Textile Or Cellulosic Base Patents (Class 427/342)
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Patent number: 7214736Abstract: Fluorochemical composition for rendering fibrous substrates oil repellent, water repellent, and/or stain or soil repellent. The composition comprises a dispersion or a solution of a fluorinated compound which comprises the reaction product of the following combination of reactants: (i) a fluorinated polyether according to the formula: Rf—Q—Tk ??(I) ?wherein Rf represents a monovalent perfluorinated polyether group having a molecular weight of at least 750 g/mol, Q represents a chemical bond or a divalent or trivalent organic linking group, T represents a functional group capable of reacting with an isocyanate and k is 1 or 2; (ii) an isocyanate component selected from a polyisocyanate compound that has at least 3 isocyanate groups or a mixture of polyisocyanate compounds wherein the average number of isocyanate groups per molecule is more than 2; and (iii) optionally one or more co-reactants capable of reacting with an isocyanate group.Type: GrantFiled: May 23, 2003Date of Patent: May 8, 2007Assignee: 3M Innovative Properties CompanyInventors: Frans A. Audenaert, Rudolf J. Dams, Richard S. Buckanin, Cheryl L. S. Elsbernd, Chetan P. Jariwala, E. Steven McAlister, Pierre J. Vander Elst
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Patent number: 7135209Abstract: The present invention relates to water soluble radiation activatable polymer resin formulations which are suitable to modify the absorption properties of fibrous materials and the polymer obtained by such radiation activatable polymer resins and the method of preparing such polymer. Fibrous materials made with radiation activatable resin formulations according to this invention are especially suitable for use in disposable absorbent articles.Type: GrantFiled: May 29, 2002Date of Patent: November 14, 2006Assignee: Basf AktiengesellschaftInventors: Thomas Daniel, Rainer Dyllick-Brenzinger, Ralf Fink, Karl-Heinz Schumacher, Oliver Koch
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Patent number: 6960371Abstract: The present invention is directed to triggerable, water-dispersible cationic polymers. The present invention is also directed to a method of making triggerable, water-dispersible cationic polymers and their applicability as binder compositions. The present invention is further directed to fiber-containing fabrics and webs comprising triggerable, water-dispersible binder compositions and their applicability in water-dispersible personal care products, such as wet wipes.Type: GrantFiled: September 20, 2002Date of Patent: November 1, 2005Assignee: Kimberly-Clark Worldwide, Inc.Inventors: W. Clayton Bunyard, Michael R. Lostocco, Kelly D. Branham
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Patent number: 6863764Abstract: Scented decorative grasses having an appearance and/or texture simulating the appearance and/or texture of cloth are disclosed, as are methods for making such scented decorative grasses from materials wherein at least one surface of the material is modified to simulate the appearance and/or texture of cloth.Type: GrantFiled: April 17, 2003Date of Patent: March 8, 2005Assignee: Southpac Trust International, Inc.Inventor: Donald E. Weder
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Patent number: 6852360Abstract: A knitted screen cloth fabric including a polymer coated, fiber-reinforced, flexible, foil-like web and method for making same are disclosed, the web including a lattice material of filaments and a polyester binding thread.Type: GrantFiled: February 25, 2004Date of Patent: February 8, 2005Assignee: Saint-Gobain Technical Fabrics Canada, Ltd.Inventors: John Frederick Porter, Roger Peter Lewington
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Publication number: 20040248486Abstract: Fibrous sheets are coated or impregnated with a biodegradable composition to render the sheets more resistant to penetration by liquids. Biodegradable polymer blends suitable for use in coating or impregnating a fibrous sheet can be manufactured from at least one “hard” biodegradable polymer and at least one “soft” biodegradable polymer. “Hard” biopolymers typically have a glass transition temperature of at least about 10° C. “Soft” biodegradable polymers typically have a glass transition temperature less than about 0° C. Another useful biodegradable polymer composition includes one or more biodegradable polymers and sufficient inorganic filler so as to render the treated sheet microwaveable. The biodegradable polymer compositions are especially well-suited for coating or impregnating paper sheets, e.g., 12-15 lb/3000 ft2 tissue paper to yield food wraps.Type: ApplicationFiled: June 3, 2003Publication date: December 9, 2004Inventor: Simon K. Hodson
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Patent number: 6821636Abstract: A method of producing formaldehyde laden layered products, the products having reduced emission of formaldehyde, of at least 2 layers, at least one of the layers being a veneer, comprising a step of treating at least one of the surfaces of said veneer, prior to bonding the layers together, with a solution comprising an ammonium salt. The invention also relates to a flooring material obtained by the method.Type: GrantFiled: March 11, 2002Date of Patent: November 23, 2004Assignee: Akzo Nobel N.V.Inventors: Robin Ljungar, Ingvar Lindh, Salme Pirhonen
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Patent number: 6773752Abstract: A method for making synthetic leather includes the steps of: preparing a knitted substrate having a longitudinal direction and a transverse direction transverse to the longitudinal direction, the knitted substrate being stretchable in the longitudinal and transverse directions; positioning two opposite sides of the knitted substrate along the longitudinal direction respectively on two conveyer chains and advancing the knitted substrate without tensioning the substrate along the longitudinal direction; and forming a coating on the knitted substrate by applying a polyurethane solution on the knitted substrate.Type: GrantFiled: October 30, 2002Date of Patent: August 10, 2004Assignee: Feng Shern Enterprise Co., Ltd.Inventor: Hsi-Chin Lo
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Patent number: 6749949Abstract: A method of producing formaldehyde laden layered products, the products having reduced emission of formaldehyde, of at least 2 layers, at least one of the layers being a board or veneer, comprising a step of treating at least one of the surfaces of said board or veneer, prior to bonding the layers together, with a solution comprising an inorganic sulphur containing salt. The invention also relates to a flooring material obtained by the method.Type: GrantFiled: March 11, 2002Date of Patent: June 15, 2004Assignee: Akzo Nobel N.V.Inventors: Robin Ljungar, Ingvar Lindh, Salme Pirhonen
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Publication number: 20040086647Abstract: Process for preparing durable, re-usable intermediate toner image-transfer belts or electrostatic transfuse belts. The present belts have a continuous elastomer-impregnated fibrous fabric support and at least one outer smooth release layer of a cured elastomer polymer. The invention is characterized by the application of a thin primer layer of a hydrolyzable polyfunctional silicone composition between the elastomer-coated surface of the fabric support and the outer elastomer polymer layer. The polyfunctional silicone chemically-bonds to the elastomer of the fabric support during hydrolysis and chemically-bonds to the outer elastomer layer during its cure, to form a durable, heat-resistant transfuse belt. The layers maybe applied to the fabric support by spray application as dilute solutions.Type: ApplicationFiled: October 22, 2003Publication date: May 6, 2004Applicant: Xerox CorporationInventors: Joseph A. Swift, Donald Stanton
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Patent number: 6569495Abstract: A composite porous structure capable of absorbing organic pollutants from water is produced by preparing a dispersion of non film-forming PVC particles in a water-soluble organic liquid, impregnating a macroporous matrix such as a cellulosic sponge or paper with the dispersion, and curing the impregnated matrix by heating to achieve sintering of the PVC particles to produce a microporous substrate which is retained within the macroporous matrix.Type: GrantFiled: October 9, 2001Date of Patent: May 27, 2003Inventor: Norman B. Rainer
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Patent number: 6565924Abstract: A process for treating a yarn and/or a fabric to form fine inorganic particulate material in the intra-yarn pores and/or on the surface of the fibers constituting the yarn or fabric, which would substantially maintain fabric reflectance after repeated wash/wear cycles without affecting the desired characteristics of air permeability. The inorganic particles are preferably formed by reacting in an aqueous medium a first reagent selected from mineral and organic acids and a second reagent selected from alkali or alkaline earth metal salts with inorganic anions. The invention also relates to a treatment product composition directed to provide instant inorganic deposits in the yarn or fiber surface.Type: GrantFiled: August 1, 2001Date of Patent: May 20, 2003Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventors: Gangundi Prakash Babu, Vinodkumar Ramniranjan Dhanuka, Kaushik Narotam Divecha, Manish Hardas Keswani, Raghavachari Rajan
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Patent number: 6333078Abstract: A collector is disclosed that is made of a polyolefin fiber having amidoxime groups and that is capable of efficient adsorptive recovery of useful metals such as uranium, vanadium, cobalt and titanium which are dissolved in small quantities in seawater. In the presence of a polymerizable monomer having a hydrophilic group, a polymerizable monomer having a cyano group is grafted to a polyolefin fiber by radiation-initiated graft polymerization to form both a hydrophilic group and a cyano group in the same graft side chains, and the cyano groups in the graft side chains are reacted with hydroxylamine to be converted to amidoxime groups, thereby producing a collector capable of recovering dissolved metals from seawater.Type: GrantFiled: December 14, 1999Date of Patent: December 25, 2001Assignee: Japan Atomic Energy Research InstituteInventors: Takanobu Sugo, Akio Katakai, Noriaki Seko
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Patent number: 6248404Abstract: The present invention involves a method for altering preexisting patterns of ink on paper. Used, waste paper is treated such that words, images and pictures are altered to form substantially different and aesthetically pleasing patterns. A chemical activator is applied to waste paper, thereby causing the present ink to diffuse. Optionally, additional inks may be added and further diffused across the paper. Once the treated paper has dried, a new, unique pattern has formed. In this manner, previously unuseable paper becomes suitable for a variety of aesthetic purposes. The resulting paper product may be used for wrapping paper, contact paper, wallpaper or the like.Type: GrantFiled: August 24, 1999Date of Patent: June 19, 2001Inventor: Mary Virginia Greene-Mathis
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Patent number: 6238742Abstract: The process for preadherizing a drawn polyester filament to improve adhesion of rubber material with the filament includes applying a preadherizing agent to a running drawn polyester filament. The preadherizing agent is made by mixing a first solution containing a polyepoxide and a second solution containing a tertiary amine. In order to minimize soiling of the applicators used to apply the solutions to the running drawn polyester filament, the first solution is applied to the running drawn polyester filament at a site spaced a predetermined distance from the site at which the second solution is applied.Type: GrantFiled: September 30, 1999Date of Patent: May 29, 2001Assignee: Rhodia Filtec AGInventors: Istvan Csonka, Beat Meyer
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Patent number: 6231926Abstract: A process for producing poromeric synthetic leather comprises I. producing an essentially nonporous impregnate by impregnating a textile sheet material with an aqueous polyurethane dispersion and drying, and II. producing a poromeric synthetic leather from the impregnate by subjecting the impregnate to the action of an aqueous solution of a Brønsted base.Type: GrantFiled: June 4, 1999Date of Patent: May 15, 2001Assignee: BASF AktiengesellschaftInventors: Cesare Ronzani, Ralf Mossbach, Karl Häberle
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Patent number: 6214417Abstract: A cloth for ink jet printing, fabricated by providing a low density cloth with a sizing agent of the gel-transition type, gel-initiating agent, and ink receiving agent for filling up gaps between fibers, and by drying the low density cloth so that even in the case where the ink-jet printing process is applied to such a low density cloth as a loosely woven or knitted fabric, a clear image can be printed thereon without ink striking through gaps between fibers, and without causing the cloth to be stained. For the low density cloth, a cloth of a single yarn weight fineness of 100 d or less, and a woven or knitted fabric of a warp density of 120 warps or less/inch or a filling density of 150 fillings or less/inch are suitable. With the use of the cloth, an ink-jet printed fabric deep in color as well as abundantly expressive of gradation (that is, having a wide range of color strength) can be obtained while preventing ink from passing through, and supporting members and the cloth from being stained.Type: GrantFiled: July 10, 1998Date of Patent: April 10, 2001Assignee: Seiren Co., Ltd.Inventors: Ichiei Watanabe, Saiko Yamada, Naohiro Oobayashi, Hiroyuki Makita
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Patent number: 6110533Abstract: Articles comprising a substrate and a polymeric desiccant either impregnated therein or coated thereon are disclosed as well as processes for their manufacture. The invention also contemplates a process for synthesizing a polymeric dessicant in particulate form for use as such or for use as a coating material for desiccant articles.Type: GrantFiled: March 16, 1998Date of Patent: August 29, 2000Assignee: Her Majesty the Queen in right of Canada, as represented by the Minister of Natural ResourcesInventors: Roland Cote, Sophie Hosette, Mouloud Amazouz
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Patent number: 6071549Abstract: Salts of hydroxy acids include functional groups capable of forming "hybrid" ionic bonds with fibers or particles and another functional group capable of forming a hydrogen bond or "hybrid" ionic bond with the fibers when the binder forms a "hybrid" ionic bond with the particles or a hydrogen, coordinate covalent, or "hybrid" ionic bond with the particles when the binder forms a "hybrid" ionic bond with the fibers. Amino acids are also described as binders capable of forming "hybrid" ionic or ionic bonds between fibers and particles. Salts of bases, such as choline chloride are also described as being useful binders for attaching particles to fibers. The salts of bases form ionic bonds with either the particles or the fibers. Such binding systems provide viable alternatives to existing binding systems.Type: GrantFiled: August 6, 1998Date of Patent: June 6, 2000Assignee: Weyerhaeuser CompanyInventor: Michael R. Hansen
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Patent number: 6042877Abstract: A method for making an anti-microbial article is described, the method comprising: providing a substrate; forming a solution comprising a chelating polymer and a metal ion; depositing the solution on the substrate; drying the substrate to form a coated substrate; and adding a potentiator to the coated substrate to form the antimicrobial article. Forming of the solution comprises (A) selecting a chelating polymer from the group consisting of polyglucosamines, ethylene acrylic acid copolymers, polycarboxylic acids, and polyamines, (B) dissolving the chelating polymer in acid to form an acidic solution, (C) preparing an aqueous solution of the metal ion, preferably by selecting a salt of the metal ion and dissolving the salt in water, and (D) combining the aqueous solution of the metal ion and the acidic solution.Type: GrantFiled: July 28, 1998Date of Patent: March 28, 2000Assignee: 3M Innovative Properties CompanyInventors: Keith R. Lyon, Michael M. Rock, Jr.
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Patent number: 6033719Abstract: A method for making a medical device having at least one biomolecule immobilized on a substrate surface is provided. The method may include combining a biomolecule comprising a 1,2 dicarbonyl moiety with a material comprising a guanidino moiety to form an immobilized biomolecule on a medical device biomaterial surface through covalent bonds. Another method of the present invention may include combining a biomolecule comprising a guanidino moiety with a material comprising a 1,2 dicarbonyl moiety to form an immobilized biomolecule on a medical device biomaterial surface through covalent bonds. Additionally, one method of the present invention may be employed to crosslink biomolecules, located in solution or on a medical device biomaterial surface, thereby forming a crosslinked biomaterial or a crosslinked medical device coating.Type: GrantFiled: January 22, 1998Date of Patent: March 7, 2000Assignee: Medtronic, Inc.Inventor: James R. Keogh
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Patent number: 6020397Abstract: A printing system consisting of at least two reactive components is disclosed, in which one component is a polymer having attached at least one functional group that is reactive with an aziridine, such as a carboxyl, thiocarboxyl, sulfonic, phosphoric, epoxy, or isocyanate group or derivative thereof, and the other component is an aziridine, which printing system can be used to provide printed images of excellent quality that are wet-rub resistant and accent marker resistant. In addition to using the invention two-component system to produce printed images directly, a method for using the two-component system to develop lithographic printing plates is disclosed.Type: GrantFiled: October 10, 1997Date of Patent: February 1, 2000Assignee: Westvaco CorporationInventor: Michael D. Matzinger
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Patent number: 5824370Abstract: A process for treating wood involving impregnation of the wood with a preservative followed by the heat-fixation of the preservative in the wood using a pre-heated aqueous heat transfer fluid to effect the heat fixation of the preservative. The process particularly relates to steps which are taken to reduce the level of any contamination of the aqueous heat transfer fluid resulting from any wood extractives, any unfixed preservative and/or any particulate matter (i.e. "sludge") that may be present in the fluid. The contamination is preferably reduced by incorporating in the heat transfer fluid an oxidant which will preferentially oxidize any wood extractives resulting from the contact of the treated wood with the fluid without any significant reaction occurring between the oxidant and the preservative. Useful oxidants include inorganic chlorate salts such as sodium chlorate.Type: GrantFiled: February 26, 1997Date of Patent: October 20, 1998Assignee: Chemical Specialties, Inc.Inventors: Anthony J. Bergervoet, James L. Marcinko, Paul Joseph Walcheski
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Patent number: 5789031Abstract: A process for manufacturing a coated paper for use in printing is characterized in that the coated paper for printing is produced by coating a color consisting mainly of pigment and a water-soluble binder made of starch or starch derivatives to the surface of a base paper, then drying and finishing it. Steam or an aqueous penetrant solution having a penetrating force of less than 50 seconds is sprayed or applied over the dry coated layer surface of the coated paper, prior to it being finished with a calender, for redistributing the water-soluble binder in the coated layer in order to correct its uneven distribution, which is the cause of printing mottle during the offset printing operation.Type: GrantFiled: December 16, 1996Date of Patent: August 4, 1998Assignee: Oji Paper Co., Ltd.Inventors: Tetsuya Hirabayashi, Hideyuki Suzuki, Terunobu Fukui
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Patent number: 5789087Abstract: A method of preserving waterlogged materials and more specifically, preserving artifacts that have been submerged in water for long periods of time. A method of treating waterlogged materials that have been subjected to preservation techniques using polyethylene glycol as the preservative, and a method of restoring such materials from the deleterious effects of the glycol.Type: GrantFiled: January 8, 1997Date of Patent: August 4, 1998Assignee: Dow Corning CorporationInventors: Jerome Melvin Klosowski, Charles Wayne Smith
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Patent number: 5776598Abstract: A method of treating a surface of a fiber, e.g. cellulosic fiber, with a finish in which the surface finish is applied as an aqueous emulsion stabilized at a first pH value and at the latest when applied to the fiber the emulsion is caused to destabilize by a change in the first pH value. The invention also relates to cellulosic fiber and threads thereof and to tampons made from cellulosic fiber.Type: GrantFiled: January 30, 1996Date of Patent: July 7, 1998Assignee: Faserwerk Kelheim GmbHInventors: Bernd Huber, Gerhard Stein, Heinz Paul Poter, David Eric William Hill
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Patent number: 5770266Abstract: According to the invention, molecules having conductive, photofunctional and other functions are secured by chemical bonds to a substrate via a chemically adsorbed monomolecular film by an adsorption process. The process comprises a step of contacting the substrate with a non-aqueous solution containing a material. The material includes a straight chain molecules having a plurality of chlorosilyl groups at both ends. A reaction occures between hydroxyl groups on the substrate surface and chlorosilyl groups at one of the ends of the material having the chlorosilyl groups. Prior to the reaction the substrate is washed with a non-aqueous organic solution by dipping the substrate in a non-aqueous solution containing molecules having a specific function for causing the reaction of the molecules with the chlorosilyl groups at the other end of the molecules having the chlorosilyl groups, thereby securing the molecules to the surface of the substrate.Type: GrantFiled: August 16, 1995Date of Patent: June 23, 1998Assignee: Matsushita Electric Industrial Co., Ltd.Inventor: Kazufumi Ogawa
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Patent number: 5733603Abstract: A method for coating the surface of a substrate composed of a hydrophobic polymer with a hydrophobic vinyl polymer. The method includes preparing a solution of the hydrophobic vinyl polymer in a polar nonaqueous solvent, such as 1-methyl-1-pyrrolidinone, in which the hydrophobic vinyl polymer is surface-active. The substrate then is treated with the solution under conditions sufficient to deposit the hydrophobic vinyl polymer on the substrate. The hydrophobic vinyl polymer may have readily hydrolyzable pendant groups which, upon hydrolysis thereof in an aqueous medium, will result in the formation of a hydrophilic vinyl polymer coating on the substrate. For example, the hydrophobic vinyl polymer may be poly(vinyl trifluoroacetate). Also provided are coated substrates, in which the substrate is a shaped article composed of a hydrophobic polymer. The shaped article may be, for example, a film, fiber, or nonwoven web.Type: GrantFiled: June 5, 1996Date of Patent: March 31, 1998Assignee: Kimberly-Clark CorporationInventors: Leonid Anthony Turkevich, David Lewis Myers, Gunilla Elsa Gillberg-LaForce
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Patent number: 5692936Abstract: A moisture-permeable waterproof fabric comprising a textile fabric and, provided on at least one surface of said textile fabric, a resin film comprising a polyurethane resin produced by reacting an isocyanate with a polyol and a chain extender and having a glass transition temperature in the range of from -20.degree. to 20.degree. C. and an ethylene oxide unit content of at least 7.0 mol/kg. The moisture-permeable waterproof fabric is produced by coating at least one surface of a textile fabric with a solution of a resin in a polar organic solvent, the resin comprising a polyurethane resin, and subjecting the coating to wet solidification in a coagulation bath to form a film, or coating a release paper with a solution of a resin in a polar organic solvent, the resin comprising a polyurethane resin, to form a resin film and adhering the resin film on at least one surface of a textile fabric.Type: GrantFiled: April 22, 1996Date of Patent: December 2, 1997Assignees: Komatsu Seiven Co., Ltd., Mitsubishi Jokogyo Kabushiki KaishaInventors: Munehide Yamaguchi, Hideki Chatani, Shunichi Hayashi, Yukihiro Sakaguchi, Satoru Kondo
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Patent number: 5683744Abstract: The invention relates to a process for the preparation of a porous material layer covered with an electronically conductive polymer and to the product obtained by this process.This process consists of placing the layer (1) on a support sheet (3) optionally having roughnesses or unevennesses (4), applying to the layer a polymerization solution comprising a monomer (pyrrole), an oxidizing agent (FeCl.sub.3) and a doping agent (naphthalene disulphonic acid salt) using nozzles (6). The assembly is then wound up to form a composite roll (11), which is then immersed in the same polymerization solution for an adequate time to form a uniform, conductive polymer deposit (polypyrrole).It is thus possible to obtain conductive textiles with surface resistances of 5 to 20 Ohm.sup.2.Type: GrantFiled: October 23, 1995Date of Patent: November 4, 1997Assignee: Commissariat a l'Energie AtomiqueInventors: Renaud Jolly, Cornelia Petrescu
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Patent number: 5670572Abstract: The present invention relates to melamine-formaldehyde resins comprising a guanamine, to processes for their preparation and to their use for the production of melamine resin films and edgings.Type: GrantFiled: November 3, 1995Date of Patent: September 23, 1997Assignee: Hoechst AktiengesellschaftInventors: Jurgen Ott, Manfred Schon, Wilhelm Adam, Frank Scholl, Alfons Wolf
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Patent number: 5670211Abstract: A method of applying a two-part liquid composition to a workpiece is provided. In particular, a two-step method is provided wherein a first liquid composition is applied to the workpiece by roll coating, and a second liquid composition is applied by spraying the workpiece. Generally, the first liquid composition is a polyurethane adhesive and the second liquid composition is a polyurethane catalyst. By applying the reactive components of the polyurethane composition in two steps, the open time may be controlled.Type: GrantFiled: September 14, 1995Date of Patent: September 23, 1997Assignee: Hoover Universal, Inc.Inventors: Kenneth G. Huber, Richard P. Doerer, Normand R. Marceau
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Patent number: 5626912Abstract: The present invention relates to a tufted fabric and a method of manufacturing the same. The tufted fabric generally comprises a primary backing and tufts mounted in the primary backing to form a fabric with a faceside having piles and a backside having loops. A thermoplastic polymer adhesive, which bonds the tufts to the primary backing, is formed by applying a reactive mixture comprising a polymerizable monomer to the backside of the tufted fabric and in-situ polymerizing the monomers to form the thermoplastic polymer adhesive. The process is particularly advantageous for the manufacture of recyclable tufted fabrics in which the adhesive polymer and tufts are formed from substantially the same polymer. The tufted fabric can be used in articles, such as, for example carpets, rugs and upholstery.Type: GrantFiled: April 14, 1995Date of Patent: May 6, 1997Assignees: DSM N.V., AlliedSignal Inc.Inventors: Jan A. J. Hendrix, Arnoldus M. Kerssemakers, Yousef Mohajer, Forrest E. Sloan
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Patent number: 5626950Abstract: A moisture-permeable, waterproof fabric comprising a textile fabric and a resin coating containing a fluorine-containing polyurethane resin and polyurethane resin having a low degree of polymerization on at least one side of said textile fabric. This moisture-permeable, waterproof fabric is obtained by a process comprising coating a resin solution, containing a fluorine-containing polyurethane resin and a polyurethane resin having a low degree of polymerization, on at least one side of a textile fabric, followed by coagulating the resin, removing the solvent, drying the fabric and applying a water repellent.Type: GrantFiled: December 22, 1994Date of Patent: May 6, 1997Assignee: Komatsu Seiren Co., Ltd.Inventors: Yasunao Shimano, Masashi Mukai, Hideki Chatani, Kazuhiko Takashima, Yoshihiro Umezawa, Dai Hara
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Patent number: 5571288Abstract: In the flame-retardant treatment of fabrics, there is provided a means for increased "loading" of phosphorus compounds (up to 25% moisture is retained after impregnation and drying of the fabric). This in turn enables a phosphonium compound "add-on" of 50% to 73% (relative to the weight of the fabric) and gives a correspondingly higher degree of flame-retardant properties.Type: GrantFiled: June 6, 1995Date of Patent: November 5, 1996Assignee: Albright & Wilson UK LimitedInventors: Mohsen Zakikhani, Xiao P. Lei
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Patent number: 5567478Abstract: The present invention relates to a process for producing water-absorbing sheet-like materials which consist of a water-absorbent polymer and a prefabricated nonwoven fabric, wherein the prefabricated nonwoven fabric is impregnated with a solution comprising partially neutralized acrylic acid and at least one cross-linking agent and is squeezed to a certain coating amount, and the monomer solution thus applied is characterized in that the polymerization is carried out in the presence of radical initiators which cannot be activated thermally and at least one thermally activatable radical former used in addition. The additional use of a thermally activatable radical former in the polymerization results in products having a low residual monomer content, an improved water absorption under load, and a higher retention, with a production method being employed which is technically simple and economically efficient at the same time.Type: GrantFiled: May 31, 1995Date of Patent: October 22, 1996Assignee: Chemische Fabrik Stockhausen GmbHInventors: Jochen Houben, Edgar Herrmann, Kurt Dahmen
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Patent number: 5547536Abstract: A ballistic laminate structure in sheet form, which includes a first array of high performance, unidirectionally-oriented fiber bundles and a second array of high performance, unidirectionally-oriented fiber bundles cross-plied at an angle with respect to the first array of fiber bundles, and laminated to the first array of fiber bundles in the absence of adhesives or bonding agents. First and second thermoplastic films are bonded to outer surfaces of the laminated first and second arrays of unidirectional fiber bundles without penetration of the films into fiber bundles or through the laminate from one side to the other.Type: GrantFiled: October 21, 1994Date of Patent: August 20, 1996Inventor: Andrew D. Park
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Patent number: 5494747Abstract: Textile fabrics, yarns and cords are impregnated with rubber, resin and particulate materials by dipping in an aqueous dispersion comprising an aqueous rubber latex, resin and the particulate material, the dispersion further containing a very minor amount of a water-soluble silicate, such as sodium silicate. After drying, the products can be used as reinforcement for mechanical rubber goods and friction materials such as clutch facings and the like.Type: GrantFiled: August 17, 1994Date of Patent: February 27, 1996Assignee: G B Tools & Components Exports LimitedInventor: Dong S. Rha
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Patent number: 5484825Abstract: The present invention is directed to a water-resistant, aqueous base-dispersible article which comprises a pulp-filled binder, one of which is an ethylenically unsaturated carboxylated (e.g. acrylic) polymer soluble in base, the other of which is water-resistant. Accordingly, the pulp can be water-resistant while the binder is base-dispersible or the converse can be true. Cellulosic and polymeric pulp are ideally suited for filling an base-soluble acrylic polymer. Water-soluble resins can be incorporated into the article for controlling the properties for special purposes. The method for forming such an article comprises yet another aspect of the present invention.Type: GrantFiled: September 14, 1993Date of Patent: January 16, 1996Assignee: Battelle Memorial InstituteInventors: Richard J. Dick, Nancy J. Fulton, James P. Pfau, Philip E. Bailey, John D. Booton
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Patent number: 5482747Abstract: Compositions based on blends of certain specified poly(vinyl alcohol) copolymers and other poly(vinyl alcohol) polymers are described which are useful as sizes, and have improved ability to be desized from fabrics compared with the other poly(vinyl alcohol) polymers alone. The specific poly(vinyl alcohol) copolymers useful in the blends with other poly(vinyl alcohol) polymers are copolymers having a high level of acrylic ester comonomer. The blend sizes are useful in producing woven materials since they are excellent sizes, and are uniquely adaptable to caustic desizing.Type: GrantFiled: May 19, 1995Date of Patent: January 9, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventors: Richard A. Hayes, George D. Robinson
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Patent number: 5433827Abstract: Acidic papers, books, and other sheets of cellulosic material may be deacidified and so given a prolonged life by bringing the papers, books, or other sheets of cellulosic material to be treated in intimate contact with a source of solid alkali such as calcium carbonate filled paper, at an elevated humidity and under mechanical pressure for a period long enough to produce deacidification; the process differs from other processes in that it is carried out in the solid state without the use of liquid or gaseous reactants.Type: GrantFiled: December 21, 1993Date of Patent: July 18, 1995Assignee: Pulp and Paper Research Institute of CanadaInventors: Derek H. Page, Anthony M. Scallan, Steven R. Middleton, Xuejun Zou
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Patent number: 5427844Abstract: A yarn, cloth, woven fabric, knitted fabric or nonwoven fabric composed of natural cellulose fibers, each fiber having incorporated therein a water-insoluble inorganic metal compound, and each fiber having at least one cured polycarboxylic acid combined therewith, said polycarboxylic acid being one selected from the group consisting of polycarboxylic acids and partial salts thereof, and a process for preparing the same.Type: GrantFiled: December 15, 1993Date of Patent: June 27, 1995Assignees: New Japan Chemical Co., Ltd., Shikibo Ltd.Inventors: Koichi Murai, deceased, by Kei Takeda, heir, by Kumi Fujimoto, heir, by Rumi Emori, heir, Hidekazu Nakagawa, Motohiko Otani, Yoshiaki Sakai, Hiroyuki Miura, Yutaka Tsujimoto, Kango Fujitani
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Patent number: 5413846Abstract: The following describes elasticized artificial leather characterized in that it is formed by a woven support material comprising warp threads and weft threads, said material being coated on at least one of its two sides by at least one layer of synthetic polymer, said woven material having its weft made from elasticized yarn produced using elastomeric fibers. A further object of the present invention is a process for production of the elasticized artificial leather.Type: GrantFiled: February 17, 1994Date of Patent: May 9, 1995Assignee: Man Made S.R.L.Inventor: Raffaele Besana
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Patent number: 5407699Abstract: A process is provided for forming an electrically conductive polymer of a pyrrole monomer, optionally substituted at the 3- and 4- positions. The process comprises dispersing a polymerization initiator selected from the group consisting of anhydrous halides of iron, cobalt or nickel (Group VIII metal) in an anhydrous liquid reaction medium and, adding essentially pure pyrrole monomer, or a solution of the monomer in the liquid at a temperature in the range from about -20.degree. C. to below about the boiling point of the solution. The pyrrole polymer so formed is a Group VIII metal halide counterion, and a conductor having a conductivity in the range from about 1 to about 150 ohm.sup.-1 cm.sup.-1 ("S/cm" for brevity), or a semiconductor having a conductivity in the range from about 10.sup.-3 to about 1 S/cm, depending upon the particular structure of the monomer, the ratio of the initiator to pyrrole monomer, and the molecular weight of the polymer formed.Type: GrantFiled: July 5, 1988Date of Patent: April 18, 1995Assignee: The B. F. Goodrich CompanyInventor: Ronald E. Myers
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Patent number: 5405653Abstract: Compositions based on blends of certain specified poly(vinyl alcohol) copolymers and various starches are described which are useful as sizes, and can have improved ability to be desized from fabrics compared with the starches alone. The specific poly(vinyl alcohol) copolymers useful in the blends with the starches are copolymers having a high level of acrylic ester comonomer. The blend sizes are useful in producing woven materials since they are excellent sizes, and are uniquely adaptable to caustic desizing.Type: GrantFiled: February 28, 1994Date of Patent: April 11, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventors: Richard A. Hayes, George D. Robinson
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Patent number: 5387437Abstract: A method to improve bonding of breathable coatings onto fabrics uses a hydrophobic polyurethane resin solution having isocyanates and/or double bond polar group crosslinking agents. The substrates used for coating are nylon and polyester taffeta.Type: GrantFiled: November 26, 1993Date of Patent: February 7, 1995Assignee: China Textile T&R InstituteInventor: Shin-Chuan Yao
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Patent number: 5362573Abstract: This invention relates to an improved process of surface sizing of paper and paperboard. The process consists of:a) Preparing an aqueous surface sizing compound by combining and mixing an aqueous solution of at least one water soluble or dispersible polymer or interpolymer, a solution or dispersion of auxiliary materials, and an aqueous solution of a metal salt, selected from the group of metals consisting of zirconium, hafnium or titanium, to the polymer solution;b) Adjusting the pH of the aqueous sizing compound from about 5 to about 10.Type: GrantFiled: January 28, 1993Date of Patent: November 8, 1994Inventors: Vernon E. Pandian, Dan van Calcar, Bernard W. Wolff
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Patent number: 5318802Abstract: In a method of treating a raw wood material with a formaldehyde polymer in the presence of sulfur dioxide at a reaction temperature within a reaction vessel to obtain a modified wood material, sulfur dioxide is supplied into the reaction vessel when a gas pressure of the formaldehyde polymer within the reaction vessel is 4.00.times.10.sup.4 Pa or more. In addition, a concentration of the formaldehyde polymer is in a range of 30 to 350 mol/m.sup.3 of formaldehyde monomer, and a molar ratio of the formaldehyde polymer to sulfur dioxide is in a range of 10 to 350. As the formaldehyde polymer, for example, trioxane, tetraoxane, or paraformaldehyde is used. The modified wood material manufactured by the method including the above conditions shows excellent dimensional stability while a discoloration thereof is effectively prevented. Therefore, the modified wood material is particularly fit to use for an interior furniture, musical instrument and a bath tub, etc.Type: GrantFiled: April 20, 1993Date of Patent: June 7, 1994Assignee: Matsushita Electric Works, Ltd.Inventors: Hiroyuki Ishikawa, Arihiro Adachi, Hiroaki Usui
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Patent number: 5294481Abstract: A printing blanket including a base fabric and a surface layer in a laminated structure wherein a surface reforming agent containing a perfluoroalkyl group is applied to the surface layer such that a critical surface tension ranging from 10 to 16 dyn/cm appears on the surface of the surface layer is disclosed. To practically manufacture a printing blanket of the foregoing type, there is also disclosed a method wherein a compressible layer is placed on a base fabric, a surface layer is then placed on the compressible layer thereby to form a laminated structure with the base fabric and the compressible layer, and thereafter, a surface modifier containing a perfluoroalkyl group is applied to the surface layer such that a critical surface tension ranging from 10 to 16 dyne/cm appears on the surface of the surface layer. It is preferable that the surface layer is molded of a compound based on a nitrile butadiene rubber.Type: GrantFiled: December 27, 1991Date of Patent: March 15, 1994Assignee: Fujikura Rubber Ltd.Inventors: Takato Nakamura, Takao Kawata, Tsukasa Fukuma, Yasunobu Kobayashi
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Patent number: RE35278Abstract: Production of electrically conductive composites comprising a dielectric porous substance, e.g., fiberglass fabric, and a pyrrole polymer in the pores of such substance, by treating the porous substance with a liquid pyrrole, and then treating the resulting porous substance with a solution of a strong oxidant in the presence of a non-nucleophilic anion, such as ferric chloride. The pyrrole monomer is oxidized to a pyrrole polymer, which precipitates in the interstices of the porous material. Alternatively, the dielectric porous material can first be treated with a solution of strong oxidant and non-nucleophilic anion followed by treatment with liquid pyrrole, to precipitate an electrically conductive polypyrrole in the pores of the material. The resulting composite of porous material, e.g., fiberglass fabric, containing polypyrrole is electrically conductive while the other properties of such impregnated conductive porous material are substantially unaffected.Type: GrantFiled: April 21, 1992Date of Patent: June 18, 1996Assignee: Rockwell International CorporationInventors: Paul R. Newman, Leslie F. Warren, Jr., Edward F. Witucki