Kobasa, Wojciech J. Strus, Mykhaylo A. Kovbasa
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Patent number: 7998453Abstract: The disclosure pertains to a process for making a suspension of finely divided titanium (IV) oxide particles, comprising: vigorously mixing (a) a volume of a first component comprising a major proportion of an alcohol, a minor proportion of a titanium alkoxide and a minor proportion of a titanium alkoxide activator selected from the group consisting of water and a first aqueous base, and (b) a volume of a second component selected from the group consisting of water and a second aqueous base, at least one of the first component or the second component having a base therein, the second component being substantially free of alcohol, to form a mixture comprising a suspension of finely divided titanium (IV) oxide particles, the mixture having a water to titanium molar ratio ranging from about 40 to about 1 to about 5000 to about 1, wherein the proportion of the titanium alkoxide, the proportion of the activator, the mixing vigor, and a ratio of the volume of the first component to the volume of the second compoType: GrantFiled: December 20, 2007Date of Patent: August 16, 2011Assignee: E.I. du Pont de Nemours and CompanyInventors: David M Scott, Carmine Torardi, Vladimir Grushin
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Patent number: 7998430Abstract: A reactor 20 has a plurality of tubular downcomers 32, 34, 36, 38, 40 and risers 42, 44, 46, 48, 50, joined by sections 86, 88 in a continuous serpentine path the tubes dimensioned to provide substantially plug flow conditions for solid and liquid reagents fed into a first downcomer 24 with the products extracted from final riser 52. The reactor 20 is designed for a desired residence time by the number, height and diameter of the tubes. The downcomers 24, 32, 34, 36, 38, 40 may include a bend to improve residence time and to thereby reduce the number of tubes required for a desired overall residence time. The reactor 20 can be used in a leaching operation for producing synthetic rutile, where a pre-treated feedstock including ilmenite, leucoxene or titania slag is leached with hot HCl.Type: GrantFiled: June 20, 2008Date of Patent: August 16, 2011Assignee: Austpac Resources N.L.Inventor: John Winter
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Publication number: 20110192322Abstract: The invention relates to a method of preparing a well-dispersable, rutile-structured, microcrystalline titanium dioxide product, a product prepared by the method, and an effect paint and a lacquer provided by means of the product. In the method, the titanium dioxide starting material is first treated with a base to have an alkaline pH value, after which it is treated with an acid to have a hydrochloric acid content of 8 to 30 g/l, neutralized, processed, and calcinated. In particular, the preparation method is characterized by the use of a pretreatment chemical before the calcination stage to improve the dispersability.Type: ApplicationFiled: August 15, 2008Publication date: August 11, 2011Inventors: Ralf-Johan Lamminmäki, Esa Latva-Nirva, Riitta Linho, Johanna Niinimäki, Visa Vehmanen
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Publication number: 20110189081Abstract: A method for synthesizing high quality crystalline anatase titanium dioxide having a substantial occurrence of (001) facets. Including the steps of combining a source of fluoride anions with a titanium precursor and subjecting the mixture to hydrolysis. A solvent can be combined with the source of fluoride anions and the titanium precursor prior to hydrolysis. The crystalline anatase titanium dioxide can be produced to have the highly reactive (001) facets predominant by area in a variety of crystal structures, such as nanosheets.Type: ApplicationFiled: March 25, 2009Publication date: August 4, 2011Inventors: Gao Qing Lu, Shizhang Qiao, Huagui Yang
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Publication number: 20110189605Abstract: The present invention relates to a method of manufacturing titania nanoparticles, and specifically to a method of manufacturing titania nanoparticles wherein the particle size is uniform, it is possible to manufacture monodisperse particles without aggregation among particles, a uniform coating can be applied, that is suitable to large-scale production, and that can obtain high-resolution images by maintaining the toner electric charge and electric charge distribution; and the developer included in said titania nanoparticles.Type: ApplicationFiled: September 4, 2009Publication date: August 4, 2011Applicant: Sukgyung AT Co., Ltd.Inventors: Hyung Sup Lim, Hyung Joon Lim, Young Cheol Yoo, Osung Kwon
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Patent number: 7988780Abstract: A method of predicting photostability of coatings with various dopants on titanium dioxide pigment particles is disclosed. Calculations of the density of states show that a doped coating which reduces the density of states near the band edge or increases the density of states within the band gap of the pigment particles increases the photostability of the doped pigment.Type: GrantFiled: July 26, 2010Date of Patent: August 2, 2011Assignee: Kronos International IncInventors: Siegfried Bluemel, Lydia Drews-Nicolai
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Publication number: 20110180769Abstract: A method for producing microcrystalline titanium dioxide in the rutile form having a crystal size below 15 nm by an aqueous method, and a titanium dioxide product doped with silicon obtained by the method. The method generally includes adding a silicon containing compound during crystal formation to provide said titanium dioxide product with a small crystal size.Type: ApplicationFiled: June 30, 2009Publication date: July 28, 2011Applicant: SACHTLEBEN PIGMENTS OYInventors: Ralf-Johan Lamminmäki, Johanna Niinimäki
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Publication number: 20110183833Abstract: The disclosed subject matter relates to ceramic powders coated with a layer of nanoparticles of multiple crystalline structures and processes for obtaining the same. These coatings can be obtained by means of the introduction of precursors in water in oil emulsions, which upon decomposition during its detonation, form the nanoparticles that adhere to the surface of the ceramic powder intended to coat. The later base ceramic powder can be synthesized during the emulsion detonation (W/O) or simply be directly placed in its composition. The properties of the obtained coating, such as thickness, adhesion, porosity and coated surface percentage, can be adjusted according to the application desired. The ceramic powders coated can applicable to several types of areas of nanotechnology, such as electronics, biomedicine, chemistry, ceramics, energy industries, and the like.Type: ApplicationFiled: October 13, 2008Publication date: July 28, 2011Inventors: João Manuel Calado Da Silva, Elsa Marisa Dos Santos Antunes
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Patent number: 7985389Abstract: A method for producing pig iron by direct processing of ferrotitania sands, by the steps of: (a) mixing carbonaceous reductant, a fluxing agent, and a binder with titanium-containing materials selected from iron sands, metallic oxides, and/or iron ore concentrates, to form a mixture; (b) forming agglomerates from the mixture (c) introducing the agglomerates to a melting furnace; (d) melting the agglomerates at a temperature of from 1500 to 1760 C and forming hot metal with a slag thereon; (e) removing the slag; (f) tapping the hot metal; and (g) recovering the titanium and vanadium values.Type: GrantFiled: August 12, 2008Date of Patent: July 26, 2011Assignee: Cardero Resource CorporationInventor: Glenn E. Hoffman
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Publication number: 20110160047Abstract: “It has been demanded to produce titanium dioxide having an excellent photocatalytic activity and an excellent super-hydrophilic property by a simple procedure suitable for the production on an industrial scale. Rutile-type titanium dioxide having an excellent photocatalytic activity can be produced by carrying out the anodic oxidization of the surface of a base material comprising titanium or a titanium alloy by applying a voltage (e.g., a high voltage) or carrying out the anodic oxidation of the surface of the base material under high current density conditions. Further, a film is produced on the surface of the base material by the anodic oxidation technique by applying a voltage or the anodic oxidization technique under high current density conditions, and the film is subjected to heat treatment, thereby producing rutile-type titanium dioxide having excellent crystallinity.Type: ApplicationFiled: May 26, 2009Publication date: June 30, 2011Inventors: Naoya Masahasshi, Yoshiteru Mizukoshi, Naofumi Ootsu, Yu Matsuda, Satoshi Senboshi
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Publication number: 20110150752Abstract: A method of synthesizing nanoparticles, comprising providing a precursor comprising a titanium alkoxide compound; forming a plasma from oxygen gas at a first location, wherein the plasma comprises plasma products that contain oxygen atoms; causing the plasma products to flow to a second location remote from the first location; contacting the precursor with the plasma products at the second location so as to oxidize the precursor and form nanoparticles; and collecting the nanoparticles with a collector.Type: ApplicationFiled: December 17, 2010Publication date: June 23, 2011Inventors: Rajesh K. Katare, Moses M. David
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Publication number: 20110150753Abstract: The present invention relates to a method for preparing anatase-type titanium dioxide (TiO2) nanoparticles, the method comprising the steps of: uniformly mixing titanium n-butoxide and cetyltrimethyl ammonium salt (CTAS) in water; subjecting the mixture to hydrothermal treatment at a temperature of 60˜120° C.; and collecting anatase-type titanium dioxide nanoparticles produced by the hydrothermal treatment and drying the collected nanoparticles. According to the present invention, anatase-type titanium dioxide nanoparticles having excellent crystallinity can be easily prepared in large amounts by a simple process without needing heat treatment.Type: ApplicationFiled: February 18, 2011Publication date: June 23, 2011Applicant: Korea Basic Science InstituteInventors: Hae jin Kim, Soon Chang Lee, Jin Bae Lee
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Publication number: 20110144406Abstract: The invention provides a catalyst for thermal decomposition of an organic substance having the form of spherical granule having a particle diameter of 0.1 to 1.2 mm, a pore volume of 0.1 to 0.3 mL/g, a tap density of 1.05 to 1.4 g/mL, and a wear rate of 2% by weight or less, the catalyst being obtained by mixing and granulating a pulverized product of an inorganic oxide exemplified by titanium oxide with at least one sol selected from a titania sol, a silica sol, an alumina sol, and a zirconia sol to make spherical granules, calcining the spherical granules at a temperature from 400 to 850° C., and sieving the calcined granules.Type: ApplicationFiled: August 18, 2009Publication date: June 16, 2011Inventors: Mitsuru Masatsugu, Toshikatsu Umaba, Itsushi Kashimoto
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Publication number: 20110143923Abstract: The present invention relates to a titanium dioxide composition which comprises titanium dioxide nanoparticles, its preparation and use.Type: ApplicationFiled: June 2, 2009Publication date: June 16, 2011Applicant: BASF SEInventors: Virginie Bette, Roelof Balk, Alexandre Terrenoire, Harm Wiese, Ekkehard Jahns, Matthias Ballauff, Yan Lu, Martin Hoffmann
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Publication number: 20110123409Abstract: The invention relates to a chemical reactor with a nanometric superstructure, comprising at least one member wherein at least one reaction chamber is arranged, and said reaction chamber being filled at least partially with a high specific surface area material having a specific surface area greater than 5 m2/g, and characterised in that said high specific surface area material is selected from nanotubes or nanofibres. These nanotubes or nanofibres are preferably selected in the group consisting of carbon nanofibres or nanotubes, ?-SiC nanofibres or nanotubes, TiO2 nanofibres or nanotubes. They may be deposited on an intermediate structure selected in the group consisting of glass fibres, carbon fibres, SiC foams, carbon foams, alveolar ?-SiC foams, said intermediate structure filling the reaction chamber of said reactor at least partially.Type: ApplicationFiled: November 26, 2008Publication date: May 26, 2011Inventors: Cuong Phamhuu, Nicolas Keller, Marc Jacques Ledoux, Izabella Janowska, David Edouard, Valérie Keller-Spitzer, Thierry Romero, Liu Yu
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Patent number: 7947249Abstract: The present invention relates to fine hollow powder with a titanium oxide shell, obtained by spray drying an exfoliated titania sol, and thin flaky titanium oxide powder obtained by pulverizing the fine hollow powder, and also to processes for producing the same. The present fine hollow powder and thin flaky titanium oxide powder have a distinguished dispersibility and are useful for additives to cosmetics, pigments, paints, etc., and the present fine hollow powder also has a distinguished flowability and is useful for seed particles for flow measurement.Type: GrantFiled: June 22, 2007Date of Patent: May 24, 2011Assignee: Ishihara Sangyo Kaisha, Ltd.Inventors: Takayoshi Sasaki, Mamoru Watanabe, Yuichi Michiue, Masaki Iida
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Patent number: 7943114Abstract: The present invention relates to fine hollow powder with a titanium oxide shell, obtained by spray drying an exfoliated titania sol, and thin flaky titanium oxide powder obtained by pulverizing the fine hollow powder, and also to processes for producing the same. The present fine hollow powder and thin flaky titanium oxide powder have a distinguished dispersibility and are useful for additives to cosmetics, pigments, paints, etc., and the present fine hollow powder also has a distinguished flowability and is useful for seed particles for flow measurement.Type: GrantFiled: June 22, 2007Date of Patent: May 17, 2011Assignee: Ishihara Sangyo Kaisha, Ltd.Inventors: Takayoshi Sasaki, Mamoru Watanabe, Yuichi Michiue, Masaki Iida