Resin, Rubber, Or Hardenable Oil Containing Coating Patents (Class 427/221)
  • Patent number: 4970117
    Abstract: A composite comprising: a substrate; and a polymeric coating adhered to at least one surface of said substrate, said polymer coating having a thickness of about 1 to about 100 micrometers, wherein said polymer coating comprises a neutralized carboxylated polymer having a carboxylate content of about 5 to about 300 meq. per 100 grams of said neutralized carboxylated polymer.
    Type: Grant
    Filed: October 28, 1988
    Date of Patent: November 13, 1990
    Assignee: Exxon Research and Engineering Company
    Inventors: Ilan Duvdevani, Pacifico V. Manalastas, Evelyn N. Drake
  • Patent number: 4966785
    Abstract: A method for coating interior capillary column surfaces, or packing material of a packed column, used for gas chromatography, with a stationary polymer phase that is cross-linked by exposing it to a low-temperature plasma that is uniformly distributed over the column or packing material for a predetermined period of time to effect the desired degree of cross-linking of the coating.
    Type: Grant
    Filed: July 3, 1989
    Date of Patent: October 30, 1990
    Assignee: Associated Universities, Inc.
    Inventor: Stephen R. Springston
  • Patent number: 4965012
    Abstract: A composition capable of releasing active enzyme into an aqueous, active chlorine containing media which in a first aspect comprises an enzyme core encapsulated with an initial coating of a time-release substance, a first coating of a bleach-neutralizing substance and a second coating of a time-release substance.In a second aspect, the composition comprises an enzyme encapsulated in a time-release substance designed to delay release of the enzyme in dissolution for a first-time delay, and a bleach-neutralizing substance, present as either a core material and/or a first coating on a diluent core, which is encapsulated in a time-release substance designed to delay release of the bleach-neutralizing substance into solution for a second-time delay; the first-time delay being longer than the second-time delay so that the bleach-neutralizing substance will be released and completely neutralize all active chlorine present in the solution before the enzyme is released.
    Type: Grant
    Filed: February 27, 1989
    Date of Patent: October 23, 1990
    Inventor: Keith E. Olson
  • Patent number: 4962166
    Abstract: In the manufacture of creep-free prepregs based on phenolic resins of the resole type, the reinformcing agents are impregnated with an essentially solvent-free mixture of a phenolic resin and a viscosity controlling amount up to 60% by weight of the resin of an alkali metal metaborate or an alkaline-earth metaborate or a mixture thereof. The resultant compression molded articles exhibit improved strengths.
    Type: Grant
    Filed: August 18, 1988
    Date of Patent: October 9, 1990
    Assignee: Norsolor
    Inventors: Francois Boinot, Michel Cousin
  • Patent number: 4956203
    Abstract: An improved electrically conductive polydiorganosiloxane of the type comprising a polydiorganosiloxane and conductive carbon particles has been developed. The improved electrical conductivity results from the addition of a conductivity improver comprising disilazane of the formula (R.sub.3 Si).sub.2 NH where R is a substituted or unsubstituted alkyl radical of from 1 to 6 carbon atoms or hydroxyl endblocked polymethylphenylsiloxane.
    Type: Grant
    Filed: November 20, 1989
    Date of Patent: September 11, 1990
    Assignee: Dow Corning Corporation
    Inventor: Loretta N. Kroupa
  • Patent number: 4954394
    Abstract: Phenolic resin compositions.Phenolic resin compositions containing an additive consisting of at least 20% by weight of an alkaline or alkaline-earth metaborate relative to the total weight of the additive.Applications to the manufacture of phenolic pre-preg mats which are stable in storage.
    Type: Grant
    Filed: January 22, 1990
    Date of Patent: September 4, 1990
    Assignee: Norsolor
    Inventors: Francois Boinot, Michel Cousin, Andre Hochin, Nicolas Meyer
  • Patent number: 4950502
    Abstract: A method of producing hydrophobic colloidal silica is disclosed. The method comprises combining an aqueous colloidal silica dispersion, polyorganosiloxane, and anionic surfactant to yield a stable aqueous emulsion of hydrophobic colloidal silica. The emulsion may be further processed by evaporating the water to yield a white material which may be easily ground to a fine powder of hydrophobic colloidal silica. This powder is useful as a reinforcement for silicone rubber.
    Type: Grant
    Filed: May 19, 1989
    Date of Patent: August 21, 1990
    Assignee: Dow Corning Corporation
    Inventors: John C. Saam, Bruce W. Sands
  • Patent number: 4927564
    Abstract: The invention concerns a method for conditioning in a thermosetting resin a quantity of waste stored in water.According to the invention, a liquid hardening agent, immiscible with water and having a density greater than that of the water, is used in order to harden the resin; this hardening agent is then mixed with the waste stored in the water and then the waste is left to decant in the hardening agent; then the water present above the decanted waste transferred into the liquid hardening agent is extracted and the waste transferred into the liquid hardening agent is mixed with the epoxy resin so as to obtain a solid block.In particular, the waste may be ion exchanger resins. Adding of the hardening agent to the waste stored in the water makes it possible to limit a temperature rise during hardining and to obtain solid products having an improved density.
    Type: Grant
    Filed: November 17, 1988
    Date of Patent: May 22, 1990
    Assignee: Commissariat a l'Energie Atomique
    Inventors: Andre Barlou, Alexandre Beltritti, Patrick Gramondi, Hugues Vidal
  • Patent number: 4925704
    Abstract: In a process for preparing spherical particles of a metal oxide or hydroxide having a particle size of from 0.1 to 10 .mu.m by adding a corresponding metal alkoxide to a dispersion of water-alcohol system having dispersed therein a metal oxide or hydroxide as a seed, under alkaline conditions and allowing a decomposition product from said metal alkoxide to attach onto said seed to effect particle growth of the seed, the improvement which comprises maintaining said dispersion at a substantially constant pH within the range between 10 and 13 during the addition of the metal alkoxide to said dispersion and the subsequent particle growth of the seed, thereby to prepare mono-dispersed particles substantially free from particle aggregation having a sharp particle size distribution of a standard deviation of not greater than 0.5. The white particles so prepared may be, after separation, heat treated to provide black particles. The white or black particles may be coated with a synthetic resin in the surface.
    Type: Grant
    Filed: June 13, 1988
    Date of Patent: May 15, 1990
    Assignee: Catalsts & Chemicals Industries Co., Ltd.
    Inventors: Goro Sato, Michio Komatsu, Hiroyasu Nishida, Yoshichika Tanaka, Tsuguo Koyanagi, Kei Mihara
  • Patent number: 4923714
    Abstract: Ceramic particulates useful as a proppant in hydraulic fracturing and in gravel packing operations is provided which comprises a ceramic (sometimes vitreous) core surrounded by an epoxy resin coating. Novolac epoxy resin compounds without any substantial acid soluble filler are used to coat ceramic particulates similar to those discloses in U.S. Pat. Nos. 4,680,230 and 4,632,876. The result is a product which combines the excellent solvent resistance of the ceramics with the acid resistance of the resin. The resin coating gives the added benefits of lower specific gravity and improved crush resistance.
    Type: Grant
    Filed: May 1, 1989
    Date of Patent: May 8, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: James L. Gibb, James A. Laird, Leslie G. Berntson
  • Patent number: 4921589
    Abstract: This invention relates to a photosensitizer which is bound to a polysiloxane polymer, a method of preparing the bound photosensitizer and a process for using the bound photosensitizer. The photosensitizers which may be used in the invention include rose bengal, rhodamine B, acridine orange, methylene blue and zinc phthalocyanine. The photosensitizer is attached to the polysiloxane by reacting a hydroxyl or vinyl group on the photosensitizer with a hydrogen on the polyhydrosiloxane, thereby binding the photosensitizer into the polymer network. Finally, the bound photosensitizer may be used to oxidize undesirable oxidizable compounds present in a hydrocarbon or aqueous fraction. One specific example is the sweetening of kerosene which involves oxidizing the mercaptans contained in the kerosene.
    Type: Grant
    Filed: December 20, 1988
    Date of Patent: May 1, 1990
    Assignee: Allied-Signal Inc.
    Inventors: Stephen F. Yates, Mary L. Good, Inara M. Brubaker
  • Patent number: 4919841
    Abstract: A process is provided for preparing encapsulated active particles by the steps of: dispersing active materials in molten wax; emulsifying the active/wax dispersion in aqueous surfactant solution for no longer than 4 minutes; quenching the capsules by cooling; and retrieving solidified capsules. The active materials may be selected from chlorine or oxygen bleaching agents, bleach precursors, enzymes, perfumes, fabric softening agents, and surfactants. Optimal capsules are obtainable where a blend of hard and soft waxes are utilized for the coating. The hard and soft waxes are characterized by needle penetration values no higher than 30 mm and no lower than 35 mm, respectively, at 25.degree. C. The resultant capsules have utility for cleaning compositions such as automatic dishwashing detergent formulations.
    Type: Grant
    Filed: June 6, 1988
    Date of Patent: April 24, 1990
    Assignee: Lever Brothers Company
    Inventors: Ahmed Kamel, Lisa C. Hurckes, Monica M. Morelli
  • Patent number: 4915987
    Abstract: A method of improving the quality of the surface of solid particles is disclosed. The method includes fixing material different from the solid particles to the surface of the solid particles by the use of an impact striking device. The material fixed to the solid particles can be other solid particles or particles contained in a liquid, which forms a film.
    Type: Grant
    Filed: April 11, 1988
    Date of Patent: April 10, 1990
    Assignee: Nara Machinery Co., Ltd.
    Inventors: Yorioki Nara, Masumi Koishi
  • Patent number: 4915985
    Abstract: A method of fabricating an electrode which comprises an intimate mixture of finely divided electroactive material in a matrix composed of a conjugated backbone polymer which comprises the steps of: derivatizing the surface of finely divided alkali-metal alloying metal, alkali metal cation inserting material or anion inserting material with active polymer catalyst; dispersing the derivatized metal or material having a desired small particle size in a gas, suspension or solution of a monomer or other precursor of the desired conjugated backbone polymer and polymerizing the monomer and/or precursor in the presence of the dispersed metal or material; and fabricating a cohesive solid by recovering the polymerization product from said gas, suspension or solution comprising derivatized metal or material coated with conjugated backbone polymer and forming same into a cohesive solid.
    Type: Grant
    Filed: August 15, 1986
    Date of Patent: April 10, 1990
    Assignee: Allied-Signal Inc.
    Inventors: MacRae Maxfield, Lawrence W. Shacklette, Sharon Gould
  • Patent number: 4915804
    Abstract: This invention relates to a photosensitizer which is bound to a titanate polymer, a method of preparing the bound photosensitizer and a process for using the bound photosensitizer. The photosensitizers which may be used in the invention include rose bengal, azure blue, rhodamine B, fluorescein and eosin. The photosensitizer is attached to the titanate by displacing a ligand on the titanate with a hydroxyl group on the photosensitizer. Finally, the bound photosensitizer may be used to oxidize undesirable oxidizable compounds present in a hydrocarbon or aqueous fraction. One specific example is the sweetening of kerosene which involves oxidizing the mercaptans contained in the kerosene to disulfides.
    Type: Grant
    Filed: December 20, 1988
    Date of Patent: April 10, 1990
    Assignee: Allied-Signal Inc.
    Inventors: Stephen F. Yates, Mary L. Good, Romulus Gaita
  • Patent number: 4913935
    Abstract: The invention includes producing a stable polybutadiene film on an alumina support wherein the alumina contains an alumina having a habit or form of crystals formed during a precipitation of aluminum hydroxide from an alkali metal aluminate by preselecting and controlling the pH of the alkali metal aluminate and the addition of certain monohydric and polyhydric alcohols to the alkali metal aluminate solution. Precipitation is controlled to form crystals having a habit or form which varies from principally acicular to principally lamellar crystal forms. This alumina is (a) coated with polybutadiene to form a polymer film layer on the alumina support and (b) the polymer film layer is cross-linked to form a stable polybutadiene coated and crosslinked on a support of acicular or lamellar alumina.
    Type: Grant
    Filed: December 28, 1988
    Date of Patent: April 3, 1990
    Assignee: Aluminum Company of America
    Inventor: GwoChung Lin
  • Patent number: 4912178
    Abstract: Phenolic resin compositions.Phenolic resin compositions containing an additive consisting of at least 20% by weight of an alkaline or alkaline-earth metaborate relative to the total weight of the additive.Applications to the manufacture of phenolic prepreg mats which are stable in storage.
    Type: Grant
    Filed: November 6, 1987
    Date of Patent: March 27, 1990
    Assignee: Societe Chimique des Charbonnages S.A.
    Inventors: Francois Boinot, Michel Cousin, Andre Hochin, Nicolas Meyer
  • Patent number: 4902570
    Abstract: The invention relates to a process for preparing highly dispersed metal oxides whose surfaces are modified by an ammonium-functional organopolysiloxane as a charge controlling substance for positive chargeable toners, in which the highly dispersed metal oxides are reacted with an organopolysiloxane which contains silicon-bonded terminal hydroxyl and/or alkoxy groups, diorganosiloxane units, in which the two organic radicals are monovalent hydrocarbon radicals, and siloxane units in which the organic radicals contain a positive charged nitrogen which is bonded to silicon via carbon.
    Type: Grant
    Filed: March 4, 1988
    Date of Patent: February 20, 1990
    Assignee: Wacker-Chemie GmbH
    Inventors: Mario Heinemann, Johann Bindl, Johann Doppelberger, Hans P. Scherm
  • Patent number: 4898750
    Abstract: We have found that it is possible to produce resin coated particular matter having uniform coating of resin to protect the particles against erosion or dissolution on contact with high pH fluids. The coated sand or other particles is produced by introducing the particles into a mixing device, to which is added a resin mixture comprising a urea formaldehyde resin and a furfural alcohol resin. The sand and resin mixture is mixed for sufficient time to accomplish uniform coating of the sand particle with the resin mixture. Next a foaming aqueous surfactant containing fluid is added which causes the resin-coated sand particles to be suspended in the foaming aqueous mixture. The surfactant fluid also contains acid catalyst. This mixture is allowed to set for a period of time after which the coated particles are washed and then cured at 300.degree. C. to accomplsih drying and complete the polymerization reaction.
    Type: Grant
    Filed: December 5, 1988
    Date of Patent: February 6, 1990
    Assignee: Texaco Inc.
    Inventors: Robert H. Friedman, Billy W. Surles
  • Patent number: 4897309
    Abstract: The surfaces of particulate adsorbents are consolidated by a process in which the adsorbent is impregnated with a cationic aqueous polymer solution and then treated with an anionic aqueous dispersion of a polymer having a softening point of from 60.degree. to 150.degree. C. and the materials are dried together.
    Type: Grant
    Filed: June 30, 1988
    Date of Patent: January 30, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Franz Haas, Gerold Schreyer
  • Patent number: 4897286
    Abstract: A process for producing a product of carbon fiber reinforced thermoplastic resin comprising immersing carbon fibers in a suspension of a powder of a thermoplastic resin in a liquid medium, which contains at least 20 wt % of an organic liquid and which contains from 0 to 80 wt % water, to impregnate the thermoplastic resin among carbon fibers, and heating the thermoplastic resin deposited on the fibers to melt and form a unitary assembly with carbon fibers.
    Type: Grant
    Filed: December 29, 1988
    Date of Patent: January 30, 1990
    Assignee: Toho Rayon Co., Ltd.
    Inventors: Hiroyuki Kosuda, Yasuhisa Nagata, Yoshihiro Endoh
  • Patent number: 4895687
    Abstract: A particulate mass that can be dusty but is generally sticky, due to the presence of water, is coverted to an apparently dry, non-dusty granular material by polymerizing a polymerizable material within the mass and breaking the mass down to the desired granular form after the polymerization has gone sufficiently far that the mass is substantially non-sticky but before the polymerization is completed.
    Type: Grant
    Filed: October 26, 1988
    Date of Patent: January 23, 1990
    Assignee: Allied Colloids Ltd.
    Inventors: David Farrar, Peter Flesher
  • Patent number: 4894105
    Abstract: An improved multifilamentary fibrous material is formed having particles of a matrix-forming thermoplastic polymer substantially uniformly dispersed among adjoining filaments in the absence of fusion bonding. The polymer particles initially are dispersed in an aqueous medium containing an effective amount of a dissolved polymeric binding agent and the viscosity of the medium subsequently is substantially increased to at least 50,000 cps. to form a gelled impregnation bath having a plastic flow characteristic with shear-thinning behavior wherein the polymer particles are substantially uniformly suspended. The resulting impregnation bath is caused to flow between the adjoining filaments of the multifilamentary fibrous material with a concomitant viscosity reduction which aids in the incorporation of the polymer particles. The concentration of the aqueous medium in the product is controlled to yield a uniform, handleable, drapable, tacky, and highly stable product.
    Type: Grant
    Filed: November 4, 1987
    Date of Patent: January 16, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Robert Dyksterhouse, Joel Dyksterhouse
  • Patent number: 4891245
    Abstract: A process for producing particles for use in electrophoretic displays, wherein a heavy, solid pigment preferred for its high contrast or refractive index properties is coated with a polymer starting material. The process significantly reduces the specific density of the resultant particle, and creates particles with smooth polymer surfaces that can be chosen for stability in a given electrophoretic carrier fluid, and possess acceptable electrophoretic characteristics.
    Type: Grant
    Filed: March 21, 1986
    Date of Patent: January 2, 1990
    Assignee: Koh-I-Noor Rapidograph, Inc.
    Inventor: Fortunato J. Micale
  • Patent number: 4889747
    Abstract: Expanded perlite compositions containing thereon, therein or thereon and therein buffered aqueous silane emulsion compositions as well as hydrophobic expanded perlite compositions as described above but from which residual water has been removed are provided. A process for the preparation of the same is also provided.
    Type: Grant
    Filed: March 1, 1989
    Date of Patent: December 26, 1989
    Assignee: PCR, Inc.
    Inventor: Michael E. Wilson
  • Patent number: 4888216
    Abstract: A process for preparing a copper powder for electroconductive paints, which comprises adding to a dispersion bath of copper powder and a dispersion medium a mixture of a titanium acylate polymer and a higher carboxylic acid ester to form a film of the titanium acylate polymer and the higher caboxylic acid ester on the surfaces of the particles of said copper powder, and if necessary, removing the dispersion medium to obtain the copper powder for electroconductive paints. The copper powder thus obtained is coated on the surfaces of its particles with the titanium acylate polymer and the higher carboxylic acid ester.
    Type: Grant
    Filed: March 27, 1989
    Date of Patent: December 19, 1989
    Assignee: Mitsui Kinzoku Kogyo Kabushiki Kaisha
    Inventors: Kanetaro Sannohe, Hirohisa Senzaki, Yoshio Sohama
  • Patent number: 4888248
    Abstract: There is disclosed a novel colloidal metal dispersion in which colloidal particles of a metal are protected by specific polymers including hydrazide polymers, acrylic ester polymers and acrylamide polymers. The colloidal metal dispersion is highly stable, and the colloidal metal particles protected by such specific polymers can be easily and strongly bound to various amino group-containing compounds to give stable colloidal metal complexes, which have a wide variety of uses, such as the use as a solid catalyst, the use for the treatment and diagnosis of various diseases, the use for studying tissues of living bodies, the use for including mutation of microorganisms, etc.
    Type: Grant
    Filed: May 7, 1987
    Date of Patent: December 19, 1989
    Assignee: Hidefumi Hirai
    Inventors: Hidefumi Hirai, Makoto Komiyama, Michitaka Otaki
  • Patent number: 4888215
    Abstract: A granular carbonaceous heat insulator comprising a carbon black pellet the surface of which is coated with a carbon layer having a dense structure is disclosed. This heat insulator is prepared by adhering a binder solution to a carbon black pellet, heating the resulting coating to remove a solvent from the binder solution and, at the same time, to cure the binder, and baking the carbon black pellet coated with the cured binder in a non-oxidizing atmosphere to carbonize the cured binder. Alternatively, the heat insulator is prepared by subjecting a carbon black pellet having specific characteristics to wet granulation in the presence of a binder solution to crush the carbon black pellet and, at the same time, to granulate the crushed pellet, thereby preparing a granulated carbon black pellet, followed by removal of the solvent from the prepared pellet, curing of the binder and baking of the cured binder in the same manner as that described above.
    Type: Grant
    Filed: December 17, 1987
    Date of Patent: December 19, 1989
    Assignee: Tokai Carbon Co., Ltd.
    Inventors: Toshio Nakada, Fumio Takemura, Masao Ishiwata
  • Patent number: 4885209
    Abstract: The invention relates to thermoplastic particulate graft polymers of a rubber (AB), consisting of a core (A) of rubber-like polymer of olefinically unsaturated monomers having softening temperatures (glass temperatures) below 0.degree. C. and a shell (B) of organopolysiloxane, and a polymer (C) of at least one ethylenically unsaturated monomer grafted into the rubber (AB) and to their use, optionally in admixture with brittle thermoplastic vinyl resins, as thermoplastic molding compositions.
    Type: Grant
    Filed: June 8, 1988
    Date of Patent: December 5, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Lindner, Herbert Eichenauer, Dieter Wittmann, Volker Damrath
  • Patent number: 4885191
    Abstract: The invention relates to a pigment coated with polycyanoacrylate and to a process for coating pigments.
    Type: Grant
    Filed: May 24, 1988
    Date of Patent: December 5, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Podszun, Helmut Waniczek
  • Patent number: 4879067
    Abstract: A flame retardant comprising of spherical red phosphorus free of pulverized face which is directly produced in the form of fine powder by conversion of yellow phosphorus, without pulverizing process. The red phosphorus characterized by its surface state and shape entirely different from any prior pulverized red phosphorus has not only a high flame retarding ability, but also a superior combination of chemical and physical properties, particularly with regard to corrosion resistance, moisture resistance, mechanical strength and dielectric properties which make it highly valuable and useful as a flame retardant for various nonflammable resinous compositions used in electric articles including electronic parts, machines, automobiles and buildings. The flame retardant is desirably coated with thermosetting resin and/or hydroxide of aluminum and/or zinc, thereby greatly improved in its stability.
    Type: Grant
    Filed: April 17, 1987
    Date of Patent: November 7, 1989
    Assignee: Rinkagaku Kogyo Co., Ltd.
    Inventors: Ichiro Sakon, Masao Sekiguchi, Atsushi Kanayama
  • Patent number: 4873145
    Abstract: A substantially water-resistant resin-coated aggregate for use in concrete includes a porous aggregate body, such as an artificial light weight aggregate, with an elastic layer made of a phenol resin elastomer deposited on the aggregate body, a rigid phenol resin coated on the elastic covered aggregate body. This resin-coated aggregate has a high water absorption prevention and further an external stress-damping function.
    Type: Grant
    Filed: November 26, 1986
    Date of Patent: October 10, 1989
    Assignee: Shimitzu Construction Co., Ltd.
    Inventors: Takeji Okada, Minoru Sawaide, Minoru Imai, Daisuke Tachibana
  • Patent number: 4869960
    Abstract: Ceramic particulate useful as a proppant in hydraulic fracturing and in gravel packing operations is provided which comprises a ceramic (sometimes vitreous) core surrounded by an epoxy resin coating. Novolac epoxy resin compounds without any substantial acid soluble filler are used to coat ceramic particulates similar to those disclosed in U.S. Pat. Nos. 4,680,230 and 4,632,876. The result is a product which combines the excellent solvent resistance of the ceramics with the acid resistance of the resin. The resin coating gives the added benefits of lower specific gravity and improved crush resistance.
    Type: Grant
    Filed: September 17, 1987
    Date of Patent: September 26, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: James L. Gibb, James A. Laird, Leslie G. Berntson
  • Patent number: 4868083
    Abstract: A process for producing a developer carrier is disclosed, which comprises heating a carrier composition containing a resin, magnetic particles and a compound having a lower critical surface energy than the resin, to produce a carrier particle having a higher surface concentration of the compound having a lower critical surface energy. A developer carrier having an average particle size of at least about 50 .mu.m and containing a fluorine-containing compound and fine magnetic particles dispersed in a binder resin is also disclosed. The developer carriers according to the invention when used in magnetic brush development provide superior charge generation, extended life and improved image reproduction.
    Type: Grant
    Filed: July 27, 1987
    Date of Patent: September 19, 1989
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Ikutaroh Nagatsuka, Yasuo Matsumura, Masayuki Takeda, Chiaki Suzuki, Takayoshi Aoki
  • Patent number: 4867902
    Abstract: An oxygen generating microencapsulated composition includes an oxygen generating core material and a coating which is water swellable. When exposed to water, the coating ruptures in an exfoliating manner, exposing the core material to water and thereby generating oxygen. The rate of oxygen release from the microcapsule can be controlled by altering wall continuity, thickness, capsule diameter, and coating characteristics. In other embodiments, combustion resistant materials are included in the wall material.
    Type: Grant
    Filed: March 23, 1988
    Date of Patent: September 19, 1989
    Assignee: Z-Gard, Inc.
    Inventor: Donald H. Russell
  • Patent number: 4859718
    Abstract: A method of producing a calcium carbonate, magnesium carbonate or calcium-magnesium carbonate which is surface modified with an organic material wherein the carbonate in substantially dry, particulate form is contacted with an organic monomer, copolymers or a prepolymer, and surface polymerization or reaction in situ on the carbonate in the presence of a gaseous hydrogen atmosphere is effected. In the case where the carbonate has been wet processed and residues of a dispersing agent employed remain as a coating on the carbonate particles after drying, a minor amount of a calcined kaolin or TiO.sub.2 is used as a polymerization catalyst. When the carbonate has been dry ground so that the particles are free from processing chemicals, no catalyst is needed to initiate the polymerization.
    Type: Grant
    Filed: March 31, 1988
    Date of Patent: August 22, 1989
    Assignee: E.C.C. America Inc.
    Inventor: Camilla A. Rice
  • Patent number: 4859497
    Abstract: A process is disclosed for pigmenting and coating a silver activated zinc sulfide phosphor and for imparting stir-in capabilities to the phosphor. The process comprises deagglomerating the phosphor, forming an aqueous slurry of phosphor particles, pigment particles, a binding agent which can be latex polymers or copolymers, the binding agent having a glass transition temperature of greater than about 20.degree. C. and a silica-based compound to produce a silica based coating on the phosphor particles, and agitating the slurry, separating the solids from the resulting liquor, and drying the solids at a temperature above the Minimum Film Formation Temperature of the latex to produce the phosphor particles wherein the pigment particles are bonded to them and wherein the pigmented phosphor particles are coated with the silica-based coating. The process comprises also pigmenting the phosphor and imparting stir-in capabilities thereto by the process as described above without adding the coating agent to the slurry.
    Type: Grant
    Filed: April 25, 1988
    Date of Patent: August 22, 1989
    Assignee: GTE Products Corporation
    Inventors: Robert W. Wolfe, James E. Morse
  • Patent number: 4857243
    Abstract: A method of making activated carbon microspherules including kneading activated carbon particles of a size below 100 .mu.m, together with a dispersion of a water-insoluble synthetic resin to form an intimate mixture; pressing the mixture through a screen having holes related to the size of the desired microspherules; powdering the pressed material; and granulating and drying the resulting microspherules.
    Type: Grant
    Filed: December 24, 1987
    Date of Patent: August 15, 1989
    Inventors: Hubert Von Blucher, Hasso Von Blucher, Ernest De Ruiter
  • Patent number: 4853259
    Abstract: A particulate built nonionic synthetic organic detergent composition includes a detersive proportion of a nonionic synthetic organic detergent and a building proportion, in combination, of a polyacetal carboxylate builder for the nonionic detergent and carbonate and bicarbonate builders for such nonionic detergent. Such compositions are readily made by adding polyacetal carboxylate builder to the formula of a control detergent composition, with corresponding diminutions of other component(s), and have detersive powers superior to such control despite the decrease in proportions present of detergent and other builders. Preferably, certain nonionic detergents, polyacetal carboxylate builders, carbonate and bicarbonate, in certain proportions, are employed to make a product of better detergency and physical characteristics, e.g., flowability.
    Type: Grant
    Filed: January 11, 1988
    Date of Patent: August 1, 1989
    Assignee: Colgate-Palmolive Company
    Inventor: Riad A. Taha
  • Patent number: 4851155
    Abstract: A solidification processing apparatus for radioactive waste materials comprises a tank for a solidifying agent for solidifying the radioactive waste materials, a waste material vessel connected to the tank for the radioactive waste materials, a pouring control unit for controlling pouring of the solidifying agent into the vessel, and a heating and curing chamber for heating the vessel by an indirect heating unit after pouring the solidifying agent onto the waste materials in the vessel to polymerize and set the solidifying agent, thereby solidifying the radioactive waste materials. With this arrangement, the solidifying agent superior in impregnation is poured into a vessel filled with radioactive waste materials, whose poured amount is controlled by the pouring control unit. After pouring the solidifying agent into the vessel, the vessel is heated indirectly by an indirect heating unit in order to avoid deflagration if the solidifying agent is combustible.
    Type: Grant
    Filed: February 1, 1988
    Date of Patent: July 25, 1989
    Assignees: NGK Insulators, Ltd., Chichibu Cement Co., Ltd.
    Inventors: Yutaka Kanagawa, Kanjiro Ishizaki, Mitsuzo Ozawa
  • Patent number: 4846893
    Abstract: A process for producing a surface treated pigment wherein pigment particles are dispersed in a solution of a water soluble high polymer having radical generation sites to adsorb the water soluble high polymer on the surfaces of the pigment particles, adding a vinyl monomer to the resulting aqueous liquid dispersion of the pigment particles subjected to the adsorption treatment and polymerizing in the presence of a polymerization initiator, if desired, to form a polymer layer on the surfaces of the pigment particles. Formation of the white polymer particles composed only of polymer can be prevented and dispersion stability can be improved.
    Type: Grant
    Filed: February 3, 1988
    Date of Patent: July 11, 1989
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yutaka Akasaki, Naoya Yabuuchi, Tatsuro Ohki
  • Patent number: 4840866
    Abstract: A photographic material exhibiting improved photographic characteristics comprising a photographic material comprising a support having a layer of microcapsules thereon, and an image-forming agent being associated with said microcapsules, said microcapsules including a mixture of a first subset of microcapsules and a second subset of microcapsules, said first and second subsets of microcapsules being associated with an image-forming agent for the same color, and said first subset of microcapsules providing a higher film speed than said second subset of microcapsules when said first and second subsets of microcapsules are exposed to a broad band white light source and developed under identical conditions.
    Type: Grant
    Filed: March 24, 1988
    Date of Patent: June 20, 1989
    Assignee: The Mead Corporation
    Inventors: Kerry Kovacs, William Simpson, Amy L. Burkholder, Russell K. Messer, Teresa M. Thomas
  • Patent number: 4839407
    Abstract: A method for preparation of solid particulate polyacetal carboxylate. The method comprises agglomerating a solution comprising less than about 1% by weight methanol and between about 30% by weight and about 60% by weight polyacetal carboxylate onto a substrate to produce a free-flowing particulate solid. The solid comprises between about 30% by weight and about 55% by weight polyacetal carboxylate. The polyacetal carboxylate corresponds to the formula: ##STR1## where n is at least about 4 and represents the average chain length of the polyacetal carboxylate in the mixture, R.sub.1 and R.sub.2 are independently selected chemically stable groups that stabilize the polymer against rapid depolymerization in alkaline solution, and M is selected from the group consisting of alkali metals, ammonium, alkyl groups of 1 to about 4 carbon atoms, tetraalkyl ammonium groups, and alkanolamine groups having from 1 to about 4 carbon atoms in the alkyl chain.
    Type: Grant
    Filed: February 8, 1988
    Date of Patent: June 13, 1989
    Assignee: Monsanto Company
    Inventors: David A. Martin, Edward L. Ries, William Vanderlinde, Marvin J. Young
  • Patent number: 4835023
    Abstract: An ornamental article comprising a natural ornamental material such as pearl and a cured coating membrane of a composition based on organic materials which is coated on the surface of said natural ornamental material in a thickness from 0.01 .mu.m to 30 .mu.m, with improved properties such as surface luster and resistivity to scratch, light, chemicals, etc.
    Type: Grant
    Filed: July 1, 1986
    Date of Patent: May 30, 1989
    Assignee: Toray Industries, Inc.
    Inventors: Takashi Taniguchi, Hiroshi Hosono, Itaru Nakamura
  • Patent number: 4831959
    Abstract: To uniformly and economically disperse liquids, via sprays of droplets, on surfaces of particles a method of moving the particles involves their rotary lifting, followed by their free falling, with a spray of droplets originating from a central area of the overall motion path of the particles. In a preferred embodiment of the method and a preferred embodiment of the blending apparatus, a hollow drum is rotated about a near horizontal axis. Inside the drum on a common rotating shaft spaced slightly conical discs ultimately disperse respective sprays of droplets from a central area. This central area is defined by particles being lifted while centrifugally held to the interior of the drum and then at a zenith locale the gravitational force becomes effective enough so the particles drop in an arcuate cascade path back to the interior surface of the drum to start another cycle.
    Type: Grant
    Filed: June 27, 1983
    Date of Patent: May 23, 1989
    Inventor: Harold D. Turner
  • Patent number: 4828883
    Abstract: A method and material for protection from airborne asbestos and other particular contamination is disclosed that is useful for protecting the environment and individuals working therein as occurs at a job site when friable or cementitious asbestos containing coatings are being removed from existing structures. The method includes application of a combined wetting and encapsulation formula which bonds the asbestos fibers to materials in the formula so as to convert friable asbestos to non-friable asbestos and a hardening procedure and formula which places the bonded non-friable asbestos in a hardened mass so that it may be safely disposed of.
    Type: Grant
    Filed: April 22, 1987
    Date of Patent: May 9, 1989
    Assignee: Allied Gator, Inc.
    Inventor: John R. Ramun
  • Patent number: 4820347
    Abstract: Means are disclosed for rendering talcs such as Montana talc or like talcs hitherto considered incompatible or unsuitable as fillers for thermoplastic resinous compositions, and particularly polypropylene molding resins, suitable for this use. Such talcs, which in their unbeneficiated state strongly discolor the resinous matrix and affect its long-term heat stability, are beneficiated in accordance with this invention, generally at low cost, while improving or at least not unacceptably diminishing other significant physical properties, particularly yellowness index, flexural modulus and impact strength, of the resulting molded article. This is accomplished by admixing Montana talc or the like with an effective amount of a combination of:(A) one or a mixture of certain octyl- or nonylphenol/poly(ethylene oxide) condensates, and(B) one or a mixture of certain poly(ethylene glycols) or alkoxypoly(ethylene glycols).
    Type: Grant
    Filed: January 14, 1987
    Date of Patent: April 11, 1989
    Assignee: Cyprus Minerals Company
    Inventor: Kenneth E. Weber
  • Patent number: 4816259
    Abstract: This invention provides a new gelatin capsule formulation and subcoating for producing soft gelatine capsules having better mechanical strength and an improved capacity for adhering to known coating compositions, particularly enteric coating compositions. The finished capsule shell formulation comprises gelatin 65%-70%, glycerin 22%-25% and water 8%-10% and the subcoating is a suspension of hydroxypropyl methylcellulose. The subcoating may also be used to manufacture improved enteric coated hard gelatin capsules.
    Type: Grant
    Filed: February 12, 1987
    Date of Patent: March 28, 1989
    Assignee: Chase Chemical Company, L.P.
    Inventors: James W. Matthews, Gerald Vergilio
  • Patent number: 4816371
    Abstract: A method for forming images which comprises image-wise exposing a photosensitive material to heat while simultaneously exposing said material to non-infrared actinic radiation, said material including a support and a layer of microcapsules containing an image-forming agent and a radiation curable composition on the surface of said support; said radiation curable composition being liquid at ambient temperatures and being substantially unhardened in the areas in which said material is simultaneously exposed to said heat and radiation and being substantially hardened in the areas in which said material is not simultaneously exposed to said heat and radiation; and subjecting said microcapsules to a uniform rupturing force such that said microcapsules image-wise release said image-forming agent.
    Type: Grant
    Filed: September 1, 1987
    Date of Patent: March 28, 1989
    Assignee: The Mead Corporation
    Inventors: Richard F. Wright, Paul C. Adair
  • Patent number: 4816299
    Abstract: Compositions for encapsulating electronic components are provided which comprise a blend of a curable resin and an ultra-pure silica filler. The filler is composed of fused silica granules which are prepared from a gel of a silicon-containing organic compound, such as TEOS, and which have a uranium content of less than about 0.1 parts per billion and a thorium content of less than about 0.5 parts per billion. The compositions can be readily manufactured in commercial quantities at reasonable costs and are particular well-suite for encapsulating components, such as, high density RAMs, which are sensitive to alpha particles.
    Type: Grant
    Filed: May 20, 1987
    Date of Patent: March 28, 1989
    Assignee: Corning Glass Works
    Inventors: James W. Alpha, Paul M. Schermerhorn, Michael P. Teter