Fiber Embedded In A Ceramic, Glass, Or Carbon Matrix Patents (Class 428/293.4)
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Patent number: 6815037Abstract: This invention provides a carrier member made of a UV resistant fiber-reinforced composite material where a UV resistant coating material is applied on the surface of the fiber-reinforced composite material and a process for producing thereof. A preferable fiber-reinforced composite material is a fiber-reinforced plastic or carbon fiber-reinforced carbon composite material. A UV resistant coating material is one or more selected from the group consisting of ceramics, cermets, metals and alloys. The carrier member is produced by coating the surface of the fiber-reinforced composite material with a UV resistant coating material by spraying. This carrier member is advantageous in that it can exhibit properties inherent to a fiber-reinforced composite material such as a light weight, higher rigidity and higher heat resistance and that it little contaminates a precision instrument material when being used in cleansing with UV.Type: GrantFiled: September 19, 2001Date of Patent: November 9, 2004Assignee: Nippon Mitsubishi Oil CorporationInventors: Akio Ooshima, Takashi Kobayashi, Kenichi Aoyagi, Daisuke Uchida
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Publication number: 20040211354Abstract: A one-piece bowl of thermostructural composite material comprising fiber reinforcement densified by a matrix. The bowl is made by supplying deformable fiber in plies that are whole, being free from slots or cutouts, superposing said plies on a former of shape corresponding to the bowl to be made, deforming the plies, and bonding the superposed plies to one another by means of fibers extending transversely relative to the plies, e.g. by needling so as to obtain a bowl preform which is then densified. The bowl can be used as a support for a crucible in an installation for producing monocrystalline silicon.Type: ApplicationFiled: May 24, 2004Publication date: October 28, 2004Inventors: Jean-Michel Guirman, Dominique Coupe, Jean-Michel Georges
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Patent number: 6805946Abstract: Fibrous monolith processing techniques to fabricate multifunctional structures capable of performing more than one discrete function such as structures capable of bearing structural loads and mechanical stresses in service and also capable of performing at least one additional non-structural function.Type: GrantFiled: December 4, 2001Date of Patent: October 19, 2004Assignee: Advanced Ceramics Research, Inc.Inventors: Anthony C. Mulligan, John Halloran, Dragan Popovich, Mark J. Rigali, Manish P. Sutaria, K. Ranji Vaidyanathan, Michael L. Fulcher, Kenneth L. Knittel
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Publication number: 20040204533Abstract: Process for a fiber-reinforced ceramic material whose reinforcing fibers are present in the form of at least one of woven fabrics, short fibers and long fibers, wherein the mass ratio of the fibers in the form of woven fabrics, short fibers and long fibers is 0-35:25-80:0-45 and at least a part of the reinforcing fibers has at least one protective layer of carbon produced by pyrolysis of resins or pitches, boron compounds or phosphorus compounds or combinations thereof which have been deposited thereon, a process for producing it and its use as material for brake liningsType: ApplicationFiled: March 12, 2004Publication date: October 14, 2004Inventors: Ronald Huner, Moritz Bauer, Peter Winkelmann
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Patent number: 6803108Abstract: Carbon fiber bundles may be dispersed into substantially single mono-filaments in pitch by stirring a mixture of fibers and pitch at a temperature at which the pitch has a viscosity of about 0.1 to about 5 poise. The resulting fiber pitch binder contains about 0.5 to about 10.0 wt. % carbon fibers substantially dispersed as substantially single mono-filaments which are randomly oriented which may then be used directly as a binder for producing carbon bodies, for example, graphite electrodes, pinstock or specialty graphite articles. This unique binder using an economical amount of carbon fibers has the capacity to increase the strength and reduce the coefficients of thermal expansion of the resulting carbon products in more than one direction due to the random orientation of the carbon fibers.Type: GrantFiled: February 11, 2002Date of Patent: October 12, 2004Assignee: UCAR Carbon Company Inc.Inventors: Irwin C. Lewis, Terrence A. Pirro
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Patent number: 6773793Abstract: An electrical insulating sheet is disclosed. The sheet includes 50-99% D glass flakes and 1-50% additives. Optional ingredients include a bonding agent, porosity control agent, and reinforcing agent(s) to enhance tensile strength.Type: GrantFiled: May 24, 2002Date of Patent: August 10, 2004Assignee: Electrolock, Inc.Inventors: Ronald T. Flynn, Darryl A. Payne, Ralph E. Brandon
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Patent number: 6770584Abstract: A hybrid insulation material comprises of porous ceramic substrate material impregnated with nanoporous material and method of making the same is the topic of this invention. The porous substrate material has bulk density ranging from 6 to 20 lb/ft3 and is composed of about 60 to 80 wt % silica (SiO2) 20 to 40 wt % alumina (Al2O3) fibers, and with about 0.1 to 1.0 wt % boron-containing constituent as the sintering agent. The nanoporous material has density ranging from 1.0 to 10 lb/ft3 and is either fully or partially impregnated into the substrate to block the pores, resulting in substantial reduction in conduction via radiation and convention. The nanoporous material used to impregnate the fiber substrate is preferably formed from a precursor of alkoxysilane, alcohol, water, and an acid or base catalyst for silica aerogels, and from a precursor of aluminum alkoxide, alcohol, water, and an acid or base catalyst for alumina aerogels.Type: GrantFiled: August 16, 2002Date of Patent: August 3, 2004Assignee: The Boeing CompanyInventors: Andrea O. Barney, Vann Heng, Kris Shigeko Oka, Maryann Santos, Alfred A. Zinn, Michael Droege
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Patent number: 6761967Abstract: The invention relates to an external reinforcement for beams, columns, plates and the like, substantially consisting in the combination of fibers and a resin and whereby the majority of the fibers is situated in the longitudinal direction of the reinforcement, characterized in that at least well-defined portions of the external reinforcement are provided with an additional reinforcement formed by fibers which are arranged according to at least one direction differing from the longitudinal direction of the reinforcement.Type: GrantFiled: July 15, 2002Date of Patent: July 13, 2004Assignee: Immo Emergo, Naamloze VennootschapInventor: Dirk Christiaan Jozef Isidoor De Neef
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Publication number: 20040131835Abstract: A heat dissipating structure includes a composite having a thermal expansion coefficient between 30° C. and 250 ° C. in a range from 2 to 13.10−6 K−1, a volume mass below 3000 kg·m−3, and a conductivity equal to or greater than 113 W·m−1·K−1. The composite is formed by a matrix which is made of a metal, polymer, or resin, in combination with a reinforcement component. The reinforcement component contains microfibers at a volume proportion in a range from 5 to 90% and nanofibers at a volume proportion from 1 to 60%, with the composite obtained through infiltration of the reinforcement component by the metal in liquid state or the polymer and resin in liquid or uncured state. Applied onto the composite is a surface layer having entirely or at least partially a metallic character.Type: ApplicationFiled: November 12, 2003Publication date: July 8, 2004Applicant: ELECTROVAC, FABRIKATION ELEKTROTECHNISCHER SPEZIALARTIKEL GESELLSCHAFT M.B.H.Inventors: Theodore Nicolas Schmitt, Klaus Dieter Mauthner, Ernst Hammel
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Patent number: 6759117Abstract: A multilayer ceramic composite is described which contains at least one supporting zone having oxidation-sensitive reinforcing fibers as well as a matrix. The matrix optionally contains oxidation-sensitive components. The composite further contains at least one surface layer, as well as at least one additional protective layer disposed between the supporting zone and surface layer, and whose matrix is composed substantially of at least one component of the matrix of the supporting zone or cover layer. The protective layer further contains additives that form self-healing layers.Type: GrantFiled: July 8, 2002Date of Patent: July 6, 2004Assignee: SGL Carbon AGInventors: Moritz Bauer, Martin Christ, Udo Gruber, Michael Heine, Andreas Kienzle, Jens Rosenlöcher, Rainer Zimmermann-Chopin
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Patent number: 6758386Abstract: A method of joining a ceramic matrix composite rocket nozzle to a metal manifold is provided, wherein a silicon nitride insert is disposed inside the ceramic matrix composite rocket nozzle and the metal manifold to provide a joint therebetween. The silicon nitride insert is preferably co-processed with the ceramic matrix composite rocket nozzle such that the ceramic matrix provides a bond between the rocket nozzle and the insert. The metal manifold is then secured to the silicon nitride insert, preferably using brazing, to form a joint assembly.Type: GrantFiled: September 18, 2001Date of Patent: July 6, 2004Assignee: The Boeing CompanyInventors: David B. Marshall, Min Z Berbon, John R. Porter
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Patent number: 6756112Abstract: A high-temperature fiber-reinforced carbon-carbon composite material of essentially uniform density, is fabricated by the following sequence of steps: (a) selecting a fiber/matrix material combination; (b) providing a fiber preform of desired shape and fiber placement; (c) selecting at least one low-viscosity pre-carbon monomer material that wets the surfaces of the fiber preform; (d) impregnating the fiber preform with the monomer; (e) polymerizing the monomer material in-situ in a single phase process into a pre-carbon polymer of desired molecular weight; (f) pryolyzing the pre-carbon polymer to form a carbon matrix material; and (g) repeating steps (d)-(f) to further densify the preform.Type: GrantFiled: September 13, 2001Date of Patent: June 29, 2004Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Phillip G. Wapner, Wesley P. Hoffman, Steven P. Jones
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Patent number: 6749937Abstract: Carbon-silicon carbide brake preforms are manufactured by carbonizing a blend of carbon (e.g., polyacrylonitrile) fibers and thermosetting pitch resin, optionally along with a lubricant such as graphite, to provide an intermediate product having open porosity and subsequently filling the pores of the intermediate product with silicon by a melt infiltration process. Molded articles that consist principally of carbon, that have relatively high strength and resistance to decomposition by frictional heat, and that are suitable for melt infiltration with silicon, are produced by, e.g.Type: GrantFiled: March 19, 2002Date of Patent: June 15, 2004Assignee: Honeywell International Inc.Inventor: Paul E. Gray
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Patent number: 6734237Abstract: Provided is a fiberglass binder composition which comprises a polycarboxy polymer, polyol and an imidazoline. The binder also preferably includes a catalyst which is an alkali metal salt of a phosphorus-containing organic acid. The resultant binder provides minimal processing difficulties and a product which exhibits minimal water absorption.Type: GrantFiled: October 28, 2002Date of Patent: May 11, 2004Assignee: Johns Manville International,, Inc.Inventors: Thomas J. Taylor, Philip Francis Miele, Lance Wang
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Publication number: 20040076810Abstract: A composite high temperature insulator (A) includes a planar layer (10) having anisotropic thermal conductivity properties. A second planar layer (12) is formed from a rigid insulation material, such as a carbonized mixture of carbon fibers and a binder. The second layer is coextensive with the first layer and is preferably bonded thereto by a carbonaceous cement (44). When used to insulate a heat source, such as a furnace (50), convective heat is directed back to the source by the reflective surface (16) of the inner, anisotropic layer (10). Heat which enters the anisotropic layer is dissipated evenly through the plane of the layer along a plurality of heat paths defined by a plurality of layers (14) of flexible graphite. Accordingly, heat which reaches the outer, second layer (12) results in fewer hot spots than occur with a conventional rigid insulation material, thereby reducing the total amount of insulation material required to achieve a desired level of thermal insulation.Type: ApplicationFiled: October 17, 2002Publication date: April 22, 2004Applicant: UCAR Carbon Company Inc.Inventors: David P. Blain, Robert E. Smith
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Patent number: 6716782Abstract: A porous ceramic fiber insulating material and method of making a material having a combination of silica (SiO2) and alumina (Al2O3) fibers, and boron-containing powders is the topic of the new invention. The insulative material is composed of about 60 wt % to about 80 wt % silica fibers, about 20 wt % to about 40 wt % alumina fibers, and about 0.1 wt % to about 1.0 wt % boron-containing powders. A specific boron-containing powder used for this invention is boron carbide powder which provide boron-containing by-products, which aid in fusion and sintering of the silica and alumina fibers. The material is produced by forming an aqueous slurry, blending and chopping the fibers via a shear mixer, orienting the fibers in the in-plane direction, draining water from the fibers, pressing the fibers into a billet, heating the fibers to remove residual water, and firing the billet to fuse the fibers of the material. After sintering, bulk density of the new insulation material ranges from 6 to 20 lb/ft3.Type: GrantFiled: August 16, 2002Date of Patent: April 6, 2004Assignee: The Boeing CompanyInventors: Vann Heng, Karrie Ann Hinkle, Mary Ann Santos
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Patent number: 6713162Abstract: Using plural layers selected from among composite resin substrates having a fully high or low dielectric constant, composite resin substrates having a fully high magnetic permeability, and composite resin substrate layers having a fully high Q value, the invention provides a multilayer electronic part of small size having high performance and improved overall electrical characteristics. The multilayer electronic part includes constituent layers of at least two types formed of composite materials and a conductor layer formed on at least one composite material layer, wherein the conductor layer constructs a predetermined electric circuit.Type: GrantFiled: December 28, 2000Date of Patent: March 30, 2004Assignee: TDK CorporationInventors: Minoru Takaya, Toshikazu Endo
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Patent number: 6709736Abstract: Protection products and armored products made of a fiber-reinforced composite material with a ceramic matrix, include a protection element for partial or complete absorption of at least one impact-like load focussed at a point. The protection element has a body having at least one dimension at least equal to 3 cm, in a direction perpendicular to a load to be absorbed. The body includes a fiber-reinforced composite material having a ceramic matrix with at least 10% by weight of silicon carbide and having reinforcing fibers. At least 5% by weight of the reinforcing fibers are carbon fibers and/or graphite fibers.Type: GrantFiled: January 30, 2003Date of Patent: March 23, 2004Assignee: SGL Carbon AGInventors: Udo Gruber, Michael Heine, Andreas Kienzle, Reinhard Nixdorf
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Publication number: 20040038027Abstract: The present invention provides a synthetic fiber and methods for its use and formation. The present invention may comprise a fiber component that is a twisted bundle comprised of multiple strands of a nonfibrillating monofilament, the degree of twist being greater than about 0.9 turns/inch (about 0.36 turns/cm). The present invention may further comprise another fiber component, discrete from the twisted fiber component, that is fibrillated.Type: ApplicationFiled: August 1, 2003Publication date: February 26, 2004Inventors: Jeffrey B. Lovett, Daniel T. Biddle, H. Charles Pitts,
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Publication number: 20040038029Abstract: The invented insulation is a ceramic fiber insulation wherein the ceramic fibers are treated with a coating which contains transition metal oxides. The invented process for coating the insulation is a process of applying the transition metal oxide coating to the fibers of the insulation after the fibers have been formed into a tile or other porous body. The coating of transition metal oxide lowers the transmittance of radiation through the insulation thereby lowering the temperature of the backface of the insulation and better protecting the structure that underlies the insulation.Type: ApplicationFiled: August 16, 2002Publication date: February 26, 2004Applicant: The Boeing CompanyInventors: Alfred A. Zinn, Ryan Jeffrey Tarkanian
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Patent number: 6696144Abstract: The present invention is a low density hybrid airfoil comprising a temperature resistant exterior layer and a tough, high impact resistant interior layer. Specifically, the airfoil comprises a monolithic ceramic exterior layer and a fiber reinforced ceramic matrix composite interior layer. Both the monolithic ceramic and fiber reinforced ceramic matrix composite are low density materials. Additionally, the monolithic ceramic is a high temperature resistant material, and the fiber reinforced ceramic matrix composite is a relatively high impact resistant structure. Encapsulating the airfoil with a temperature resistant exterior layer protects the airfoil in a high temperature environment, and supporting the airfoil with a high impact resistant, fiber reinforced ceramic matrix composite improves the overall impact resistance of the airfoil thereby resulting in a tough, high temperature resistant, low density airfoil.Type: GrantFiled: April 24, 2002Date of Patent: February 24, 2004Assignee: United Technologies CorporationInventors: John E. Holowczak, Karl M. Prewo, Jayant S. Sabnis, William K. Tredway
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Publication number: 20040023015Abstract: A thermal insulation material comprises an intimate mixture of:Type: ApplicationFiled: June 6, 2003Publication date: February 5, 2004Inventor: Mark Bradshaw
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Patent number: 6670026Abstract: A method for producing apertures in hot section components of gas turbine engines made from ceramic matrix composites that have at least one oxidizable component. The method involves forming the apertures using a laser beam controlled by parameters that ablate the ceramic matrix composite in the path of the beam, while simultaneously heating the matrix material, SiC or SiN, to a sufficient temperature to oxidize it to form a silica. Sufficient heat is supplied by the beam to melt the silica to cause it to flow. The melted silica is quickly solidified as recast silica along the walls of the newly created aperture before it has an opportunity to flow and form undesirable geometries. The wall of the aperture is formed of recast silica that is a smooth surface and that forms an oxidation barrier to inhibit any further oxidation of the underlying composite as it is exposed to the high temperatures and oxidative, corrosive atmosphere of an operating gas turbine.Type: GrantFiled: June 20, 2002Date of Patent: December 30, 2003Assignee: General Electric CompanyInventors: James Dale Steibel, Wayne Garcia Edmondson, Wilbur Douglas Scheidt
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Patent number: 6670021Abstract: 12A high temperature gas turbine component includes an inner core made of a monolithic ceramic material embedded within an outer CMC shell. The inner core may be formed with a through hole, blind hole, wear pads and the like. A method of making the bushing includes the steps of a) forming an inner core of silicon nitride or silicon carbide; and b) applying a ceramic matrix composite material over substantially all of the inner core.Type: GrantFiled: November 14, 2001Date of Patent: December 30, 2003Assignee: General Electric CompanyInventors: Mark Stewart Schroder, Paul Stephen DiMascio, Randall Richard Good
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Patent number: 6666310Abstract: The invention relates to a fiber-reinforced ceramic body and a method for producing same. The ceramic body consists of a core and a boundary layer (93, 94) which is joined to the core and has at least one outer surface (96, 97) which can preferably be subjected to tribological stress. The core consists of one or more layers (92) of which at least one is reinforced with long fibers. The boundary layer (93, 94) is reinforced with short fibers. The fibers are preferably reaction-bonded in a matrix by melt infiltration and are made of high-temperature resistant fibers with covalent bonds on the basis of silicon, carbon, boron or nitrogen.Type: GrantFiled: November 28, 2001Date of Patent: December 23, 2003Assignee: Universitat Stuttgart, Institut fur Fertigungstechnologie Kermaischer BautelleInventors: Karl Berreth, Marcus Speicher, Rainer Gadow
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Publication number: 20030215625Abstract: A protective coating for a carbon-containing component comprises a material selected from the group consisting of non-stoichiometric silicon and carbon; non-stoichiometric silicon and oxygen; non-stoichiometric silicon and nitrogen; compounds of silicon, oxygen, and carbon; compounds of silicon, oxygen and nitrogen; compounds of silicon, nitrogen, and carbon; and silicon.Type: ApplicationFiled: April 6, 2001Publication date: November 20, 2003Inventor: IIan Golecki
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Patent number: 6641903Abstract: A transparent plastic pane of acrylic glass with internal plastic filaments, which largely hold together the fragments formed in the event of a break characterized in that the plastic filaments are at least partly sized. The internal filaments can be sized completely and/or partly, for example in portions. Hereby the matrix adhesion of the filaments can be adjusted to the effect that any fragments which may be formed in the event of break are largely held together by the filaments without permitting undesired detachment of the filaments during thermal stresses in the normal range of −20 to 120° C. The plastic panes are suitable in particular as a noise protection wall.Type: GrantFiled: December 29, 1999Date of Patent: November 4, 2003Assignee: Roehm GmbH & Co. KGInventors: Egbert Schoela, Gerald Molnar, Mojmir Ruzicka
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Publication number: 20030198795Abstract: Modular surface treatment materials such as carpet tiles, ceramic floor and wall panels and tiles, ceiling tiles, vinyl flooring squares, wall covering materials, and the like, are provided in a matrix of a plurality of different colors and a sequential array of tonal variations within each color. A system and method, including a computer-aided design tool for laying out patterns of individual modular material units selected from the color-tone matrix, is included, as well as display devices for materials in the matrix.Type: ApplicationFiled: April 17, 2003Publication date: October 23, 2003Inventor: William K. Grant
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Patent number: 6627143Abstract: SiC—C/C composite materials having a suitable kinetic coefficient of friction, good corrosion resistance in strongly oxidizing and corrosive environments, good creep resistance and spalling resistance, and high hardness. The materials are hardly oxidized or abraded even when exposed to high temperatures, while maintaining the excellent impact resistance and light weight of C/C composites. Molten metal pumps using the materials are provided from which components do not dissolve into the molten metal even when used in molten metal and have sufficient thermal impact resistance and oxidation resistance.Type: GrantFiled: December 6, 2001Date of Patent: September 30, 2003Assignee: NGK Insulators, Ltd.Inventors: Shigeru Hanzawa, Kenji Nakano
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Patent number: 6624105Abstract: The present invention discloses an oxide ceramic fiber/oxide ceramic composite material comprising primary composite materials each consisting of (a) an assembly of ceramic fibers composed mainly of a metal oxide and (b) a metal oxide ceramic which includes the ceramic fiber assembly (a) therein, the metal oxide of the ceramic (b) being different from the main component metal oxide of the ceramic fiber assembly (a) and the amount of the metal oxide ceramic (b) being 1 to 85% by weight relative to the weight of the ceramic fiber assembly (a), and a metal oxide ceramic which is a matrix for the primary composite materials and which includes the primary composite materials therein, the metal oxide of the ceramic being the same as or different from the main component metal oxide of the ceramic fiber assembly (a); and a process for producing thereof.Type: GrantFiled: April 19, 2001Date of Patent: September 23, 2003Assignee: Mitsui Mining Material Co., Ltd.Inventors: Yutaka Kagawa, Yoshinobu Komatsubara, Hiroshi Nakamura, Katsusuke Iwanaga
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Patent number: 6620471Abstract: An ultra dense composite strip for flexible pipe having armouring formed of longitudinal carbon fibers provided within a thermoplastic or thermosetting matrix in the form of a flat ribbon with a substantially rectangular cross-section, whereof at least one of the surfaces of the strip is reinforced with a film made integral with said surface, over substantially its whole width and over substantially its whole length.Type: GrantFiled: September 12, 2000Date of Patent: September 16, 2003Assignee: CoflexipInventor: Anh Tuan Do
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Patent number: 6617013Abstract: A ceramic matrix composite material (10) having a plurality of interlaminar stitches (16) as shown in FIG. 1. The stitches are formed by directing laser energy into the material to melt and recast zones of the material in a direction transverse to the layers of reinforcing fibers(12). The stitches not only improve the interlaminar strength of the material, but they also increase the through-thickness thermal conductivity of the material, thereby reducing thermal-induced stresses. The zones of recast material (18) may define holes (20) extending at least partially through the thickness of the material. The holes may be filled with a filler material (24), thereby mitigating any adverse loss-of-area effect created by the holes.Type: GrantFiled: May 10, 2001Date of Patent: September 9, 2003Assignee: Siemens Westinghouse Power CorporationInventors: Jay A. Morrison, Gary Brian Merrill
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Patent number: 6607851Abstract: A multi-layer tile material produced from layers of alumina enhanced thermal barrier material having different densities. The insulation layers are bound together by a high strength, high temperature alumina or silica binder having a coefficient of thermal expansion similar to that of the insulation layers. Use of the multi-layered tile allows the problems of tile slumping and of insufficient heat management associated with low density alumina enhanced thermal barrier tile to be overcome.Type: GrantFiled: October 26, 2001Date of Patent: August 19, 2003Assignee: The Boeing CompanyInventors: Robert A. DiChiara, Jr., Franklin K. Myers
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Publication number: 20030138615Abstract: Protection products and armored products made of a fiber-reinforced composite material with a ceramic matrix, include a protection element for partial or complete absorption of at least one impact-like load focussed at a point. The protection element has a body having at least one dimension at least equal to 3 cm, in a direction perpendicular to a load to be absorbed. The body includes a fiber-reinforced composite material having a ceramic matrix with at least 10% by weight of silicon carbide and having reinforcing fibers. At least 5% by weight of the reinforcing fibers are carbon fibers and/or graphite fibers.Type: ApplicationFiled: January 30, 2003Publication date: July 24, 2003Applicant: SGL Technik GmbHInventors: Udo Gruber, Michael Heine, Andreas Kienzle, Reinhard Nixdorf
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Patent number: 6596373Abstract: The present invention relates to an epoxy resin composition for a fibre reinforced composite material, which is thermosetting resin composition where the glass transition temperature Tg of the cured material obtained by heating for 2 hours at 180° C. is at least 150° C., and the modulus of rigidity G′R in the rubbery plateau in the temperature region above the aforesaid Tg is no more than 10 MPa. In accordance with the present invention, it is possible to provide a fibre-reinforced composite material which is outstanding in its resistance to hot-wet environmental condition, impact resistance, and strength characteristics such as tensile strength and compression strength, and furthermore it is possible to provide a thermosetting resin composition and a prepreg outstanding in terms of their peel strength to a honeycomb core.Type: GrantFiled: June 5, 2001Date of Patent: July 22, 2003Assignee: Toray Industries, Inc.Inventors: Hajime Kishi, Hiroaki Ninomiya, Junko Kawasaki
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Publication number: 20030134098Abstract: Fiber-reinforced ceramic composites comprising bundles, tows or hanks of long fibers, wherein the long fiber bundles, tows or hanks are completely surrounded by a short fiber-reinforced matrix, with the long and short fibers having, independently of one another, a mean diameter of from 4 to 12 &mgr;m and the long fibers having a mean length of at least 50 mm and the short fibers having a mean length of not more than 40 mm, a process for producing them and their use for producing clutch disks or brake disksType: ApplicationFiled: December 23, 2002Publication date: July 17, 2003Inventors: Moritz Bauer, Georg Burkhart, Martin Christ, Ronald Huener, Andreas Kienzle, Peter Winkelmann, Rainer Zimmermann-Chopin
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Patent number: 6592981Abstract: A lightweight insulating sandwich tile (110) having applications such as spacecraft and reusable launch vehicle thermal protection is disclosed. In one embodiment, the lightweight insulating sandwich tile (110) includes an outer structural facesheet (120) that is bonded or co-cured with an inner insulating core (130). The outer structural facesheet (120) is comprised of carbon-carbon and includes an oxidation resistant layer (140) on an outer surface thereof. The oxidation resistant layer (140) may comprise a coating or surface treatment of, for example, MoSi2, amorphous SiCN, amorphous SiCBN, Ti3SiC2, HfC, HfO2, HfB2, SiC, Ir, and ZrB2. The inner insulating core (130) is comprised of bonded discontinuous carbon fibers, a network of vitreous carbon ligaments, carbon aerogel, or graphite felt or a hybrid combination of these materials.Type: GrantFiled: July 20, 2000Date of Patent: July 15, 2003Assignee: Lockheed Martin CorporationInventors: Suraj P. Rawal, Frank M. Kustas
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Patent number: 6592979Abstract: Hybrid matrix fiber composites having enhanced compressive performance as well as enhanced stiffness, toughness and durability suitable for compression-critical applications. The methods for producing the fiber composites using matrix hybridization. The hybrid matrix fiber composites include two chemically or physically bonded matrix materials, whereas the first matrix materials are used to impregnate multi-filament fibers formed into ribbons and the second matrix material is placed around and between the fiber ribbons that are impregnated with the first matrix material and both matrix materials are cured and solidified.Type: GrantFiled: February 17, 2000Date of Patent: July 15, 2003Assignee: The Regents of the University of CaliforniaInventors: Steven J. Deteresa, Richard E. Lyon, Scott E. Groves
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Publication number: 20030129375Abstract: Fiber-reinforced ceramic composites which comprise at least two layers of a multidirectional woven fiber fabric as reinforcement, with at least 5% of the area of each layer of woven fiber fabric being permeated by matrix material, friction disks comprising these composites as core zone or support zone, a process for producing them and their use as brake disks or clutch disks.Type: ApplicationFiled: December 23, 2002Publication date: July 10, 2003Inventors: Moritz Bauer, Andreas Kienzle, Ingrid Kraetschmer, Mario Krupka
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Publication number: 20030124296Abstract: This invention comprises a transparent laminate having at least one layer of glass and having self-adhered directly to the layer of glass a thermoplastic polymer layer wherein the laminate is capable of sustaining repeated or prolonged stress after the breakage of the glass layer while maintaining the structural integrity of the laminate.Type: ApplicationFiled: October 9, 2002Publication date: July 3, 2003Inventor: Charles Anthony Smith
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Patent number: 6576330Abstract: A fully inorganic boron nitride paste, containing 80 to 94% of a boron nitride paint and 6 to 20% of ceramic fibers, is provided to allow the process of manufacturing boron nitride “shell” coatings of 0.0313 to 0.25 inch onto ceramic substrates chosen from a wide range of densities. De-clumping of the ceramic fibers such that fiber lengths are greater than 100 micrometers and clumps are less than {fraction (3/32)} inch improves boron nitride “shell” layer uniformity. Boron nitride content of greater than 36 wt. % (or about 50 vol. %) in the boron nitride “shell” provides ceramic structures with a matrix of boron nitride that provides long-term nonwetting behavior for molten nonferrous metals.Type: GrantFiled: July 28, 2000Date of Patent: June 10, 2003Assignees: Rex Roto Technologies, Inc., Zyp Coatings, Inc.Inventors: Steven R. Schenck, Karl W. Dersch, Lloyd R. Chapman, Cressie E. Holcombe, Jr., William B. Webb, Christopher W. Ivey
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Patent number: 6558782Abstract: Flexible graphite article of manufacture made by compressing a mixture of expanded graphite particle and a fluoro-resin including ethylene-tetrafluoroethylene (ETFE) copolymers after additional heat treatment. An article of manufacture of a gasket material made shows enhanced mechanical properties especially after oil immersion and reduced leakage.Type: GrantFiled: April 18, 2000Date of Patent: May 6, 2003Assignee: SGL Technic, Inc.Inventors: Anatoliy S. Bakman, Akira Kubo
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Patent number: 6547190Abstract: A solar array including a carbon fiber mesh substrate is provided. The solar panels including a series of hybrid structures formed along the common and continuous substrate by sandwiching the substrate between a series of discontinuous upper and lower support layers. In order to construct the solar panels having such hybrid structure, a series of top support layers or upper face sheets is disposed on a upper surface of the substrate and between the folding sections. The solar cells are placed on top of the upper face sheets. Similarly, a series of lower support layers or lower face sheets are disposed on a bottom surface of the substrate and between the folding sections. The folding sections are the regions where the upper and lower face sheets discontinue and expose the underlying substrate. The solar array can be folded along the folding section when a bending force is applied over one of the hybrid structures.Type: GrantFiled: May 6, 2002Date of Patent: April 15, 2003Assignee: Hughes Electronics CorporationInventors: Brian D. Thompson, Wah L. Lim
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Publication number: 20030059595Abstract: The present invention is a process for modifying the properties of a porous freeform fabricated part by increasing its density and reducing its porosity. The porosity and density of a freeform fabricated part are altered by packing the pores in a freeform part with an infiltrant, such as a preceramic polymer. The process includes drawing a vacuum on or pressurizing the freeform part while it is in an infiltrant bath, thereby forcing the infiltrant into the pores of the freeform part. After removing the densified freeform part from the infiltrant bath, the freeform part is subjected to a treating process, such that the infiltrant within the pores transforms to a ceramic or ceramic-containing phase to thereby increasing the density of the freeform part.Type: ApplicationFiled: July 3, 2002Publication date: March 27, 2003Inventor: Wayde R. Schmidt
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Patent number: 6537654Abstract: Protection products and armored products made of a fiber-reinforced composite material with a ceramic matrix, include a protection element for partial or complete absorption of at least one impact-like load focussed at a point. The protection element has a body having at least one dimension at least equal to 3 cm, in a direction perpendicular to a load to be absorbed. The body includes a fiber-reinforced composite material having a ceramic matrix with at least 10% by weight of silicon carbide and having reinforcing fibers. At least 5% by weight of the reinforcing fibers are carbon fibers and/or graphite fibers.Type: GrantFiled: April 12, 2000Date of Patent: March 25, 2003Assignee: SGL Technik GmbHInventors: Udo Gruber, Michael Heine, Andreas Kienzle, Reinhard Nixdorf
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Publication number: 20030041987Abstract: An acoustical panel has a fiberboard which includes a fibrous filler and a base binder, and a nodulated overlay disposed on the fiberboard, wherein the overlay includes nodulated wool and an overlay binder and has a substantially smooth surface. In one embodiment of the present invention, the fibrous filler is mineral wool and the base binder is granular starch. In an another embodiment of the present invention, the nodulated wool is nodulated mineral wool and the overlay binder is cooked pearl cornstarch.Type: ApplicationFiled: July 23, 2002Publication date: March 6, 2003Applicant: Armstrong World Industries, Inc.Inventors: Robert E. Foster, Larry R. Parks, James R. Lokey, John J. Janczura, Robert G. Ganse, Barry Buhay, Walter W. Chamberlain, John Felegi
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Patent number: 6528190Abstract: A composite (20) has a matrix (10), preferably of ceramic, interspersed with reinforcement structures (12), preferably ceramic fibers, coated with a material (14) selected from ZrGeO4, HfGeO4 and CeGeO4, where the composite can be used as a component in high temperature turbines.Type: GrantFiled: August 2, 2000Date of Patent: March 4, 2003Assignee: Siemens Westinghouse Power CorporationInventors: Christian X. Campbell, Jay E. Lane
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Patent number: 6517960Abstract: An article comprises a silicon-containing substrate and a zircon coating. The article can comprise a silicon carbide/silicon (SiC/Si) substrate, a zircon (ZrSiO4) intermediate coating and an external environmental/thermal barrier coating.Type: GrantFiled: April 26, 1999Date of Patent: February 11, 2003Assignee: General Electric CompanyInventor: Hongyu Wang
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Publication number: 20030021975Abstract: An oxidation-protected brake disk is made of a fiber-reinforced ceramic material. A method of producing such a brake disk comprises applying at least one paint layer to a brake disk. In order to reduce damage to the brake disk under extreme thermal stress, the brake disk is provided with a layer of a highly temperature-stable paint that is viscous at the operating temperature of the brake disk.Type: ApplicationFiled: July 15, 2002Publication date: January 30, 2003Inventor: Roland Martin
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Publication number: 20030012938Abstract: A multilayer ceramic composite is described which contains at least one supporting zone having oxidation-sensitive reinforcing fibers as well as a matrix. The matrix optionally contains oxidation-sensitive components. The composite further contains at least one surface layer, as well as at least one additional protective layer disposed between the supporting zone and surface layer, and whose matrix is composed substantially of at least one component of the matrix of the supporting zone or cover layer. The protective layer further contains additives that form self-healing layers.Type: ApplicationFiled: July 8, 2002Publication date: January 16, 2003Inventors: Moritz Bauer, Martin Christ, Udo Gruber, Michael Heine, Andreas Kienzle, Jens Rosenlocher, Rainer Zimmermann-Chopin