Cadmium Component Is Active Material Patents (Class 429/222)
  • Publication number: 20140120378
    Abstract: A composite cathode active material, a method of preparing the composite cathode active material, and a cathode and a lithium battery each including the composite cathode active material. The composite cathode active material includes a core including a lithium intercalatable oxide which enables intercalation and deintercalation of lithium; and a coating layer disposed on at least a portion of the core, wherein the conductive layer includes a lithium metal oxide which is an inactive lithium ion conductor, and wherein the lithium metal oxide contains a metal which has an atomic weight of 27 Daltons or more and is selected an element of Groups 3 to 14 of the Periodic Table of the Elements.
    Type: Application
    Filed: October 11, 2013
    Publication date: May 1, 2014
    Applicants: Samsung SDI Co., Ltd.
    Inventors: Jun-young MUN, Jin-hwan PARK, Gue-sung KIM, Jun-ho PARK, Jae-gu YOON
  • Publication number: 20140106212
    Abstract: Disclosed is a cathode material comprising a mixture of an oxide powder (a) defined herein and an oxide powder (b) selected from the group consisting of an oxide powder (b1) defined herein and an oxide powder (b2) defined herein and a combination thereof wherein a mix ratio of the two oxide powders (oxide powder (a): oxide powder (b)) is 50:50 to 90:10. The cathode material uses a combination of an oxide powder (a) and 50% or less of an oxide powder (b) which can exert high capacity, high cycle stability, superior storage stability and high-temperature stability, thus advantageously exhibiting high energy density and realizing high capacity batteries.
    Type: Application
    Filed: November 4, 2013
    Publication date: April 17, 2014
    Applicant: LG CHEM, LTD.
    Inventors: Seungeun CHOI, Eunyoung GOH, Hyang Mok LEE, Heegyoung KANG, Sangbaek RYU, Kiwoong KIM
  • Publication number: 20140087254
    Abstract: A cathode composite material includes a cathode active material and a coating layer coated on a surface of the cathode active material. The cathode active material includes a layered type lithium transition metal oxide. A material of the coating layer is a lithium metal oxide having a crystal structure belonging to C2/c space group of the monoclinic crystal system. The present disclosure also relates to a lithium ion battery including the cathode composite material.
    Type: Application
    Filed: November 30, 2012
    Publication date: March 27, 2014
    Applicants: HON HAI PRECISION INDUSTRY CO., LTD., TSINGHUA UNIVERSITY
    Inventors: YA-DONG LI, JUN LU, DING-SHENG WANG, XIANG-WEN LIU, QING PENG
  • Publication number: 20140050972
    Abstract: Batteries with particularly high energy capacity and low internal impedance have been described herein. The batteries can exhibit extraordinary long cycling with acceptable low amounts of fade. Pouch batteries using high specific capacity lithium rich metal oxide as positive electrode material combined with graphitic carbon anode can reach an energy density of at least about 180 Wh/kg at a rate of C/3 from 4.35V to 2V at room temperature while having a room temperature areas specific DC resistance of no more than about 75 ohms-cm2 at 20% SOC based on a full charge to 4.35V. High specific capacity lithium rich metal oxide with specific stoichiometry ranges used in these batteries are disclosed.
    Type: Application
    Filed: August 17, 2012
    Publication date: February 20, 2014
    Inventors: Shabab Amiruddin, Subramanian Venkatachalam, Bing Li, Charles Bowling, Yezi Bei, Deepak Kumaar Karthikeyan, Herman Lopez, Sujeet Kumar
  • Publication number: 20140050979
    Abstract: The present invention relates to an anode active material for a lithium secondary battery, comprising a carbon material, and a coating layer formed on the surface of particles of the carbon material and having a plurality of Sn-based domains having an average diameter of 1 ?m or less. The inventive anode active material having a Sn-based domains coating layer on the surface of a carbon material can surprisingly prevent stress due to volume expansion which generates by an alloy of Sn and lithium. Also, the inventive method for preparing an anode active material can easily control the thickness of the coating layer.
    Type: Application
    Filed: September 30, 2013
    Publication date: February 20, 2014
    Applicant: LG CHEM, LTD.
    Inventors: Sang-Wook Woo, Ki-Tae Kim, Yo-Han Kwon
  • Publication number: 20130252031
    Abstract: A negative active material, a method of preparing the negative active material and a lithium ion battery comprising the negative active material are provided. The negative active material may comprise: a core (1) composed of a carbon material; and a plurality of composite materials (2) attached to a surface of the core (1), each of which may comprise a first material (21) and a second material (22) coated on the first material (21), in which the first material (21) may be at least one selected from the elements that may form an alloy with lithium, and the second material (22) may be at least one selected from the group consisting of transition metal oxides, transition metal nitrides and transition metal sulfides.
    Type: Application
    Filed: August 31, 2011
    Publication date: September 26, 2013
    Applicant: Shenzhen BYD Auto R&D Company Limited and BYD Company Limited
    Inventors: Yongjun Ma, Pei Tu, Zizhu Guo
  • Patent number: 8541135
    Abstract: The invention is an electrochemical cell with a catalytic electrode and an aqueous alkaline electrolyte within a cell housing having one or more ports for the passage of a gas to or from the catalytic electrode and a process for making the cell. The catalytic electrode includes a catalytic layer, containing a catalytic material, and a porous current collector, at least partially embedded in the catalytic layer. The current collector includes a substrate with an electrically conductive metal layer, in contact with the catalytic material on the side of the current collector facing the ports, and a coating including electrically conductive particles, in contact with the catalytic layer on the side facing the separator.
    Type: Grant
    Filed: June 1, 2010
    Date of Patent: September 24, 2013
    Assignee: Eveready Battery Co, Inc.
    Inventors: Wayne B. Bennett, Jingdong Guo
  • Publication number: 20130244087
    Abstract: A negative active material, a method for preparing the negative active material and a lithium ion battery comprising the same are provided. The negative active material may comprise: a core, an intermediate layer consisting of a first material and an outmost layer consisting of a second material, which is coated on a surface of the intermediate layer. The first material may be at least one selected from the group consisting of the elements that form alloys with lithium, and the second material may be at least one selected from the group consisting of transition metal oxides, transition metal nitrides and transition metal sulfides.
    Type: Application
    Filed: August 25, 2011
    Publication date: September 19, 2013
    Applicant: Shenzhen BYD Auto R&D Company Limited and BYD Company Limited
    Inventors: Yongjun Ma, Pei Tu, Zizhu Guo
  • Publication number: 20130196209
    Abstract: A positive electrode composition is presented. The composition includes at least one electroactive metal; at least one alkali metal halide; and at least one additive including a plurality of nanoparticles, wherein the plurality of nanoparticles includes tungsten carbide. An energy storage device, and a related method for the preparation of an energy storage device, are also presented.
    Type: Application
    Filed: January 30, 2012
    Publication date: August 1, 2013
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Richard Louis Hart, Michael Alan Vallance, David Charles Bogdan, JR.
  • Publication number: 20130189575
    Abstract: A porous silicon based material comprising porous crystalline elemental silicon formed by reducing silicon dioxide with a reducing metal in a heating process followed by acid etching is used to construct negative electrode used in lithium ion batteries. Gradual temperature heating ramp(s) with optional temperature steps can be used to perform the heating process. The porous silicon formed has a high surface area from about 10 m2/g to about 200 m2/g and is substantially free of carbon. The negative electrode formed can have a discharge specific capacity of at least 1800 mAh/g at rate of C/3 discharged from 1.5V to 0.005V against lithium with in some embodiments loading levels ranging from about 1.4 mg/cm2 to about 3.5 mg/cm2. In some embodiments, the porous silicon can be coated with a carbon coating or blended with carbon nanofibers or other conductive carbon material.
    Type: Application
    Filed: January 19, 2012
    Publication date: July 25, 2013
    Inventors: Yogesh Kumar Anguchamy, Charan Masarapu, Haixia Deng, Yongbong Han, Subramanian Venkatachalam, Sujeet Kumar, Herman A. Lopez
  • Publication number: 20130183579
    Abstract: A positive active material for a rechargeable lithium battery includes a core including a lithium composite metal oxide selected from the group consisting of compounds represented by the following Chemical Formula 1, Chemical Formula 2, and combinations thereof; and a shell on the core, the shell including lithium iron phosphate (LiFePO4), and the lithium iron phosphate being present in an amount in a range of about 5 to about 15 wt % based on the total weight of the positive active material. LixMO2 ??[Chemical Formula 1] (wherein, in the above Chemical Formula 1, M is one or more transition elements, and 1?x?1.1) yLi2MnO3·(1?y)LiM?O2 ??[Chemical Formula 2] (wherein, in the above Chemical Formula 2, M? is one or more transition elements, and 0?x?1).
    Type: Application
    Filed: July 27, 2012
    Publication date: July 18, 2013
    Inventors: Seung-Mo Kim, Jun-Sik Jeoung
  • Publication number: 20130177808
    Abstract: An anode protector of a lithium-ion battery and a method for fabricating the same are provided. A passivation protector (110) is formed on a surface of an anode (102) in advance by film deposition, such as atomic layer deposition (ALD). The passivation protector (110) is composed of a metal oxide having three dimensional structures, such as columnar structures. Accordingly, the present invention is provided with effective protection of the anode electrode structure and maintenance of battery cycle life under high-temperature operation.
    Type: Application
    Filed: March 2, 2012
    Publication date: July 11, 2013
    Applicant: National Taiwan University of Science and Technology
    Inventors: Fu-Ming Wang, Hsin-Yi Wang, Chin-Shu Cheng
  • Publication number: 20130171502
    Abstract: The present invention provides a multi-component hybrid electrode for use in an electrochemical super-hybrid energy storage device. The hybrid electrode contains at least a current collector, at least an intercalation electrode active material storing lithium inside interior or bulk thereof, and at least an intercalation-free electrode active material having a specific surface area no less than 100 m2/g and storing lithium on a surface thereof, wherein the intercalation electrode active material and the intercalation-free electrode active material are in electronic contact with the current collector. The resulting super-hybrid cell exhibits exceptional high power and high energy density, and long-term cycling stability that cannot be achieved with conventional supercapacitors, lithium-ion capacitors, lithium-ion batteries, and lithium metal secondary batteries.
    Type: Application
    Filed: December 29, 2011
    Publication date: July 4, 2013
    Inventors: Guorong Chen, Aruna Zhamu, Xiqing Wang, Bor Z. Jang, Yanbo Wang
  • Publication number: 20130130103
    Abstract: A cathode and a battery including a cathode active material including a layer-structured material having a composition of xLi2MO3-(1-x)LiMeO2; and a metal oxide having a perovskite structure. The cathode active material may have improved structural stability by intermixing a metal oxide having a similar crystalline structure with the layer-structured material, and thus, life and capacity characteristics of a cathode and a lithium battery including the metal oxide may be improved.
    Type: Application
    Filed: October 17, 2012
    Publication date: May 23, 2013
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Myung-hoon KIM, Kyu-sung PARK, Min-sik PARK, Jin-hwan PARK
  • Publication number: 20130130101
    Abstract: A negative electrode active material and a secondary battery are provided. The negative electrode active material can be useful in maintaining excellent cell efficiency and lifespan while showing high-capacity properties, and the secondary battery may be manufactured using the negative electrode active material.
    Type: Application
    Filed: November 19, 2010
    Publication date: May 23, 2013
    Inventors: Jae Woong Kim, Seung Chul Lee, Ki Duck Park, Chul Gyu Bae, Jong Goo Kang, Yoon Seong Cho
  • Publication number: 20130115513
    Abstract: An electrode active material includes a core capable of intercalating and deintercalating lithium; and a surface treatment layer disposed on at least a portion of a surface of the core, wherein the surface treatment layer includes a lithium-free oxide having a spinel structure, and an intensity of an X-ray diffraction peak corresponding to impurity phase of the lithium-free oxide, when measured using Cu—K? radiation, is at a noise level of an X-ray diffraction spectrum or less.
    Type: Application
    Filed: July 23, 2012
    Publication date: May 9, 2013
    Applicants: SAMSUNG CORNING PRECISION MATERIALS CO., LTD., SAMSUNG SDI CO., LTD.
    Inventors: Won-chang CHOI, Gue-sung KIM, Min-sang SONG, Young-min CHOI, Ryoung-hee KIM, So-yeon KIM
  • Patent number: 8435676
    Abstract: This invention provides a mixed nano-filament composition for use as an electrochemical cell electrode. The composition comprises: (a) an aggregate of nanometer-scaled, electrically conductive filaments that are substantially interconnected, intersected, or percolated to form a porous, electrically conductive filament network, wherein the filaments have a length and a diameter or thickness with the diameter/thickness less than 500 nm (preferably <100 nm) and a length-to-diameter or length-to-thickness aspect ratio greater than 10; and (b) Multiple nanometer-scaled, electro-active filaments comprising an electro-active material capable of absorbing and desorbing lithium ions wherein the electro-active filaments have a diameter or thickness less than 500 nm (preferably <100 nm). The electro-active filaments (e.g., nanowires) and the electrically conductive filaments (e.g.
    Type: Grant
    Filed: January 9, 2008
    Date of Patent: May 7, 2013
    Assignee: NanoteK Instruments, Inc.
    Inventors: Aruna Zhamu, Bor Z. Jang
  • Publication number: 20130095377
    Abstract: An electrochemical cell including an anode comprising a carbonaceous material, where the carbonaceous material is capable of reversibly incorporating lithium ions therein and lithium metal on the surface thereof, a cathode capable of reversibly incorporating therein lithium ions, and a non-aqueous electrolyte in contact with the anode and the cathode, where the ratio of the capacity to reversibly incorporate lithium ions of the cathode to the capacity to reversibly incorporate lithium ions in the form of LiC6 of the carbonaceous material of the anode is equal to or larger than 4.5:1.
    Type: Application
    Filed: October 22, 2012
    Publication date: April 18, 2013
    Applicant: TADIRAN BATTERIES LTD.
    Inventor: Tadiran Batteries Ltd.
  • Publication number: 20130089784
    Abstract: A negative active material and a lithium battery including the negative active material. The negative active material includes primary particles, each including: a crystalline carbonaceous core having a surface on which silicon-based nanowires are disposed; and an amorphous carbonaceous coating layer that is coated on the crystalline carbonaceous core so as not to expose at least a portion of the silicon-based nanowires. Due to the inclusion of the primary particles, an expansion ratio is controlled and conductivity is provided and thus, a formed lithium battery including the negative active material may have improved charge-discharge efficiency and cycle lifespan characteristics.
    Type: Application
    Filed: July 19, 2012
    Publication date: April 11, 2013
    Inventors: Yu-Jeong Cho, So-Ra Lee, Ha-Na Yoo, Ui-Song Do, Chang-Su Shin, Su-Kyung Lee, Jae-Myung Kim
  • Publication number: 20130084499
    Abstract: In a non-aqueous electrolyte secondary battery, a positive electrode active material includes a carbon-coated lithium vanadium phosphate and a lithium nickel composite oxide. A negative electrode active material includes a carbon-based active material capable of intercalating and deintercalating lithium ions. When a first charge capacity of a negative electrode per unit area is “x” (mAh/cm2), and a first charge capacity of a positive electrode per unit area is “y” (mAh/cm2), a relation of “x” and “y” satisfies 0.6?y/x?0.92.
    Type: Application
    Filed: September 6, 2012
    Publication date: April 4, 2013
    Applicant: FUJI JUKOGYO KABUSHIKI KAISHA
    Inventors: Hideo Yanagita, Kazuki Takimoto
  • Publication number: 20130059203
    Abstract: Provided are an anode active material for a lithium secondary battery, a method for preparing same, and a lithium secondary battery including same. An anode active material for a lithium secondary battery according to the present invention includes: active particles by means of which lithium ions may be absorbed/released; and a coating layer coated on the surface of the active particles, wherein the coating layer includes a first material which is a hollow nanofiber and a second material which is a carbon precursor or LTO.
    Type: Application
    Filed: May 11, 2011
    Publication date: March 7, 2013
    Applicant: ROUTE JJ CO., LTD.
    Inventors: Ji Jun Hong, Ki Taek Byun, Hyo Won Kim
  • Patent number: 8389150
    Abstract: Composite current collectors containing coatings of metals, alloys or compounds, selected from the group of Zn, Cd, Hg, Ga, In, Tl, Sn, Pb, As, Sb, Bi and Se on non-metallic, non-conductive or poorly-conductive substrates are disclosed. The composite current collectors can be used in electrochemical cells particularly sealed cells requiring a long storage life. Selected metals, metal alloys or metal compounds are applied to polymer or ceramic substrates by vacuum deposition techniques, extrusion, conductive paints (dispersed as particles in a suitable paint), electroless deposition, cementation; or after suitable metallization by galvanic means (electrodeposition or electrophoresis). Metal compound coatings are reduced to their respective metals by chemical or galvanic means. The current collectors described are particular suitable for use in sealed primary or rechargeable galvanic cells containing mercury-fee and lead-free alkaline zinc electrodes.
    Type: Grant
    Filed: April 20, 2012
    Date of Patent: March 5, 2013
    Inventor: Klaus Tomantschger
  • Publication number: 20130052534
    Abstract: A cathode includes a lithium transition metal complex compound including lithium, one, or two or more transition metals, magnesium, and oxygen as constituent elements. In a standardized X-ray absorption spectrum of the lithium transition metal complex compound measured by an X-ray absorption spectroscopic method, a first absorption edge having absorption edge energy E1 in X-ray absorption intensity of about 0.5 exits in a range where X-ray energy is from about 1303 eV to about 1313 eV both inclusive, in a discharged state in which a discharge voltage is about 3.0 V, and a second absorption edge having absorption edge energy E2 in X-ray absorption intensity of about 0.5 exits, in a charged state in which a charge voltage V is from about 4.3 V to about 4.5 V both inclusive. The absorption edge energies E1 and E2 and the charge voltage V satisfy a relation of E2?E1?(V?4.25)×4.
    Type: Application
    Filed: August 13, 2012
    Publication date: February 28, 2013
    Applicant: SONY CORPORATION
    Inventors: Satoshi Fujiki, Hirotaka Fukudome, Kazunari Motohashi, Yosuke Hosoya, Yoshihiro Kudo
  • Publication number: 20130043843
    Abstract: Battery formation protocols are used to perform initial charging of batteries with lithium rich high capacity positive electrode to result a more stable battery structure. The formation protocol generally comprises three steps, an initial charge step, a rest period under an open circuit and a subsequent charge step to a selected partial activation voltage. The subsequent or second charge voltage is selected to provide for a desired degree of partial activation of the positive electrode active material to achieve a desired specific capacity while providing for excellent stability with cycling. The formation protocol is particularly effective to stabilize cycling for compositions with moderate lithium enrichment.
    Type: Application
    Filed: August 17, 2012
    Publication date: February 21, 2013
    Inventors: Shabab Amiruddin, Bing Li
  • Publication number: 20130029223
    Abstract: The invention relates to materials for use as electrodes in an alkali-ion secondary (rechargeable) battery, particularly a lithium-ion battery. The invention provides transition-metal compounds having the ordered-olivine or the rhombohedral NASICON structure and the polyanion (PO4)3? as at least one constituent for use as electrode material for alkali-ion rechargeable batteries.
    Type: Application
    Filed: October 4, 2012
    Publication date: January 31, 2013
    Inventors: Michel Armand, John B. Goodenough, Akshaya K. Padhi, Kirakodu S. Nanjundaswamy, Christian Masquelier
  • Publication number: 20130022852
    Abstract: Methods for improving the electrical conductivity of a carbon felt material is provided. In some embodiments, a method improving the electrical conductivity of a carbon felt material comprises applying a carbon source liquid to at least a portion of a carbon felt material, optionally removing excess carbon source liquid from the carbon felt material, and converting the carbon source material to solid carbon, such as by heating. Also provided are materials and products created using these methods.
    Type: Application
    Filed: January 12, 2012
    Publication date: January 24, 2013
    Applicant: EnerVault Corporation
    Inventors: On Kok Chang, Kimio Kinoshita, Ronald James Mosso
  • Publication number: 20130022869
    Abstract: A positive electrode active material for a lithium secondary battery includes a lithium cobalt complex oxide containing an alkali earth metal and a transition metal in a predetermined mixture ratio. A method of preparing the positive electrode active material includes mixing a lithium salt, a transition metal precursor, and an alkali earth metal salt to form a mixture, and performing at least one thermal treatment on the mixture. A positive electrode for a lithium secondary battery includes the positive electrode active material, and a lithium secondary battery includes the positive electrode.
    Type: Application
    Filed: May 21, 2012
    Publication date: January 24, 2013
    Inventor: Seung-Beob Yi
  • Patent number: 8349492
    Abstract: The negative electrode for a rechargeable lithium battery includes a current collector and a negative active material layer disposed on the current collector. The negative active material layer includes a metal-based negative active material and sheet-shaped graphite and has porosity of 20 to 80 volume %. The negative electrode for a rechargeable lithium battery can improve cell characteristics by inhibiting volume change and stress due to active material particle bombardment during charge and discharge, and by decreasing electrode resistance.
    Type: Grant
    Filed: January 22, 2008
    Date of Patent: January 8, 2013
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Sang-Min Lee, Goo-Jin Jeong, Min-Seok Sung, Yong-Mook Kang, Wan-Uk Choi, Sung-Soo Kim
  • Patent number: 8338031
    Abstract: Provided are a cathode and a lithium battery including the cathode. The cathode includes a cathode active material that includes an oxide represented by the following Formula 1: LixNi0.5+y(Mn1-z1-z2Mz1Moz2)0.5?yO2,??<Formula 1> wherein 0.9<x<1.2, ?0.02<y<0.2, 0.001<z1<0.5, 0.001<z2<0.5, and M is a metallic atom having an oxidation number of +2.
    Type: Grant
    Filed: August 5, 2008
    Date of Patent: December 25, 2012
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Kyu-sung Park
  • Publication number: 20120321955
    Abstract: A lithium-ion secondary battery is characterized in that it is equipped with: a positive electrode comprising a positive-electrode active material that includes a lithium-transition metal composite oxide including at least lithium and manganese and possessing a layered rock-salt structure; a negative electrode comprising a negative-electrode active material that includes at least one kind of carbon-based materials, silicon-based materials, and tin-based materials; and a non-aqueous electrolytic solution, wherein: said lithium-transition metal composite oxide exhibits an irreversible capacity; and an actual capacity of said negative electrode at the time of first-round charging up to 0 V with respect to metallic lithium is smaller than an actual capacity of said positive electrode at the time of first-round charging up to 4.7 V with respect to metallic lithium.
    Type: Application
    Filed: April 1, 2011
    Publication date: December 20, 2012
    Applicant: KABUSHIKI KAISHA TOYOTA JIDOSHOKKI
    Inventors: Naoto Yasuda, Toru Abe, Junichi Niwa
  • Publication number: 20120321954
    Abstract: The present invention is a production process for composite oxide being expressed by a compositional formula: LiMn1-xAxO2 (where “A” is one or more kinds of metallic elements other than Mn; and 0?“x”<1), and the composite oxide is obtained via the following: a raw-material mixture preparation step of preparing a raw-material mixture by mixing a metallic-compound raw material and a molten-salt raw material with each other, the metallic-compound raw material at least including an Mn-containing nitrate that includes one or more kinds of metallic elements in which Mn is essential, the molten-salt raw material including lithium hydroxide and lithium nitrate, and exhibiting a proportion of the lithium nitrate with respect to the lithium hydroxide (i.e., (Lithium Nitrate)/(Lithium Hydroxide)) that falls in a range of from 1 or more to 3 or less by molar ratio; a molten reaction step of reacting the raw-material mixture at 500° C.
    Type: Application
    Filed: February 7, 2011
    Publication date: December 20, 2012
    Applicant: KABUSHIKI KAISHA TOYOTA JIDOSHOKKI
    Inventors: Ryota Isomura, Hitotoshi Murase, Naoto Yasuda
  • Publication number: 20120321953
    Abstract: A nano graphene-enabled vanadium oxide composite composition for use as a lithium battery cathode active material, wherein the composite composition is formed of one or a plurality of graphene, graphene oxide, or graphene fluoride sheets or platelets and a plurality of nano-particles, nano-rods, nano-wires, nano-sheets, and/or nano-belts of a vanadium oxide with a size smaller than 100 nm (preferably smaller than 20 nm, further preferably smaller than 10 nm, and most preferably smaller than 5 nm), and wherein the graphene, graphene oxide, or graphene fluoride (having a thickness <20 nm, preferably <10 nm, further preferably <5 nm, and being most preferably of single-layer or less than 5 layers) is in an amount of from 0.01% to 50% (preferably <10%) by weight based on the total weight of graphene, graphene oxide or graphene fluoride and the vanadium oxide combined.
    Type: Application
    Filed: June 17, 2011
    Publication date: December 20, 2012
    Inventors: Guorong Chen, Aruna Zhamu, Bor Z. Jang, Zhenning Yu
  • Publication number: 20120315543
    Abstract: A coin-type lithium secondary battery includes a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte. The negative electrode includes a negative electrode active material including a silicon alloy material, a conductive agent including a carbon material, and a binder. The silicon alloy material includes a phase A including a lithium-silicon alloy and a phase B including an intermetallic compound of a transition metal element and silicon. In the lithium-silicon alloy, a ratio of lithium atoms relative to silicon atoms is 2.75 to 3.65 in a 100% state-of-charge.
    Type: Application
    Filed: September 15, 2010
    Publication date: December 13, 2012
    Inventors: Toshie Wata, Tadayoshi Takahashi
  • Publication number: 20120295155
    Abstract: Silicon oxide based materials, including composites with various electrical conductive compositions, are formulated into desirable anodes. The anodes can be effectively combined into lithium ion batteries with high capacity cathode materials. In some formulations, supplemental lithium can be used to stabilize cycling as well as to reduce effects of first cycle irreversible capacity loss. Batteries are described with surprisingly good cycling properties with good specific capacities with respect to both cathode active weights and anode active weights.
    Type: Application
    Filed: May 16, 2011
    Publication date: November 22, 2012
    Inventors: Haixia Deng, Yongbong Han, Charan Masarapu, Yogesh Kumar Anguchamy, Herman A. Lopez, Sujeet Kumar
  • Publication number: 20120282521
    Abstract: An electrode active material, a method of manufacturing the same, and an electrode and a lithium battery adopting the same. The electrode active material includes a core capable of occluding and emitting lithium; and a surface treatment layer formed on at least a portion of a surface of the core, wherein the surface treatment layer includes a lithium-free oxide having a spinel structure.
    Type: Application
    Filed: May 1, 2012
    Publication date: November 8, 2012
    Applicant: Samsung Electronics Co. Ltd.
    Inventors: Won-chang CHOI, Jin-hwan Park
  • Publication number: 20120270105
    Abstract: A nonaqueous electrolyte secondary battery disclosed in the present application includes: a positive electrode capable of absorbing and releasing lithium, containing a positive electrode active material composed of a lithium-containing transition metal oxide having a layered crystalline structure; and a negative electrode capable of absorbing and releasing lithium, containing a negative electrode active material composed of a lithium-containing transition metal oxide obtained by substituting some of Ti element of a lithium-containing titanium oxide having a spinel crystalline structure with one or more element different from Ti, wherein a retention of the negative electrode is set to be greater than a retention of the positive electrode, and an irreversible capacity rate of the negative electrode is set to be greater than an irreversible capacity rate of the positive electrode, whereby a discharge ends by negative electrode limitation.
    Type: Application
    Filed: April 18, 2012
    Publication date: October 25, 2012
    Inventors: Natsumi Goto, Takashi Takeuchi, Masaki Hasegawa
  • Publication number: 20120264018
    Abstract: A composite positive electrode material with a core-shell structure for a lithium ion battery consists of a core active material and a shell active material. The core active material is a lithium iron phosphate or a lithium manganate, and the shell active material is a composite lithium iron phosphate with carbon. The carbon is one or more of carbon nanotube, superfine conductive carbon black and amorphous carbon material. The composite positive electrode material includes from 65% to 99% core active material and from 1% to 35% shell active material, based on the total weight of the composite positive electrode material. The composite positive electrode material has stable property and excellent electrochemistry performance. The lithium ion battery made with the material has higher charge-discharge capacity, excellent cycle performance. It can be charged quickly and discharged at high rate. A preparing method for the composite positive electrode material is also provided.
    Type: Application
    Filed: September 29, 2010
    Publication date: October 18, 2012
    Inventors: Lingyong Kong, Xuewen Ji, Yunshi Wang
  • Patent number: 8287772
    Abstract: A method of making nanostructured alloy particles includes milling a millbase in a pebble mill containing milling media. The millbase comprises: (i) silicon, and (ii) at least one of carbon or a transition metal, and wherein the nanostructured alloy particles are substantially free of crystalline domains greater than 50 nanometers in size. A method of making a negative electrode composition for a lithium ion battery including the nanostructured alloy particles is also disclosed.
    Type: Grant
    Filed: May 14, 2009
    Date of Patent: October 16, 2012
    Assignee: 3M Innovative Properties Company
    Inventors: Dinh B. Le, Mark N. Obrovac, Robert Y. Kube, James R. Landucci
  • Patent number: 8273478
    Abstract: A rechargeable lithium battery includes an electrolyte including an additive such as an ethylene carbonate-based compound represented by Chemical Formula 1 and a silicon-included compound, and a negative electrode including a negative active material including an active element selected from the group consisting of Si, Sn, Ga, Cd, Al, Pb, Zn, Bi, In, Mg, and Ge. In Chemical formula 1, X and Y are independently selected from the group consisting of hydrogen, a halogen, and a C1 through C5 fluoroalkyl, provided that at least one of X and Y is selected from the group consisting of a halogen and a C1 through C5 fluoroalkyl. The rechargeable lithium battery has a suppressed volume expansion characteristic due to a high-capacity negative active material, and has excellent reliability and cycle-life characteristics.
    Type: Grant
    Filed: March 31, 2009
    Date of Patent: September 25, 2012
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Jin-Sung Kim, Na-Rae Park, Su-Hee Han, Jin-Hyunk Lim
  • Patent number: 8268148
    Abstract: A reference electrode having a casing with an inner cavity successively filled with a paste constituting an active material and a porous material impregnated with an electrolyte solution. The projecting end of a silver wire is embedded in the paste at the bottom of the inner cavity. The paste is constituted of a powder of a silver compound and of the alkaline electrolyte solution. The silver compound is any insoluble silver salt or oxide containing the negative ion of the electrolyte solution. The impregnated porous material is preferably constituted by a plurality of mat separator pieces mechanically and compressed by a closing plug, closing the inner cavity and forming a porous liquid junction.
    Type: Grant
    Filed: June 25, 2007
    Date of Patent: September 18, 2012
    Assignee: Commissariat a l'energie Atomique
    Inventor: Angel Zhivkov Kirchev
  • Publication number: 20120177993
    Abstract: The present invention relates to nonaqueous electrolyte secondary batteries and durable anode materials and anodes for use in nonaqueous electrolyte secondary batteries. The present invention also relates to methods for producing these anode materials. In the present invention, a metal-semiconductor alloy layer is formed on an anode material by contacting a portion of the anode material with a displacement solution. The displacement solution contains ions of the metal to be deposited and a dissolution component for dissolving a part of the semiconductor in the anode material. When the anode material is contacted with the displacement solution, the dissolution component dissolves a part of the semiconductor in the anode material thereby providing electrons to reduce the metal ions and deposit the metal on the anode material. After deposition, the anode material and metal are annealed to form a uniform metal-semiconductor alloy layer.
    Type: Application
    Filed: February 15, 2012
    Publication date: July 12, 2012
    Applicant: ENOVIX CORPORATION
    Inventors: Murali RAMASUBRAMANIAN, Robert SPOTNITZ
  • Publication number: 20120171570
    Abstract: The present disclosure relates to an electrode composite material. The electrode composite material includes a number of electrode composite material particles. Each of the plurality of electrode composite material particles includes an electrode active material particle and a doped aluminum phosphate layer coated on a surface of the electrode active material particle. A material of the doped aluminum phosphate layer is a semiconducting doped aluminum phosphate.
    Type: Application
    Filed: April 29, 2011
    Publication date: July 5, 2012
    Applicants: HON HAI PRECISION INDUSTRY CO., LTD., TSINGHUA UNIVERSITY
    Inventors: XIAN-KUN HUANG, XIANG-MING HE, CHANG-YIN JIANG, DAN WANG, JIAN GAO, JIAN-JUN LI
  • Publication number: 20120164532
    Abstract: A lithium ion secondary battery includes a positive electrode, a negative electrode, and an electrolytic solution, wherein the positive electrode includes a first lithium composite oxide and a second lithium composite oxide expressed by the following equation (1), as a positive electrode active material, and a charge capacity (vs lithium metal) per unit volume during a charge and discharge of a first cycle is larger in the second lithium composite oxide compared to the first lithium composite oxide, and a discharge voltage (vs lithium metal) during the charge and discharge of the first cycle is lower in the second lithium composite oxide compared to the first lithium composite oxide, Li1+a(MnbCocNi1-b-c)1-aO2 . . . (1), where a, b, and c satisfy relationships of 0<a?0.25, 0.5?b<0.7, and 0?c<1?b.
    Type: Application
    Filed: December 8, 2011
    Publication date: June 28, 2012
    Applicant: Sony Corporation
    Inventors: Masaharu Senoue, Kenichi Kawase, Nozomu Morita, Kazuaki Endoh, Akira Takamuku, Yosuke Hosoya, Guohua Li
  • Publication number: 20120164533
    Abstract: A lithium ion secondary battery including a positive electrode; a negative electrode; and an electrolytic solution, wherein the positive electrode includes a first lithium composite oxide and a second lithium composite oxide expressed by following formula (1) as a positive electrode active material, and wherein the second lithium composite oxide has a charge capacity greater than the first lithium composite oxide Li1+a(NibM1cM21?b?c)1.5?0.5aO2??(1) wherein, M1 represents at least one selected from among elements of group 13 to group 15 in an extended periodic table of elements excluding boron B, or carbon C, or nitrogen N, M2 represents at least one selected from among elements of group 3 to group 12, and a, b, and c satisfy relationships of 0.95?a?1.05, 0<b?0.99, and 0<c?0.15.
    Type: Application
    Filed: December 14, 2011
    Publication date: June 28, 2012
    Applicant: SONY CORPORATION
    Inventors: Masaharu Senoue, Kenichi Kawase, Takakazu Hirose, Masayuki Ihara
  • Patent number: 8182938
    Abstract: Composite current collectors containing coatings of metals, alloys or compounds, selected from the group of Zn, Cd, Hg, Ga, In, Tl, Sn, Pb, As, Sb, Bi and Se on non-metallic, non-conductive or poorly-conductive substrates are disclosed. The composite current collectors can be used in electrochemical cells particularly sealed cells requiring a long storage life. Selected metals, metal alloys or metal compounds are applied to polymer or ceramic substrates by vacuum deposition techniques, extrusion, conductive paints (dispersed as particles in a suitable paint), electroless deposition, cementation; or after suitable metallization by galvanic means (electrodeposition or electrophoresis). Metal compound coatings are reduced to their respective metals by chemical or galvanic means. The current collectors described are particular suitable for use in sealed primary or rechargeable galvanic cells containing mercury-free and lead-free alkaline zinc electrodes.
    Type: Grant
    Filed: May 3, 2011
    Date of Patent: May 22, 2012
    Inventor: Klaus Tomantschger
  • Publication number: 20120077087
    Abstract: The present invention relates to negative-electrode active material for rechargeable lithium battery comprising: a core comprising material capable of doping and dedoping lithium; and, a carbon layer formed on the surface of the core, wherein the carbon layer has a three dimensional porous structure comprising nanopores regularly ordered on the carbon layer with a pore wall of specific thickness placed therebetween.
    Type: Application
    Filed: September 22, 2011
    Publication date: March 29, 2012
    Applicants: UNIST ACADEMY-INDUSTRY RESEARCH CORPORATION, LG CHEM, LTD.
    Inventors: Jaephil Cho, Jae-Bum Choo, Byung-Hee Han, Hyun-Jung Kim, Ki-Tae Kim, Je-Young Kim
  • Publication number: 20120045696
    Abstract: A negative electrode of a non-aqueous electrolyte secondary battery comprises a current collector and a mixture comprising a negative electrode active material, a conductive material, and a binder on the current collector. The negative electrode active material has the overall composition: MaSibPcBd; in which: 0<a<1, 0<b<1, 0<c<1, 0<d<1, and a+b+c+d=1; and M is selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Tc, Cu, Zn, Pd, Ag, Cd, Au, Mn, Co, Ni, Sn, and Re, and mixtures thereof. A non-aqueous electrolyte secondary battery comprises a positive electrode, the negative electrode, and a non-aqueous electrolyte between the positive and negative electrodes. A method for preparing the negative electrode comprises the steps of preparing a mixture comprising a negative electrode active material, a conductive material, a binder, and a solvent; coating the mixture on a current collector; and drying the mixture.
    Type: Application
    Filed: August 23, 2010
    Publication date: February 23, 2012
    Inventor: P. Subramanya Herle
  • Patent number: 8119285
    Abstract: A positive electrode material is disclosed which contains an iron lithium phosphate as a positive electrode active material and has a large charge/discharge capacity, high-rate adaptability, and good charge/discharge cycle characteristics at the same time. Also disclosed are a simple method for producing such a positive electrode material and a high-performance secondary battery employing such a positive electrode material. Specifically, disclosed is a positive electrode material for secondary battery characterized by mainly containing a positive electrode active material represented by the general formula: LinFePO4 (wherein n is a number of 0-1) and further containing at least one different metal element selected from the group consisting of vanadium (V), chromium (Cr), copper (Cu), zinc (Zn), indium (In) and tin (Sn). This positive electrode material can be produced using a halide of such a metal element as the raw material.
    Type: Grant
    Filed: October 26, 2004
    Date of Patent: February 21, 2012
    Assignee: Mitsui Engineering & Shipbuilding Co., Ltd.
    Inventors: Naoki Hatta, Toshikazu Inaba, Izumi Uchiyama
  • Patent number: 8119288
    Abstract: The present invention provides an exfoliated graphite-based hybrid material composition for use as an electrode, particularly as an anode of a lithium ion battery. The composition comprises: (a) micron- or nanometer-scaled particles or coating which are capable of absorbing and desorbing alkali or alkaline metal ions (particularly, lithium ions); and (b) exfoliated graphite flakes that are substantially interconnected to form a porous, conductive graphite network comprising pores, wherein at least one of the particles or coating resides in a pore of the network or attached to a flake of the network and the exfoliated graphite amount is in the range of 5% to 90% by weight and the amount of particles or coating is in the range of 95% to 10% by weight. Also provided is a lithium secondary battery comprising such a negative electrode (anode). The battery exhibits an exceptional specific capacity, excellent reversible capacity, and long cycle life.
    Type: Grant
    Filed: November 5, 2007
    Date of Patent: February 21, 2012
    Assignee: Nanotek Instruments, Inc.
    Inventors: Aruna Zhamu, Bor Z. Jang
  • Publication number: 20120028113
    Abstract: An anode composite material includes an anode active material particle having a surface and a continuous aluminum phosphate layer. The continuous aluminum phosphate layer is coated on the surface of the anode active material particle. The present disclosure also relates to a lithium ion battery that includes the cathode composite material.
    Type: Application
    Filed: May 16, 2011
    Publication date: February 2, 2012
    Applicants: HON HAI PRECISION INDUSTRY CO., LTD., TSINGHUA UNIVERSITY
    Inventors: XIAN-KUN HUANG, XIANG-MING HE, CHANG-YIN JIANG, DAN WANG, JIAN GAO, JIAN-JUN LI