Hydrogen Containing Patents (Class 429/200)
  • Patent number: 10177414
    Abstract: A nonaqueous electrolytic solution, containing an electrolyte, a nonaqueous solvent, an aromatic carboxylate ester and a compound is provided. The compound is fluorine-containing cyclic carbonates, sulfur-containing organic compounds, phosphonate esters, cyano group-containing organic compounds, isocyanate group-containing organic compounds, silicon-containing compounds, aromatic compounds, cyclic compounds having a plurality of ether bonds, monofluorophosphate salts, difluorophosphate salts, borate salts, oxalate salts or fluorosulfonate salts.
    Type: Grant
    Filed: July 14, 2016
    Date of Patent: January 8, 2019
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Shuhei Sawa, Takashi Fujii, Kanako Ito, Koji Fukamizu, Ryo Yamaguchi, Hiromu Watanabe
  • Patent number: 10177404
    Abstract: A magnesium-ion battery includes a first electrode including an active material and a second electrode. An electrolyte is disposed between the first electrode and the second electrode. The electrolyte includes a magnesium compound. The active material includes tin.
    Type: Grant
    Filed: November 16, 2012
    Date of Patent: January 8, 2019
    Assignee: Toyota Motor Engineering & Manufacturing North America, Inc.
    Inventors: Nikhilendra Singh, Timothy Sean Arthur, Chen Ling, Masaki Matsui, Fuminori Mizuno
  • Patent number: 10164293
    Abstract: Disclosed are a non-aqueous electrolytic solution, which can improve cycle characteristics when a power storage device is used at high temperature and high voltage, and a power device using the same. The non-aqueous electrolytic solution according to the present invention comprises, in addition to a non-aqueous solvent and an electrolyte salt dissolved therein, a compound represented by the following formula (I): wherein n is an integer of 1 or 2; and when n is 1, L represents a straight or branched unsaturated hydrocarbon group of which at least one hydrogen atom is optionally substituted by a halogen atom, a cycloalkyl group of which at least one hydrogen atom is optionally substituted by a halogen atom, or an aryl group of which at least one hydrogen atom is optionally substituted by a halogen atom; and when n is 2, L represents a saturated or unsaturated divalent hydrocarbon group which optionally contains ether bond(s), or an arylene group.
    Type: Grant
    Filed: May 28, 2015
    Date of Patent: December 25, 2018
    Assignee: UBE INDUSTRIES, LTD.
    Inventors: Koji Abe, Kei Shimamoto, Shoji Shikita
  • Patent number: 10141762
    Abstract: The all-solid-state battery system that has an all-solid-state battery, the all-solid-state battery having a positive electrode active material layer, a solid electrolyte layer and a negative electrode active material layer, and a control device that controls the lower limit discharge potential of the positive electrode active material layer of the all-solid-state battery. The positive electrode active material layer and/or the solid electrolyte layer have a sulfide solid electrolyte. In addition, the positive electrode active material layer has an olivine-type positive electrode active material. In addition, the capacity of the negative electrode active material layer is lower than the capacity of the positive electrode active material layer. In addition, the control device controls the lower limit discharge potential of the positive electrode active material layer during normal use of the all-solid-state battery to within the range of 1.6 V vs. Li/Li+ to 2.1 V vs. Li/Li+.
    Type: Grant
    Filed: November 29, 2016
    Date of Patent: November 27, 2018
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Yohei Shindo, Manabu Imano, Mayuko Osaki, Taishi Shiotsuki
  • Patent number: 10084190
    Abstract: A lithium secondary battery, including: a hydrofluoric acid-containing electrolytic solution; an electrode; and a conductive assistant, in which the conductive assistant (1) contains a substance that is poorly soluble in the hydrofluoric acid-containing electrolytic solution, the substance including one or more kinds selected from transition metal compounds, and (2) contains a substance that is soluble in the hydrofluoric acid-containing electrolytic solution, the substance having a total metal mass of 0 mass % or more and 0.003 mass % or less with respect to a total mass of the electrode; and a conductive assistant, including: a substance that is poorly soluble in a hydrofluoric acid-containing electrolytic solution; and a substance that consumes hydrofluoric acid, the conductive assistant being substantially free, or including 1 mass % or less with respect to a total mass thereof, of a substance that is soluble in the hydrofluoric acid-containing electrolytic solution.
    Type: Grant
    Filed: January 14, 2015
    Date of Patent: September 25, 2018
    Assignee: SHOWA DENKO K.K.
    Inventors: Ryuji Yamamoto, Tsuyoshi Inose
  • Patent number: 10084205
    Abstract: The present invention relates to electrolyte of a high-voltage lithium-ion battery, comprising a non-aqueous organic solvent, lithium salt and an electrolyte additive; the electrolyte additive comprises the following ingredients based on the total weight of the electrolyte: 1%-10% of fluoroethylene carbonate, 1%-5% of dinitrile compound and 0.1%-2% of 2-methyl maleic anhydride; further, the electrolyte can be further added with additives such as 0.2%-2% of lithium bisoxalatoborate and 1,3-propane sultone. The present invention also relates to a high-voltage lithium-ion battery using the electrolyte, with the charging cut-off voltage being greater than 4.2V and smaller than or equal to 4.5V. The electrolyte of the high-voltage lithium-ion battery provided by the present invention can protect the positive electrode and also form good SEI at the negative electrode, and the high-voltage lithium-ion battery has good cycle performance and storage performance.
    Type: Grant
    Filed: October 22, 2014
    Date of Patent: September 25, 2018
    Assignee: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.
    Inventors: Qiao Shi, Muchong Lin, Dixiong Zhou
  • Patent number: 10062924
    Abstract: The lithium-ion secondary battery includes a positive electrode containing an active material made of a compound including lithium and a transition metal; an electrolyte containing 5 to 30 ppm of hydrofluoric acid; and a negative electrode containing 1 to 100 ppm of vanadium.
    Type: Grant
    Filed: March 18, 2013
    Date of Patent: August 28, 2018
    Assignee: TDK CORPORATION
    Inventors: Atsushi Sano, Keitaro Otsuki, Masahiro Oishi, Keiichi Fukuda
  • Patent number: 10014552
    Abstract: Embodiments of the disclosed lithium ion rechargeable battery include an anode, a cathode, and a separator including an electrolyte to prevent physical contact between the anode and the cathode, while also providing medium for transporting the lithium ions. In some embodiments, the anode may include a microporous scaffold structure that includes a silicon crystal covered in a thin polycrystalline silicon cover. Additionally, the various embodiments described herein further describe increasing the surface area of the microporous scaffold structure so as to provide a more efficient charge flow between the anode and the cathode. In some embodiment, the two or more microporous scaffold structures are stacked on top of one another so that there is an increase in contact area and reduced contact resistance, thus further increasing the charge capacity of the disclosed lithium ion rechargeable battery.
    Type: Grant
    Filed: May 2, 2016
    Date of Patent: July 3, 2018
    Assignee: Physical Optics Corporation
    Inventors: Paul Shnitser, Jonathan Ryan Daneman, Jeffrey Ryan Norell, David Miller
  • Patent number: 10008744
    Abstract: A lithium ion battery electrolyte, comprises lithium salt, a non-aqueous organic solvent and additives. The additives comprise an SEI film forming additive and furil and derivatives thereof, and the SEI film forming additive is at least one of vinylene carbonate, fluoroethylene carbonate and vinyl ethylene carbonate. Compared with the prior art, furil and derivatives thereof are added to the electrolyte as electrolyte additives in the present invention, to enhance the permeability for separator and the wettability for positive/negative electrode materials, facilitate the film forming reaction of the SEI film forming additive, and further improve the cycling performance of the lithium ion battery using the electrolyte. Furthermore, the furil and derivatives thereof have good chemical and electrochemical stability and free from decomposition reaction within the operating voltage range of the lithium ion battery, thereby imparting no negative effect upon battery performances.
    Type: Grant
    Filed: March 19, 2014
    Date of Patent: June 26, 2018
    Assignee: NingDe Contemporary Amperex Technology Limited
    Inventors: Shilin Huang, Kefei Wang, Chenghua Fu
  • Patent number: 9991553
    Abstract: An electrolyte for a lithium air battery and lithium air battery including the electrolyte are provided.
    Type: Grant
    Filed: May 27, 2015
    Date of Patent: June 5, 2018
    Assignee: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Dongjoon Lee, Dongmin Im, Kihyun Kim, Taeyoung Kim, Victor Roev, Sangbok Ma, Minsik Park, Wonsung Choi
  • Patent number: 9905885
    Abstract: The present invention provides a compound with a general formula (I) or a salt thereof, wherein, R1 and R2, are, independently of each other, F or CnF2n+1 with n=1-10, and R3 and R4 are, independently of each other, C1-C10-alkyl.
    Type: Grant
    Filed: April 25, 2013
    Date of Patent: February 27, 2018
    Assignees: JACOBS UNIVERSITY BREMEN GGMBH, WESTFAELISCHE WILHELMS-UNIVERSITAET MUENSTER
    Inventors: Nataliya Kalinovich, Gerd-Volker Roeschenthaler, Tanja Schedlbauer, Johannes Kasnatscheew, Katja Vlasov, René Schmitz, Raphael Wilhelm Schmitz, Romek Ansgar Mueller, Martin Winter, Stefano Passerini
  • Patent number: 9847553
    Abstract: Provided are an electrolyte for a lithium secondary battery, and a lithium secondary battery containing the same, wherein the electrolyte for a secondary battery has significantly excellent high-temperature stability, low-temperature discharge capacity, and life cycle characteristics.
    Type: Grant
    Filed: September 15, 2015
    Date of Patent: December 19, 2017
    Assignee: SK Innovation Co., Ltd.
    Inventors: Jin Sung Kim, Cheol Woo Kim, Seung Yon Oh, Kwang Kuk Lee, Seong Il Lee
  • Patent number: 9786918
    Abstract: A non-aqueous electrolyte secondary battery in which it is possible to increase a capacity retention rate is provided. A non-aqueous electrolyte secondary battery is provided which includes: a positive electrode layer that includes a positive electrode active material and a conductive material; a negative electrode layer; and a non-aqueous electrolytic solution that is arranged between the positive electrode layer and the negative electrode layer, where an upper limit voltage is equal to or more than 4.5 V with respect to the oxidation-reduction potential of lithium, and the surface of the conductive material is coated with a coating layer mainly formed of P, O, C and H.
    Type: Grant
    Filed: August 31, 2015
    Date of Patent: October 10, 2017
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Yohei Shindo
  • Patent number: 9768471
    Abstract: A rechargeable lithium battery includes a positive electrode including a positive active material, a negative electrode and an electrolyte including a lithium salt, an organic solvent and an additive. The positive active material includes a compound represented by Chemical Formula 1, and the additive includes about 0.5 to about 2 parts by weight of lithium difluorophosphate (LiPO2F2) and about 0.5 to about 3 parts by weight of vinylene carbonate, based on 100 parts by weight of the organic solvent. LiaNixCoyMnzO2??Chemical Formula 1.
    Type: Grant
    Filed: February 24, 2015
    Date of Patent: September 19, 2017
    Assignee: Samsung SDI Co., Ltd.
    Inventors: In-Hyun Lee, Su-Jin Yoon, Tae-Ahn Kim, Seung-Ju Oh
  • Patent number: 9755206
    Abstract: Provided is a nonaqueous electrolyte secondary battery 10 which, in cases where separators 70 each having a heat-resistant layer 74 on only one face thereof are used, has an excellent thermal stability and thus a higher safety and reliability when the battery 10 reaches a high temperature. Such a nonaqueous electrolyte secondary battery 10 includes a positive electrode 30 in which a positive electrode active material layer 34 is provided on both faces of a positive electrode current collector 32, a negative electrode 50 in which a negative electrode active material layer 54 is provided on both faces of a negative electrode current collector 52, at least two separators 70 each having a heat-resistant layer 74 on one face of a base material 72, and an electrolyte. The nonaqueous electrolyte secondary battery has an electrode assembly 20 in which the positive electrode 30 and the negative electrode 50 are stacked on top of one another with the separators 70 interposed therebetween.
    Type: Grant
    Filed: April 10, 2012
    Date of Patent: September 5, 2017
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Hiroki Nagai, Hiroyuki Akita, Takumi Tamaki, Katsushi Saito, Masato Kamiya, Shinji Suzuki
  • Patent number: 9742035
    Abstract: An exemplary electrochemical energy storage device includes: a positive electrode including a positive electrode active material; a negative electrode including a negative electrode active material; and a non-aqueous electrolytic solution. The non-aqueous electrolytic solution includes an electrolyte salt represented by Li(XSO2NSO2Y) (where X and Y are any of F, CnF2n+1 and (CF2)m, and (CF2)m forms a cyclic imide anion), an organic solvent which is capable of dissolving the electrolyte salt, and a polyethylene glycol of which both terminals are not OH. The positive electrode active material includes a chloride of Cu, Bi or Ag, and the negative electrode active material includes lithium.
    Type: Grant
    Filed: February 8, 2016
    Date of Patent: August 22, 2017
    Assignees: PANASONIC CORPORATION, KYOTO UNIVERSITY
    Inventors: Toru Matsui, Akiyoshi Nakata, Toshiro Hirai, Jun-ichi Yamaki, Zempachi Ogumi
  • Patent number: 9716292
    Abstract: An exemplary electrochemical energy storage device includes: a positive electrode including a positive electrode active material; a negative electrode including a negative electrode active material; and a non-aqueous electrolytic solution including LiCl, at least one of Li(XSO2NSO2Y) (where X and Y are any of F, CnF2n+1 and (CF2)m, and (CF2)m forms a cyclic imide anion) and LiBF4, and at least one of tetrahydrofuran and a polyethylene glycol of which both terminals are alkyl groups, the non-aqueous electrolytic solution being in contact with the positive electrode and the negative electrode, wherein the positive electrode active material includes a chloride of Cu, Bi or Ag, or the negative electrode active material includes magnesium chloride.
    Type: Grant
    Filed: February 8, 2016
    Date of Patent: July 25, 2017
    Assignees: PANASONIC CORPORATION, KYOTO UNIVERSITY
    Inventors: Toru Matsui, Toshiro Hirai, Jun-ichi Yamaki, Zempachi Ogumi
  • Patent number: 9603245
    Abstract: To provide an electrolytic copper foil for a negative electrode for a lithium-ion secondary battery with which it is possible to produce a long-life lithium-ion secondary battery in which there is no decline in the capacity retention ratio even when the charge-discharge cycling is repeated, that has long life, and no deformation of a negative electrode current collector occurs. The electrolytic copper foil constituting the negative electrode current collector for the lithium-ion secondary battery has, after heat treatment at from 200 to 400° C., a 0.2% proof stress of 250 N/mm2 or more, and elongation of 2.5% or more; and the surface on which an active material layer of the electrolytic copper foil is provided has been rust-proofed, or roughened and rust-proofed.
    Type: Grant
    Filed: December 27, 2011
    Date of Patent: March 21, 2017
    Assignee: FURUKAWA ELECTRIC CO., LTD.
    Inventors: Akitoshi Suzuki, Kensaku Shinozaki, Toshio Tani, Hirokazu Sasaki, Isamu Futaba, Kouji Hataya, Shinya Ohtomo, Hirokazu Yoshikawa
  • Patent number: 9559361
    Abstract: The presently disclosed and/or claimed inventive concept(s) relates generally to a composition of a slurry for use in preparation of a lithium ion battery. The slurry comprises a binder composition comprising a modified guaran for use in battery electrodes and methods of preparing such. The presently disclosed and/or claimed inventive concept(s) also relates to compositions and methods of making electrodes, either anodes and/or cathodes, with the binder composition comprising the modified guaran.
    Type: Grant
    Filed: February 20, 2015
    Date of Patent: January 31, 2017
    Assignee: HERCULES LLC
    Inventors: Sung Gun Chu, Feng Gao, Alan Edward Goliaszewski, Shufu Peng
  • Patent number: 9484598
    Abstract: Disclosed are an electrolyte for a lithium secondary battery which includes a non-aqueous solvent and a lithium salt, wherein the non-aqueous solvent includes a cyclic carbonate and a linear solvent, wherein an amount of the cyclic carbonate in the non-aqueous solvent is in the range of 1 wt % to 30 wt % based on a total weight of the non-aqueous solvent and a lithium secondary battery including the same.
    Type: Grant
    Filed: September 18, 2014
    Date of Patent: November 1, 2016
    Assignee: LG CHEM, LTD.
    Inventors: Jong Ho Jeon, Yoo Seok Kim, Doo Kyung Yang, Shulkee Kim
  • Patent number: 9463709
    Abstract: A vehicle includes a controller. When a brake operation amount has increased, the controller calculates an estimated input value at the time when a main battery is charged in response to an increase in the brake operation amount, on the basis of a current speed and an amount of increase in brake operation amount. The controller discharges the main battery for charging an auxiliary battery at a current value that is calculated on the basis of the estimated input value by controlling an operation of a DC-DC converter before charging the main battery in response to an increase in the brake operation amount. Thus, it is possible to cancel a bias of salt concentration that is developed during charging by a bias of salt concentration that is developed during discharging, so, after the main battery has been charged, it is possible to suppress development of a bias of the salt concentration and suppress an increase in the internal resistance value of the main battery.
    Type: Grant
    Filed: July 22, 2015
    Date of Patent: October 11, 2016
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Kazuhisa Takeda, Hiroki Tashiro, Hideaki Oka, Shuji Tomura
  • Patent number: 9368283
    Abstract: An electrochemical cell includes solid-state, printable anode layer, cathode layer and non-aqueous gel electrolyte layer coupled to the anode layer and cathode layer. The electrolyte layer provides physical separation between the anode layer and the cathode layer, and comprises a composition configured to provide ionic communication between the anode layer and cathode layer by facilitating transmission of multivalent ions between the anode layer and the cathode layer.
    Type: Grant
    Filed: August 16, 2013
    Date of Patent: June 14, 2016
    Assignees: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA, IMPRINT ENERGY, INC.
    Inventors: Paul K. Wright, James W. Evans, Christine Ho
  • Patent number: 9331360
    Abstract: A fluoride ion battery includes a substantially lithium-free anode and cathode. At least one of the anode or cathode contains fluorine, and a substantially lithium-free liquid electrolyte is used for charge transport. The electrolyte is liquid at temperatures below about 200 degrees Celsius, and can be formed from an organic-soluble fluoride salt dissolved in selected classes of solvents.
    Type: Grant
    Filed: December 9, 2010
    Date of Patent: May 3, 2016
    Assignee: CALIFORNIA INSTITUTE OF TECHNOLOGY
    Inventors: Cedric M. Weiss, Simon Christopher Jones, Arunkumar Tiruvannamalai, Isabelle Darolles, Maksudul M. Alam, Sohrab Hossain
  • Patent number: 9325035
    Abstract: The present invention provides non-aqueous electrolyte solution for a lithium secondary battery, comprising an ester-based compound having a branched-chain alkyl group and an ester-based compound having a straight-chain alkyl group; and a lithium secondary battery using the same.
    Type: Grant
    Filed: July 3, 2013
    Date of Patent: April 26, 2016
    Assignee: LG CHEM LTD.
    Inventors: Sung-Hoon Yu, Doo-Kyung Yang, Jong-Ho Jeon, Min-Jung Jou
  • Patent number: 9303011
    Abstract: A non-aqueous electrolyte solution containing a cyclic sulfone compound having a 1,3-dithietane-1,1,3,3-tetraoxide structure is provided. The cyclic sultone compound is preferably a compound represented by formula (I) [wherein in formula (I), R1 to R4 each represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, or the like].
    Type: Grant
    Filed: April 25, 2011
    Date of Patent: April 5, 2016
    Assignee: MITSUI CHEMICALS, INC.
    Inventors: Shigeru Mio, Mitsuo Nakamura, Hidenobu Nogi, Takashi Hayashi, Takeshi Kobayashi
  • Patent number: 9300007
    Abstract: An ultrasonic welding process for joining a current collector to an anode or cathode material of electrochemical cells is described. The ultrasonic welding process utilizes an ultrasonic welding frequency which may be combined with an applied force to bond dissimilar metals comprising the electrode material and the current collector. Preferably, the method is used to bond the anode material to the anode current collector. This method of attachment is suitable for either primary or secondary cells, particularly those powering implantable biomedical devices.
    Type: Grant
    Filed: January 9, 2012
    Date of Patent: March 29, 2016
    Assignee: Greatbatch Ltd.
    Inventors: Xiangyang Dai, Mark J. Roy
  • Patent number: 9287585
    Abstract: An electrolyte for a rechargeable lithium battery includes a non-aqueous organic solvent; a lithium salt; and an additive including vinylene carbonate, fluoroethylene carbonate, and a nitrile-based compound represented by Formula 1: wherein n ranges from 1 to 12 and R1 and R2 are independently a halogen, a hydrogen, or an alkyl group. Further, the alkyl group can be CmH(2m+1), in which m ranges from 1 to 10. The electrolyte for a rechargeable lithium battery improves storage stability of the rechargeable lithium battery at a high temperature. And, a rechargeable lithium battery including the electrolyte has improved storage stability.
    Type: Grant
    Filed: December 4, 2014
    Date of Patent: March 15, 2016
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Euy-Young Jung, Duck-Chul Hwang, Jong-Hwa Lee, In-Tae Mun, Sae-Weon Roh, So-Hyun Hur, Yong-Chul Park, Jeom-Soo Kim, Jae-Yul Ryu
  • Patent number: 9263764
    Abstract: An electrolyte for a lithium ion battery includes a non-aqueous organic solvent and a lithium salt. The non-aqueous organic solvent includes a flame-retardant solvent and a carbonate-based solvent. The flame-retardant solvent includes an ionic liquid including a fluorinated cation and a phosphorus-based solvent.
    Type: Grant
    Filed: September 6, 2011
    Date of Patent: February 16, 2016
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Sae-Weon Roh, Man-Seok Han, Sung-Soo Kim
  • Patent number: 9252457
    Abstract: A non-aqueous liquid electrolyte suitable for use in a non-aqueous liquid electrolyte secondary battery comprising a negative electrode and a positive electrode, capable of intercalating and deintercalating lithium ions, and the non-aqueous liquid electrolyte, the negative electrode containing a negative-electrode active material having at least one kind of atom selected from the group consisting of Si atom, Sn atom and Pb atom, wherein the non-aqueous liquid electrolyte comprises a carbonate having at least either an unsaturated bond or a halogen atom.
    Type: Grant
    Filed: November 23, 2011
    Date of Patent: February 2, 2016
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Takashi Fujii, Noriko Shima, Youichi Ohashi, Shinichi Kinoshita
  • Patent number: 9203114
    Abstract: Provided are an electrolyte for a magnesium secondary battery having improved ion conductivity and stability, and a method for preparing the same. The electrolyte for a magnesium secondary battery shows higher ion conductivity as compared to the electrolyte according to the related art, increases the dissociation degree of a magnesium halide electrolyte salt, and provides stable electrochemical characteristics. In addition, after determining the capacity, output characteristics and cycle life of the magnesium secondary battery including the electrolyte, the battery provides significantly higher discharge capacity after 100 cycles, as compared to the electrolyte according to the related art. Therefore, the electrolyte may be useful for an electrolyte solution of a magnesium secondary battery.
    Type: Grant
    Filed: April 25, 2013
    Date of Patent: December 1, 2015
    Assignee: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Kyung Yoon Chung, Byung Won Cho, Joong Kee Lee, Jae Hyun Cho, Sang Hoon Lee, Won Young Chang
  • Patent number: 9112243
    Abstract: For a metal anode in a battery, the capacity fade is a significant consideration. In energy storage devices having an anode that includes Mg, the cycling stability can be improved by an electrolyte having a first salt, a second salt, and an organic solvent. Examples of the organic solvent include diglyme, triglyme, tetraglyme, or a combination thereof. The first salt can have a magnesium cation and be substantially soluble in the organic solvent. The second salt can enhance the solubility of the first salt and can have a magnesium cation or a lithium cation. The first salt, the second salt, or both have a BH4 anion.
    Type: Grant
    Filed: April 8, 2013
    Date of Patent: August 18, 2015
    Assignee: Battelle Memorial Institute
    Inventors: Yuyan Shao, Jun Liu
  • Patent number: 9048491
    Abstract: In the invention, a lithium-ion secondary battery, in which a value obtained by dividing average 3% modulus strength of a separator by average 3% modulus strength of a negative electrode including a negative electrode active material layer containing silicon and silicon oxide as a main component is 0.079 or less, is used.
    Type: Grant
    Filed: March 18, 2013
    Date of Patent: June 2, 2015
    Assignee: TDK CORPORATION
    Inventors: Yasuyuki Kawanaka, Kazumasa Tanaka, Yasuhiro Ikeda, Atsushi Sano
  • Publication number: 20150147632
    Abstract: An electrolyte composition including a lithium salt (A), an first anion (B1) represented by formula (1), and an organic solvent (C) are provided. When the electrolyte composition is applied in a lithium battery, good structural stability, high battery efficiency, and long charge-discharge cycle life of the lithium battery can be achieved.
    Type: Application
    Filed: May 25, 2014
    Publication date: May 28, 2015
    Applicant: National Taiwan University of Science and Technology
    Inventors: Fu-Ming Wang, Sylvia Ayu Pradanawati
  • Publication number: 20150147662
    Abstract: An electrolyte for a lithium battery, the electrolyte including a compound represented by Formula 1; a nonaqueous organic solvent; and a lithium salt. wherein, in Formula 1, X, Ya, Z, R1, and R2 are as defined.
    Type: Application
    Filed: November 10, 2014
    Publication date: May 28, 2015
    Inventors: Insun Park, Yoonsok Kang, Minsik Park, Jinhwan Park
  • Publication number: 20150147644
    Abstract: A non-aqueous electrolyte secondary battery of the present disclosure includes: a positive electrode containing a first and a second positive electrode active material; and a non-aqueous electrolyte containing a fluorinated chain carboxylic acid ester represented by the following structural formula 1. The first positive electrode active material includes a lithium-containing transition metal oxide represented by a Li2MnO3—LiMO2 solid solution, and the second positive electrode active material includes a lithium-containing transition metal oxide which contains at least Ni, has a Ni rate of 50 percent by mole or more to the total moles of metal elements other than Li, and has a layered structure. (R represents an alkyl group having 1 to 4 carbon atoms, and X's each independently represent F, H, an alkyl group having 1 to 4 carbon atoms, or a group obtained by substituting at least one H of the above alkyl group by F.
    Type: Application
    Filed: November 2, 2014
    Publication date: May 28, 2015
    Inventors: MASAHIRO KINOSHITA, HIROSHI KAWADA
  • Publication number: 20150147645
    Abstract: Disclosed is a secondary battery including an electrolyte and/or an electrode, the electrolyte including an electrolyte salt and an electrolyte solvent, i) a cyclic carbonate compound substituted with at least one halogen element; and ii) a compound containing a vinyl group in a molecule thereof, and the electrode including a solid electrolyte interface (SEI) layer partially or totally formed on the surface thereof by electrical reduction of the two compounds.
    Type: Application
    Filed: January 28, 2015
    Publication date: May 28, 2015
    Applicant: LG Chem, Ltd.
    Inventors: Hochun Lee, Jeong-Ju Cho, Sujin Yoon
  • Publication number: 20150140441
    Abstract: A composition suitable as a solid polymer electrolyte for a lithium ion battery comprises a mixture of polyoctahedral silsesquioxane-phenyl7(BF3Li)3 and a poly(ethylene oxide).
    Type: Application
    Filed: March 14, 2013
    Publication date: May 21, 2015
    Inventors: Stephanie L. Wunder, Parameswara Rao Chinnam
  • Publication number: 20150140450
    Abstract: An electrolyte solution including a non-aqueous organic solvent and a magnesium salt represented by Formula 1: wherein in Formula 1, groups CY1, CY2, A1 to A10, and variable n are defined in the specification.
    Type: Application
    Filed: April 17, 2014
    Publication date: May 21, 2015
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Basab ROY, Dong-young KIM, Youn-hee LIM, Seok-soo LEE
  • Publication number: 20150140422
    Abstract: Embodiments of an electrolyte for a hybrid magnesium-alkali metal ion battery are disclosed. The electrolyte includes a magnesium salt, a Lewis acid, and an alkali metal salt. Embodiments of battery systems including the electrolyte also are disclosed.
    Type: Application
    Filed: December 19, 2014
    Publication date: May 21, 2015
    Inventors: Tianbiao Liu, Jun Liu, Xilin Chen, Yuyan Shao, Guosheng Li, Jiguang Zhang
  • Publication number: 20150132639
    Abstract: A non-aqueous liquid electrolyte for a secondary battery, containing an electrolyte and a compound (A) represented by any one of formulae (I-1) to (I-3) in an organic solvent: wherein X1 represents an alkyl group substituted with a halogen atom; Y1 represents a hydrogen atom or an organic group; and ma represents an integer from 1 to 6; wherein X2 represents a group having an oxygen atom; Y2 represents a hydrogen atom or an organic group; and mb represents an integer from 1 to 6; and wherein Y3 represents an organic group having 4 or more carbon atoms, or an organic group having an oxygen atom or a nitrogen atom; and mc represents an integer from 1 to 6.
    Type: Application
    Filed: January 21, 2015
    Publication date: May 14, 2015
    Applicant: FUJIFILM CORPORATION
    Inventor: Kunihiko KODAMA
  • Patent number: 9029021
    Abstract: A method of charging and discharging a battery that includes an anode. The anode includes silicon and is capable of inserting and extracting lithium. At the time of charge, the potential of the anode vs. lithium metal as a reference potential is 0.04 V or more. At the time of discharge, the potential of the anode vs. lithium metal as a reference potential is 1.4 V or less.
    Type: Grant
    Filed: April 16, 2010
    Date of Patent: May 12, 2015
    Assignee: Sony Corporation
    Inventor: Tadahiko Kubota
  • Publication number: 20150125760
    Abstract: There is provided an improvement for capacitors having activated carbon electrodes by the use of an electrolyte solution containing a carbonate of the formula RO(C?O)OR1 and a conductive salt such as a lithium salt or a quaternary ammonium salt at a concentration of from 0.6 to 3 mol/l.
    Type: Application
    Filed: November 6, 2013
    Publication date: May 7, 2015
    Inventors: W. Novis Smith, Joel R. McCloskey
  • Publication number: 20150125735
    Abstract: A rechargeable lithium battery includes: a negative electrode including a negative active material; a positive electrode; a separator interposed between the negative electrode and the positive electrode; and an electrolyte solution including an additive, wherein the negative active material includes a Si-based material, the Si-based material is included in an amount from about 1 to about 70 wt % based on total amount of the negative active material, and the additive includes fluoroethylene carbonate and a compound represented by the following Chemical Formula 1. In the above Chemical Formula 1, R1 to R3 are each independently a substituted or unsubstituted C2 to C5 alkyl group.
    Type: Application
    Filed: September 23, 2014
    Publication date: May 7, 2015
    Inventors: Tae-Hyun Bae, Woo-Cheol Shin, Sang-Hyun Eom, Myung-Hoon Kim, Seung-Tae Lee, Ae-Ran Kim, Dong-Myung Choi
  • Publication number: 20150118580
    Abstract: What is disclosed is a non-aqueous electrolyte for non-aqueous electrolyte battery including a non-aqueous solvent and at least lithium hexafluorophosphate as a solute. This electrolyte is characterized by containing at least one siloxane compound represented by the general formula (1) or the general formula (2). This electrolyte has a storage stability which is improved than electrolytes prepared by adding conventional siloxane compounds.
    Type: Application
    Filed: June 10, 2013
    Publication date: April 30, 2015
    Inventors: Yuki Kondo, Makoto Kubo, Takayoshi Morinaka, Kenta Yamamoto
  • Publication number: 20150118581
    Abstract: A rechargeable lithium ion battery including a negative active material, the negative active material including a carbon-based active material, and an electrolyte solution that includes a S?O-containing compound, the S?O-containing compound having a structure that is selected according to a G band/D band ratio of the carbon-based active material.
    Type: Application
    Filed: October 28, 2014
    Publication date: April 30, 2015
    Inventors: Hironari TAKASE, Hokuto YOKOTSUJI
  • Patent number: 9017881
    Abstract: Provided are an electrolyte comprising an amide compound of a specific structure, in which an alkoxy group is substituted with an amine group, and an ionizable lithium salt, and an electrochemical device containing the same. The electrolyte may have excellent thermal and chemical stability and a wide electrochemical window. Also, the electrolyte may have a sufficiently low viscosity and a high ionic conductivity, and thus, may be usefully applied as an electrolyte of electrochemical devices using various anode materials.
    Type: Grant
    Filed: September 2, 2011
    Date of Patent: April 28, 2015
    Assignee: LG Chem, Ltd.
    Inventors: Byoung-Bae Lee, Jae-Seung Oh, Ji-Won Park, Hyo-Jin Lee, Dong-Su Kim, Yeon-Suk Hong
  • Patent number: 9017866
    Abstract: A non-aqueous electrolyte battery using a lithium-containing metal oxide containing manganese as a positive electrode active material, which can suppress the elution of manganese from the positive electrode active material. The non-aqueous electrolyte secondary battery has a negative electrode capable of intercalating and deintercalating lithium ions, a positive electrode containing a lithium-containing compound as a positive electrode active material, and a non-aqueous electrolyte in which a lithium salt is dissolved in an organic solvent. The lithium-containing compound is a lithium-containing metal oxide containing manganese, and the non-aqueous electrolyte contains a fluorosilane compound: R1 to R3 each represents a 1-8 carbon alkyl group, a 2-8 carbon alkenyl group, a 5-8 carbon cycloalkyl group, a 6-8 carbon aryl group or a fluorine atom, and R4 represents a 1-8 carbon alkylene group or a 4-8 carbon alkylene group having an ether group.
    Type: Grant
    Filed: October 13, 2011
    Date of Patent: April 28, 2015
    Assignee: Adeka Corporation
    Inventors: Takayuki Taki, Yuyu Ohnuma, Atsuki Shibuya, Hiroaki Watanabe
  • Publication number: 20150111098
    Abstract: The present invention provides a method of safely producing a solution containing a tetrafluoro(oxalate)phosphate in which the amounts of chlorine compounds and free acids are low such that crystallization refinement is not required in a post-process. The method produces a tetrafluoro(oxalate)phosphate solution by mixing a tetrafluoro(oxalate)phosphate with oxalic acid in a non-aqueous solvent and then adding silicon tetrachloride to the resulting mixture solution for reaction. In the reaction, the addition ratio of the hexafluorophosphate, oxalic acid, and silicon tetrachloride is controlled such that the amount of the hexafluorophosphate is 1.90 moles or more and the amount of the oxalic acid is 1.90 to 2.10 moles, based on 1 mole of the silicon tetrachloride.
    Type: Application
    Filed: May 29, 2013
    Publication date: April 23, 2015
    Inventors: Makoto Kubo, Takayoshi Morinaka, Keita Nakahara, Satoshi Muramoto
  • Patent number: 9012095
    Abstract: An electrolyte includes a solvent and an electrolyte salt. The solvent contains at least one selected from ester compounds, lithium monofluorophosphate, and lithium difluorophosphate, and at least one selected from anhydrous compounds. The ester compounds are chain compounds having ester moieties, such as (—O—C(?O)—O—R), at both ends. The anhydrous compounds are cyclic compounds having, for example, a disulfonic anhydride group, (—S(O?)2—O—S(O?)2—).
    Type: Grant
    Filed: January 8, 2010
    Date of Patent: April 21, 2015
    Assignee: Sony Corporation
    Inventors: Masayuki Ihara, Shinya Wakita, Tadahiko Kubota
  • Patent number: 9012086
    Abstract: A magnesium ion battery includes a first electrode including a substrate and an active material deposited on the substrate. Also provided is a second electrode. An electrolyte is located between the first electrode and the second electrode. The electrolyte includes a magnesium compound. The active material includes indium and an intermetallic compound of magnesium and indium.
    Type: Grant
    Filed: March 5, 2013
    Date of Patent: April 21, 2015
    Assignee: Toyota Motor Engineering & Manufacturing North America, Inc.
    Inventors: Nikhilendra Singh, Masaki Matsui