Catalytic Reaction Patents (Class 423/651)
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Patent number: 11988127Abstract: An assembly for induction heating an exhaust gas flow includes a substrate and linear cells for the flow of the gas through the substrate from a front end of the substrate body to a back end. Metal members such as pins or wires have linear supporting parts projecting from a front end of the substrate into front-end parts of the cells. The metal members have turbulence-inducing part to generate turbulence in the exhaust gas flowing into the cells and through the substrate. The turbulence-inducing parts are integral with respective linear supporting parts and extend away from the substrate. Configurations of an induction heating coil and a magnetic flux concentrator are adapted for the particular location and form of the pins.Type: GrantFiled: October 26, 2021Date of Patent: May 21, 2024Inventors: Robin Crawford, John Douglas
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Patent number: 11560306Abstract: The invention relates to a method for producing ammonia (1), wherein a carbon-containing energy carrier flow (2) and an oxygen flow (3) from an oxygen-producing assembly (4) are fed to a synthesis gas reactor assembly (5) for obtaining a synthesis gas flow (6) with hydrogen and carbon oxides, wherein the synthesis gas flow (6) is fed to an adsorption device (7) for separating the synthesis gas flow (6) into a hydrogen flow (8), which comprises hydrogen, and a purge flow (9), and wherein the hydrogen flow (8) and a nitrogen flow (10) are fed to an ammonia reactor assembly (11) and converted into ammonia (1) there. The method is characterized in that the purge flow (9) is fed to a recovery device (12), which obtains a hydrogen-containing recovery flow (13) from the purge flow (9) and discharges a waste gas flow (14) therefrom, and that the hydrogen of the recovery flow (13) is at least partly fed to the ammonia reactor assembly (11) for conversion into ammonia (1).Type: GrantFiled: May 9, 2018Date of Patent: January 24, 2023Assignee: GASONTEC GMBHInventors: Peter Ulrich Koss, Dierk Müller, Ulrich Wagner
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Patent number: 11478777Abstract: Modified red mud catalyst compositions, methods for production, and methods for use, a composition including red mud material produced from an alumina extraction process from bauxite ore; nickel oxide, the nickel oxide present at between about 5 wt. % to about 40 wt. % of the modified red mud catalyst composition; and a Periodic Table Group VIB metal oxide, the Group VIB metal oxide present at between about 1 wt. % and about 30 wt. % of the modified red mud catalyst composition.Type: GrantFiled: January 28, 2020Date of Patent: October 25, 2022Assignee: Saudi Arabian Oil CompanyInventors: Bandar H. Alsolami, Bandar A. Fadhel, Rami Bamagain, Mohammed A. Albuali
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Patent number: 11465113Abstract: The invention relates to the use of a reactor, methods, and devices for the quantitative recovery of molecular hydrogen from solid, liquid, or gaseous substances which contain hydrogen and which have heteroatoms, as well as to reactors. In this case, the reactors have material containing chromium. The subject matter of the invention also includes the use of the reactor, the method, and the device for the compound-specific or component-specific measurement of the isotope ratio (?2H) of hydrogen using online apparatuses.Type: GrantFiled: February 11, 2016Date of Patent: October 11, 2022Inventors: Matthias Gehre, Julian Renpenning, Steffen Kuemmel
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Patent number: 11362342Abstract: The present invention relates to a catalyst for solid polymer fuel cells in which catalyst particles including platinum are supported on a carbon powder carrier. The invention provides a catalyst for solid polymer fuel cells in which the ratio of zerovalent platinum to platinum present on the surfaces of the catalyst particles is 80% or more and 100% or less. In the platinum catalyst, excellent durability is exhibited in an environment of operating a solid polymer fuel cell, and the amount of platinum eluted at the time of immersing the catalyst in a predetermined sulfuric acid solution is lower as compared to conventional platinum catalysts. The invention provides a catalyst for solid polymer fuel cells excellent in both initial activity and durability.Type: GrantFiled: April 16, 2018Date of Patent: June 14, 2022Assignee: TANAKA KIKINZOKU KOGYO K.K.Inventor: Koichi Matsutani
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Patent number: 11148985Abstract: A process for producing ethylene and syngas comprising reacting, via OCM, first reactant mixture (CH4&O2) in first reaction zone comprising OCM catalyst to produce first product mixture comprising ethylene, ethane, hydrogen, CO2, CO, and unreacted methane; introducing second reactant mixture comprising first product mixture to second reaction zone excluding catalyst to produce second product mixture comprising ethylene, ethane, hydrogen, CO, CO2, and unreacted methane, wherein a common reactor comprises both the first and second reaction zones, wherein ethane of second reactant mixture undergoes cracking to ethylene, wherein CO2 of second reactant mixture undergoes hydrogenation to CO, and wherein an amount of ethylene in the second product mixture is greater than in the first product mixture; recovering methane stream, ethane stream, CO2 stream, ethylene stream, and syngas stream (CO&H2) from the second product mixture; and recycling the ethane stream and the carbon dioxide stream to second reactionType: GrantFiled: January 29, 2018Date of Patent: October 19, 2021Assignee: Sabic Global Technologies, B.V.Inventors: Aghaddin Mamedov, David West, Vidya Sagar Reddy Sarsani, Wugeng Liang
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Patent number: 11103844Abstract: A process and system that use the heat produced in the generation of Syngas to provide heat to an endothermic reaction zone are disclosed. A method for providing heat to an endothermic reaction may comprise producing Syngas in a reforming reactor. The method may further comprise recovering heat from the producing the Syngas to heat an endothermic reaction stream in a heat transfer zone. The method may further comprise allowing reactants in the endothermic reaction stream to react to form an endothermic reaction product stream. The method may further comprise withdrawing the endothermic reaction product stream from the heat transfer zone.Type: GrantFiled: June 26, 2019Date of Patent: August 31, 2021Assignee: ExxonMobil Research and Engineering CompanyInventor: Mohsen N. Harandi
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Patent number: 10710056Abstract: Catalysts for hydrogenation of CO2 to dimethyl ether. These catalysts comprise 0.1-10 wt % per total catalyst weight of a catalytic material containing Pd (e.g. metallic palladium), 0.05-5 wt % per total catalyst weight of a promoter containing Ca (e.g. metallic calcium), as well as 85-99 wt % of CeO2 as a catalyst support. Methods of preparing and characterizing the catalysts as well as processes for catalyzing the hydrogenation of CO2 to dimethyl ether and other byproducts such as methanol, carbon monoxide, and methane portrayed by reactant conversion, product selectivity, and catalyst stability are disclosed.Type: GrantFiled: October 31, 2018Date of Patent: July 14, 2020Assignee: King Abdulaziz UniversityInventors: Sharif Fakhruz Zaman, Ali Shan Malik, Abdulrahim Ahmed Alzahrani, Muhammad A. Daous, Lachezar A. Petrov
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Patent number: 10629933Abstract: A process for producing hydrogen from a hydrocarbon gas comprising contacting at elevated temperature the hydrocarbon gas with a catalyst to catalytically convert the hydrocarbon gas to hydrogen and solid carbon; wherein, the catalyst comprises one or both of the following: (a) a calcined Fe-containing catalyst; or (b) a bimetallic MxNiy-type catalyst supported on a substrate.Type: GrantFiled: November 30, 2015Date of Patent: April 21, 2020Assignee: HAZER GROUP LTDInventors: Hui Tong Chua, Andrew Cornejo, Colin Llewellyn Raston, Lizhen Gao
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Patent number: 10407364Abstract: Improved methods of oxidative dehydrogenation (ODH) of short chain alkanes or ethylbenzene to the corresponding olefins, and improved methods of oxidative coupling of methane (OCM) to ethylene and/or ethane, are disclosed. The disclosed methods use boron- or nitride-containing catalysts, and result in improved selectivity and/or byproduct profiles than methods using conventional ODH or OCM catalysts.Type: GrantFiled: May 31, 2018Date of Patent: September 10, 2019Assignee: Wisconsin Alumni Research FoundationInventors: Ive Hermans, Joseph Thomas Grant, Carlos Alberto Carrero Marquez, Alessandro Chieregato, Juan Mauricio Venegas
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Patent number: 10189709Abstract: A power generation system that includes a membrane reformer assembly, wherein syngas is formed from a steam reforming reaction of natural gas and steam, and wherein hydrogen is separated from the syngas via a hydrogen-permeable membrane, a combustor for an oxy-combustion of a fuel, an expander to generate power, and an ion transport membrane assembly, wherein oxygen is separated from an oxygen-containing stream to be combusted in the combustor. Various embodiments of the power generation system and a process for generating power using the same are provided.Type: GrantFiled: June 22, 2017Date of Patent: January 29, 2019Assignee: King Fahd University of Petroleum and MineralsInventors: Esmail Mohamed Ali Mokheimer, Yinka Sofihullahi Sanusi, Mohamed A. Habib
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Patent number: 10118153Abstract: The present application discloses method for making air adsorbent particles. The method includes the steps of: providing and mixing porous powder, water, adhesive, and additive agent for obtaining sizing agent; obtaining air adsorbent particles by spray shaping, drying, and screening the sizing agent. The mass ratio between the porous powder, water, adhesive and the additive agent is 1:(0.5˜8):(0.01˜0.16):(0.001˜0.15). Particles obtained by the method of the present application have higher strength.Type: GrantFiled: August 7, 2018Date of Patent: November 6, 2018Assignee: AAC TECHNOLOGIES PTE. LTD.Inventors: Yanyan Jin, Ning Kang
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Patent number: 9780391Abstract: To provide a fuel cell device capable of extending the years of service life of a reformer by suppressing thermal runaways. The present invention is a solid oxide fuel cell device, including a fuel cell module having fuel cell units; a reformer disposed above the fuel cell units, for producing hydrogen by a partial oxidation reforming reaction and a steam reforming reaction; a vaporizing chamber disposed adjacent to the reformer; a combustion chamber for heating the vaporization chamber; a water supply device; an electrical generation oxidant gas supply device; and a controller for raising the fuel cell units to a temperature at which electrical generation is possible; whereby over the entire period of the startup step, the reforming oxidant gas supply device and water supply device are controlled so that partial oxidation reforming reactions do not occur independently in the reformer.Type: GrantFiled: July 17, 2013Date of Patent: October 3, 2017Assignee: TOTO LTD.Inventors: Yousuke Akagi, Toshiya Abe, Toshiharu Otsuka, Katsuhisa Tsuchiya, Takuya Matsuo, Naoki Watanabe, Hajime Omura, Shuhei Tanaka, Takuya Hoshiko
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Patent number: 9604200Abstract: A process for the steam reforming of hydrocarbons comprises partially oxidizing a feedgas comprising a hydrocarbon feedstock with an oxygen-containing gas in the presence of steam to form a partially oxidized hydrocarbon gas mixture at a temperature >1200° C. and passing the resultant partially oxidized hydrocarbon gas mixture through a bed of steam reforming catalyst, wherein the bed comprises a first layer and a second layer, each layer comprising a catalytically active metal on an oxidic support wherein the oxidic support for the first layer is a zirconia.Type: GrantFiled: May 22, 2014Date of Patent: March 28, 2017Assignee: JOHNSON MATTHEY PLCInventors: Peter William Farnell, Martin Fowles
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Patent number: 9561462Abstract: Sorbent compositions including sorbent particles of a small particle sized sorbent with increased pneumatic conveyance properties. The sorbent compositions have relatively small median particle size and have a controlled particle size distribution (PSD). Specifically, the sorbent compositions include a relatively small percentage of very fine particles, such as a small percentage of particles having a particle size of not greater than about 5 ?m. The sorbent compositions are particularly useful for the treatment of a flue gas stream to remove mercury from the flue gas stream.Type: GrantFiled: April 8, 2016Date of Patent: February 7, 2017Assignee: ADA Carbon Solutions, LLCInventors: Sarah G. McMurray, Jacob B. Lowring
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Particulate, heterogeneous solid COabsorbent composition, method for its preparation and use thereof
Patent number: 9550147Abstract: A particulate, heterogeneous solid CO2 absorbent composition, comprising decomposition products of Ca3Al2O6 after having been heated to a temperature between 500° C. and 925° C. in the presence of H2O and CO2 for a period of time sufficient to allow the Ca3Al2O6 to react and form the particulate, heterogeneous absorbent composition which exhibits a higher concentration of aluminum than calcium in the particle core but a higher concentration of calcium than aluminum at the particle surface. The invention also comprises a method for preparing the particulate, heterogeneous product as well as a method for utilizing the composition for separating CO2 from a process gas.Type: GrantFiled: July 6, 2010Date of Patent: January 24, 2017Assignee: INSTITUTT FOR ENERGITEKNIKKInventors: Johann Mastin, Julien Meyer, Arne Raaheim -
Patent number: 9409157Abstract: Provided is a catalyst for preparing a syngas by reforming methane wherein a nickel-based catalyst is mixed with a metal oxide catalyst. More particularly, alumina is used as a support and a metal oxide catalyst including magnesia, nickel, vanadium, tungsten, iron, molybdenum or chromium is used to inhibit carbon deposition and maintain or improve catalytic activity.Type: GrantFiled: June 4, 2013Date of Patent: August 9, 2016Assignee: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Dong Ju Moon, Young Chul Kim, Hye Jeong Ok
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Patent number: 9394219Abstract: Method for producing synthesis gas for methanol production The present invention relates to a method for producing synthesis gas from a hydrocarbon containing feed, which synthesis gas is particularly suitable for subsequent use in methanol production. In this method, a hydrocarbon containing feed, particularly natural gas (100), is subjected to catalytic partial oxidation (CPO) (2), followed by the water gas shift (WGS) (4) reaction of a part of the reformed feed. At least part of the shifted feed is then subjected to hydrogen purification, preferably by pressure swing adsorption (PSA) (5) to obtain pure hydrogen (108), which hydrogen is subsequently combined with the remaining parts of the feeds to yield synthesis gas particularly suitable for methanol synthesis. The recombined stream preferably has an R ratio, being the molar ratio (H2?CO2)/(CO+CO2), in the range 1.9-2.2 and preferably about 2.Type: GrantFiled: October 25, 2012Date of Patent: July 19, 2016Assignee: STAMICARBON B.V.Inventors: Gaetano Iaquaniello, Barbara Cucchiella, Elena Antonetti
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Patent number: 9302250Abstract: A method of steam reforming where a reaction occurs in which an oxygenated feed contacts a catalyst to produce hydrogen. The catalyst of the reaction comprises a metal/metal promoter on a nickel/transition metal blend catalyst supported on a high-energy lattice metal oxide.Type: GrantFiled: November 4, 2013Date of Patent: April 5, 2016Assignee: Phillips 66 CompanyInventors: Jimmy A. Faria, Jon M. Nelson, Uchenna P. Paul, Danielle K. Smith
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Publication number: 20150139896Abstract: A solar energy based continuous process and reactor system for the production of an alkene by dehydrogenation of the corresponding alkane is performed in a reactor which process comprises alternatingly performing a first mode and a second mode in the same reactor, wherein the first mode is a non-oxidative dehydrogenation wherein the non-oxidative dehydrogenation is performed by contacting the alkane with a suitable dehydrogenation catalyst at a temperature of at least 500° C. to produce the corresponding alkene and hydrogen and wherein the second mode is an oxidative dehydrogenation wherein the oxidative dehydrogenation is performed by contacting the alkane with a suitable dehydrogenation catalyst and an oxidation agent at a temperature from 300 to 500° C. to produce the corresponding alkene wherein the dehydrogenation catalyst for the oxidative dehydrogenation and the non-oxidative dehydrogenation are the same, wherein the heat for the first mode is provided by a solar energy source.Type: ApplicationFiled: April 19, 2013Publication date: May 21, 2015Inventors: Mohamed Sabri Abdelghani, Mustapha Karime, Zeeshan Nawaz, Abdullah Mohammad Al-Qahtani
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Patent number: 9034282Abstract: The invention relates to a catalytic reactor including: at least one first architecture/microstructure including a ceramic and/or metal cellular architecture having a pore size of 2 to 80 ppi and a macroporosity of more than 85%, and a microstructure having a grain size of 100 nm to 5 microns, and skeleton densification of more than 95%, and a catalytic layer; and at least one second architecture/microstructure including a spherical or cylindrical architecture having a pore size of 0.1 to 100 ?m and a macroporosity of less than 60%, and a microstructure having a grain size of 20 nm to 10 ?m and a skeleton densification of 20% to 90%, and a catalytic layer; the first and second architecture/microstructure being stacked inside said reactor.Type: GrantFiled: November 24, 2010Date of Patent: May 19, 2015Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Pascal Del-Gallo, Daniel Gary, Mathieu Cornillac, Aude Cuni
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Patent number: 9017642Abstract: A process for reducing free oxygen in a hydrocarbon gas stream comprises the steps of (i) forming a gas mixture containing hydrogen from a hydrocarbon, (ii) mixing the hydrogen gas mixture with a gaseous hydrocarbon stream containing free oxygen, and (iii) passing the resulting hydrocarbon gas mixture over a conversion catalyst that converts at least a portion of the free oxygen present in the gaseous hydrocarbon to steam.Type: GrantFiled: March 5, 2007Date of Patent: April 28, 2015Assignee: Johnson Matthey PLCInventors: Peter John Herbert Carnell, Martin Fowles, Raymond Anthony Hadden, Suzanne Rose Ellis
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Patent number: 9011814Abstract: Reactive diluent fluid (22) is introduced into a stream of synthesis gas (or “syngas”) produced in a heat-generating unit such as a partial oxidation (“POX”) reactor (12) to cool the syngas and form a mixture of cooled syngas and reactive diluent fluid. Carbon dioxide and/or carbon components and/or hydrogen in the mixture of cooled syngas and reactive diluent fluid is reacted (26) with at least a portion of the reactive diluent fluid in the mixture to produce carbon monoxide-enriched and/or solid carbon depleted syngas which is fed into a secondary reformer unit (30) such as an enhanced heat transfer reformer in a heat exchange reformer process. An advantage of the invention is that problems with the mechanical integrity of the secondary unit arising from the high temperature of the syngas from the heat-generating unit are avoided.Type: GrantFiled: February 22, 2013Date of Patent: April 21, 2015Assignee: GTLpetrol LLCInventors: Shoou-I Wang, John Michael Repasky, Shankar Nataraj, Xiang-Dong Peng
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Patent number: 9005571Abstract: Hydrogenated liquid organic compounds are used for storage and supply of hydrogen at near ambient conditions. The hydrogen is released from the hydrogenated liquid organic compounds through a catalytic dehydrogenation reaction using a M/support or M-M?/support catalyst. The M/support catalyst comprises a metal M selected from Pt, Pd, Rh, Ru, Ir, Os, or combination thereof, and a support selected from Y2O3 or V2O5 or combinations thereof. The M-M?/support catalyst comprises a first metal M selected from Cu, Ag, Au, or combination thereof, a second metal M? selected from Pt, Pd, Rh, Ru, Ir, Os, Fe, Ni, Re, Mo, W, V, Cr, Co or combinations thereof, and a support selected from activated carbon, alumina, alumite, zirconia, silica or combination thereof. Synergistic effects are created by using the combination of the M and M? in the catalyst, which result in shifting of the equilibrium of the reaction favorably to dehydrogenation.Type: GrantFiled: January 25, 2013Date of Patent: April 14, 2015Assignee: Council of Scientific & Industrial ResearchInventors: Rajesh Bhaskar Biniwale, Jayshri Vijay Pande, Anshu Ajit Shukla
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Patent number: 9005344Abstract: The present application is directed to a hydrophobic membrane assembly (28) used within a gas-generating apparatus. Hydrogen is separated from the reaction solution by passing through a hydrophobic membrane assembly (28) having a hydrophobic lattice like member (36) disposed within a hydrogen output composite (32) further enhancing the ability of the hydrogen output composite's ability to separate out hydrogen gas and prolonging its useful life.Type: GrantFiled: January 3, 2014Date of Patent: April 14, 2015Assignees: Societe Bic, The Commissariat a L'energie Atomique et Aux Energies Alternatives (CEA)Inventors: Andrew J. Curello, Michael Curello, Constance R. Stepan
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Publication number: 20150086472Abstract: One exemplary embodiment can be a process for catalytic reforming The process can include catalytically reforming a hydrocarbon feed in a reaction zone, obtaining an effluent stream having hydrogen and hydrocarbons from the reaction zone, obtaining from at least a portion of the effluent stream a waste hydrocarbon stream from an adsorption zone, passing at least a portion of the waste hydrocarbon stream as a feed stream across a feed side of a membrane having the feed side and a permeate side, and being selective for hydrogen over one or more C1-C6 hydrocarbons, and withdrawing from the permeate side a permeate stream enriched in hydrogen compared with a residue stream withdrawn from the feed side.Type: ApplicationFiled: September 23, 2013Publication date: March 26, 2015Applicant: UOP, LLCInventors: Eleftherios Adamopoulos, Wim Frans Elseviers, Bryan K. Glover
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Publication number: 20150078986Abstract: A reformer reactor is provided for converting hydrocarbon fuel into hydrogen rich gas by auto-thermal reaction process having a cylindrically shaped and double walled, housing with two side faces forming a. reaction chamber of the reformer. Additionally, a fuel inlet is provided in one of the to side faces for providing hydrocarbon fuels into the reaction chamber, wherein further a fuel preheating means is provided which preheats the hydrocarbon fuel before the hydrocarbon fuel enters the reaction chamber.Type: ApplicationFiled: November 23, 2014Publication date: March 19, 2015Applicant: POWERCELL SWEDEN ABInventors: Bård LINDSTRÕM, Anders KARLSSON, Lars PETTERSSON
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Patent number: 8979953Abstract: An apparatus for generating hydrogen including a housing, a reservoir, and a piston is provided. The housing has a top wall, a bottom wall, and a sidewall. The top wall has vents and a protrudent column extending to the interior of the housing. At least one vent communicates with the top wall and the protrudent column and rest of the vents surround the protrudent column. The reservoir is disposed in the housing for storing a solid state reactant and divides the housing into a first chamber and a second chamber. The first chamber is located between the top wall and the reservoir. The second chamber is located between the bottom wall and the reservoir for storing a liquid reactant. The piston is disposed on the bottom wall. The piston is used to push the liquid reactant towards the reservoir to react with the solid state reactant to generate hydrogen.Type: GrantFiled: November 9, 2011Date of Patent: March 17, 2015Assignee: Young Green Energy Co.Inventors: Yu-Hsiang Lin, Po-Kuei Chou, Tsai-Hsin Cheng, Hsuan-Yi Lu
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Publication number: 20150068953Abstract: Herein disclosed is a method of producing value-added product from light gases, the method comprising: (a) providing light gases comprising at least one compound selected from the group consisting of C1-C6 compounds and combinations thereof; (b) intimately mixing the light gases with a liquid carrier in a high shear device to form a dispersion of gas in the liquid carrier, wherein the dispersion is supersaturated with the light gases and comprises gas bubbles at least some of which have a mean diameter of less than or equal to about 5 micron(s); (c) allowing the value-added product to form and utilizing vacuum to extract unreacted light gases from the liquid carrier; (d) extracting the value-added product; wherein the value-added product comprises at least one component selected from the group consisting of higher hydrocarbons, hydrogen, olefins, alcohols, aldehydes, and ketones. A system for producing value-added product from light gases is also disclosed.Type: ApplicationFiled: August 20, 2014Publication date: March 12, 2015Inventors: Abbas HASSAN, Aziz HASSAN, Rayford G. ANTHONY, Gregory G. BORSINGER
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Patent number: 8974699Abstract: The invention relates to a cyclic process for producing synthesis gas comprising: a first step of oxidation of an oxidizable oxygen-carrying solid; a second purge step; a third combustion step with production of CO2; a fourth step of production of synthesis gas; a fifth purge step.Type: GrantFiled: February 9, 2011Date of Patent: March 10, 2015Assignees: Total Raffinage Chimie, IFP Energies NouvellesInventors: Sebastien Rifflart, Gregory Patience, Francois Xavier Chiron
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Patent number: 8951312Abstract: A compact, chemical-mechanical apparatus, having no electrical components, for storing and generating hydrogen safely, on-demand, at the time and point of use in small or large quantities using the environmentally clean chemical reaction between sodium metal and water to generate hydrogen (H2) gas and sodium hydroxide (NaOH) byproduct is presented, for powering electricity generating fuel cells for large scale commercial and private electric motor vehicle transport. The apparatus of the present invention supports hydrogen gas generation by the controlled addition of liquid water to solid sodium metal to produce hydrogen gas and sodium hydroxide using only mechanical components without electrical components that require external power and can generate sparks or short circuits, producing catastrophic failure in hydrogen systems.Type: GrantFiled: November 9, 2011Date of Patent: February 10, 2015Inventor: Alvin Gabriel Stern
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Patent number: 8940061Abstract: An apparatus for generating hydrogen for fuel cells is provided. The apparatus includes a housing, a button, a first separating plate, a solid state reactant, and a separating membrane. The housing has an opening and a reservoir. The button connected to the housing covers the opening. The first separating plate disposed in the housing divides the reservoir into first and second sub-rooms. The opening communicates with the first sub-room and the first sub-room is suitable for storing a liquid reactant. The first separating plate has a through hole opposite to the button. The solid state reactant is disposed in the second sub-room. The separating membrane disposed on the through hole separates the first sub-room from the second sub-room. When the button is pushed, the button damages the separating membrane. Therefore, the liquid reactant flows to the second sub-room and reacts with the solid state reactant to generate hydrogen.Type: GrantFiled: September 25, 2011Date of Patent: January 27, 2015Assignee: Young Green Energy Co.Inventors: Yu-Hsiang Lin, Po-Kuei Chou, Men-Chi Hsieh
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Patent number: 8915979Abstract: The present application is directed to a gas-generating apparatus. Hydrogen is generated within the gas-generating apparatus and is transported to a fuel cell. The first fuel component is introduced into the second fuel component through a conduit which punctures a septum separating the reaction chamber and the first fuel component reservoir, and the fuel conduit introduces the first fuel component to different portions of the second fuel component to produce hydrogen.Type: GrantFiled: September 29, 2009Date of Patent: December 23, 2014Assignee: Societe BICInventors: Alain Rosenzweig, Kurt Rath
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Patent number: 8888873Abstract: A method for generating and purifying syngas and to an apparatus for generating and purifying syngas is presented.Type: GrantFiled: July 23, 2009Date of Patent: November 18, 2014Assignee: L'air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Natacha Haik-Beraud, Antoine Hernandez, Pascal Marty, Bernd Polster
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Patent number: 8889098Abstract: A system and method of producing hydrogen from a mixture of hydrocarbon fuel and steam. Reaction cells are provided that each contains a first tube of hydrogen permeable material and a second tube of hydrogen impermeable material that are concentrically positioned. This creates a gap space between the first tube and the second tube. The gap space is heated by burning a combustion gas outside of the two concentric tubes. A water gas shift reaction occurs in the gap space. Hydrogen is created that permeates through the first tube and becomes separated from the remainder of the reaction gases. The hydrogen gas is collected for use. As such, the system and method acts both as a gas shift reactor and as a hydrogen separator even though it is a single unit.Type: GrantFiled: February 17, 2012Date of Patent: November 18, 2014Inventors: Peter R. Bossard, Jacob Mettes
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Patent number: 8883118Abstract: A process for producing the porous catalyst body for decomposing hydrocarbons, the body containing at least magnesium, aluminum and nickel, and has a pore volume of 0.01 to 0.5 cm3/g, an average pore diameter of not more than 3006 ? and an average crushing strength of not less than 3 kgf. The process includes molding hydrotalcite containing at least magnesium, aluminum and nickel, and calcining the resulting molded product at a temperature of 700 to 1500° C.Type: GrantFiled: June 25, 2013Date of Patent: November 11, 2014Assignee: Toda Kogyo CorporationInventors: Shinji Takahashi, Naoya Kobayashi
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Publication number: 20140328749Abstract: The present invention relates to the use of a process for hydrogen production in which at least a part of a hydrocarbonaceous feed gas (a) is passed into a reformer (c), wherein the feed gas is contacted in the reformer with a catalyst and the feed gas is converted to hydrogen and solid carbon, for the direct production of a hydrogenous gas at filling stations for sale to a consumer, and also to a reactor (d) for hydrogen production.Type: ApplicationFiled: June 20, 2014Publication date: November 6, 2014Applicant: BESTRONG INTERNATIONAL LIMITEDInventors: Ernst Hammel, Klaus-Dieter Mauthner, Walter Briceta
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Patent number: 8864857Abstract: An apparatus for generating hydrogen gas from a replaceable aluminum pack comprising an aluminum and hydride mixture encased in a breathable membrane that is raised and lowered into a fluid contained within an enclosed tank wherein contact with the fluid releases hydrogen gas from the aluminum. A pressure transducer and microprocessor chip are provided for monitoring and regulating the rate of hydrogen production by engaging and disengaging a reversible motor that raises and lowers an inner tray on which the aluminum pack resides accordingly.Type: GrantFiled: July 26, 2011Date of Patent: October 21, 2014Inventor: Harlo Mayne
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Patent number: 8865117Abstract: The invention provides an integrated catalyst and membrane reactor for the production a predetermined gas such as hydrogen. The reactor comprises a gas flow channel, comprising a plurality of alternating catalyst sections and membrane sections, wherein each catalyst section comprises a catalyst bed and each membrane section comprises a plurality of membranes, and wherein the membranes are selectively permeable for the predetermined gaseous species.Type: GrantFiled: February 17, 2012Date of Patent: October 21, 2014Assignee: Stichting Energieonderzoek Centrum NederlandInventors: Arend De Groot, Yvonne Christine Van Delft, Marija Saric
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Patent number: 8852822Abstract: When terminating power generation by a fuel cell 3 in a fuel cell system 1, an amount of a raw fuel material introduced to a reforming catalyst 2a of a reformer 2 is reduced. Here, before the temperature of the reforming catalyst 2a is lowered to the un-reformed gas generation temperature, an amount of water supplied to the reforming catalyst 2a is controlled to increase the temperature of the reforming catalyst 2a. Thus, upon termination of power generation in the fuel cell 3, no un-reformed gas is generated and the reformed gas is supplied to the fuel cell 3.Type: GrantFiled: January 8, 2014Date of Patent: October 7, 2014Assignee: Nippon Oil CorporationInventor: Tomotaka Ishida
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Patent number: 8834587Abstract: Reactor systems and methods are provided for the catalytic conversion of liquid feedstocks to synthesis gases and other noncondensable gaseous products. The reactor systems include a heat exchange reactor configured to allow the liquid feedstock and gas product to flow concurrently in a downflow direction. The reactor systems and methods are particularly useful for producing hydrogen and light hydrocarbons from biomass-derived oxygenated hydrocarbons using aqueous phase reforming. The generated gases may find used as a fuel source for energy generation via PEM fuel cells, solid-oxide fuel cells, internal combustion engines, or gas turbine gensets, or used in other chemical processes to produce additional products. The gaseous products may also be collected for later use or distribution.Type: GrantFiled: July 2, 2012Date of Patent: September 16, 2014Assignee: Virent, Inc.Inventors: Randy D. Cortright, Robert T. Rozmiarek, Charles C. Hornemann
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Patent number: 8834585Abstract: A hydrogen generating device is adapted for a fuel cell. The hydrogen generating device includes a casing, a button, a solid reactant, a bag-shaped body, and at least one flexible element. The casing has a containing space and an opening. The button is integrally formed and connected to the casing to seal the opening. The solid reactant is disposed in the casing. The bag-shaped body is disposed in the casing and contains a liquid reactant. The flexible element is connected to the casing and is located in the containing space. The flexible element includes a bending end, wherein the flexible element is aligned to the button and is located between the button and the bag-shaped body. When the button is pressed, the button pushes the flexible element so the bending end pierces the bag-shaped body, and the liquid reactant flows out and reacts with the solid reactant to generate hydrogen.Type: GrantFiled: July 21, 2011Date of Patent: September 16, 2014Assignee: Young Green Energy Co.Inventors: Yu-Hsiang Lin, Hsuan-Yi Lu
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Patent number: 8834834Abstract: Processes for producing synthesis gas from biomass in which char particles, which are formed during the production of synthesis gas from biomass, are employed as catalysts. The char particles may be used as catalysts in a gasifier or in a thermal reformer, whereby gaseous components, formed as a result of the gasification of the biomass, such as methane, light alkyl and aromatic compounds, and phenolics, as well as tar, may be reformed and/or converted into synthesis gas.Type: GrantFiled: July 16, 2012Date of Patent: September 16, 2014Assignee: Enerkem, Inc.Inventors: Antonin Paquet, Esteban Chornet
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Patent number: 8834604Abstract: A membrane for use in a high temperature gas processing system and method for making the same. The membrane includes a dense, gas impermeable layer and a first and second porous layer, wherein each of the first and second porous layers is a ceramic oxide material having a non-symmetrical load bearing skeleton of a plurality of pores having a graded porosity. Each porous layer provides a reduction of an oxygen partial pressure gradient across the dense layer and reduces resultant stresses in the dense layer that are small compared to its strength thereby improving long term mechanical durability of the dense layer.Type: GrantFiled: September 16, 2011Date of Patent: September 16, 2014Assignee: Volt Research, LLCInventors: Ajit Y. Sane, Thomas L. Cable
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Patent number: 8821832Abstract: The invention relates to a fuel processor that produces hydrogen from a fuel. The fuel processor comprises a reformer and a heater. The reformer includes a catalyst that facilitates the production of hydrogen from the fuel; the heater provides heat to the reformer. Multipass reformer and heater chambers are described that reduce fuel processor size. Single layer fuel processors include reformer and heater chambers in a compact form factor that is well suited for portable applications. Some fuel processors described herein place an electrically resistive material in contact with a thermally conductive material to heat fuel entering the fuel processor. This is particularly useful during start-up of the fuel processor. Fuel processors described may also include features that facilitate assembly.Type: GrantFiled: December 5, 2011Date of Patent: September 2, 2014Assignee: UltraCell, L.L.C.Inventors: Jennifer E. Brantley, Ian W. Kaye, Arpad Somogyvari, Gerry Tucker, Fan Liang Chan
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Patent number: 8815208Abstract: A process for the steam reforming of hydrocarbons comprises partially oxidising a feedgas comprising a hydrocarbon feedstock with an oxygen-containing gas in the presence of steam to form a partially oxidised hydrocarbon gas mixture at a temperature >1200° C. and passing the resultant partially oxidised hydrocarbon gas mixture through a bed of steam reforming catalyst, wherein the bed comprises a first layer and a second layer, each layer comprising a catalytically active metal on an oxidic support wherein the oxidic support for the first layer is a zirconia.Type: GrantFiled: May 9, 2006Date of Patent: August 26, 2014Assignee: Johnson Matthey Public Limited CompanyInventors: Peter William Farnell, Martin Fowles
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Publication number: 20140235912Abstract: A method for the recovery of energy from synthesis gas waste products obtained from wet crushed coal, according to a gasification-pyrolysis process, which comprises the submission of the waste products obtained during the production of the synthesis gas to a subsequent treatment, to transform such products into other products of the branched-chain alkane type and aromatic compounds, recovering the hydrogen obtained during these reactions, which will be available to be used at other chemical processing plants, as fuel or simply to be fed back to the gasification-pyrolysis process itself, to enrich the synthesis gas obtained.Type: ApplicationFiled: September 1, 2011Publication date: August 21, 2014Applicant: GURADOOR, S.L.Inventor: Daniel Gonzalez Gonzalez
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Patent number: 8809603Abstract: A method of producing a hydrocarbon fuel from a hydrocarbon-containing gas is disclosed and described. A hydrocarbon-containing gas is produced (10) containing from about 25% to about 50% carbon dioxide and can be reformed (12) with a steam gas to form a mixture of hydrogen, carbon monoxide and carbon dioxide. The reforming can be a composite dry-wet reforming or a tri-reforming step. The mixture of hydrogen, carbon monoxide and carbon dioxide can be at least partially converted (14) to a methanol product. The methanol product can be converted to the hydrocarbon fuel (18), optionally via UME synthesis (16). The method allows for effective fuel production with low catalyst fouling rates and for operation in an unmanned, self-contained unit at the source of the hydrocarbon-producing gas.Type: GrantFiled: February 15, 2013Date of Patent: August 19, 2014Assignee: Oberon Fuels, Inc.Inventors: Andrew Corradini, Jarod McCormick
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Patent number: 8784531Abstract: In a gas separation apparatus that separates carbon dioxide and water vapor from a first mixture gas containing a predetermined major component gas, carbon dioxide, and water vapor, the energy utilization efficiency thereof is improved. Also, by utilizing the function of this gas separation apparatus, a membrane reactor and a hydrogen production apparatus exhibiting high energy utilization efficiency are provided. The gas separation apparatus is constructed to include a first separation membrane 33 and a second separation membrane 34 that are made of different materials. When the first mixture gas is supplied at a temperature of 100° C. or higher, the first separation membrane 33 separates a second mixture gas containing carbon dioxide and water vapor that permeate through the first separation membrane by allowing carbon dioxide and water vapor to permeate selectively.Type: GrantFiled: December 26, 2011Date of Patent: July 22, 2014Assignee: Renaissance Energy Research CorporationInventors: Osamu Okada, Masaaki Teramoto, Eiji Kamio, Nobuaki Hanai, Yasato Kiyohara
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Patent number: 8764854Abstract: In some embodiments, a deposit-forming reference fuel composition comprises a high sulfur base fuel composition in an amount greater than 50 weight % based on total weight % of the deposit-forming reference fuel composition, wherein the high sulfur base fuel composition comprises greater than or equal to 200 ppm sulfur based on total sulfur content of the base fuel composition. The deposit-forming reference fuel composition also comprises a reactive diolefin dopant; and a reaction initiating peroxide. The reaction initiating peroxide has an active oxygen content greater than or equal to 2 weight % based on total oxygen content of the reaction initiating peroxide and a half-life temperature of 80° C. to 200° C. The deposit-forming reference fuel composition is free from a detergent additive and has a concentration ratio of greater than 1:1 for the reactive diolefin dopant to the reaction initiating peroxide.Type: GrantFiled: March 20, 2012Date of Patent: July 1, 2014Assignee: GM Global Technology Operations LLCInventors: William M. Studzinski, Jill M. Cummings