Abstract: Described herein is a method for providing a clean edge at the interface of a portion of a substrate coated with a coating system and an adjacent portion of the substrate which is uncoated. The method includes the step of forming a zone of non-adherence on the substrate portion which is to be uncoated, prior to application of the coating system. The zone of non-adherence is adjacent the interface, so that the coating system will not adhere to the zone of non-adherence, but will adhere to the portion of the substrate which is to be coated with the coating system.

Abstract: Method for manufacturing a workpiece with wear protective coating starts with depositing a first hard material layer selected from the group consisting of TiN, TiCN, TiAlN, TiAlCN or the workpiece. Above the first hard material layer, a second hard material layer selected from the group consisting of TiN, TiCN, TiAlN, TiAlCN is deposited. The second layer is either deposited directly on the first layer or on a transition layer between the first and second layers. The transition layer is made of a material composed of the materials of the first and second layers, and has a thickness of between 5 nm and 500 nm. The first and second hard material layers have the same crystal structure, but different crystallographic privileged orientation with a value I(200)/I(111) between an intensity of the (111) plane, I(111), and an intensity of the (200) plane, I(200), of one of the first and second layers being at most 1 and the value of the other being at least 1. The values are thus different from each other.

Abstract: A thermal barrier coating system and a method for forming the coating system on an article designed for use in a hostile thermal environment. The method is particularly directed to a coating system that includes a plasma-sprayed MCrAlY bond coat on which a thermal-insulating APS ceramic layer is deposited, in which the oxidation resistance of the bond coat and the spallation resistance of the ceramic layer are substantially increased by vapor phase aluminizing the bond coat. The bond coat is deposited to have a surface area ratio of at least 1.4 and a surface roughness of at least 300 &mgr;inch Ra in order to promote the adhesion of the ceramic layer. The bond coat is then overcoat aluminized using a vapor phase process that does not alter the surface area ratio of the bond coat. This process is carried out at relatively low temperatures that promote inward diffusion of aluminum relative to outward diffusion of the bond coat constituents, particularly nickel and other refractory elements.

Abstract: An article includes a substrate and an adhesion layer overlying the substrate. The adhesion layer includes a first phase including particles, and a second phase including braze alloy that bonds the particles to the substrate. The article further includes a ceramic layer overlying the adhesion layer. In one embodiment, the ceramic layer is a thermal barrier coating (TBC), formed of stabilized zirconia (ZrO2).

Abstract: A coating system having a low thermal conductivity, and a method by which the low thermal conductivity of the coating system is maintained through the development of cracks within a thermal-insulating layer of the coating system. The thermal-insulating layer is a mixture of two or more materials with different coefficients of thermal expansion (CTE). The materials of the thermal-insulating layer are selected and combined so that a low thermal conductivity is maintained for the coating system as the result of cracks developing and propagating from interfaces between the materials when the coating system is subjected to heating and cooling cycles.

Abstract: The invention relates to a novel thermal spray process for the deposition of coatings with a graded or layered composition and the coated articles produced thereby. More particularly, the invention relates to feeding mixtures of coating materials to a thermal spray device and continuously or intermittently changing the composition of the deposited coatings by changing the thermal spray operating parameters. The continuous or intermittent change in the composition of the coating material during deposition creates a graded or layered coating structure.

Abstract: Combinatorial high throughput screening is used to rapidly investigate and screen a multiplicity of complex thermal barrier coating candidates. In the screening method, a solution of thermal barrier coating precursors is formed and injected into a plasma jet of an air plasma spray (APS). The plasma jet is directed toward a substrate to deposit a gradient film formed from the precursors onto the substrate. An APS torch system comprises an APS torch, solution precursor vessels connected to the torch through a mixing zone and injector, a substrate oriented with respect to the torch to receive a plasma spray film formed from solution precursors from the vessels and a controller. The controller is connected to the solution precursor vessels and the torch or substrate to control mixing of the solution precursors and to control orientation of the torch or substrate to deposit a gradient film onto the substrate from the plasma spray.

Abstract: A method of treating the surface of a substrate by thermally spraying large size particles, >10 micrometers, of a composition such as a metal hydroxide, carbonate, or nitrate directly onto the substrate whereby a small size particle coating, <5 microns and more particularly <3, is formed on the substrate, enhancing the surface area and porosity properties of the substrate, and substrates with metal oxide surfaces produced thereby.

Abstract: The present invention provides a refractory and heat insulating material excellent in heat resistance, slag resistance, molten steel resistance, wear resistance, and mechanical impact resistance, and relates to a highly durable heat insulating material characterized by having a thermally sprayed film of refractory ceramic on a surface of a formed body of an inorganic refractory fiber which surface is covered with a cloth material or was covered with the cloth material until it burned out by flame fusion coating of refractory ceramic powder material during the fabricating process of the heat insulating material, with an application film of a surface hardening material acting as an intermediary layer between the thermally sprayed film and the fiber body.

Abstract: The invention relates to an apparatus and process for solid-state deposition and consolidation of powder particles entrained in a subsonic or sonic gas jet onto the surface of an object. Under high velocity impact and thermal plastic deformation, the powder particles adhesively bond to the substrate and cohesively bond together to form consolidated materials with metallurgical bonds. The powder particles and optionally the surface of the object are heated to a temperature that reduces yield strength and permits plastic deformation at low flow stress levels during high velocity impact, but which is not so high as to melt the powder particles.

Abstract: The wet film thickness during spraying of the coating composition onto the substrate is preferably adjusted such that it is greater by a factor of at least 8 than the target dry film thickness.

Abstract: A roll for use in the manufacture of paper and board, a press roll, in particular a center roll in a press, a backup roll for an extended-nip press roll, a hot press roll, or equivalent, which is in direct contact with a wet paper web, or a calender roll, a method for manufacturing the same and a coating composition therefor including an adhesion layer arranged on the frame part of the roll and a ceramic layer arranged on the adhesion layer. The ceramic layer has a thickness of from about 100 &mgr;m to about 2000 &mgr;m and includes from about 50% to about 95% by weight of Cr2O3 and from about 3% to about 50% by weight of TiO2, or from about 50% to about 80% by weight of Al2O3 and from about 20% to about 50% by weight of ZrO2, or exclusively Al2TiO5. The outer face of the ceramic layer is finished until the roughness Ra is from about 0.2 &mgr;m to about 2.0 &mgr;m and/or the porosity of the outer face of the roll is from about 1% to about 20%.

Abstract: A sputtering target comprising a substrate and a target material formed on the substrate, wherein the target material comprises a metal oxide of the chemical formula MOx as the main component, wherein MOx is a metal oxide which is deficient in oxygen as compared with the stoichiometric composition, and M is at least one metal selected from the group consisting of Ti, Nb, Ta, Mo, W, Zr and Hf, a process for its production, and a method for forming a film having a high refractive index.

Abstract: A process for applying a vertically cracked ceramic thermal barrier coating to a machine component includes a.) applying a plurality of layers of the ceramic thermal barrier coating on the component, utilizing a nozzle at a first distance from the component; b.) applying an additional sacrificial outer layer of the ceramic thermal barrier coating of the same chemical composition as the plurality of layers on the component, with the nozzle at a second distance from the component, greater than the first distance; and c) removing at least some of the outer layers to achieve thickness and surface roughness specifications.

Abstract: A method for making a sensor is disclosed comprising using a sensing electrode having a first and second side. Using a reference electrode having a first and second side and a second electrical lead in electrical communication with the reference electrode. Disposing an electrolyte between the first side of sensing electrode and the first side of reference electrode. Disposing a first side of a protective layer adjacent to the side of sensing electrode. Mixing a metal oxide, a fugitive material, and a solvent to form a mixture. Applying the mixture to a second side of the protective layer and calcining the sensor to form the protective coating on the protective layer second side.

Abstract: A primary layer of an MCrAlY-type material is first applied to a metal-based substrate by a vacuum plasma spray (VPS) technique, or by HVOF. A secondary layer is then also applied by VPS or HVOF. It is formed of the following alloy (in atom percent): 0 to about 25 cobalt; about 7 to 25 chromium; about 18 to about 55 aluminum; 0 to about 1 yttrium; and 0 to about 2 silicon, with the balance comprising nickel. The applied layers are then heat-treated. Related articles are also described.

Abstract: A process for applying a thermal barrier coating to a machine component including:

Abstract: A thermal barrier coating for superalloy turbine engine vanes and blades that are exposed to high temperature gas is disclosed. The coating includes an aluminide or MCrAIY layer, an alumina layer, and a ceramic top layer. The ceramic layer has a columnar grain microstructure. A bond inhibitor is disposed in the gaps between the columnar grains. This inhibitor is either unstabilized zirconia, unstabilized hafnia, or a mixture thereof.

Abstract: A device (10) comprising a substrate (22) having a deposited ceramic thermal barrier coating characterized by a microstructure having gaps (28) where the thermal barrier coating comprises a first thermal barrier layer (40), and a second thermal barrier layer (30) with a pyrochlore crystal structure having a chemical formula of An+2−xBm+2+xO7−y, where A is selected from the group of elements consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and mixtures thereof, where B is selected from the group of elements consisting of Zr, Hf, Ti and mixtures thereof, where n and m are the valence of A and B respectively, and for −0.5≦x≦0.

Abstract: A thermal barrier coating system for a superalloy substrate is disclosed. The superalloy is preferably of the type that is capable of forming an adherent alumina layer. A bond coat is applied to a local area of the substrate, so that a portion of the substrate remains exposed. The localized area is defined to be the area(s) at which a TBC typically fails first, e.g., the leading and trailing edges of an airfoil, or other area. An alumina layer is formed on the remaining portion of the substrate, and also on the bond coat. A ceramic layer is then applied on the alumina layer. Even if the ceramic material is removed, the localized bond coat remains, and reduces the rate at which the underlying substrate oxidizes. A coated article is also disclosed, as is a system that utilizes a conventional superalloy and aluminide coating with the localized bond coat.

Abstract: A method for improving the cooling effectiveness of a gaseous coolant stream which flows through at least one passage hole in a substrate to an exit site on a high-temperature surface of the substrate is disclosed. The method comprises disrupting the coolant stream at the exit site, so that the coolant stream contacts a greater area of the high-temperature surface. In some embodiments, the exit site is a crater. Moreover, the exit site may be formed within a coating applied over the substrate, e.g., a thermal barrier coating applied over a superalloy substrate. Related articles are also disclosed.

Abstract: A composite emitter (100) for a thermophotovoltaic cell and other applications, and a method of forming the composite emitter. The composite emitter includes a substrate (102) and a selective emitter layer (104) composed of at least one substantially pure ceramic oxide selective emitter material applied to the substrate using a thermal spraying method. The substrate is preferably made of a durable material such as a silicon-based material or a refractory metal oxide. In one embodiment, the selective emitter layer may be composed of two or more selective emitter materials. In another embodiment, the composite emitter may further include a reflective metal layer (106). The method includes providing a substrate and plasma spraying one or more selective emitter materials onto the substrate to a thickness of between about 10 microns and about 400 microns to form the selective emitter layer.

Abstract: A multi-layer thermal barrier coating for a superalloy article includes a metallic matrix coating containing particles, a MCrAlY alloy bond coating on the metallic matrix coating, a thin oxide layer on the MCrAlY alloy bond coating and a columnar grain ceramic thermal barrier coating. The metallic matrix coating includes a 80 wt % nickel-20 wt % chromium alloy. The particles include metallic compounds such as carbides, oxides, borides and nitrides, which react with harmful transition metal elements such as titanium, tantalum and hafnium, in the superalloy substrate. One suitable compound is chromium carbide because the hafnium transition metal elements will take part in an exchange reaction with the chromium in the chromium carbide to form a stable carbide of the harmful transition metal element. This reduces the amount of harmful elements in the superalloy reaching the oxide layer and increases the service life of the thermal barrier coating.

Abstract: A method for providing a protective coating on a metal-based substrate is disclosed. The method involves the application of an aluminum-rich mixture to the substrate to form a discontinuous layer of aluminum-rich particles, followed by the application of a second coating over the discontinuous layer of aluminum-rich particles. Aluminum diffuses from the aluminum-rich layer into the substrate, and into any bond coat layer which is subsequently applied. Related articles are also described.

Abstract: A method for forming a thermal barrier coating system on a turbine engine component includes forming a bondcoat on the turbine engine component and depositing a thermal barrier coating so as to overlie the bondcoat. The bondcoat is formed by thermally co-spraying first and second distinct alloy powders on the turbine engine component forming an oxidation-resistant region, and thermally spraying a third alloy powder on the oxidation-resistant region to form a bonding region.

Abstract: Multi-layer corrosion resistant polymer composite coatings are described wherein a first coating layer is applied by high velocity high temperature spray, thermal spray, plasma spray, fluidized bed, hot melt or electrostatic spray onto an unprepared, particle embedded or alternatively prepared substrate, and the outer surface of the still warm first layer is roughened by embedding particles therein or the outer surface is roughened mechanically, and a second coating layer is applied thereover. Filler powder may be added to one or both of the layers to substantially match the thermal expansion coefficients of the two layers.

Abstract: A sputtering target comprising a substrate and a target material formed on the substrate, wherein the target material comprises a metal oxide of the chemical formula MOx as the main component, wherein MOx is a metal oxide which is deficient in oxygen as compared with the stoichiometric composition, and M is at least one metal selected from the group consisting of Ti, Nb, Ta, Mo, W, Zr and Hf, a process for its production, and a method for forming a film having a high refractive index.

Abstract: A method of coating an inner surface of a weapon barrel includes the following steps: introducing a plasma burner into the weapon barrel; producing a plasma flame by the plasma burner; directing the plasma flame against the inner barrel surface to cause impingement thereon; introducing a coating material in powder, wire or ribbon form into the plasma flame for melting the coating material to form a molten liquid and for depositing the molten liquid by the plasma flame on the inner barrel surface; and moving the plasma burner inside the weapon barrel axially thereof and relative thereto while performing the depositing step for obtaining a surface coating on the inner barrel surface.

Abstract: A member covered with a self-fluxing alloy sprayed coating is produced by previously forming a porous ceramic sprayed coating on a surface of a self-fluxing alloy sprayed coating prior to a refusing treatment of the coating formed on a substrate, heating the sprayed coating in an inert gas atmosphere controlled to 1˜300 hPa or by a high frequency induction heating system and thereafter removing the ceramic sprayed coating to expose the self-fluxing alloy sprayed coating. This member is uniform in the thickness, less in the retention of pores or oxide impurities and has a strong coating property.

Abstract: Disclosed is a method of forming a multilayer opaque coating on an integrated circuit or multichip module. First, an opaque coating composition is heated to a molten state and the molten opaque coating composition is applied so as to form an opaque coating that overlies active circuitry on the surface of the integrated circuit or multichip module, to prevent optical and radiation based inspection and reverse engineering of the active circuitry. Further coatings are applied over the opaque coating to shield the active circuitry of the integrated circuit or multichip module from the adverse affects of electromagnetic interference and/or high energy radiation.

Abstract: In order to provide a heat pipe for transporting heat from an evaporation area to a condensation area, comprising a housing with housing walls, a capillary structure arranged in the housing and thermally coupled to the respective, corresponding housing wall in the evaporation area as well as in the condensation area, a vapor channel arranged in the housing and leading from the evaporation area to the condensation area as well as a heat transport medium, as well to make available a process for the production of such a heat pipe it is suggested that the capillary structure be an open-pored capillary layer produced by way of thermal plasma spraying of powder particles.

Abstract: The invention provides an improved near net-shape VPS formed multilayered combustion system component having an inner surface consisting of a smooth protective thermal barrier coating, and an outer layer of superalloy capable of withstanding temperatures in excess of 700° C. The invention also includes the method of forming such components by first vacuum plasma spraying a suitable mold with a ceramic top coat, followed by a bond coat and followed by a thick structural layer of superalloy. The mold is then separated from the multilayered structure which results in the desired near net-shape component. Combustor liners and transition ducts of gas turbine engines can be advantageously formed in this manner.

Abstract: A process for depositing a mullite coating on a silicon-based material, such as those used to form articles exposed to high temperatures and including the hostile thermal environment of a gas turbine engine. The process is generally to thermally spray a mullite powder to form a mullite layer on a substrate, in which the thermal spraying process is performed so that the mullite powder absorbs a sufficient low level of energy from the thermal source to prevent evaporation of silica from the mullite powder. Processing includes deposition parameter adjustments or annealing to maintain or reestablish phase equilibrium in the mullite layer, so that through-thickness cracks in the mullite layer are avoided.

Abstract: Embodiments include a method for depositing material onto a workpiece in a sputtering chamber. The method includes sputtering a target and a coil in said sputtering chamber. The coil may have a preformed multilayer structure formed outside of the sputtering chamber. The outer layer of the coil may act as a secondary source of deposition material. The multilayer structure may be formed with an inner region or a base metal and an outer layer of a sputtering metal. The outer layer may be formed using a process such as plasma spraying, arc spraying, flame spraying, ion plating, chemical vapor deposition and electroplating.

Abstract: A thick film resistive element heater is shown with an aluminum substrate having a ceramic oxide dielectric insulator there between.

Abstract: An article is described, which includes a metal-based substrate, such as a superalloy; a dense, primary bond layer; and a spongy secondary bond layer. A thermal barrier coating is applied over the secondary bond layer. The spongy layer has a microstructure which includes an open network of interconnected pores. A process is also described. It includes the step of applying a spongy, metallic bond layer over the substrate, followed by the application of a thermal barrier coating. A dense, primary bond layer may optionally be applied before the application of the spongy layer.

Abstract: An article is formed of a gas turbine component having a substrate, an internal passage through the substrate defining an internal surface of the substrate, and an internal protective layer overlying the internal surface of the substrate. The internal protective layer has a composition of aluminum, plus, in weight percent, on average from about 0.1 to about 5.0 percent of a modifying element selected from the group consisting of hafnium, yttrium, zirconium, chromium, and silicon, and combinations thereof, and elements found in the substrate.

Abstract: A thermal barrier coating system for a superalloy substrate is disclosed. The superalloy is preferably of the type that is capable of forming an adherent alumina layer. A bond coat is applied to a local area of the substrate, so that a portion of the substrate remains exposed. The localized area is defined to be the area(s) at which a TBC typically fails first, e.g., the leading and trailing edges of an airfoil, or other area. An alumina layer is formed on the remaining portion of the substrate, and also on the bond coat. A ceramic layer is then applied on the alumina layer. Even if the ceramic material is removed, the localized bond coat remains, and reduces the rate at which the underlying substrate oxidizes. A coated article is also disclosed, as is a system that utilizes a conventional superalloy and aluminide coating with the localized bond coat.

Abstract: A device (10) comprising a substrate (22) having a deposited ceramic thermal barrier coating layer (20) characterized by a microstructure having gaps (28) where the thermal barrier coating (20) consists essentially of a pyrochlore crystal structure having a chemical formula consisting essentially of An+2−xBm+2+xO7−y, where A is selected from the group of elements selected from La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and mixtures thereof; where B is selected from the group of elements selected from Zr, Hf, Ti and mixtures thereof; n and m are the valence of A and B respectively, and for −0.5≦x≦0.

Abstract: A thermal spraying method involves the creation of a coating comprising titanium wire in the presence of nitrogen. The apparatus of the invention comprises a nozzle which has a cylindrical throat, with feedstock guides which guide the feedstock wires to a point of intersection in the throat. A current is passed through the wires to cause an arc in the throat, and a nitrogen rich gas under pressure is forced through the throat, generating a spray of molten particles which is used to coat a substrate. In a variation of the method, one of the feedstock wires comprises a binder metal, which produces a coating having enhanced toughness.

Abstract: A method for applying a barrier layer which comprises a barium-strontium aluminosilicate to a silicon containing substrate which inhibits the formation of cracks.

Abstract: A method of providing a roughened bond coat, for example in a thermal barrier coating system, comprises providing an oxidation-resistant plasma-sprayed layer onto a substrate and disposing a slurry overlayer on the oxidation-resistant plasma-sprayed layer. These steps form a roughened bond coat possessing an uneven, undulated, and irregular surface. A roughened bond coat in a thermal barrier coating system reduces de-bonding of the bond coat and a thermal barrier coating layer, which is desirable to maintain the insulation features of the thermal barrier coating system.

Abstract: A method of preparing a planographic printing member is disclosed. In one embodiment, the method comprises forming a hydrophilic layer by thermally spraying a hydrophilic particulate material onto an ablatable layer. Typical hydrophilic materials are SiO2, Al2O3, Cr2O3, TiO2 and ZrO2. Spraying a plasma containing the hydrophilic material in an inert gas atmosphere is preferred method for forming the hydrophilic layer.

Abstract: A method of repairing a damaged area of a thermal barrier coating on a component which is subjected to a hostile thermal environment, which comprises cleaning the damaged area, applying a partially stabilized zirconium sol-gel to the area, and pyrolizing the sol-gel to form a TBC repair layer.

Abstract: A protective coat formed by thermal spraying, and having an outstanding durability against corrosion by a molten light alloy. A thermal spraying composite material used to form such a coat contains from about 30 to about 70% by weight of molybdenum boride, from about 20 to about 40% by weight of nickel or cobalt, from about 5 to about 20% by weight of chromium, and from about 5 to about 10% by weight of at least one metal boride selected from the borides of Cr, W, Zr, Ni and Nb.

Abstract: The invention relates to a method for applying a coating by means of plasma spraying to a substrate, in which method the beam of a laser is additionally used, it being possible to coat a very wide variety of substrates in order, in particular, to improve the properties on the substrate surface. Moreover, the method according to the invention is to achieve a high coating rate and, in addition to advantageous adhesion and density of the layer, also to influence in a controlled manner the layer structure which is being formed.

Abstract: An article having a spallation resistant TBC comprises a metal substrate, such as a high temperature superalloy, and a TBC, such as a coating of yttria stabilized zirconia. The TBC comprises a plurality of plasma-sprayed layers. The TBC has a coherent, continuous columnar grain microstructure, wherein at least one layer has a plurality of continuous columnar grains which have been extended by directional solidification into an adjacent layer. In a preferred embodiment, the coherent, continuous columnar microstructure comprises substantially all of the volume of TBC. A coherent, continuous columnar grain microstructure is also taught wherein at least some of the plurality of coherent, continuous columnar grains which comprise a TBC extend through essentially the entire thickness of the coating.

Abstract: A press roll for a paper or board machine, a method for manufacturing a roll for a paper or board machine and a coating composition for a roll which enable the roll to endure difficult corrosion conditions. An adhesion/corrosion-protection layer having a thickness of from about 150 &mgr;m to about 300 &mgr;m is applied onto the frame part of the roll by a high-velocity flame spraying technique. The adhesion/corrosion-protection layer contains a nickel-chromium alloy. A tight-ceramic layer having a thickness from about 50 &mgr;m to about 150 &mgr;m is applied onto the adhesion/corrosion-protection layer by a high-velocity flame spraying technique and includes from about 50% to about 100% of Al2O3 and optionally includes up to about 50% of TiO2 and/or any amount of Al2TiO5. A porous ceramic layer is applied onto the tight ceramic layer. The tight-ceramic layer may include only Al2TiO5 instead of Al2O3, with or without TiO2.

Abstract: A coating of whisker shaped beta silicon nitride grains are formed upon a silicon nitride substrate by sintering over a period of several hours, and the resulting product has a porous reaction bond coating strongly adhered to the silicon nitride substrate.

Abstract: A process for depositing a mullite coating on a silicon-based material, such as those used to form articles exposed to high temperatures and including the hostile thermal environment of a gas turbine engine. The process is generally to thermally spray a mullite powder to form a mullite layer on a substrate, in which the thermal spraying process is performed so that the mullite powder absorbs a sufficient low level of energy from the thermal source to prevent evaporation of silica from the mullite powder. Processing includes deposition parameter adjustments or annealing to maintain or reestablish phase equilibrium in the mullite layer, so that through-thickness cracks in the mullite layer are avoided.