Halogen-containing Patents (Class 428/691)
  • Patent number: 6815095
    Abstract: A binderless stimulable phosphor screen is provided, comprising a vapor deposited phosphor layer on a support, wherein between the support and the phosphor layer a ceramic layer is present, wherein said ceramic layer preferably comprises a mixture of pigments so that the optical density of the phosphor screen is higher for the stimulating wavelength than for the stimulated emission wavelength of the vapor deposited phosphor.
    Type: Grant
    Filed: November 21, 2002
    Date of Patent: November 9, 2004
    Assignee: AGFA-Gevaert
    Inventors: Paul Leblans, Luc Struye, Ludo Joly
  • Publication number: 20040028944
    Abstract: This invention relates to highly reliable organic electroluminescent (EL) materials and devices exhibiting high luminance, high light emitting efficiency, minimal deterioration in light emission, usability at high temperature and good storage stability.
    Type: Application
    Filed: August 11, 2003
    Publication date: February 12, 2004
    Inventors: Tatsuo Mori, Teruyoshi Mizutani, Toru Takeda, Koichi Yamashita
  • Patent number: 6638646
    Abstract: Poly(arylenevinylenes) comprising at least 20% of recurring units of the formula (I), where the symbols and indices have the following meanings: Aryl: is an aryl group having 4 to 14 carbon atoms; R′: is a substituent which is either in the labeled phenylene position 5 or 6 and is CN, F, Cl, N(R1R2) or a straight-chain, branched or cyclic alkyl, alkoxy or thioalkoxy group having 1 to 20 carbon atoms, in which, in addition, one or more H atoms may be replaced by F; R″: are identical or different and are CN, F, Cl or a straight-chain, branched or cyclic alkyl or alkoxy group having 1 to 20 carbon atoms, where one or more non-adjacent CH2 groups may be replaced by —O—, —S—, —CO—, —COO—, —O—CO—, —NR1—, —(NR2R3)+—A− or —CONR4—, and where one or more H atoms may be replaced by F, or an aryl group having 4 to 14 carbon atoms, which may be substituted by one or more non-aro
    Type: Grant
    Filed: June 28, 2002
    Date of Patent: October 28, 2003
    Assignee: Semiconductors GmbH
    Inventors: Hubert Spreitzer, Willi Kreuder, Heinrich Becker, Hermann Schenk, Nu Yu
  • Patent number: 6626011
    Abstract: The invention provides a monomode optical fiber and a monomode preform (2) having a mother preform (22) housed in an outer sleeve tube (20). It is characterized in that it also includes an intermediate tube (21) between the mother preform (22) and the outer tube (20), the intermediate tube (21) possessing viscosity at fiber-drawing temperature which is less than the viscosity(ies) at fiber-drawing temperature of the mother preform (22) and of the outer tube (20). The invention also provides a method of manufacturing a monomode optical fiber. The fiber has a core that is better centered and less deformed than in the prior art. An application of the invention lies in making an optical amplifier.
    Type: Grant
    Filed: May 13, 1998
    Date of Patent: September 30, 2003
    Assignee: Alcatel
    Inventors: Frédéric Chiquet, Marylise Le Thuaut, Jean-Jacques Girard, Pascal Baniel
  • Patent number: 6597012
    Abstract: An organic electroluminescent device having a luminescent layer interposed between an anode and a cathode, on a substrate, wherein a layer containing an electron-accepting compound containing a boron atom represented by the following formula (I): wherein each of Ar1 to Ar3 which are independent of one another, is an aromatic hydrocarbocyclic group or aromatic heterocyclic group which may have a substituent, and a hole transport compound, is formed between the luminescent layer and the anode.
    Type: Grant
    Filed: May 1, 2002
    Date of Patent: July 22, 2003
    Assignees: Mitsubishi Chemical Corporation
    Inventors: Junji Kido, Yoshiharu Sato
  • Patent number: 6555253
    Abstract: In an organic electroluminescent device constructed by providing at least an emitting layer and a carrier transport layer using an organic material between a hole injection electrode and an electron injection electrode, at least one of the emitting layer and the carrier transport layer contains a chelate compound of a chromone derivative with zinc or aluminum, a chelate compound of a 3-hydroxyflavone derivative with a metal, a chelate compound composed of an 8-quinolinol derivative dimer and another ligant which are coordinated to a metal, or a chelate compound composed of two 8-quinolinol derivatives coordinated to a metal and one halogen bonded thereto.
    Type: Grant
    Filed: June 24, 1999
    Date of Patent: April 29, 2003
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Yuji Hamada, Masayuki Shono, Yasuhiko Matsushita
  • Patent number: 6521359
    Abstract: Provided is a polymeric fluorescent substance which emits a fluorescence in a solid state, which comprises the following repeating unit in an amount of 20 mol % or more based on the total amount of all repeating units, in the formula, X1 represents a group selected from the group consisting of —CR3═CR4—, —C≡C—, —SiR5R6—, —NR7—, —CO—, —CO—O—, —O—CO—, —SO2—, a carbon-carbon single bond, —O— and —S—. The polymeric fluorescent substance has strong fluorescence, and can be suitably used as a polymer LED and a dye for laser.
    Type: Grant
    Filed: March 31, 2000
    Date of Patent: February 18, 2003
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takanobu Noguchi, Shuji Doi, Makoto Kitano, Fumi Yamaguchi
  • Patent number: 6495273
    Abstract: A light-emitting polymer and its preparation method, the polymer being excellent in electron injection and transport ability as well as hole injection and transport ability in an EL device, the EL device manufactured from the polymer being also emittable in the blue emission region, in which the EL device from an inorganic material is not mostly emittable. The light-emitting polymer of the invention is an alternated copolymer having repeated units (arylenevinylene units) excellent in hole injection and transport ability and repeated units (fluorinated tetraphenyl units) excellent in electron injection and transport ability with alternated order, as shown in formula (II). An EL device manufactured from the light-emitting polymer, a fluorinated tetraphenyl derivative of formula (I), which is used as a monomer to prepare the light-emitting polymer, and their preparation methods.
    Type: Grant
    Filed: September 15, 1999
    Date of Patent: December 17, 2002
    Assignee: Electronics and Telecommunications Research Institute
    Inventors: Do Hoon Hwang, Tae Hyoung Zyung, Lee Mi Do, Hye Yong Chu
  • Patent number: 6440587
    Abstract: A phosphor powder for producing a high resolution phosphor screen and a phosphor screen are provided. The phosphor screen comprises a substrate, an infrared-absorbing layer, and a phosphor layer coated on the infrared-absorbing layer, wherein the phosphor layer comprises a phosphor powder in which a substantial amount of particles in the powder have a particle size as measured in the longest dimension of greater than 0 and less than about 5 microns. The phosphor screen may also comprise a black, infrared-absorbing substrate with the phosphor layer coated on the substrate. The phosphor powder is formed by preparing a phosphor composition, sintering the composition to form ingots, grinding the ingots to form a powder wherein a substantial amount of particles in the powder have a particle size of greater than 0 and less than about 5 microns, reactivating the powder in an inert atmosphere to a temperature of from about 500° C. to about 550° C.
    Type: Grant
    Filed: August 28, 2000
    Date of Patent: August 27, 2002
    Assignee: The Institute For Radiological Image Sciences, Inc.
    Inventors: Fauzia Jamil, Peter K. Soltani
  • Publication number: 20020076550
    Abstract: A luminescent coating compound of organic binder and luminescent fibers containing at least one organic binder and fibers which of a fiber-forming material with at least one luminescent dye or pigment distributed therein. Also a process of producing coatings of such compounds and articles with such coatings.
    Type: Application
    Filed: September 24, 2001
    Publication date: June 20, 2002
    Inventors: Michael Kohla, Christoph Frigge
  • Publication number: 20020064680
    Abstract: Poly(arylenevinylenes) comprising at least 20% of recurring units of the formula (I), 1
    Type: Application
    Filed: August 22, 2000
    Publication date: May 30, 2002
    Inventors: Hubert Spreitzer, Willi Kreuder, Heinrich Becker, Hermann Schenk, Nu Yu
  • Patent number: 6387297
    Abstract: A rare earth fluoride phosphor favorably employable for the incorporation into a radiographic intensifying screen has the following formula (I) or (II): (Gd1−xLnx)F3·aMX  (I) LnF3·aMX:yA  (II) in which Ln is Y, La or Lu; M is Na, K, Cs or Rb; X is F, Cl, Br or I; A is Ce, Tb or Bi; and a, x and y numbers satisfying the conditions of 0<a≦0.03 and 0≦x≦0.1, 0<y≦0.1, respectively.
    Type: Grant
    Filed: June 4, 1999
    Date of Patent: May 14, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yuji Isoda
  • Publication number: 20020041977
    Abstract: An europium activated cesium bromide phosphor having the formula of CsBr:xEu [0<x≦0.2], in which a relationship between an emission intensity (IE) of Eu2+ and a coloring intensity (IF) at F (Br−) center satisfies the condition of 0.2≦IExIF, and/or in which a ratio of Eu2+ to Eu3+ contained in the phosphor in terms of emission intensity satisfies the condition of 5×10−5≦Eu3+/Eu2+≦0.1 gives an increased stimulated emission amount and is favorably employed for producing a radiation image storage sheet.
    Type: Application
    Filed: June 25, 2001
    Publication date: April 11, 2002
    Inventors: Yasuo Iwabuchi, Yuji Isoda
  • Patent number: 6368731
    Abstract: Electroluminescent assembly comprising a substrate, an anode, an electroluminescent element and a cathode, where at least one of the two electrodes is transparent in the visible spectral region and the electroluminescent element contains one or more zones selected from the group consisting of hole injection zone, hole transport zone, electroluminescent zone, electron transport zone and electron injection zone in the order specified, where each of the zones present may also assume functions of the other zones mentioned, characterized in that the electroluminescent element contains a boron complex of an 8-aminoquinoline derivative.
    Type: Grant
    Filed: June 30, 1999
    Date of Patent: April 9, 2002
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut-Werner Heuer, Rolf Wehrmann, Andreas Elschner
  • Patent number: 6359211
    Abstract: This invention relates to dye sensitized polycrystalline photoelectrochemical solar cells for use in energy transduction from light to electricity. It concerns the utility of highly absorbing organic chromophores as sensitizers in such cells and the degree to which they may be utilized alone and in combination to produce an efficient photoelectrochemical cell, e.g., a regenerative solar cell.
    Type: Grant
    Filed: June 19, 2000
    Date of Patent: March 19, 2002
    Assignee: Chemmotif, Inc.
    Inventors: Mark T. Spitler, Anne Ehret, Louis S. Stuhl
  • Publication number: 20020013451
    Abstract: A polymeric material comprising alternate substituted fluorene and phenylene units, as represented by the following formula 1
    Type: Application
    Filed: April 24, 2001
    Publication date: January 31, 2002
    Inventors: Wei Huang, Wang Lin Yu, Jian Pei, Soo Jin Chua
  • Patent number: 6323266
    Abstract: An extended life fluorescent polyvinyl chloride sheeting and a method for forming the sheeting are disclosed. The sheeting includes a polyvinyl chloride film having a fluorescent colorant incorporated therein. A protective polymer layer is attached to the polyvinyl chloride film. A light filtering agent is incorporated into the protective layer, wherein the filter agent blocks the 425 nm and lower wavelengths of the visible spectrum.
    Type: Grant
    Filed: January 8, 2001
    Date of Patent: November 27, 2001
    Assignee: Reflexite Corporation
    Inventor: Edward D. Phillips
  • Patent number: 6316130
    Abstract: Electroluminescent assembly comprising a substrate, an anode, an electroluminescent element and a cathode, where at least one of the two electrodes is transparent in the visible spectral region and the electroluminescent element contains one or more zones selected from the group consisting of hole injection zone, hole transport zone, electroluminescent zone, electron transport zone and electron injection zone in the order specified, where each of the zones present may also assume functions of the other zones mentioned, characterized in that the electroluminescent element contains an azomethine-metal complex.
    Type: Grant
    Filed: July 1, 1999
    Date of Patent: November 13, 2001
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut-Werner Heuer, Rolf Wehrmann, Andreas Elschner
  • Publication number: 20010024738
    Abstract: Multifunctional electroactive copolymers are provided. The copolymers may be A-B-A triblock copolymers, brush-type graft copolymers, or variations thereof. In a preferred embodiment, the copolymers are “dual use” in that they comprise both a light emitting segment and a charge transport segment. Methods of synthesizing the novel electroactive copolymers are provided as well, as are opto-electronic devices, particularly LEDs, fabricated with the novel copolymers.
    Type: Application
    Filed: March 27, 2001
    Publication date: September 27, 2001
    Inventors: Craig Jon Hawker, Gerrit Klaerner, Jeong-Ik Lee, Victor Yee-Way Lee, Robert Dennis Miller, John Campbell Scott
  • Patent number: 6294273
    Abstract: Electroluminescent assembly comprising a substrate, an anode, an electroluminescent element and a cathode, where at least one of the two electrodes is transparent in the visible spectral region and the electroluminescent element contains one or more zones selected from the group consisting of hole injection zone, hole transport zone, electroluminescent zone, electron transport zone and electron injection zone in the stated order, where each of the zones present can also assume functions of the other zones mentioned, characterized in that the electroluminescent element contains an N-alkyl-2,2′-imino-bis-(8-hydroxyquinoline)-metal complex.
    Type: Grant
    Filed: June 8, 1999
    Date of Patent: September 25, 2001
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut-Werner Heuer, Rolf Wehrmann, Andreas Elschner
  • Publication number: 20010021455
    Abstract: A linear aperture deposition apparatus and process are provided for coating substrates with sublimed or evaporated coating materials. The apparatus and process are particularly suited for producing flexible films having an optical interference coating with a very high surface thickness uniformity and which is substantially free of defects from particulate ejection of a source material. The apparatus includes a source box containing a source material, a heating element to sublime or evaporate the source material, and a chimney to direct the source material vapor from the source box to a substrate. A flow restricting baffle having a plurality of holes is positioned between the source material and the substrate to confine and direct the vapor flow, and an optional floating baffle is positioned on the surface of the source material to further restrict the vapor flow, thereby substantially eliminating source material spatter.
    Type: Application
    Filed: January 10, 2001
    Publication date: September 13, 2001
    Inventors: Matthew R. Witzman, Richard A. Bradley, Christopher W. Lantman, Eric R. Cox
  • Patent number: 6287713
    Abstract: Electroluminescent assembly comprising a substrate, an anode, an electroluminescent element and a cathode, where at least one of the two electrodes is transparent in the visible spectral region and the electroluminescent element contains one or more zones selected from the group consisting of hole injection zone, hole transport zone, electroluminescent zone, electron transport zone and electron injection zone in the order specified, where each of the zones present may also assume functions of the other zones mentioned, characterized in that the electroluminescent element contains a boron complex of an 8-hydroxyquinoline derivative.
    Type: Grant
    Filed: June 29, 1999
    Date of Patent: September 11, 2001
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut Werner Heuer, Rolf Wehrmann, Andreas Elschner
  • Patent number: 6238774
    Abstract: A high temperature oxide superconductor is efficiently protected from the affects of water and acids by forming a passivation layer of a fluoride. The fluoride layer comprises a fluoride composed of one or more elements composing the oxide superconductor and/or one or more elements that can compose an oxide superconductor by replacing at least in part one or more elements composing the oxide superconductor.
    Type: Grant
    Filed: June 14, 1994
    Date of Patent: May 29, 2001
    Assignee: Fujitsu Limited
    Inventors: Kyung-ho Park, Nagisa Ohsako
  • Patent number: 6203725
    Abstract: According to the present invention, when the traveling of an automatic guided vehicle is optically controlled, a traveling controlling means containing a luminescent compound satisfying the following formula (1) is placed in a predetermined range for traveling of the automatic guided vehicle: A−B≧150 nm  (1) wherein, A represents the minimum wavelength end (nm) of the luminescent compound, and B represents the maximum wavelength end (nm) of an irradiation light used for the traveling controlling.
    Type: Grant
    Filed: July 18, 1997
    Date of Patent: March 20, 2001
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Akira Ogiso, Yasuhisa Fujii, Kyozo Kurita, Masataka Iwata, Shizuo Kuroda, Hisato Itoh
  • Patent number: 6168876
    Abstract: An improved, “fail-safe” safety device comprising, in combination, a backlighted fluorescent film and a retroreflective sheet.
    Type: Grant
    Filed: March 15, 1994
    Date of Patent: January 2, 2001
    Inventors: Elizabeth M. Thorp, Stephen N. Thorp
  • Patent number: 6132640
    Abstract: Quinoline compound, zinc halogenide complex and zinc complex suited for use in an electro-luminescence (EL) element, a fluorescent material and an ultraviolet absorption material, and a preparation process for these compounds are described. These compounds and a tautomer of the same have a strong luminescent intensity and are used for an EL material, the compound of zinc halogenide complex and zinc complex and a tautomer of the same has absorption at a wave length of 400 nm or less and is used for an ultraviolet absorption material, and further the quinoline compound and a tautomer has a strong luminescent intensity and is used for a fluorescent material. The zinc halogenide complex and zinc complex can be prepared by related preparation processes directly from a quinoline derivative and a phthalimide derivative, or by way of the quinoline compound which is obtained from these derivatives.
    Type: Grant
    Filed: June 18, 1997
    Date of Patent: October 17, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tadashi Okuma, Hideki Ikuta, Tatsuya Nagayoshi, Akira Ogiso, Hisato Ito
  • Patent number: 6111063
    Abstract: A photoluminescence polymer having a repeating unit in which an aromatic amine and a double bond are conjugated. The photoluminescence polymer can be used as an emission material for the display device, which is particularly useful in a display device requiring an film forming property. Also, a device having the photoluminescence polymer has a low driving voltage and a short response time, and can display various colors over a range from blue to green, especially, blue.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: August 29, 2000
    Assignee: Samsung Display Devices Co., Ltd.
    Inventors: Jong-wook Park, Seong-woo Cho
  • Patent number: 6107452
    Abstract: Preparation of thermally and/or photochemically crosslinkable oligomeric precursors and the use of those oligomeric precursors in preparing crosslinked electroactive polymers are described. The oligomers, polymers, and synthetic methods find utility in the manufacture of opto-electronic devices such as light emitting diodes, photoconductors, photovoltaic cells, and the like, wherein synthesis of electroactive films and polymeric multilayers is required.
    Type: Grant
    Filed: October 9, 1998
    Date of Patent: August 22, 2000
    Assignees: International Business Machines Corporation, Board of Trustees of the Leland Stanford Junior University
    Inventors: Robert Dennis Miller, Gerrit Klaerner, John Campbell Scott
  • Patent number: 6083634
    Abstract: A new class of organometallic complexes for use in electroluminescent (EL) devices and a method of preparation are disclosed. The organometallic complexes are prepared by mixing organic ligands with metal salts and a layer is formed in an EL device by vacuum evaporation. The organometallic material in the EL device forms a light emission layer.
    Type: Grant
    Filed: August 11, 1997
    Date of Patent: July 4, 2000
    Assignee: Motorola, Inc.
    Inventor: Song Q. Shi
  • Patent number: 6068940
    Abstract: Described is an organic electroluminescent device material which comprises a coumarin derivative represented by the following formula (1): ##STR1## wherein R.sub.1 to R.sub.4 each independently represents a hydrogen atom, a halogen atom or a substituted or unsubstituted alkyl, alkoxy, thioalkyl, aryloxy, arylthio, carbocyclic aromatic or heterocyclic aromatic group; and an organic electroluminescent device fabricated using the material. According to the present invention, a red-emitting material with high brightness and high luminous efficiency indispensable for full color display can be provided.
    Type: Grant
    Filed: May 22, 1998
    Date of Patent: May 30, 2000
    Assignee: NEC Corporation
    Inventor: Taizou Tanaka
  • Patent number: 6057048
    Abstract: An electroluminescent device comprised of an anode, a hole transporting layer, a light emitting layer, and a cathode, wherein said light emitting layer contains a component of the formula ##STR1## wherein Ar.sup.1, Ar.sup.2, Ar.sup.3, and Ar.sup.4 are each independently aryl or optionally aliphatic; R.sup.1 and R.sup.2 are independently selected from the group consisting of hydrogen, aliphatic, halogen, and cyano; L is a suitable linking group; and n is a number of from 0 to about 3.
    Type: Grant
    Filed: October 1, 1998
    Date of Patent: May 2, 2000
    Assignee: Xerox Corporation
    Inventors: Nan-Xing Hu, Mohammad Esteghamatian, Yu Qi, Zoran D. Popovic, Beng S. Ong, Ah-Mee Hor
  • Patent number: 6048631
    Abstract: An object of this invention is to provide an organic EL device material stable against heat, having a high purity in bluish light emission and a high efficiency. The organic EL device comprises a glass substrate, a transparent anode, a TPD which is an electron hole implanted transporting layer, an organic luminous layer, Alq.sub.3 which is an electron implanted transporting layer and a cathode. The organic luminous layer is an aluminum complex which is .mu.-oxozi [bis(2-(2-benzo oxazolyl)-phenolate) aluminum (III)]. Plus and minus DC voltages are applied to the anode and cathode respectively. The organic luminous layer indicates bluish light emission of 1314 cd/m.sup.2 at 16V. A peak wave length of the luminous spectrum is 420 nm and chromaticity coordinates are x=0.185 and y=0.178 and a high purity as bluish color is assured. The organic EL device material is stable against heat and difficult to deteriorate.
    Type: Grant
    Filed: July 11, 1997
    Date of Patent: April 11, 2000
    Assignee: Futaba Denshi Kogyo K.K.
    Inventors: Hisamitsu Takahashi, Yoshihisa Tsuruoka, Satoshi Tanaka, Toshio Miyauchi
  • Patent number: 6045930
    Abstract: Disclosed herein are organic light emitting devices in which emitting layers (EL) comprise a suitable receiving compound according to Formulas I and II: ##STR1## wherein M is an ion of a divalent or trivalent metal atom, wherein n=3 when M is trivalent, and n=2 when M is divalent, wherein the metal atom is selected from the group consisting of aluminum, gallium, indium, and zinc, and wherein X, Y, and Z are each individually and independently C or N, such that at least two of X, Y and Z are N; and ##STR2## wherein R is alkyl, phenyl, substituted alkyl, substituted phenyl, trimethylsilyl, or substituted trimethylsilyl.Also disclosed are OLED's utilizing device elements comprising the above compounds and display devices based on those OLED's.
    Type: Grant
    Filed: May 2, 1997
    Date of Patent: April 4, 2000
    Assignees: The Trustees of Princeton University, The University of Southern California
    Inventors: Mark E. Thompson, Jon A. Cronin, Stephen R. Forrest, Paul Burrows
  • Patent number: 6030715
    Abstract: Organic light emitting devices are disclosed which are comprised of a heterostructure for producing electoluminescence wherein the heterostructure is comprised of an emissive layer containing a dopant compound selected from the class of azlactone-related compounds having the chemical structure as represented by formula I: ##STR1## where R is hydrogen or a donor or acceptor group relative to hydrogen; R'=alkyl or substituted or unsubstituted aryl;R.sub.1 and R.sub.2 are hydrogen or are joined to form a fused aryl ring;X is O; NR.sub.5, where R.sub.5 is hydrogen or substituted or unsubstituted alkyl; alkyl or substituted or unsubstituted aryl;Z.sub.1 and Z.sub.2 are, independently of one another, a carbon or nitrogen atom; andY is M, a metal atom, whenever Z.sub.1 and Z.sub.2 are both nitrogen atoms;Y is O; NR.sub.6, where R.sub.6 is hydrogen or substituted or unsubstituted alkyl; or S; whenever either Z.sub.1 or Z.sub.2 is a carbon atom; orY is absent.
    Type: Grant
    Filed: October 9, 1997
    Date of Patent: February 29, 2000
    Assignees: The University of Southern California, The Trustees of Princeton University
    Inventors: Mark Thompson, Yujian You, Nicos A. Petasis, Paul E. Burrows, Stephen R. Forrest
  • Patent number: 6017644
    Abstract: A light emitting device is composed of a pair of electrodes and an organic compound layer interposed between the electrodes. In the organic compound layer is used a organic compound shown by the following formula (1): ##STR1## wherein R.sup.1 is a hydrogen atom, an alkyl group or a halogen atom, R.sup.2 is X--Ar.sup.1 ; X is NH, O or S, Ar.sup.1 is a substituted or unsubstituted aromatic ring having a partial structure shown by the following formula (2): ##STR2## or a substituted or unsubstituted heterocyclic ring; each of R.sup.3 and R.sup.4 is a hydrogen atom, an alkyl group, a substituted or unsubstituted aromatic ring, or a substituted or unsubstituted heterocyclic ring; each of R.sup.5 and R.sup.6 is a hydrogen atom, a halogen atom, an alkyl group, an aralkyl group, an alkoxy group, a substituted or unsubstituted aromatic ring, or a substituted or unsubstituted heterocyclic ring.
    Type: Grant
    Filed: September 11, 1998
    Date of Patent: January 25, 2000
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yomishi Toshida, Akihiro Senoo, Kazunori Ueno, Seiji Mashimo
  • Patent number: 6013383
    Abstract: An organic electroluminescent display device (10) includes a plurality of organic layers (16, 18, 20, 22 and 24) disposed between opposing electrodes (14 and 26). The hole transporting layer (22) comprises a hole transporting material characterized by the general formula: ##STR1## where n, m, and p each independently take the value of 0, 1 or 2; A1 and A2 each represents:(a) an alkyl group; or(b) an alkyl substituted with aryl, hydroxy, cyano, alkoxy, halo, or amino group(s); or(c) an aryl group; or(d) an aryl group substituted with alkyl, aryl, hydroxy, cyano, alkoxy, phenyl, halo, or amino group(s).
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: January 11, 2000
    Assignee: Motorola, Inc.
    Inventors: Song Shi, Cynthia Gorsuch, Maridela C. Siethoff, H. C. Lee
  • Patent number: 6010796
    Abstract: An organic electroluminescent device of a single heterostructure is fabricated by forming a transparent electrode (anode) of ITO, a hole transport layer, an electron transport layer and a metal electrode (cathode) in that order on a glass substrate. An exciton generation promoting layer is formed between the hole transport layer and the electron transport layer. The hole transport layer is a two-layer structure consisting of a hole transport light emitting layer or a hole injection layer, and a hole transport light emitting layer. Exciton generation in the hole transport light emitting layers 4a and 4b can be promoted. The hole injection layer enables efficient hole injection.
    Type: Grant
    Filed: July 7, 1997
    Date of Patent: January 4, 2000
    Assignee: Sony Corporation
    Inventor: Yasunori Kijima
  • Patent number: 6007928
    Abstract: An EL cell exhibiting high luminous efficiency and excellent durability is disclosed. The EL cell comprises a layer of a block copolymer comprising a block component (A) of the following formula (1) having a positive hole transfer capability and a block component (B) of the following formula (2) having an electron transfer capability at molar ratio of the block component (A) to the block (B) between 0.1:99.9 and 99.9:0.1.
    Type: Grant
    Filed: August 10, 1998
    Date of Patent: December 28, 1999
    Assignees: JSR Corporation, International Center for Materials Research, TECO Electric & Machinery Co., Ltd.
    Inventors: Mitsuhiko Sakakibara, Yasumasa Takeuchi, Ding-Kuo Ding
  • Patent number: 6004685
    Abstract: An OLED having a cathode constructed from a first conducting layer. An electron transport layer constructed from a first electron transport material overlays the cathode. An electroluminescent layer constructed from the first electron transport material doped with dibenzotetraphenylperiflanthene overlays the electron transport layer. A hole transport layer constructed from a first hole transport material overlays the electroluminescent layer. The anode overlays the hole transport layer. In one embodiment of the invention, a second hole transport layer constructed from a second hole transport material is sandwiched between the anode and the first hole transport layer. In a third embodiment of the invention, a second electron transport layer constructed from a second electron transport material is sandwiched between the electroluminescent layer and the first hole transport layer.
    Type: Grant
    Filed: December 23, 1997
    Date of Patent: December 21, 1999
    Assignee: Hewlett-Packard Company & The Board of Regents of The University of Texas System
    Inventors: Homer Antoniadis, Allen J. Bard
  • Patent number: 5998046
    Abstract: An organic thin film electroluminescent device has at least an organic thin film provided between an anode and a cathode,wherein the organic thin film includes a compound which is represented by a general formula (I): ##STR1## where Ar.sup.1, Ar.sup.2, Ar.sup.3, Ar.sup.4, Ar.sup.5, and Ar.sup.6 are selected from the group consisting of non-substituted phenyl groups and phenyl groups substituted with at least a substituent which is selected from the group consisting of alkyl groups having 1-4 carbon atoms, alkoxyl groups having 1-4 carbon atoms, amino groups, alkyl amino groups having 1-4 carbon atoms, dialkyl amino groups having 1-4 carbon atoms, alkyl thio groups having 1-4 carbon atoms, halogens, and halogeno alkyl groups having 1-4 carbon atoms, and R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 are selected from the group consisting of hydrogen and methyl groups.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: December 7, 1999
    Assignee: NEC Corporation
    Inventors: Hiroshi Tada, Hiroyuki Endoh, Akira Hirano, Koji Utsugi
  • Patent number: 5998045
    Abstract: The invention relates to an organic electroluminescent device comprising a light-emitting composition disposed between a first and second electrode. The composition comprises poly(fluorene-co-anthracene).
    Type: Grant
    Filed: July 3, 1997
    Date of Patent: December 7, 1999
    Assignees: International Business Machines Corporation, The Board of Trustees of the Leland Stanford Junior University
    Inventors: Weidong Chen, Gerrit Klaerner, Robert Dennis Miller, John Campbell Scott
  • Patent number: 5989738
    Abstract: An organic electroluminescent component with a layer arrangement includes a first electrode layer, an inorganic layer which conducts electrons, one or several optoelectronically active layers with at least one light-emitting layer which comprises an organic emitter, and a second electrode layer. The inorganic layer which conducts electrons is an N-type conducting oxide of a transition metal chosen from the group consisting of zirconium oxide, hafnium oxide, vanadium oxide, barium titanate, barium-strontium titanate, strontium titanate, calcium titanate, calcium zirconate, potassium tantalate, and potassium niobate.
    Type: Grant
    Filed: June 24, 1997
    Date of Patent: November 23, 1999
    Assignee: U.S. Philips Corporation
    Inventors: Markus Haase, Ulrich Kynast, Herbert Boerner, Cornelis Ronda
  • Patent number: 5981092
    Abstract: An organic EL device of the invention includes an inorganic material layer with a resistivity of less than 20 .OMEGA.-cm disposed between an electrode and a light emitting layer. The inorganic material layer contains at least one of indium oxide, tin oxide, and zinc oxide as a primary component, which is the same material as an anode, and at least one of silicon and germanium as an auxiliary component. This improves physical properties at the electrode-organic layer interface and restrains generation of dark spots, establishing an organic EL device featuring a long life, high efficiency and low cost.
    Type: Grant
    Filed: March 25, 1997
    Date of Patent: November 9, 1999
    Assignee: TDK Corporation
    Inventors: Michio Arai, Masami Mori, Kenji Nakaya
  • Patent number: 5968675
    Abstract: A hole-transporting material having excellent hole transportation capability and sufficient durability, used in an organic EL device and an electrophotographic photoreceptor, the hole-transporting material having the general formula specified in claim 1.
    Type: Grant
    Filed: May 28, 1998
    Date of Patent: October 19, 1999
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Michiko Tamano, Satoshi Okutsu, Toshio Enokida
  • Patent number: 5955209
    Abstract: The thin-film electroluminescent device of the present invention comprises a thin film of a polyoxadiazole derivative represented by the formula: ##STR1## wherein each of X.sub.0 and Y.sub.0 independently represents a divalent organic group which may comprise a silicon atom, and n is an integer of 2 or greater,formed as an electroluminescent layer or a charge injecting/transporting layer between electrodes, at least one thereof being transparent. This thin-film electroluminescent device is excellent not only in electroluminescence and capability of charge injection/transport to thereby ensure high light emission efficiency but also in durability such as heat resistance.
    Type: Grant
    Filed: May 6, 1996
    Date of Patent: September 21, 1999
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hideyuki Murata, Takahiro Fujiyama, Shogo Saito, Tetsuo Tsutsui, Tooru Yamanaka
  • Patent number: 5935720
    Abstract: An organic EL device, includes an anode and a cathode, and at least one organic luminescent medium containing a compound of the formula: ##STR1## wherein: R.sub.1, and R.sub.2 are individually alkyl of from 1 to 20 carbon atoms, aryl, carbocyclic and other heterocyclic systems; andR.sub.3, and R.sub.4 are individually alkyl of from 1 to 10 carbon atoms, and a branched or unbranched 5 or 6 member substituent ring connecting with R.sub.1, R.sub.2 respectively; andR.sub.5 is alkyl of from 2-20 carbon atoms; sterically hindered aryl and heteroaryl; andR.sub.6 is alkyl of from 1 to 10 carbon atoms, and a 5 or 6-member carbocyclic ring connecting with R.sub.5.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: August 10, 1999
    Assignee: Eastman Kodak Company
    Inventors: Chin H. Chen, Ching W. Tang, Jianmin Shi
  • Patent number: 5932363
    Abstract: A luminescent composition containing a mixture of a fluorescent material and a metal chelate compound of the formulaL.sub.n --M.sup.+n (I)wherein M represents a metal; n is a number of from 1 to 3, and L is a ligand of the formula ##STR1## wherein Ar is an aryl; X is selected from the group consisting of oxygen, sulfur, and selenium; N is nitrogen; O is oxygen, and Z is a suitable aromatic component.
    Type: Grant
    Filed: October 2, 1997
    Date of Patent: August 3, 1999
    Assignee: Xerox Corporation
    Inventors: Nan-Xing Hu, Shuang Xie, Zoran D. Popovic, Beng S. Ong, Ah-Mee Hor
  • Patent number: 5928802
    Abstract: An organic EL device, includes an anode, cathode, and at least one organic luminescent layer including a compound of the formula: ##STR1## where: n is an integer of 2 or 3;M is a divalent metal or a trivalent metal;G is a substituted or unsubstituted aryl group or a substituted or unsubstituted heteroaryl group, both the aryl and the heteroaryl groups having 6 to 24 carbon atoms, wherein the substituted aryl or heteroaryl group is an alkyl, haloalkyl group having 1-8 carbon atoms, an alkoxy or haloalkoxy group having 1-18 carbon atoms, halogen, cyano, amino, amido, sulfonyl, carbonyl, aryl, or heteroaryl;R.sup.1 and R.sup.2 are individually hydrogen, an alkyl or haloalkyl group having 1-18 carbon atoms, halogen, cyano, amono, amido, sulfonyl, carbonyl, and 5-24 atoms necessary to complete a fused aromatic ring.
    Type: Grant
    Filed: May 16, 1997
    Date of Patent: July 27, 1999
    Assignee: Eastman Kodak Company
    Inventors: Jianmin Shi, Chin H. Chen
  • Patent number: 5925473
    Abstract: A radiation image storage panel having a stimulable phosphor layer and a protective film composed of a plastic material film and a coated layer of a fluororesin-containing resin composition containing light-scattering fine particles gives a radiographic image of improved quality.
    Type: Grant
    Filed: March 31, 1998
    Date of Patent: July 20, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Haruyoshi Kuriyama, Hideki Suzuki, Shinichiro Fukui
  • Patent number: 5919579
    Abstract: An organic electroluminescent device comprising an anode, an organic hole transport layer, an organic emission layer and a cathode layered in this order on a substrate, or, optionally, comprising an additional electron transport layer between the organic emission layer and the cathode, wherein the organic emission layer comprises a naphthalimide derivative represented by formula (1) wherein R.sup.1 is a hydrogen atom, a straight chain or branched chain alkyl group having from 1 to 16 carbon atoms, an aryl group which may have substituents or an aralkyl group which may have substituents, and R.sup.2, R.sup.3, R.sup.4 are special substituents.
    Type: Grant
    Filed: January 17, 1997
    Date of Patent: July 6, 1999
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Wen-Bing Kang, Nu Yu, Akihiko Tokida, Thomas Potrawa, Andreas Winterfeldt