Of Cellulosic Next To Another Carbohydrate Patents (Class 428/533)
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Patent number: 6844081Abstract: A wood product is made from treating wood with two solutions, in series, including a penetrating solution and a topcoat composition. The penetrating solution is made up of boric acid, a metallocene catalyst, a free radical initiator, a first film-forming polymer and an adhesion promoter. The topcoat includes a continuous film-forming polymer. Application of the penetrating solution to the wood gets the solution into the wood to cross-link boric acid with cellulose fibers, then the topcoat forms the continuous film. The film seals in the penetrating solution so that it does not leach out during subsequent exposure to water and weather, allowing soluble salts such as borax to migrate and infiltrate deeper into the wood. Microbiological growth is prevented by several mechanisms.Type: GrantFiled: April 30, 2003Date of Patent: January 18, 2005Assignee: HBF, Inc.Inventors: Eric R. Hart, Mark D. Brown
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Patent number: 6838187Abstract: An aqueous adhesive composition with good release properties. A preferred embodiment comprises sodium lauryl sulfate and a modified tapioca dextrin.Type: GrantFiled: May 10, 2002Date of Patent: January 4, 2005Assignee: National Starch and Chemical Investment Holding CorporationInventors: Edmund W. Figiel, Melissa Allen, Peter D. Pierce, Kristina L. Thompson
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Patent number: 6777075Abstract: A coated printing sheet is provided that is suitable for conventional offset printing grades, exhibiting desirable surface and optical properties and providing a surface that is image receptive and resistant to coating failure. The coated printing sheet includes an image receptive coating containing a hard polymer pigment having a shear modulus of at least 5.0×109 dynes/cm2 and a film forming binder. The coated printing sheets resist burnishing and exhibit desirable properties, e.g., gloss, bulk, stiffness and smoothness, with minimal or no calendering.Type: GrantFiled: March 15, 2002Date of Patent: August 17, 2004Assignee: S.D. Warren Services CompanyInventors: Paul W. Concannon, Paul Durocher, Joseph M. Fernandez, Lisa A. Gubrud, Thomas A. Waecker
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Publication number: 20040137253Abstract: In a paper/film composite structure, the film is made of a low substituted cellulose ether having a molar degree of substitution with alkyl and/or hydroxyalkyl groups in the range of 0.05 to 1.3. The paper/film composite structure can be delivered to the waste paper recycling process without previously removing the film portion. The strength of film is increased without adding to the manufacturing cost. The paper/film composite structure is inexpensive and eliminates the risk of film rupture during the working, transporting and use stages.Type: ApplicationFiled: January 8, 2004Publication date: July 15, 2004Inventors: Soji Tanioka, Sakae Obara, Kazuhisa Hayakawa
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Publication number: 20040126607Abstract: The object of the present invention is to provide a coating material for recycling a thermoplastic resin mold, wherein said coating material is coated on the surface of said thermoplastic resin mold and said thermoplastic resin mold, discarded, can be recycled without removing the coating film of said coating material.Type: ApplicationFiled: September 16, 2003Publication date: July 1, 2004Applicant: Suzuka Fuji Xerox Co., Ltd.Inventor: Yasuhiro Suzuki
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Patent number: 6713140Abstract: The disclosure describes a latently dispersible barrier composite material including an exposed low strength barrier component, an internal water sensitive layer, and a water permeable, inextensible, water dispersible support layer. When exposed to aqueous conditions on the barrier side, the composite prevents it from passing through to the other layers. When exposed to aqueous conditions on the opposite side, the composite readily disperses and may be disposed of by flushing in a toilet, for example. Uses are many and include numerous containment applications such as commode liners, containers for bodily and animal wastes, components of personal care products and the like. Examples of barrier layers include polylactic acid. Examples of water sensitive layers include polyvinyl alcohol. Examples of support layers include low stretch grades of toilet tissue.Type: GrantFiled: December 21, 2001Date of Patent: March 30, 2004Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Ann Louise McCormack, Richard Lee Shick
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Patent number: 6709762Abstract: The invention provides a sewage purification assist toilet paper that carries pineapple enzyme and at least one powdery additive selected from slag, porous ore, and activated carbon. The pineapple enzyme and additive decompose salinity and chlorides contained in toilet sewage which otherwise would inhibit the growth of microorganisms used in the biological treatment of sewage taking place not only in individual septic tanks but also in public sewage systems.Type: GrantFiled: August 2, 2001Date of Patent: March 23, 2004Inventor: Shizuo Uyama
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Patent number: 6692801Abstract: The present invention provides a method for producing a packaging laminate having excellent gas barrier properties. The method involves applying a solution or dispersion of starch or starch derivative to a surface of a substrate of paper or paperboard, and applying a layer of plastic to said starch or starch derivative so as to modify the properties of same such that the starch or starch derivative provides a gas barrier property.Type: GrantFiled: November 13, 2000Date of Patent: February 17, 2004Assignee: Tetra Laval Holdings & Finance S.A.Inventors: Mikael Berlin, Ib Leth, Mats Bentmar
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Patent number: 6692800Abstract: A method for reducing the migration of aldehyde compounds present in packaging material the interior of a package formed by said packaging material, said method comprising: (a) selecting an initial packaging sheet stock used for forming a package having an interior in which an aldehyde sensitive product can be contained, wherein said initial packaging sheet stock has a first surface that forms the interior wall of said formed package, wherein said initial packaging sheet stock has a second surface that forms the exterior wall of said formed package, and wherein said initial packaging sheet stock contains one or more aldehyde compounds that are capable of migrating from said initial packaging sheet stock to said package interior or exterior; (b) preparing an amine-containing composition comprising an amine that chemically reacts with said aldehyde compounds to form a substantially non-migrating compound; and (c) applying said amine-containing composition onto said first surface of said initial packaging sheetType: GrantFiled: October 25, 2000Date of Patent: February 17, 2004Assignee: The Quaker Oats CompanyInventor: Stephen Alan Jacobs
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Publication number: 20030173045Abstract: The present invention relates to a liquid starch dispersion for paper coating where the dispersion has 5 to 50 percent by weight of starch, and the starch contains from 20 to 100 percent by weight of at least one cationic starch. The liquid starch composition is characterized in that a 25 percent by weight starch solids dispersion has a 25° C. viscosity of from 500 to 2500 cps both initially, and also upon storage at room temperature for 90 days. The dispersion preferably contains a blend of cationic starch and ASA starch. The liquid starch dispersion is useful in paper and paperboard coating processes, as a rheology modifier, a structurant, and/or a binder, all at the same time. The liquid starch dispersion provides good coating holdout, gloss, and stiffness properties. The cationic nature of the starch coating improves printability with anionic inks, and makes the coatings useful for ink-jet and photographic papers.Type: ApplicationFiled: March 18, 2002Publication date: September 18, 2003Inventors: Philip Confalone, Daniel B. Solarek, Aqnieszka Lapinska, Wayne Kibble
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Publication number: 20030143417Abstract: The invention relates to a dry mixture, which comprises starch, biologically degradable fiber material, protein and, optionally, additives, for producing biologically degradable shaped bodies, and to a method for producing such a dry mixture. The invention additionally relates to a paste that can be baked, whereby this paste comprises starch, biologically degradable fiber material protein, water and, optionally, additives. Finally, the invention relates to shaped bodies that are produced by using said dry mixture or said paste that is capable of being baked.Type: ApplicationFiled: December 6, 2002Publication date: July 31, 2003Inventors: Anneliese Kesselring, Thomas Koblitz
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Patent number: 6586109Abstract: A method for not only preserving cellulose material from deterioration and from fire, but also for producing plywood, chip and particle aborad with an inexpensive and environmentally acceptable adhesive is described. The cellulose material is processed by spraying, immersing or being subjected to vacuum and pressure application in two steps. One step processes the cellulose material with a sodium silicate preservative solution. Another step processes the cellulose material with a gaseous carbon dioxide. Pressure application, moreover, can be varied in a range not to exceed 250 psi to improve product quality. Moistened cellulose material, treated in the foregoing manner, is coated with a comminuted protein, e.g. soybean meal, and pressed into a cellulose product, typically plywood and chip board.Type: GrantFiled: September 21, 2001Date of Patent: July 1, 2003Assignee: Premier Wood Treating, LLCInventor: James N. Ray
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Patent number: 6544649Abstract: A hog fuel board is made by placing a hog fuel mat including an ammonium chloride catalyst with flexible non-sticking layers on outside surfaces between screens in a preheated platen press and pressing the mat to preset stops and for a predetermined time and pressure to cause adhesives naturally present in the hog fuel to disperse throughout the board. The presence of ammonium chloride as a catalyst uniformly distributed through the hog fuel mat significantly lowers the temperature required at the heating press platens to form a board which also has improved properties. There is also described a hog fuel veneer board with a hog fuel mat sandwiched between veneer sheets and a lumber product with a hog fuel coating thereon. These additional products are both formed using the ammonium chloride catalyst to reduce press temperatures and create a product with improved properties, particularly, internal bond strength.Type: GrantFiled: June 13, 2001Date of Patent: April 8, 2003Assignee: Forintek Canada CorporationInventor: Gary Ellis Troughton
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Patent number: 6537680Abstract: Paper or paperboard laminate composed of at least one bulk-promoting layer, here termed the bulk layer, and on at least one side at the bulk layer at least one secondary layer, secondary layer and bulk layer being joined to one another directly or indirectly over basically the whole of their surfaces facing one another, 40-95% of the bulk layer consists of cellulose fibers with a freeness of 550-950 ml CSF, the secondary layer/layers has/have a greater density than the bulk layer, and the laminate has a bending stiffness index higher than 2.5 Nm7/kg3, but less than 14 Nm7/kg3, calculated as a geometric mean value for machine and transverse direction.Type: GrantFiled: February 27, 2001Date of Patent: March 25, 2003Assignee: Stora Kopparbergs Bergslags Aktiebolag (publ)Inventors: Leif Norlander, Annika Karlsson, Mats Fredlund
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Publication number: 20030049481Abstract: A recording sheet for an ink jet printer can improve both recording properties such as vividness of images, printing density, etc., and shelf life such as light resistance of images, ozone resistance, etc. The recording sheet for an ink jet printer comprises a base material and an ink receiving layer provided on at least one surface of the base material, in which the recording sheet contains oligosaccharide and divalent metallic salt.Type: ApplicationFiled: August 29, 2002Publication date: March 13, 2003Applicant: TOMOEGAWA PAPER CO., LTD.Inventors: Fumikazu Tatsuhashi, Nobuhiro Kubota, Shigeki Asai, Senichi Yoshizawa, Kazushige Katagiri, Minoru Tsuchida
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Publication number: 20030005857Abstract: The present invention relates to a cellulose derivative having biodegradability, recycling properties, excellent mechanical strength and mold processability. The cellulose derivative is a product of a monosaccharide derivative or oligosaccharide derivative and cellulose. The monosaccharide derivative or oligosaccharide derivative is a copolymer of a saccharide and dicarboxylic acid.Type: ApplicationFiled: August 20, 2002Publication date: January 9, 2003Inventors: Masato Minami, Chieko Mihara, Toshihiko Takeda, Yoshihiko Kikuchi
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Patent number: 6468668Abstract: The present invention relates to a cellulose derivative having biodegradability, recycling properties, excellent mechanical strength and mold processability. The cellulose derivative is a product of a monosaccharide derivative or oligosaccharide derivative and cellulose. The monosaccharide derivative or oligosaccharide derivative is a copolymer of a saccharide and dicarboxylic acid.Type: GrantFiled: September 13, 1999Date of Patent: October 22, 2002Assignee: Canon Kabushiki KaishaInventors: Masato Minami, Chieko Mihara, Toshihiko Takeda, Yoshihiko Kikuchi
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Publication number: 20020142031Abstract: Film-forming compositions are disclosed that can comprise, on a dry solids basis, 25 to 75 percent by weight of certain starch derivatives and 25 to 75% primary external plasticizer. The starch derivatives can be chemically modified starches that range in molecular weight from 100,000 to 2,000,000. The high levels of plasticizer in the films give excellent film flexibility and integrity. The films are also resistant to penetration by water, oil and/or grease.Type: ApplicationFiled: February 26, 2001Publication date: October 3, 2002Inventors: G. M. Gilleland, J. L. Turner, P. A. Patton, M. D. Harrison
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Patent number: 6365667Abstract: Synthetic polymers having hydrogen bonding capability and one or more aliphatic hydrocarbon moieties are capable of providing two distinct properties to paper products, such as tissues, which properties heretofore have been imparted through the use of at least two different molecules. The backbone of these synthetic polymers is based on modified vinyl polymers, such as polyvinyl alcohol, polyacrylamides and polyacrylic acids.Type: GrantFiled: August 21, 2000Date of Patent: April 2, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Thomas Gerard Shannon, Daniel Arthur Clarahan, Mike Thomas Goulet, Wen Zyo Schroeder
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Patent number: 6350531Abstract: A biodegradable plastic article molded of a mixture comprising the following components: (A) a biodegradable plastic at 98 to 59% by weight, (B) a dry powder of a water-swelling fiber at 1 to 40% by weight, and (C) a fertilizer powder at 1 to 40% by weight (wherein the sum of (B) and (C) is from 2 to 41% by weight). This biodegradable plastic article can improve biodegradability of the biodegradable plastics and make it possible to regulate the rate of biodegradation thereof.Type: GrantFiled: October 30, 2000Date of Patent: February 26, 2002Assignee: Keiichi SugimotoInventor: Ichiro Sugimoto
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Patent number: 6322899Abstract: A plastic laminate with two or more plastic layers, at least one of which is polyhydroxyalkanoate, such as hydroxybutyrate/hydroxyvalerate copolymer. Next to the polyhydroxyalkanoate layer and attached to it is a layer of biodegradable polyester amide.Type: GrantFiled: May 6, 1999Date of Patent: November 27, 2001Assignee: UPM-Kymmene OyjInventors: Hannu Karhuketo, Heikki Korpela
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Publication number: 20010033941Abstract: Described is a building material composition prepared from or having added thereto a particulate material selected from particulate polysaccharides or particulate polysaccharide derivatives. The particulate material of the building material composition is prepared by a method comprising: (a) forming a feed composition comprising a member selected from the group consisting of polysaccharides and polysaccharide derivatives, and 35 wt. % to 99 wt. % of water, based on the total weight of the feed composition, wherein said member is at least one of swelled and dissolved in the feed composition; (b) contacting, in a mill, the feed composition with a gas stream, thereby converting simultaneously the water of said feed composition into water vapor, and said member of said feed composition into a solid state form of finely particulate material; (c) separating the particulate material from the gas stream; and (d) optionally drying the particulate material.Type: ApplicationFiled: March 14, 2001Publication date: October 25, 2001Inventors: Rene Kiesewetter, Hartwig Schlesiger, Martin Morning, Gunter Weber, Werner Lange
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Patent number: 6254958Abstract: The present invention aims to develop a photosensitive resin composition which exhibits a rapid ink absorption rate, which has an excellent water resistance, and which is appropriate for providing an ink receiving layer forming a sharp ink dot shape and having an excellent color formability of ink. A photosensitive resin composition forming an excellent ink receiving layer is obtained by incorporating at least one selected from an ethylenically unsaturated group-containing compound having quaternary nitrogen and a grain flour (filler) such as a wheat flour or the like in a photosensitive resin composition containing a quaternary nitrogen-free ethylenically unsaturated group-containing compound, a photopolymerization initiator etc.Type: GrantFiled: July 22, 1998Date of Patent: July 3, 2001Assignee: Nippon Kayaku Kabushiki KaishaInventors: Kenji Yoshida, Kiyohisa Tokuda, Kazuhiko Ishii
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Patent number: 6071576Abstract: The disclosure relates to a laminated packaging material (10) comprising a core layer (11) of paper or paperboard and a layer (12) of polyvinyl alcohol serving as oxygen gas barrier on one side of the core layer. In order to avoid excessively large quantities of polyvinyl alcohol on application of the oxygen gas barrier layer (12), a layer (13) is applied which serves as a binder and consists of a mixture of polyvinyl alcohol and a gel-forming substance, for example agar, between the polyvinyl alcohol layer (12) and the core layer (11), with the aid of which excessive penetration of polyvinyl A alcohol into the core layer (11) is effectively counteracted, at the same time as the applied binder layer (13) smoothes and evens out the coarse surface structure of the core layer (11) and forms a smooth substrate for the polyvinyl alcohol layer (12). The quantity of gel-forming substance in the binder layer (13) may amount to between 1 and 20 per cent of the total weight of the mixture.Type: GrantFiled: April 14, 1998Date of Patent: June 6, 2000Assignee: Tetra Laval Holdings & Finance S.A.Inventors: Mats Bentmar, Mikael Berlin
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Patent number: 6007614Abstract: Moisture vapor barrier coating composition comprising:a) a starch ester having 2 to 8 carbon atoms in the ester component and a degree of substitution (DS) of from 1.1 to 2.2;b) a hydrophobic plasticizer; andc) water.Type: GrantFiled: December 3, 1997Date of Patent: December 28, 1999Assignee: National Starch and Chemical Investment Holding CorporationInventors: Robert L. Billmers, Gregory A. Sweeney
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Patent number: 5993530Abstract: A thermally-decomposable, biodegradable resin composition is dispersed and stabilized in water optionally along with additives to give an aqueous dispersion of the resin composition. In the dispersion, the base polymer consists substantially of a water-insoluble starch-type, biodegradable resin. The dispersion is usable in various fields of papermaking, non-woven fabric production, film and sheet production and woven fabric production, in those of dispersed adhesive production, and in those of metal processing, plastic processing, wood processing and stone processing.Type: GrantFiled: March 9, 1998Date of Patent: November 30, 1999Assignee: Japan Corn Starch Co., Ltd.Inventors: Hideyuki Tanaka, Nobuhiro Hosokawa, Nobuyuki Sugtura, Masato Takahara
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Patent number: 5962123Abstract: A decorative laminate comprising a decorative paper sheet and a plurality of resin impregnated sheets wherein color is incorporated into said decorative paper sheet as non-resin impregnated paper chips or one or more colors.Type: GrantFiled: June 6, 1996Date of Patent: October 5, 1999Assignee: The Mead CorporationInventors: Mahendra Mehta, Richard D. Brownhill, John H. Bantjes, William M. Stanard
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Patent number: 5906894Abstract: A multi-ply paperboard comprising at least one ply of conventional cellulose fibers and from about 0.1 to about 6 weight percent of a water-borne binding agent; and at least one ply containing up to 20% of chemically intra-fiber crosslinked cellulosic high-bulk fibers and from about 0.1 to about 6 weight percent of a water-borne binding agent. The water-borne binding agent may be a starch, a modified starch, a polyvinyl alcohol, a polyvinyl acetate, a polyethylene/acrylic acid copolymer, an acrylic acid polymer, a polyacrylate, a polyacrylamide, a polyamine, guar gum, an oxidized polyethylene, a polyvinyl chloride, a polyvinyl chloride/acrylic acid copolymer, an acrylonitrile/butadiene/styrene copolymer or polyacrylonitrile. A method for making the paperboard is disclosed.Type: GrantFiled: October 4, 1996Date of Patent: May 25, 1999Assignee: Weyerhaeuser CompanyInventors: Hugh West, Amar N. Neogi, Dwight A. Dudley, II, Dwayne M. Shearer
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Patent number: 5820998Abstract: A process of making a coated paper comprises the following steps: 1) providing a paper layer composed of a blend of pulp fibers and particulate material containing polyvalent metal cations, 2) applying a acidified alginate solution of a material selected from salts and derivatives of alginic acid to cover at least a portion of the paper, 3) reacting the salts and/or derivatives of alginic acid with polyvalent metal cations in the paper to form a polymer coating, and 4) drying the paper and polymer coating. The permeability of the coated paper is generally at least about 75 percent less than the permeability of an identical uncoated portion of the paper. The solution of alginate material may be partially cross-linked. The alginate solution may be deposited utilizing gravure printing techniques. Also disclosed is a coated paper and a wrapper for a smoking article.Type: GrantFiled: March 8, 1994Date of Patent: October 13, 1998Assignee: Schweitzer-Mauduit International, Inc.Inventors: Raymond Dwayne Hotaling, Vladimir Hampl, Jr.
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Patent number: 5770319Abstract: The invention comprises a method of densifying lignocellulosic material such as wood. The wood is impregnated with a maltodextrin solution under vacuum and/or pressure and the maltodextrin is then cross linked to insolubilise the maltodextrin. A wood-polymer composite is formed. Suitable cross linking agents include compounds having at least one hydroxyl group. Maltodextrins having a dextrose equivalent in the range 15 to 30 are preferred. The resulting composite material has improved appearance, hardness, impact resistance, strength and water repellency.Type: GrantFiled: December 19, 1994Date of Patent: June 23, 1998Assignee: Her Majesty the Queen in Right of New ZealandInventors: Robert Franich, Kathryn Anderson
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Patent number: 5757408Abstract: Disclosed is a recording sheet which comprises a paper substrate and a material selected from the group consisting of monomeric amino acids, monomeric hydroxy acids, monomeric polycarboxyl compounds, and mixtures thereof. Another embodiment of the present invention is directed to a recording sheet which comprises a substrate and a material selected from the group consisting of monomeric amino acids, monomeric hydroxy acids, and mixtures thereof.Type: GrantFiled: June 2, 1995Date of Patent: May 26, 1998Assignee: Xerox CorporationInventor: Shadi L. Malhotra
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Patent number: 5744220Abstract: The present invention relates to a thermosetting decorative laminate (11), primarily intended as flooring laminate, comprising two or more layers (3, 4, 5), whereby at least one layer is a decorative layer (4) comprising a decor paper (9) provided with a bar pattern comprising a plurality of parallel rows of bars (14), whereby the bars (14) in adjoining rows preferably are mutually offset in the longitudinal direction. The bar pattern allows said laminate (11) to be divided into m longitudinal units or panels each consisting of p rows of bars (14), whereby said unit or panel comprises m.times.p rows of bars (14). The pattern of each left end bar (A1-A9) matches the pattern of corresponding right end bar (B1-B9) of each unit or panel and the pattern of these bars matches the pattern of corresponding end bars (A, B) in corresponding rows of all m units or panels.Type: GrantFiled: August 16, 1996Date of Patent: April 28, 1998Assignee: Perstorp ABInventor: Peter Ringo
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Patent number: 5736259Abstract: A process for easily producing a packing material for high-performance liquid chromatography, which produces only a small amount of a dissolved matter. The process has a low cost and contributes to an improvement in the quality of the separated product, without reducing the separation capacity in the field of the separation of only a small amount of a dissolved matter derived from the polysaccharide derivative is obtained by washing the packing material comprising a polysaccharide coated on a carrier with a solvent.Type: GrantFiled: October 20, 1995Date of Patent: April 7, 1998Assignee: Daicel Chemical Industries, Ltd.Inventors: Hiroshi Oda, Kiyokazu Murata
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Patent number: 5658622Abstract: A packaging laminate comprising a rigid, but foldable paper or paperboard layer which has, at least on its one side, an outer film or coating of a water-insoluble polysaccharide compound which imparts to the packaging laminate tightness properties against liquid and water vapor and good sealing properties. Preferably, the other side of the core layer also has an outer film or coating of said polysaccharide compound. The polysaccharide compound in the two outer films or coatings contains a first water-soluble polysaccharide of polyanionic character and a second water-soluble polysaccharide of polycationic character, these being chemically or otherwise bonded to one another to form the water-insoluble polysaccharide compound. One preferred such polysaccharide compound may, for example, consist of a chemical compound or a chemical complex of chitosan and agar.Type: GrantFiled: May 22, 1995Date of Patent: August 19, 1997Assignee: Tetra Laval Holdings & Finance S.A.Inventors: Mikael Berlin, Bo Lundgren
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Patent number: 5635123Abstract: Fiber-reinforced protein-based biocomposite particulate material containing a legume-based thermosetting resin and cellulosic material, and rigid biocomposite pressure-formed materials produced therefrom, are provided. The particulate material and resultant pressure-formed materials contain the legume-based resin and fibrous cellulosic material in amounts such that the ratio of cellulose solids to resin solids is about 0.8:1.0 to about 1.5:1.0. Particularly preferred pressure-formed materials also include a secondary thermosetting binder, such as an isocyanate.Type: GrantFiled: June 7, 1995Date of Patent: June 3, 1997Assignee: Phenix Biocomposites, Inc.Inventors: Michael J. Riebel, Paul L. Torgusen, Kenneth D. Roos, Donald E. Anderson, Carl Gruber
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Patent number: 5631078Abstract: A thermoplastic film is comprised of an admixture of 20 to 85 weight percent cellulose ester fibers and 80 to 15 weight percent cellulose fibers and a functional amount of a cellulose ester plasticizer. The film has an opacity in the range of 10 to 85 percent, a thickness in the range of 0.002 to 0.010 inch, a porosity in the range of 0.0 to 50 ml/min/cm.sup.2 at a 1.0 centibar pressure drop and a compostability of less than 65 days fragmentation. The film is prepared by making a paper comprised of 20 to 85 weight percent cellulose ester fibers and 80 to 15 weight percent cellulose fibers and saturating the paper with a functional amount of a cellulose ester plasticizer. The saturated paper is subjected to heat and pressure for a period of time to obtain the thermoplastic film. The thermoplastic film is prepared without the use of solvents and is economically attractive since it is compatible with conventional paper printing materials and techniques.Type: GrantFiled: October 30, 1995Date of Patent: May 20, 1997Assignee: Eastman Chemical CompanyInventors: Eric E. Ellery, Melvin G. Mitchell, Charles K. Crosswhite, Donald W. Monk
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Patent number: 5620757Abstract: Disclosed are heat-sealable edible films comprising at least a film layer containing a water-soluble polysaccharide as the principal component, or comprising at least (a) a film layer as described above and (b) a subfilm layer containing an alkali metal salt of casein, soybean protein or a combination of soybean protein and gelatin, as the principal component. Preferably, the water-soluble polysaccharide is composed chiefly of carrageenan and the film layer additionally contains a polyhydric alcohol. These edible films are useful in sealing or packaging powdery foods, granular foods, dry solid foods, oily foods and the like.Type: GrantFiled: September 30, 1991Date of Patent: April 15, 1997Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Hirofumi Ninomiya, Shoji Suzuki, Kazuhiro Ishii
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Patent number: 5601930Abstract: A decor sheet for use in decorative laminates wherein the sheet is treated with a sizing agent to reduce its capacity for a laminating resin and enhance its opacity; in a preferred embodiment, the resin-impregnated decor sheet exhibits a resin gradient in the thickness direction to provide a decor sheet having a resin-rich top layer and a resin-starved bottom layer; in accordance with a preferred embodiment, the resin gradient is achieved by differentially sizing the bottom versus the top surface of the decor sheet; a decorative laminate employing such decor sheets are described.Type: GrantFiled: February 15, 1995Date of Patent: February 11, 1997Assignee: The Mead CorporationInventors: Mahendra Mehta, Larry O. Hill
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Patent number: 5580922Abstract: The invention is directed to a composition of matter useful as a paper impregnant, to the method of its use, and to the products produced by the method. Poly (diphenylmethane diisocyanate) or PMDI has been used in the past as a paper impregnant with or without propylene carbonate as a diluent. These products have generally required pressing under high pressures and at elevated temperatures. It has now been found that triacetin and/or triethyl citrate in usages up to about 20% of PMDI give superior performance in impregnated products. The modified PMDI will cure at essentially ambient conditions in times as short as 1-2 days to insoluble polyureas with low residual amounts of isocyanates and reaction byproducts such as 4,4'-diaminodiphenylmethane. The treated papers can be used in applications of which skins for sandwich panels and high strength corrugated board would be exemplary.Type: GrantFiled: June 6, 1995Date of Patent: December 3, 1996Assignee: Weyerhaeuser CompanyInventors: David W. Park, Frank R. Hunter
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Patent number: 5578372Abstract: Composite films have a layer structure comprising a base film, and a coating layer containing a vinylidene chloride polymer, a laminating agent layer composed of a polyisocyanate component and a polyol component, and a polymer film as laminated in that order on at least one side of the base film. The vinylidene chloride polymer is a copolymer having a vinylidene chloride content of 91 to 94% or a copolymer having a weight average molecular weight of 7.5.times.10.sup.4 to 20.times.10.sup.4. By using such copolymer, the transparency and gas barrier properties can be prevented from decreasing and the heat-sealed portions from whitening. The base film includes nylon films, among others. The base film may also be a stretched or oriented one. The polymer film includes heat-weldable films.Type: GrantFiled: March 22, 1994Date of Patent: November 26, 1996Assignee: Daicel Chemical Industries, Ltd.Inventor: Tadashi Murakami
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Patent number: 5512378Abstract: Thin-walled biodegradable starch-based articles, particularly sheets of film including at least one first layer of polymeric material including starch and at least one second layer of hydrophobic material, are characterized in that the second layer includes a natural or synthetic wax or mixture of waxes.Type: GrantFiled: January 23, 1995Date of Patent: April 30, 1996Assignee: Novamont S.p.A.Inventors: Catia Bastioli, Giancarlo Romano, Mario Scarati, Maurizio Tosin
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Patent number: 5492756Abstract: Low-density press board material is prepared by particulate kenaf core raw material and a cold-set, thermosetting or thermoplastic binder. The compressed and cured material exhibits dimensional stability, acoustical and thermal insulative properties and related characteristics roughly equivalent to some currently available wood and wood-substitute materials. The surfaces of the kenaf core board can be upgraded with the addition of overlays.Type: GrantFiled: July 22, 1994Date of Patent: February 20, 1996Assignee: Mississippi State UniversityInventors: Roy D. Seale, Terry Sellers, Jr., Marty J. Fuller
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Patent number: 5451456Abstract: A latex comprises a colloidal suspension in water of essentially non-crystalline particles of a polymer or copolymer or .beta.-hydroxyalkanoates, for example .beta.-hydroxybutyrate and .beta.-hydroxyvalerate; the latex may be employed to produce self-supporting filfms or papers which are biodegradable and also readily recyclable.Type: GrantFiled: August 18, 1992Date of Patent: September 19, 1995Assignee: Pulp and Paper Research Institute of CanadaInventors: Robert H. Marchessault, Pierre F. LePoutre, Peter E. Wrist
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Patent number: 5451467Abstract: The present invention relates to thermoplastic membranes which are selectively permeable to water or water vapor and which can be simply produced by the lamination of a thermoplastic sheet onto an absorbent material at or around the glass transition temperature of the thermoplastic.Type: GrantFiled: June 25, 1992Date of Patent: September 19, 1995Inventor: Peter M. Lock
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Patent number: 5434011Abstract: A method for manufacturing a peat moss board suitable for use as an absorbent core in structures for absorbing body exudate. The method is characterized by conditioning a wet laid board to a specific water content and calendering the conditioned board at a predetermined pressure. The water content and the calendering pressure determine the density of the peat moss board in final form. The invention also extends to a peat moss board manufactured by the novel method.Type: GrantFiled: December 13, 1991Date of Patent: July 18, 1995Assignee: Johnson & Johnson Inc.Inventor: Martin Roy
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Patent number: 5413843Abstract: An inkable sheet, especially suitable for use with aqueous based inks, having an ink-absorbent later substrate which, on depositing an aqueous droplet thereon, exhibits an advancing contact angle not exceeding 100.degree. and has an ink absorption capacity not exceeding 35 grams of water per gram of the ink-absorbent layer. The contact angle of the sheet may be modified by the presence of a supercoat. This sheet has an excellent combination of characteristics even at high ink loadings, for example 300 dpi.Type: GrantFiled: August 6, 1992Date of Patent: May 9, 1995Assignee: Imperial Chemical Industries PLCInventors: Stephen Mann, Roger N. Barker, Graham A. Page, Stephen P. Corr
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Patent number: 5411637Abstract: The invention relates to an improvement in the art of making high pressure laminated materials utilizing saturating kraft paper. In particular, the invention relates to a method for making laminated materials which greatly reduces pressure mark defects caused by fuzz balls.Type: GrantFiled: November 24, 1993Date of Patent: May 2, 1995Assignee: Westvaco CorporationInventors: John W. Glomb, Yvette A. Tramount
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Patent number: 5384130Abstract: Pharmacologically inactive spherical seed cores comprising at least 50% by weight of microcrystalline cellulose having an average degree of polymerization of 60 to 375, wherein the spherical seed cores have an average particle size of 100 to 1000 .mu.m, a tapped bulk density of at least 0.65 g/ml, an aspect ratio of at least 0.7, a water absorption capacity of 0.5 to 1.5 ml/g, and a friability of no more than 1%; spherical granules comprising the spherical seed cores coated with a powdery layer comprising active ingredients and having an outer layer of coating provided on the powdery layer; and a process for the production of spherical granules, comprising the steps of coating the spherical seed cores with powder comprising active ingredients using an aqueous binding solution, spraying an aqueous solution or suspension of a coating agent thereon, and drying the resulting coated granules.Type: GrantFiled: January 12, 1993Date of Patent: January 24, 1995Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventor: Etsuo Kamada
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Patent number: 5340530Abstract: A method of manufacturing a protective insert (1) on a metal part (2) in which a foil (3) that serves as a barrier for gases is fixed between the part (2) and the insert (1), the edges of a metal capsule (4) are fixed to the edges of the foil (3), the space (5) between the capsule (4) and the part (2) is filled with a metal or ceramic powder and the ends of the capsule (4) are closed, the part (2) together with the filled capsule (4) are inserted in an isostatic pressing oven under a controlled atmosphere, with the pressure and the temperature being selected so that the powder is pressed in situ. The part (2) is cooled and then the capsule is removed before giving the part (2) together with its insert (1) the desired final shape. The method is very simple and it enables reliable products to be obtained.Type: GrantFiled: June 4, 1993Date of Patent: August 23, 1994Assignee: GEC Alsthom Electromecanique SAInventor: Andre Coulon
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Patent number: 5314753Abstract: A matte printing paper, excepting bank note and security document paper, especially for offset or intaglio printing, is coated with a composition containing calcium carbonate as a coating pigment, a binding agent for absorption of printing ink and 10 to 65% by weight, based on its total solids content, of ungelatinized starch granules, except rice starch granules.Type: GrantFiled: November 12, 1992Date of Patent: May 24, 1994Assignee: Stora Feldmuhle AktiengesellschaftInventor: Werner Bergmann