Refractory Metal Salt Or Oxide Patents (Class 428/472)
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Patent number: 7118807Abstract: The subject of the invention is the use of MoO3 as a corrosion inhibitor, and an anti-corrosion coating composition for metal parts, characterized in that it comprises:—at least one particulate metal;—an organic solvent;—a thickener;—a silane-based binder, preferably carrying epoxy functional groups;—molybdenum oxide (MoO3);—possibly a silicate of sodium, potassium or lithium, and;—water.Type: GrantFiled: December 20, 2005Date of Patent: October 10, 2006Assignee: Dacral, S.A.Inventors: Etienne Maze, Carmen Mocquery, Benoit Millet, Antonio Francisco Iandoli Espinosa
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Patent number: 7101810Abstract: Transparent articles comprising transparent, nonmetallic substrate and a transparent film stack is sputter deposited on the substrate. The film stack is characterized by including at least one infrared reflective metal film, a dielectric film over the metal film, and a protective silicon nitride film of 10 ? to 150 ? in thickness over the said dielectric film. The dielectric film desirably has substantially the same index of refraction as does silicon nitride and is contiguous with the silicon nitride film.Type: GrantFiled: April 7, 2005Date of Patent: September 5, 2006Assignee: Cardinal CG CompanyInventors: Robert Bond, Roger P. Stanek, Wayne L. Hoffman
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Patent number: 7097901Abstract: The present invention relates to a coated cemented carbide cutting tool insert particularly useful for turning of cast irons but also low alloyed steels at mediate to high cutting speeds. The cutting tool insert is characterised by a cemented carbide body comprising WC, cubic carbonitrides, a W-alloyed Co binder phase, a surface zone of the cemented carbide body that is binder phase enriched and nearly free of cubic carbonitride phase, and a coating including an innermost layer of TiCxNyOz with equiaxed grains, a layer of TiCxNyOz with columnar grains and at least one layer of Al2O3.Type: GrantFiled: February 19, 2004Date of Patent: August 29, 2006Assignee: Seco Tools ABInventors: Andreas Larsson, Jenni Zackrisson
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Patent number: 7087295Abstract: A coated cutting tool can suppress film spalling due to adhesion. The tool has on its substrate an inner layer, intermediate layer, and outer layer. The inner layer is composed of at least one material selected from the group consisting of the carbide, nitride, carbonitride, boride, boronitride, borocarbonitride, oxide, oxycarbide, oxynitride, and oxycarbonitride of the elements belonging to the IVa, Va, and VIa groups. The inner layer includes at least one layer having a columnar-crystal structure. The outer layer is composed of at least one oxide selected from the group consisting of aluminum oxide, zirconium oxide, hafnium oxide, and their solid solutions. The intermediate layer is composed of titanium boronitride, TiBxNy (x, y: atomic %), that satisfies 0.001<x/(x+y)<0.04. The intermediate layer has an average thickness of 0.1 to 1 ?m and a surface roughness of 50 to 500 nm expressed by the vertical distance between the peak and valley lines within a reference length of 1 ?m.Type: GrantFiled: January 14, 2003Date of Patent: August 8, 2006Assignee: Sumitomo Electric Industries, Ltd.Inventors: Yoshio Okada, Hideki Moriguchi
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Patent number: 7077895Abstract: The present invention provides a coating composition for forming a titanium oxide film, comprising (A) a specific titanium-containing aqueous liquid and (B) at least one compound selected from the group consisting of organic acids and their salts. The present invention also provides a process for forming a titanium oxide film using the coating composition, and a metal substrate coated therewith.Type: GrantFiled: October 17, 2002Date of Patent: July 18, 2006Assignee: Kansai Paint Co., Ltd.Inventors: Jun Akui, Akinori Nagai, Yasuhiko Haruta, Osamu Isozaki
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Patent number: 7067447Abstract: A material (100) formed of a sintered aggregation of ceria particles (106), mullite particles (108) and an alumina matrix material (110). Differential thermal expansion of the ceria and mullite particles generates thermal stress sufficient to create micro-cracking of the ceria particles. The ratio of ceria to mullite may be selected to achieve a desired coefficient of thermal expansion for matching the thermal growth of a mating CMC material (102). The micro cracks provide the material with a desired degree of strain tolerance useful in high temperature applications such as a solid core gas turbine vane (20).Type: GrantFiled: September 4, 2003Date of Patent: June 27, 2006Assignee: Siemens Power Generation, Inc.Inventor: Christian X. Campbell
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Patent number: 7063889Abstract: [Problem] The object is to provide a resin film for metal sheet laminate which endures severe forming owing to excellent formability and impact resistance, and also to excellent adhesion after forming and heating, further gives stable performance independent of forming conditions, and also provides a laminated metal sheet, and a method for manufacturing the same. [Means for Resolution] The resin film for metal sheet laminate has a mixed resin in which a granular resin mainly existing in a state of grains having 0.1 to 5 ?m in diameter is dispersed in a polyester resin having a main basic skeleton of polyethylene terephthalate and/or isophthalic acid copolymerized polyethylene terephthalate, in a range from 3 to 30% by weight in entire resin. The granular resin is a modified polyolefin resin containing a functional group derived from carboxylic acid in a range from 2 to 20% by weight as carboxylic acid.Type: GrantFiled: September 18, 2003Date of Patent: June 20, 2006Assignee: JFE Steel CorporationInventors: Yasuhide Yoshida, Hiroki Iwasa, Hiroshi Kubo, Takeshi Suzuki, Akihiko Furuta, Keiji Sugawara, Masaaki Yamashita
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Patent number: 7060345Abstract: Coating-film furnished coated tools that are lubricative while maintaining resistance to wear are realized by coated tools in which a plurality of coating films is furnished on a base part. Furnished as the coating are one or more layers of, respectively: a first film composed of one compound selected from nitrides, carbides, carbonitrides, oxynitrides and carboxynitrides of TiSi; and a second film composed of one compound selected from nitrides, carbides, carbonitrides, oxynitrides and carboxynitrides of one metal M selected from Ti, Cr, and TiCr. The first film and the second film are laminated in alternation.Type: GrantFiled: June 17, 2003Date of Patent: June 13, 2006Assignee: Sumitomo Electric Industries, Ltd.Inventors: Haruyo Fukui, Kazuo Yamagata, Keiichi Tsuda, Shinya Imamura
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Patent number: 7056587Abstract: A low-reflective thin-film substrate comprising a transparent glass substrate having formed by sputtering a thin film in multilayer containing no chromium series component and made up of at least one kind of Ni, Fe, Co, Mo, W, Ta, Cu, and Nb as a main constituent form or as an alloy thereof, the thin film having a minimum reflectivity of 0.5% or lower and the optical density of at least 4 or having a minimum reflectivity of 0.1% or lower, a maximum reflectivity of 2.0% or lower, an average reflectivity of 0.3% or lower, and an optical density of at least 4.0, in the visible light region. The low-reflective thin-film substrate is useful as a black matrix for a color filter substrate of a liquid crystal panel, etc., and is free from an environmental pollution caused by the use of a chromium component as the target material.Type: GrantFiled: March 24, 2004Date of Patent: June 6, 2006Assignee: Kuramoto Seisakusho Co., Ltd.Inventor: Tadakatsu Suzuki
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Patent number: 7037596Abstract: This invention relates to a catalytic composition which comprises a coating of a coating material on a support and is obtainable by applying the coating material, comprising (1) a polycondensate of at least one hydrolysable organosilane and also, if desired, one or more compounds of glass-forming elements, and (2) particles of one or more transition metal oxides, the weight ratio of transition metal oxide particles to polycondensate being from 10:1 to 1:10, to the support and subjecting the applied coating material to thermal treatment. The invention also relates to a process for preparing this catalytic composition and to its use for the purpose of deodorizing or oxidizing organic components or carbon.Type: GrantFiled: April 5, 2000Date of Patent: May 2, 2006Assignee: Leibniz-Institut Fuer Neue Materialien Gemeinnuetzige GmbHInventors: Thomas Benthien, Stefan Faber, Gerhard Jonschker, Stefan Sepeur, Helmut Schmidt, Philipp Stoessel
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Patent number: 7037577Abstract: A transparent substrate particularly of glass, provided with a stack of thin layers having at least one metallic layer (4) having properties in the infrared range particularly having low emissivity and two coatings having a base of dielectric material located one (8) under and the other (9) over the layer having properties in the infrared range, as well as a protective metallic layer (5) place immediately over an in contact with the layer having properties in the infrared range, characterized in that in order to prevent the modification of properties of the stack, particularly optical and thermal properties, in the case where the substrate is submitted to a thermal treatment of the tempering or bending kind, firstly the second coating (9) having a base of dielectric material, includes a barrier layer for the diffusion of oxygen chosen from the following materials: components of silicon SiO2, SiOxCy, SiONNy, nitrates such as Si3N4 or AlN, carbides such as SiC, TiC, CrC, TaC of a thickness of at least 10 nanomeType: GrantFiled: June 30, 2004Date of Patent: May 2, 2006Assignee: Saint-Gobain Glass FranceInventors: Philippe Macquart, Olivier Guiselin, Veronique Rondeau
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Patent number: 7037390Abstract: A method of heat treatment for an efficient forming of two-layered oxide film on the inside surface of a Ni-base alloy tube. The oxide film suppresses the Ni release in a high-temperature water environment. At least two gas supplying devices are provided on the outlet side of a continuous heat treatment furnace; or one gas supplying device is provided respectively on the outlet side and the inlet side thereof. The tube is put into the furnace while supplying an atmospheric gas into the tube from the front end of the tube moving direction with one of these gas supplying devices and a gas introducing pipe, which is arranged inside the furnace, and this tube is maintained at 650 to 1200° C. for 1 to 1200 minutes. The atmospheric gas consists of hydrogen or a mixture of hydrogen and argon, whose dew point is in a range of from ?60° C. to +20° C.Type: GrantFiled: October 9, 2003Date of Patent: May 2, 2006Assignee: Sumitomo Metal Industries, Ltd.Inventors: Osamu Miyahara, Toshihiro Imoto, Hiroyuki Anada, Kazuyuki Kitamura
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Patent number: 7033682Abstract: Advanced machine tool coatings for Ti machining are presented. The coatings of the present invention provide for protection from chemical reactivity and higher cutting temperatures. In accordance with one embodiment of the present invention, a coated machine tool is provided including a relatively hard underlayer and a chemically inert overlayer. The relatively hard underlayer is formed over the base material of the machine tool. The overlayer is formed over the underlayer, is chemically inert with respect to titanium, and comprises an oxide of yttrium or another metal oxide. In accordance with another embodiment of the present invention, a coated machine tool is provided including an alkaline earth metal fluoride overlayer that is substantially chemically inert with respect to titanium. The overlayer includes a metal intermixed with the metal fluoride. The intermixed metal is softer than the base material.Type: GrantFiled: December 28, 2001Date of Patent: April 25, 2006Assignee: UES, Inc.Inventors: Amarendra K. Rai, Satish J. Dixit, Rabi S. Bhattacharya
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Patent number: 7022403Abstract: The inventive coating for diamond and diamond-containing materials represents a coupling of an internal layer, made of tungsten carbide, with an external tungsten layer, both layers being fluorine alloyed. The inventive coating makes it possible to ensure a good adhesion of diamonds and diamond-containing materials to a backing. Methods for applying said coatings are also disclosed.Type: GrantFiled: March 15, 2000Date of Patent: April 4, 2006Assignee: Hardide LimitedInventors: Jury V. Lakhotkin, Vladimir P. Kuzmin
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Patent number: 7018706Abstract: Disclosed is a static-proof tile utilizing carbon. The static-proof tile comprises: a tile substrate made from synthetic resin; a color-printed film made from synthetic resin and attached to an upper surface of the tile substrate; a transparent film made from synthetic resin and attached to an upper surface of the color-printed film; and a carbon film disposed between the tile substrate and the color-printed film, the carbon film having a thickness smaller than that of the tile substrate. The static-proof tile has a high surface stiffness, can prevent the carbon from being detached from a surface thereof, has a uniform static-proof effect, can be manufactured at a small cost, and can shield electromagnetic waves and water vein waves.Type: GrantFiled: May 13, 2003Date of Patent: March 28, 2006Inventor: Moon Soo Lee
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Patent number: 7011895Abstract: The present invention is intended to provide an inorganic-organic composite-treated zinc-plated steel sheet whose treated coatings do not contain any hazardous chromate and which is excellent in corrosion resistance after alkaline degreasing and coating adhesion. An inorganic-organic composite-treated zinc-plated steel sheet which has a zinc phosphate coating, in a coating weight of 0.3 to 5 g/m2, on the zinc-plated steel sheet surface and, thereon, a post-treatment coating, in a coating weight of 0.01 to 1 g/m2, containing an organic resin (A), a zirconium compound (B), an inorganic corrosion inhibitor (C) and an organic corrosion inhibitor (D).Type: GrantFiled: June 24, 2004Date of Patent: March 14, 2006Assignee: Nippon Steel CorporationInventors: Kiyokazu Ishizuka, Hidetoshi Shindo, Koichi Saito, Motohiro Sasaki, Atsuhiko Tounaka
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Patent number: 7005189Abstract: A laminate having improved visible light transmittance and abrasion resistance, which comprises a substrate, and a titanium oxide layer, a metal layer and a titanium oxide layer laminated alternately in this order on the substrate in (2n+1) layers (wherein n is a positive integer), wherein an interlayer having a refractive index of less than 2.4 at a wavelength of 550 nm is interposed at at least one interlaminar boundary between the titanium oxide layer and the metal layer.Type: GrantFiled: December 27, 1999Date of Patent: February 28, 2006Assignee: Asahi Glass Company, LimitedInventors: Yuko Tachibana, Hisashi Ohsaki
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Patent number: 7004975Abstract: Joint endoprostheses are provides which respectively have a joint part with a metallic core, wherein the metallic core is coated, in regions that roll and/or slide on another joint part during execution of the joint function, with a glass-ceramic composite mixture. In one embodiment, the glass-ceramic has the following composition with approximate amounts in wt. %: Component Amount (wt %) SiO2 45–50% Al2O3 15–20% ZrO2 ?8–12% K2O 0–8% Na2O ??0–7.5% CaO ??0–2.5% TiO2 ??0–1.5% and furthermore a residual amount of up to about 12.5% of MnO2 and/or Fe2O3 and/or Co2O3.Type: GrantFiled: November 5, 2004Date of Patent: February 28, 2006Assignee: ESKA Implants GmbH & Co.Inventor: Hans Grundei
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Patent number: 7001675Abstract: There is disclosed a method of depositing a nanocomposite coating of stainless steel and a metallic carbide or metallic nitride, e.g. chromium carbide or chromium nitride, onto a stainless steel substrate 10, including the steps of (a) providing the stainless steel substrate 10; (b) depositing stainless steel on the substrate 10; (c) depositing chromium carbide or chromium nitride on the substrate 10; and allowing a nanocomposite coating 14 of the stainless steel and chromium carbide or chromium nitride to form on the substrate 10.Type: GrantFiled: June 4, 2003Date of Patent: February 21, 2006Assignee: Winsky Technology Ltd.Inventor: Winston Siu Yeung Chan
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Patent number: 6998173Abstract: A coated cemented carbide tool, and a method for making the same, wherein the as-sintered substrate is formed by sintering in an atmosphere having at least a partial pressure and for a part of the time a nitrogen partial pressure.Type: GrantFiled: November 13, 2002Date of Patent: February 14, 2006Assignee: Kennametal Inc.Inventors: Yixiong Liu, Donald A. Botbyl, George P. Grab, Mark S. Greenfield
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Patent number: 6984454Abstract: A tough wear-resistant hard member that includes a hard composite member and a support that has a surface area adjacent to the hard composite member wherein the hard composite member is affixed to the support over at least a portion of the adjacent surface area of the support. The hard composite member includes a plurality of discrete hard constituents distributed in the hard composite member wherein each one of the discrete hard constituents is of a size so as to have a surface area between about 0.001 square inches and about 16 square inches. The hard composite member further contains a matrix powder that includes particles wherein substantially all of the hard particles have a size smaller than the size of the hard constituents.Type: GrantFiled: June 4, 2003Date of Patent: January 10, 2006Assignee: Kennametal Inc.Inventor: Shivanand I. Majagi
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Patent number: 6982120Abstract: The invention relates to components made of steel, more particularly outer joint parts and inner joint parts of constant velocity joints, and to a process of heat treating such components made of steel. The heat treatment operation includes the process stages of nitriding, induction surface layer hardening and tempering, which processes follow one another. As a result of the nitriding operation, the joint parts are provided with a surface layer (15) including nitrides and a diffusion layer (18) positioned thereunderneath. The subsequent induction hardening process causes the diffusion layer (18) to be hardened, so that it comprises good supporting characteristics for supporting the surface layer (15) positioned above same.Type: GrantFiled: July 20, 2002Date of Patent: January 3, 2006Assignee: GKN Driveline Duetschland GmbHInventor: Manfred Schuster
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Patent number: 6974629Abstract: A coated article (e.g., a coated glass article) is provided with a low-emissivity, water-sheeting coating. The coating comprises a sputtered silica layer over a pyrolytically-applied dielectric layer. In certain embodiments, an automobile windscreen is provided with a low-emissivity, water-sheeting coating. Also provided are methods of rendering a surface of a substrate (e.g., a pane of glass) resistant to soiling and staining, such as by depositing on the substrate a low-emissivity, water-sheeting coating.Type: GrantFiled: August 6, 1999Date of Patent: December 13, 2005Assignee: Cardinal CG CompanyInventors: Annette J. Krisko, Bob Bond, Roger Stanek, Gary Pfaff, Klaus Hartig
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Patent number: 6953539Abstract: A composite material includes an SiC porous ceramic sintered body, which is formed by preliminarily sintering a porous body, having a coefficient of thermal expansion lower than the coefficient of thermal expansion of copper to construct a network therein. A copper alloy impregnating the porous ceramic sintered body includes copper and one or more additive elements which are prepared to impart a coefficient of thermal conductivity of 160 W/mK or higher to the composite material. The additive elements include up to 5% of at least one element selected from Be, Al, Si, Mg, Ti, Ni, Bi, Te, Zn, Pb, Sn, and mish metal, and also contain unavoidable impurities and gas components.Type: GrantFiled: September 18, 2002Date of Patent: October 11, 2005Assignee: NGK Insulators, Ltd.Inventors: Shuhei Ishikawa, Tsutomu Mitsui, Ken Suzuki, Nobuaki Nakayama, Hiroyuki Takeuchi, Seiji Yasui
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Patent number: 6942917Abstract: Transparent articles comprising transparent, nonmetallic substrate and a transparent film stack is sputter deposited on the substrate. The film stack is characterized by including at least one infrared reflective metal film, a dielectric film over the metal film, and a protective silicon nitride film of 10 ? to 150 ? in thickness over the said dielectric film. The dielectric film desirably has substantially the same index of refraction as does silicon nitride and is contiguous with the silicon nitride film.Type: GrantFiled: November 28, 2003Date of Patent: September 13, 2005Assignee: Cardinal CG CompanyInventors: Robert Bond, Roger P. Stanek, Wayne Hoffman
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Patent number: 6942935Abstract: A foodware article having a thermally stable color, tarnish-resistant ceramic coating that enables direct contact with a heat source, such as a gas flame or the heating element of an electric stove. The foodware article of the present invention includes a metal foodware article having an inner food-contacting surface and an outer heat source-contacting surface, a bonding layer deposited on a portion of the outer heat source-contacting surface, and a first ceramic layer deposited adjacent to a portion of the bonding layer, the first ceramic layer selected from (Ti,Al)N, (Ti,Al)CN, (Ti,Al,X)N, or (Ti,Al,X)CN. A top layer of TiCN can be deposited adjacent to the first ceramic layer. There may optionally be alternating layers of a third ceramic selected from (Ti,Al)N, (Ti,Al)CN, (Ti,Al,X)N, or (Ti,Al,X)CN and a fourth ceramic selected from TiN, TiCN, XN or XCN deposited adjacent to the bonding layer and below the first ceramic layer. The alternating layers can be repeated as many times as desired.Type: GrantFiled: March 24, 2003Date of Patent: September 13, 2005Assignee: National Material IPInventor: Molly Mo Hui Ge
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Patent number: 6936347Abstract: A coated article that can be used in applications such as insulating glass (IG) units, so that resulting IG units can achieve high visible transmission of at least 70% (e.g., when using clear glass substrates from 1.0 to 3.5 mm thick), combined with at least one of: (a) SHGC no greater than about 0.45, more preferably no greater than about 0.40; (b) SC no greater than about 0.49, more preferably no greater than about 0.46; (c) chemical and/or mechanical durability; (d) neutral transmissive color such that transmissive a* is from ?5.0 to 0 (more preferably from ?3.5 to ?1.5), and transmissive b* is from ?2.0 to 4.0 (more preferably from 1.0 to 3.0); and (e) neutral reflective color from the exterior of the IG unit (i.e., Rg/Rout) such that reflective a* is from ?3.0 to 2.0 (more preferably from ?2.0 to 0.5), and reflective b* is from ?5.0 to 1.0 (more preferably from ?4.0 to ?1.0).Type: GrantFiled: October 17, 2001Date of Patent: August 30, 2005Assignees: Guardian Industries Corp., Centre Luxembourgeois de Recherches pour le Verre et la Ceramique S.A. (C.R.V.C.)Inventors: Carole Laird, Uwe Kriltz, Ronald E. Laird
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Patent number: 6933053Abstract: In accordance with one aspect of the present invention, a process for forming a specific reactive element barrier on a titanium and aluminum containing substrate is provided. The process includes creating a dry air atmosphere with a concentration of water vapor below about 750 ppm at a temperature above about 550° C. contiguous to a surface of the substrate on which the barrier layer is to be formed. The temperature is maintained above 550° C. and the water vapor concentration is maintained below about 100 ppm while the water vapor in the dry air atmosphere is reacted with specific reactive elements at the substrate surface. The reaction forms a specific reactive element oxide barrier layer which is strongly bonded to the substrate surface. The barrier layer includes an aluminum oxide layer at the substrate/barrier layer interface and a second oxide layer at a barrier layer/atmosphere interface.Type: GrantFiled: March 18, 2003Date of Patent: August 23, 2005Inventor: Donald L. Alger
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Patent number: 6933041Abstract: A method for increasing the surface area of foil electrodes of electrolytic capacitors. A valve metal is deposited by evaporation on a valve metal foil in a low pressure inert atmosphere including oxygen at a pressure one to two orders of magnitude lower than the pressure of the inert gas. The resulting surface is fractal-like. The foil thus treated is suitable as such for use as a cathode. Prior to anodization to produce an anode, a discontinuous layer of a valve metal oxide is deposited on the foil, to preserve the high surface area of the fractal-like surface and otherwise promote the formation of a dielectric coating whose interface with the metal foil has a high surface area.Type: GrantFiled: June 28, 2001Date of Patent: August 23, 2005Assignee: Acktar Ltd.Inventors: Dina Katsir, Iris Tartakovsky, Israel Tartakovsky
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Patent number: 6933531Abstract: Graphite is placed in a case, and the case is set in a furnace. The interior of the furnace is subjected to sintering to produce a porous sintered member of graphite. After that, the case with the porous sintered member therein is taken out of the furnace, and is set in a recess of a press machine. Subsequently, molten metal of metal is poured into the case, and then a punch is inserted into the recess to forcibly press the molten metal in the case downwardly. Open pores of the porous sintered member are infiltrated with the molten metal of the metal by the pressing treatment with the punch.Type: GrantFiled: December 22, 2000Date of Patent: August 23, 2005Assignee: NGK Insulators, Ltd.Inventors: Shuhei Ishikawa, Tsutomu Mitsui, Ken Suzuki, Nobuaki Nakayama, Hiroyuki Takeuchi, Seiji Yasui
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Patent number: 6933052Abstract: A turbine engine component comprising a substrate made of a nickel-base or cobalt-base superalloy, a non-metallic oxide or nitride diffusion barrier layer overlying the substrate, and a protective coating overlying the barrier layer, the protective coating comprising at least one platinum group metal selected from the group consisting of platinum, palladium, rhodium, ruthenium and iridium. The diffusion barrier layer may be a deposited or thermally grown oxide material, especially aluminum oxide. The protective coating may be heat treated to increase homogeneity of the coating and adherence with the substrate. The component typically further comprises a ceramic thermal barrier coating overlying the protective coating. Also disclosed are methods for forming a protective coating system on the turbine engine component by forming the non-metallic oxide or nitride diffusion barrier layer on the substrate and then depositing the platinum group metal on top of the barrier layer.Type: GrantFiled: October 8, 2003Date of Patent: August 23, 2005Assignee: General Electric CompanyInventors: Mark Daniel Gorman, Bangalore Aswatha Nagaraj, Ramgopal Darolia
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Patent number: 6929851Abstract: Method for removing a portion of the binder phase from the surface of a substrate that is composed of particles of at least a first phase joined together by the binder phase, and wherein the surface is etched by contacting it with a gas flow of an etchant gas and a second gas. The second gas is one or more gases that will not react with the substrate or the removed binder phase and will not alter the oxidation state of the substrate during etching.Type: GrantFiled: July 28, 2000Date of Patent: August 16, 2005Assignee: TDY Industries, Inc.Inventors: Roy V. Leverenz, John Bost
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Patent number: 6926966Abstract: A functional film, which has photo-catalytic effects, is overlaid on a surface of each of at least two substrate materials. The functional film, which has been overlaid on the surface of each of the substrate materials, is exposed to light having a wavelength falling within an absorption wavelength range of the functional film. The substrate materials are then bonded to each other with the functional films, which have been exposed to the light, intervening between the substrate materials. The functional film may be a film containing TiO2, and the light irradiated to the functional film may be ultraviolet light. In cases where a film other than the functional film is also overlaid on the surface of each of the substrate materials, the functional film is formed as a top layer.Type: GrantFiled: March 4, 2003Date of Patent: August 9, 2005Assignee: Fuji Photo Film Co., Ltd.Inventor: Akinori Harada
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Patent number: 6924040Abstract: A ceramic material has particular utility as a thermal insulating or thermal barrier coating on metallic substrates. The ceramic material includes gadolinia and hafnia, preferably forming gadolinia-hafnia. This material exhibits chemical stability, thermal stability and thermal insulating properties superior to those of currently used thermal barrier ceramics, and also provides resistance to sintering and erosion comparable to currently used ceramics. A preferred material has between about 3-70 mol. % hafnia, balance hafnia.Type: GrantFiled: December 21, 2001Date of Patent: August 2, 2005Assignee: United Technologies CorporationInventor: Michael J. Maloney
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Patent number: 6919536Abstract: A window includes an ice removal structure thereon for weakening the adhesion strength of ice to the window upon an application of voltage. The ice removal structure is at least partially covered and/or coated with a layer of diamond-like carbon (DLC) in certain embodiments. In certain embodiments, the DLC may be of a type known as ta-C which can be very dense and have a large number of sp3 carbon-carbon bonds. The DLC protects the ice removal structure, and in certain instances can act as a semiconductor in order to aid ice removal. In other embodiments, the ice removal structure may include first and second substantially transparent electrodes sandwiching an anodized layer with columnar structure therebetween.Type: GrantFiled: April 5, 2002Date of Patent: July 19, 2005Assignee: Guardian Industries Corp.Inventors: Vijayen S. Veerasamy, Scott V. Thomsen
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Patent number: 6916408Abstract: A coated article that can be used in applications such as insulating glass (IG) units, so that resulting IG units can achieve high visible transmission of at least 70% (e.g., when using clear glass substrates from 1.0 to 3.5 mm thick), combined with at least one of: (a) SHGC no greater than about 0.45, more preferably no greater than about 0.40; (b) SC no greater than about 0.49, more preferably no greater than about 0.46; (c) chemical and/or mechanical durability; (d) neutral transmissive color such that transmissive a* is from ?5.0 to 0 (more preferably from ?3.5 to ?1.5), and transmissive b* is from ?2.0 to 4.0 (more preferably from 1.0 to 3.0); and (e) neutral reflective color from the exterior of the IG unit (i.e., Rg/Rout) such that reflective a* is from ?3.0 to 2.0 (more preferably from ?2.0 to 0.5), and reflective b* is from ?5.0 to 1.0 (more preferably from ?4.0 to ?1.0).Type: GrantFiled: August 20, 2004Date of Patent: July 12, 2005Assignees: Guardian Industries Corp., Centre Luxembourgeois de Recherches pour le Verre et la Ceramique S.A. (C.R.V.C.)Inventors: Ronald E. Laird, Carole Laird, Uwe Kriltz
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Patent number: 6913843Abstract: A cutting tool insert has a cemented carbide substrate and a coating. The cemented carbide substrate includes 73-93 wt % WC, 4-12 wt % binder phase, and cubic carbide phase with a binder phase enriched surface zone essentially free of cubic carbide phase. The cubic carbide phase includes elements from the groups IVB and VB, with the Ta content on a level corresponding to a technical impurity. Inserts according to the invention exhibit favorable edge strength and thermal shock resistance.Type: GrantFiled: May 17, 2004Date of Patent: July 5, 2005Assignee: Seco Tools ABInventors: Jenni Zackrisson, Jan Qvick
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Patent number: 6908679Abstract: A coated article is provided so as to include a solar control coating having an infrared (IR) reflecting layer sandwiched between at least a pair of dielectric layers. The IR reflecting layer includes NbZr and/or NbZrOx in certain embodiments of this invention. The use of such materials as an IR reflecting layer(s) allows the coated article to have good corrosion resistance to alkaline solutions, good mechanical performance such as scratch resistance, and/or good color stability (i.e., a low ?E* value(s)) upon heat treatment (HT). The coated article may or may not be heat treated in different embodiments of the invention.Type: GrantFiled: September 29, 2003Date of Patent: June 21, 2005Assignee: Guardian Industries Corp.Inventors: Grzegorz Stachowiak, Ratchaneekorn Chonlamaitri
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Patent number: 6905758Abstract: A decorative item and method for making same, such as an exterior part of a timepiece, wristwatch band and the like, includes a basis material of stainless steel having a carburized hardened later thereon in which carbon is diffused so as to form a solid solution in which crystalline chromium carbide is not formed and at least one hard coating is deposited on the carburized hardened layer of basis material, wherein the hard coating has a surface hardness greater than that of the carburized layer.Type: GrantFiled: September 7, 2000Date of Patent: June 14, 2005Assignee: Citizen Watch Co., Ltd.Inventors: Hachirou Kushida, Kenji Hanai, Yoshitugu Andou, Takeshi Inoue, Kazumi Hamano, Yukio Tanokura, Akira Meguro, Shinji Ikeda
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Patent number: 6906295Abstract: A foodware article having a multilayer, stick resistant, ceramic coating. The foodware article of the present invention includes a metal foodware article having an inner food-contacting surface and an outer surface; a bonding layer deposited on the food-contacting surface; and a first layer of (Ti,Al,Cr)N deposited adjacent to the bonding layer. There is optionally a layer of chromium nitride deposited adjacent to the first (Ti,Al,Cr)N layer, and a second layer of (Ti,Al,Cr)N deposited on the chromium nitride layer. These layers can be repeated as many times as desired. The (Ti, Al, Cr)N layer is generally the top layer of the multiplayer coating. The coating is stick resistant, scratch resistant, thermally stable, corrosion resistant, and color stable. The foodware is suitable for use with both salty-based and acidic-based foods. A method of making such a foodware article is also disclosed.Type: GrantFiled: February 20, 2003Date of Patent: June 14, 2005Assignee: National Material L.P.Inventor: Molly Mo Hui Ge
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Patent number: 6896970Abstract: The process for coating a substrate with a coating giving a polished effect and improved corrosion resistance and coatings produced from this process. The process includes the steps of applying an atomized metal layer onto the substrate and applying a corrosion inhibiting layer to the atomized metal layer.Type: GrantFiled: January 31, 2001Date of Patent: May 24, 2005Assignee: Areway, Inc.Inventor: Alexander Mayzel
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Patent number: 6890659Abstract: A coated article is provided so as to include a solar control coating having an infrared (IR) reflecting layer sandwiched between at least a pair of dielectric layers. The IR reflecting layer includes NbZr and/or NbZrNx, in certain embodiments of this invention. The use of such materials as an IR reflecting layer(s) enables the coated article to have good corrosion resistance to alkaline solutions, good mechanical performance such as scratch resistance, and/or good color stability (i.e., a low ?E* value(s)) upon heat treatment (HT). The coated article may or may not be heat treated in different embodiment of the invention.Type: GrantFiled: April 25, 2003Date of Patent: May 10, 2005Assignee: Guardian Industries Corp.Inventor: Grzegorz Stachowiak
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Patent number: 6890655Abstract: A diamond coated cutting tool that has a treated substrate and a diamond coating thereon. In the process of making the substrate, the sintered substrate is re-sintered to form a re-sintered substrate and the re-sintered substrate is chemically treated to remove cobalt on the surface of the re-sintered substrate as to form a treated substrate.Type: GrantFiled: August 6, 2003Date of Patent: May 10, 2005Assignee: Kennametal Inc.Inventors: Yixiong Liu, Joseph M. Tauber, Charles Erik Bauer
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Patent number: 6890640Abstract: A metal oxide coating has a nanotextured surface defined by a plurality of capillary openings arranged in a pattern on the surface of the coating. Each of the capillary openings have a diameter defined by a previously present organic macromolecule. The metal oxide coating is formed by depositing a solution containing uniformly dispersed micelles composed of amphiphilic molecules on a metal, oxide, or plastic substrate. The micelles are self-arranging, in solution, as a result of mutually repulsive electrostatic forces on the surface of the micelles, and form a uniformly patterned organic template when the solution is deposited on the surface of the substrate. A metal oxide coating is then applied to the substrate, which forms a ceramic monolayer that is a negative image of the organic template. The organic template is then removed, thereby forming a metal oxide coating having a plurality of macromolecular-sized apertures formed therein.Type: GrantFiled: March 25, 2002Date of Patent: May 10, 2005Assignee: Caterpillar IncInventors: Kurtis C. Kelley, Jill E. Rockwood, Norval P. Thomson
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Patent number: 6890665Abstract: Martensitic stainless steel whose steel composition is restricted within a specific range for each element is provided. The scale layer formed on the surface of the base material consists of an inner layer scale mainly including FeCr2O4 and an outer layer scale having a thickness of not more than 20 ?m, which outer layer is deposited on the inner layer scale at a surface coverage of not less than 1% and not more than 15%. The application of rust preventive oil onto the surface of the steel ensures an excellent weather resistance during a long term, and therefore a martensitic stainless steel forming no rust either in the outdoor depository or in the indoor depository can be provided. The steel can be used to manufacture, not only steel pipes, but also steel plates, steel rods and others in a wide application field.Type: GrantFiled: September 26, 2003Date of Patent: May 10, 2005Assignee: Sumitomo Metal Industries, Ltd.Inventor: Mutsumi Tanida
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Patent number: 6890632Abstract: Coated cemented carbide inserts (cutting tool), particularly useful for milling at high cutting speeds in steels and milling in hardened steels are characterised by a WC—Co cemented carbide containing NbC and TaC and a W-alloyed binder phase and a coating including a first, innermost layer of TiCxNyOz with equiaxed grains, a second layer of TiCxNyOz with columnar grains and at least one layer of Al2O3 composed primarily of the ?-phase.Type: GrantFiled: March 18, 2003Date of Patent: May 10, 2005Assignee: Seco Tools ABInventors: Andreas Larsson, Anette Sulin, Lena Pettersson
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Patent number: 6887579Abstract: A metal oxide layer may made more highly oxidized by exposing the layer to sulfur trioxide. The leakage current of the layer may thereby be decreased, providing a capacitor containing such a layer with improved performance properties. The capacitor may be incorporated into a dynamic random access memory cell or other structure useful in the semiconductor or other industry.Type: GrantFiled: May 29, 2002Date of Patent: May 3, 2005Assignee: Micron Technology, Inc.Inventor: Alan R. Reinberg
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Patent number: 6884496Abstract: A method of increasing the compressive stress or of reducing the tensile residual stress of a CVD layer, a PCVD layer or PVD layer and a cutting insert for machining. The invention relates to a method of increasing the compressive residual stress or of reducing the tensile residual stress of a hard material outer layer or a hard material outermost layer in which the coated substrate after coating is subjected to a dry blast treatment using a granular blast agent that, according to the invention, has a maximum diameter of 150 ?m.Type: GrantFiled: December 22, 2001Date of Patent: April 26, 2005Assignee: Widia GmbHInventors: Hartmut Westphal, Volkmar Sottke
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Patent number: 6884497Abstract: A coated cemented carbide insert (cutting tool), particularly useful for milling at high cutting speeds in alloyed steels, tool steels and milling in hardened steels includes a WC—Co cemented carbide containing NbC and TaC and a W-alloyed binder phase, and a coating including an inner layer of TixAlyN, 0.8<x+y<1.2, with 0.25<x/y<1.45, with columnar grains.Type: GrantFiled: March 18, 2003Date of Patent: April 26, 2005Assignee: Seco Tools ABInventors: Anette Sulin, Andreas Larsson, Jacob Sjölén
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Patent number: 6881475Abstract: An amorphous carbon coated tool includes a base material of WC base cemented carbide, and an amorphous carbon film formed on this base material. The cobalt content in the base material is at least 12% by mass. The maximum thickness of the amorphous carbon film is at least 0.05 ?m and not more than 0.5 ?m at the cutting edge. The amorphous carbon film is deposited with graphite as the source material by physical vapor deposition in an atmosphere substantially absent of hydrogen. The amorphous carbon film coated tool superior in wear resistance and adhesion resistance is preferably applicable to rotating tools such as drills, end mills and reamers, indexable inserts used for milling cutters and turning tools, and cutting-off tools such as cutters, knives, or slitters.Type: GrantFiled: June 11, 2002Date of Patent: April 19, 2005Assignees: Sumitomo Electric Industries, Ltd, Nissin Electric Co., Ltd.Inventors: Satoshi Ohtani, Naoto Okazaki, Kiyoshi Ogata, Haruyo Fukui, Miki Irie, Yoshiharu Utsumi, Hisanori Ohara, Hideki Moriguchi, Akihiko Ikegaya, Keiichi Tsuda, Makoto Setoyama