Forming Catalyst, Sorbent Activated, Or Narrow Pore Alumina Patents (Class 423/628)
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Patent number: 6638888Abstract: The present invention relates to a mesoporous gel comprising an alumina matrix in which one or more oxides selected from silica, boron oxide, phosphorus oxide, oxides of metals of groups VIII and VIB, may be uniformly dispersed. The present invention also relates to a process for the preparation of this gel and its uses as carrier, as catalyst for acid-catalyzed reactions and as hydrotreating catalyst.Type: GrantFiled: May 14, 1996Date of Patent: October 28, 2003Assignee: Eniricerche S.p.A.Inventors: Stefano Peratello, Giuseppe Bellussi, Vicenzo Calemma, Roberto Millini
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Publication number: 20030185736Abstract: Disclosed are a porous material comprising particles without substantial fibrous structure and having pores, the pores having a mean pore diameter in a meson-pore region, sharp pore size distribution, and at least a part of the pores being connected three-dimensionally to form a three-dimensional network structure with random passages, the porous material preferably being of alumina and having a spongy structure or the porous material preferably being an aggregate of particles having an aspect ratio of 3 or less; a process of producing the porous material which includes a step of aging a system capable of becoming an oxide on thermal decomposition; a catalyst for exhaust gas purification having excellent NOx removal performance, high resistance against sulfur poisoning, and satisfactory high-temperature durability which comprises the porous material as a carrier having supported thereon a noble metal and an NOx storage component; and a method of exhaust gas purification using the catalyst.Type: ApplicationFiled: October 2, 2002Publication date: October 2, 2003Applicant: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHOInventors: Miho Hatanaka, Akihiko Suda, Toshiyuki Tanaka, Naoki Takahashi, Toshio Yamamoto, Yusuke Akimoto, Naohiro Terao
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Publication number: 20030180213Abstract: Multiple-component solid compositions including at least two intermingled, different solid oxides or hydroxides are provided which have extremely small crystallite sizes (at least one of the materials exhibits a crystallite size of about zero to 4 nm) and large surface areas. The compositions comprise at least two molecularly intermingled nanocrystalline materials selected from the group consisting of the oxides and hydroxides of the elements of Groups IIA, IIIA, IVA, the transition metals and the lanthanide series of the Periodic Table. The compositions are synthesized by separately preparing alkoxide solutions which are then mixed and hydrolyzed to give a gel; the gel is then treated to yield the desired hydroxide or oxide final composition. The compositions are useful for sorption of target materials such as undesireable compounds or biological materials. Extremely high surface area aluminum oxides having BET surface areas of at least about 700 m2/g are also disclosed.Type: ApplicationFiled: February 11, 2002Publication date: September 25, 2003Inventors: Corrie L. Carnes, Gavin Mark Medine, Kenneth J. Klabunde
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Publication number: 20030180197Abstract: Disclosed herein is a catalyst, an emission control device, and a method for treating exhaust gas. In one embodiment, the catalyst comprises: a catalytic metal component and a macro-pore component. The macro-pore component comprises an oxygen storage component and an aluminum oxide component, wherein the oxygen storage component, the aluminum oxide component, or both comprise pores, and wherein greater than or equal to about 40% of a macro-pore component pore volume, based on a total macro-pore component pore volume, is associated with pores greater than 120 Å in diameter. In one embodiment, the method for treating an exhaust gas comprises: contacting the exhaust gas with the catalyst at a temperature and for a period of time sufficient to reduce the concentration of a material in the exhaust gas.Type: ApplicationFiled: February 5, 2003Publication date: September 25, 2003Inventor: John G. Nunan
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Patent number: 6620458Abstract: A two-step method for producing monolithic alumina aerogels having porosities of greater than 80 percent. Very strong, very low density alumina aerogel monoliths are prepared using the two-step sol-gel process. The method of preparing pure alumina aerogel modifies the prior known sol method by combining the use of substoichiometric water for hydrolysis, the use of acetic acid to control hydrolysis/condensation, and high temperature supercritical drying, all of which contribute to the formation of a polycrystalline aerogel microstructure. This structure provides exceptional mechanical properties of the alumina aerogel, as well as enhanced thermal resistance and high temperature stability.Type: GrantFiled: September 27, 2001Date of Patent: September 16, 2003Assignee: The Regents of the University of CaliforniaInventors: John F. Poco, Lawrence W. Hrubesh
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Publication number: 20030171216Abstract: A lean NOx catalyst and method of preparing the same is disclosed. The lean NOx catalyst includes a substrate, an oxide support material, preferably &ggr;-alumina deposited on the substrate and a metal or metal oxide promoter or dopant introduced into the oxide support material. The metal promoters or dopants are selected from the group consisting of indium, gallium, tin, silver, germanium, gold, nickel, cobalt, copper, iron, manganese, molybdenum, chromium, cerium, and vanadium, and oxides thereof, and any combinations thereof. The &ggr;-alumina preferably has a pore volume of from about 0.5 to about 2.0 cc/g; a surface area of between 80 and 350 m2/g; an average pore size diameter of between about 3 to 30 nm; and an impurity level of less than or equal to about 0.2 weight percent. In a preferred embodiment the &ggr;-alumina is prepared by a sol-gel method, with the metal doping of the &ggr;-alumina preferably accomplished using an incipient wetness impregnation technique.Type: ApplicationFiled: December 18, 2001Publication date: September 11, 2003Inventor: Paul W. Park
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Publication number: 20030152509Abstract: Catalysts made from a newly discovered phase of aluminum trihydroxide and processes for making such catalysts. This invention also relates to a method for improving the activity of and for regenerating catalysts having a silica-alumina support.Type: ApplicationFiled: October 25, 2002Publication date: August 14, 2003Inventors: James Donald Carruthers, Eduardo A. Kamenetzky, Peter J. Achorn
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Patent number: 6589908Abstract: A method for making alumina having a pore structure characterized by the absence of macropores, no more than 5% of the total pore volume in pores greater than 350 Å, a high pore volume (greater than 0.8 cc/g measured by mercury intrusion) and a bi-modal pore volume distribution character, where the two modes are separated by 10 to 200 Å, and the primary pore mode is larger than the median pore diameter (MPD), calculated either by volume or by surface area, the MPD by volume being itself larger than the MPD by surface area. Alumina made by such process and catalyst made therefrom.Type: GrantFiled: November 28, 2000Date of Patent: July 8, 2003Assignee: Shell Oil CompanyInventors: Josiane M. Ginestra, Russell C. Ackerman, Christian G. Michel
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Publication number: 20030113255Abstract: An activated alumina formed by complexing a dehydrated alumina with an agglomerate blocking agent and then hydrating the activated alumina.Type: ApplicationFiled: November 27, 2002Publication date: June 19, 2003Inventor: Wayne Harlan
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Patent number: 6573214Abstract: Disclosed is a hydrogen generation process for use with fuel cells which includes a preferential oxidation step to reduce the concentration of carbon monoxide. The preferential oxidation step includes contacting a fuel stream comprising hydrogen and carbon monoxide in the presence of an oxygen at a preferential oxidation temperature of between about 70° and about 160° C. with preferential oxidation catalyst for reducing the concentration of carbon monoxide to produce a treated fuel gas stream comprising less than about 50 ppm-vol carbon monoxide. The preferential oxidation catalyst comprises ruthenium metal disposed on an alumina carrier having a low density and a high porosity. Superior performance at low preferential oxidation temperatures below 130° C. was observed when the alumina carrier contained a bimodal pore distribution with an average pore distribution of from about 20 to about 3000 angstroms.Type: GrantFiled: June 8, 2001Date of Patent: June 3, 2003Assignee: UOP LLCInventors: Suheil F. Abdo, Cynthia A. DeBoy, Geralyn F. Schroeder
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Patent number: 6565825Abstract: This invention relates to a method of producing an alumina porous material using a mixed powder of alumina powder and aluminum hydroxide represented by the chemical formula Al(OH)3 at different percentages as the starting material, comprising the steps of heating this mixed powder to decompose the aluminum hydroxide and further heat treating it within a temperature range of 1,000 to 1,600° C., and to the alumina porous material produced by the above-mentioned method with a porosity exceeding 40 volume % and its specific surface area of 8 to 40 m2/g, and further to a filter and catalyst carrier that are obtained using this alumina porous material.Type: GrantFiled: December 27, 2000Date of Patent: May 20, 2003Assignee: Japan as represented by Secretary of Agency of Industrial Science and TechnologyInventors: Tatsuki Ohji, Zhen-Yan Deng
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Patent number: 6555496Abstract: A microcrystalline boehmite containing additive in a homogeneously dispersed state. Suitable additives are compounds containing elements selected from the group consisting of alkaline earth metals, alkaline metals, rare earth metals, transition metals, actinides, silicon, gallium, boron, titanium, and phosphorus. The microcrystalline boehmite according to the invention may be prepared in several ways. In general, a microcrystalline boehmite precursor and an additive are converted to a microcrystalline boehmite containing the additive in a homogeneously dispersed state. The additive does not contain zirconia or magnesia.Type: GrantFiled: August 11, 2000Date of Patent: April 29, 2003Assignee: Akzo Nobel N.V.Inventors: Dennis Stamires, Paul O'Connor, Gregory Pearson, William Jones
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Publication number: 20030077221Abstract: Collections of particles are described that include crystalline aluminum oxide selected from the group consisting of delta-Al2O3 and theta-Al2O3. The particles have an average diameter less than about 100 nm. The particles generally have correspondingly large BET surface areas. In certain embodiments, the particle collections are very uniform. In some embodiments, collections of particles include doped aluminum oxides particles with an average diameter less than about 500 nm. The collections of particles can be deposited as coatings. Methods are described for producing desired aluminum oxide particles.Type: ApplicationFiled: October 1, 2001Publication date: April 24, 2003Inventors: Shivkumar Chiruvolu, Yu K. Fortunak
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Patent number: 6551572Abstract: A modified alumina is useful as metals passivator in fluidizable catalytic cracking catalysts. The modified alumina is prepared from a hydrated alumina, e.g., gibbsite, which is reacted with a low-molecular weight organic acid, e.g., acetic acid, forming aluminum salts. Calcination of the modified alumina results in decomposition of the aluminum salt.Type: GrantFiled: September 20, 2001Date of Patent: April 22, 2003Assignee: Akzo Nobel N.V.Inventor: Jose Carlos Duarte Macedo
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Patent number: 6527825Abstract: Disclosed is a process for preparing nanoscale metal-based powders from a metal salt and an amphiphilic copolymer containing ethylene oxide. The copolymer and metal salt are mixed to form a metal salt/copolymer paste which is then calcined at a temperature sufficient to remove water and organics and to form a metal oxide.Type: GrantFiled: March 28, 2001Date of Patent: March 4, 2003Assignee: Dow Global Technologies Inc.Inventors: Henri J. M. Gruenbauer, Jacobus A. F. Broos, Ronald van Voorst
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Patent number: 6518219Abstract: A catalyst for hydrofining fraction oils, comprises an alumina carrier and at least one metal and/or thereof oxide of Group VIB and at least one metal and/or thereof oxide of Group VIII supported on said alumina carrier. The pore volume of said alumina carrier is not less than 0.35 ml/g, in which the pore volume of the pores having a diameter of 40-100 angstrom accounts for more than 80% of the total pore volume, the alumina carrier is prepared by a special process. The catalyst possesses relatively high hydrogenation activity.Type: GrantFiled: October 13, 2000Date of Patent: February 11, 2003Assignees: China Petrochemical Corporation, Research Institute of Petroleum Processing, SinopecInventors: Qinghe Yang, Bin Liu, Hong Nie, Xuefen Liu, Dadong Li, Yahua Shi, Fucheng Zhuang
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Patent number: 6511642Abstract: Disclosed are a porous material comprising particles without substantial fibrous structure and having pores, the pores having a mean pore diameter in a meso-pore region, sharp pore size distribution, and at least a part of the pores being connected three-dimensionally to form a three-dimensional network structure with random passages, the porous material preferably being of alumina and having a spongy structure or the porous material preferably being an aggregate of particles having an aspect ratio of 3 or less; a process of producing the porous material which includes a step of aging a system capable of becoming an oxide on thermal decomposition; a catalyst for exhaust gas purification having excellent NOx removal performance, high resistance against sulfur poisoning, and satisfactory high-temperature durability which comprises the porous material as a carrier having supported thereon a noble metal and an NOx storage component; and a method of exhaust gas purification using the catalyst.Type: GrantFiled: January 12, 2000Date of Patent: January 28, 2003Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Miho Hatanaka, Akihiko Suda, Toshiyuki Tanaka, Naoki Takahashi, Toshio Yamamoto, Yusuke Akimoto, Naohiro Terao
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Patent number: 6506358Abstract: The present invention pertains to an improved process for the preparation of quasi-crystalline boehmite. In this improved process a quasi-crystalline boehmite precursor is aged at a pH below 7, prefereably under hydrothermal conditions. It was found that when conducting the preparation processes for quasi-crystalline aluminas described in the prior art at a pH below 7 and under hydrothermal conditions instead of the high pH and thermal aging used in the prior art, QCBs with higher crystallinity are obtained. In the process according to the invention additives may be added to the quasi-crystalline boehmite precursor. This results in a high quality QCB with additives in a homogeneously dispersed state. Suitable additives are compounds containing elements selected from the group of rare earth metals alkaline earth metals, transition metals, actinides, silicon, gallium, boron, and phosphorus.Type: GrantFiled: August 11, 2000Date of Patent: January 14, 2003Assignee: Akzo Nobel B.V.Inventors: Dennis Stamires, Paul O'Connor, Gregory Pearson, William Jones
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Patent number: 6503867Abstract: The present invention pertains to a quasi-crystalline boehmite containing additive in a homogeneously dispersed state. Suitable additives are compounds containing elements selected from the group of alkaline earth metals, alkaline metals, transition metals, actinides, silicon, gallium, boron, titanium, and phosphorus. Said QCBs according to the invention may be prepared in several ways. In general, a quasi-crystalline boehmite precursor and an additive are converted to a quasi-crystalline boehmite containing the additive in a homogeneously dispersed state.Type: GrantFiled: August 11, 2000Date of Patent: January 7, 2003Assignee: Akzo Nobel N.V.Inventors: Dennis Stamires, Paul O'Connor, Gregory Pearson, William Jones
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Patent number: 6503821Abstract: An integrated circuit chip carrier assembly is provided by joining a substrate having electrically conductive regions on at least one major surface thereof to a stiffener by a bonding film. The bonding film comprises a dielectric substrate having a thermoset adhesive on both of its major surfaces. The thermoset adhesive prior to the bonding is a B-stage adhesive, is tack-free at normal room temperatures and is solvent free.Type: GrantFiled: December 10, 2001Date of Patent: January 7, 2003Assignee: International Business Machines CorporationInventors: Donald Seton Farquhar, Lisa Jeanine Jimarez, Michael Joseph Klodowski, Jeffrey Alan Zimmerman
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Publication number: 20020197204Abstract: A high-strength &agr;-alumina formed body with a low soda content, of which pore distribution is controlled, can be provided in an easy and inexpensive manner. The &agr;-alumina formed body can be produced by a method comprising calcining a gibbsite-phase aluminum hydroxide to obtain rehydratable alumina powder; forming the rehydratable alumina powder in the presence of water to obtain a formed body; maintaining the formed body in the presence of water at about 110-200 ° C., to rehydrate the formed body; and calcining the rehydrated formed body at about 1200° C. or higher. The &agr;-alumina formed body is useful as a carrier for catalysts, chemicals, microbes for food leftover disposal and the like.Type: ApplicationFiled: May 28, 2002Publication date: December 26, 2002Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Hidekatsu Kawazu, Osamu Yamanishi, Kazuya Tsuchimoto
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Publication number: 20020192151Abstract: An activated alumina formed body with a high bulk density and a large macro-pore volume is provided. The activated alumina formed body can be produced by a method comprising the steps of calcining a gibbsite-phase aluminum hydroxide having a median particle size of from about 10 &mgr;m to about 35 &mgr;m and a packed bulk density of from about 1.05 g/cm3 to about 1.3 g/cm3 to obtain an at least partially rehydratable alumina powder; forming the rehydratable alumina powder in the presence of water; maintaining the formed body in the presence of water to rehydrate the formed body; and calcining the rehydrated formed body to obtain an activated alumina formed body. The activated alumina formed body is usable as an adsorbent, a catalyst supporting precious metal or the like.Type: ApplicationFiled: May 28, 2002Publication date: December 19, 2002Inventors: Hidekatsu Kawazu, Osamu Yamanishi, Keiichiro Suzuki
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Publication number: 20020192155Abstract: There is provided macrostructures of porous inorganic material which can have controlled size, shape, and/or porosity and a process for preparing the macrostructures. The macrostructures comprise a three-dimension network of particles of porous inorganic materials. The process for preparing the macrostructures involves forming an admixture containing a porous organic ion exchanger and a synthesis mixture capable of forming the porous inorganic material and then converting the synthesis mixture to the porous inorganic material. After formation of the composite material, the porous organic ion exchanger can be removed from the composite material to obtain the macrostructures.Type: ApplicationFiled: April 5, 2002Publication date: December 19, 2002Inventors: Per Johan Sterte, Lubomira Borislavova Tosheva, Valentin Panov Valtchev, Svetlana Ivanova Mintova
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Publication number: 20020192150Abstract: Thermally stable transitional alumina particulates retaining high specific surface area after calcination at 1000° C. suitable for the use as catalysts or catalysts supports are produced by treating an aqueous solution containing Al3+ and optionally a doping amount of La3+ (e.g., 0.3 mol. %) with an anion-exchange resin to give a stable hydroxide sol followed by freeze drying of the sol and further thermal dehydration. The resultant stabilized transitional alumina retains high specific surface area at 1000° C., and additionally stabilization is achieved at very low levels of added La.Type: ApplicationFiled: April 3, 2001Publication date: December 19, 2002Inventors: Michael V. Glazov, John W. Novak, Alexey Vertegel
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Patent number: 6495709Abstract: A precursor for forming an aluminum oxide film comprises a liquid solution of an aluminum organic precursor compound in an organic solvent. In a second embodiment, the precursor comprises a suspension of aluminum oxide powder in a solution of an aluminum organic precursor compound. A precursor according to the invention is deposited on a substrate by dipping, rolling, spraying, misted deposition, spin on deposition, or chemical vapor deposition then heated to fabricate transparent aluminum oxide films. The electronic properties of the aluminum oxide films may be improved by depositing a plurality of layers of the precursor and annealing the precursor between layers.Type: GrantFiled: March 16, 2000Date of Patent: December 17, 2002Assignees: Symetrix Corporation, Matsushita Electric Industrial Co., Ltd.Inventors: Jolanta Celinska, Jeffrey W. Bacon, Akihiro Matsuda, Carlos A. Paz de Araujo
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Patent number: 6429172Abstract: Pseudo-boehmite, which is a raw material for a catalyst carrier for hydrogenation refining, is produced by mixing, under a predetermined condition, an aluminate aqueous solution produced from an alkaline etching step for aluminum in an alumite treatment and an acidic aluminum aqueous solution produced from an anodization step for aluminum in the alumite treatment. Pseudo-boehmite can be also produced by maturing, with an alkaline solution, an aluminum hydroxide sludge produced from a washing step for aluminum in the alumite treatment. It is possible to establish a method for producing pseudo-boehmite, which makes it possible to reutilize a resource at extremely low cost by utilizing a treatment waste liquid and a sludge in an alumite treatment site.Type: GrantFiled: September 29, 1999Date of Patent: August 6, 2002Assignee: Japan Energy CorporationInventors: Takayuki Tsukada, Yuji Ohashi, Hideo Segawa
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Patent number: 6399528Abstract: The present invention relates to a porous aluminum oxide structure comprising Al2O3 and Zr, the structure having an open porosity greater than about 30% and an average pore size from about 20 nm to about 1000 nm, wherein the Zr, expressed as ZrO2, has a concentration less than about 5 weight % of the weight of the Al2O3.Type: GrantFiled: March 5, 2001Date of Patent: June 4, 2002Assignee: Fraunhofer-Gesellschaft zur Forderung der Angewandten Forschung e.V.Inventors: Andreas Krell, Frank Buse, Hongwei Ma
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Patent number: 6365259Abstract: Ceramic honeycombs incorporating cell walls of a sintered alumina material providing controlled pore size distribution in combination with high BET surface area and flexural (MOR) strength are formed by the extrusion, drying and firing of plasticized alumina powder batches containing major proportions of anhydrous, high-surface-area gamma alumina powders dispersed with selected acids; low combined drying and firing shrinkages provide strong, crack-free bodies of high surface area and strength.Type: GrantFiled: December 20, 1999Date of Patent: April 2, 2002Assignee: Corning IncorporatedInventors: Kevin R. Brundage, Srinivas H. Swaroop
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Publication number: 20020036157Abstract: A modified alumina is useful as metals passivator in fluidizable catalytic cracking catalysts. The modified alumina is prepared from a hydrated alumina, e.g., gibbsite, which is reacted with a low-molecular weight organic acid, e.g., acetic acid, forming aluminum salts. Calcination of the modified alumina results in decomposition of the aluminum salt.Type: ApplicationFiled: September 20, 2001Publication date: March 28, 2002Inventor: Jose Carlos Duarte Macedo
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Publication number: 20010055558Abstract: Alumina particles obtained from aluminum chloride by a gas phase method, the particles being amorphous or transition alumina particles and having an amorphous, &ggr;-, &dgr;- or &thgr;-crystalline form or a mixed form thereof, with primary particles thereof having an average particle diameter of 5 to 100 nm, and secondary particles, resulting from the aggregation of primary particles, having an average particle diameter of 50 to 800 nm.Type: ApplicationFiled: June 27, 2001Publication date: December 27, 2001Applicant: SHOWA DENKO K.K.Inventors: Hisao Kogoi, Jun Tanaka, Hayato Yamaya
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Publication number: 20010050354Abstract: The present invention relates to a method of containing nickel into the alumina aerogel prepared by sol-gel method and supercritical drying and of preparing the nickel-alumina hybrid aerogel catalyst. The nickel-alumina catalyst prepared in the present invention has an excellent reactivity with a prolonged lifetime.Type: ApplicationFiled: December 21, 2000Publication date: December 13, 2001Applicant: KOREA INSTITUTE OF TECHNOLOGYInventors: Dong Jin Suh, Tae Jin Park, Young Hyun Yoon, Jin Hong Kim
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Patent number: 6306795Abstract: Stable highly active supported copper based catalysts are comprised of copper oxide or elemental copper crystallites supported on mechanically stable aluminum oxide and are characterized by high surface area, small copper crystallite size, and high metal loading. The average crystallite size of the copper compound is from about 20 to about 300 Å, the copper loading is from about 10 to about 35 weight percent, the average particle diameter is from about 0.1 mm to about 10 mm, and the total surface area is from about 20 to about 400 square meters per gram. The catalysts are useful for hydration of nitriles to amides, especially hydration of acrylonitrile to acrylamide. The catalysts are distinguished by high mechanical stability, extended lifetime, and excellent resistance to hydration and copper leaching.Type: GrantFiled: September 7, 1999Date of Patent: October 23, 2001Assignee: Cytec Technology Corp.Inventors: Mark Donal Ryan, John Bradley Roucis, James Donald Carruthers
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Publication number: 20010029229Abstract: The present invention concerns a moulded microcrystalline spherical Al2O3- sintered body, process for its production as well as its use.Type: ApplicationFiled: November 23, 1998Publication date: October 11, 2001Inventors: PAUL MOELTGEN, PIRMIN WILHELM, MARTIN LUETTE
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Patent number: 6284694Abstract: The present invention concerns a moulded microcrystalline spherical Al2O3- sintered body, process for its production as well as use.Type: GrantFiled: November 23, 1998Date of Patent: September 4, 2001Assignee: Korund Laufenburg GmbHInventors: Paul Moeltgen, Pirmin Wilhelm, Martin Luette
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Patent number: 6284207Abstract: A material with high surface area can be obtained through the partial or total removal of CaO and MgO by acid leaching of blast furnace slag. This is accomplished by an improved process for selective leaching of blast furnace slag and other solid solution materials by control of temperature during leaching, rate of addition of acid, type of the acid, concentration of the acid, and concentration of the slag in the slurry. When these variables are controlled as disclosed a hierarchy of dissolution occurs. The hierarchy begins with MgO, progresses to CaO, and is followed by A12O3, and the rate of acid addition is slow and controlled so that alumina does not dissolve (thereby depriving the remaining silica has no acid sites or catalytic activity). By invoking the hierarchy one gains selectivity, and this can be used to convert blast furnace slag to a material with high surface area which may have applications as an absorbent could be economically feasible.Type: GrantFiled: September 5, 2000Date of Patent: September 4, 2001Inventor: John R. McCauley
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Patent number: 6261533Abstract: A process for the production of an aluminum oxide composition which includes subjecting an aluminoxane with a basic structural element of —Al—O—Al— or a basic oligomeric structural element of —Al—O—Al—O—Al—O—Al— to mild hydrolysis with at least one inert gas moistened below its dew point to produce a composition and subjecting the composition to thermolysis at temperatures from about 300 to about 900° C.Type: GrantFiled: August 7, 2000Date of Patent: July 17, 2001Assignee: Sud-Chemie AGInventors: Norbert Von Thienen, Hansjörg Sinn
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Patent number: 6251823Abstract: A process for producing spherical catalyst carrier of silica, silica-alumina composition, zirconia-alumina composition, titania-alumina composition, boria-alumina composition, or boria-silica-alumina composition which has almost the same pore characteristics as alumina hydrate gel, silica-alumina hydrate gel, zirconia-alumina hydrate gel, or titania-alumina hydrate gel (or alumina hydrate paste, boria-alumina hydrate paste, or boria-silica-alumina hydrate paste) as the major raw material, having uniform sphericity and smooth surface and homogeneity, and has a macropore volume that can be controlled includes adding a polysaccharide solution to any of alumina, silica-alumina, zirconia-alumina, or titania-alumina in the form of hydrate gel, or alumina, boria-alumina, or boria-silica-alumina in the form of hydrate paste, mixing them to form a slurry with a controlled concentration, dropping the slurry into a solution containing multivalent metal ions, thereby forming spherical hydrogel, and performing the additioType: GrantFiled: August 10, 1999Date of Patent: June 26, 2001Assignee: Sumitomo Metal Mining Co., Ltd.Inventors: Toshio Yamaguchi, Kikoo Uekusa
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Patent number: 6218335Abstract: A porous spinel type oxide shows a large surface area and a uniform micro-porous structure. The oxide is expressed by general formula MO—Al2O3 and shows a surface area per unit weight of not less than 80 m2/g. Such a porous spinel type compound oxide is obtained by impregnating a specific &ggr;-alumina carrier with a solution of a compound of metal element M capable of taking a valence of 2, drying the impregnated carrier and calcining it at a temperature of 600° C. or higher. The specific &ggr;-alumina carrier shows a surface area per unit weight of not less than 150 m2/g, a micro-pore volume per unit weight of not less than 0.55 cm3/g and an average micro-pore diameter between 90 and 200 angstroms. The micro-pores with a diameter between 90 and 200 angstroms occupy not less than 60% of the total micro-pore volume of the carrier.Type: GrantFiled: July 23, 1999Date of Patent: April 17, 2001Assignee: Chiyoda CorporationInventors: Yoshimi Okada, Kenichi Imagawa, Susumu Yamamoto
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Patent number: 6214312Abstract: The invention concerns a process for synthesising aluminas with a controlled porosity in which the pore diameter is in the range 0.6 nm to 80 nm. This process is carried out in a plurality of steps including at least one step a) in which an alumina precursor is prepared by hydrolysis of at least one anionic inorganic source of aluminium in the presence of at least one surfactant. Step a) of the process is carried out in an essentially aqueous medium the pH of which is generally higher than the isoelectric point of the alumina. The process of the invention also comprises at least one step b) in which the precipitate obtained is dried in air at a temperature of about 40° C. to 110° C. for a period of about 2 to 30 hours, and at least one step c) in which the dried precipitate is calcined at a temperature which is sufficient to eliminate the molecules of surfactant present in the precursor.Type: GrantFiled: July 21, 1999Date of Patent: April 10, 2001Assignee: Institut Francais du PetroleInventors: Frédéric Kolenda, Jean-Louis Guth, Sabine Valange, Zélimir Gabelica, Sylvie Lacombe
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Patent number: 6207611Abstract: A catalyst for hydrodemetalization of heavy oil, especially residuum oil, and a process for preparing the same, wherein said catalyst comprises the metal elements of Groups VIII and/or VIB as active components supported on an alumina carrier having large pores. The total pore volume of said carrier is in the range of 0.80˜1.20 ml/g (by mercury porosimetry method), the specific surface area in the range of 110˜200 m2/g, the peak pore diameter in the range of 15˜20 nm, and the bulk density in the range of 0.50˜0.60 g/ml. In the process of the invention, a physical pore-enlarging agent and a chemical pore-enlarging agent are added simultaneously during the mixing of the pseudoboehmite to a plastic mass, then extruding, drying, calcining, the carrier is obtained, then impregnating with active components by spraying onto the carrier, after drying and calcining, the catalyst is obtained.Type: GrantFiled: July 22, 1998Date of Patent: March 27, 2001Assignees: China Petro-Chemical Corporation, Fushun Research Institute of Petroleum and Petrochemicals, SINOPECInventors: Suhua Sun, Weiping Fang, Jiahuan Wang, Guolin Wu, Jianan Sun, Gang Wang, Zemin Fu, Hao Zhang, Yonglin Wang
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Patent number: 6197277Abstract: Alumina particles having high dispersibility and plasticity, at least on the surface of which a phosphoric acid or phosphate is present and suitable for use as a material for pigments for paints, precision abrasives or ceramics. The alumina particles are produced by adding a crystallization inhibitor containing at least phosphate ion to aluminum hydroxide or alumina hydrate and then conducting a hydrothermal synthesis treatment. The amount of the phosphate ion to be added is in the range of 3.0×10−3 to 2.5×10−2 mol per mol of aluminum hydroxide or alumina hydrate. The particle size of aluminum hydroxide or alumina hydrate is 0.1 to 5.0 &mgr;m. The hydrothermal synthesis is preferably conducted at 350° C. or above under a pressure of 50 to 200 atm and at a temperature elevation rate of 5° C./min to 0.3° C./min. The thus obtained alumina is &agr;-alumina in the form of hexagonal plate single crystal having a particle size of 0.Type: GrantFiled: May 4, 1999Date of Patent: March 6, 2001Assignee: YKK CorporationInventors: Takeshi Fukuda, Ryuichi Shido
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Patent number: 6197276Abstract: Hydrated aluminium compounds of the present invention are represented by the general formula nS, mM, Al2O3, xH2O where S is a surfactant or a group of surfactants, n is the number of moles of S, M is an alkaline cation, preferably selected from the group formed by Na+, K+, NH4+, m is the number of moles of M and x is the number of moles of water. The hydrated compounds are obtained from inorganic aluminium sources which are in the form of cation-monomers and/or cation-oligomers. The surfactants are anionic and/or non-ionic surfactants. When the group of surfactants comprises at least one anionic surfactant, at least one cationic surfactant can optionally be added.Type: GrantFiled: February 12, 1999Date of Patent: March 6, 2001Assignee: Institut Francais du PetroleInventors: Frédéric Kolenda, Jean-Louis Guth, Sabine Valange, Zelimir Gabelica, Eric Benazzi
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Patent number: 6197073Abstract: In order to produce aluminium oxide beads, an acid aluminium oxide sol or an acid aluminium oxide suspension is converted into droplets by a vibrating nozzle plate and pre-solidified after the formation of a bead shape by laterally blowing gaseous ammonia and then coagulated in an ammonia solution.Type: GrantFiled: October 27, 1997Date of Patent: March 6, 2001Assignee: Egbert BrandauInventors: Martin Kadner, Egbert Brandau, Hans Huschka
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Patent number: 6174511Abstract: An aluminum salt solution and an alkali aluminate solution are subjected to a neutralization reaction to precipitate and form a pseudo-boehmite powder. The neutralization reaction is performed under a condition in which the reaction temperature is within a range of 55 to 71° C., pH is within a range of 8.5 to 9.5, and the solution feed time is within a range of 7 to 25 minutes. The obtained pseudo-boehmite is as follows. That is, the pore volume concerning pores having a pore diameter ranging from 20 to 600 Å is within a range of 0.8 to 1.8 cc/g as measured by the nitrogen adsorption method, and the maximum value of variation ratio dV/dD of the pore volume with respect to the pore diameter as measured by the BJH method is not more than 0.018 cc/g•Å. When the pseudo-boehmite is used, it is possible to produce a catalyst carrier for hydrogenation refining, which has a sharp pore diameter distribution and which suffers less decrease in strength upon impregnation with a catalyst solution.Type: GrantFiled: May 6, 1999Date of Patent: January 16, 2001Assignee: Japan Energy CorporationInventors: Takayuki Tsukada, Hiroyuki Nakamura
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Patent number: 6171573Abstract: An alumina sol, containing a small amount of water of crystallization inside the crystal lattice of boehmite, having high mechanical strength, properties suitable for use as an alumina adsorbent or carrier, and the ability to be formed without additional concentration. The alumina sol comprises a fibrous boehmite having the molecular formula Al2O3.1.05-1.30 H2O with the weight average diameter and the weight average length being respectively in the range of 3 to 50 nm and in the range of 30 to 3000 nm, and has an alumina concentration of 15 to 60% by weight.Type: GrantFiled: September 4, 1998Date of Patent: January 9, 2001Inventor: Goro Sato
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Patent number: 6143816Abstract: A fire-retardant plastic mixture contains 55%-75% by weight of boehmite which has an orthorhombic crystal structure and has the general formula AlO.sub.x (OH).sub.3-2x with x-values ranging between 0.8 and 0.99, and has a mean grain diameter d.sub.50 ranging between 0.4 and 0.7 .mu.m, a d.sub.10 value ranging between 0.7 and 1.2 .mu.m and a d.sub.90 value ranging between 0.2 and 0.4 .mu.m. The filler material is used in the form of a finely-crystallized hydrargillite which is obtained during a precipitation process according to Bayer with a grain diameter of 0.5 to 3 .mu.m, which is suspended and which, without any mechanical working, is transformed directly in a hydro-thermal process at temperatures ranging between 220.degree. C. and 240.degree. C. under turbulent conditions into a boehmite of the general formula AlO.sub.x (OH).sub.3-2x with x-values ranging between 0.8 and 0.99.Type: GrantFiled: March 19, 1999Date of Patent: November 7, 2000Assignee: Nabaltec-Nabwerk Aluminiumhydroxid Technologie GmbHInventors: Klaus-Dieter Prescher, Johann Trettenbach, Josef Fischer, Stefan Ross, Josef Brandl
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Patent number: 6129904Abstract: An aluminum oxide mass characterized by a specific surface area greater than or equal to 70 m.sup.2 /g and a narrow pore radius distribution, with at least 90% of the pore radii being approximately 0.5 to 2.5 nm, preferably approximately 1.7 to 2.2 nm.Type: GrantFiled: March 16, 1999Date of Patent: October 10, 2000Assignee: Sud-Chemie A.G.Inventors: Norbert Von Thienen, Hansjorg Sinn
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Patent number: 6110862Abstract: A novel catalytic material is prepared by dispersing a catalytically active species, e.g., one or more platinum group metals, on a support phase that contains a high porosity, meso-pores high surface area (HPMPHSA) material. The HPMPHSA material has a porosity, measured in milliliters per gram of material, that is typically at least about 30 percent greater than that of a corresponding conventional material, preferably at least 50 percent greater. In a particular embodiment, the support phase of the catalytic material contains a HPMPHSA alumina having a porosity of about 0.9 ml/g, whereas a conventional alumina typically has a porosity of about 0.45 ml/g. The surface area is above 90, preferably above 100, more preferably equal or above 150 to 160 m.sup.2 /g. The support phase may be wholly composed of the HPMPHSA material or it may be composed of a mixture of the HPMPHSA material and a conventional material. Such a mixture preferably contains at least about 20 percent HPMPHSA material, by weight, e.g.Type: GrantFiled: May 7, 1998Date of Patent: August 29, 2000Assignee: Engelhard CorporationInventors: Shau-Lin F. Chen, Harold N. Rabinowitz, Chong Kim
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Patent number: 6103660Abstract: A method of depositing catalytically active components on high-surface carrier materials is disclosed by dispersing the carrier materials in water and mixing this dispersion with an aqueous solution of soluble precursors of the catalytically active components. The pH of the dispersion is adjusted to a value between 6 and 8 before the aqueous solution of the precursors is supplied by capillary injection under constant agitation of the dispersion and thereafter, if necessary, the precursors of the catalytically active components are precipitated on the carrier material by capillary injection of a dilute base.Type: GrantFiled: April 7, 1998Date of Patent: August 15, 2000Assignee: Degussa Huls AktiengesellschaftInventors: Renee Van Yperen, Dieter Lindner, Lothar Mussmann, Egbert Lox, Thomas Kreuzer
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Patent number: 6093672Abstract: A noble metal hydrocracking catalyst which has high selectivity for naphtha range products is provided. The hydrocracking catalyst comprises:a) from about 70 to about 90 weight percent of a Y zeolite, based on the catalyst having a silica to alumina mole ratio of from about 4.8 to less than 6.0, a unit cell constant within the range of about 24.50 to about 24.57, a Na.sub.2 O level of less than or equal to about 0.2 weight percent;b) from about 10 to about 30 weight percent, based on the catalyst of an alumina having a mercury intrusion pore volume within the range from about 0.55 to about 0.85 cc/g; andc) from about 0.5 to 1 weight percent, based on the catalyst of a noble metal; wherein said hydrocracking catalyst have a dispersivity of the noble metal of equal or greater than about 50% by hydrogen chemisorption measurement, a surface area of greater than or equal to 700 m.sup.2 /g by BET surface area measurement, a compacted bulk density within the range of from about 0.40 to 0.Type: GrantFiled: March 20, 1997Date of Patent: July 25, 2000Assignee: Shell Oil CompanyInventors: Bruce Herman Charles Winquist, David Allen Cooper