Pb-base Component Patents (Class 428/645)
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Patent number: 5916730Abstract: An optical information recording medium capable of recording information, reproducing recorded information, erasing recorded information, and rewriting recorded information, is composed of a substrate, a recording layer formed on the substrate, the recording layer including as the main component a four-component phase-change recording material comprising Ag, In, Te and Sb, and containing a crystalline phase composed of the microcrystallites of AgSbTe.sub.2 at the erasure of recorded information, an upper heat resistant protective layer formed on the recording layer, the upper heat resistant protective layer including a heat resistant material with a thermal conductivity of 1.0 W/cm.deg or more, and an optical reflecting layer formed on the upper heat resistant protective layer. Optical information can be recorded in this recording medium by applying a laser beam to the recording layer through the substrate at a linear velocity of disc rotation of 1.2 to 5.6 m/sec.Type: GrantFiled: January 14, 1997Date of Patent: June 29, 1999Assignee: Ricoh Company, Ltd.Inventors: Yukio Ide, Makoto Harigaya, Yoshiyuki Kageyama, Hiroko Iwasaki
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Patent number: 5910377Abstract: The present invention provides a clad steel plate of a base material and a cover material attached to the base material. The base material has holes with rising rims and the rims pass through the covering material and expand over its surface to unite the base and covering materials.Type: GrantFiled: February 7, 1997Date of Patent: June 8, 1999Assignees: Shinsozaihanbai Kabushiki Kaisha, Akiyama Gasket Kabushiki KaishaInventors: Katsuro Tsukamoto, Susumu Ishikawa
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Patent number: 5906874Abstract: The invention provides a phase change type optical recording medium enabling an increased jitter concomitant with repeated overwriting to be restrained or substantially eliminated. In the optical recording medium comprising a phase change type recording layer on a substrate, the recording layer has a lower dielectric layer in contact with a lower side thereof and an upper dielectric layer in contact with an upper side thereof, and at least one of the upper and lower dielectric layers contains zinc sulfide, and further includes a metal element A that has a standard free energy for forming a sulfide thereof lower than a standard free energy for forming ZnS at 0 to 1,000.degree. C. The ratio of metal element A to all metal elements in the zinc sulfide-containing dielectric layer is less than 2 at %. Metal element A is typically Ce, Ca, Mg, Sr, Ba, and Na.Type: GrantFiled: December 11, 1997Date of Patent: May 25, 1999Assignee: TDK CorporationInventors: Makoto Takahashi, Takashi Kikukawa, Isamu Kuribayashi, Junji Tominaga
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Patent number: 5891542Abstract: One object of the invention is to achieve a phase change type optical recording medium having high degree of modulation and recording sensitivity, and another object of the invention is to achieve a phase change type optical recording medium having already stable write/read characteristics at the time of the first overwriting. The optical recording medium comprises a recording layer made up of an optical recording material containing given amounts of In, Ag, Te and Sb. In one Raman spectrum embodiment of the optical recording there are a scattering peak I-1 having a Raman shift in a range of 113 to 117 cm.sup.-1 and a scattering peak I-2 having a Raman shift in a range of 123 to 127 cm.sup.-1, said scattering peak I-2 being larger in half-width than said scattering peak I-1. In another Raman spectrum embodiment, there are a scattering peak II-1 having a Raman shift in a range of 105 to 125 cm.sup.-1 and a scattering peak II-2 having a Raman shift in a range of 140 to 160 cm.sup.Type: GrantFiled: December 2, 1997Date of Patent: April 6, 1999Assignee: TDK CorporationInventors: Junji Tominaga, Takashi Kikukawa, Isamu Kuribayashi, Makoto Takahashi
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Patent number: 5882758Abstract: A phase-change type optical recording medium, wherein (1) recording, erasing and reading of information by irradiating light is possible, and the medium has a structure in which a first protective layer, a recording layer, a second protective layer, and a reflective layer are consecutively deposited in this order on a transparent substrate, (2) the thickness of the first protective layer is in the range of the thickness, where reflectivity of light on irradiating the layer from the side of the transparent substrate exhibits a minimum, .+-.30 nm, and (3) the second protective layer has the absorption coefficient k satisfying the equation as follows0.05.ltoreq.k.ltoreq.2.5.According to the present invention, unevenness of shapes and sizes of the recording pits can be reduced, irrespective of whether the state of the recording layer is crystalline or amorphous.Type: GrantFiled: May 27, 1997Date of Patent: March 16, 1999Assignee: Asahi Kasei Kogyo KabushikiInventors: Masato Terada, Kazuyuki Furuya, Tatsuya Okamura, Masaru Suzuki
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Patent number: 5882587Abstract: An overlay alloy for sliding bearing is deposited on a lining by plating and consists of from 2 to less than 5% of tin, from 0.05 to 10% of indium, from 0.05 to 5% of copper, the balance consisting of lead and unavoidable compound. Seizure at high speed travel is almost completely eliminated.Type: GrantFiled: June 2, 1997Date of Patent: March 16, 1999Assignee: Taiho Kogyo Co., Ltd.Inventors: Shinichi Okamoto, Takashi Tomikawa, Shigeyuki Suga
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Patent number: 5882759Abstract: An information recording medium which comprises as a recording layer an information recording thin layer, formed on a substrate directly or via an underlayer, which records and/or reads back information through the use of atomic arrangement change caused by the irradiation of energy beams, a protective layer and at least two reflective layers, the reflective layers including a first reflective layer and a second reflective layer, the materials of which differ in refractive index or extinction coefficient or both, the aforesaid layers being laminated in the order, from the side of light incidence, of the protective layer, the recording layer, an intermediate layer, the first reflective layer and the second reflective layer.Type: GrantFiled: July 29, 1997Date of Patent: March 16, 1999Assignees: Hitachi, Ltd., Hitachi Maxell, Ltd.Inventors: Akemi Hirotsune, Motoyasu Terao, Yasushi Miyauchi, Makoto Miyamoto
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Patent number: 5876822Abstract: A description is given of an reversible optical information medium comprising a substrate (1), a first dielectric layer (2), a phase-change recording layer on the basis of Ge-Sb-Te (3), a second dielectric layer (4), and a metal mirror layer (5). The recording layer (3) comprises an alloy having the composition Ge.sub.50x Sb.sub.40-40x Te.sub.60-10x, in atom %, wherein0.166.ltoreq.x.ltoreq.0.444and wherein the layer thickness d.sub.3 of said recording layer (3) ranges between 25 and 35 nm. Such a medium is suitable for high speed recording (i.e. at least twice the CD-speed), and has a large cyclability of at least 10.sup.5 direct overwrite cycles.Type: GrantFiled: February 6, 1997Date of Patent: March 2, 1999Assignee: U.S. Philips CorporationInventors: Guofu F. Zhou, James H. Coombs, Johan P. W. B. Duchateau
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Patent number: 5846625Abstract: An optical disk apparatus using an optical disk in which a layer (a reflectivity adjustment layer) in which the optical constants are changed by melting at the time of irradiation of light is provided separately from a recording layer using a phase change, and the reflectivity at a portion having a high reflectivity on the recording track is 40% or lower at the time of irradiation of strong light, and the reflectivity at the same portion is 60% or higher at the time of irradiation of weak light, wherein when the laser power is set to a power which is higher than the power at which the optical constants of the reflectivity adjustment layer are greatly changed at the time of rewriting and at which a high melting-point component is not melted, remaining of an unerased portion during rewriting due to a difference in reflectivity between the written mark portion and the other portions can be prevented and the possible number of rewritings can be increased, and hence an optical disk which has a high recording sensiType: GrantFiled: August 28, 1995Date of Patent: December 8, 1998Assignees: Hitachi, Ltd., Hitachi Maxell, Ltd.Inventors: Motoyasu Terao, Tetsuya Nishida, Yasushi Miyauchi, Akemi Hirotsune
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Patent number: 5843553Abstract: A recordable element including a substrate and having over its surface, in order, an optical recording layer and a light reflecting layer, the improvement includes an optical recording layer containing Te.sub.a Ge.sub.b C.sub.c H.sub.d O.sub.e where a, b, c, d, and e are atomic percents such that a+b+c+d+e=100, and wherein 10<a<40, 10<b<60, 5<c<35, 10<d<5, e.gtoreq.0; an the optical recording layer having one or more sublayers which can be of different compositions; and the thickness t of the optical recording layer is 0.7 Tmin<t<1.3 Tmin.Type: GrantFiled: July 29, 1997Date of Patent: December 1, 1998Assignee: Eastman Kodak CompanyInventors: George R. Olin, Yuan-Sheng Tyan, Pranab K. Raychaudhuri, Fridrich Vazan
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Patent number: 5840391Abstract: A decorative glass sheet simulating a multi-pane, camed window or door, and a method for forming the same. The decorative glass sheet includes a glass panel having an outer surface. At least one groove is formed through the outer surface and into the glass panel. Each groove includes a first wall extending from a first peripheral edge to a groove bottom apex and a second wall extending from the apex to a second peripheral edge. The second wall has a width greater than a width of the first wall. At least one decorative caming strip is adhered to the outer surface of the glass panel and is disposed adjacent and along the first peripheral edge of the at least one groove.Type: GrantFiled: October 15, 1997Date of Patent: November 24, 1998Assignee: Glass Unlimited of High Point, Inc.Inventors: Keith L. Eichhorn, Lars Richter
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Patent number: 5817389Abstract: It is an object of the present invention to increase an amount of information recorded on an optical disk having at least two information recording layers. An optical disk having a plurality of information recording layers according to the present invention includes a transparent substrate, a transparent layer and at least two information recording layers formed on the transparent substrate. The information recording layers are provided so as to sandwich the transparent layer. At least one of the information recording layers has a transmittance varying layer. The transmittance varying layer is made of a material whose transmittance is changed at a predetermined temperature as a threshold value. The transmittance varying layer is made of a phase change material. The threshold value is within the temperature range from 700.degree. to 500.degree.. Crystallization speed of the transmittance varying layer is equal to or slower than 500 ns.Type: GrantFiled: October 29, 1996Date of Patent: October 6, 1998Assignee: Sony CorporationInventor: Masumi Ono
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Patent number: 5789055Abstract: An optical recording medium of phase change improves the erase ratio and the repeat writing characteristic by coexistence of an amorphous phase and a crystalline phase at the stage of initiation so as to reduce the size of crystalline grain in a recording layer and a method of fabricating the same. The optical recording medium of phase change comprises: a substrate; a first dielectric layer deposited on said substrate; a recording layer deposited on said first dielectric layer; a second dielectric layer deposited on said recording layer; a reflection layer and a protective film formed sequentially on said second dieletric layer; said recording layer being consisted of (GeSbTe).sub.x (In.sub.y Sb.sub.1-y).sub.1-x ; and a crystalline phase of said recording layer being a structure co-existing with a crystalline material of GeSbTe and an amorphous material of InSb.Type: GrantFiled: August 6, 1996Date of Patent: August 4, 1998Assignee: LG Electronics Inc.Inventor: DooWon Yoon
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Patent number: 5785828Abstract: A sputtering target for fabricating a recording layer of a phase-change type optical recording medium contains a compound or mixture including as constituent elements Ag, In, Te and Sb with the respective atomic percent (atom.%) of .alpha., .beta., .gamma.and .delta.thereof being in the relationship of 2.ltoreq..alpha..ltoreq.30, 3.ltoreq..beta..ltoreq.30, 10.ltoreq..gamma..ltoreq.50, 15.ltoreq..delta..ltoreq.83 and .alpha.+.beta.+.gamma.+.delta.=100, and a method of producing the above sputtering target is provided. A phase-change type optical recording medium includes a recording layer containing as constituent elements Ag, In, Te and Sb with the respective atomic percent of .alpha., .beta., .gamma.and .delta.thereof being in the relationship of 0<.alpha..ltoreq.30, 0<.beta..ltoreq.30, 10.ltoreq..gamma..ltoreq.50, 10.ltoreq..delta..ltoreq.80, and .alpha.+.beta.+.gamma.+.delta.Type: GrantFiled: December 12, 1995Date of Patent: July 28, 1998Assignee: Ricoh Company, Ltd.Inventors: Katsuyuki Yamada, Hiroko Iwasaki, Yukio Ide, Makoto Harigaya, Yoshiyuki Kageyama, Hiroshi Deguchi, Masaetsu Takahashi, Yoshitaka Hayashi
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Patent number: 5770293Abstract: A method of forming a recordable element including a substrate and having on its surface, in order, an optical recording layer and a light reflecting layer, the optical recording layer having at least two sublayers of different compositions is disclosed. The method includes forming in a sputtering chamber on the substrate surface a first sublayer of a predetermined thickness by sputtering at least two metal elements having Ge and Te, or alloys thereof, in a flowing environment of a hydrocarbon gas and an inert gas wherein the flow rate of the hydrocarbon gas is selected relative to the flow rate of the inert gas to provide the first sublayer with an elemental R.sub.Type: GrantFiled: April 12, 1996Date of Patent: June 23, 1998Assignee: Eastman Kodak CompanyInventors: Pranab K. Raychaudhuri, Fridrich Vazan
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Patent number: 5770323Abstract: Bearings are described having composite overlay coatings. The composite overlay coating comprises an electro co-deposited soft metallic matrix having incorporated therein from 0.05 to 2 wt % of a hard metal oxide, said material exhibiting a Vickers hardness (Hv) of from at least 300 to in excess of 600.Type: GrantFiled: February 23, 1996Date of Patent: June 23, 1998Assignee: T & N Technology LimitedInventors: Charan P. S. Johal, David R. Eastham, Alan D. Pope
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Patent number: 5750228Abstract: An optical information storage medium includes a multilayer structure formed on a substrate. The multilayer structure is formed by a sputtering process in a discharge gas and includes at least a first dielectric layer, a recording layer which shows reversible phase change between an amorphous phase and a crystal phase, and a second dielectric layer. The multilayer structure contains sufficiently small amount of the discharge gas so that a limited amount or less of voids of the discharge gas generates in the recording layer during repeated overwrite operations.Type: GrantFiled: December 1, 1995Date of Patent: May 12, 1998Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Yoshitaka Sakaue, Eiji Ohno, Kazuhisa Ide, Kenichi Nagata, Noboru Yamada
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Patent number: 5741603Abstract: An optical disc comprising transparent substrate, a phase-changing material layer disposed on the transparent substrate and made of a material which is phase-changeable by radiation of a light beam, a reflecting film layer disposed on the phase-changing material layer, and a cooling layer disposed between the phase-changing material layer and the reflecting layer, wherein the cooling layer has a heat conductivity ranging from 0.25 J/cmKs to 20.00 J/cmKs. The optical disc of the present invention has such a structure that a crystal phase portion of the phase-changing material layer shows a higher light absorptivity than that of the amorphous phase portion and exhibits a high carrier to noise ratio (C/N ratio) irrespective of a line speed upon rotational driving of the optical disc.Type: GrantFiled: April 3, 1997Date of Patent: April 21, 1998Assignee: Sony CorporationInventor: Koichi Yasuda
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Patent number: 5736657Abstract: A sputtering target contains a target material including as constituent elements Ag, In, Te and Sb with the respective atomic percents (atom. %) of .alpha., .beta., .gamma. and .delta. thereof being in the relationship of 0.5.ltoreq..alpha.<8, 5.ltoreq..beta..ltoreq.23, 17.ltoreq..gamma..ltoreq.38, 32.ltoreq..delta..ltoreq.73, .alpha..ltoreq..beta., and .alpha.+.beta.+.gamma.+.delta.=100, and a method of producing the above sputtering target is provided. An optical recording medium includes a recording layer containing a phase-change recording material which includes as constituent elements Ag, In, Te and Sb with the respective atomic percents of .alpha., .beta., .gamma. and .delta. thereof being in the relationship of 1.ltoreq..alpha.<6, 7.ltoreq..beta..ltoreq.20, 20.ltoreq..gamma..ltoreq.35, 35.ltoreq..delta..ltoreq.70, and .alpha.+.beta.+.gamma.+.delta.=100, and is capable of recording and erasing information by utilizing the phase change of the recording material in the recording layer.Type: GrantFiled: March 26, 1996Date of Patent: April 7, 1998Assignee: Ricoh Company, Ltd.Inventors: Yukio Ide, Hiroko Iwasaki, Yoshiyuki Kageyama, Yujiro Kaneko, Katsuyuki Yamada, Michiaki Shinotsuka, Makoto Harigaya, Hiroshi Deguchi
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Patent number: 5733623Abstract: A recordable element with improved performance, and a method of making such element is disclosed. The recordable element includes a substrate and an optical recording layer deposited on the substrate, wherein the optical recording layer is formed of Te.sub.a Ge.sub.b C.sub.c H.sub.d O.sub.e where a, b, c, d, and e are atomic percents such that a+b+c+d+e=100, and wherein 10<a<40, 10<b<60, 5<c<35, and 15<(c+d)<65 and e.gtoreq.0; a metal layer over the optical recording layer; and the recording element having its properties changed by heat treatment for a time and temperature selected so as to significantly improve jitter, window margin, reflectivity, and recording sensitivity performance.Type: GrantFiled: October 15, 1996Date of Patent: March 31, 1998Assignee: Eastman Kodak CompanyInventors: Pranab K. Raychaudhuri, Fridrich Vazan, George R. Olin, Yuan-Sheng Tyan
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Patent number: 5727727Abstract: The invention features a method for flowing solder in a gap between two surfaces. A supply of solder is heated to cause it to reflow and flow in the gap. The solder is directed to flow as a main stream in the gap and to flow as peripheral streams from the main stream toward edges of the gap to reduce formation of voids.Type: GrantFiled: May 9, 1997Date of Patent: March 17, 1998Assignee: VLT CorporationInventor: George J. Ead
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Patent number: 5718983Abstract: A composition of materials having ferromagnetic and piezoelectric properties is disclosed. In the preferred embodiment, the composition of materials comprises a first layer of Pb.sub.(1-x-y) Cd.sub.x Fe.sub.y and a second layer of Cr.sub.(1-z-w) Zn.sub.z Te.sub.w where x, y, z and w are values within the ranges of 0.38.ltoreq.x.ltoreq.0.042, 0.08.ltoreq.y.ltoreq.0.094, 0.38.ltoreq.z.ltoreq.0.41, 0.28.ltoreq.w.ltoreq.0.31, and 0.25.ltoreq.(1-z-w).ltoreq.0.32. Additionally, each of the layers contain the elements of Bi, O, and S. A random-accessible, non-volatile memory built using the This memory provides for storing two independent bits of binary information in a single storage cell. Each cell comprises two orthogonal address lines formed on the opposite surface of a Si substrate, a composition of materials of the present invention formed over each of the address lines, and an electrode formed over each composition of materials. The data is stored electromagnetically and retrieved as a piezoelectric voltage.Type: GrantFiled: January 6, 1997Date of Patent: February 17, 1998Assignee: Kappa Numerics, Inc.Inventor: Shimon Gendlin
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Patent number: 5718961Abstract: An optical recording medium is provided in which a first dielectric film, a second dielectric film, a recording film, a reflective film are sequentially stacked on a substrate, said first dielectric film and second dielectric film are formed of ZnO-BN. The optical disk has high recording sensitivity and high thermal stability.Type: GrantFiled: October 11, 1996Date of Patent: February 17, 1998Assignee: Samsung Electronics Co., Ltd.Inventor: Hyeon-chang Hong
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Patent number: 5709978Abstract: A recording film 3 of phase change type of Sb--Te--Ge system or Sb--Te--In system has at least one of lanthanoid elements and elements selected from among Ag, Ba, Co, Cr, Ni, Pt, Si, Sr, Au, Cd, Cu, Li, Mo, Mn, Zn, Al, Fe, Pb, Na, Cs, Ga, Pd, Bi, Sn, Ti, and V added thereto. A high melting point component 3b is precipitated in the recording film 3 to coexist with a phase change component 3a, thereby preventing the recording film 3 from flowing and segregating during recording and erasing. The recording film 3 can be made not as recording film, but as superresolution readout thin film to mask an optical disc recorded by ruggedness, an optical disc of phase change type, and a magneto-optical disc, thereby increasing number of possible superresolution readouts to a great extent.Type: GrantFiled: June 16, 1994Date of Patent: January 20, 1998Assignee: Hitachi, Ltd.Inventors: Akemi Hirotsune, Motoyasu Terao, Yasushi Miyauchi
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Patent number: 5695866Abstract: An optical recording medium comprising a substrate and, provided thereon, a recording layer and a dielectric layer, wherein the dielectric layer comprises a dielectric comprised of a chalcogenide and carbon (C).Type: GrantFiled: April 25, 1996Date of Patent: December 9, 1997Assignee: Toray Industries Inc.Inventors: Yuji Watanabe, Gentaro Ohbayashi, Kusato Hirota
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Patent number: 5688574Abstract: Disclosed is a phase-change optical recording medium which has a reflectance and a signal modulation conformed to the CD standard, and which is usable for recording at the same linear velocity as the reproducing velocity specified in the CD standard. The phase-change optical recording medium comprises a metallic layer, a first protective layer, a recording layer, a second protective layer, and a reflecting layer on a substrate, in which recording is performed through change from a crystalline state to an amorphous state in the recording layer. The recording layer comprises a recording material of a Ge--Te--Sb--Se system, and the recording layer has an average composition in a direction of thickness which satisfies the following relations as represented by atomic %:Ge.gtoreq.40%, and Sb+Se.ltoreq.Type: GrantFiled: March 14, 1996Date of Patent: November 18, 1997Assignee: Hitachi Maxell, Ltd.Inventors: Reiji Tamura, Yoshihiro Ikari, Toshiaki Taii, Norio Ota
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Patent number: 5681632Abstract: On a substrate, a recording layer which reversibly transforms between two states with different optical properties--a crystalline phase and an amorphous phase--by the irradiation of a laser beam, a first and a second dielectric layer on the bottom and the top surfaces of the recording layer, and a third dielectric layer on one surface of the first or the second dielectric layers and on the opposite side with respect to the recording layer are successively laminated, thus preparing an optical information recording medium. The third dielectric layer has a smaller coefficient of thermal expansion than the first and the second dielectric layers, so that the thermal deformation of the first and the second dielectric layers is reduced and the mass transfer of the recording layer is controlled. As a result, the overwrite cycle characteristics of the optical information recording medium are excellent.Type: GrantFiled: February 8, 1996Date of Patent: October 28, 1997Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Hideki Kitaura, Tetsuya Akiyama, Takeo Ohta, Ken'ichi Nagata, Katsumi Kawahara, Noboru Yamada
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Patent number: 5665480Abstract: A copper-lead alloy bearing having a high corrosion resistance, especially a high corrosion resistance to sulfur, comprising a back metal and a copper-lead-based bearing alloy bonded thereto. The copper-lead-based bearing alloy consists of more than 10 but not more than 20% Ni, 0.5 to 8% Sn, 8 to 30% Pb, not less an 0.005 but not more than 0.2% P, and the balance of Cu and incidental impurities.Type: GrantFiled: March 12, 1996Date of Patent: September 9, 1997Assignee: Daido Metal Company Ltd.Inventors: Tadashi Tanaka, Masaaki Sakamoto, Koichi Yamamoto, Tsukimitsu Higuchi
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Patent number: 5652036Abstract: An information recording medium comprising a substrate, a phase-change type recording layer and capable of storing information therein through a phase-change of a portion thereof upon being irradiated by light beam, a first dielectric protecting layer interposed between the substrate and the recording layer, a second dielectric protecting layer formed on the recording layer, a first light-absorptive protecting layer comprising a dielectric material and at least one material selected from metals, semimetals and semiconductor materials and interposed between the recording layer and the first dielectric protecting layer, and a second light-absorptive protecting layer comprising a dielectric material and at least one material selected from metals, semimetals and semiconductor materials and interposed between the recording layer and the second dielectric protecting layer.Type: GrantFiled: September 15, 1995Date of Patent: July 29, 1997Assignee: Kabushiki Kaisha ToshibaInventor: Tadashi Kobayashi
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Patent number: 5645909Abstract: An optical recording medium for a land & groove recording method capable of suppressing crosstalk and cross-erase (increase of jitter) upon increasing the capacity by the increase of track density, wherein a depth for a groove is made greater than 60 nm, at least one of a protection layer, a recording layer and an interference layer is formed to a layer thickness different between the groove and the land, such that reflectance to an optical beam upon irradiation of the optical beam to a predetermined track comprising the land or the groove is equal with each other between a portion in a recorded state and a portion in a unrecorded state of an adjacent track adjacent with the predetermined track, and a land wall for one of the protection layer, the recording layer and the interference layer is made thinner than the thickness of the groove and the land or removed.Type: GrantFiled: October 18, 1995Date of Patent: July 8, 1997Assignee: Fuji Xerox Co., Ltd.Inventors: Hideo Kobayashi, Osamu Ueno, Hironori Gotoh
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Patent number: 5637371Abstract: An optical recording medium comprising a phase change recording layer and a dielectric layer on a substrate is improved in reliability during storage at elevated temperature when the recording layer has a composition of the following formula.[{(Ag,Au).sub.a (Sb,Bi).sub.b (Te,Se).sub.c }.sub.1-d (In,Al,P).sub.d ].sub.1-e M.sub.eLetters a to e are: 0<a .ltoreq.0.20, 0.6.ltoreq.b<1, 0<c<0.40, a+b+c=1, 0<d<0.06, and 0.ltoreq.e.ltoreq.0.20. The recording layer should have an activation energy of at least 3.0 eV as determined from the crystallization temperature versus heating rate of the recording layer sandwiched between dielectrics.Type: GrantFiled: February 12, 1996Date of Patent: June 10, 1997Assignee: TDK CorporationInventors: Junji Tominaga, Ryo Inaba, Susumu Haratani
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Patent number: 5637372Abstract: In an optical recording medium comprising a phase change recording layer on a substrate, the recording layer is essentially of the formula:[{(Ag,Au).sub.a (Sb,Bi).sub.b (Te,Se).sub.c }.sub.1-d (In,Al,P).sub.d ].sub.1-e (Si,Ge,Sn,Pb).sub.ewherein 0.001.ltoreq.a.ltoreq.0.20, 0.40.ltoreq.b.ltoreq.0.90, 0.10.ltoreq.c.ltoreq.0.50, a+b+c=1, 0<d.ltoreq.0.06, and 0.001.ltoreq.e.ltoreq.0.10. The medium can be overwritten at a high linear velocity and remains reliable when stored at elevated temperature.Type: GrantFiled: March 12, 1996Date of Patent: June 10, 1997Assignee: TDK CorporationInventors: Junji Tominaga, Ryo Inaba, Masanori Kosuda, Tatsuya Kato
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Patent number: 5620767Abstract: A light reflecting and heat dissipating material which is capable of reflecting light and dissipating heat transmitted thereto from a layer in contact with or adjacent to the material to cool the layer is composed of an alloy represented by formula (I):Ag.sub.x Pd.sub.1-x (I)wherein 0.6.ltoreq..times..ltoreq.0.85. An optical information recording medium for recording information, reproducing and erasing recorded information is composed of a substrate, a recording layer formed thereon and a light reflection and heat dissipation layer composed of the above light reflecting and heat dissipating material formed on the recording layer.Type: GrantFiled: August 9, 1993Date of Patent: April 15, 1997Assignee: Ricoh Company, Ltd.Inventors: Makoto Harigaya, Yukio Ide, Osamu Nonoyama, Yoshiyuki Kageyama, Hiroko Iwasaki
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Patent number: 5620765Abstract: Flexible digital optical media, such as optical tapes, are provided with an aqueous-applied backing layer which provides excellent performance with regard to runnability, scratch resistance, abrasion resistance, frictional properties and curl characteristics. The backing layer comprises a film-forming water-dispersible polymeric binder and water-dispersible static-dissipative filler particles and a water-dispersible lubricant is either incorporated within the backing layer or forms a thin film over the surface of the backing layer.Type: GrantFiled: May 2, 1995Date of Patent: April 15, 1997Assignee: Eastman Kodak CompanyInventors: Lori J. Shaw-Klein, John B. Murphy
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Patent number: 5616390Abstract: An optical information recording medium is configured so that grooves and lands formed spirally or concentrically on a disk substrate are used as recording tracks. Identification signal areas are provided in which identification signals including positional information are formed in advance on the disk substrate. Information signal areas are formed separately from the identification signal areas so that information signals are recorded by irradiation with a light beam. The identification signals are formed on the grooves and lands not independently of each other, but so that each identification signal is formed so as to be shared by a respective adjacent groove and land. The period of arrangement of the identification signals in the radial direction of the recording tracks is twice the period of the recording tracks and crosstalk at the time of reproduction of the identification signals is suppressed.Type: GrantFiled: July 18, 1995Date of Patent: April 1, 1997Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Naoyasu Miyagawa, Yasuhiro Gotoh
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Patent number: 5614279Abstract: A recording and reproducing medium includes: at least one recording and reproducing layer; and a heating layer which receives light for writing data, converts a part of energy of the light into heat, and selectively heats a desired portion of the recording and reproducing layer, thereby changing optical characteristics of the desired portion, wherein the heating layer converts the part of energy of the light into the heat by a surface plasmon resonance phenomenon.Type: GrantFiled: March 21, 1996Date of Patent: March 25, 1997Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Makoto Kuwamoto, Hiroshi Kohso, Tatsuhiko Inagaki
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Patent number: 5604003Abstract: A description is given of an optical information carrier comprising a substrate (1), a thin reflective layer (5), a dielectric layer (7), a phase-change recording layer on the basis of GeTeSe (9), a dielectric layer (11), an opaque metal reflective layer (13) and a protective layer (15). The information carrier can be inscribed, erased and read by means of a laser-light beam a and, in the inscribed state, complies with the CD-industrial standard. The recording layer (9) comprises an alloy having the composition Ge.sub.x Te.sub.y Se.sub.z, in atom %, wherein47.ltoreq.x.ltoreq.5317.ltoreq.y.ltoreq.4112.ltoreq.z.ltoreq.30andx+y+z.gtoreq.96 and, preferably, equal to 100.Type: GrantFiled: June 15, 1995Date of Patent: February 18, 1997Assignee: U.S. Philips CorporationInventors: James H. Coombs, Wilma van Es-Spiekman, Bernardus A. J. Jacobs, Adrianus P. J. M. Jongenelis
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Patent number: 5591501Abstract: A phase change optical recording medium which includes 1) a substrate having a planar surface; and 2) a plurality of discrete data recording points deposited upon the substrate. The discrete data recording points are formed from a phase change material which changes from a state of a first relative order to a state of a second relative order and visa versa upon the application of optical beam energy. Preferably the phase change material forming the plurality of discrete data recording points is deposited within individual cavities embossed into the surface of the substrate. More preferably the individual cavities are cylindrical or parabolic (bowl shaped) cavities having their central axis perpendicular to the plane of the surface of the substrate.Type: GrantFiled: December 20, 1995Date of Patent: January 7, 1997Assignee: Energy Conversion Devices, Inc.Inventors: Stanford R. Ovshinsky, Hellmut Fritzsche
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Patent number: 5591500Abstract: An information recording medium includes a transparent substrate, an interference layer formed on the transparent substrate, a recording layer formed on the interference layer, a reflective layer formed on the recording layer, and a coating resin formed on the reflective layer. The recording layer has a pit region and a mirror region. The reflectivity of the pit portion changes as a thickness of the recording layer changes. The reflectivity characteristic of the mirror region is selectively adjustable from that of the pit region within a range of thicknesses of the interference layer.Type: GrantFiled: August 18, 1995Date of Patent: January 7, 1997Assignee: NEC CorporationInventor: Yoshitaka Kawanishi
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Patent number: 5585158Abstract: There is disclosed a recordable optical element that has a substrate and on the surface of the substrate, a recording layer and a light reflecting layer. The recording layer has a material with the formula Te.sub.a Ge.sub.b C.sub.c H.sub.d O.sub.e wherein a, b, c, d, and e are atomic percents and (c+d)>40, d>10, a>5, b>5, and e.gtoreq.0 such that a+b+c+d+e=100; and the reflecting layer and the recording layer being selected such that the element R.sub.max or R.sub.min (element reflectivity) is about or greater than 70% at about 780 nm.Type: GrantFiled: June 7, 1995Date of Patent: December 17, 1996Assignee: Eastman Kodak CompanyInventors: Pranab K. Raychaudhuri, Fridrich Vazan
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Patent number: 5580632Abstract: The present invention provides an information recording medium including a first recording film formed on a substrate and having an amorphous phase made of an alloy containing at least Ge and Te, and a second recording film formed on the first recording film and made of a material with a relatively large light absorption coefficient, wherein the alloy of the first recording film exhibits a Raman scattering spectrum having scattering peaks at 140 to 160 cm.sup.-1 and 120 to 130 cm.sup.-1 and no scattering peaks at 100 to 110 cm.sup.-1, and recording is performed by changing optical characteristics by alloying the materials of the first and second recording films by radiating recording light on the first and second recording films.Type: GrantFiled: August 17, 1994Date of Patent: December 3, 1996Assignee: Kabushiki Kaisha ToshibaInventors: Hideki Ohkawa, Motonari Matsubara, Nobuhisa Yoshida
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Patent number: 5573831Abstract: An optical recording medium comprising a transparent substrate; a recording layer on the transparent substrate; a metal reflective layer; and one or more protective layers. These layers are laminated successively on the transparent substrate. The outermost protective layer is formed of an ultraviolet curable resin containing an organic filler and/or an inorganic filler having water absorbency and/or oil absorbency. The protective layer has a printable surface permitting writing characters with writing instruments or ink jet printers.Type: GrantFiled: October 17, 1994Date of Patent: November 12, 1996Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Yuko Suzuki, Shin Aihara, Sumio Hirose
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Patent number: 5569517Abstract: An optical information medium has on a substrate (2) with information-carrying pits (21), a light transmittance control layer (3) including a lower dielectric layer (31), a mask layer (32) and an upper dielectric layer (33). The mask layer has an original state before irradiation of reading light. Upon irradiation of a reading light beam to define a beam spot, the mask layer undergoes a crystal-to-crystal transition in a region (H) of the beam spot depending on the intensity distribution of the beam spot. Multiple reflection condition changes in the transition portion so that the beam spot contributing to read-out is limited to the transition or transition-free region (H or L). The transition temperature is in the range of 200.degree. to 450.degree. C. The mask layer returns to the original state after passage of the beam spot. The invention is also applicable to an optical recording medium having a recording layer above or below the transmittance control layer.Type: GrantFiled: June 5, 1995Date of Patent: October 29, 1996Assignee: TDK CorporationInventors: Junji Tominaga, Susumu Haratani, Ryo Inaba, Tsuneo Kuwahara
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Patent number: 5545489Abstract: A multi-layer sliding bearing having an excellent anti-fretting property, comprises a back steel layer, and a bearing alloy layer formed on the back steel layer. A film of phosphate having a thickness of 0.1-15 .mu.m is formed on a back surface of the back steel layer, thereby enhancing the anti-fretting property of the bearing. The provision of the phosphate film well compatible with a mating material overcomes damage to the bearing due to fretting in a high-speed range. Therefore, the bearing can fully exhibit a bearing performance even under severe conditions of use in a high-speed, high-temperature and high-load range as typically experienced in a high-performance engine.Type: GrantFiled: October 20, 1994Date of Patent: August 13, 1996Assignee: Daido Metal Company Ltd.Inventors: Tadashi Tanaka, Masaaki Sakamoto, Koichi Yamamoto, Tohru Kato, Mitsuru Sugita
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Patent number: 5545454Abstract: Phase-change-type optical recording medium comprises a first dielectric layer, a recording layer made of a phase change material, a second dielectric layer and a reflecting layer wherein the thicknesses of the first and second dielectric layers are determined for a given thickness of the recording layer so that the following conditions are satisfied;.DELTA.A+.DELTA.R.gtoreq.20% and .DELTA.A.gtoreq.5%wherein.DELTA.A=A(cry)-A(amo),A(cry), A(amo): light absorption rates of the recording layer in the crystal state and amorphous state, respectively,.DELTA.R=R(cry)-R(amo),R(cry) and R(amo): light reflection rates of the recording lates in the crystal state and amorphous state, respectively.Type: GrantFiled: March 6, 1995Date of Patent: August 13, 1996Assignee: Matsushita Electric Industrial Inc., Ltd.Inventors: Noboru Yamada, Nobuo Akahira, Kenichi Nishiuchi, Kenichi Nagata, Eiji Ohno, Shigeaki Furukawa
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Patent number: 5543236Abstract: A bearing material is produced by forming a Cu-Pb-system or Pb-bronze-system bearing alloy layer on a steel plate optionally plated with Cu, and forming a Pb alloy overlay containing Zn on the bearing alloy layer so as to enhance corrosion resistance and conformability of the bearing alloy layer. A Cu-Zn alloy layer of 0.5 to 10 .mu.m is present between the Cu matrix of the bearing alloy layer and the overlay. The Cu-Zn alloy layer prevents Sn and In in the overlay from diffusing into the Cu matrix of the bearing alloy layer. The multi-layered slide bearing material can be manufactured by forming the bearing alloy lining layer on the steel plate optionally plated with Cu so as to obtain a bimetal plate, rolling the bimetal plate and a lead alloy plate for the overlay containing Zn to bond the plates in accumulative reduction of 8 to 48%, and thereafter subjecting the plates to heat treatment at 170.degree. to 250.degree. C.Type: GrantFiled: November 29, 1994Date of Patent: August 6, 1996Assignee: Daido Metal Company, Ltd.Inventors: Tadashi Tanaka, Masaaki Sakamoto, Koichi Yamamoto, Koji Kitagawa
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Patent number: 5510164Abstract: A single-sided ablative write-once optical disk is usable without a protective cartridge. The disk includes the conventional radiation-transparent polycarbonate substrate that has one surface serving as the disk outer face and an opposite surface that supports the fluorinated hydrocarbon subbing layer and the tellurium-based active data layer. The tellurium alloy in the data layer flows to form holes when subjected to incident laser radiation through the substrate. A multilayer protective coating is formed over the tellurium-based layer and has an outer surface that serves as the other outer face for the disk. The multilayer protective coating includes a deformable layer formed directly on the tellurium-based layer and a scratch-resistant hardcoat formed on the deformable layer. The deformable layer has sufficient hardness and modulus of elasticity to permit the tellurium alloy to flow at conventional laser power levels. In one embodiment the deformable layer is a silicone elastomer.Type: GrantFiled: December 16, 1994Date of Patent: April 23, 1996Assignee: International Business Machines CorporationInventors: Margaret E. Best, Paul B. Comita, Kurt A. Rubin, Takao Suzuki, Wade W. C. Tang, Yu-Sze Yen
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Patent number: 5506022Abstract: An optical information-recording medium includes a substrate, and a lower protective layer, a recording layer, an upper protective layer, and a reflective layer, formed on the substrate. The recording layer exhibits different optical properties dependent on different thermal histories of a rise and a fall in temperature caused by irradiation of a laser beam on the substrate. The optical information-recording medium has a layer structure constructed such that reflectivity of the optical information-recording medium and the phase of light reflected therefrom vary with the change in the optical properties of the recording layer, with absorptivity of light of the recording layer being larger when the recording layer is in a crystalline state than when the recording layer is in an amorphous state, and at the same time, reflectivity exhibited when the recording layer in the crystalline state being 10% or higher.Type: GrantFiled: June 16, 1994Date of Patent: April 9, 1996Assignee: NEC CorporationInventor: Tatsunori Ide
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Patent number: 5492794Abstract: An information recording medium includes a recording thin film formed on a substrate. The recording thin film consists of a material containing cobalt, antimony, and tellurium as main components, and an energy beam is irradiated on the recording thin film to change optical characteristics of the recording thin film, thereby recording information.Type: GrantFiled: December 21, 1994Date of Patent: February 20, 1996Assignee: NEC CorporationInventors: Yoshitaka Kawanishi, Tatsunori Ide
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Patent number: 5468567Abstract: A slide member includes a surface layer of a Pb alloy on a slide surface for a mating member, and the crystal form of the Pb alloy is formed such that the orientation index in a (h00) plane by Miller indices is in a range of 50 to 100%.Type: GrantFiled: May 9, 1994Date of Patent: November 21, 1995Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Yoshikazu Fujisawa, Takeshi Narishige, Yuzuru Miyazaki