Water-settable Material (e.g., Gypsum, Etc.) Patents (Class 428/703)
  • Patent number: 5945198
    Abstract: A coating for providing a cover sheet used in the manufacture of wallboard with a light colored finish without the use of manila top plies is disclosed. The coating has a porosity adapted to allow evaporation of moisture from the wallboard core through the cover sheet, and maintain a desired smooth appearance. A high pigment-to-binder ratio is used to provide porosity, with soy protein being added to further enhance the porosity of the coating. The coating may be applied through various conventional methods of coating paper such as roll, spray, curtain, rod and vacuum.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: August 31, 1999
    Assignee: United States Gypsum Company
    Inventors: Subhash S. Deodhar, Thomas M. Haugeberg, Claudia B. Hill, Thomas G. Houman, Robert H. Negri
  • Patent number: 5945208
    Abstract: Fiberboards are provided containing at least about 65 wt. % calcium sulfate dihydrate derived from hemihydrate or anhydrous gypsum, and at least about 7 wt. % pulped paper fibers. The boards are capable of being formed into structural members having superior mechanical properties and/or fire resistance, including screw-holding capacities in excess of 650 lbs.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 31, 1999
    Assignee: G-P Gypsum Corporation
    Inventors: Turner W. Richards, Hubert C. Francis, George F. Fowler
  • Patent number: 5935699
    Abstract: The present invention relates to a lightweight composite material comprising:(a) hollow ceramic microspheres;(b) cement;(c) concrete admixture or additive; and(d) water.The invention also relates to a process for preparing the lightweight composite material and construction products, concrete furniture or art objects wholly or partly composed of the lightweight composite material.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: August 10, 1999
    Inventor: Robert Frederick Barber
  • Patent number: 5932344
    Abstract: A cement retarder which comprises a saturated or unsaturated polyester obtained by a reaction of a polycarboxylic acid component comprising a polycarboxylic acid having 2 to 6 carbon atoms in the main chain or its derivative, and a polyol component containing a polyhydric alcohol having 2 to 4 carbon atoms or its condensate, wherein:(a) the saturated polyester has a weight average molecular weight of about 300 to about 50,000; or(b) the unsaturated polyester has a weight average molecular weight of about 500 to about 25,000; or(c) the polyhydric alcohol used to obtain the saturated or unsaturated polyester is a condensate of a C.sub.2-4 alkylene glycol; or(d) the saturated polyester is a polyester obtained by the use of a condensate of a C.sub.2-4 alkylene glycol and has a weight average molecular weight of about 300 to about 50,000; or(e) the unsaturated polyester is a polyester obtained by the use of a condensate of a C.sub.
    Type: Grant
    Filed: October 7, 1996
    Date of Patent: August 3, 1999
    Assignee: Daicel-Huels Ltd.
    Inventors: Yoshiyuki Ikemoto, Toru Ikuta
  • Patent number: 5922447
    Abstract: A lightweight gypsum board is provided, including, by dry weight, gypsum as the largest single ingredient, perlite as the second largest single ingredient, and starch as a minor ingredient, in the board. The starch may be pre-cooked prior to mixing, and is dispersed in the core of the board to act as a binder for binding the gypsum to the perlite. Gypsum board made according to the invention is lighter in weight, yet has a comparable nail pull value to conventional wallboard.
    Type: Grant
    Filed: September 16, 1996
    Date of Patent: July 13, 1999
    Assignee: United States Gypsum Company
    Inventor: Mirza A. Baig
  • Patent number: 5900321
    Abstract: The invention provides a method of producing a composite material. The method comprises subjecting a surface of a polyolefin component comprising a polyolefin material to surface activation thereof, followed by the step of adhesively securing together the polyolefin component and a substrate component. The substrate component is selected from cementitious components and metal components, and the securing takes place at the activated surface of the polyolefin component. The invention also extends to a composite material comprising a polyolefin component and a substrate component adhesively secured together. The substrate component is selected from cementitious components and metal components. The components are secured together at a surface of the polyolefin component which is activated.
    Type: Grant
    Filed: December 16, 1996
    Date of Patent: May 4, 1999
    Assignee: Pelindaba District Brits Atomic Energy Corp. of South Africa Limited
    Inventors: Pieter A. B. Carstens, Georges A. B .M. G. Boyazis, Jennifer A. De Beer
  • Patent number: 5879446
    Abstract: A method of preparation of gypsum wallboard, as well as a core composition suitable for use therein, are disclosed. The core composition includes a slurry of calcium sulfate hemihydrate (stucco), water, and calcium aluminum lignosulfonate and/or aluminum lignosulfonate.
    Type: Grant
    Filed: August 21, 1998
    Date of Patent: March 9, 1999
    Assignee: National Gypsum Company
    Inventors: Jashbhai M. Patel, Ronald S. Finkelstein
  • Patent number: 5879817
    Abstract: A metal coating of typically a valve metal, especially a titanium metal coating, is applied by thermal spraying to the surface of concrete, most particularly steel-reinforced concrete. The metal such as titanium may be sprayed by any one of several thermal spraying techniques including flame spray, electric-arc spray, plasma spray, high-velocity oxyfuel spray, or detonation gun spray. The metal coating should be tightly adhered to the concrete and desirably will have a porosity to facilitate extensive coating of the metal itself, as well as facilitate any activation that may be needed for the metal. Such activation can be in the form of an electrochemically active material which allows the coating to function in electrochemically active form. One coating option is to apply a solution onto the spray-applied metal, then polarize the metal anodically to effect deposition of active material on the metal.
    Type: Grant
    Filed: January 19, 1995
    Date of Patent: March 9, 1999
    Assignee: Eltech Systems Corporation
    Inventors: Carl W. Brown, Jr., John E. Bennett, John J. Bartholomew, Barry L. Martin, Thomas J. Schue
  • Patent number: 5879778
    Abstract: A method and a pre-form for strengthening a substrate structural member. Layers are applied to a surface of a substrate where the layers include dry fibre reinforcement materials. A reduced pressure is then applied to the layers and a curable resin is introduced to the layers such that the resin is drawn therethrough until the interstices therein are substantially filled with the resin. The resin is then cured. The layers are preferably woven fabric and may include resin distribution layers of relatively low weave density and high permeability and reinforcement layers of higher weave density and lower permeability. The layers may be provided as a pre-form.
    Type: Grant
    Filed: July 21, 1997
    Date of Patent: March 9, 1999
    Assignee: Davonport Management Limited
    Inventor: Frazer John Charles Barnes
  • Patent number: 5879825
    Abstract: A method of preparation and use of high-strength gypsum wallboard, as well as a core composition suitable for use therein, are disclosed. The core composition includes a slurry of calcium sulfate hemihydrate (stucco), water, and a strengthening agent. The strengthening agent includes an acrylic polymer composition having a glass transition temperature of about 15.degree. C. or greater, and preferably has good divalent ion stability. The method provides wallboard having increased core strength, paper-to-core bonding, and strength-to-weight ratio.
    Type: Grant
    Filed: January 7, 1997
    Date of Patent: March 9, 1999
    Assignee: National Gypsum Company
    Inventors: W. Roy Burke, Larry W. Kingston
  • Patent number: 5873936
    Abstract: A cement composition comprising fine aggregate, preferably sand, in an amount of about 10 to about 25 wt %; blast furnace slag cement, in an amount of about 20 to about 35 wt %; gypsum, in an amount of about 20 to about 35 wt %; Portland cement, in an amount of about 4 to about 30 wt %; and cement plasticizer in an amount of about 0.3 to about 3 wt %. The dry cement composition may be formulated with aggregate and water to prepare a flowable liquid, self-leveling and self-smoothing coating material that may be applied to a substrate such as a floor substrate. The applied coating requires no manual finishing or smoothing, yet hardens to form a level, very smooth coating that possesses excellent compressive strength.
    Type: Grant
    Filed: November 17, 1997
    Date of Patent: February 23, 1999
    Assignee: Maxxon Corp.
    Inventor: J. Herbert Ogden
  • Patent number: 5871857
    Abstract: A highly fire resistant construction board is produced by embedding a sheet of expanded metal net in a building board made from a water settable inorganic binder. In a preferred embodiment, the wallboard is made from a combination of gypsum, cement, and a particulate mineral filler such as perlite or vermiculite, and contains an embedded layer of expanded metal net made from a magnesium alloy.
    Type: Grant
    Filed: December 26, 1990
    Date of Patent: February 16, 1999
    Inventor: Shaikh Ghaleb Mohammad Yassin Alhamad
  • Patent number: 5843554
    Abstract: Multi-layer covering articles having a base layer adapted to yieldably conform to a surface to be covered and having properties appropriate for a particular application in which the article is to be used, and a thermoplastic surface layer bonded to a surface of the base layer and incorporating a reinforcing material to provide strength and tear resistance for the covering article. The reinforcing material permits the surface layer to function as the strength-providing member of the article, permitting the base layer to be designed solely in accordance with the requirements of a particular application without regard to its strength.
    Type: Grant
    Filed: February 18, 1994
    Date of Patent: December 1, 1998
    Assignee: Katman, Inc.
    Inventor: Donald P. Katz
  • Patent number: 5834075
    Abstract: A method for protecting concrete surfaces of sanitary sewers includes the steps of providing a concrete surface in a sanitary sewer environment; and coating the concrete surface with magnesium hydroxide or magnesium oxide.
    Type: Grant
    Filed: December 4, 1996
    Date of Patent: November 10, 1998
    Assignee: PSC Technologies, Inc.
    Inventor: Thomas Michael Miller
  • Patent number: 5816009
    Abstract: A load bearing structure having a set of uniform voids functions to resolve the forces imposed by developing compression in the material having the voids and minimizing the amount of tension developed in the material. The voids are deployed to encompass a matrix of points arranged such that each point is spaced an equal distance from twelve and only twelve adjacent matrix points. If the structure is considered to be composed of a closely packed set of hypothetical rhombic dodecahedra (RD) and the four-edge vertices of each of those hypothetical RDs is truncated, the result will be a set of cubic voids. The center of each of those cubic voids will define the matrix referred to above and the cubic voids will serve to provide the optimum resolution of stress which minimizes the development of tension in the material. One in four of the hypothetical RDs can be eliminated achieving the same force resolution in a structure containing less material.
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: October 6, 1998
    Assignee: Hexas LLC
    Inventor: Charles R. Owens
  • Patent number: 5814411
    Abstract: The present invention provides a novel method of rendering a wallboard water-repellent comprising applying to the wallboard a water-repellent composition comprising a hydrogen siloxane component and a high molecular weight silicone.
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: September 29, 1998
    Assignee: General Electric Company
    Inventors: James Hale Merrifield, Donna Ann Riccio
  • Patent number: 5804003
    Abstract: The object of the present invention is to prevent delamination of an inorganic board. To attain this object, a method of manufacturing an inorganic board comprising forming a single mat by the paper making method by using slurry of raw material mixture substantially consisting of cement material, fiber material and inorganic filler inside of which is empty wherein said empty inorganic filler is effected on an alkali treatment; laminating the plural number of said single mats to form a laminated mat; and molding, incubating and curing said laminated mat.
    Type: Grant
    Filed: December 2, 1996
    Date of Patent: September 8, 1998
    Assignee: Nichiha Corporation
    Inventor: Kazuhide Nishizawa
  • Patent number: 5798151
    Abstract: Methods and apparatus for continuously extruding a hydraulically settable mixture and simultaneously placing continuous filaments within the extruding mixture to yield articles having a filament-reinforced, hydraulically settable matrix. The filaments can be placed within the mixtures in a parallel configuration, a helical configuration, or combinations thereof, in order to yield an article having the desired properties of, e.g., tensile strength, flexural strength, hoop strength, burst strength, toughness, and elongation ability. The desired properties of the hydraulically settable mixture, as well as of the cured hydraulically settable matrix of the hardened article, may also be adjusted by including varying amounts and types of aggregates, discontinuous fibers, binders, rheology-modifying agents, dispersants, or other admixtures within the hydraulically settable mixture.
    Type: Grant
    Filed: July 9, 1996
    Date of Patent: August 25, 1998
    Assignee: E. Khashoggi Industries, LLC
    Inventors: Per Just Andersen, Simon K. Hodson
  • Patent number: 5788760
    Abstract: The present invention relates to processes for enhancing the bond strength of a cement matrix including reinforcement fibers and for modifying the surface characteristics of reinforcement fibers useful in cementitious materials. The processes further relate to controlling the interface properties and, more particularly, the bond strength (.tau.) and interface toughness (T.sub.i), between synthetic fibers and a cementitious material forming a matrix. By plasma treating synthetic fibers with an excitable gas capable of displacing hydrogen atoms occurring along said reinforcement fibers, the bond strength and interface toughness of the composite is dramatically increased over composites employing non-plasma treated fibers.
    Type: Grant
    Filed: March 4, 1996
    Date of Patent: August 4, 1998
    Assignee: The Regents of the University of
    Inventors: Victor C. Li, Hwai-Chung Wu
  • Patent number: 5783280
    Abstract: An insulation material comprising the double salt of aluminum potassium sulphate and method of producing such. Aluminum sulphate materials and potassium sulphate materials are combined to form aluminum potassium sulphate which is then dehydrated to remove the water of hydration. Porous forms are made by mixing the hydrated aluminum potassium sulphate with a binder before dehydration. The resultant dehydrated sulphate expands greatly to provide an insulative material which is of lightweight and inorganic.
    Type: Grant
    Filed: October 7, 1996
    Date of Patent: July 21, 1998
    Assignee: Solv-Ex Corporation
    Inventors: John S. Rendall, Massoud Ahghar
  • Patent number: 5766728
    Abstract: The invention relates to a method of patterning a concrete surface and a pattern transfer mat for use in the method. The pattern transfer mat has a transfer surface having three-dimensional irregularities and carrying a multiplicity of grains to be transferred to the substrate concrete. Concrete is cast against the transfer surface of the mat and cured in situ and the mat is then detached. The aesthetic grains are grains having a cement powder deposited thereon beforehand. The cement powder absorbs water to cause fine air cells therein to collapse. Thus, the finished surface of the case concrete structure is made smoother.
    Type: Grant
    Filed: May 31, 1994
    Date of Patent: June 16, 1998
    Assignee: Tokai Rubber Industries, Ltd.
    Inventor: Nobuo Iwaya
  • Patent number: 5763090
    Abstract: A building element has a slab of concrete having a face, a sheet of glass juxtaposed with the face, and a layer of mortar between and bonded monolithically to the glass sheet and the slab face. The mortar consists essentially of a fine-particulate neutral aggregate, cement, and an aqueous dispersion of a polyacrylic-acid derivative having a logarithmic decrement according to DIN 53,445 which is at a maximum below 0.degree. C. The aqueous dispersion is in an amount insufficient to fully hydrate the cement. In addition the mortar layer has a thickness and a content of polyacrylic acid sufficient to permit differential thermal expansion of the slab and glass without cracking of the mortar layer.
    Type: Grant
    Filed: November 14, 1995
    Date of Patent: June 9, 1998
    Inventor: Hans Peter Boe
  • Patent number: 5753033
    Abstract: A composition for transforming a chrysotile asbestos-containing material into a non-asbestos material is disclosed, wherein the composition comprises water, at least about 30% by weight of a boron tetrafluoride salt, free of or having only small amounts of an inorganic acid, an inorganic acid salt or a mixture thereof. A method of transforming the asbestos-containing material into a non-asbestos material using the present composition also is disclosed.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: May 19, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Jacob Block
  • Patent number: 5753032
    Abstract: A composition for transforming a chrysotile asbestos-containing material into a non-asbestos material is disclosed, wherein the composition comprises water, at least about 30% by weight of phosphoric acid, and from about 0.1 to about 4% by weight of a source of fluoride ions. A method of transforming the asbestos-containing material into a non-asbestos material using the present composition also is disclosed.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: May 19, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Jacob Block
  • Patent number: 5753031
    Abstract: A composition for transforming a chrysotile asbestos-containing material into a non-asbestos material is disclosed, wherein the composition comprises water, at least about 30% by weight of an inorganic acid, and from about 0.1 to about 4% by weight of a hexafluorosilicate of ammonia, an alkali metal or an alkaline earth metal. A method of transforming the asbestos-containing material into a non-asbestos material using the present composition also is disclosed.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: May 19, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Jacob Block
  • Patent number: 5753035
    Abstract: A composition for transforming a chrysotile asbestos-containing material into a non-asbestos material is disclosed, wherein the composition comprises water, at least about 30% by weight of an inorganic acid, and from about 0.1 to about 4% by weight of a tetrafluoroborate of ammonia, an alkali metal or an alkaline earth metal. A method of transforming the asbestos-containing material into a non-asbestos material using the present composition also is disclosed.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: May 19, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Jacob Block
  • Patent number: 5753034
    Abstract: A composition for transforming a chrysotile asbestos-containing material into a non-asbestos material is disclosed, wherein the composition comprises water, at least about 30% by weight of a hexafluorosilicate salt, and free of or having only small amounts of an inorganic acid, an inorganic acid salt or a mixture thereof. A method of transforming the asbestos-containing material into a non-asbestos material using the present composition also is disclosed.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: May 19, 1998
    Assignee: W. R. Grace & Co. -Conn.
    Inventor: Jacob Block
  • Patent number: 5750276
    Abstract: This invention relates to a method of inhibiting alkali-silica or alkali-aggregate reactions (AAR/ASR) in concrete structures by introducing lithium compounds or the like in conjunction with conventional techniques for the treatment of steel reinforcement corrosion.It is also proposed to provide lithium compounds in repair concretes, grouts or mortars and use the difference in concentration between the article under repair and the repair material to introduce the lithium ions into the concrete under repair, once again inhibiting AAR/ASR reactions.
    Type: Grant
    Filed: September 8, 1994
    Date of Patent: May 12, 1998
    Assignee: Tarmac Construction Limited
    Inventor: Christopher Lyndon Page
  • Patent number: 5744257
    Abstract: A process for producing a composite material, structure or artifact comprising a cementitious substrate or matrix which is strengthened or reinforced by reinforcing material which adheres thereto, includes bringing a reinforcing component into contact with a cementitious substrate component which is in a settable state. The substrate component is allowed to set in contact with the reinforcing component, thereby to adhere thereto. Adhesion of the substrate component to the reinforcing component is enhanced by, prior to bringing the components into contact with each other, subjecting the reinforcing component to surface fluorination thereof.
    Type: Grant
    Filed: March 3, 1995
    Date of Patent: April 28, 1998
    Assignee: Atomic Energy Corporation of South Africa Limited
    Inventor: Pieter Andries Blatt Carstens
  • Patent number: 5741358
    Abstract: A composition for transforming a chrysotile asbestos-containing material into a non-asbestos material is disclosed, wherein the composition comprises water, at least about 30% by weight of an acid component, optionally a source of fluoride ions, and a corrosion inhibiting amount of thiourea, a lower alkylthiourea, a C.sub.8 -C.sub.15 alkylpyridinium halide or mixtures thereof. A method of transforming an asbestos-containing building material, while part of a building structure, into a non-asbestos material by using the present composition also is disclosed.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: April 21, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Judithann Ruth Hartman
  • Patent number: 5733671
    Abstract: A recycled fiber reinforced, moldable, settable cementitious composition which comprises cementitious material, recycled fibers, accelerator (optional), and water and a cured product therefrom, as well as a method for its preparation by suction-dewatering are disclosed.
    Type: Grant
    Filed: April 19, 1996
    Date of Patent: March 31, 1998
    Assignee: San Diego State University Foundation
    Inventor: M. Ziad Bayasi
  • Patent number: 5714217
    Abstract: Sealable liquid-tight containers and methods for economically manufacturing such containers for storing and dispensing substances and any other purposes for which conventional sealable liquid-tight containers are utilized. The containers are readily and economically formed from mixtures of hydraulically settable binders such as hydraulic cement, gypsum and clay with water. Appropriate additives can also be added to the mixture which impart desired characteristics and properties to both the mixture and the hardened containers. The mixtures can be utilized to form containers by various methods. One method involves forming the containers without substantial mixing of the mixture, compacting the mixture and hydrating the mixture. Other methods involve molding the mixture, extruding the mixture and forming sheets from the mixture to be converted into containers. The components may also be dried, coated, lined, laminated and/or receive printing.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: February 3, 1998
    Assignee: E. Khashoggi Industries
    Inventors: Just Andersen, Simon K. Hodson
  • Patent number: 5705237
    Abstract: Containers incorporating a hydraulically settable structural matrix including a hydraulically settable binder such as cement for use in the storing, dispensing, and/or packaging of food and beverage products are disclosed. The disposable and nondisposable food and beverage articles of manufacture have high tensile, compressive, and flexural strengths, and are lightweight, insulative (if desired), inexpensive, and more environmentally compatible than those currently used. These disposable containers and cups are particularly useful for dispensing hot and cold food and beverages in the fast food restaurant environment. The structural matrix of the food and beverage containers includes a hydraulic cement paste (formed from the reaction of water with, e.g., a portland-type cement) preferably in combination with a rheology-modifying plasticizer, such as methylhydroxyethylcellulose, various aggregate materials, and fibrous materials, which provide desired properties at a cost which is economical.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: January 6, 1998
    Assignee: E. Khashoggi Industries
    Inventors: Per Just Andersen, Simon K. Hodson
  • Patent number: 5695553
    Abstract: A composition suitable for use in making water-resistant gypsum products is provided. The composition is an aqueous emulsion comprising water, a paraffinic hydrocarbon wax, a Montan wax, an alkali metal or ammonium hydroxide in an amount sufficient to at least partially saponify the Montan wax, an emulsifier and a dispersant.
    Type: Grant
    Filed: August 9, 1996
    Date of Patent: December 9, 1997
    Assignee: Conoco Inc.
    Inventors: Thomas C. Claret, Wesley E. Church, Roy S. Hodgson
  • Patent number: 5665439
    Abstract: Articles of manufacture fashioned from sheets having a hydraulically settable matrix are disclosed, particularly food containers, beverage containers and packaging containers. Suitable compositions are prepared by mixing together a hydraulic binder, water, and appropriate additives (such as aggregates, fibers, and rheology-modifying agents) which impart predetermined properties so that a sheet formed therefrom has the desired performance criteria. Hydraulically settable sheets are formed from the mixture by extrusion, then calendering the sheets using a set of rollers and then drying the sheets in an accelerated manner to substantially harden the sheets. The resulting hydraulically settable sheets may have properties substantially similar to sheets made from presently used materials like paper, cardboard, polystyrene, or plastic.
    Type: Grant
    Filed: December 7, 1993
    Date of Patent: September 9, 1997
    Assignee: E. Khashoggi Industries
    Inventors: Per Just Andersen, Simon K. Hodson
  • Patent number: 5658624
    Abstract: Hydraulically settable mixtures and methods for extruding such mixtures into a variety of objects which are form-stable in the green state are disclosed. High green strength is achieved by increasing the yield stress of the mixture while maintaining adequate extrudability. Optimizing the particle packing density while including a deficiency of water yields a hydraulically settable mixture which will flow under pressures typically associated with the extrusion of clay or plastic. In addition, a rheology-modifying agent can be added to increase the yield stress of the mixture while not significantly increasing the viscosity. The desired strength properties and other performance criteria of the final hardened extruded product are controlled by adding aggregates, fibers, a hydraulically settable binder, water, and other admixtures.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 19, 1997
    Assignee: E. Khashoggi Industries
    Inventors: Per Just Anderson, Simon K. Hodson
  • Patent number: 5656350
    Abstract: A thermosetting resin composition comprising:[A] a polyfunctional epoxy resin produced from a reaction between a mixture of at least two polyhydric phenols selected from (a) bis(4-hydroxyphenyl)methane, (b) bis(4-hydroxyphenyl)ethane, (c) bis(4-hydroxyphenyl)-propane, (d) tris(4-hydroxyphenyl)alkane and (e) tetra(4-hydroxyphenyl)alkane, and epichlorohydrin, and[B] an acid anhydride curing agent; and a coil and a panel formed of said composition.
    Type: Grant
    Filed: January 31, 1995
    Date of Patent: August 12, 1997
    Assignee: Hitachi, Ltd.
    Inventors: Toru Koyama, Chikashi Kanno, Hirokazu Takasaki, Koo Honjoo, Shinichi Toyoda, Hiroshi Suzuki, Ikushi Kano
  • Patent number: 5654048
    Abstract: Cementitious containers which have a cementitious structural matrix for use in the packaging, storing, partitioning, and/or shipping of goods. The containers are manufactured from cementitious materials in order to be strong, durable, tough, lightweight, cushioning, insulative, inexpensive, and more environmentally compatible than those currently used in packaging, storing, and/or shipping goods. The cementitious structural matrix of the containers includes a hydraulic cement paste (formed from the reaction of water with, e.g., a portland cement) in combination with a rheology-modifying plasticizer, such as methylhydroxyethylcellulose. Preferred embodiments may also in include various aggregate materials, fibrous materials, and air voids, which add the necessary strength while making the product lightweight, and which can provide insulative properties (if desired) at a cost which is economically justified in comparison to conventional paper and polystyrene products.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 5, 1997
    Assignee: E. Khashoggi Industries
    Inventors: Per Just Andersen, Simon K. Hodson
  • Patent number: 5641584
    Abstract: Insulation barriers incorporating a cementitious structural matrix formed from a cementitious mixture including a hydraulic cement and water. The insulation barriers are manufactured from cementitious materials in order to be lightweight, insulative, less expensive, and more environmentally compatible than those currently used; they may augment, and even take the place of, traditional insulation materials including insulations made of glass fibers, polyurethane foam, urea-formaldehyde foam, polystyrene, wood fiber, cellulose fiber, rock-wool, etc. The cementitious structural matrix of the insulation barriers usually includes a hydraulic cement paste (formed from the reaction of water with, e.g., a portland-type cement) in combination with a rheology-modifying agent, such as methylhydroxyethylcellulose, and a lightweight aggregate material, which lowers the density of the insulation barrier and increases its insulation ability.
    Type: Grant
    Filed: March 28, 1995
    Date of Patent: June 24, 1997
    Assignee: E. Khashoggi Industries
    Inventors: Per Just Andersen, Simon K. Hodson
  • Patent number: 5637236
    Abstract: A method for producing a wall, roadway, sidewalk or floor of cementitious material having the appearance of natural stone and mortar including a base with an outer surface with a plurality of irregular shaped protrusions disposed in a random pattern to simulate natural stones and a plurality of simulated grout lines formed therebetween, the method including the steps of preparing a cementitious material, pouring the cementitious material into a form, vibrating the cementitious material, allowing the cementitious material to cure forming the base with the outer surface, releasing the base with the plurality of irregular shaped protrusions disposed in the random pattern to simulate natural stones and the plurality of simulated grout lines formed therebetween from the form, coloring the outer surface and accenting the plurality of simulated grout lines.
    Type: Grant
    Filed: September 1, 1994
    Date of Patent: June 10, 1997
    Inventor: Michael Lowe
  • Patent number: 5637362
    Abstract: A process for making a thin, sealant-coated, fire and indentation resistant gypsum panel. A layer of a mixture of cellulosic fibers moistened with water and an additive to restrict the adhesion of cellulosic fibers to one another, is deposited on at least two separate conveyors to form a fibrous matt on each conveyor. A layer of dry calcined gypsum containing set accelerator is deposited on the fibrous matt on each conveyor which contains, by weight on a dry weight basis, about 70-90% gypsum, about 10%-19% cellulosic fiber and about 1%-9% of combined additive and set accelerator. Each layer on each conveyor is directed to a mixing station to form a homogeneous layer, and the formed homogeneous layers on separate conveyors are placed atop one another on a single conveyor to form a combined homogeneous layer. Water is added to the layer or layers to rehydrate calcined gypsum. The combined homogeneous layer is subjected to pressure to form a pressed, homogeneous fiber-reinforced gypsum panel, and dried.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: June 10, 1997
    Assignee: Louisiana-Pacific Corporation
    Inventors: Peter D. Chase, Lloyd M. George, John D. McInnis, Thomas P. Krawiec
  • Patent number: 5637412
    Abstract: The present invention relates to hydraulically bonded cement compositions and methods. More particularly, the present invention is directed to novel compositions and methods of hydrating hydraulic cement without mechanical mixing of the cement and water. The present invention includes materials prepared by manipulating under pressure powdered hydraulic cement compositions using known or novel powder packing, casting, or expanding techniques, such that air within the powdered hydraulic cement is substantially removed while the cement is formed into a self-supporting near net final position. Thereafter, the formed hydraulic cement is hydrated without mechanical mixing of the cement and water.
    Type: Grant
    Filed: September 26, 1994
    Date of Patent: June 10, 1997
    Assignee: E. Khashoggi Industries
    Inventors: Hamlin M. Jennings, Per J. Andersen, Simon K. Hodson
  • Patent number: 5635292
    Abstract: Incorporation of solid removable aggregates into powdered cement which later completely dissolve, evaporate, volatilize, or melt leaving voids in the cement composition is discussed. Cementitious articles are prepared by manipulating powdered hydraulic cement or cement paste compositions into mechanically self-supporting structures of a predetermined configuration and thereafter hydrating the hydraulic cement compositions without mechanical mixing of the cement and water.
    Type: Grant
    Filed: October 18, 1994
    Date of Patent: June 3, 1997
    Assignee: E. Khashoggi Industries
    Inventors: Hamlin M. Jennings, Simon K. Hodson
  • Patent number: 5635263
    Abstract: The present invention has an object to provide a reinforcing fiber sheet which permits sufficient reinforcement of a concrete structure with a smaller number of layers than in the conventional cases, without causing fracture of the sheet within a range of yielding of reinforcing bars. The reinforcing fiber sheet 1 of the invention comprises high-elasticity and high-elongation carbon fibers 4 having a modulus of elasticity of at least 35 ton/mm.sup.2 and a fracture elongation of at least 0.9%, arranged in an amount of at least 250 g/m.sup.2 in one direction through an adhesive layer 3 on a substrate sheet 2. The object of the invention can be achieved by providing the carbon fibers 4 of the reinforcing fiber sheet 1 with the above-mentioned properties.
    Type: Grant
    Filed: September 22, 1994
    Date of Patent: June 3, 1997
    Assignee: Tonen Corporation
    Inventor: Makoto Saito
  • Patent number: 5631097
    Abstract: Laminate insulation barriers including a highly insulative layer and a structural layer which has a cementitious structural matrix. The laminate insulation barriers are lightweight and more environmentally compatible than those currently used; they may augment, and even take the place of, traditional insulation materials which typically contain nondegradable, environmentally damaging materials.
    Type: Grant
    Filed: April 24, 1995
    Date of Patent: May 20, 1997
    Assignee: E. Khashoggi Industries
    Inventors: Per J. Andersen, Simon K. Hodson
  • Patent number: 5631052
    Abstract: Cementitious containers which have a cementitious structural matrix for use in the packaging, storing, partitioning, and/or shipping of goods. The containers are manufactured from cementitious materials in order to be strong, durable, tough, lightweight, cushioning, insulative, inexpensive, and more environmentally compatible than those currently used in packaging, storing, and/or shipping goods. The cementitious structural matrix of the containers includes a hydraulic cement paste (formed from the reaction of water with, e.g., a portland cement) in combination with a rheology-modifying plasticizer, such as methylhydroxyethylcellulose. Preferred embodiments may also include various aggregate materials, fibrous materials, and air voids, which add the necessary strength while making the product lightweight, and which can provide insulative properties (if desired) at a cost which is economically justified in comparison to conventional paper and polystyrene products.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 20, 1997
    Assignee: E. Khashoggi Industries
    Inventors: Per J. Andersen, Simon K. Hodson
  • Patent number: 5626954
    Abstract: Compositions and methods for manufacturing sheets having a hydraulically settable matrix. Suitable compositions are prepared by mixing together a hydraulic binder, water, and appropriate additives (such as aggregates, fibers, and rheology-modifying agents) which impart predetermined properties so that a sheet formed therefrom has the desired performance criteria. The compositions are formed into sheets by first extruding them into a sheet and then calendering the sheet using a set of rollers. The calendered sheets are dried in an accelerated manner to form a substantially hardened sheet. The drying is performed by heated rollers and/or a drying chamber. The hydraulically settable sheets so formed may have properties substantially similar to sheets made from presently used materials like paper, cardboard, polystyrene, or plastic. Such sheets can be rolled, pressed, scored, perforated, folded, and glued. They have especial utility in the mass production of containers, particularly food and beverage containers.
    Type: Grant
    Filed: August 3, 1993
    Date of Patent: May 6, 1997
    Assignee: E. Khashoggi Industries
    Inventors: Per J. Andersen, Simon K. Hodson
  • Patent number: 5615528
    Abstract: A load bearing structure having a set of uniform voids functions to resolve the forces imposed by developing compression in the material having the voids and minimizing the amount of tension developed in the material. For the voids to have this function, they must be deployed in a particular fashion. The voids are deployed to encompass a particular set of points. The set of points are such that each point in the matrix is spaced an equal distance from twelve and only twelve adjacent points of the matrix. The distance between the points does not matter as long as all are uniformly distanced in accordance with that rule. If the structure is considered to be composed of a closely packed set of hypothetical rhombic dodecahedra (RD) and the four edge vertices of each of those hypothetical RDs is truncated, the result will be a set of cubic voids.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: April 1, 1997
    Inventor: Charles R. Owens
  • Patent number: 5614307
    Abstract: Compositions and methods for manufacturing sheets having a hydraulically settable matrix are disclosed. Suitable compositions are prepared by mixing together a hydraulic binder, water, and appropriate additives (such as aggregates, fibers, and rheology-modifying agents) which impart predetermined properties so that a sheet formed therefrom has the desired performance criteria. The compositions are formed into sheets by first extruding them into a sheet and then calendering the sheet using a set of rollers. The calendered sheets are dried in an accelerated manner to form a substantially hardened sheet. The drying is performed by heated rollers and/or a drying chamber. The hydraulically settable sheets so formed may have properties substantially similar to sheets made from presently used materials like paper, cardboard, polystyrene, or plastic. Such sheets can be rolled, pressed, scored, perforated, folded, and glued.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 25, 1997
    Assignee: E. Khashoggi Industries
    Inventors: Per J. Andersen, Simon K. Hodson
  • Patent number: 5612116
    Abstract: A decorative sheet for construction is disclosed. The decorative sheet for construction comprises a thermoplastic polyester resin foam forming a surface layer, a large number of inorganic aggregates scattered over the surface of the foam in the presence of an adhesive, said inorganic aggregates forming a decorative face layer by the medium of the adhesive, and a backing layer formed on the decorative face layer. The decorative sheet of the present invention enables its decorative face layer with a backing layer to be reliably and readily transferred to the surface of concrete construction or products, and yet which enables a foam layer as a protective layer for the decorative face layer with a backing layer to be readily removed after application. A decorative concrete product for construction using the same, and processes for preparing them are also disclosed.
    Type: Grant
    Filed: March 13, 1996
    Date of Patent: March 18, 1997
    Assignees: Sekisui Kaseihin Kogyo Kabushiki Kaisha, Nippon Preston Kabushiki Kaisha, Eslen Chemical Co., Ltd.
    Inventors: Chitoshi Jinno, Hiroyuki Toyohara, Hikaru Mimura, Takashi Murohashi