Glass Particles Or Spheres Patents (Class 428/406)
  • Patent number: 5026596
    Abstract: An aqueouse composition of an acrylic polymer to which a water soluble peroxide radical initiator has been added, said initiator being adapted to decompose at a temperature of from about 40.degree. C. to about 180.degree. C. and act on the polymer to crosslink the same. Using the aqueous composition, a water absorbent crosslinked polymer and a water absorbent polymer-coated article can be produced through simplified processes. The water absorbent crosslinked polymer exhibits excellent water absorbing and swelling properties so that it can be advantageously utilized for the production of wet absorbent articles such as disposable diaper, sanitary napkin or the like. The water absorbent polymer-coated article is excellent in water absorption properties and can be used safely for the purposes as mentioned above.
    Type: Grant
    Filed: December 13, 1989
    Date of Patent: June 25, 1991
    Assignee: Taiyo Fishery Co., Ltd.
    Inventor: Kazuo Saotome
  • Patent number: 4983458
    Abstract: A reflective marker for highway striping, signs and other surfaces is produced from a multiplicity of thermoplastic or thermosetting granules in the shape of tetrahedrons. A plurality of glass spheres having a diameter in the range of from about 6.0 microns to about 0.125 inches are substantially evenly dispersed throughout each granule with some of the spheres protruding through the outer granule surfaces. To form the granules the glass spheres, the granule material and a suitable pigment are mixed together and then applied to a flexible sheet or a roller containing a multiplicity of tetrahedron-shaped indentations. The mixture is urged into each of the indentations and is then cured. The resulting granules are removed from the indentations and are dropped from a random position onto a freshly painted highway line or other surface such that one of the flat faces on each granule is disposed in a downward direction.
    Type: Grant
    Filed: October 2, 1986
    Date of Patent: January 8, 1991
    Assignee: Potters Industries, Inc.
    Inventor: Robert Dejaiffe
  • Patent number: 4968545
    Abstract: The invention relates to tubular composite constructions of a composite comprising at least one layer of a prepreg construction of continuous filaments of high modulus fiber in a resin matrix and at least one layer of a thin film of syntactic foam comprising rigid microballoons uniformly dispersed in a matrix resin cocurable with the resin matrix of the prepreg.
    Type: Grant
    Filed: November 2, 1987
    Date of Patent: November 6, 1990
    Assignee: The Dexter Corporation
    Inventors: Michael Fellman, James J. Jarvis
  • Patent number: 4965159
    Abstract: A carrier for use in a developer for electro-photography, which comprises a core material and provided thereon in order, an intermediate resin layer and a layer for controlling triboelectric chargeability, said resin containing as a repeating unit a fluorinated alkylmethakrylarte unit, and a developer for electrophotography using the carrier and a positively chargeable toner is disclosed.
    Type: Grant
    Filed: February 20, 1990
    Date of Patent: October 23, 1990
    Assignee: Konica Corporation
    Inventors: Shigenori Kohno, Kenji Tsujita
  • Patent number: 4960816
    Abstract: A mineral particulate is disclosed selected from the group consisting of metal carbonates, glass fibers and layered lattice silicates, comprising particles of said mineral, the surface of which have been modified by a polymer synthesized in situ in the presence of a reactive gas selected from the group consisting of hydrogen, carbon monoxide and carbon dioxide; said particulate having a predetermined particle size distribution which substantially corresponds to the particle size distribution of the surface-unmodified feed particulate from which the product particulate is produced.
    Type: Grant
    Filed: December 2, 1988
    Date of Patent: October 2, 1990
    Assignee: ECC America Inc.
    Inventor: Camilla A. Rice
  • Patent number: 4959256
    Abstract: A cooking utensil having an enamel coating of a first enamel layer (7) covered in the zone of the bottom (1) of the utensil with a second enamel layer (3) which is in turn covered with a non-continuous third enamel layer (4) constituting a decoration and applied by screen process after drying of the first layer, these three layers (7, 3, 4) being obtained from an enamel frit and being fired simultaneously.The two enamel layers (3, 4) contain glass beads (5, 6), at least a certain number of which have a diameter of greater value than the thickness of these enamel layers and project from the surface of the layers, a certain number of beads (6) of the non-continuous third layer (4) being applied on beads (5) of the second layer (3). The second layer also contains heat-conducting flakes.The enamel coating offers enhanced resistance to wear and high thermal conductivity.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: September 25, 1990
    Assignee: SEB S.A.
    Inventor: Henri Piera
  • Patent number: 4959264
    Abstract: A release paper for the manufacture of artificial leather, characterized by the release coating of the paper being essentially of a flexible poly(4-methyl pentene-1) resin (TPX) loaded with particulate mineral filler.
    Type: Grant
    Filed: January 5, 1988
    Date of Patent: September 25, 1990
    Assignee: The Wiggins Teape Group Limited
    Inventors: Paul Dunk, Roger M. Hindin, Peter J. Miles
  • Patent number: 4939038
    Abstract: A light metallic composite material containing therein fine granular additives dispersed in a matrix of a light metallic material, which composite material has a light weight, high mechanical strength, and excellent characteristics such as high damping ability. The additives each have a density less than that of the matrix and heat resistance enough to withstand a heating temperature at which they are composited with the matrix. Preferably, the additives are each formed with a coating which increases mechanical strength and provides an electromagnetic characteristic different from that of the matrix. Preferably, the composite material is produced by heating a mixture of matrix powders and additives up to a temperature where only part of the mixture including no microspheres is softened but the mixture is adequately composited, an amount of additives being equal to 10% to 70% by volume of the matrix, and by forming the composited mixture into a desired shape and solidifying same.
    Type: Grant
    Filed: November 30, 1987
    Date of Patent: July 3, 1990
    Assignee: Inabata Techno Loop Corporation
    Inventor: Tadao Inabata
  • Patent number: 4935294
    Abstract: A composite sheet material which yields under non-uniform pressures caused by irregularities of contact between two relatively hard surfaces adapted to provide a more uniform pressure distribution comprising the combination of relatively small granules and relatively small stiff fibers in a matrix of waxy material adhered to a web of flexible material.
    Type: Grant
    Filed: November 17, 1988
    Date of Patent: June 19, 1990
    Assignee: Colgate-Palmolive Company
    Inventors: Kenneth W. Misevich, Roy R. McGregor
  • Patent number: 4931356
    Abstract: A sheet material which yields under non-uniform pressures caused by irregularities of contact between two relatively hard surfaces adapted to provide a more uniform pressure distribution comprising the combination of relatively small granules and relatively small stiff fibers in a matrix of waxy material adhered to a cover sheet of flexible material.
    Type: Grant
    Filed: November 17, 1988
    Date of Patent: June 5, 1990
    Assignee: Colgate-Palmolive Company
    Inventors: Kenneth W. Misevich, Thomas E. Mintel
  • Patent number: 4931498
    Abstract: Methods and materials are described for the preparation of novel immobilized membrane compositions. The described compositions are useful for evaluating membrane association charcteristics of chemical compounds, and as a chromatographic support material for separation/purification of biomolecules and particularly those expressed by genetically transformed cells as novel hybrid proteins having covalently bound membrane-binding peptides. Novel phospholipid carboxylates are useful intermediates for the preparation of chromatography supports having surfaces formed as covalently bound artificial membranes which simulate natural cellular membranes. The immobilized membrane compositions are adapted for use in chromatographic systems to study interactions of biologically active substances with membranes in vitro.
    Type: Grant
    Filed: February 25, 1988
    Date of Patent: June 5, 1990
    Assignee: Purdue Research Foundation
    Inventor: Charles Pidgeon
  • Patent number: 4927879
    Abstract: A membrane mimetic structure having a hydrophilic outer portion and a hydrophobic inner portion is covalently bound to a surface having reactive functional groups. The membrane mimetic structure consists essentially of adjacent amphiphilic molecules independently covalently bound to the surface. The structures can be applied to surfaces and should find application in a wide variety of disciplines requiring surfaces exhibiting properties of biological membranes.
    Type: Grant
    Filed: October 24, 1988
    Date of Patent: May 22, 1990
    Assignee: Purdue Research Foundation
    Inventor: Charles Pidgeon
  • Patent number: 4927688
    Abstract: A cast-iron element with a non-iron interior area utilizes a molding core formed of a glass material, which may be tubular or solid and may, as desired, be entirely enclosed within the casting.
    Type: Grant
    Filed: January 27, 1989
    Date of Patent: May 22, 1990
    Assignee: Eisengiesserei Monforts GmbH & Co.
    Inventors: Rudi Hass, Georg Jansen, Wilhelm Kallen
  • Patent number: 4916014
    Abstract: A paint for structures comprising infrared reflecting particles of a metal oxide or noble metal on a substrate comprising a plastic or mica.
    Type: Grant
    Filed: October 30, 1987
    Date of Patent: April 10, 1990
    Inventors: Paul Weber, Michael R. Weber
  • Patent number: 4906518
    Abstract: A filler material, having a light weight, an increased mechanical strength, and various excellent characteristics such as damping ability, as well as a composite material and a structural material thereof are provided. The filler material comprises mats made of alumina fibers, and layers of hollow silica-alumina-microspheres which are dispersed of and affixed to the associated mat, with the mats and the layers alternately stacked with each other. The composite material comprises a matrix of aluminum in which the above-mentioned filler material is filled. The structural material, which contains therein a predetermined amount of microspheres enough to provide the material with a desired vibration amplitude-frequency characteristic, is applied to a head arm for supporting a magnetic head of a disk device, for instance.
    Type: Grant
    Filed: November 17, 1988
    Date of Patent: March 6, 1990
    Assignee: Inabata Techno Loop Corporation
    Inventor: Tadao Inabata
  • Patent number: 4900767
    Abstract: A method of producing a mineral such as calcium carbonate, glass fibers and layered lattice silicates which is surface modified with an organic material wherein said mineral in substantially dry, particulate form is contacted with an organic monomer, co-monomers or a prepolymer, and surface polymerization or reaction in situ on the mineral is carried out in the presence of gaseous carbon monoxide.
    Type: Grant
    Filed: October 28, 1988
    Date of Patent: February 13, 1990
    Assignee: E.C.C. America Inc.
    Inventor: Camilla A. Rice
  • Patent number: 4898770
    Abstract: A process for forming a continuous strand preformable mat is disclosed which consists of applying a binder matrix material which includes a thermosetting polyester binder material and a thermoplastic polyester binder to the continuous strand mat. The mat is heated such that the thermosetting binder material cures and hardens while the thermoplastic binder material softens and flows around strand intersections. The mat is thereafter cooled in order to solidify the thermoplastic polyester material of the binder matrix for additional handling for packaging and for subsequent handling by the customer. The preforms are made by heating the mat to over 200.degree. F., placing in a cold mold, and then closing the mold to form and solidify the mat shape.
    Type: Grant
    Filed: April 7, 1987
    Date of Patent: February 6, 1990
    Assignee: Owens-Corning Fiberglas Corporation
    Inventor: Sidney G. Dunbar
  • Patent number: 4895745
    Abstract: A pressure-sensitive adhesive tape can be produced by photopolymerization and yet its pressure-sensitive adhesive layer can have a dark appearance when it contains a pigment or dye plus finely divided hydrophobic silica. As compared to a tape which is identical except for omission of the hydrophobic silica, the adhesive layer of the tape is substantially darker and usually of substantially more intense color. Furthermore, the tape exhibits better adhesive properties than do otherwise identical tapes containing no silica. The pressure-sensitive adhesive preferably is an acrylic pressure-sensitive adhesive and may be filled with glass microbubbles which afford a foamlike appearance and character.
    Type: Grant
    Filed: February 21, 1989
    Date of Patent: January 23, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: George F. Vesley, Jurgen Klingen
  • Patent number: 4894310
    Abstract: The improved photo-sensitive recording medium carrying the photo-curing microcapsules, capable of minimizing the variation of its "sensitivity" and therefore the image recording speed at the time when the optical image is exposed.A stable "sensitivity", which makes a duplicating operation stable in any environmental conditions, is obtained by fabricating the capsule walls of the photo-curing microcapsules with inorganic substances.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: January 16, 1990
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventor: Jun Sakai
  • Patent number: 4888240
    Abstract: A high strength self-consolidating particle comprised of a particulate substrate, a substantially cured inner resin coating and a fusible curable outer resin coating.
    Type: Grant
    Filed: August 26, 1985
    Date of Patent: December 19, 1989
    Inventors: John W. Graham, A. Richard Sinclair
  • Patent number: 4888247
    Abstract: Heat conducting laminates and laminated heat conducting devices having at least one layer of metal and at least one layer of polymer matrix composite material having low-thermal-expansion reinforcing material distributed throughout and embedded therein. The coefficient of thermal expansion and the thermal conductivity of the laminated heat conducting devices are defined by the metal in combination with the polymer matrix material and the low-thermal-expansion reinforcing material in the laminate. The coefficient of thermal expansion and thermal conductivity of a heat conducting device can be controlled by bonding at least one layer of metal to at least one layer of polymer matrix composite material having low-thermal-expansion reinforcing material distributed throughout and embedded therein. In one embodiment, the laminated heat conducting device comprises a plurality of alternating layers of aluminum and epoxy resin having graphite fibers distributed throughout the epoxy resin.
    Type: Grant
    Filed: August 27, 1986
    Date of Patent: December 19, 1989
    Assignee: General Electric Company
    Inventors: Carl H. Zweben, Rodman A. Mogle, Benjamin T. Rodini, Jr., Charles L. Thaw
  • Patent number: 4879321
    Abstract: In or for a polymeric article incorporating a synthetic polymer and a filler material, which filler material includes glass beads bearing coatings of at least one coating agent in a total coating amount not exceeding 1%, and preferably between 0.02% and 0.2%, by weight based on the weight of uncoated beads, which coatings limit adhesion between the glass beads and the synthetic polymer and confer an increased impact resistance on the article as compared with an article which includes uncoated glass beads as filler material but is otherwise identical. Preferred coating materials include silanes, fluorocarbon compounds and synthetic polymers having shockabsorbing properties, especially synthetic polymers having a glass transition temperature (Tg), determined by differential scanning calorimetry, which is lower than 15.degree. C.
    Type: Grant
    Filed: March 30, 1988
    Date of Patent: November 7, 1989
    Assignee: Glaverbel
    Inventor: Pierre Laroche
  • Patent number: 4871477
    Abstract: Disclosed are foam polymer compositions having outstanding resistance to expose to flame. The compositions comprise the product of reaction of a foamable composition and certain inorganic filler materials including one or more of (A) microexplodable micron-sized particles having an internal phase of a non-flammable gas releasing inorganic particulate material such as alumina trihydrate and an external phase of fusible inorganic material such as sodium silicate, (B) particulate, expandable alkali metal silicate, and (C) a particulate inorganic fire retardant such as ammonium salt of a phosphate or polyphosphate. The foams are self-extinguishing, essentially non dripping, and generate only low levels of smoke when impacted directly with the flame of a blowtorch.
    Type: Grant
    Filed: October 20, 1988
    Date of Patent: October 3, 1989
    Assignee: Firestop Chemical Corporation
    Inventor: Felix Dimanshteyn
  • Patent number: 4871711
    Abstract: An active material is disclosed comprising metal oxide/hydroxide particles having chemically bonded to reactive sites on a surface thereof, a monolayer of a phosphorous-containing organic material comprised of a phosphorous-containing group and a carbon-containing group. The bond to the metal oxide/hydroxide particle surface is formed by reaction of the phosphorous-containing group with the metal oxide/hydroxide particle surface, so that the carbon-containing group of the material is oriented away from the metal oxide/hydroxide surface.
    Type: Grant
    Filed: March 9, 1987
    Date of Patent: October 3, 1989
    Assignee: Aluminum Company of America
    Inventors: Edward S. Matin, Larry F. Wieserman
  • Patent number: 4869960
    Abstract: Ceramic particulate useful as a proppant in hydraulic fracturing and in gravel packing operations is provided which comprises a ceramic (sometimes vitreous) core surrounded by an epoxy resin coating. Novolac epoxy resin compounds without any substantial acid soluble filler are used to coat ceramic particulates similar to those disclosed in U.S. Pat. Nos. 4,680,230 and 4,632,876. The result is a product which combines the excellent solvent resistance of the ceramics with the acid resistance of the resin. The resin coating gives the added benefits of lower specific gravity and improved crush resistance.
    Type: Grant
    Filed: September 17, 1987
    Date of Patent: September 26, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: James L. Gibb, James A. Laird, Leslie G. Berntson
  • Patent number: 4851282
    Abstract: Thermochromic particle-containing linear material product produced by the process characterized by dipping a core in the form of a monofilament or multifilament into a vinyl chloride resin sol composition having a thermochromic particulate material incorporated therein, the thermochromic particulate material being prepared by enclosing with a high polymer compound an electron-donating chromogenic substance, an electron-accepting substance for the chromogenic substance and a solvent having a boiling point of at least 150.degree. C. and selected from the group consisting of alcohols, amides, esters and azomethines and further covering the resulting product with a different high polymer compound; withdrawing the core from the sol composition; and heating the core to gel the sol composition and cover the core with the gelled composition.
    Type: Grant
    Filed: May 23, 1988
    Date of Patent: July 25, 1989
    Assignee: Matsui Shikiso Chemical Co., Ltd.
    Inventors: Goro Shimizu, Masayasu Kamada, Yoshimi Hayashi
  • Patent number: 4849289
    Abstract: Fibres, particularly glass or rock wool fibres coated with a modified polyvinyl alcohol-based polymer and suitable for use as a base material to produce a surface coating on a backing by simultaneous spraying of the coated fibres mixed with water and a cross-linking agent. A method of producing the fibres to make them suitable to be sprayed in the manner described is also provided.
    Type: Grant
    Filed: October 1, 1987
    Date of Patent: July 18, 1989
    Assignee: Isover Saint-Gobain
    Inventors: Jean-Luc Bernard, Etienne Serein
  • Patent number: 4844831
    Abstract: The use of combination granulates consisting of metasilicate and silica in detergent products. These combination granulates can particularly be used as anti-redeposition and antisoiling agents in detergent compositions for washing laundry.
    Type: Grant
    Filed: March 30, 1988
    Date of Patent: July 4, 1989
    Assignee: Rhone-Poulenc Chimie
    Inventors: Daniel Joubert, Philippe Parker
  • Patent number: 4830921
    Abstract: A packing material for liquid chromatography, which comprises an optically active compound having the formula: ##STR1## wherein Ar is a phenyl group, an .alpha.-naphthyl group or a .beta.-naphthyl group, R.sub.1 is an alkyl group having from 1 to 4 carbon atoms, a phenyl group or a 3,5-dinitrophenyl group, R.sub.2 is an alkyl group having from 1 to 4 carbon atoms, *indicates an asymmetric carbon atom and n is an integer of 2 or 3, as a stationary phase.
    Type: Grant
    Filed: December 3, 1987
    Date of Patent: May 16, 1989
    Assignee: Tosoh Corporation
    Inventors: Ryuichi Kitayama, Katsuo Komiya, Yoshio Kato
  • Patent number: 4828695
    Abstract: A novel packing material suitable for high pressure liquid chromatography comprising the chemically bonded, crosslinked reaction product of porous inorganic particles, with an organic silane compound having epoxy groups on the surface of the particles, and then with polyvinyl alcohol, in which the hydroxyl groups of the polyvinyl alcohol and the epoxy groups on the silane moieties react to form ether bonds, which cover almost or almost completely the residual silica hydroxyl groups on the surface of the support.
    Type: Grant
    Filed: February 10, 1988
    Date of Patent: May 9, 1989
    Assignee: Yamamura Chemical Laboratories, Co., Ltd.
    Inventors: Ryuji Yamamura, Mikio Tsuboi, Keishi Kitagawa, Masaru Abe
  • Patent number: 4818607
    Abstract: The present invention provides an electrically conductive material (10) comprising a substantially spherical refractory particle (12) having an exterior surface (14) and having a diameter of no more than about 5 millimeters. An electrically conducting coating (22) substantially equally covers the entire exterior surface (14), the coating (22) having at least about 70 atomic percent carbon and being from about 10 Angstroms to about 500 Angstroms thick. A plurality of such particles (12) are useful as filler materials. Also, such particles (12) are useful as flowing electrodes. Objects containing the particles (12) have desirable electrical properties.
    Type: Grant
    Filed: May 8, 1987
    Date of Patent: April 4, 1989
    Assignee: Northrop Corporation
    Inventors: Steven F. Rickborn, Donald Z. Rogers
  • Patent number: 4816364
    Abstract: The present invention is intended to provide a carrier to be used as a two-component developer, wherein a nuclide particle surface has a magnetic plated layer composed of an iron oxide. The carrier according to the present invention is to be used in the electrophotographic method, electrostatic recording method, and electrostatic printing method, and also provides an excellent developer which is lightweight and has a long service life.
    Type: Grant
    Filed: September 3, 1987
    Date of Patent: March 28, 1989
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Masao Oishi, Takao Saito, Kouichi Nagata, Katsukiyo Ishikawa, Eio Hisajima
  • Patent number: 4804580
    Abstract: A non-combustible, inorganic heat insulation which can be sprayed onto a surface being insulated is particularly useful for forming the cold face insulation layer in a catalytic reformer housing. The insulation is formed from an inorganic cement having glass and/or ceramic microspheres mixed therein.
    Type: Grant
    Filed: July 7, 1988
    Date of Patent: February 14, 1989
    Assignee: International Fuel Cells Corporation
    Inventor: James D. Singelyn
  • Patent number: 4786555
    Abstract: An aqueous solution of precursors for biologically active glass, support particles coated with the solution, support particles coated with the glass, spheroidal particles of biologically active glass, processes for making the solution, coating the support, and for making the coated support and the spheroidal glass particles. The materials that comprise the biologically active glass are useful in prosthetic devices and implants for the human body.
    Type: Grant
    Filed: June 9, 1986
    Date of Patent: November 22, 1988
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Edward G. Howard, Jr.
  • Patent number: 4781968
    Abstract: A low dielectric constant material for use in the formation of thick film circuits such as VLSI devices. The material comprises a thick film insulation matrix of standard viscosity; a thick film organic vehicle; and a plurality of dry, hollow, glass microspheres. The insulation matrix, vehicle, and microspheres are thoroughly combined into a homogeneous material of standard viscosity.
    Type: Grant
    Filed: February 28, 1986
    Date of Patent: November 1, 1988
    Assignee: Digital Equipment Corporation
    Inventor: David Kellerman
  • Patent number: 4780491
    Abstract: The invention primarily concerns a pressure-sensitive adhesive tape, the adhesive layer of which is filled with glass microbubbles and has a dark appearance by virtue of (1) the microbubbles are stained glass which preferably is dark, and (2) dispersed throughout the adhesive layer is a pigment or dye which preferably is dark. More broadly, the invention concerns any coherent article filled with stained-glass microbubbles. The glass of the microbubbles preferably has an ultraviolet window, permitting the article to be made by photopolymerizing a matrix filled with the microbubbles.
    Type: Grant
    Filed: February 9, 1987
    Date of Patent: October 25, 1988
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: George F. Vesley, Alan H. Paulson
  • Patent number: 4780248
    Abstract: Thick film electronic compositions comprising finely divided particles of electrically functional material and a PbO-compatible inorganic binder dispersed in an organic medium in which 0.1 to 10.0% wt. lead nitrate is coated on the surface of at least one of the solide components.
    Type: Grant
    Filed: February 6, 1987
    Date of Patent: October 25, 1988
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Paul C. Donohue, Vincent P. Siuta
  • Patent number: 4775592
    Abstract: A fluoroaluminosilicate glass powder for dental glass ionomer cement, a surface of which is treated with a fluoride in an amount of from 0.01 to 5 parts by weight based on 100 parts by weight of the glass powder, is disclosed. The fluoroaluminosilicate glass powder of the invention is improved in not only physical properties such as crushing strength but also mixing workability without impairing the inherent characteristics thereof for the dental use.
    Type: Grant
    Filed: August 21, 1986
    Date of Patent: October 4, 1988
    Assignee: G-C Dental Industrial Corp.
    Inventors: Shoji Akahane, Kazuo Hirota, Kentaro Tomioka
  • Patent number: 4769348
    Abstract: A process for fabrication of refractory insulating materials wherein essentially pure silica shells are mixed with a polymeric graphite precursor dissolved in a solvent. The resulting slurry is placed in a forming mold, and the solvent is evaporated to form a polymeric matrix containing the shells as a dispersion. This matrix is pyrolized under an inert or reducing atmosphere to decompose the polymer and form a first product consisting essentially of a carbon matrix containing a dispersion of silica shells. To enhance refractory characteristics, such first product is fired at high temperature in an inert or reducing atmosphere to form a second product consisting of a carbon matrix containing a dispersion of SiC-lined voids, or in a nitrogen atmosphere to form a third product consisting of the carbon matrix containing a dispersion of Si.sub.3 N.sub.4 -lined voids.
    Type: Grant
    Filed: July 28, 1986
    Date of Patent: September 6, 1988
    Assignee: KMS Fusion, Inc.
    Inventor: Thomas P. O'Holleran
  • Patent number: 4767670
    Abstract: A chromatographic packing useful for the separation of oligonucleotides is disclosed. The packing includes an insert porous support particle and a silane bonded phase comprising a weak anion exchange group in close proximity to at least one polar non-ionic group.
    Type: Grant
    Filed: January 21, 1987
    Date of Patent: August 30, 1988
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Geoffrey B. Cox, Anthony Atkinson, Peter A. D. Edwardson, Michael D. Scawen
  • Patent number: 4764424
    Abstract: Solid particles are coated with a uniform and continuous polyamide layer by immersion in a reaction medium capable of forming polyamides by anionic polymerization in solution.
    Type: Grant
    Filed: March 31, 1986
    Date of Patent: August 16, 1988
    Assignee: Atochem
    Inventors: Roland Ganga, Jacques Grossoleil, Jean-Paul Merval
  • Patent number: 4763576
    Abstract: A detonating energy transmittal device is provided which, when combined with even relatively low-power blasting caps, is capable of promoting and initiating the explosive detonation of liquid nitromethane, which device comprises a plurality of layers of foam material, an effective amount of frangible articles carried on at least one surface of the foam material layers and forming thereon a substantially continuous layer intermediate the adjacent foam material layer, and a cavity capable of accommodating a blasting cap and of placing said blasting cap in intimate contact with said plurality of foam material layers. Methods for detonating fluid explosives also are provided.
    Type: Grant
    Filed: April 21, 1986
    Date of Patent: August 16, 1988
    Assignee: Angus Chemical Company
    Inventors: Robert E. Kass, Robert J. Frederick, Louis L. Hallock
  • Patent number: 4759987
    Abstract: A polyimide molding powder and a process for producing the same are disclosed, said powder comprising an aggregate of polyimide particles, in which the whole or a large portion of said powder comprises polyimide particles composed of a particulate filler coated with a polyimide resin and/or polyimide particles composed of a fibrous filler coated with a polyimide resin, and said process comprising reacting an aromatic tetracarboxylic acid dianhydride and an aromatic diamino compound in an organic solvent to synthesize a polyimide precursor and imidating the polyimide precursor to precipitate polyimide particles, wherein a particulate filler and/or a fibrous filler dispersed in a prescribed amount of an organic solvent is or are added to the reaction system at any stage before the imidation of the polyimide precursor. The molding powder produces polyimide molded products free from brittleness and excellent in appearance, as well as various performance characteristics due to the improving effects of the filler.
    Type: Grant
    Filed: June 5, 1986
    Date of Patent: July 26, 1988
    Assignee: Nitto Electric Industrial Co., Ltd.
    Inventors: Keizo Mizobe, Koji Suzuki, Osamu Yoshikai, Yuzuru Noda
  • Patent number: 4755407
    Abstract: A fire and wear-resistant strap material particularly useful in conjunction with fire fighting apparatus is disclosed. The strap material comprises a carrier fabric, the surfaces of which have been provided with a flexible retro-reflective coating permanently bonded thereto. The carrier fabric is preferably comprised of aramid yarns which, while having low abrasion resistance, are rendered highly wear-resistant by the retro-reflective coating, which also functions to minimize heat transfer to the supporting fabric.
    Type: Grant
    Filed: September 22, 1986
    Date of Patent: July 5, 1988
    Assignee: C.M.Offray & Son, Inc.
    Inventors: John A. Mortensen, Timothy A. Sands, Mark P. Henderson, Richard P. Lee, Linda B. Patterson
  • Patent number: 4755422
    Abstract: A multilayered electronics protection system includes a first ablator layer providing thermal protection that is sprayed on to a non-metallic surface of an electronics enclosure. A second ablator layer comprised of highly conductive material is sprayed on to the first ablator layer and provides protection against strategic environmental threats.
    Type: Grant
    Filed: April 17, 1986
    Date of Patent: July 5, 1988
    Assignee: United Technologies Corporation
    Inventors: Stephen E. Headrick, Charles E. Cataldo
  • Patent number: 4751202
    Abstract: A process of manufacturing vitreous beads is disclosed in which feedstock particles of a glass-former composition containing chemically bound water, are fed through a heating zone in which the particles are vitrified and spherulized and the resulting vitreous beads are cooled. The size of the feedstock particles and their content of substance which becomes gaseous during the passage of the particles through said heating zone are such that a least 20% by weight of the formed beads have a relative density greater than I.O. The vitrifiable oxide forming elements of said glass-former composition may be chemically interlinked, and the feedstock may be prepared as a silica-based gel or precipitate having a composition suitable for vitrification into a glass of any desired composition for example one which by virtue of its low alkali content is resistant to hydrolytic attack.
    Type: Grant
    Filed: June 20, 1986
    Date of Patent: June 14, 1988
    Assignee: Glaverbel
    Inventors: Francois Toussaint, Pierre Goelff
  • Patent number: 4751203
    Abstract: A process of manufacturing vitreous beads is disclosed in which feedstock particles of a glass-former composition containing less than 15% by dry weight of sodium and potassium calculated as their respective oxides and containing chemically bound water, are fed through a heating zone in which the particles are vitrified and spherulized and the resulting vitreous beads are cooled. The vitrifiable oxide forming elements of said glass-former composition may be chemically interlinked, and the feedstock may be prepared as a silica-based gel or precipitate having a composition suitable for vitrification into a glass of a desired composition which by virtue of its low alkali content is resistant to hydrolytic attack. By control of the cellulating agent content (bound water and optionally a gas evolving salt radical such as nitrate or sulphate) of the feedstock, and its granulometry, the relative proportions of solid and hollow beads which will be produced in a given spherulizing run can be controlled.
    Type: Grant
    Filed: June 20, 1986
    Date of Patent: June 14, 1988
    Assignee: Glaverbel
    Inventors: Francois Toussaint, Pierre Goelff
  • Patent number: 4746572
    Abstract: A bidentate silane containing at least two silicon atoms bridged by certain groups, arranged to form at least a seven member ring system, is formed between the bidentate silane and the atoms to which the silane is covalently attached on the substrate surface.
    Type: Grant
    Filed: November 28, 1986
    Date of Patent: May 24, 1988
    Assignee: E. I. DuPont de Nemours and Company
    Inventors: Joseph L. Glajch, Joseph J. Kirkland
  • Patent number: 4735837
    Abstract: A removable adhesive sheet comprising a substrate (A) and an adhesive composition layer which comprises elastic micro-balls (B) and an adhesive (C), the adhesive composition layer being formed on an adhesive layer forming surface of the substrate, wherein the mixing proportion of the elastic micro-balls (B) to the adhesive (C) in the adhesive composition layer is 1:10 to 10:1 in terms of weight ratio, and the protrusive areas of the elastic micro-balls (B) partially protruding from the surface of the adhesive composition layer is entirely covered with the adhesive (C) has an adhesion capability that is not lowered through a frequent repetition of bonding to and removing from an adherend.
    Type: Grant
    Filed: August 8, 1985
    Date of Patent: April 5, 1988
    Assignee: Nichiban Company Limited
    Inventors: Hiroyasu Miyasaka, Yasuaki Kitazaki, Tetsuaki Matsuda, Junichi Kobayashi
  • Patent number: 4732806
    Abstract: Method and apparatus is provided for reinforcing a structural member of a vehicle body by the use of adhesively bonded together glass macrospheres of 3 to 9 mm. in diameter. The adhesive is not more than about 40% by weight of the mixture so that voids remain between the adjacent macrospheres to permit airflow through the reinforcement and the reinforced structural member upon curing adhesive. The adhesive may be curable at ambient temperature or may be a high temperature curable adhesive which is cured in a vehicle body paint curing oven to bond the macrospheres to one another and to the structural member. The adhesion of the macrospheres to the structural member may be facilitated by an epoxy coated flexible sheet material lining the walls of the structural member. The adhesive coated macrospheres may be closely packed into the structural member by pouring or blowing.
    Type: Grant
    Filed: January 28, 1987
    Date of Patent: March 22, 1988
    Assignee: General Motors Corporation
    Inventor: Joseph S. Wycech