Fe Patents (Class 428/653)
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Patent number: 11881549Abstract: An electrochemical electrode and method for making same that provides enhanced characteristics for use in biosensors, such as blood glucose sensors. The electrode comprises a substrate, a conductive layer deposited on the substrate, and a resistive material layer deposited on the conductive layer. The conductive layer comprises nickel and chromium, and the resistive material layer comprises carbon and a carbon-nitrogen species.Type: GrantFiled: June 5, 2018Date of Patent: January 23, 2024Assignee: Eastman Chemical CompanyInventors: Dennis Lee Ashford, II, Daniel Patrick Puzzo, Spencer Erich Hochstetler
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Patent number: 11827964Abstract: A coated steel member includes: a steel sheet substrate containing, as a chemical composition, by mass %, C: 0.25% to 0.65%, Si: 0.10% to 1.00%, Mn: 0.30% 1.00%, P: 0.050% or less, S: 0.0100% or less, N: 0.010% or less, Ti: 0.010% to 0.100%, B: 0.0005% to 0.0100%, Nb: 0.02% to 0.10%, Mo: 0.10% to 1.00%, Cu: 0.15% to 1.00%, and Ni: 0.05% to 0.25%; and a coating formed on a surface of the steel sheet substrate and containing Al and Fe. The maximum Cu content in a range from the surface to a depth of 5.0 ?m is 150% or more of the Cu content of the steel sheet substrate.Type: GrantFiled: November 20, 2020Date of Patent: November 28, 2023Assignee: NIPPON STEEL CORPORATIONInventor: Shinichiro Tabata
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Patent number: 11807941Abstract: Red rust staining of Al/Zn coated steel strip in “acid rain” or “polluted” environments can be minimised by forming the coating as an Al—Zn—Si—Mg alloy coating with an OT:SDAS ratio greater than a value of 0.5:1, where OT is the overlay thickness on a surface of the strip and SDAS is the measure of the secondary dendrite arm spacing for the Al-rich alpha phase dendrites in the coating. Red rust staining in “acid rain” or “polluted” environments and corrosion at cut edges in marine environments can be minimised in Al—Zn—Si—Mg alloy coatings on steel strip by selection of the composition (principally Mg and Si) and solidification control (principally by cooling rate) and forming Mg2Si phase particles of a particular morphology in interdendritic channels.Type: GrantFiled: October 14, 2022Date of Patent: November 7, 2023Assignee: Bluescope Steel LimitedInventors: Ross McDowall Smith, Qiyang Liu, Bryan Andrew Shedden, Aaron Kiffer Neufeld, Joe Williams, David James Nolan, Wayne Renshaw
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Patent number: 11667988Abstract: The present invention relates to a hot stamped component, a precoated steel sheet used for hot stamping, and a hot stamping process. The hot stamped component of the present invention is provided with a coating of aluminium or an aluminium alloy on at least one surface of the base steel, the coating is produced by interdiffusion between the base steel and a precoating of aluminium or aluminium alloy, and the coating has a thickness of 6 to 26 ?m.Type: GrantFiled: June 17, 2022Date of Patent: June 6, 2023Assignee: Ironovation Materials Technology Co., Ltd.Inventors: Hongliang Yi, Zhiyuan Chang, Zhaoyuan Liu, Dapeng Yang, Xiaochuan Xiong
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Patent number: 11629428Abstract: A metal article comprises two metals, and a first hole and an oxide layer are set correspondingly on the surfaces of the two metals. To avoid the electrolytic corrosion on the interface between the two metals during the formation of the first hole, the disclosure provides a method of manufacturing the metal article. By putting a metal substrate in a first electrolyte including an etching agent and a passivating agent and applying electricity on the metal substrate, the metal article with the first hole is formed without electrolytic corrosion. The disclosure also provides a metal composite, which is formed by setting a material part in the first hole of the metal article.Type: GrantFiled: May 27, 2021Date of Patent: April 18, 2023Assignee: Fulian Yuzhan Precision Technology Co., LtdInventors: Kar-Wai Hon, Ching-Hao Yang, Hao Zhou, Dong-Xu Zhang
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Patent number: 11609205Abstract: A biosensor component that provides enhanced characteristics for use in biosensors, such as blood glucose sensors. The biosensor component comprises a substrate, and a composite layer deposited on the substrate. The composite layer includes a conductive metal component and a resistive material component, where the conductive metal component comprises one or more non-noble metals, and where the resistive material component in the composite layer is present in an amount greater than 20 atomic percent.Type: GrantFiled: May 20, 2019Date of Patent: March 21, 2023Assignee: Eastman Chemical CompanyInventors: Spencer Erich Hochstetler, Dennis Lee Ashford, II, Senthil Nathan Sambandam
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Patent number: 11549167Abstract: A steel plate plated with an aluminum-iron alloy for hot press forming can include a base steel sheet and an alloy plated layer formed on the base steel sheet. The alloy plated layer can include an alloyed layer (I) formed on the base steel sheet and containing, by weight, Al: 5-30%; an alloyed layer (II) formed on the alloyed layer (I) and containing, by weight, Al: 30-60%; and an alloyed layer (III) formed on the alloyed layer (II) and containing, by weight, Al: 20-50%. The alloy layer (II) can have a FeAl (Si) alloy phase dispersed and distributed therein, in which the FeAl (Si) alloy phase includes, by weight, Al: 20-50% and Si: 5-20%, and the number density of the FeAl (Si) alloy phase having a circle-equivalent diameter of 5 ?m or less 15 is 103/mm2 or more.Type: GrantFiled: November 29, 2019Date of Patent: January 10, 2023Assignee: POSCOInventors: Seong-Woo Kim, Jin-Keun Oh, Sang-Heon Kim, Yeol-Rae Cho
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Patent number: 11535916Abstract: An aluminum-based plated steel sheet according to an aspect of the present invention includes: a base material; an aluminum-based plating layer located above the base material; and an intermetallic compound layer that is located between the base material and the aluminum-based plating layer and contains an intermetallic compound of Al and Fe, in which the base material has a chemical component within a predetermined range, the aluminum-based plating layer contains, on average, 80 mass % or more and 97 mass % or less of Al, 3 mass % or more and 15 mass % or less of Si, 0 mass % or more and 5 mass % or less of Zn, 0 mass % or more and 5 mass % or less of Fe, 0 mass % or more and 3 mass % or less in total of one or more selected from the group consisting of Mg and Ca, and impurities so that a total amount thereof is 100 mass %, an average value of a thickness of the intermetallic compound layer is 2 ?m or more and 10 ?m or less, a maximum value of the thickness of the intermetallic compound layer is 10 ?m or morType: GrantFiled: December 5, 2018Date of Patent: December 27, 2022Assignee: NIPPON STEEL CORPORATIONInventors: Soshi Fujita, Yuki Suzuki, Masahiro Fuda, Jun Maki, Hideaki Irikawa, Takashi Aramaki, Tatsuya Kubota
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Patent number: 11512377Abstract: Red rust staining of Al/Zn coated steel strip in “acid rain” or “polluted” environments can be minimised by forming the coating as an Al—Zn—Si—Mg alloy coating with an OT:SDAS ratio greater than a value of 0.5:1, where OT is the overlay thickness on a surface of the strip and SDAS is the measure of the secondary dendrite arm spacing for the Al-rich alpha phase dendrites in the coating. Red rust staining in “acid rain” or “polluted” environments and corrosion at cut edges in marine environments can be minimised in Al—Zn—Si—Mg alloy coatings on steel strip by selection of the composition (principally Mg and Si) and solidification control (principally by cooling rate) and forming Mg2Si phase particles of a particular morphology in interdendritic channels.Type: GrantFiled: September 9, 2020Date of Patent: November 29, 2022Assignee: Bluescope Steel LimitedInventors: Ross McDowall Smith, Qiyang Liu, Bryan Andrew Shedden, Aaron Kiffer Neufeld, Joe Williams, David James Nolan, Wayne Renshaw
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Patent number: 11491764Abstract: The present invention provides an iron-aluminum-based plated steel sheet, and a manufacturing method therefor, the iron-aluminum-based plated steel sheet comprising a base steel sheet and a plated layer formed on the surface of the base steel sheet, wherein the alloy plated layer comprises: a diffusion layer comprising an Fe—Al-based intermetallic compound having a cubic structure; and an alloyed layer formed on the diffusion layer and composed of an alloy phase differing from that of the cubic structure, the thickness of the diffusion layer is 3-20 ?m, and the thickness of the diffusion layer is greater than 50% of the total thickness of the plated layer.Type: GrantFiled: November 29, 2019Date of Patent: November 8, 2022Assignee: POSCOInventors: Jin-Keun Oh, Seong-Woo Kim, Sang-Heon Kim, Yeol-Rae Cho
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Patent number: 11462723Abstract: Presented are electrochemical devices with copper-free electrodes, methods for making/using such devices, and lithium alloy-based electrode tabs and current collectors for rechargeable lithium-class battery cells. A method of manufacturing copper-free electrodes includes feeding an aluminum workpiece, such as a strip of aluminum sheet metal, into a masking device. The masking device then applies a series of dielectric masks, such as strips of epoxy resin or dielectric tape, onto discrete areas of the workpiece to form a masked aluminum workpiece with masked areas interleaved with unmasked areas. The masked workpiece is then fed into an electrolytic anodizing solution, such as sulfuric acid, to form an anodized aluminum workpiece with anodized surface sections on the unmasked areas interleaved with un-anodized surface sections underneath the dielectric masks of the masked areas.Type: GrantFiled: October 28, 2020Date of Patent: October 4, 2022Assignee: GM Global Technology Operations LLCInventors: Xingcheng Xiao, Hongliang Wang, Meinan He
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Patent number: 11453194Abstract: The present invention aims to provide an interlayer film for a laminated glass capable of exhibiting high deaeration properties in a vacuum deaeration method and enabling production of a highly transparent laminated glass, and a laminated glass including the interlayer film for a laminated glass. The present invention relates to an interlayer film for a laminated glass, having a large number of recesses on at least one surface, the recesses each having a groove shape with a continuous bottom and being regularly adjacent and parallel to each other, the recesses each having a radius of rotation R of a bottom of the groove shape with a continuous bottom of 45 ?m or less.Type: GrantFiled: October 13, 2015Date of Patent: September 27, 2022Assignee: SEKISUI CHEMICAL CO., LTD.Inventors: Kazuhiko Nakayama, Hiroaki Inui, Hirofumi Kitano
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Patent number: 11414720Abstract: A high-strength steel sheet for warm working having excellent warm workability, and a method for manufacturing the steel sheet. The steel sheet has a chemical composition including, by mass %, C: 0.05% to 0.20%, Si: 3.0% or less, Mn: 3.5% to 8.0%, P: 0.100% or less, S: 0.02% or less, Al: 0.01% to 3.0%, N: 0.010% or less, one or more selected from Nb: 0.005% to 0.20%, Ti: 0.005% to 0.20%, Mo: 0.005% to 1.0%, and V: 0.005% to 1.0%. The steel sheet has a microstructure including, in terms of area ratio, 10% to 60% of retained austenite, 10% to 80% of ferrite, 10% to 50% of martensite, and 0% to 5% of bainite, in which a C content in the retained austenite is less than 0.40 mass % and the average crystal grain diameter of the retained austenite, the martensite, and the ferrite is 2.0 ?m or less.Type: GrantFiled: January 26, 2017Date of Patent: August 16, 2022Assignee: JFE STEEL CORPORATIONInventors: Hiroshi Hasegawa, Yoshimasa Funakawa
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Patent number: 11414721Abstract: A method for the manufacture of a TWIP steel is provided including: (A) feeding of a slab comprising by weight: 0.5<C<1.2%, 13.0?Mn<25.0%, S?0.030%, P?0.080%, N?0.1%, Si?3.0%, 0.051%?Al?4.0%, 0.1?V?2.5%, and on a purely optional basis, one or more of Nb?0.5%, B?0.005%, Cr?1.0%, Mo?0.40%, Ni?1.0%, Cu?5.0%, Ti?0.5%, 0.06?Sn?0.2%, the remainder of the composition being made of iron and inevitable impurities resulting from the elaboration, (B) reheating the slab and hot rolling the slab to provide a hot rolled slab, (C) coiling the hot rolled slab to provide a coiled slab, (D) first cold-rolling the coiled slab to provide a first cold rolled slab, (E) recrystallization annealing the first cold rolled slab such that an annealed steel sheet having an UTSannealed is obtained and (F) second cold-rolling the annealed steel sheet with a reduction rate CR % that satisfies the following equation A: 1216.472?0.98795*UTSannealed?(?0.0008*UTSannealed+1.0124)*CR %2+(0.0371*UTSannealed?29.583)*CR %.Type: GrantFiled: May 18, 2017Date of Patent: August 16, 2022Assignee: ArcelorMittalInventors: Nicolas Charbonnier, Gerard Petitgand, Sebastien Allain, Marie-Christine Theyssier
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Patent number: 11414732Abstract: Provided are a ferritic stainless steel for automotive exhaust systems with improved heat resistance and condensate corrosion resistance and a method for manufacturing the same. The ferritic stainless steel according to an exemplary embodiment of the present invention includes a stainless steel base material comprising, in % by weight, C: 0.01% or less, Si: 0.5 to 1.0%, Mn: 0.5% or less, P: 0.035% or less, S: 0.01% or less, Cr: 11 to 18%, N: 0.013% or less, Ti: 0.15 to 0.5%, Sn: 0.03 to 0.5%, and the remainder of Fe and other inevitable impurities, and an Al-plated layer formed on the stainless steel base material, wherein the ferritic stainless steel comprises a plating compound comprising (Al19FeMnSi2)5.31 (Aluminum Iron Manganese Silicide) at an interface between the stainless steel base material and the Al-plated layer.Type: GrantFiled: November 27, 2017Date of Patent: August 16, 2022Assignee: POSCOInventor: Hyung Joon Kim
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Patent number: 11401577Abstract: A manufacturing process of a press hardened coated part including providing a furnace containing N zones, each furnace zone being respectively heated at a setting temperature ?1F, ?2F, . . . ?iF, . . . , ?NF, including: providing a steel sheet with thickness th between 0.5 and 5 mm, the steel sheet covered by an aluminium alloy precoating with a thickness between 15 and 50 ?m, the emissivity coefficient being equal to 0.15(1+?), ? being between 0 and 2.4, then cutting the steel sheet to obtain a precoated steel blank, then placing the precoated steel blank in furnace zone 1 for a duration t1 between 5 and 600 s, wherein ?1F and t1 are such that: ?1Fmax>?1F>?1Fmin then transferring the precoated steel blank in the furnace zone 2 heated at a setting temperature ?2F=?1B and maintaining isothermally the precoated steel blank for a duration t2, then transferring the precoated steel blank in further zones (3, . . . i, . . . , N) of the furnace, so to reach a maximum blank temperature ?MB between 850° C.Type: GrantFiled: December 8, 2017Date of Patent: August 2, 2022Assignee: ArcelorMittalInventor: Alexandre Blaise
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Patent number: 11365469Abstract: Provided is a hot-dip aluminized steel sheet with fine-sized spangles produced in a different way from conventional methods, and a method of producing a hot-dip aluminized steel sheet with fine-sized spangles in a different way from conventional methods. The hot-dip aluminized steel sheet includes: a substrate steel sheet; and an aluminum-based coating which is formed by a hot-dip method on the surface of the substrate steel sheet and in which the average B concentration is not less than 0.005 mass % and the sum of the average Ti concentration and the average V concentration is not more than 0.03 mass %.Type: GrantFiled: December 19, 2018Date of Patent: June 21, 2022Assignees: NIPPON STEEL NISSHIN CO., LTD., NS Wheeling-Nisshin, Inc.Inventors: Koutarou Ishii, Shinya Furukawa, Shinichi Koga, Yasunori Hattori, Tetsuhiko Okano, Patrick Edward Pendleton
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Patent number: 11358369Abstract: A plating steel sheet for hot press forming includes: a base steel sheet; an Al—Zn-based plating layer formed on at least one surface of the base steel sheet; and an Fe—Al-based surface alloy layer formed between the base steel sheet and the Al—Zn-based plating layer, wherein the Al—Zn-based plating layer can include 10-30 wt % of Zn, 1 wt % or less of Fe, and the balance of Al and impurities.Type: GrantFiled: December 21, 2018Date of Patent: June 14, 2022Assignee: POSCOInventors: Hyeon-Seok Hwang, Il-Jeong Park, Myung-Soo Kim
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Patent number: 11319623Abstract: A method for producing a steel strip with an aluminium alloy coating layer in a continuous coating process. Also, a steel strip coated with an aluminium alloy coating layer that can be produced in accordance with the method, the use of such a coated steel strip and the product made by using the coated steel strip.Type: GrantFiled: February 23, 2018Date of Patent: May 3, 2022Assignee: TATA STEEL IJMUIDEN B.V.Inventors: Hugo Van Schoonevelt, Guido Cornelis Hensen
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Patent number: 11248275Abstract: A warm-workable high-strength steel sheet having superior warm workability and residual ductility after warm working, and a method for manufacturing such steel sheets. The warm-workable high-strength steel sheet has a chemical composition including, in mass %, C: 0.05 to 0.20%, Si: not more than 3.0%, Mn: 3.5 to 8.0%, P: not more than 0.100%, S: not more than 0.02%, Al: 0.01 to 3.0% and N: not more than 0.010%, the balance being Fe and inevitable impurities. The steel sheet has a microstructure that includes, in area fractions, 10 to 60% retained austenite, 10 to 80% ferrite, 5 to 50% martensite and 0 to 5% bainite, the C content in the retained austenite being less than 0.40 mass %.Type: GrantFiled: January 26, 2017Date of Patent: February 15, 2022Assignee: JFE STEEL CORPORATIONInventors: Hiroshi Hasegawa, Yoshimasa Funakawa
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Patent number: 11242579Abstract: A method to manufacture a hot-rolled high-strength steel sheet or strip with tensile strength of 570 MPa or higher, or preferably 780 MPa or higher, or even more preferably 980 MPa or higher, with an excellent combination of tensile elongation, SFF, and PEF strength.Type: GrantFiled: September 22, 2017Date of Patent: February 8, 2022Assignee: TATA STEEL IJMUIDEN B.V.Inventors: Rolf Arjan Rijkenberg, Maxim Peter Aarnts, Paul Joseph Bellina, Andrew Paul Vass
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Patent number: 11225050Abstract: Disclosed is a steel sheet for hot press forming, which includes: a base steel sheet; and a plating layer disposed on the base steel sheet and including a diffusion layer and a surface layer that are sequentially laminated, wherein the diffusion layer includes an Fe—Al alloy layer and an Fe—Al intermetallic compound layer that are sequentially disposed on the base steel sheet and each include silicon, and an area fraction of the Fe—Al intermetallic compound layer with respect to the diffusion layer is 84.5% to 98.0%.Type: GrantFiled: December 2, 2020Date of Patent: January 18, 2022Assignee: Hyundai Steel CompanyInventors: Sung Min Kim, Hye Rim Choi
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Patent number: 11203802Abstract: Provided are a single layer zinc alloy plated steel material and a fabrication method therefor, the single layer zinc alloy plated steel material comprising a base iron and a zinc alloy plating layer formed on the base iron, wherein the zinc alloy plating layer contains 13-24 wt % of Mg, and the adhesion amount of the zinc alloy plating layer is at most 40 g/m2 (excluding 0 g/m2).Type: GrantFiled: December 21, 2017Date of Patent: December 21, 2021Assignee: POSCOInventors: Young-Jin Kwak, Tae-Yeob Kim
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Patent number: 11136656Abstract: A high strength steel comprises up to about 0.25 wt % C, up to about 2.0 wt % Si, up to about 2.0 wt % Cr, up to 14% Mn, and less than 0.5% Ni. It preferably has an Ms temperature less than 50° C. The high strength steel may have a tensile strength of at least 1000 MPa and total elongations of at least about 25% after hot rolling. It may have a tensile strength of at least 1200 MPa and total elongations of at least about 20% after hot rolling.Type: GrantFiled: May 20, 2016Date of Patent: October 5, 2021Assignee: Cleveland-Cliffs Steel Properties Inc.Inventors: Luis Gonzalo Garza-Martinez, Grant Aaron Thomas, Amrinder Singh Gill
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Patent number: 11078555Abstract: An austenitic, low-density, high-strength steel strip or sheet having a high ductility, and a method of producing the steel strip or sheet, and for its use.Type: GrantFiled: February 28, 2017Date of Patent: August 3, 2021Assignee: TATA STEEL NEDERLAND TECHNOLOGY B.V.Inventors: Shangping Chen, Arunansu Haldar, Alireza Saeed-Akbari, Richard Mostert
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Patent number: 11014195Abstract: Provided is a steel welding component having a steel welding blank with an aluminum or aluminum alloy coating. The welding blank is composed of a steel substrate and coatings comprising an intermetallic compound alloy layer contacting the substrate, and a metal alloy layer on the intermetallic compound alloy layer. On at least one of the coating surfaces of the welding blank, the coating within an area to be welded has been totally removed, and an end face of the coating on the side of the coating within the area to be welded removed has an angle of ? being 0-80° with a plane vertical to a surface of the substrate which is parallel to the welding seam. Also provided are welding methods for the steel welding component. The steel welding blank provided ensures the tensile strength, elongation, and corrosion resistance of a hot-stamped welded joint.Type: GrantFiled: October 17, 2017Date of Patent: May 25, 2021Assignee: Baoshan Iron & Steel Co., Ltd.Inventors: Hua Pan, Yongchao Su, Ming Lei, Lei Shi, Haomin Jiang
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Patent number: 10982296Abstract: An aluminium-zinc-hot-dipped and colour-coated steel plate having yield strength of ?500 MPa and a high elongation and a manufacturing method thereof, with the chemical components in mass percentage of a substrate of the steel plate being: 0.07-0.15% of C, 0.02-0.5% of Si, 1.3-1.8% of Mn, N?0.004%, S?0.01%, Ti?0.15%, Nb?0.050%, and the balance being Fe and other inevitable impurities, and meanwhile satisfying the conditions of: (C+Mn/6)?0.3%; Mn/S?150; Nb satisfying 0.01%?(Nb-0.22C-1.1N)?0.05% where no Ti is contained; Ti satisfying 0.5?Ti/C?1.5 where no Nb is contained; and 0.04%?(Ti+Nb)?0.2% where Ti and Nb are added in combination. The steel plate has a tensile strength of ?550 MPa, an elongation after fracture of ?15%, a good strength and toughness and an excellent corrosion resistance.Type: GrantFiled: July 25, 2016Date of Patent: April 20, 2021Assignee: Baoshan Iron & Steel Co., Ltd.Inventors: Jun Li, Dechao Xu, Xin Liu, Zhilong Ding, Yuling Ren, Xuewei Ye, Hengfa Hu, Hongming Chen
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Patent number: 10968506Abstract: Provided is a high-manganese hot-dip aluminum-coated steel sheet comprising: a base steel sheet containing, by weight, 5% to 35% of Mn, 0.3 to 6% of Al, 0.1 to 1.2% of Si, the balanced amount of Fe, and inevitable impurities; a hot-dip aluminum-coated layer, formed on a surface of the base steel sheet, containing, by weight, 3 to 12% of Si and the balanced amount of Al, and inevitable impurities; and an alloy layer, 0.1 to 10 ?m in thickness with a Fe—Al—Si—Mn-based alloy phase on an interface between the base steel sheet and the hot-dip aluminum-coated layer, containing, by weight, 40 to 70% of Al, 2 to 13% of Si, 3 to 9% of Mn, the balance amount of Fe, and inevitable impurities.Type: GrantFiled: December 23, 2016Date of Patent: April 6, 2021Assignee: POSCOInventors: Heung-Yun Kim, Hyeon-Seok Hwang, Young-Ha Kim
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Patent number: 10947608Abstract: A steel sheet coated with a metallic coating is provided. The coating includes from 1.0 to 22.0% by weight of zinc, from 0.1 to 1.0% by weight of titanium, from 1.6 to 15.0% by weight of silicon, below 0.5% by weight of magnesium, below 0.05% by weight of La or Ce or both, below 0.2% by weight of Sn and optionally, less than 0.3% by weight of additional elements chosen from Sb, Pb, Ca, Mn, Cr, Ni, Zr, In, Hf or Bi. A balance of the coating includes aluminum and optionally unavoidable impurities and residual elements. A microstructure of the coating does not include Al—Zn binary phases. A coated part is also provided.Type: GrantFiled: September 30, 2016Date of Patent: March 16, 2021Assignee: ArcelorMittalInventors: Christian Allely, Tiago Machado Amorim, Beril Corlu, Joost De Strycker
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Patent number: 10906113Abstract: Hot dip Zn-based alloy coated steel sheets (1, 1?) are arc-weld in such a way that (a) a current waveform is a pulsed current waveform in which (i) a peak current and a base current alternate with each other at a pulse period of 1 ms to 50 ms and (ii) an average welding current is 100 A to 350 A and (b) an average welding voltage is 20 V to 35 V. Each of the hot dip Zn-based alloy coated steel sheets (1, 1?) includes a coating layer that contains Zn as a main component and that contains Al at a concentration of 1.0% by mass to 22.0% by mass, and has a coating weight W of 15 g/m2 to 250 g/m2.Type: GrantFiled: February 2, 2016Date of Patent: February 2, 2021Assignee: Nisshin Steel Co., Ltd.Inventors: Kazuaki Hosomi, Tomokazu Nobutoki, Takefumi Nakako
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Patent number: 10753007Abstract: The present invention deals with a process for deposition of indium or indium alloys and an article obtained by the process, wherein the process includes the steps i. providing a substrate having at least one metal or metal alloy surface; ii. depositing a first indium or indium alloy layer on at least one portion of said surface whereby a composed phase layer is formed of a part of the metal or metal alloy surface and a part of the first indium or indium alloy layer; iii. removing partially or wholly the part of the first indium or indium alloy layer which has not been formed into the composed phase layer; iv. depositing a second indium or indium alloy layer on the at least one portion of the surface obtained in step iii.Type: GrantFiled: October 4, 2016Date of Patent: August 25, 2020Assignee: Atotech Deutschland GmbHInventors: Grigory Vazhenin, Jan Sperling, Stefan Pieper, Mauro Castellani, Andreas Kirbs, Dirk Rohde
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Patent number: 10669607Abstract: This invention relates to a sheet or pre-coated blank comprising a steel substrate for heat treatment, overlaid on at least a part of at least one of its principal faces, by a pre-coating having, at least one layer of aluminum or aluminum alloy overlaid, on at least a part of the above-mentioned pre-coating, by a polymerized layer having a thickness between 2 and 30 ?m composed of a polymer that does not contain silicon, and the nitrogen content of which, is greater than 1% by weight expressed in relation to the above-mentioned layer, wherein the above-mentioned polymerized layer contains carbon pigments in a quantity between 3 and 30% by weight, expressed in relation to said layer.Type: GrantFiled: February 13, 2015Date of Patent: June 2, 2020Assignee: ArcelorMittalInventors: Michel Sanadres, Christine Dessain
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Patent number: 10626476Abstract: A high specific strength steel sheet and a method for manufacturing same are disclosed. The high specific strength steel sheet, which is an aspect of the present invention, is characterized in that an Fe—Al-based intermetallic compound having an average particle diameter of 20 ?m or less is homogeneously dispersed in an austenite matrix, the volume fraction of the Fe—Al-based intermetallic compound is 1 to 50%, and the volume fraction of ?-carbide ((Fe,Mn)3AlC) which is a perovskite carbide and has an L12 structure is 15% or less.Type: GrantFiled: December 26, 2013Date of Patent: April 21, 2020Assignees: POSCO, Postech Academy-Industry FoundationInventors: Han-Soo Kim, Nack-Joon Kim, Yoon-Uk Heo, Sang-Heon Kim, Jae-Sang Lee, Jin-Mo Koo
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Patent number: 10590522Abstract: An Al—Fe alloy coated steel sheet includes a base steel sheet and an alloy coating layer, wherein the base steel sheet includes, by wt %, C: 0.1%˜0.5%, Si: 0.01%˜2%, Mn: 0.01%˜10%, P: 0.001%˜0.05%, S: 0.0001%˜0.02%, Al: 0.001%˜1.0%, N: 0.001%˜0.02%, and the balance of Fe and other impurities, wherein the alloy coating layer includes: an Al—Fe alloy layer I formed on the base steel sheet and having a Vickers hardness of 200˜800 Hv; an Al—Fe alloy layer III formed on the Al—Fe alloy layer I and having a Vickers hardness of 700˜1200 Hv; and an Al—Fe alloy layer II formed in the Al—Fe alloy layer III continuously or discontinuously in a length direction of the steel sheet, and having a Vickers hardness of 400˜900 Hv, wherein an average oxygen content at a depth of 0.1 ?m from a surface of the oxide layer is 20% or less by weight.Type: GrantFiled: December 23, 2016Date of Patent: March 17, 2020Assignee: POSCOInventors: Jin-Keun Oh, Yeol-Rae Cho, Il-Ryoung Sohn, Yong-Soo Kim
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Patent number: 10392686Abstract: A Mg-containing Zn alloy coated steel including a steel and a metallic coating layer placed on a surface of the steel, in which the metallic coating layer is a layered structure of plural flat-form metal particles having a particle diameter of from 5 to 100 ?m, and a thickness of from 0.5 to 30 ?m, the composition of the metal particles include Zn from 11 to 80 mass %, Al from 3 to 80 mass %, Mg from 8 to 45 mass %, and Ca from 1 to 5 mass %, and the Zn, Al, and Mg content satisfy Zn+Al>Mg, and in which the metal particles include a quasicrystalline phase, an MgZn2 phase, and optionally a balance structure.Type: GrantFiled: September 29, 2016Date of Patent: August 27, 2019Assignee: NIPPON STEEL CORPORATIONInventors: Nobuyuki Shimoda, Kohei Tokuda, Kenichiro Matsumura, Yasuto Goto
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Patent number: 10351943Abstract: A Mg-containing Zn alloy coated steel including a steel and a metallic coating layer placed on a surface of the steel, in which the metallic coating layer is a layered structure of plural flat-form metal particles having a particle diameter of from 5 to 100 ?m, and a thickness of from 0.5 to 30 ?m, the composition of the metal particles include Zn from 11 to 80 mass %, Al from 3 to 80 mass %, Mg from 8 to 45 mass %, and Ca from 1 to 5 mass %, and the Zn, Al, and Mg content satisfy Zn+Al>Mg, and in which the metal particles include a quasicrystalline phase, an MgZn2 phase, and optionally a balance structure.Type: GrantFiled: September 29, 2016Date of Patent: July 16, 2019Assignee: NIPPON STEEL CORPORATIONInventors: Nobuyuki Shimoda, Kohei Tokuda, Kenichiro Matsumura, Yasuto Goto
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Patent number: 10323292Abstract: A process for producing a three-dimensionally shaped steel component from a steel sheet with a metallic coating may involve hot forming the steel sheet into the steel component. The metallic coating may involve an Fe—Al-based alloy. To protect the steel sheet or the steel component against scale formation, the Fe—Al-based alloy may be applied directly to the steel sheet by galvanic coating and/or physical vapor deposition. The coating produced in this way may contain 30-60% by weight Fe, a balance of Al, and, in some cases, 0.1-10% by weight Mg, 0.1-5% by weight Ti, 0.1-10% by weight Si, 0.1-10% by weight Li, and/or 0.1-10% by weight Ca. Before heating the coated steel sheet as part of the hot forming process, the coated steel sheet may have an Fe—Al phase is stable to above 900° C.Type: GrantFiled: April 29, 2015Date of Patent: June 18, 2019Assignees: ThyssenKrupp Steel Europe AG, ThyssenKrupp AGInventors: Bernd Schuhmacher, Christian Schwerdt, Axel Schrooten, Ralf Bause
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Patent number: 10287440Abstract: A steel product may include a metallic anticorrosion coating of an aluminum alloy. So that such a steel product possesses high media resistance, more particularly high acid resistance and corrosion resistance, the steel product may be immersed in a liquid-melt coating bath that includes an aluminum alloy. In addition to Aluminum and unavoidable impurities, the aluminum alloy may include at least one of 0.2-2% by weight Mn or 0.2-7% by weight Mg, 0.5-5% by weight Fe, and at least one of 0.05-0.4% by weight Ti or 0.05-0.4% by weight Zr. A method for producing such steel products may involve providing a steel product in a hot-rolled or cold-rolled state, activating a surface of the steel product to remove passive oxides, and coating the surface-activated steel product by immersion in a liquid-melt coating bath that comprises an aluminum alloy having the aforementioned composition.Type: GrantFiled: June 30, 2015Date of Patent: May 14, 2019Assignees: THYSSENKRUPP STEEL EUROPE AG, THYSSENKRUPP AGInventors: Marc Blumenau, Oliver Moll, Michael Peters, Thiemo Wuttke
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Patent number: 10106866Abstract: An exemplary embodiment of the present invention provides a coated steel sheet on which a magnesium-aluminum alloy coating layer is formed, including: a steel sheet; and a coating layer configured to include a first magnesium-aluminum alloy layer formed on a top surface of the steel sheet and a second magnesium-aluminum alloy layer formed on a top surface of the first magnesium-aluminum alloy layer, wherein a magnesium content of the first magnesium-aluminum alloy layer is higher than that of the second magnesium-aluminum alloy layer.Type: GrantFiled: December 17, 2014Date of Patent: October 23, 2018Assignees: POSCO, RESEARCH INSTITUTE OF INDUSTRIAL SCIENCE & TECHNOLOGYInventors: Jae In Jeong, Ji Hoon Yang, Tae Yeob Kim, Yong Hwa Jung
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Patent number: 10041139Abstract: A high-strength steel sheet according to the present invention comprises, by weight, 10.0-15.0% Mn, 6.0-9.0% Al, 0.5-2.0% Cr, 0.8-1.6% C, and 0.001-0.01% N, and further comprises, by weight, 0.02-0.1% V, 0.005-0.015% Nb, and 0.005-0.02% Mo, or further comprises 0.1-0.5 wt % TiAl particles. The high-strength steel sheet has a mixed structure comprising austenite and a fine k-carbide having a mean particle diameter of 10-500 nm.Type: GrantFiled: June 27, 2014Date of Patent: August 7, 2018Assignee: HYUNDAI STEEL COMPANYInventors: Jun Ho Chung, Seong-Ju Kim, Hyo Dong Shin
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Patent number: 9976203Abstract: A cold rolled, annealed TRIP steel sheet which has a composition including (in wt. %): C: 0.1-0.3; Mn: 4-10, Al: 0.05-5, Si: 0.05-5; and Nb: 0.008-0.1, the remainder being iron and inevitable residuals. The cold rolled sheet has an ultimate tensile strength of at least 1000 MPa, and a total elongation of at least 15%. The cold rolled sheet may have at least 20% retained austenite in its microstructure and may have greater than 50% lath-type annealed ferrite structure. The cold rolled sheet may have an ultra fine grain size of less than 5 micron for the retained austenite and ferrite.Type: GrantFiled: January 22, 2013Date of Patent: May 22, 2018Assignee: ArcelorMittalInventors: Hyun Jo Jun, Narayan Subramaniam Pottore, Nina Michailovna Fonstein, Oleg N. Yakubovsky
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Patent number: 9963758Abstract: Provided is a hot press-formed (HPF) member with excellent powdering resistance at the time of press forming. The HPF member includes a hot-dip coating layer containing Al on a surface of a base steel sheet. The base steel sheet includes, based on wt %, 0.18-0.25% of C, 0.1-1.0% of Si, 0.9-1.5% of Mn, 0.03% or less of P, 0.01% or less of S, 0.01-0.05% of Al, 0.05-0.5% of Cr, 0.01-0.05% of Ti, 0.001-0.005% of B, 0.009% or less of N, the balance Fe, and the other impurities. The hot-dip coating layer comprises a soft diffusion layer and a hard alloy layer. The alloy layer has a Tau phase in the range of 10-30%, in terms of area percent.Type: GrantFiled: August 29, 2016Date of Patent: May 8, 2018Assignee: POSCOInventors: Il-Ryoung Sohn, Dae-Chul Bae, Heung-Yun Kim
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Patent number: 9708683Abstract: Coated steel having a well defined and uniform thickness is useful and advantageous for preparing products by hot stamping. Products prepared by hot stamping such a steel are particularly advantageous when subjected to a subsequent spot welding step.Type: GrantFiled: September 15, 2012Date of Patent: July 18, 2017Assignee: ArcelorMittal FranceInventors: Pascal Drillet, Dominique Spehner, Ronald Kefferstein
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Patent number: 9701177Abstract: A ceramic coated heat exchanger component and method for making the ceramic coated heat exchanger component by creating porous metal oxide coatings on an aluminum surface of the heat exchanger component by plasma electrochemical deposition of a metal oxide on the aluminum surface and layering an odor neutralization agent on the porous metal oxide ceramic coatings to form an odor remediation ceramic coating on the heat exchanger.Type: GrantFiled: April 2, 2009Date of Patent: July 11, 2017Assignees: Henkel AG & Co. KGaA, DENSO Manufacturing Michigan, Inc.Inventors: Chris McDermott, Jason Amoss, Rajaram Shembekar, Shawn E. Dolan
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Patent number: 9683604Abstract: Provided is a plain bearing including a backing layer, a bearing metal layer, an optional intermediate layer and an overlay. The overlay includes a plurality of sub-layers disposed one on top of the other, which sub-layers include two or more relatively soft sub-layers and one or more relatively hard sub-layer. The soft and hard sub-layers are arranged alternately with respect to one another. Each soft sub-layer includes a metal or metal alloy, and each hard sub-layer includes one or more intermetallic compound. A method of making a coated plain bearing is also provided.Type: GrantFiled: June 18, 2015Date of Patent: June 20, 2017Assignee: Daido Metal Company Ltd.Inventors: Yi Zhang, Madan Pal, Elena Banchelli, Ian Kerr
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Patent number: 9518603Abstract: In a bearing apparatus provided herein a hard steel shaft is an opposite shaft of an Al—Sn—Si based alloy plain bearing. Its wear resistance is enhanced. The bearing apparatus comprises a steel shaft having hardness of Hv 500 or more at least on a surface thereof, and a plain bearing. The plain bearing is formed of an aluminum alloy containing 2 to 10 mass % of Si, 8 to 18 mass % Sn, and the balance being Al and unavoidable impurities, wherein the volume of Sn phase is 50% or more of the volume of the Si particles(the average particle diameter of Si of the aluminum alloy is 4 to 10 ?m). The aluminum alloy has a hardness of Hv 45 or more.Type: GrantFiled: April 22, 2011Date of Patent: December 13, 2016Assignee: TAIHO KOGYO CO., LTD.Inventors: Shinichiro Sakamoto, Atsushi Koyama
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Patent number: 9493868Abstract: An aluminum or aluminum alloy-coated steel material includes base steel; and a coating layer formed on a surface of the base steel and containing by mass % Mg: 6% to 10%, Si: 3% to 7%, Fe: 0.2% to 2%, Mn: 0.02% to 2%, and the balance as Al and incidental impurities, wherein the coating layer has pseudoternary eutectic microstructures of ?Al—Mg2Si—(Al—Fe—Si—Mn) and an area ratio of the pseudoternary eutectic microstructures in the coating layer is at least 30%.Type: GrantFiled: December 10, 2012Date of Patent: November 15, 2016Assignees: JFE Steel Corporation, Tokyo Institute of TechnologyInventors: Tooru Tsuru, Toshio Maruyama, Tatsuo Sato, Masao Takeyama, Masahiro Yoshida, Sakae Fujita, Sachiko Suzuki, Satoru Ando, Hiroki Nakamaru
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Patent number: 9353424Abstract: A high strength steel sheet containing chemical components of, in mass %, C: 0.20 to 0.42%, Si: 0.06 to 0.5%, Mn: 0.2 to 2.2%, Cr: 0.1 to 2.5%, B: 0.0005 to 0.01%, O: 0.0020 to 0.020%, Al: 0.001 to 0.03%, Ti: 0.001 to 0.05%, N: 0.1% or less, P: 0.03% or less, S: 0.02% or less, and the balance: Fe and inevitable impurities. In steel, 5×103 pieces per mm2 or more to 1×105 pieces per mm2 or less of Mn oxides having a maximum length of 1 ?m or more to 5 ?m or less are present, and 1.7×102 pieces per mm2 or more to 5×103 pieces per mm2 or less of Mn—Si composite oxides having a short-axial length of 1 ?m or more and a longitudinal length of 10 ?m or less are present.Type: GrantFiled: March 13, 2014Date of Patent: May 31, 2016Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Hiroyuki Tanahashi, Toshimasa Tomokiyo
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Patent number: 9302449Abstract: Provided is a hot dip zinc (Zn) alloy plated steel sheet having excellent corrosion resistance and surface qualities, and a method of manufacturing the same. For this purpose, provided is a high corrosion resistant hot dip Zn alloy plated steel sheet which includes an underlying steel sheet and a hot dip Zn alloy plating layer, wherein a composition of the hot dip Zn alloy plating layer includes 1 to 3 wt % of aluminum (Al), 1.5 to 4.0 wt % of magnesium (Mg), and Zn and unavoidable impurities as a remainder, in which Al+Mg is in a range of 2.5 to 7.0 wt % and Al: (Al+Mg) ratio is in a range of 0.38 to 0.48, and a method of manufacturing the high corrosion resistant hot dip Zn alloy plated steel sheet.Type: GrantFiled: December 26, 2011Date of Patent: April 5, 2016Assignee: POSCOInventors: Sang-Heon Kim, Young-Sool Jin, Min-Suk Oh, Su-Young Kim, Bong-Hwan Yoo
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Patent number: 9234267Abstract: There is provided a hot-dip Al—Zn coated steel sheet that has a steel sheet containing Si and Mn as a base steel sheet and has excellent coating appearance and corrosion resistance. The Al—Zn coating layer has an Al content in the range of 20% to 95% by mass. The Al—Zn coating layer has a Ca content in the range of 0.01% to 10% by mass. Alternatively, the Ca and Mg content is in the range of 0.01% to 10% by mass. A steel sheet surface layer within 100 ?m from a surface of the base steel sheet directly under the Al—Zn coating layer contains less than 0.060 g/m2 per surface of an oxide of at least one selected from Fe, Si, Mn, Al, P, B, Nb, Ti, Cr, Mo, Cu, and Ni in total.Type: GrantFiled: November 25, 2011Date of Patent: January 12, 2016Assignee: JFE Steel CorporationInventors: Masahiro Yoshida, Hiroki Nakamaru