Abstract: A single or multi-component polymer coating is applied to components used in fabrication of electrochemical cells to protect the cells from damages that can result in cell imbalance or cell performance reduction. The polymer coating is electrically conductive under normal operating conditions but, when operated at low voltages, functions as an insulative material that increases the electrical resistance of the cell components. This increased electrical resistance improves cell safety by minimizing short-circuit current flow and reducing heating rate in the cell components.

Abstract: In an aspect, an electrode active material for a lithium secondary battery, the electrode active material including a silicon-based alloy and a coating film containing a polymer that includes a 3,4-ethylenedioxythiophene repeating unit and an oxyalkylene repeating unit, coated on the surface of the silicon-based alloy are provided.

Abstract: A method of forming a carbon coating includes heat treating lithium transition metal composite oxide Li0.9+aMbM?cNdOe, in an atmosphere of a gas mixture including carbon dioxide and compound CnH(2n+2?a)[OH]a, wherein n is 1 to 20 and a is 0 or 1, or compound CnH(2n), wherein n is 2 to 6, wherein 0?a?1.6, 0?b?2, 0?c?2, 0?d?2, b, c, and d are not simultaneously equal to 0, e ranges from 1 to 4, M and M? are different from each other and are selected from Ni, Co, Mn, Mo, Cu, Fe, Cr, Ge, Al, Mg, Zr, W, Ru, Rh, Pd, Os, Ir, Pt, Sc, Ti, V, Ga, Nb, Ag, Hf, Au, Cs, B, and Ba, and N is different from M and M? and is selected from Ni, Co, Mn, Mo, Cu, Fe, Cr, Ge, Al, Mg, Zr, W, Ru, Rh, Pd, Os, Ir, Pt, Sc, Ti, V, Ga, Nb, Ag, Hf, Au, Cs, B, Ba, and a combination thereof, or selected from Ti, V, Si, B, F, S, and P, and at least one of the M, M?, and N comprises Ni, Co, Mn, Mo, Cu, or Fe.

Abstract: In one embodiment, the present disclosure provides a sulfur-hydroxylated graphene nanocomposite including at least one graphene sheet with a surface and a plurality of amorphous sulfur nanoparticles homogeneously distributed on the surface. The nanocomposite substantially lacks sulfur microparticles. In other embodiments, the disclosure provides a cathode and a battery containing the nanocomposite. In still another embodiment, the disclosure provides a method of making a sulfur-hydroxylated graphene nanocomposite by exposing a hydroxylated graphene to a sulfur-containing solution for a time sufficient to allow formation of homogeneously distributed sulfur nanoparticles on a surface of the hydroxylated graphene.

Abstract: A battery capable of ensuring storage characteristics and overcharge characteristics is provided. The battery comprising a cathode, an anode, and an electrolytic solution. The cathode has a cathode current collector and a cathode active material layer provided on the cathode current collector. The cathode active material layer includes an aromatic compound having three or more benzene rings. The electrolytic solution includes at least one of an ester carbonate containing a halogen and an ester carbonate containing an unsaturated bond.

Abstract: Disclosed is a composition for electrode comprising (i) a positive electrode active material comprising an iron compound and carbon, and (ii) a copolymer (P) prepared by copolymerization of acrylic acid esters and/or methacrylic acid esters, with an ?,?-unsaturated nitrile compound. Also disclosed is an electrode comprised of an active material layer made of the composition for electrode, and a collector. This electrode can be produced by mixing the positive electrode active material, the copolymer (P), a solvent and an optional thickener, by a mixer to prepare an electrode composition slurry with solid content of 40-90% by weight, coating a collector with the electrode composition slurry, and then, removing the solvent from the thus-formed coating. Further disclosed a battery provided with the electrode.

Abstract: A silicon-based electrode includes a silicon layer on a substrate, an electrically conductive layer overlying a top surface of the silicon layer, an optional polymer layer overlying the top surface of the electrically conducting layer, and a plurality of channels extending through the electrically conductive layer and the silicon layer to the substrate. The channels define sidewalls in the silicon layer. The electrically conductive layer and the optional polymer layer act to inhibit lithium ion intercalation through the top surface of the silicon layer during charging of a lithium-ion cell, and the lithium ion intercalation into the silicon layer occurs through the sidewalls that are defined by the channels.

Abstract: A positive electrode for a rechargeable lithium battery including a current collector and a positive active material layer disposed on the current collector, a method of manufacturing the positive electrode, and a rechargeable lithium battery including the positive electrode. Here, the positive active material layer includes a positive active material and a coating layer on the surface of the positive active material, wherein the coating layer is formed of a coating layer composition including carbon nano particles, polyvinylpyrrolidone, and polyvinylidene fluoride.

Abstract: A thin film structure, method of producing it and the use thereof. The thin film structure comprises a substrate with a thin conductive layer containing an oxidizing enzyme mixed with an electron transfer mediator. The thin layer is protected against wetting to allow for its storage in dry conditions and further being sufficiently porous to allow for immediate activation of the oxidizing enzyme when contacted with an aqueous solution. The thin film can be used as a cathode in electrochemical fuel cells.

Abstract: Particles of cathodic materials are coated with polymer to prevent direct contact between the particles and the surrounding electrolyte. The polymers are held in place either by a) growing the polymers from initiators covalently bound to the particle, b) attachment of the already-formed polymers by covalently linking to functional groups attached to the particle, or c) electrostatic interactions resulting from incorporation of cationic or anionic groups in the polymer chain. Carbon or ceramic coatings may first be formed on the surfaces of the particles before the particles are coated with polymer. The polymer coating is both electronically and ionically conductive.

Abstract: Electrode structures and electrochemical cells are provided. The electrode structures and/or electrochemical cells described herein may include one or more protective layers comprising a polymer layer and/or a gel polymer electrolyte layer. The polymer layer may be formed from the copolymerization of an olefinic monomer comprising at least one electron withdrawing group and an olefinic comonomer comprising at least one electron donating group. Methods for forming polymer layers are also provided.

Abstract: A nonaqueous electrolyte battery includes: a positive electrode having a positive electrode active material layer that includes a positive electrode active material, a binder, and a compound having a pyrrolidone skeleton; a negative electrode having a negative electrode active material layer; a nonaqueous electrolyte that includes a solvent and an electrolyte salt; and a polyacid and/or a polyacid compound contained inside the battery.

Abstract: Disclosed is an electrode active material having a core-shell structure, which includes: (a) a core capable of intercalating and deintercalating lithium ions; and (b) a shell including a polymer or an oligomer having a glass transition temperature of 25° C. or less when impregnated with an electrolyte, wherein a surface of the core is coated with the shell. Also, an electrode manufactured by using the electrode active material and a secondary battery including the electrode are disclosed. The shell (b) suppresses the formation of an SEI layer during initial charge of a battery, and prevents initial capacity reduction.

Abstract: Disclosed herein are negative active material compositions, comprising: a carbonaceous material having a surface area of at least 250 m2/g; and an organic molecule expander, wherein the ratio of carbonaceous material to expander ranges from 5:1 to 1:1, and wherein the composition has a median pore size ranging from 0.8 ?m to 4 ?m. Also disclosed are electrodes and batteries comprising such compositions, and methods of making thereof.

Abstract: An expander formulation used in battery paste compositions. The expander formulation incorporates effective amounts, or elevated concentrations of up to 6% of graphite and mixtures of carbon black and graphite to lessen or minimize the accumulation of lead sulfate on the surface of the negative plate during high rate PSOC battery operation, and/or to increase the electrochemical efficiency, the reserve capacity, the cold cranking performance and the cycle life of lead-acid batteries.

Abstract: A cathode material with double carbon coatings is provided. The cathode material includes a lithium metal phosphate matrix, a first carbon coating, and a second carbon coating. The first carbon coating is coated on the lithium metal phosphate matrix. The second carbon coating is coated on the first carbon coating. The carbon source of the first carbon coating is a carbohydrate or a water-soluble macromolecule compound having relatively smaller molecular weight. The carbon source of the second carbon coating is a macromolecule compound having relatively higher molecular weight.

Abstract: An electrode composition that includes the combination of a finely ground silicon mixture, a partially carbonized polymeric material, and a buffering agent is disclosed. The silicon mixture can be formed by mechanical milling of crystalline silicon to create amorphous silicon particles, while the polymeric material can be formed from polymers such as polystyrene, polyethylene, polypropylene, polyacrylonitrile, polyvinyl chloride, polyethylene oxide that are heated under inert gasses to slightly decompose the polymers.

Abstract: An electrode slurry which includes an active component, a conductive agent, a binder, an organic solvent, and octylphenolpoly(ethyleneglycolether)x, wherein x=9˜10. The active component, conductive agent, binder, organic solvent, and octylphenolpoly(ethyleneglycolether)x are mixed together. An electrode of lithium battery includes a current collector, and a layer of electrode material applied on a surface of the current collector, wherein a material of the layer of electrode material comprises an active component, a conductive agent, a binder, and octylphenolpoly(ethyleneglycolether)x, wherein x=9˜10.

Abstract: A battery electrode or separator surface protective agent composition having fluidity and being capable of being solidified by hot melt, and comprising at least two types of organic particles comprising organic materials, wherein the organic particles of types different from each other are substantially incompatible with each other, wherein when the composition is solidified by hot melt, the organic particles of the same type thermally fuse with one another to form a continuous phase.

Abstract: A silicon electrode is described, formed by combining silicon powder, a conductive binder, and SLMP™ powder from FMC Corporation to make a hybrid electrode system, useful in lithium-ion batteries. In one embodiment the binder is a conductive polymer such as described in PCT Published Application WO 2010/135248 A1.

Abstract: A method for forming a battery from via thin-film deposition processes is disclosed. A mesoporous carbon material is deposited onto a surface of a conductive substrate that has high surface area, conductive micro-structures formed thereon. A porous, dielectric separator layer is then deposited on the layer of mesoporous carbon material to form a half cell of an energy storage device. The mesoporous carbon material is made up of CVD-deposited carbon fullerene “onions” and carbon nano-tubes, and has a high porosity capable of retaining lithium ions in concentrations useful for storing significant quantities of electrical energy. Embodiments of the invention further provide for the formation of an electrode having a high surface area conductive region that is useful in a battery structure.

Abstract: The present invention provides a nonaqueous electrolyte secondary battery that includes inside a battery cell; a positive electrode; a negative electrode prepared by using a negative electrode paste containing a silicon-based negative electrode active material; and a nonaqueous electrolyte solution, wherein an ionic compound represented by the following general formula (1) is contained inside the battery cell, wherein Xm+ represents an organic cation having N+, P+ or S+, an alkali metal cation, or an alkaline earth metal cation, m represents a valence of the X, and n represents a natural number satisfying n=m. As a result, there is provided a nonaqueous electrolyte secondary battery of which recovery characteristic between before and after high temperature standing is improved.

Abstract: A subject is to provide a nonaqueous secondary battery which is sufficiently low in charge/discharge irreversible capacity in initial cycling even when an active-material layer comprising a negative-electrode material and formed on a current collector is densified for capacity increase where the subject is accomplished with composite graphite particles for a nonaqueous secondary battery which comprise a composite of spherical graphite particles and a binder graphite and which satisfy at least one of (a) to (g) conditions as presently claimed and a negative electrode produced using the carbonaceous negative-electrode material according to the invention is excellent in electrolytic-solution infiltration and provides a nonaqueous secondary battery having excellent charge/discharge high-load characteristics.

Abstract: An electrochemical energy cell has a galvanic cell including an anode electrode unit, a cathode electrode unit, an electrolyte body between the anode and cathode electrode units and contacting both the anode and cathode electrode units, and a separator layer including the electrolyte body and placed within the cell to contact both the anode and cathode electrode units to bring the anode and cathode electrode units in contact with the electrolyte body. The cathode electrode unit includes a cathode material including a powder mixture of a powder of hydrated ruthenium oxide and one or more additives. The anode electrode unit includes a structure formed of an oxidizable metal, and the separator layer includes a material that is porous to ions in liquid and is electrically non-conductive. A flexible electrochemical cell can be configured for a reduction-oxidation reaction to generate power at a surface of the electrode unit(s).

Abstract: A lithium secondary battery includes a positive electrode including a positive electrode active material, a negative electrode including a negative electrode active material, and a non-aqueous electrolyte. The positive electrode active material comprises at least one lithium-containing composite oxide represented by the following general formula: LixM11?yM2yO2 where M1 and M2 are different elements, M1 is Ni or Co, M2 is at least one selected from Ni, Co, Mn, Mg, and Al, 1?x?1.05, and 0?y?0.7. The negative electrode active material comprises at least one selected from the group consisting of silicon, tin, a silicon-containing alloy, and a tin-containing alloy. The non-aqueous electrolyte includes an organic peroxide.

Abstract: Composite current collectors containing coatings of metals, alloys or compounds, selected from the group of Zn, Cd, Hg, Ga, In, Tl, Sn, Pb, As, Sb, Bi and Se on non-metallic, non-conductive or poorly-conductive substrates are disclosed. The composite current collectors can be used in electrochemical cells particularly sealed cells requiring a long storage life. Selected metals, metal alloys or metal compounds are applied to polymer or ceramic substrates by vacuum deposition techniques, extrusion, conductive paints (dispersed as particles in a suitable paint), electroless deposition, cementation; or after suitable metallization by galvanic means (electrodeposition or electrophoresis). Metal compound coatings are reduced to their respective metals by chemical or galvanic means. The current collectors described are particular suitable for use in sealed primary or rechargeable galvanic cells containing mercury-fee and lead-free alkaline zinc electrodes.

Abstract: Provided is a lithium secondary battery comprising a lithium transition metal compound-containing cathode and a graphitized carbon-containing anode with addition of a surfactant to the cathode and/or the anode, whereby the addition of the surfactant improves the wettability of an electrolyte on the electrode, thereby increasing the battery capacity and improving rate properties and cycle properties of the battery, in conjunction with a significant reduction of a manufacturing process time of the battery.

Abstract: A non-aqueous electrolyte secondary battery having a high negative electrode energy density, good safety and high discharge characteristics is provided without damaging manufacturing facilities. The non-aqueous electrolyte secondary battery includes a positive electrode, a negative electrode, a porous heat-resistant layer interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte. The negative electrode comprises a negative electrode current collector and a negative electrode mixture layer on a surface of the negative electrode current collector, and the negative electrode mixture layer has an active material density of 1.5 g/ml to 1.8 g/ml. The porous heat-resistant layer is carried on the negative electrode, and the porous heat-resistant layer comprises magnesium oxide particles having a mean particle size of 0.5 ?m to 2 ?m.

Abstract: A button cell includes a positive electrode, a negative electrode and a separator arranged in a housing comprising a cell cup and a cell lid insulated from one another by a seal, wherein the negative electrode is tablet-shaped pressed body having a self-supporting structure.

Abstract: The present invention is directed to an electrode for a nonaqueous electrolyte secondary battery and a nonaqueous electrolyte secondary battery using the same. The nonaqueous electrolyte secondary battery electrode includes an electrode material mixture and a current collector. The electrode material mixture includes an active material and a polymer. The thickness change rate of the electrode material mixture is ?3 to 10% when immersing in an electrolyte at 60° C. for 72 hours.

Abstract: A lithium ion battery includes: a positive electrode capable of occluding and emitting lithium ions; a negative electrode that is capable of occluding and emitting lithium ions; a separator disposed between the positive electrode and the negative electrode; and an electrolytic solution. The negative electrode of the lithium ion battery is coated with a lithium ion conductive polymer. The lithium ion battery maintains high-temperature storage characteristics at temperatures of 50° C. or more and output characteristics at room temperature of the lithium ion battery are improved.

Abstract: The invention relates to performance improvements in lead-acid batteries by admixing so-called expanders or spreading materials to the active negative materials. Succinates are proposed as a new synthetic and consequently chemically clearly defined spreading means that can be used in place of lignin sulphonates, particularly iminodisuccinates or succinyl groups or oligomers containing iminosuccinyl groups or polymer compounds, individually or in any mixtures.

Abstract: The present invention relates to a rechargeable lithium ion battery having an electrode plate with a high active material density and high electrolyte permeability. Upon producing the rechargeable lithium ion battery, hollow resin particles that can be collapsed by rolling are incorporated in a positive electrode mixture layer or a negative electrode mixture layer before the electrode mixture layer is rolled. The hollow resin particles are collapsed in the course of rolling the positive electrode mixture layer or the negative electrode mixture layer, so that the active material density can be easily increased. Further, the collapsed resin particles form unevenness on the surface of the electrode plate and also form open pores in the electrode plate, so that electrolyte permeability can be enhanced. As a result, the discharge capacity and rate characteristics of rechargeable lithium ion batteries can be increased.

Abstract: The object is to obtain a positive electrode for a nonaqueous electrolyte secondary battery capable of suppressing gas generation even if continuous charging is performed at a high temperature. Provided is a positive electrode for a nonaqueous electrolyte secondary battery comprising a positive-electrode active material, wherein the positive-electrode active material has a surface-treated layer with a silane coupling agent represented by the following general formula (1): X1-Y—X2 ??(1) wherein Y is an alkylene group having 10 or less carbon atoms, and X1 and X2 are each represented by the general formula (2): wherein Z is an alkyl group having 10 or less carbon atoms or OR3, and R1, R2 and R3, are each an alkyl group having 5 or less carbon atoms.

Abstract: An electrode for a lithium secondary battery includes an electrode active material, a conductive agent, and a polyurethane-based compound, and has pores having an average diameter of about 2 to about 20 nm. A lithium secondary battery includes the electrode.

Abstract: The present invention relates to a process for producing a cathode, which comprises mixing: (A) sulfur, (B) carbon in an electrically conductive polymorph and (C) at least one saccharide selected from monosaccharides, disaccharides, oligosaccharides and polysaccharides, which is soluble or swellable in an acidic aqueous medium, and applying the resulting mixture to a flat carrier (D) and then optionally drying it.

Abstract: A non-aqueous secondary battery of the present invention includes a positive electrode, a negative electrode and a non-aqueous electrolyte. The positive electrode includes a positive electrode material mixture layer containing a lithium-containing transition metal oxide. The negative electrode includes a negative electrode material mixture layer and a porous layer containing an insulating material unreactive with lithium formed thereon. The negative electrode material mixture layer includes a negative electrode material including a core and a carbon covering layer covering a surface of the core. The core includes a material containing silicon and oxygen at an atomic ratio x of the oxygen to the silicon of 0.5?×?1.5. The material containing silicon and oxygen has a peak at least in a range of 1850 to 1860 eV in an X-ray absorption near edge structure spectrum at the K absorption edge of Si in a state in which discharge of the battery is finished.

Abstract: An anode is provided as one capable of suppressing rapid entrance/exit of lithium ions during quick charge-discharge and ensuring sufficient safety in use as an anode of a lithium-ion secondary battery. The anode is an anode for lithium-ion secondary battery having a current collector, and an active material-containing layer formed on the current collector, wherein the active material-containing layer is comprised of an outermost layer disposed on the farthest side from the current collector, and a lower layer composed of at least one layer disposed between the outermost layer and the current collector, and wherein a degree of flexion of the outermost layer is larger than a degree of flexion of the lower layer.

Abstract: Disclosed are a negative active material of a rechargeable lithium battery and a rechargeable lithium battery including a negative electrode, and the negative electrode includes a negative active material layer including a negative active material represented by the following Chemical Formula 1. X—Ra—Rb In Chemical Formula 1, X is an active material which comprises a metal and has a functional group which has been reacted with a silane coupling agent, Ra is a residual group from a silane coupling agent, and Rb is a polymer.

Abstract: Composite current collectors containing coatings of metals, alloys or compounds, selected from the group of Zn, Cd, Hg, Ga, In, Tl, Sn, Pb, As, Sb, Bi and Se on non-metallic, non-conductive or poorly-conductive substrates are disclosed. The composite current collectors can be used in electrochemical cells particularly sealed cells requiring a long storage life. Selected metals, metal alloys or metal compounds are applied to polymer or ceramic substrates by vacuum deposition techniques, extrusion, conductive paints (dispersed as particles in a suitable paint), electroless deposition, cementation; or after suitable metallization by galvanic means (electrodeposition or electrophoresis). Metal compound coatings are reduced to their respective metals by chemical or galvanic means. The current collectors described are particular suitable for use in sealed primary or rechargeable galvanic cells containing mercury-free and lead-free alkaline zinc electrodes.

Abstract: This invention relates to a positive electrode active material for a lithium secondary battery and a lithium secondary battery including the same, and particularly to a positive electrode active material for a lithium secondary battery, in which a lithium composite oxide having a composition of LiNi1-xMxO2 (wherein M represents one or a combination of two elements selected from the group consisting of Co, Al, Mn, Mg, Fe, Cu, Ti, Sn and Cr, and 0.96?x?1.05) is surface-modified using carbon or an organic compound, thereby achieving superior stability and improved high-rate capability compared to conventional positive electrode active materials, and to a lithium secondary battery including the same.

Abstract: Li-based anodes for use in an electric current producing cells having long life time and high capacity are provided. In certain embodiments, the Li-based anode comprises at least one anode active Li-containing compound and a composition comprising at least one polymer, at least one ionic liquid, and optionally at least one lithium salt. The composition may be located between the at least one Li-containing compound and the catholyte used in the electric current producing cell. In some embodiments, the at least one polymer may be incompatible with the catholyte. This configuration of components may lead to separation between the lithium active material of the anode and the catholyte. Processes for preparing the Li-based anode and to electric current producing cells comprising such an anode are also provided.

Abstract: An electrochemical cell comprising a lithium anode, a cathode comprising a blank cut from a free-standing sheet of a silver vanadium oxide mixture contacted to a current collector. The active material has having a relatively lower surface area and an electrolyte activating the anode and the cathode is described. By optimizing the cathode active material surface area in a SVO-containing cell, the magnitude of the passivating film growth at the solid-electrolyte interphase (SEI) and its relative impermeability to lithium ion diffusion is reduced. Therefore, by using a cathode of an active material in a range of from about 0.2 m2/gram to about 2.6 m2/gram, and preferably from about 1.6 m2/gram to about 2.4 m2/gram, it is possible to eliminate or significantly reduce undesirable irreversible Rdc growth and voltage delay in the cell and to extend its useful life in an implantable medical device.

Abstract: According to one embodiment, there is provided a battery electrode. The battery electrode includes a titanium oxide compound having a monoclinic titanium dioxide crystal structure and a basic polymer.

Abstract: A nonaqueous electrolyte secondary battery including a negative electrode having a negative electrode mixture layer on at least one surface of a negative collector; a positive electrode; a separator disposed between the positive electrode and the negative electrode; and a nonaqueous electrolyte, wherein the negative electrode mixture layer contains a negative electrode active material, poly(ethylene oxide), carboxymethylcellulose, and styrene-butadiene rubber, the mass of the carboxymethylcellulose is greater than the mass of the poly(ethylene oxide), and the percentage of the total amount of the carboxymethylcellulose and the lithium ion conducting polymer with respect to the total amount of the negative electrode mixture layer is 0.2% by mass or more and 2.2% by mass or less.

Abstract: Disclosed is a composition for a positive electrode of a rechargeable lithium battery that includes a positive active material, a binder, and an ionic liquid including a borate-based anion.

Abstract: The electrode for the nonaqueous electrolyte secondary battery includes a current collector and an active material layer formed on the current collector. The active material layer contains active material particles each coated with a conductive carbon material layer, a surfactant as a dispersant, and conductive carbon material particles.

Abstract: Electrochemical battery cells, and more particularly, to cells comprising a lithium negative electrode and an iron disulfide positive electrode. Before use in the cell, the iron disulfide has an inherent pH, or a mixture of iron disulfide and an pH raising additive compound have a calculated pH, of at least a predetermined minimum pH value. In a preferred embodiment, the pH raising additive compound comprises a Group IIA element of the Periodic Table of the Elements, or an acid scavenger or pH control agent such as an organic amine, cycloaliphatic epoxy, amino alcohol or overbased calcium sulfonate. In one embodiment, the iron disulfide particles utilized in the cell have a specific reduced average particle size range.

Abstract: A solid lithium ion secondary battery with high safety and high capacity, and an electrode for the solid lithium ion secondary battery. At least one of positive and negative electrodes of the solid lithium ion secondary battery includes a lithium salt of a cyclic imide compound.

Abstract: A shiny is manufactured using a low-molecular-weight organic acid as a dispersant and a nonaqueous organic solvent as a solvent, whereby a coated electrode for a power storage device in which an active material which has been made into microparticles each having a particle diameter of 100 nm or less is uniformly dispersed can be manufactured. By the use of the coated electrode manufactured in this manner, a power storage device with high charge/discharge characteristics can be manufactured. In other words, a power storage device with high capacity density can be realized because the amount of impurities is small and the power density is high due to the sufficient dispersion of the active material in the active material layer.