Plural Layers Patents (Class 429/144)
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Patent number: 9601739Abstract: A method for producing a porous polyimide film comprises: forming a first un-burned composite film wherein the first film is formed on a substrate using a first varnish that contains (A1) a polyamide acid or a polyimide and (B1) fine particles at a volume ratio (A1):(B1) of from 19:81 to 45:65; forming a second un-burned composite film wherein the second film is formed on the first film using a second varnish that contains (A2) a polyamide acid or a polyimide and (B2) fine particles at a volume ratio (A2):(B2) of from 20:80 to 50:50 and has a lower fine particle content ratio than the first varnish; burning wherein an un-burned composite film composed of the first film and the second film is burned, thereby obtaining a polyimide-fine particle composite film; and a fine particle removal step wherein the fine particles are removed from the polyimide-fine particle composite film.Type: GrantFiled: March 31, 2014Date of Patent: March 21, 2017Assignee: TOKYO OHKA KOGYO CO., LTD.Inventors: Tsukasa Sugawara, Takahiro Asai
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Patent number: 9601723Abstract: Electrochemical device and method. The electrochemical device has an electrochemical module and an enclosure configured to enclose the electrochemical module. The enclosure has an electrically conductive first housing portion forming a first rim and an electrically conductive second housing portion forming a second rim, the first housing portion and the second housing portion, when the first rim of the first housing portion substantially abuts the second rim of the second housing portion, forming, at least in part, a volume configured to enclose the electrochemical device. The enclosure further has a substantially non-conductive grommet positioned between the first rim and the second rim, and a crimp ring engaging the first rim and the second rim, the crimp ring being configured to secure the first housing portion with respect to the second housing portion. The grommet is further positioned between the crimp ring and the first rim and the second rim.Type: GrantFiled: October 31, 2012Date of Patent: March 21, 2017Assignee: Medtronic, Inc.Inventor: Christian S. Nielsen
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Patent number: 9570720Abstract: A rechargeable battery includes an electrode assembly; a case accommodating the electrode assembly; a cap plate coupled to an opening of the case; an electrode terminal connected to the electrode assembly and extending through a terminal hole of the cap plate; and a retainer having first ends contacting the case and located between the electrode assembly and the side wall to support the electrode assembly and the side wall, wherein a thickness of the retainer gradually decreases away from the first ends of the retainer.Type: GrantFiled: December 31, 2014Date of Patent: February 14, 2017Assignee: Samsung SDI Co., Ltd.Inventor: Sang-Won Byun
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Patent number: 9564655Abstract: A manufacturing method of an all-solid battery includes fabricating a single battery including a positive electrode layer, a negative electrode layer, and a solid electrolyte layer arranged between the positive electrode layer and the negative electrode layer; fabricating a plurality of battery packs including the plurality of single batteries; confining a plurality of battery packs by an equal confining pressure; measuring the electrical characteristics of the plurality of confined battery packs; determining the battery pack whose measured electrical characteristics are the worst of the plurality of battery packs; reducing the confining pressures of the other battery packs so that the electrical characteristics of the other battery packs are equal to that of the battery pack whose electrical characteristics have been determined to be the worst; and electrically connecting in parallel the battery packs.Type: GrantFiled: December 2, 2014Date of Patent: February 7, 2017Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Hajime Hasegawa, Norihiro Ose, Tomoharu Sasaoka, Kazuhito Kato, Kengo Haga, Daichi Kosaka
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Patent number: 9564638Abstract: A battery electrode or separator surface protective agent composition having fluidity and being capable of being solidified by hot melt, and comprising at least two types of organic particles comprising organic materials, wherein the organic particles of types different from each other are substantially incompatible with each other, wherein when the composition is solidified by hot melt, the organic particles of the same type thermally fuse with one another to form a continuous phase.Type: GrantFiled: December 12, 2011Date of Patent: February 7, 2017Assignee: KYORITSU CHEMICAL & CO., LTD.Inventor: Taichi Uemura
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Patent number: 9543566Abstract: Miniature electrodes and electrochemical cells are disclosed. Such electrodes are made from forming an electrode mixture onto a current collector and distal end of a feedthrough pin such that the current collector and distal end of the feedthrough pin is encapsulated. The methods and electrode assemblies disclosed herein allow such electrode assemblies to be made free from the step of directly attaching a formed electrode to a feedthrough pin and thus simplifying assembly and decreasing size.Type: GrantFiled: January 13, 2014Date of Patent: January 10, 2017Assignee: Medtronic, Inc.Inventors: Hailiang Zhao, Christian S. Nielsen
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Patent number: 9537178Abstract: Provided is an electrode assembly, and more particularly, an electrode assembly having a structure wound in a state, in which a plurality of unit cells having a stacking structure is disposed on a long sheet type separation film, and including the unit cells having two or more types of configurations of electrode materials, wherein a separator stacked on the unit cell having a stacking structure has a coating material coated on both sides thereof and the long sheet type separation film has a coating material coated on one side thereof. According to the present invention, an electrode assembly improving processability of preparation of a battery while reducing initial resistance during the preparation of the battery as well as having battery lifetime equivalent to that of a conventional battery and a lithium secondary battery including the electrode assembly may be provided.Type: GrantFiled: January 11, 2013Date of Patent: January 3, 2017Assignee: LG Chem, Ltd.Inventors: Sung Joon Park, Seung Don Choi, Yong Kyu Ju, Ji Hoon Jeon, Hye Jin Kang
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Patent number: 9525189Abstract: An adhesive resin composition for a secondary battery for bonding a separator for a secondary battery and an electrode for a secondary battery, wherein the composition comprises an adhesive resin, the adhesive resin contains the following (A) and (B), and the phase composed of (A) and (B) has a core shell heterophase structure and/or a sea-island heterophase structure: (A) a resin having a glass transition temperature of ?30° C. to +20° C., (B) a resin having a glass transition temperature 20° C. to 200° C. higher than the glass transition temperature of (A).Type: GrantFiled: September 24, 2012Date of Patent: December 20, 2016Assignee: Sumitomo Chemical Company, LimitedInventor: Toshihiko Ogata
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Patent number: 9508975Abstract: A nonaqueous electrolyte secondary battery separator is a porous film containing a polyolefin as a main component. The nonaqueous electrolyte secondary battery separator (i) has a phase difference of 80 nm or less with respect to light having a wavelength of 590 nm in a state where the nonaqueous electrolyte secondary battery separator is impregnated with ethanol and (ii) has a porosity of 30% to 60%.Type: GrantFiled: June 24, 2016Date of Patent: November 29, 2016Assignee: Sumitomo Chemical Company, LimitedInventor: Takahiro Matsuo
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Patent number: 9478804Abstract: A cathode active material including a composite transition metal oxide including: sodium; a first transition metal; and a second transition metal, wherein the composite transition metal oxide has a first diffraction peak corresponding to a Miller index of (003) and derived from a layered rock salt structure, and a second diffraction peak corresponding to a Miller index of (104) and derived from a cubic rock salt structure in an X-ray powder diffraction (XRD) pattern, wherein an intensity ratio (I1/I2) of the first diffraction peak to the second diffraction peak is about 7 or greater.Type: GrantFiled: October 21, 2014Date of Patent: October 25, 2016Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Kwang-jin Park, Dong-wook Han, Hyun-jin Kim, Seok-soo Lee, Won-seok Chang
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Patent number: 9453805Abstract: The instant application relates to an X-ray sensitive battery separator for a secondary lithium battery and a method for detecting the position of a separator in a secondary lithium battery. The X-ray sensitive battery separator includes a microporous membrane having an X-ray detectable element therein, thereon, or added thereto. The X-ray detectable element constitutes less than 20% by weight of the microporous membrane or separator. The method for detecting the position of a separator in a battery, cell, stack, jellyroll, can, or the like includes the following steps: (1) providing a battery, cell, stack, jellyroll, or the like including an X-ray sensitive battery separator; (2) subjecting the battery, cell, stack, jellyroll, or the like to X-ray radiation; and (3) thereby detecting the position of said separator in said battery, cell, stack, jellyroll, or the like.Type: GrantFiled: January 19, 2010Date of Patent: September 27, 2016Assignee: Celgard, LLCInventors: Xuefa Li, C. Glen Wensley, Zhengming Zhang
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Patent number: 9455432Abstract: A multi-layered battery separator for a lithium secondary battery includes a first layer of a dry processed membrane bonded to a second layer of a wet processed membrane. The first layer may be made of a polypropylene based resin. The second layer may be made of a polyethylene based resin. The separator may have more than two layers. The separator may have a ratio of MD/TD tensile strength in the range of about 1.5-3.0. The separator may have a thickness of about 35.0 microns or less. The separator may have a puncture strength of greater than about 630 gf. The separator may have a dielectric breakdown of at least about 2000V.Type: GrantFiled: March 14, 2014Date of Patent: September 27, 2016Assignee: Celgard, LLCInventors: Lie Shi, Jill V. Watson, Ronald W. Call, Ronnie E. Smith
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Patent number: 9450230Abstract: A lithium-ion secondary battery including an electrode having a current collector and an active material layer, formed on the current collector, that contains an active material and polybenzimidazole. Also, a method of manufacturing a lithium-ion secondary battery including manufacturing an electrode having a current collector and an active material layer, formed on the current collector, that contains an active material and polybenzimidazole.Type: GrantFiled: February 9, 2010Date of Patent: September 20, 2016Assignee: TDK CORPORATIONInventors: Atsushi Sano, Hisashi Suzuki
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Patent number: 9425460Abstract: Embodiments of the invention provide batteries, electrodes, and methods of making the same. According to one embodiment, a battery may include a positive plate having a grid pasted with a lead oxide material, a negative plate having a grid pasted with a lead based material, a separator separating the positive plate and the negative plate, and an electrolyte. A nonwoven glass mat may be in contact with a surface of either or both the positive plate or the negative plate to reinforce the plate. The nonwoven glass mat may include a plurality of first coarse fibers having fiber diameters between about 6 ?m and 11 ?m and a plurality of second coarse fibers having fiber diameters between about 10 ?m and 20 ?m.Type: GrantFiled: July 16, 2015Date of Patent: August 23, 2016Assignee: Johns ManvilleInventors: Zhihua Guo, Souvik Nandi, Jawed Asrar, Albert G Dietz, III
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Patent number: 9412988Abstract: A porous separator including a porous base film; and a coating layer, the coating layer being on a surface of the porous base film and including a polyvinylidene fluoride homopolymer, a polyvinylidene fluoride-hexafluoropropylene copolymer, and inorganic particles, wherein the separator exhibits a thermal shrinkage of about 30% or less in a machine direction (MD) or in a transverse direction (TD), as measured after leaving the separator at 150° C. for 1 hour, a peel strength of about 50 gf/cm2 or more between the coating layer and the base film, and an adhesive strength of about 20 gf/cm2 or more between the coating layer and electrodes of a battery.Type: GrantFiled: February 27, 2013Date of Patent: August 9, 2016Assignee: CHEIL INDUSTRIES, INC.Inventors: Ki Chul Hong, Myung Kook Park, Jae Goo Doh, Jun Ho Chung
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Patent number: 9391344Abstract: Disclosed is a polymer electrolyte having a multilayer structure including a first polymer layer providing mechanical strength against external force and a second polymer layer to secure a conduction path for lithium ions, wherein the first polymer layer includes an organic electrolyte containing an ionic salt in an amount of 0 wt % to 60 wt % based on a weight of a polymer matrix of the first polymer layer and the second polymer layer includes an organic electrolyte containing an ionic salt in an amount of 60 wt % to 400 wt % based on a weight of a polymer matrix of the second polymer layer, and a lithium secondary battery including the same.Type: GrantFiled: December 27, 2013Date of Patent: July 12, 2016Assignee: LG Chem, Ltd.Inventors: YoHan Kwon, Sung-Kyun Chang, Seung-tae Hong, Je Young Kim, ByungHun Oh
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Patent number: 9379369Abstract: Disclosed herein is an integrated electrode assembly including a cathode, an anode, and a separation layer disposed between the cathode and the anode. The cathode, the anode, and the separation layer are integrated with each other. The separation layer includes 3 phases including a liquid-phase component containing an ionic salt, a solid-phase component supporting the separation layer between the cathode and the anode, and a polymer matrix in which linear polymers and cross-linked polymers form a viscoelastic structure with the liquid-phase component and the solid-phase component being incorporated in the polymer matrix. The polymer matrix is coupled to each of the cathode and the anode. The liquid-phase component of the separation layer flows into the electrodes (i.e., the cathode and anode) during preparation of the integrated electrode assembly to greatly improve wetting properties of the electrodes and to increase ionic conductivity of the electrodes.Type: GrantFiled: February 8, 2012Date of Patent: June 28, 2016Assignee: LG Chem, Ltd.Inventors: Yohan Kwon, Sung-Kyun Chang, Seung-Tae Hong, Je Young Kim
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Patent number: 9368777Abstract: Disclosed is an electrochemical device. The electrochemical device includes: (a) a composite separator including a porous substrate, a first porous coating layer coated on one surface of the porous substrate, and a second porous coating layer coated on the other surface of the porous substrate; (b) an anode disposed to face the first porous coating layer; and (c) a cathode disposed to face the second porous coating layer. The first and second porous coating layers are each independently composed of a mixture including inorganic particles and a binder polymer. The first porous coating layer is thicker than the second porous coating layer. The electrochemical device has good thermal stability and improved cycle characteristics.Type: GrantFiled: March 10, 2014Date of Patent: June 14, 2016Assignees: LG Chem, Ltd., Toray Battery Seperator Film Co., Ltd.Inventors: Joo-Sung Lee, Jang-Hyuk Hong, Jong-Hun Kim, Bo-Kyung Ryu
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Patent number: 9343719Abstract: The present invention produces a laminated porous film which improves the stability of an aqueous dispersion of a metal oxide without lowering battery characteristics, while having high binding properties and excellent heat resistance. This laminated porous film exhibits excellent characteristics when used as a separator for batteries. This laminated porous film is produced by forming a porous coating layer on at least one outer surface of a resin porous film, which is formed of a single layer or a laminate of a plurality of layers, by applying a coating liquid that contains a metal oxide, a resin binder and a volatile acid thereto and drying the applied coating liquid. The coating liquid is prepared so that the difference between the pH (pH1) of the coating liquid and the pH (pH2) of the coating layer is not less than 2.Type: GrantFiled: September 18, 2012Date of Patent: May 17, 2016Assignee: MITSUBISHI PLASTICS, INC.Inventors: Hiroto Yamada, Tomoyuki Nemoto
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Patent number: 9343772Abstract: A rechargeable battery includes an electrode assembly undergoing charging and discharging, a pressurization holder covering the electrode assembly and fixing the electrode assembly, a positive terminal and a negative terminal electrically connected to the electrode assembly, and a case accommodating the electrode assembly and the pressurization holder in a state in which the positive terminal and the negative terminal protrude from the case.Type: GrantFiled: August 10, 2011Date of Patent: May 17, 2016Assignees: Samsung SDI Co., Ltd., Robert Bosch GmbHInventor: Sang-Won Byun
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Patent number: 9293749Abstract: Provided is an ultrafine fibrous porous separator with heat resistance and high-strength and a manufacturing method thereof, which enables mass-production of a heat-resistant and high-strength ultrafine fibrous separator by using an air-electrospinning (AES) method, and to a secondary battery using the same. The method of manufacturing a heat-resistant and high-strength ultrafine fibrous porous separator includes the steps of: air-electrospinning a mixed solution of 50 to 70 wt % of a heat-resistant, polymer material and 30 to 50 wt % of a swelling polymer material, to thereby form a porous web of a heat-resistant ultrafine fiber in which the heat-resistant polymer material and the swelling polymer material are consolidated in an ultrafine fibrous form; performing drying to control a solvent and moisture that remain on the surface of the porous web; and performing thermal compression on the dried porous web at a temperature of between 170° C. and 210° C. so as to obtain the separator.Type: GrantFiled: November 3, 2010Date of Patent: March 22, 2016Assignee: AMOGREENTECH CO., LTD.Inventors: In Yong Seo, Byung Gwang Jo, Yong Sik Jung, Yun Hye Kim
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Patent number: 9293753Abstract: The porous membrane according to the present invention comprises non-conductive particles, a binder, and a water-soluble polymer, and is characterized in that: the three dimensions of the non-conductive particles, namely the length (L), thickness (t), and width (b), are such that the length (L) is 0.1 to 0 ?m, the ratio (b/t) of the width (b) and the thickness (t) is 1.5 to 100; the binder is a copolymer containing (meth)acrylonitrile monomer units and (meth)acrylic acid ester monomer units; and the water-soluble polymer contains sulfonic acid groups, and has a weight average molecular weight of 1000 to 15000. The slurry for a porous membrane according to the present invention is characterized by being formed by dispersing the non-conductive particles, the binder, and the soluble polymer, in water.Type: GrantFiled: February 24, 2012Date of Patent: March 22, 2016Assignee: ZEON CORPORATIONInventor: Yujiro Toyoda
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Patent number: 9287589Abstract: A system and method for stabilizing electrodes against dissolution and/or hydrolysis including use of cosolvents in liquid electrolyte batteries for three purposes: the extension of the calendar and cycle life time of electrodes that are partially soluble in liquid electrolytes, the purpose of limiting the rate of electrolysis of water into hydrogen and oxygen as a side reaction during battery operation, and for the purpose of cost reduction.Type: GrantFiled: March 31, 2014Date of Patent: March 15, 2016Assignee: Alveo Energy, Inc.Inventors: Colin Deane Wessells, Ali Firouzi, Shahrokh Motallebi, Sven Strohband
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Patent number: 9274068Abstract: A method for detecting the position of a separator relative to electrodes in a secondary lithium battery includes the steps of: providing a secondary lithium battery including a positive electrode, a negative electrode, a X-ray sensitive separator located between the electrodes, and a can or pouch housing the electrodes and separator, the X-ray sensitive separator comprising a microporous membrane having a X-ray detectable element dispersed therein or thereon, the X-ray detectable element comprising at least 2 and no greater than 20 weight % of the membrane; subjecting the secondary lithium battery to X-ray radiation; determining the position of the separator relative to the electrodes; and approving or rejecting the secondary lithium battery based upon the position of the separator relative to the electrodes.Type: GrantFiled: September 21, 2015Date of Patent: March 1, 2016Assignee: Celgard LLCInventors: Xuefa Li, C. Glen Wensley, Zhengming Zhang
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Patent number: 9257702Abstract: To provide a lithium secondary battery which has high capacity while maintaining excellent charge-discharge characteristic, and to provide a cathode of the lithium secondary battery and a plate-like particle for cathode active material to be contained in the cathode. The plate-like particle of cathode active material for a lithium secondary battery of the present invention has a layered rock salt structure, a thickness of 5 ?m or more and less than 30 ?m, 2 or less of [003]/[104] which is a ratio of intensity of X-ray diffraction by the (003) plane to intensity of X-ray diffraction by the (104) plane, a voidage of 3% or more and less than 30%, and an open pore ratio of 70% or higher.Type: GrantFiled: June 21, 2011Date of Patent: February 9, 2016Assignee: NGK Insulators, Ltd.Inventors: Ryuta Sugiura, Nobuyuki Kobayashi, Tsutomu Nanataki
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Patent number: 9252411Abstract: Use of a flexible, nonconductive, porous, and thermally tolerant ceramic material as a separator in a lithium-ion battery or lithium-sulfur battery is described. The separator can be made of aluminum oxide and provides excellent mechanical and thermal properties that prevent wear and puncture of the separator caused by particles removed from the electrodes during the charging and discharging process. The separator is designed to mitigate effects of melt shrinkage and facilitate the lithium ion transport, in contrast to separators that include a polymeric material, thus preventing short-circuiting between the positive and the negative electrode. Improved wetting and filling of the separator with electrolyte solution are provided, for improved rate capability of the battery (fast charging and discharging). The separator further reduces the potential for thermal runaway in Li batteries.Type: GrantFiled: November 22, 2013Date of Patent: February 2, 2016Assignee: GM Global Technology Operations LLCInventors: Mahmoud H. Abd Elhamid, Xingcheng Xiao, Mei Cai
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Patent number: 9231239Abstract: An electricity supply element and the ceramic separator thereof are provided. The ceramic separator is adapted to separate two electrode layers of the electricity supply element for permitting ion migration and electrical separation. The ceramic separator is made of ceramic particulates and the adhesive. The adhesive employs dual binder system, which includes linear polymer and cross-linking polymer. The adhesion and heat tolerance are enhanced by the characteristic of the two type of polymers. The respective position of the two electrode layers are maintained during high operation temperature to improve the stability, and battery performance. Also, the ceramic separator enhances the ion conductivity and reduces the possibility of the micro-short to increase practical utilization.Type: GrantFiled: January 12, 2013Date of Patent: January 5, 2016Assignee: PROLOGIUM HOLDING INC.Inventor: Szu-Nan Yang
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Patent number: 9231238Abstract: In an electric storage device, lithium electrodes are disposed on respective outermost portions of an electrode laminated unit in which a positive electrode and a negative electrode are laminated alternately via positive/negative electrode separators. The lithium electrode includes lithium metal serving as a lithium ion supply source, and a lithium electrode separator (a non-woven fabric separator) constituted by a non-woven fabric that satisfies the following conditions: (a) an average fiber diameter of 0.1 ?m to 10 ?m; and (b) a thickness of 5 ?m to 500 ?m is provided. By forming the lithium electrode separator that contacts the lithium electrode including the lithium ion supply source from a non-woven fabric in this manner, a dramatic improvement can be achieved in the cycle characteristic of the electric storage device.Type: GrantFiled: March 3, 2011Date of Patent: January 5, 2016Assignee: FUJI JUKOGYO KABUSHIKI KAISHAInventors: Sawako Noda, Kunio Nakazato, Hideo Yanagita, Satoru Kudo
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Patent number: 9196885Abstract: The present invention provides a lamination type secondary battery in which separators are prevented from becoming wrinkled and are free from laminating dislocation. An aspect of the present invention is a lamination type secondary battery in which a plurality of planar positive electrodes (2) and negative electrodes (3) are alternately laminated. The lamination type secondary battery includes a plurality of pairs of separators (4?), an intermittent joining section (6), and an outer periphery joining section (7). Each pair of separators (4?) sandwiches and coats at least one among from the positive electrodes (2) and the negative electrodes (3). The intermittent joining section (6) is arranged at predetermined intervals along an outer periphery of each of the positive electrodes (2) or each of the negative electrodes (3). The intermittent joining section (6) is a section that joins the pair of separators (4?).Type: GrantFiled: December 15, 2010Date of Patent: November 24, 2015Assignee: NEC ENERGY DEVICES, LTD.Inventors: Takeshi Ise, Takao Daidoji
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Patent number: 9177729Abstract: The present invention provides a separator and a method for manufacturing the separator. The separator includes a first nanofiber layer (20) which has a lattice shape when viewed from a plan view, a second nanofiber layer (30) which is provided on a first surface of the first nanofiber layer (20) and is thinner than the first nanofiber layer, and a third nanofiber layer (40) which is provided on a second surface of the first nanofiber layer and is thinner than the first nanofiber layer. The thickness of the first nanofiber layer ranges from 7 ?m to 30 ?m. The thickness of each of the second and third nanofiber layers ranges from 1 ?m to 5 ?m. The present invention can provide a separator which has high insulation, high dendrite resistance, high ion conductivity and high mechanical strength.Type: GrantFiled: February 6, 2012Date of Patent: November 3, 2015Assignees: TOPTEC COMPANY LIMITED, SHINSHU UNIVERSITYInventors: Ick-soo Kim, Byoung-Suhk Kim, Kei Watanabe, Naotaka Kimura, Kyu-oh Kim, Jae-hwan Lee
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Patent number: 9178199Abstract: A lithium battery including a positive electrode; a negative electrode including a negative active material layer including a first aqueous binder and a second aqueous binder, the first aqueous binder including a monomer unit; and a separator between the positive electrode and the negative electrode, the separator including a base material layer and a polymer layer formed on at least one surface of the base material layer, and the polymer layer including a non-aqueous binder including a monomer unit identical to the monomer unit of the first aqueous binder is disclosed.Type: GrantFiled: July 24, 2012Date of Patent: November 3, 2015Assignee: Samsung SDI Co., Ltd.Inventors: In-Seop Byun, Young-Bae Sohn, Kyeong-Min Jeong
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Patent number: 9166251Abstract: A nonaqueous electrolyte battery of the present invention includes a positive electrode having a positive active material capable of intercalating and deintercalating a lithium ion, a negative electrode having a negative active material capable of intercalating and deintercalating a lithium ion, a separator interposed between the positive electrode and the negative electrode, and a nonaqueous electrolyte. The heat generation starting temperature of the positive electrode is 180° C. or higher. The separator includes heat-resistant fine particles and a thermoplastic resin. The proportion of particles with a particle size of 0.2 ?m or less in the heat-resistant fine particles is 10 vol % or less and the proportion of particles with a particle size of 2 ?m or more in the heat-resistant fine particles is 10 vol % or less. The separator effects a shutdown in the range of 100° C. to 150° C.Type: GrantFiled: September 30, 2008Date of Patent: October 20, 2015Assignee: HITACHI MAXELL, LTD.Inventors: Hideaki Katayama, Mitsuhiro Kishimi, Yoshinori Sato, Yasutaka Kuroki, Toshiyuki Edamoto
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Patent number: 9147905Abstract: A lithium mixed metal oxide, shown by the following formula (A): Lix(Mn1?y?z?dNiyFezMd)O2??(A) wherein M is one or more elements selected from the group consisting of Al, Mg, Ti, Ca, Cu, Zn, Co, Cr, Mo, Si, Sn, Nb and V; x is 0.9 or more and 1.3 or less; y is 0.3 or more and 0.7 or less; z is more than 0 and 0.1 or less, and d is more than 0 and 0.1 or less. A positive electrode active material, including the lithium mixed metal oxide. A positive electrode, including the positive electrode active material. A nonaqueous electrolyte secondary battery, including the positive electrode.Type: GrantFiled: March 18, 2010Date of Patent: September 29, 2015Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Kenji Takamori, Cedric Pitteloud
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Patent number: 9142357Abstract: The object of an exemplary embodiment of the invention is to provide a separator for an electric storage device which has small heat shrinkage in a high-temperature environment, and in which the increase of the battery temperature can be suppressed. An exemplary embodiment of the invention is a separator for an electric storage device, which comprises a cellulose derivative represented by a prescribed formula. The separator for an electric storage device can be obtained, for example, by treating a cellulose separator containing cellulose with a halogen-containing carboxylic acid or a halogen-containing alcohol.Type: GrantFiled: February 21, 2012Date of Patent: September 22, 2015Assignee: NEC CORPORATIONInventor: Kazuaki Matsumoto
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Patent number: 9123942Abstract: A method for making a separator of a lithium ion battery is provided. In the method, a modifier, and a porous membrane are provided. The modifier is a mixture of a phosphorus source having a phosphate radical, a trivalent aluminum source, and a metallic oxide provided in a liquid phase solvent. The modifier is coated on a surface of the porous membrane to form a coating layer. The coated porous membrane is dried to form a modifier layer disposed on the surface of the porous membrane.Type: GrantFiled: February 16, 2012Date of Patent: September 1, 2015Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.Inventors: Xiang-Ming He, Wei-Hua Pu, Li-Chun Zhang, Jian-Guo Ren, Jian-Jun Li, Jian Gao
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Patent number: 9112214Abstract: A battery separator comprises a multi-layered film, individual layers of film having been bonded together by heat and pressure, having a peel strength of greater than or equal to 40 grams per inch (1.6 g/mm) and a thickness of ?25 microns. A method for making a battery separator comprises the steps of: extruding and winding up a first precursor film, extruding and winding up a second precursor film, unwinding the first and second precursor films, stacking up the first and second precursor films to form a single stacked precursor, laminating the single stacked precursor film, winding up the laminated single stacked precursor film, stacking up a plurality of laminated single stacked precursor films, and making microporous the stacked plurality of laminated single stacked precursor films.Type: GrantFiled: March 7, 2007Date of Patent: August 18, 2015Assignee: Celgard Inc.Inventor: Ronald W. Call
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Patent number: 9083036Abstract: The present invention refers to a separator, comprising a porous substrate having multiple pores; a porous coating layer formed on at least one area selected from at least one surface of the porous substrate and the pores of the porous substrate, and comprising multiple inorganic particles and a binder polymer, the binder polymer being existed on a part or all of the surface of the inorganic particles to connect and immobilize the inorganic particles therebetween; and microcapsules dispersed in at least one area selected from the pores of the porous substrate and pores formed by vacant spaces between the inorganic particles present in the porous coating layer, and containing therein an additive for improving the performances of an electrochemical device, and an electrochemical device having the same.Type: GrantFiled: December 31, 2013Date of Patent: July 14, 2015Assignee: LG Chem, Ltd.Inventors: Hyung-Kyun Yu, Jong-Hun Kim, Jang-Hyuk Hong, In-Chul Kim, Joo-Sung Lee
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Patent number: 9077024Abstract: [Problem] A non-aqueous electrolyte battery is provided that shows good cycle performance and good storage performance under high temperature conditions and exhibits high reliability even with a battery configuration featuring high capacity. A method of manufacturing the battery is also provided.Type: GrantFiled: March 16, 2007Date of Patent: July 7, 2015Assignee: SANYO Electric Co., Ltd.Inventors: Takeshi Ogasawara, Hiroshi Minami, Naoki Imachi, Atsushi Kaiduka, Yasunori Baba, Yoshinori Kida, Shin Fujitani
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Patent number: 9070954Abstract: The present invention pertains to electrochemical cells which comprise (a) an anode; (b) a cathode; (c) a solid porous separator, such as a polyolefin, xerogel, or inorganic oxide separator; and (d) a nonaqueous electrolyte, wherein the separator comprises a porous membrane having a microporous coating comprising polymer particles which have not coalesced to form a continuous film. This microporous coating on the separator acts as a safety shutdown layer that rapidly increases the internal resistivity and shuts the cell down upon heating to an elevated temperature, such as 110° C. Also provided are methods for increasing the safety of an electrochemical cell by utilizing such separators with a safety shutdown layer.Type: GrantFiled: April 12, 2007Date of Patent: June 30, 2015Assignee: Optodot CorporationInventors: Steven Allen Carlson, Ifenna Kingsley Anakor, Greg Robert Farrell
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Patent number: 9054388Abstract: Provided is an energy storage device which employs the use of a separator provided with a layer having poor thermal properties such as a heat resistant coated layer and is capable of inhibiting a decrease in performance. The energy storage device includes: a wound body including a positive electrode, a negative electrode, and separators which are layered and wound, the separators being interposed between the positive electrode and the negative electrode and having a first surface and a second surface, the first surface having thermal bonding properties superior to thermal bonding properties of the second surface; and an insulation sheet wound around an outermost layer of the wound body. At least one of the separators is bonded to the insulation sheet via the first surface thereof.Type: GrantFiled: April 16, 2013Date of Patent: June 9, 2015Assignee: GS YUASA INTERNATIONAL LTD.Inventors: Akihiko Miyazaki, Sumio Mori, Tomonori Kako
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Patent number: 9054364Abstract: A battery includes a positive electrode, a negative electrode where a negative electrode active material layer containing a negative electrode active material containing natural graphite is formed on at least one surface of a negative electrode collector, and an electrolyte. A thickness of the negative electrode active material layer per one surface of the negative electrode collector is 50 ?m or more and 100 ?m or less, and in the negative electrode active material layer from the negative electrode collector up to ½ of the thickness of the layer in a surface direction of the negative electrode active material layer, an orientation degree A expressed as (peak intensity of carbon 002 face/peak intensity of carbon 110 face) that is a peak intensity ratio of a carbon 002 face and a carbon 110 face measured by an X-ray diffraction is 100 or more and 500 or less.Type: GrantFiled: March 26, 2013Date of Patent: June 9, 2015Assignee: SONY CORPORATIONInventors: Takaaki Matsui, Aya Mashiko, Tadashi Matsushita, Takehiko Ishii
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Patent number: 9054386Abstract: The present disclosure provides a sheet-form electrode for a secondary battery, comprising a current collector; an electrode active material layer formed on one surface of the current collector; a porous polymer layer formed on the electrode active material layer; and a first porous supporting layer formed on the porous polymer layer. The sheet-form electrode for a secondary battery according to the present disclosure has supporting layers on at least one of surfaces thereof to exhibit surprisingly improved flexibility and prevent the release of the electrode active material layer from a current collector even if intense external forces are applied to the electrode, thereby preventing the decrease of battery capacity and improving the cycle life characteristic of the battery.Type: GrantFiled: September 12, 2014Date of Patent: June 9, 2015Assignee: LG Chem, Ltd.Inventors: Yo-Han Kwon, Hye-Ran Jung, Eun-Kyung Kim, Je-Young Kim, In-Chul Kim, Hyo-Mi Kim
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Patent number: 9048487Abstract: A secondary battery which can maintain alignment between a first electrode plate and a second electrode plate and can improve the cell stability and life characteristic of the battery, and a manufacturing method thereof. A secondary battery includes an electrode assembly including a first electrode plate; a second electrode plate; a first separator between the first electrode plate and the second electrode plate and including a central portion and an outer portion at a periphery of the central portion; and a second separator at a side of the first electrode plate or the second electrode plate opposite a side facing the first separator, the second separator including a central portion and an outer portion at a periphery of the central portion of the second separator, and the outer portion of the first separator and the outer portion of the second separator contact each other at least at a joining part.Type: GrantFiled: March 18, 2011Date of Patent: June 2, 2015Assignee: Samsung SDI Co., Ltd.Inventor: Yongkyun Park
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Publication number: 20150147627Abstract: A rechargeable lithium battery includes a negative electrode including a negative active material layer and a separator including a substrate and a coating layer formed on at least one of the substrate. The coating layer includes a fluorine-based polymer. The at least one coating layer faces the negative active material layer. The negative active material layer includes a negative active material, a water-soluble polymer and a fluorine-based polymer particulate.Type: ApplicationFiled: November 24, 2014Publication date: May 28, 2015Inventor: Yasuo TAKANO
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Publication number: 20150140404Abstract: There is provided a separator used in an electrochemical device and more particularly, to a porous separator in which an organic/inorganic complex coating layer is applied to a porous substrate, a method for preparing the same, and an electrochemical device using the same.Type: ApplicationFiled: November 1, 2013Publication date: May 21, 2015Applicant: SAMSUNG TOTAL PETROCHEMICALS CO., LTD.Inventors: Ji Na Yoo, Jae Yong Hyun, Do Hoon Lee, Chang Hyun Choi
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Publication number: 20150140398Abstract: To provide a novel structure of a separator in a secondary battery. A nonaquesous secondary battery includes a positive electrode, a negative electrode, an electrolyte solution, a first separator, and a second separator. The first separator and the second separator are provided between the positive electrode and the negative electrode. The first separator is provided with a first pore, the second separator is provided with a second pore, and the size of the first pore is different from the size of the second pore. Furthermore, the proportion of the volume of the first pores in the first separator is different from the proportion of the volume of the second pores in the second separator.Type: ApplicationFiled: November 11, 2014Publication date: May 21, 2015Inventor: Shunpei YAMAZAKI
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Publication number: 20150140403Abstract: A separator for a lithium battery includes a porous coating layer disposed on a surface of a porous base, and a first adhesive layer including a plurality of dots disposed at intervals at a surface of the porous coating layer, the plurality of dots of the first adhesive layer penetrating through the porous coating layer to be on the surface of the porous base.Type: ApplicationFiled: September 18, 2014Publication date: May 21, 2015Inventors: Jung-Jin MOON, Chan-Jung KIM, Ihn KIM, Yun-Kyung JO, Young-Su KIM, Na-Rae PARK, Suk-Jung SON
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Publication number: 20150140402Abstract: A separator includes an organic-inorganic hybrid coating layer on at least one surface of a porous base and a pattern coating layer on a surface of the organic-inorganic hybrid coating layer. The pattern coating layer includes patterns having an average diameter of 0.1 mm or less that are regularly spaced apart from each other.Type: ApplicationFiled: September 18, 2014Publication date: May 21, 2015Inventors: Young-Su Kim, Jung-Jin Moon, Yun-Kyung Jo, Ihn Kim, Chan-Jung Kim, Na-Rae Park, Suk-Jung Son
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Publication number: 20150132626Abstract: An electrode assembly and a secondary battery using the same are disclosed. The electrode assembly includes a positive electrode, a negative electrode, and a lithium ion conductor layer disposed at least in one of between the positive electrode and the negative electrode, on an outer surface of the positive electrode, and on an outer surface of the negative electrode, to improve thermal safety of the secondary battery.Type: ApplicationFiled: November 3, 2014Publication date: May 14, 2015Inventors: Young-Jin Park, Do-Hyung Park, Ki-Hyun Kim, Min-Han Kim, Sang-Hoon Kim, Yu-Mi Song, Sun-Ho Kang, Kwang-Hwan Cho
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Publication number: 20150132632Abstract: The present disclosure provides a method for manufacturing an electrospun microfiber non-woven web with high strength for a lithium secondary battery, a non-woven web manufactured therefrom, and a separator comprising the non-woven web. More specifically, the present disclosure provides a microfiber non-woven web manufactured by bringing a solution of engineering plastic resin with high heat-resistance into electrospinning, the manufacture thereof, and a separator comprising the web. According to the present disclosure, the engineering plastic resin with high heat-resistance is used in the manufacture of the microfiber non-woven web to provide improved physical properties including tensile strength and good heat-resistance and chemical-resistance, as compared with conventional polyethylene-based separators.Type: ApplicationFiled: October 31, 2014Publication date: May 14, 2015Applicant: LG CHEM, LTD.Inventors: Won-Pill HWANG, Byeong-Gyu CHO, Young-Deok KIM