Abstract: In the process for recovering arsenic trioxide from scrubbing water used to scrub the flue gas of sulfide ore smelting, the crude arsenic trioxide crystals collected from the scrubbing solution which contains plaster as an impurity is purified by treating it with hydrochloric acid of a concentration of 50-150 g/l at a temperature not higher than 30.degree. C.

Abstract: Colloidal antimony oxide is produced by reacting hydrogen peroxide with antimony trioxide to form a colloidal salt of antimony oxide. In the reaction there is added to the reaction system 1.5 to 30 mol percent of an inorganic alkaline substance per mol of antimony trioxide.

Abstract: At least an equivalent amount of concentrated hydrochloric acid is added to antimony trioxide containing a substance emitting alpha rays, and they are stirred. Any undissolved residue is removed to prepare an aqueous solution of antimony chloride. Water is added to the solution, or a distillate obtained by distilling it at a temperature of at least 135.degree. C. The quantity of the water is at least 10 times by volume as much as the solution, or at least 20 times by volume as much as the distillate. The solution or distillate and the water are stirred at a temperature of at least 60.degree. C. to cause precipitation of antimony trioxide, and the precipitate is separated by filtration. The precipitate is washed with at least 10 times by weight as much warm water having a temperature of 60.degree. C., and dried. This antimony trioxide has an alpha-ray strength not exceeding 0.01 C/cm.sup.

Abstract: A process is provided for the production of antimony oxide from antimony sulfide which comprises the steps of comminuting the antimony sulfide to form a plurality of antimony sulfide containing particles, mixing the antimony sulfide containing particles with substantially pure oxygen, reacting the antimony sulfide with oxygen to form a gaseous stream of antimony oxide and sulfur dioxide, cooling the gaseous stream below the boiling point of antimony oxide, separating the condensed antimony oxide from the sulfur dioxide, further cooling the separated sulfur dioxide and utilizing the cooled sulfur dioxide to cool the gaseous stream of antimony oxide and sulfur dioxide. Apparatus for accomplishing this process is also provided.

Abstract: A process for producing arsenous acid is disclosed. The reactants include an organic solvent containing 5 valent arsenic, a reducing agent and an additional component selected from the group consisting of water and an aqueous solution. The organic solvent containing 5 valent arsenic contacts and reacts with the reducing agent in the presence of the water or aqueous solution in order to directly produce arsenous acid from the organic solvent containing 5 valent arsenic. The process is a simple and economical process for producing arsenous acid.

Abstract: Bromide ions when used as the redox intermediates in the oxidation of arsenic (III) oxide to arsenic (V) acid can be removed from a solution having a major proportion of arsenic acid by treatment with an oxidant selected from H.sub.2 O.sub.2, O.sub.3 or Cr(VI) to oxidize the bromide to bromine followed by purging with air, nitrogen or other inert gas to sweep out the resultant bromine. The bromine can be recovered and recycled to a fresh batch of arsenic (III) oxide.

Abstract: Arsenic anhydride of high purity is inexpensively manufactured from an arsenic sulfide-containing substance by first contacting the arsenic sulfide-containing substance with a copper sulfate-containing aqueous solution so as to provide an extract solution containing arsenious acid, the extract solution is subjected to aeration in the presence of copper ions such that the arsenious acid therein is mostly oxidized to arsenic acid, the thus provided treated solution is subjected to a weak reducing agent to cause crystals of arsenious anhydride to form, and these crystals are then recovered.

Abstract: Arsenic is recovered from flue dusts by forming an aqueous slurry of the dust, treating the slurry with SO.sub.2 gas to solubilize arsenic, and precipitating the arsenic as As.sub.2 O.sub.3 by means of sulfuric acid.

Abstract: The invention relates to a process for obtaining senarmontite and obtained senarmontite.The invention process consists in a direct hydrolysis of antimony trichloride by means of a basic solution, the hydrolysis being carried out in the presence of an oxidizing agent.Use: Obtention of senarmontite.

Abstract: The invention relates to a process for obtaining photostable valentinite and to valentinite obtained by said process.The process consists in carrying out a basic hydrolysis of antimony trichloride at a temperature comprised between about 80.degree. and 100.degree. C. with a weight ratio of H.sub.2 O/Sb.sub.2 O.sub.3 equal to or greater than about 10.Obtention of photostable valentinite.

Abstract: The present invention provides a process for the production of solid ion ductor materials (electrolytes) based on lithium or sodium compounds which stand in thermodynamic equilibrium with their alkali metal and have a high decomposition voltage, wherein two or more binary lithium or sodium compounds with an anion which is formed from one or more elements of the group consisting of nitrogen, phosphorus, arsenic, oxygen, sulphur, selenium, tellurium, hydrogen, fluorine, chlorine, bromine and iodine and which stand in thermodynamic equilibrium with their alkali metal are reacted together in such amounts and for such a period of time that a radiographically phase-pure product is formed.The present invention also provides ion conductor materials based on lithium or sodium compounds, which have the general formula:A.sub.3u+2v+w X.sub.u Y.sub.v Z.sub.

Abstract: Yellow iron oxide pigments having improved heat stability are prepared by mixing a conventional yellow iron oxide pigment with an aqueous alkaline solution of a soluble antimony compound. This yields a yellow pigment whose particle surface is coated with "antimony-bloom", and this product has a higher heat stability temperature than does the starting yellow iron oxide. When the product coated with "antimony-bloom" is subjected to hydrothermal treatment (autoclaving), the resultant material has a yet-higher heat stability temperature. Other, related treatments furnish products with improved heat stability temperatures.

Abstract: Sodium antimonate is made to react with an acid solution so as to transform a fraction of the sodium antimonate into pentavalent antimony oxide, thus producing a mixture of pentavalent antimony oxide and sodium antimonate, the so produced mixture is separated from the solution and that mixture is dried and pulverized. The so produced powder presents good flame retardant properties.

Abstract: A process for improving the flame-retardant properties of cellulose containing fibrous materials in the absence of halogen compounds which comprises treating said fibrous materials with an effective amount of a colloidal aqueous dispersion of an alkali metal polyantimonate containing a mole ratio of alkali metal to antimony in the dispersion of at least about 0.3:1, and drying said materials is described.

Abstract: A method of preparing antimony pentoxide from solids containing antimony sulfides is described. The method comprises the steps of(a) leaching the antimony values from the solids with an aqueous potassium hydroxide solution to form an antimony-containing solution and a gangue,(b) oxidizing the antimony present in the leaching solution to a pentavalent antimony,(c) recovering the oxidized solution, and(d) adding an inorganic acid to the solution to reduce the pH of the solution to about 5-7 whereby antimony pentoxide is precipitated from the solution. The gangue may be separated from the leach solution either prior to or after the oxidizing step.In a preferred embodiment, the oxidation of the solution is conducted in the presence of a catalyst which comprises a water-soluble copper salt, a quinone, a hydroquinone or mixtures of one or more of these.

Abstract: A colloidal dispersion of hydrous antimony pentoxide particles is made by a process which comprises introducing a particulate antimony component selected from the group consisting of antimony metal, oxidizable antimony oxides and mixtures thereof into an essentially aqueous medium and contacting said antimony component with hydrogen peroxide at a temperature of from about 0.degree. C. to about the decomposition temperature of the reaction mixture for a length of time sufficient to convert at least a portion of the antimony component to colloidal particles of hydrous antimony pentoxide.

Abstract: There is disclosed an improved process and apparatus for the production of finely-divided metal and metalloid oxides by flame hydrolysis of corresponding metal and metalloid halides whereby fouling of burner apparatus is substantially completely avoided.

Abstract: X-rays or .gamma.-rays are detected by irradiating a beam of high energy radiation onto a crystalline bismuth oxide compound having the formula Bi.sub.10-14 X.sub.1 O.sub.n wherein X is at least one element selected from the group consisting of Al, Ga, Ge, Si and Ti and n is a numeral substantially equal to the stoichiometric amount of oxygen within the compound. The above bismuth oxide crystalline compound may be placed in a radiation dosimeter or be applied as a radiation-sensitive coating on a cylinder or plate of an apparatus for producing electrostatic copies (i.e., an in a xerographic process or the like). This is a division of application Ser. No. 837,197, filed Sept. 28, 1977.

Abstract: A hydrocarbon cracking catalyst is treated with a crude antimony tris(O,O-dihydrocarbyl phosphorodithioate) to passivate thereon contaminating metals, e.g., vanadium, iron and/or nickel. Used or unused catalyst can be treated.

Abstract: Purified lead and antimony oxide are produced from antimonial lead alloys by oxidation of the molten alloy to form purified metallic lead and a slag of lead oxides and antimony oxides, separation of the metal and slag, and subsequent partial reduction and fuming of the slag to produce pure antimony oxide.

Abstract: A method of manufacturing an oxide layer of semiconductor composition is disclosed.On the surface portion of semiconductor substrate, an oxide layer is formed by oxidizing it in heated water containing oxygen gas, such, for example, as ozone. One preferred method is to bubble the ozone through hot water which contains near saturated steam at the temperature of the water.

Abstract: Metals such as nickel, vanadium and iron contaminating a cracking catalyst are passivated by contacting the contaminated catalyst with a passivating agent dissolved in a secondary feedstock stream having a temperature sufficiently low to avoid or minimize decomposition of the passivating agent.

Abstract: A hydrocarbon cracking catalyst is treated with a crude antimony tris-(O,O-dihydrocarbyl phosphorodithioate) to passivate thereon contaminating metals, e.g., vanadium, iron and/or nickel. Used or unused catalyst can be treated.

Abstract: A method of preparing a colloidal aqueous dispersion of antimony pentoxide from substantially water-insoluble metal antimonate is described. The method comprises contacting an aqueous slurry of the metal antimonate with a cation exchange resin whereby the metal antimonate is converted to the colloidal antimony pentoxide. A preferred method involves passing the slurry of metal antimonate through a fluidized bed containing a cation exchange resin. The colloidal sols obtained in the prescribed manner are useful as flame retardants when combined with halogen compounds.

Abstract: A process for thermally treating fine-grained solids with high-oxygen gases at temperatures at which the solids can form molten and gaseous reaction products comprises carrying out the thermal treatment at least in part in a cyclone chamber. The solids, high-oxygen gases and, if desired, an energy carrier (usually a carbon-containing solid, liquid or gas) are mixed to form a suspension at a temperature below the reaction temperature. The suspension is fed to a vertical combustion path (tube) and reacts therein to form another suspension of primarily molten particles which is admitted to the cyclone chamber. Reactants are added to the gas phase within a core-flow region of the cyclone chamber and/or immediately after the discharge of gas therefrom to a cooling chamber.

Abstract: A method for extracting antimony from solids containing antimony sulfides is described. An improvement in the method of extracting antimony by oxidation of an aqueous mixture of the solids in an acid or by oxidation of a leaching liquor obtained by leaching the antimony from the solids with an aqueous basic solution comprises conducting the oxidation in the presence of a catalyst comprising a water-soluble copper salt, a quinone, a hydroquinone or mixtures of one or more of these. The catalyst significantly increases the rate of oxidation and the rate of the recovery of the antimony from antimony sulfide bearing solids, particularly natural ores. Where the oxidation is conducted in a basic solution, the antimony is recovered as pentavalent antimony in the form of metal antimonates. Facile reduction of the metal antimonate to antimony trioxide also is described.

Abstract: Disclosed is a process for extracting antimony trioxide from antimony sulfide ore concentrate by solubility differential of the trioxide in lower alkanol solutions of sodium or potassium hydroxide and wherein the total amount of water contained in the concentrate, the alkanol and the hydroxide is not more than 26.52 volume percent of the antimony sulfide content; which process includes treating the ore in the absence of substantial amounts of air with an alkanol solution containing an excess of sodium or potassium hydroxide, basis Sb.sub.2 S.sub.

Abstract: A colloidal dispersion of hydrous antimony pentoxide particles is made by a process which comprises introducing particles of an oxidizable antimony oxide into a polar organic solvent selected from the group consisting of formamide, methylformamide, dimethyl formamide, acetamide, methylacetamide, dimethylacetamide, dimethyl sulfoxide, formic acid, tetramethyl urea, methanol and ethanol, and contacting said particles with aqueous hydrogen peroxide in the presence of an aliphatic alpha-hydroxy carboxylic acid and a halogen acid selected from the group consisting of hydrogen chloride and hydrogen bromide, at a temperature of from about 0.degree. C to about the decomposition temperature of the reaction mixture for a length of time sufficient to convert at least a portion of said particles to colloidal particles of hydrous antimony pentoxide.

Abstract: A colloidal dispersion of hydrous antimony pentoxide particles is made by a process which comprises introducing particles of an oxidizable antimony oxide into an aliphatic polyhydroxy alcohol having vicinal hydroxyl groups and contacting said particles with aqueous hydrogen peroxide at a temperature of from about 0.degree. C to about the decomposition temperature of the reaction mixture for a length of time sufficient to convert at least a portion of said particles to colloidal particles of hydrous antimony pentoxide.

Abstract: There is provided a process and apparatus for the production of finely-divided metal and metalloid oxides by flame hydrolysis of corresponding metal and metalloid halides whereby burner fouling is minimized and burner fabrication is facilitated by transpiration of a fuel gas or vapor along the boundaries of each halide-containing stream as it is discharged from the burner into a reaction zone.

Abstract: A novel process is described for the removal and/or recovery of dissolved antimony from an industrial stream, such as a waste stream, using a strong acid and/or a strong base ion exchange resin, in the hydrogen and hydroxyl forms respectively, to adsorb the antimony.

Abstract: An aqueous stabilized antimony pentoxide sol composition, comprising from 25% to 35% antimony pentoxide, from 6.5% to 17% of an amine and the remainder water, has been prepared. A dried composition obtained from this sol composition has also been prepared. The dried powder contains from 62% to 76% antimony pentoxide, from 17% to 32% of an amine and the remainder absorbed and combined water. This dried composition when added to water or an organic solvent readily forms the stabilized sol composition originally obtained.

Abstract: An aqueous antimony pentoxide sol composition, comprising from 10% to 50% antimony pentoxide and the remainder water has been prepared. This sol composition also may contain up to 5.0% of an amine if desired. When this sol composition contains the amine, a dried composition may be obtained from this sol composition. This dried powder contains from 85% to 95% antimony pentoxide and from 2.5% to 10% of an amine, the remainder being absorbed and combined water. This dried composition when added to water or an organic solvent readily forms the stabilized sol composition originally obtained.

Abstract: A colloidal dispersion of hydrous antimony pentoxide particles is made by a process which comprises introducing particles of antimony trioxide into a polar organic solvent selected from the group consisting of formamide, methylformamide, dimethyl formamide, acetamide, methylacetamide, dimethylacetamide, dimethyl sulfoxide, formic acid, tetramethyl urea, methanol and ethanol, and contacting said particles with aqueous hydrogen peroxide in the presence of an aliphatic alpha-hydroxy carboxylic acid and a halogen acid selected from the group consisting of hydrogen chloride, hydrogen bromide, and hydrogen iodide at a temperature of from about 0.degree. C to about the decomposition temperature of the reaction mixture for a length of time sufficient to convert at least a portion of the antimony particles to colloidal particles of hydrous antimony pentoxide.

Abstract: A recovery method by means of which an antimony compound is separated from polyester still bottoms. If desired, the method can be employed so as to recover in usable form, the antimony compound, and the monomers polymerized to produce the polyester.

Abstract: Oxide microspheres having a diameter in the 0.5 to 20 micron range are produced by forming a mixture of urea or melamine and formaldehyde in an aqueous sol containing colloidal oxide particles. Copolymerization of the organic constituents produces coacervation of the organic material into microparticles containing the inorganic material. The organic constituent can be burned out to form a powder of uniform-sized porous microparticles consisting of an interconnected array of inorganic colloidal particles separated by uniform-sized pores.

Abstract: Antimony trichloride or a solution thereof is added to a basic solution containing a complexing agent, preferably ethylenediaminetetraacetic acid, in which the antimony trichloride is present in an amount up to 5 moles per mole of complexing agent to hydrolyze antimony trichloride to light stable senarmontite.

Abstract: Sodium hexahydroxy antimonate is added to powder and acts as a flash-reducing agent.

Abstract: This invention relates to the method for preparing oxygen compounds of antimony with metals.According to the invention, the method for preparing oxygen compounds of antimony with metals consists in oxidation of antimony trioxide by hydrogen peroxide at a temperature from 40.degree. to 100.degree.C to form a suspension of hydrated antimony pentoxide and interaction of the obtained suspension of hydrated antimony pentoxide with metal compounds with subsequent drying ad calcining at temperatures from 300.degree. to 700.degree.C.The invention can be employed in the manufacture of metal oxide-antimony catalysts and metal-oxide resistor materials.

Abstract: Antimony sulfide contained in an antimony sulfide bearing ore, such as stibnite, is converted to high purity antimony trichloride by reacting the antimony sulfide bearing ore with a source of chlorine to form high purity antimony trichloride and sulfur or hydrogen sulfide as separable by-products. The high purity antimony trichloride may be hydrolyzed to form high purity antimony oxide.