Of Polyamidoester (polyurethane, Polyisocyanate, Polycarbamate, Etc.) Patents (Class 428/423.1)
  • Patent number: 9309455
    Abstract: The present invention relates to compounds represented by the following Formula (II), Ring-A of Formula II can be, for example, an aryl group, and Q? and Q?? can each be independently selected from groups, such as, halogen, —OH, —CN, amine groups, amide groups, carboxylic acid ester groups, carboxylic acid groups, alkenyl groups, alkynyl groups, carbonate groups, sulfide groups, and sulfonic acid ester groups. The present invention also relates to photochromic compositions and photochromic articles that include one or more photochromic compounds such as represented by Formula II.
    Type: Grant
    Filed: February 19, 2014
    Date of Patent: April 12, 2016
    Assignee: Transitions Optical, Inc.
    Inventors: Meng He, Anil Kumar, Darrin R. Dabideen
  • Patent number: 9303179
    Abstract: A primer coating is provided for use on polymeric substrates to enhance the adhesion of metallized coatings to the substrates. The primer coating also improves the gas barrier properties of the substrate when used in combination with a metallized coating. The primer coating includes an amorphous polyvinyl alcohol, polyethyleneimine, and optionally, an aqueous dispersion of polyurethane. The primer coating may be applied to a variety of polymeric substrates including polylactic acid, polyethylene terephthalate, biaxially oriented polyethylene terephthalate, oriented polypropylene, biaxially oriented polypropylene, and biaxially oriented polyamide. When used in combination with the subsequently applied metallized coating, an oxygen transmission rate of about 0.1 and 5.0 cc/m2/day at 0% relative humidity is achieved.
    Type: Grant
    Filed: November 1, 2013
    Date of Patent: April 5, 2016
    Assignee: Michelman, Inc.
    Inventor: Michelle Ibanez
  • Patent number: 9266825
    Abstract: The present invention relates to a copolymer of the formula where A, B, and D are independently of one another an aliphatic (cyclo)alkylene radical, R is a C1-C10 alkyl radical, and 3?x?10. The present invention also relates to a process for preparing the copolymer, to its use and also to a coating composition and a coating formulation containing the copolymer.
    Type: Grant
    Filed: February 8, 2015
    Date of Patent: February 23, 2016
    Assignee: EVONIK DEGUSSA GmbH
    Inventors: Rainer Lomoelder, Hans Goerlitzer, Tobias Unkelhaeusser, Markus Hallack, Wiebke Stache
  • Patent number: 9206114
    Abstract: A compound having the formula: X?N+(CH3)(CH2CH2OH)2[(CH2)n—COO—R1]. R1 is an ester protecting group, X is a halide, and n is a positive integer. A method of reacting N-methyldiethanolamine with an ?-halo-n-alkanoate ester to form the compound.
    Type: Grant
    Filed: August 20, 2015
    Date of Patent: December 8, 2015
    Assignee: The United States of America, as represented by the Secretary of the Navy
    Inventors: Peter N. Coneski, James H. Wynne
  • Patent number: 9186701
    Abstract: This invention relates to a process for multilayer coating of substrates, comprising the steps: I) applying a layer of a water-based color-imparting and/or special effect-imparting base coat coating composition to a substrate, II) applying a layer of a clear coat coating composition curable by means of high energy radiation and optionally curable by at least one additional chemical curing reaction, and III) curing said clear coat layer by exposing it to high energy radiation, wherein the clear coat coating composition comprises: A) at least one compound capable of free-radical polymerization having at least one olefinically unsaturated group, B) at least one photoinitiator and C) at least one organic phosphine derivative.
    Type: Grant
    Filed: June 14, 2010
    Date of Patent: November 17, 2015
    Assignee: AXALTA COATING SYSTEMS IP CO., LLC
    Inventor: Helmut Loeffler
  • Patent number: 9175172
    Abstract: A water-based primer coating for use on paper and polymeric substrates is provided for enhancing the adhesion of liquid toner to the substrates, which are designed to be printed using an electrophotographic printing device. The primer coating includes an aliphatic polyurethane dispersion and an anionic wax emulsion, and is substantially free of copolymers of ethylene and acrylic acid.
    Type: Grant
    Filed: February 25, 2013
    Date of Patent: November 3, 2015
    Assignee: MICHELMAN, INC.
    Inventor: Baptiste Regnier
  • Patent number: 9149834
    Abstract: A process for applying an overlayer to a cured thermoset molding composition is provided that includes exposing the cured thermoset molding composition to a plasma under conditions that modify the surface energy of a surface of the article without visually modifying the surface. The surface of the article is then overcoated with an overlayer having superior adhesion to a like article absent the intermediate plasma treatment. A component is also provided that is cured thermoset resin article having a shape and a surface. An overlayer is applied to the surface while the surface is still plasma activated. The overlayer is adhesion is unchanged by 4 weeks in a 100% humidity chamber at 30° C. over at least 95 area % of an interface between the overlayer and the surface.
    Type: Grant
    Filed: July 23, 2012
    Date of Patent: October 6, 2015
    Assignee: Continental Structural Plastics, Inc.
    Inventors: Probir Kumar Guha, Michael J. Siwajek, Brad Anthony Haskell, SudarSan Neogi
  • Patent number: 9133372
    Abstract: The present invention relates to an adhesive compound consisting essentially of an organic phase and inorganic phase, the organic phase comprising an amorphous aliphatic (co)polymer having a Ring & Ball softening point of between 75 and 180° C., and a second aliphatic material having a Tg of about ?5° C. or lower and a kinematic viscosity of 4500 mm2/s at 100° C. or less, wherein said organic components are present in weight amounts of between 95/5 and 10/90; the inorganic phase comprising a filler, the filler being present in amount of at least about 15 wt % in the total composition. The compositions are suitable for anti-corrosion coatings or sealants against filtration or penetration of water or moisture. A rubber material may be added to this compound or other anti-corrosion coatings to increase the yield point at high temperatures.
    Type: Grant
    Filed: December 23, 2009
    Date of Patent: September 15, 2015
    Assignee: J. van Beugen Beheer B.V.
    Inventors: Edwin Welles, Leonard Van Beugen, Gerhard Maier, Martin Mayershofer
  • Patent number: 9133070
    Abstract: A smokeless high-energy solid propellant composition, which contains a bismuth-based compound as a combustion improver and exhibits a low pressure exponent, and a method of preparing the same are provided. The propellant composition contains the bismuth-based compound, thus ensuring preparation processability of the propellant, especially pot-life, and thereby a propellant curing system can be changed thus ensuring reliability of the propellant preparation processability, unlike temperature control and curing inhibition catalyst addition methods published to date. This composition advantageously exhibits a low pressure exponent.
    Type: Grant
    Filed: June 26, 2013
    Date of Patent: September 15, 2015
    Assignee: AGENCY FOR DEFENSE DEVELOPMENT
    Inventors: Byoung-Sun Min, Moon-Sam Ryoo, Seung-Won Ko
  • Patent number: 9115293
    Abstract: Provided is a coating material comprising a crosslinker component and a catalyst component, the coating material curing at temperatures of 10 to 80° C., to the use of the coating materials to coat a variety of substrates and to coating compositions comprising coating material.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: August 25, 2015
    Assignee: EVONIK DEGUSSA GmbH
    Inventors: Rainer Lomoelder, Andre Raukamp, Sabine Naumann
  • Publication number: 20150147578
    Abstract: The present invention relates to multilayer coatings of an optionally pre-coated substrate and processes for the multilayer coating of substrates. The multilayer coatings comprise a base coat layer of a water-based colour- and/or special effect-imparting base coat composition disposed on the optionally pre-coated substrate. The multilayer coatings further comprise a clear coat layer of a transparent clear coat composition disposed on the base coat layer. The water-based colour- and/or special effect-imparting base coat composition is a water-based coating composition comprising A) at least one water-dilutable polyurethane binder, B) optionally at least one curing agent, and C) at least one pigment. The at least one water-dilutable polyurethane binder is based on at least one polyhydroxyl compound, said polyhydroxyl compound comprises at least 50% by weight of at least one polycarbonate polyol, which is liquid at 20° C., the % by weight are based on the total amount of the polyhydroxyl compound.
    Type: Application
    Filed: February 2, 2015
    Publication date: May 28, 2015
    Applicant: AXALTA COATING SYSTEMS IP CO., LLC
    Inventors: ANDREAS FIEBERG, CARMEN FLOSBACH, PAUL P. BRUYLANTS, JOZEF THERESIA HUYBRECHTS
  • Publication number: 20150147577
    Abstract: [Problem] To increase adhesive strength between an aqueous base coat layer and a clear coat layer in a coating method by a two-coat one-bake system where an aqueous base coat paint is coated, then a clear coat paint is coated, and these two coated films are simultaneously hardened, in comparison with the conventional method. [Solution] Provided is a coating method using a specific hardener in a clear coat paint. Namely, the hardener is characterized in that (1) it includes a reaction product of (i) a derivative of 1,6-hexamethylene diisocyanate including a trimer and virtually not including a diisocyanate monomer, and (ii) a compound having both an active hydrogen and a hydrophilic group; and (2) viscosity at 23° C. is not more than 1,000 mPa·s. The compound having both an active hydrogen and a hydrophilic group herein is a compound having an active hydrogen-containing group and a sulfo group represented by formula (I), and preferably the sulfo group in a hardener is neutralized with a tertiary amine.
    Type: Application
    Filed: July 3, 2013
    Publication date: May 28, 2015
    Applicant: Bayer MaterialScience AG
    Inventors: Tomokazu Shigemori, Hiroshi Morita
  • Publication number: 20150140338
    Abstract: Methods and compositions for treating a substrate are provided. The composition contains a corrosion-inhibiting metal cation and a conjugated compound.
    Type: Application
    Filed: June 10, 2013
    Publication date: May 21, 2015
    Applicant: PCR-DeSoto International, Inc.
    Inventor: Eric L. Morris
  • Publication number: 20150140290
    Abstract: Multilayer articles comprise a thermoformable substrate, a base layer, and an optional transparent protective layer. Methods of making and using the paint film composites, and shaped articles made thereby, are also disclosed.
    Type: Application
    Filed: January 23, 2015
    Publication date: May 21, 2015
    Inventors: Michael A. Johnson, Frank A. Brandys, Kent E. Nielsen, Charlie C. Ho, Vijay Rajamani
  • Patent number: 9034454
    Abstract: An apparatus for filling joints in precast concrete structures includes a core that has exceptionally low creep and conforms to ASTM D 1752 made of controlled particle size composites of recycled cellular rubber and plastic materials in the form of a rectangular slab. Holes are drilled through a central area and countersink recesses are formed around the holes. An outer coating of a thermoplastic polyurethane/polyurea elastomer system of a thickness of 0.075 inch covers the slab and countersink recesses. The coated core is abrasion and UV resistant while having the creep characteristics needed to make a dam expansion joint filler.
    Type: Grant
    Filed: September 30, 2011
    Date of Patent: May 19, 2015
    Assignee: Southern Rubber Company, Inc.
    Inventor: Stephen Edward Bowman
  • Patent number: 9034937
    Abstract: A method of treating a surface of a substrate using modified urushiol derived from Toxicodendron vernicifluum is provided. More particularly, the reactivity of a hydroxyl group of urushiol extracted from fresh Toxicodendron vernicifluum is removed before the lacquer is used as a UV coating agent for a substrate such as a steel sheet. Therefore, the substrate may have high antibacterial activity, and excellent appearance and functionalities such as far-infrared radiation, blocking of electromagnetic waves, enhanced corrosion resistance, high crosslinking speed when a low content of a photoinitiator is used, excellent surface gloss and high scratch resistance.
    Type: Grant
    Filed: December 28, 2010
    Date of Patent: May 19, 2015
    Assignee: POSCO
    Inventors: Hye Jin Yoo, In Woo Cheong, Chang Se Byeon, Jae Ryung Lee, Jin Tae Kim, Jung Hwan Lee, Yang Ho Choi
  • Patent number: 9032692
    Abstract: Embodiments of the invention include insulated units and methods of producing the insulating units. The insulating units include a first surface, a structural seal disposed on at least portions of the first surface, and a second surface disposed on the structural seal. The structural seal includes the reaction product of at least one first isocyanate, at least one isocyanate reactive side, and at least one adhesion promoter including a reaction product of at least one secondary aminoalkoxy silane and at least one second isocyanate.
    Type: Grant
    Filed: November 10, 2011
    Date of Patent: May 19, 2015
    Assignee: Dow Global Technologies LLC
    Inventors: Bindushree Radhakrishnan, Laura A. Grier, Syed Z. Mahdi
  • Patent number: 9034471
    Abstract: The invention relates to a powder resin with amp from 60 to 110° C., and a particle size from 10 to 250 ?m, which comprises the reaction product of a reactive composition comprising: a) an isocyanate component comprising a polyisocyanate with functionality of at least 2, b) an alcoholic component, comprising: b1) at least one polyol with OH functionality from 2 to 4, b2) a monoalcohol component comprising: b2.1) a monoalcohol, bearing an ethylenic unsaturation b2.2) a saturated alcohol selected from the group of fatty alcohols, b2.3) optionally, an additional saturated monoalcohol from non fatty monoalcohols the molar ratios of OH functional groups, of the said alcoholic components b2.2) (possibly b2.3)) and b2.1) being defined so that the OH molar ratio of b2.2)/b2.1) or of [b2.2)+b2.3)]/b2.1) ranges from higher than 0.
    Type: Grant
    Filed: September 6, 2011
    Date of Patent: May 19, 2015
    Assignee: Arkema Coatings Resins S.A.U.
    Inventors: Enrique Grau, Lluis Casadevall
  • Publication number: 20150132580
    Abstract: A composition includes an isocyanate, a polyether diol, a branched short chain diol having a backbone including carbon atoms in a range of 1 to 9 and at least one branching group, and a cross-linker having a hydroxyl functionality in a range of 2.2 to 4. A films includes the composition and an interlayer includes the film. Transparencies including the interlayer and methods of making the same are further disclosed.
    Type: Application
    Filed: January 21, 2015
    Publication date: May 14, 2015
    Inventors: Razmik Boghossian, Khushroo H. Lakdawala
  • Patent number: 9023933
    Abstract: An autoxidisable coating composition comprising i) 10 to 60 wt % of an autoxidisable material with: a) a number average molecular weight <4500 g/mol; b) optionally 1 to 20 carbohydrate units; c) a fatty acid content of ?60 wt %; d) a viscosity at 100% solids in the range of from 0.05 to 5 Pa·s at 20+/?5° C. at a shear rate of 5000 s?1; ii) 90 to 40 wt % of an autoxidisable urethanised resin with: e) a number average molecular weight ?4000 g/mol; f) a fatty acid content of ?50 wt %; g) an acid value in the range of from 0 to 20 mgKOH/g resin; h) an isocyanate content in the range of from 1 to 35 wt % by weight of autoxidisable urethanised resin; where i)+ii)=100 wt %, based on the total solids content of the autoxidisable coating composition.
    Type: Grant
    Filed: April 27, 2010
    Date of Patent: May 5, 2015
    Assignee: DSM IP Assets B.V.
    Inventors: Willem Grisnich, Fokeltje Akke Koldijk, Adrianus Jozephus Hendricus Lansbergen, Albertus Johannes Reuvers, Stefan Hendrikus Maria Willems
  • Patent number: 9026014
    Abstract: Provided is a developing roller in which printing quality, in particular, one-dot level fine line printing quality is improved by securing a high resistance value and high surface potential on the surface layer. The elastic roller comprises successively on the outer periphery of a shaft 1 an elastic layer 2, an intermediate layer 3, and a surface layer 4. The surface layer 4 contains a urethane (meth)acrylate oligomer obtained by allowing polybutadiene polyol or hydrogenated polybutadiene polyol, polyisocyanate, and (meth)acrylate having a hydroxyl group to react.
    Type: Grant
    Filed: February 1, 2012
    Date of Patent: May 5, 2015
    Assignee: Bridgestone Corporation
    Inventors: Akihide Oosaku, Shogo Imai, Yusuke Fujisawa
  • Publication number: 20150118501
    Abstract: Coating compositions are described comprising an aqueous polymeric dispersion; a crosslinker; and an acid or salt of a polyalkylene oxide. Also described are articles comprising the dried and cured coating composition disposed on a substrate as well as a method a providing an anti-fog coating on a substrate.
    Type: Application
    Filed: November 1, 2012
    Publication date: April 30, 2015
    Inventors: Yongshang Lu, Naiyong Jing, Dang Xie, Zhigang Yu, Caroline M. Ylitalo, Mahfuza B. Ali, Alexander J. Kugel, Steven P. Swanson
  • Patent number: 9017818
    Abstract: The present invention relates to coating compositions comprising (A) at least one hydroxyl-containing polyacrylate and/or at least one hydroxyl-containing polymethacrylate and (B) at least one compound containing isocyanate groups and having at least one structural unit (I) of the formula (I) —NR—(X—SiR?x(OR?)3-x)??(I), and having at least one structural unit (II) of the formula (II) —N(X—SiR?x(OR?)3-x)n(X?—SiR?y(OR?)3-y)m??(II), where (i) (A) has a glass transition temperature of less than 10° C., (ii) (B) contains more than 10 to more than 90 mol %, of at least one structural unit of the formula (I) and 10 to less than 90 mol % of at least one structural (II), based on the entirety of the structural units (I) and (II), and (iii) 10 to 60 mol % of the isocyanate groups of the diisocyanate and/or polyisocyanate parent structure of (I) and (II). The invention provides multistage coating processes using these coating compositions.
    Type: Grant
    Filed: March 8, 2010
    Date of Patent: April 28, 2015
    Assignee: BASF Coatings GmbH
    Inventor: Matthijs Groenewolt
  • Patent number: 9017819
    Abstract: The disclosed method comprises applying a transparent coating composition to a plastics substrate, the composition comprising 30% to 60% by weight of a nanoparticles (B), 15% to 40% by weight, of urethane (meth)acrylates (A1) having 3 to 5 (meth)/acrylate groups per molecule, 0% to less than 10% by weight of urethane (meth)acrylates (A2) having more than 5 (meth)/acrylate groups per molecule, 0% to less than 10% by weight of urethane (meth)acrylates (A3) having less than 3 (meth)/acrylate groups per molecule, 55% to 80% by weight of compounds (C1) having 4 (meth)/acrylate groups per molecule, 0% to 15% by weight of compounds (C2) having 2 (meth)/acrylate groups per molecule, and 0% to 15% by weight of compounds (C3) having 3 (meth)/acrylate groups per molecule, the sum of the weight fractions of film-forming components (A1), (A2), (A3), (C1), (C2), and (C3) being in each case 100% by weight.
    Type: Grant
    Filed: October 2, 2010
    Date of Patent: April 28, 2015
    Assignee: BASF Coatings GmbH
    Inventors: Jan Bernd Kues, Andre Brosseit, Karin Homann, Stefanie Schroeder
  • Patent number: 9018304
    Abstract: An optical adhesive film prepared from an optical adhesive composition, an optical adhesive composition, and an apparatus, the optical adhesive composition including a urethane (meth)acrylate copolymer, a reactive monomer, and an initiator, wherein the optical adhesive film has a tensile strength of about 1 to about 70 gf/mm2 at a thickness of 500 ?m after curing.
    Type: Grant
    Filed: December 19, 2011
    Date of Patent: April 28, 2015
    Assignee: Cheil Industries, Inc.
    Inventors: Lee June Kim, Ji Hye Kwon, Kyoung Jin Ha, Kil Sung Lee
  • Publication number: 20150104226
    Abstract: A transfer assist member comprising a plurality of layers, one of the layers being a check film layer comprised of a crosslinked mixture of urea-glyoxal resins, and polyester polyols present on a support polymer layer.
    Type: Application
    Filed: October 16, 2013
    Publication date: April 16, 2015
    Applicant: XEROX CORPORATION
    Inventors: JIN WU, Kyle B. Tallman, Qi Ying Li, Alexander N. Klymachyov, Jonathan H. Herko
  • Publication number: 20150104652
    Abstract: A curable composition includes: a) at least one aliphatic polyisocyanate; b) at least one aliphatic polyamine; and c) from 8 to 17 percent by weight of at least one liquid compound, based on the total weight of components a), b) and c) combined. Each liquid compound is independently represented by the formula (I): wherein Z represents an n valent organic group, and n represents an integer ?1. Methods of coating the curable coating on a substrate and composite articles are also disclosed.
    Type: Application
    Filed: June 4, 2013
    Publication date: April 16, 2015
    Inventors: Alexander J. Kugel, Clinton L. Jones, Cori S. Apel, Ryan B. Prince
  • Patent number: 9006338
    Abstract: An aqueous resin composition with gas barrier properties contains (i) polyurethane resin having aurethane group and a urea group in a total concentration of 25 to 60% by weight and having a acid value of 5 to 100 mgKOH/g, (ii) a swelling inorganic layered compound (e.g., a water-swelling mica, and a montmorillonite), and (iii) a polyamine compound having an amine value of 100 to 1900 mgKOH/g. The polyurethane resin (i) is obtained by a reaction of (A) an aromatic, araliphatic or alicyclic polyisocyanate, (B) a polyhydroxyalkanecarboxylic acid, and at least one component selected from (C) a C2-8alkylene glycol and (D) a chain-extension agent (e.g., diamine, hydrazine and a hydrazine derivative), and neutralized with a neutralizing agent. The proportion of the acid group of the polyurethane resin (i) relative to the basic nitrogen atom of the polyamine compound (iii) is 10/1 to 1/5 as the equivalent ratio.
    Type: Grant
    Filed: October 7, 2004
    Date of Patent: April 14, 2015
    Assignees: Mitsui Takeda Chemicals, Inc., Futamura Kagaku Kabushiki Kaisha
    Inventors: Takashi Uchida, Tsutomu Tawa, Takuzo Imaizumi
  • Patent number: 9006304
    Abstract: The present invention relates to aqueous polyurethane-polyurea dispersions which stabilize a foam—produced by mechanical expansion—without addition of further foam-stabilizing components in such a way that aqueous foams are obtainable which are stable both during temporary storage and during processing, so that they can be applied in the form of foam also by customary application methods and substantially retain the foam structure even after drying.
    Type: Grant
    Filed: May 19, 2009
    Date of Patent: April 14, 2015
    Assignee: Stahl International B.V.
    Inventor: Juergen Muenter
  • Publication number: 20150099129
    Abstract: The present invention is directed to methods of improving burnish resistance of substrates comprising: (1) applying to at least a portion of the substrate a curable film-forming composition comprising: (a) a polymeric binder comprising at least one polymeric resin having reactive functional groups; (b) a curing agent containing functional groups that are reactive with the reactive functional groups of (a); and (c) silica particles that have been functionalized on their surfaces with an amino silane so as to impart the surfaces with primary amino functional groups; and (2) (a) heating the coated substrate to a temperature and for a time sufficient to cure the curable film-forming composition or (b) allowing a time sufficient to cure the curable film-forming composition under ambient conditions. The present invention is further directed to solventborne, curable film-forming compositions comprising the components (a) (b) and (c) above.
    Type: Application
    Filed: December 12, 2014
    Publication date: April 9, 2015
    Inventors: Scott J. Moravek, Shantilal Mohnot, Stephen John Thomas
  • Publication number: 20150099128
    Abstract: This invention relates to coating compositions comprising a linear glycidyl carbamate (GC) resin and a curing agent. The linear GC-resins were synthesized using linear and cycloaliphatic diisocyanates and a combination of diols and optional triols with glycidol. The combination of linear diisocyanates and diols introduces a more linear structure in the GC-resin compositions.
    Type: Application
    Filed: April 18, 2013
    Publication date: April 9, 2015
    Inventors: Umesh D. Harkal, Andrew J. Muehlberg, Dean C. Webster
  • Publication number: 20150097463
    Abstract: The stack of laminations consists of punched laminations (5), which are bonded together by an adhesive agent. The adhesive agent is composed of an adhesive (4) and an initiator (15), which consists of methacrylates, derivative imines and methacrylic esters. The completely cured adhesive bond has long-term resistance when exposed to a temperature of at least over 80° C. The adhesive (4) is applied over the full surface area and in a contacting manner to one side of the lamination (5) and the initiator (15) is applied to the same side and/or to the other side of the lamination (5). The initiator (15) reacts with the adhesive (4) when contact is made and establishes the adhesive connection between laminations (5) lying against one another. The adhesive agent may, however, also be an adhesive (4) that cures by itself when heat is applied.
    Type: Application
    Filed: March 13, 2013
    Publication date: April 9, 2015
    Inventors: Daniel Blocher, Steffen Bauer, Andras Bardos
  • Patent number: 9000089
    Abstract: Polyurea systems comprising: (a) an amino-functional aspartic ester of the general formula (I) wherein X represents an n-valent organic radical derived from a corresponding n-functional primary amine X(NH2)n, R1 and R2 each independently represent an organic radical having no Zerevitinov active hydrogens and n represents an integer of at least 2; and (b) an isocyanate functional prepolymer having a residual monomer content of less than 1% by weight, the prepolymer prepared by reacting: (b1) an aliphatic isocyante; and (b2) a polyol component having a number average molecular weight of ?400 g/mol and an average OH functionality of 2 to 6, wherein the polyol component comprises one or more constituents selected from the group consisting of polyester polyols, polyester-polyether polyols and mixtures thereof; processes for making the same; postoperative adhesions barriers prepared therewith and dispensing systems for such polyurea systems.
    Type: Grant
    Filed: February 13, 2009
    Date of Patent: April 7, 2015
    Assignee: Medical Adhesive Revolution GmbH
    Inventors: Heike Heckroth, Hartmut Nefzger, Christian Wamprecht
  • Patent number: 8993114
    Abstract: Provided is a hard coat film having high hardness and excellent restorability in view of the above circumstances. A hard coat film comprising: a light-transmitting substrate; and a hard coat layer, the hard coat layer comprising a cured product of a composition for a hard coat layer, the composition including an isocyanuric skeleton-containing urethane(meth)acrylate.
    Type: Grant
    Filed: December 16, 2011
    Date of Patent: March 31, 2015
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Kana Yamamoto, Toshiki Iwasaki, Masayuki Tsunekawa
  • Patent number: 8993673
    Abstract: An object of the present invention is to provide an aqueous coating composition with excellent finished appearance and removability in bell cleaning, and a method for forming a multilayer coating film having excellent smoothness by a 3-coat-1-bake method including successively applying an aqueous first colored coating composition, an aqueous second colored coating composition, and a clear coating composition to a substrate, and heat-curing the resulting three layers of the multilayer coating film all at once.
    Type: Grant
    Filed: February 9, 2010
    Date of Patent: March 31, 2015
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Hiroshi Kitagawa, Munehiro Nakata, Daisuke Takayama, Tatsuya Azuma
  • Patent number: 8993116
    Abstract: For imparting enhanced water-repellency and oil-repellency properties to substrates compositions comprising blends of (A) one or more ester oligomers and (B) one or more polycarbodiimides. Also methods for applying such compositions and articles treated with such compositions.
    Type: Grant
    Filed: June 6, 2008
    Date of Patent: March 31, 2015
    Assignee: 3M Innovative Properties Company
    Inventors: Chetan P. Jariwala, Cheryl L. S. Elsbernd, Thomas M. Butler
  • Publication number: 20150086734
    Abstract: The use of an aqueous Solution comprising at least one polyanion and at least one high molecular weight polyethyleneimine is described, for providing oxygen barrier properties to a polymer film. The polyanion is a polymer comprising acid groups neutralized with a base selected from the group consisting of inorganic bases and monovalent organic bases and having a weight average molecular weight of at least 10000 g/mol.
    Type: Application
    Filed: May 27, 2013
    Publication date: March 26, 2015
    Applicant: BASF SE
    Inventors: Ines Pietsch, Axel Weiss, Peter Preishuber-Pfluegl, Patrick Bippus, Klaus Huenerfauth
  • Publication number: 20150082976
    Abstract: Composite anti-ballistic systems having multiple nested sub-laminates manufactured from layers of unidirectional monofilaments made from engineering fibers with anti-ballistic properties embedded in polymer matrix materials and interfacial materials engineered for controlled compliance, deformation, energy release and rate sensitive behavior.
    Type: Application
    Filed: March 13, 2014
    Publication date: March 26, 2015
    Applicant: Cubic Tech Corporation
    Inventors: Heiner W. Meldner, Roland Joseph Downs
  • Patent number: 8987375
    Abstract: A moisture-curable polyurethane formulation is provided capable of curing to form a reaction product, having high green strength and being dispensable from a caulking gun. The polyurethane formulation comprises at least one isocyanate-terminated prepolymer, at least one rheology modifier or filler, optionally monomeric/polymeric isocyanate, and at least one urea-based thixotropic additive added to the formulation or formed in situ, to provide greater than 1% of urea groups in the reaction product. A method for making a moisture-curable polyurethane formulation capable of curing to form a reaction product and methods of bonding materials together using the formulation are also provided.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: March 24, 2015
    Assignee: Construction Research & Technology GmbH
    Inventors: Paula Bushendorf, John M. Davis, Michael Porsch
  • Patent number: 8986846
    Abstract: A thermosetting oligomer or thermosetting polymer is provided. The thermosetting oligomer or thermosetting polymer contains repeating units, each of which has at least one thermosetting functional group in the side chain and is represented by Formula 1: where repeating units include X1, A1, and Y1 subunits, sidechain units include linking unit L and thermosetting functional group Z, and n is an integer from 1 to 4. The thermosetting oligomer or thermosetting polymer has a low coefficient of thermal expansion and high or no glass transition temperature, stiffness, processability, heat resistance and mechanical properties. The thermosetting oligomer or thermosetting polymer is highly soluble, wettable and dimensionally stable and is suitable for use in films, prepregs and printed circuit boards. Further provided are a thermosetting resin composition including the thermosetting oligomer or thermosetting polymer and a printed circuit board using the composition.
    Type: Grant
    Filed: June 23, 2009
    Date of Patent: March 24, 2015
    Assignee: Samsung Electro-Mechanics Co., Ltd.
    Inventors: Jae Jun Lee, Mahn Jong Kim, Kwang Hee Kim
  • Publication number: 20150079406
    Abstract: There is described a process for preparing a Schiff base crosslinkable aqueous dispersion of a polyurethane A (PUD) the process comprising (a) reacting components (1) to (4) as present to form an acidic isocyanate terminated prepolymer that comprises anionic or potentially anionic functional groups thereon; where: (1) component one comprises 10 to 80% by weight of at least one polyisocyanate optionally containing at least one anionic or potentially anionic dispersing group; (2) optional component two comprises up to 15% by weight of at least one isocyanate-reactive polyol containing at least one anionic or potentially anionic dispersing group; (3) component three comprises 15 to 85% by weight of at least one isocyanate reactive polyol other than component two if present, and having a weight average molecular weight greater than or equal to 500 Daltons optionally containing at least one anionic or potentially anionic dispersing group; and (4) optional component four comprises up to 20% by weight of at least on
    Type: Application
    Filed: April 10, 2013
    Publication date: March 19, 2015
    Inventors: Ronald Tennebroek, Roel Johannes Marinus Swaans, Paul De Kok
  • Publication number: 20150079308
    Abstract: Disclosed is a coating composition and coated film having the coating composition adhered thereto in which the coating composition comprises particulate filler; binder composition comprising acrylic polymer and ethylene acrylic acid copolymers; non-cross-linking adhesion promoter; and optionally urethane polymer, styrene-acrylic copolymer, or a combination thereof; and wherein cross-linker(s) are substantially absent from the composition; and wherein the coated film has a 45° Gloss (ASTM D2457) of less than 30 or 25 or 20 or 15. The coated film is useful for pressure sensitive labels for thermal transfer ribbon printing labels.
    Type: Application
    Filed: October 28, 2014
    Publication date: March 19, 2015
    Applicant: Jindal Films Americas LLC
    Inventors: Bruno R. Gringoire, David A. Liestman
  • Patent number: 8981151
    Abstract: Fluorocarbon- and urethane-(meth)acryl-containing additives and hardcoats. The hardcoats are particularly useful as a surface layer on an optical device.
    Type: Grant
    Filed: April 8, 2014
    Date of Patent: March 17, 2015
    Assignee: 3M Innovative Properties Company
    Inventors: Thomas P. Klun, Naiyong Jing, Richard J. Pokorny, Zai-Ming Qiu, Mark J. Pellerite, William D. Coggio, Christopher B. Walker, Jr.
  • Patent number: 8980430
    Abstract: Multilayer fluoropolymer-containing films having improved interlayer adhesion. More particularly, multilayer films including a fluoropolymer layer attached to a thermoplastic polymer layer via an intermediate poly(ester-urethane) copolymer containing adhesive layer, articles produced therefrom, and products which are encased by the multilayer films. The films are suitable for encasing the sensitive luminescent components of electroluminescent lamps.
    Type: Grant
    Filed: August 28, 2006
    Date of Patent: March 17, 2015
    Inventors: Frank J. Colombo, Yuan-Ping R. Ting
  • Patent number: 8980431
    Abstract: A primer coating composition is provided for an optical article capable of forming a coating layer having excellent impact resistance, abrasion resistance, adhesion and high refractive index to an optical base material, having high refractive index, specifically a plastic lens without occurrence of poor appearance such as ununiformity, cloudiness, etc. and regardless of the materials of the plastic lens. A primer composition for an optical article may comprises urethane resin having a polycarbonate-derived skeleton, polyester resin, inorganic oxide fine particles and water, and water-soluble organic solvent, if necessary.
    Type: Grant
    Filed: September 9, 2011
    Date of Patent: March 17, 2015
    Assignee: Tokuyama Corporation
    Inventors: Katsuhiro Mori, Shunichiro Nakatsukasa
  • Publication number: 20150072152
    Abstract: A coating composition comprises high oleic oil, wherein the high oleic oil comprises C18:1 fatty acids in a range of from about 60% to 100% of the fatty acid moieties in the high oleic oil and a combination of C18:2 and C18:3 fatty acids in a range of from 0% to about 10% of the fatty acid moieties in the high oleic oil, percentage based on the total fatty acid moieties in the high oleic oil. The disclosure is further directed to a coating composition comprising the high oleic oil produced from bio-resources, such as soybeans. The coating composition can have low VOC (volatile organic compounds) and can produce a coating layer having good hardness, better appearance and improved adhesion. The coating composition can be used for coating vehicles, appliances, machinery, tools, or other industrial or consumer articles.
    Type: Application
    Filed: January 29, 2013
    Publication date: March 12, 2015
    Applicant: AXALTA COATING SYSTEMS IP CO., LLC
    Inventors: Ayumu Yokoyama, Hari Babu Sunkara, Rajesh Gopalan Saliya, Ross Sydney Morgan, Kenneth A. McDiarmid
  • Publication number: 20150072153
    Abstract: The use of an aqueous polyurethane dispersion adhesive is described for producing biodisintegratable composite foils where at least two substrates are adhesive-bonded to one another with use of the polyurethane dispersion adhesive, where at least one of the substrates is a biodisintegrable polymer foil. At least 60% by weight of the polyurethane is composed of diisocyanates, polyesterdiols, and at least one bifunctional carboxylic acid selected from dihydroxycarboxylic acids and diaminocarboxylic acids.
    Type: Application
    Filed: November 13, 2014
    Publication date: March 12, 2015
    Applicant: BASF SE
    Inventors: Cornelis Petrus BEYERS, Heiko DIEHL, Stefan DAHMEN, Volker KRIEGISCH, Ulrike LICHT, Axel MEYER, Motonori YAMAMOTO
  • Patent number: 8974911
    Abstract: The invention relates to a process for applying a fire-protection coating to a substrate using a process comprising the steps of applying a first clearcoat layer to the substrate, applying an intumescent fire-protection layer to the first clearcoat layer, and applying a second clearcoat layer to the intumescent fire-protection layer.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: March 10, 2015
    Assignee: Lufthansa Technick AG
    Inventor: Mathias Nolte
  • Patent number: 8974876
    Abstract: Disclosed is a printable paper comprising a water-resistant support having two optionally subbed sides and a single layer on at least one of said optionally subbed sides, wherein said single layer has no substantial compositional variation, has a layer thickness of at least 3 ?m, a pore volume of at least 1.2 mL/m2 and comprises at least one porous pigment. Also disclosed is a process for producing such a printable paper and use thereof in printing.
    Type: Grant
    Filed: August 29, 2012
    Date of Patent: March 10, 2015
    Assignee: Agfa-Gevaert
    Inventors: Dirk Quintens, Dirk Franky Kokkelenberg
  • Publication number: 20150064460
    Abstract: A carrier film for transparent conductive films of the invention includes a support and a pressure-sensitive adhesive layer provided on at least one side of the support, wherein the pressure-sensitive adhesive layer is made from a pressure-sensitive adhesive composition including: a (meth)acryl-based polymer (A) having a glass transition temperature of ?50° C. or lower and obtained by polymerization of a monomer component containing an alkyl(meth)acrylate and a hydroxyl group-containing monomer; an isocyanate crosslinking agent (B); and a catalyst (C) having an iron active center. The carrier film for transparent conductive films, with which the formation of irregularities on an adherend surface and zipping can be prevented.
    Type: Application
    Filed: August 20, 2014
    Publication date: March 5, 2015
    Applicant: NITTO DENKO CORPORATION
    Inventors: Masamichi MATSUMOTO, Tatsumi AMANO, Toru ISEKI, Hiromoto HARUTA