Nickel Component Is Active Material Patents (Class 429/223)
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Patent number: 12261299Abstract: An electrode having a coating layer formed from a composition including a perfluoropolyether group-containing compound represented by the formula (A1), (A2), (B1), (B2), (C1), (C2), (D1), (D2), (E1) or (E2) as defined herein, wherein in the composition, compounds represented by formulae (A2), (B2), (C2), (D2) and (E2) are 0.1 mol % or more and 35 mol % or less based on the total amount of compounds represented by formulae (A1), (B1), (C1), (D1) and (E1) and compounds represented by formulae (A2), (B2), (C2), (D2) and (E2). Also disclosed is an electrochemical device including the electrode.Type: GrantFiled: November 6, 2020Date of Patent: March 25, 2025Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Shigeaki Yamazaki, Yoshiaki Honda, Toshiharu Shimooka, Yoshimi Motonari, Hisashi Mitsuhashi
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Patent number: 12261289Abstract: Systems and methods which provide lithium-ion battery configurations with high energy density are disclosed. Embodiments provide lithium-ion batteries comprising an anode that includes 30 to 85 wt. % silicon, thereby facilitating high energy density and high N:P ratio for the lithium-ion batteries. The high N:P ratio further enables fast charging and low temperature charging capabilities of the lithium-ion batteries.Type: GrantFiled: June 3, 2022Date of Patent: March 25, 2025Assignee: Techtronic Cordless GPInventors: Denis Gaston Fauteux, Aditya Subramanian
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Patent number: 12261290Abstract: A nonaqueous electrolyte secondary battery including a positive electrode, a negative electrode, and a nonaqueous electrolyte, the positive electrode containing, as a positive active material, a lithium transition metal composite oxide having an ?-NaFeO2 type crystal structure, a molar ratio of Li to Me, Li/Me of more than 1, Me representing transition metal elements including Ni and Mn or including Ni, Mn, and Co, and a molar ratio of Mn to Me, Mn/Me of 0.40 or more and 0.65 or less, and the nonaqueous electrolyte containing, as an electrolyte salt, LiPF6 and a lithium imide salt.Type: GrantFiled: October 25, 2019Date of Patent: March 25, 2025Assignee: GS Yuasa International Ltd.Inventors: Ryo Harada, Akira Kishimoto
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Patent number: 12258271Abstract: A hydrogen compression system includes an inner container made of a non-magnetic element and having a hydrogen inlet/outlet portion through which hydrogen flows in or out of the inner container, a metal hydride material accommodated in the inner container, an outer container configured to surround the inner container and having an inlet/outlet port through which hydrogen flows in or out of the outer container, and an induction heating unit disposed between the inner container and the outer container and configured to heat the metal hydride material by induction heating, thereby obtaining an advantageous effect of simplifying a structure and process for heating the metal hydride material and quickly heating the metal hydride material to an accurate temperature.Type: GrantFiled: June 29, 2022Date of Patent: March 25, 2025Assignees: HYUNDAI MOTOR COMPANY, KIA CORPORATIONInventors: Ji Hye Park, Ji Sung Lee
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Patent number: 12255319Abstract: Provided is a positive electrode for a lithium ion secondary battery that suppresses both a decrease in discharge capacity and an increase in internal resistance due to charging and discharging. The positive electrode for the lithium ion secondary battery includes a positive-electrode current collector and a layered structure provided on the positive-electrode current collector, in which the outermost layer of the layered structure contains a first positive-electrode active material represented by Li1+XMAO2 wherein X satisfies ?0.15?X?0.15, MA represents an element group including Ni, Co, and Mn, and the innermost layer of the layered structure contains a second positive-electrode active material represented by Li1+YMBO2 wherein Y satisfies ?0.15?Y?0.15, and MB represents an element group including Ni, Co, and at least one of Mn or Al.Type: GrantFiled: November 12, 2020Date of Patent: March 18, 2025Assignee: VEHICLE ENERGY JAPAN INC.Inventors: Takeshi Miki, Yuki Takei, Yusuke Tachikawa, Shuichi Suzuki
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Patent number: 12255310Abstract: The present invention relates to a material injection scheduling method for producing a precursor having a concentration gradient using an apparatus for producing a precursor having a concentration gradient mixing materials of a first feed tank and a second feed tank with each other in advance in a mixer and injecting the mixed material into a reactor.Type: GrantFiled: December 12, 2018Date of Patent: March 18, 2025Assignees: POSCO HOLDINGS INC., RESEARCH INSTITUTE OF INDUSTRIAL SCIENCE & TECHNOLOGYInventors: Hwang Yol Ryu, Ki Sung You
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Patent number: 12249687Abstract: A main object of the present disclosure is to provide an all solid state battery capable of decreasing the heating value. The present disclosure achieves the object by providing an all solid state battery comprising a cathode layer, an anode layer, and a solid electrolyte layer formed between the cathode layer and the anode layer, and the cathode layer includes a complex cathode active material containing a spinel type active material, and a lithium oxide layer coating a surface of the spinel type active material; and a halide solid electrolyte containing an X element wherein X is a halogen, as a main component of an anion, and the anode layer includes a Si based anode active material.Type: GrantFiled: May 21, 2024Date of Patent: March 11, 2025Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Hideaki Watanabe
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Patent number: 12244009Abstract: The purpose of the present disclosure is to provide a non-aqueous electrolyte rechargeable battery that serves to improve the thermal stability of the lithium composite oxide while keeping degradation in the low-temperature characteristics of the battery under control. A non-aqueous electrolyte rechargeable battery involving one aspect of the present disclosure includes a cathode, an anode, and a non-aqueous electrolyte. The cathode includes a cathode current collector and a cathode laminate disposed on the cathode current collector. The cathode laminate includes a lithium composite oxide (30) composed of secondary particles (34) formed of aggregated primary particles (32). Letting the average particle diameter of the primary particles (32) be d and the standard deviation in the particle-size distribution be ?, among the secondary particles (34) primary particles (32a) having a particle diameter greater than d+6? are present.Type: GrantFiled: February 21, 2020Date of Patent: March 4, 2025Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Yasunobu Kawamoto, Masahiro Kinoshita
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Patent number: 12237509Abstract: A secondary battery including a positive electrode, a negative electrode, and an electrolytic solution. The negative electrode includes a carbon material electrochemically capable of absorbing and releasing lithium ions, and a solid electrolyte covering at least part of a surface of the carbon material and having lithium ion conductivity. The solid electrolyte includes a first compound represented by a general formula: LixM1Oy, where 0.5<x?9, 1?y<6, and the M1 includes at least one element selected from the group consisting of B, Al, Si, P, Ti, V, Zr, Nb, Ta, and La. The electrolytic solution includes a solvent and a lithium salt, and the solvent contains at least water.Type: GrantFiled: June 16, 2020Date of Patent: February 25, 2025Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Kenji Matsubara, Hiroshi Kawada, Atsushi Fukui, Masanobu Takeuchi
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Patent number: 12234158Abstract: The invention relates to a method for preparing transitional-metal particles (cathode particle precursor) under a co-precipitation reaction. In this method, by feeding different types of anion compositions and/or cation compositions, and adjusting the pH to match with the species, precipitated particles are deposited to form a slurry, colleting the slurry, treating with water, and drying to get a cathode particle precursor. Mixing the cathode particle precursor with a lithium source and calcining to yield core-shell structured cathode active particles. Such cathode active particle can be used to prepare cathode of lithium-ion battery.Type: GrantFiled: May 21, 2019Date of Patent: February 25, 2025Assignee: MICROVAST ADVANCED MATERIALS INC.Inventors: Bryan Yonemoto, Xiao Zhang, Huijie Guo, Jianzhao Liu
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Patent number: 12237507Abstract: A nickel composite hydroxide includes nickel, cobalt, manganese, and an element M with an atomic ratio of Ni:Co:Mn:M=1?x1?y1?z1:x1:y1:z1 (wherein M is at least one element selected from a group consisting of a transition metal element other than Ni, Co, Mn, a II group element, and a XIII group element, 0.15?0.25, 0.15?y1?0.25, 0?z1?0.1), the nickel composite hydroxide having a cobalt or manganese rich layer from a surface of a particle of the secondary particles toward an inside of the secondary particles and a layered low-density layer between the cobalt or manganese rich layer and a center of the particle of the secondary particles, and a thickness of the cobalt or manganese rich layer and low-density layer is 1% or more and 10% or less to a diameter of the secondary particles.Type: GrantFiled: April 24, 2020Date of Patent: February 25, 2025Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Mitsuru Yamauchi, Tai Ito, Tetsufumi Komukai
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Patent number: 12224436Abstract: Disclosed are a cathode active material for a lithium secondary battery and a lithium secondary battery including the same. The cathode active material includes a secondary particle in which a plurality of primary particles are agglomerated, wherein the secondary particle has a predetermined arrangement structure in which (003) surface of primary particles are aligned to be in a vertical direction with respect to a tangent line at a point (P) at which the (003) surface of the primary particles meet a surface of the secondary particle.Type: GrantFiled: January 29, 2019Date of Patent: February 11, 2025Assignee: Samsung SDI Co., Ltd.Inventors: Jongmin Kim, Soohyeon Kim, Jinhwa Kim, Pilsang Yun
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Patent number: 12224398Abstract: Provided is an all-solid-state sodium ion secondary battery in which electrode layers are difficult to peel from a solid electrolyte layer and which has excellent cycle characteristics. An all-solid-state sodium ion secondary battery 1 according to the present invention includes: a solid electrolyte layer 2 having a first principal surface 2a and a second principal surface 2b opposite each other and made of a sodium ion-conductive oxide; a positive electrode layer 3 provided on the first principal surface 2a of the solid electrolyte layer 2; and a negative electrode layer 4 provided on the second principal surface 2b of the solid electrolyte layer 2, wherein at least one of the first principal surface 2a and the second principal surface 2b has an arithmetic mean roughness Ra of 0.05 ?m or more.Type: GrantFiled: June 7, 2018Date of Patent: February 11, 2025Assignee: NIPPON ELECTRIC GLASS CO., LTD.Inventor: Hideo Yamauchi
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Patent number: 12218352Abstract: The disclosure provides a plurality of particles. Each particle may include a material comprising 0.95 to 1.30 mole fraction Li, at least 0.60 and less than 1.00 mole fraction Co, up to 10,000 ppm Al, 1.90 to 2.10 mole fraction O, and up to 0.30 mole fraction M, where M is at least one element selected from B, Na, Mg, P, Ti, Ca, V, Cr, Fe, Mn, Ni, Cu, Zn, Al, Sc, Y, Ga, Zr, Ru, Mo, La, Si, Nb, Ge, In, Sn, Sb, Te, and Ce. Each particle may also include a surface composition comprising a mixture of LiF and a metal fluoride. An amount of fluorine (F) is greater than 0 and less than or equal to 5000 ppm. The metal fluoride comprises a material selected from the group consisting of AlF3, CaF2, MgF2, and LaF2. The surface composition may also include a metal oxide comprising a material selected from the group consisting of TiO2, MgO, La2O3, CaO, and Al2O3. An amount of the metal oxide is greater than 0 and less than or equal to 20000 ppm.Type: GrantFiled: April 9, 2021Date of Patent: February 4, 2025Assignee: Apple Inc.Inventors: Hongli Dai, Huiming Wu, Chi-Kai Lin, Michael J. Erickson, Martin Bettge, Xiaoping Wang, Yan Li, Yanjie Cui, James A. Gilbert, Zhenzhen Yang, Anh D. Vu, Arthur Jeremy Kropf, Hakim H. Iddir, Christopher S. Johnson, John David Carter
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Patent number: 12211993Abstract: A positive electrode active material for a secondary battery includes a center part and a covering part. The center part includes a layered rock-salt lithium-nickel composite oxide. The covering part covers a surface of the center part and includes a boron compound. The positive electrode active material has a crystallite size of a (104) plane that is greater than or equal to 40.0 nm and less than or equal to 74.5 nm. The crystallite size is calculated by X-ray diffractometry and Scherrer equation. The positive electrode active material has a specific surface area that satisfies a condition represented by ?0.0160×Z+1.72?A??0.0324×Z+2.94 where Z is the crystallite size (nm), and A is the specific surface area (m2/g). The specific surface area is measured by BET specific surface area measurement method.Type: GrantFiled: August 4, 2021Date of Patent: January 28, 2025Assignee: Murata Manufacturing Co., Ltd.Inventors: Atsushi Ouki, Susumu Endo, Shinji Hayazaki, Sho Takahashi, Takashige Fujikawa, Masaki Kuratsuka
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Patent number: 12206101Abstract: Cation-stabilized materials and compositions are described herein, which suppress the structural and electrochemical instability of lithium-metal-oxide spinel and lithiated lithium-metal-oxide spinel electrodes for lithium batteries, notably lithium-ion batteries. The lithium metal oxide electrode material comprises a disordered rock salt structure with partial lithiated-spinel character, wherein, for example, the disordered rock salt structure comprises a formula Li2(M?2-aM??a)O4, which has the crystallographic formula: [Li2-bM??b]16c[M?2-aM??a-bLib]16dO4 wherein 16c and 16d refer to the octahedral sites of the prototypic space group symmetry Fd3m; M? and M?? are metal ions; 0<a?0.5; and 0<b<0.5. These stabilized materials are useful as positive electrodes for lithium batteries in their own right or when used as a structural component to stabilize layered metal oxide electrode systems, such as a two-component layered-layered system or a multi-component layered-layered-spinel system.Type: GrantFiled: March 17, 2021Date of Patent: January 21, 2025Assignee: UCHICAGO ARGONNE, LLCInventors: Michael M. Thackeray, Eungje Lee, Jason R. Croy
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Patent number: 12206105Abstract: Disclosed is a positive electrode material for a high-power lithium ion battery. The positive electrode material is in form of secondary particles with a hollow microsphere structure, and a shell of the secondary particles is formed by aggregating a plurality of primary particles. The secondary particles have a uniform particle size, a loose and porous surface, and a large specific surface area. The obtained particles are regular in shape, stable in material structure, so that the positive electrode material has high rate performance and excellent cycle performance.Type: GrantFiled: May 12, 2020Date of Patent: January 21, 2025Assignees: Minmetals New Energy Materials(Hunan) Co., Ltd., JINCHI ENERGY MATERIALS CO., LTD.Inventors: Xin Guo, Haishi Hu, Zhibing Hu, Chenghuan Huang, Haiyan Zhang, Youyuan Zhou
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Patent number: 12195352Abstract: Provided is a cathode active material for a non-aqueous electrolyte secondary battery that improves the cycling characteristic and high-temperature storability without impairing the charge/discharge capacity and the output characteristics. A nickel cobalt containing composite hydroxide is obtained by using a batch type crystallization method in which a raw material aqueous solution that includes Ni, Co and Mg is supplied in an inert atmosphere to a reaction aqueous solution that is controlled so that the temperature is within the range 45° C. to 55° C., the pH value is within the range 10.8 to 11.8 at a reference liquid temperature of 25° C., and the ammonium-ion concentration is within the range 8 g/L to 12 g/L. An Al-coated composite hydroxide that is expressed by the general formula: Ni1-x-y-zCoxAlyMgz(OH)2 (where, 0.05?x?0.20, 0.01?y?0.06, and 0.01?z?0.Type: GrantFiled: October 29, 2020Date of Patent: January 14, 2025Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Takehide Honma, Koji Yamaji, Ryozo Ushio
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Patent number: 12194661Abstract: A method of and apparatus for sinter forging a precursor powder to form a film may reduce or eliminate the stress in the film and may facilitate processing of continuous length of films such as ceramic films for use in batteries. The precursor powder can be provided on a substrate and is simultaneously heated and pressed in a pressing direction parallel to a thickness of the film so as to sinter and densify the precursor powder to form the film in a sinter forging area. Notably, in a plane perpendicular to the pressing direction, there are no lateral constraints on the sinter forging area or the material received therein.Type: GrantFiled: February 1, 2021Date of Patent: January 14, 2025Assignee: THE REGENTS OF THE UNIVERSITY OF MICHIGANInventors: Jeffrey Sakamoto, Michael Wang, Nathan Taylor
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Patent number: 12191487Abstract: Provided is a positive active material for a nonaqueous electrolyte secondary battery which contains a lithium transition metal composite oxide, the lithium transition metal composite oxide having an ?-NaFeO2 structure, containing Ni, Co and Mn as a transition metal (Me), and having an X-ray diffraction pattern attributable to a space group R3-m, in which a ratio of the full width at half maximum of a diffraction peak of the (003) plane to the full width at half maximum of a diffraction peak of the (104) plane, (003)/(104) at a Miller index hkl in X-ray diffraction measurement using a CuK? ray is 0.810 to 0.865, and a crystallite size is 410 ? or more.Type: GrantFiled: July 3, 2020Date of Patent: January 7, 2025Assignee: GS Yuasa International Ltd.Inventors: Daisuke Yoshikawa, Shinya Otani
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Patent number: 12191502Abstract: Described are aqueous rechargeable hydrogen batteries operating in the full pH range (e.g., pH: ?1 to 15) with potential for electrical grid storage. The pH-universal hydrogen batteries operate with different redox chemistry on the cathodes and reversible hydrogen evolution/oxidation reactions (HER/HOR) on the anode. The reactions can be catalyzed by a highly active ruthenium-based electrocatalyst. The ruthenium-based catalysts exhibit comparable specific activity and superior long-term stability of HER/HOR to that of state-of-the-art Pt/C electrocatalyst in the full pH range. New chemistries for aqueous rechargeable hydrogen batteries are also provided.Type: GrantFiled: April 2, 2019Date of Patent: January 7, 2025Assignees: EENOTECH, INC., The Board of Trustees of the Leland Stanford Junior UniversityInventors: Wei Chen, Yi Cui
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Patent number: 12183519Abstract: A method for producing an electrolytic capacitor, the electrolytic capacitor including a capacitor element including an anode body and a cathode body each having a foil shape. The anode body includes a dielectric layer on a surface of the anode body. The method includes a step of forming a capacitor element precursor by winding or stacking a separator, the anode body, and the cathode body with the separator interposed between the anode body and the cathode body, a step of impregnating the capacitor element precursor with a treatment liquid containing an acid component, a solvent, and a conductive polymer component, a step of impregnating the capacitor element precursor with a liquid component after the step of impregnating the capacitor element precursor with the treatment liquid, and a step of forming the capacitor element by eluting the acid component into the liquid component.Type: GrantFiled: September 5, 2022Date of Patent: December 31, 2024Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Yoshiaki Ishimaru, Takayuki Matsumoto, Tatsuji Aoyama
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Patent number: 12183921Abstract: Provided herein are positive electrode active substance particles comprising a lithium nickelate composite oxide which have a high energy density and are excellent in repeated charge/discharge cycle characteristics when charging at a high voltage, as well as a non-aqueous electrolyte secondary battery. The positive electrode active substance particles herein can each comprise a core particle X comprising a lithium nickelate composite oxide having a layer structure which is represented by the formula: Li1+aNi1-b-cCObMcO2, as defined herein; and a coating compound Y comprising at least one element selected from the group consisting of Al, Mg, Zr, Ti and Si and having an average film thickness of 0.2 to 5 nm, in which a crystal phase having a layered rock salt structure and comprising Ni2+ ions is present in the form of a layer between the core particle X and the coating compound Y.Type: GrantFiled: March 1, 2019Date of Patent: December 31, 2024Assignee: TODA KOGYO CORP.Inventors: Hiroyasu Watanabe, Xiang Sun, Mitchell Fetterer
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Patent number: 12172906Abstract: A precursor for lithium secondary battery positive electrode active materials containing at least nickel, in which the following formula (1) is satisfied. 0.20?Dmin/Dmax??(1) (in the formula (1), Dmin is a minimum particle diameter (?m) in a cumulative particle size distribution curve obtained by measuring the precursor for lithium secondary battery positive electrode active materials with a laser diffraction-type particle size distribution measuring instrument, and Dmax is a maximum particle diameter (?m) in the cumulative particle size distribution curve obtained by the measurement with the laser diffraction-type particle size distribution measuring instrument.).Type: GrantFiled: December 6, 2019Date of Patent: December 24, 2024Assignees: SUMITOMO CHEMICAL COMPANY, LIMITED, TANAKA CHEMICAL CORPORATIONInventors: Keiji Degura, Ryota Kobayashi, Yusuke Maeda
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Patent number: 12176539Abstract: A negative electrode active material for a lithium ion secondary battery includes graphite particles for which an R value measured by Raman spectrometry is less than 0.27, and an intensity ratio (P1/P2) of a diffraction peak (P1) on a hexagonal structure (101) plane to a diffraction peak (P2) on a rhombohedral structure (101) plane in an X-ray diffraction pattern by CuK? ray is 5.0 or less.Type: GrantFiled: January 4, 2019Date of Patent: December 24, 2024Assignee: RESONAC CORPORATIONInventors: Wakana Okamura, Kento Hoshi
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Patent number: 12176533Abstract: In one arrangement, the present disclosure relates to a positive electrode active material including a nickel-cobalt-manganese-based lithium transition metal oxide which contains nickel in an amount of 60 mol % or more based on a total number of moles of metals excluding lithium, wherein the nickel-cobalt-manganese-based lithium transition metal oxide is doped with doping element M1 (where the doping element M1 is a metallic element including Al) and doping element M2 (where the doping element M2 is at least one metallic element selected from the group consisting of Mg, La, Ti, Zn, B, W, Ni, Co, Fe, Cr, V, Ru, Cu, Cd, Ag, Y, Sc, Ga, In, As, Sb, Pt, Au, and Si), where the doping element M1 can be in an amount of 100 ppm to 10,000 ppm, and the doping element M1 and the doping element M2 are included in a weight ratio of 50:50 to 99:1.Type: GrantFiled: November 1, 2019Date of Patent: December 24, 2024Assignee: LG Energy Solution, Ltd.Inventors: Wen Xiu Wang, Wang Mo Jung, Min Suk Kang, Sang Wook Lee, So Ra Baek, Eun Sol Lho
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Patent number: 12170367Abstract: A method of preparing a positive electrode active material precursor for a secondary battery includes preparing a positive electrode active material precursor by a co-precipitation reaction while adding a transition metal-containing solution containing transition metal cations, a basic solution, and an ammonium solution to a batch-type reactor, wherein a molar ratio of ammonium ions contained in the ammonium solution to the transition metal cations contained in the transition metal-containing solution added to the batch-type reactor is 0.5 or less, and a pH in the batch-type reactor is maintained at 11.2 or less.Type: GrantFiled: September 25, 2020Date of Patent: December 17, 2024Assignee: LG Chem, Ltd.Inventors: Min Joon Lee, Seung Beom Cho, Seong Ji Ye, Yoon Bin Park
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Patent number: 12170368Abstract: A method of manufacturing a positive electrode active material for a lithium-ion secondary battery includes a water-washing step of washing a lithium-nickel composite oxide containing Li, Ni, and an element M with water, and conducting a filtration to form a washed-cake, a mixing step of mixing, while heating, the washed-cake and a tungsten compound without lithium while heating to obtain a tungsten mixture, and a heat treatment step of heat-treating the tungsten mixture, wherein a water content of the washed-cake is 3.0% by mass or more and 10.0% by mass or less, a ratio of a number of tungsten atoms contained in the tungsten mixture to a total number of nickel and the element M atoms contained in the lithium-nickel composite oxide is 0.05 at. % or more and 3.00 at. % or less, and a temperature of the mixing step is 30° C. or higher and 70° C. or lower.Type: GrantFiled: February 18, 2020Date of Patent: December 17, 2024Assignees: SUMITOMO METAL MINING CO., LTD., Panasonic Energy Co., Ltd.Inventor: Shuhei Oda
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Patent number: 12166205Abstract: A positive electrode active substance, wherein: the average primary particle diameter of an Ni-containing lithium complex oxide A is 0.5 ?m or greater, and is greater than the average primary particle diameter (0.05 ?m or greater) of an Ni-containing lithium complex oxide B; and the average secondary particle diameter of the Ni-containing lithium complex oxide A is 2-6 ?m, and is less than the average secondary particle diameter (10-20 ?m) of the Ni-containing lithium complex oxide B. The Ni-containing lithium complex oxides A, B contain 55 mol % or more of Ni relative to the total mol of metal elements excluding Li, have a crystallite diameter of 100-200 nm, and are such that the disorder of elemental Ni is 3% or less.Type: GrantFiled: March 15, 2019Date of Patent: December 10, 2024Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventor: Hidekazu Hiratsuka
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Patent number: 12156414Abstract: A conductive film contains a carbon material, a polymeric compound, and alkali metal atoms. The content of the polymeric compound is not less than 5 mass % and not more than 40 mass %, and the content of the alkali metal atoms is not less than 5.0 mass % and not more than 15.0 mass %.Type: GrantFiled: January 14, 2020Date of Patent: November 26, 2024Assignee: ZEON CORPORATIONInventor: Takumi Sugimoto
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Patent number: 12155047Abstract: In an aspect, provided is an alkaline rechargeable battery comprising: i) a battery container sealed against the release of gas up to at least a threshold gas pressure, ii) a volume of an aqueous alkaline electrolyte at least partially filling the container to an electrolyte level; iii) a positive electrode containing positive active material and at least partially submerged in the electrolyte; iv) an iron negative electrode at least partially submerged in the electrolyte, the iron negative electrode comprising iron active material; v) a separator at least partially submerged in the electrolyte provided between the positive electrode and the negative electrode; vi) an auxiliary oxygen gas recombination electrode electrically connected to the iron negative electrode by a first electronic component, ionically connected to the electrolyte by a first ionic pathway, and exposed to a gas headspace above the electrolyte level by a first gas pathway.Type: GrantFiled: March 13, 2023Date of Patent: November 26, 2024Assignee: FORM ENERGY, INC.Inventors: Ai Quoc Pham, Sandeep Nijhawan, Aswin K. Manohar, Kevin Van Galloway, Chenguang Yang, Eric E. Benson, Lang McHardy, Tim Rackers
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Patent number: 12148924Abstract: An anode active material for a non-aqueous electrolyte secondary battery, including: an aluminum phase; and a non-aluminum metal phase dispersed in the aluminum phase, in which the non-aluminum metal phase is formed of a non-aluminum metal compound containing one or more selected from the group consisting of Si, Ge, Sn, Ag Sb, Bi, In, and Mg, and an amount of the non-aluminum metal phase with respect to a total amount of the aluminum phase and the non-aluminum metal phase is 0.01 mass % or more and 8 mass % or less.Type: GrantFiled: October 17, 2019Date of Patent: November 19, 2024Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Takitaro Yamaguchi, Hiroaki Hoshikawa, Toshiaki Kumagai
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Patent number: 12148892Abstract: The present disclosure relates to a method of recovering a degenerated lithium battery cell, with the lithium battery cell being configured so that an electrode assembly including a positive electrode, a negative electrode and a separator interposed therebetween is impregnated with a non-aqueous electrolyte and embedded in a battery case, the method including: subjecting a lithium battery cell degenerated by 5% or more to a high temperature treatment for 1 to 6 hours at a temperature ranging from 60° C. to 100° C. in a fully discharged state.Type: GrantFiled: June 25, 2020Date of Patent: November 19, 2024Assignee: LG Energy Solution, Ltd.Inventors: Hyunjun Choi, Youngdeok Kim, Daesoo Kim
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Patent number: 12140639Abstract: A measurement device of a negative electrode SEI formation amount of a lithium ion battery includes a charge/discharge controller configured to perform charge/discharge control of the lithium ion battery, a voltage measurement part configured to measure a discharge voltage of the lithium ion battery, a current measurement part configured to measure a discharge current of the lithium ion battery, a discharge time measurement part configured to measure a discharge time of the lithium ion battery, a storage configured to store measurement results of the voltage measurement part, the current measurement part and the discharge time measurement part, and a calculation part configured to calculate a negative electrode SEI formation amount of the lithium ion battery.Type: GrantFiled: February 22, 2023Date of Patent: November 12, 2024Assignee: HONDA MOTOR CO., LTD.Inventors: Tadashi Kaga, Yuki Tominaga, Mao Hori
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Patent number: 12132202Abstract: This application relates to a cathode active material for a lithium secondary battery, a method of preparing the cathode active material, a cathode employing the cathode active material, and a lithium secondary battery employing the cathode. The cathode active material may include a secondary particle in which primary particles are aggregated and a first coating layer disposed on the plurality of primary particles to have a thickness of about 2.5 nm or less and including a NiO-like crystalline phase belonging to a Fm3-m space group. The cathode active material may prevent surface deterioration through a washing process using a weakly acidic or neutral organic buffer, thereby improving the initial efficiency characteristic and life characteristics of the lithium secondary battery while maintaining the initial capacity of the lithium secondary battery.Type: GrantFiled: October 27, 2020Date of Patent: October 29, 2024Assignee: SAMSUNG SDI CO., LTD.Inventors: Dongwook Shin, Jinhwan Park
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Patent number: 12132199Abstract: A positive electrode active material includes a core including a first lithium complex metal oxide, and a shell located surrounding the core and including a second lithium complex metal oxide, and further includes a buffer layer located between the core and the shell. The buffer layer includes a pore, and a three-dimensional network structure of a third lithium complex metal oxide which is connecting the core and the shell. Accordingly, the positive electrode active material is capable of enhancing an output property and a life property by minimizing destruction of the active material caused by a rolling process during the electrode preparation, maximizing reactivity with an electrolyte liquid, and by the particles that form the shell having a crystal structure with orientation facilitating lithium ion intercalation and deintercalation.Type: GrantFiled: June 8, 2023Date of Patent: October 29, 2024Assignee: LG Energy Solution, Ltd.Inventors: Byung Chun Park, Hong Kyu Park, Wang Mo Jung, Seong Hoon Kang
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Patent number: 12129185Abstract: Disclosed is an ?-phase nickel hydroxide and a preparation method and use thereof. The method for preparing an ?-phase nickel hydroxide comprises the following steps: subjecting a biomass calcium source to a calcination to obtain a porous calcium oxide; under a protective atmosphere, mixing the porous calcium oxide with a first methanol-ethanol solvent to obtain a calcium oxide heterogeneous solution; under a protective atmosphere, mixing the calcium oxide heterogeneous solution with a nickel source homogeneous solution to obtain a mixture, and subjecting the mixture to a coprecipitation to obtain a nickel calcium hydroxide precursor, wherein the nickel source homogeneous solution is prepared with a nickel source containing crystal water as a solute and a second methanol-ethanol solvent as a solvent; and subjecting the nickel calcium hydroxide precursor to a calcium hydroxide removal treatment to obtain the ?-phase nickel hydroxide.Type: GrantFiled: June 22, 2022Date of Patent: October 29, 2024Assignee: Fuzhou UniversityInventors: Yan Yu, Zanyong Zhuang, Linxin Zhou, Bixia Yang
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Patent number: 12119492Abstract: A positive electrode active material for an all-solid-state lithium ion secondary battery includes a lithium-nickel composite oxide particle and a coating layer coating a surface of the particle. The lithium-nickel composite oxide particle has a crystal structure belonging to a space group R-3m, contains at least Li, Ni, an element M, and Nb, a molar ratio among the elements being represented by Li:Ni:M:Nb=a:(1-x-y):x:y (0.98?a?1.15, 0<x?0.5, 0<y?0.03, 0<x+y?0.5, and the element M, has a crystallite diameter of 140 nm or less, and has an eluted lithium ion amount of 0.30% by mass or more and 1.00% by mass or less. The coating layer is a composite oxide containing Li and at least one element.Type: GrantFiled: July 29, 2021Date of Patent: October 15, 2024Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Hitomi Nakamura, Ryosuke Okamoto, Kazuhide Hayashi, Mikako Toma
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Patent number: 12119491Abstract: A method of preparing a bimodal positive electrode active material precursor and a positive electrode active material prepared from the same are disclosed herein. In some embodiments, the method includes inputting a first reaction source material including a first aqueous transition metal solution into a reactor, precipitating at pH 12 or more to induce nucleation of a first positive electrode active material precursor particle, and at less than pH 12 to induce growth of the same, inputting a second reaction source material including a second aqueous transition metal solution into the reactor containing the first positive electrode active material precursor particle, precipitating at pH 12 or more to induce the nucleation of a second positive electrode active material precursor particle, and at less than pH 12 to induce simultaneous growth of the first and second positive electrode active material precursor particles, thereby preparing a bimodal positive electrode active material precursor.Type: GrantFiled: May 26, 2021Date of Patent: October 15, 2024Assignee: LG Chem, Ltd.Inventors: Ju Han Yoon, Kyoung Wan Park, Hyeon Jin Kim, Song Yi Yang, Young Su Park
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Patent number: 12119479Abstract: An anode for an all solid-state secondary battery, the anode including an anode collector, and coating lithium distribution layer disposed on the anode collector, wherein the lithium distribution layer includes a metal capable of forming an alloy with lithium.Type: GrantFiled: September 10, 2021Date of Patent: October 15, 2024Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Satoshi Fujiki, Seitaro Ito, Taku Watanabe, Yuichi Aihara, Takanobu Yamada
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Patent number: 12113196Abstract: The present invention provides a method of manufacturing a positive electrode active material for a lithium ion secondary battery. The method includes a water-washing step of washing a lithium-nickel composite oxide containing lithium (Li), nickel (Ni), and an element M (M) (wherein, the element M is at least one element selected from Mn, V, Mg, Mo, Nb, T, Co, and Al) with water, and conducting a filtration to form a washed cake; a filling step of filling, the washed cake which is a material to be dried and a tungsten compound without lithium into a dryer; and a drying step of drying the material to be dried by the dryer with flowing, wherein the filling step includes a time period in which the washed cake and the tungsten compound without lithium are supplied to the dryer at the same time.Type: GrantFiled: February 18, 2020Date of Patent: October 8, 2024Assignees: SUMITOMO METAL MINING CO., LTD., Panasonic Energy Co., Ltd.Inventor: Shuhei Oda
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Patent number: 12107253Abstract: The present disclosure relates to battery plates which are useful in optimizing the power and energy density of a batter assembly by having discrete active materials. The present disclosure relates to a battery plate having: a) a substrate having a first surface opposing a second surface; b) one or more active materials disposed on the first surface, second surface, or both the first surface and the second surface of the substrate; and wherein the one or more active materials include two or more discrete active material regions.Type: GrantFiled: November 15, 2019Date of Patent: October 1, 2024Assignee: Advanced Battery Concepts, LLCInventors: Edward O. Shaffer, II, Maria Penafrancia Roma, Reed A. Shick
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Patent number: 12087946Abstract: The present invention relates to a positive electrode active material which makes it possible to improve the electrochemical properties and stability of a positive electrode active material including a lithium composite oxide by adjusting the direction of a concentration gradient of a metal element of the lithium composite oxide, and a lithium secondary battery using a positive electrode including the positive electrode active material.Type: GrantFiled: July 22, 2021Date of Patent: September 10, 2024Assignee: ECOPRO BM CO., LTD.Inventors: Gwang Seok Choi, Moon Ho Choi, Jun Won Suh, Jin Kyeong Yun, Jung Han Lee, Seung Woo Choi, Joong Ho Bae, Du Yeol Kim
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Patent number: 12087971Abstract: The present disclosure relates to a power supply assembly and a method for manufacturing the same. The power supply assembly includes a negative electrode sheet, a separator, and a positive electrode sheet. The negative electrode sheet includes a negative tab, and the positive electrode sheet includes a positive tab, a positive electrode material covering a first foil, a first recess and a second recess. The first recess is formed by removing a positive electrode material covering a first region of the first foil and configured for receiving the positive tab, and a size of the first recess is larger than a size of the positive tab. The second recess is formed by removing a positive electrode material covering a second region of the first foil and configured for receiving the negative tab, and a size of the second recess is larger than a size of the negative tab.Type: GrantFiled: May 31, 2021Date of Patent: September 10, 2024Assignee: BEIJING XIAOMI MOBILE SOFTWARE CO., LTD.Inventors: Longfei Du, Hongbin Zheng, Xuewen Wei, Zongqiang Wang
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Patent number: 12087944Abstract: The present invention relates to a positive electrode active material for a lithium ion secondary battery, including: lithium-nickel-manganese composite oxide particles having a layered hexagonal crystal system, wherein, the lithium-nickel-manganese composite oxide is represented by the following general formula: Li1+tNiaMnbMcMgdO2+???(1) in which an element M in the general formula (1) is at least one element selected from Co, Ti, W, B, Mo, V, Nb, Ca, Al, Cr, Zr, and Ta; ?0.05?t?0.2, 0.50?a?0.95, 0.03?b?0.40, 0.02?c?0.40, 0.0005?d?0.05, a+b+c+d=1.0, and 0???0.5; wherein the lithium-nickel-manganese composite oxide particles contains secondary particles formed by aggregation of primary particles of the lithium-nickel-manganese composite oxide particles, and wherein lattice constants a and c of the lithium-nickel-manganese composite oxide as determined by an X-ray diffraction method are 2.8640 ??a?2.8750 ? and 14.195 ??c?14.225 ?.Type: GrantFiled: July 30, 2019Date of Patent: September 10, 2024Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Haruki Kaneda, Yuki Koshika, Takuma Nakamura
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Patent number: 12087943Abstract: Provided is a precursor of a positive electrode active material containing, in a reduced amount, impurities which do not contribute to a charge/discharge reaction but rather corrode a firing furnace and peripheral equipment and thus having excellent battery characteristics and safety, and production method thereof. A method for producing a precursor of a positive electrode active material for nonaqueous electrolyte secondary batteries having a hollow structure or porous structure includes obtaining the precursor by washing nickel-manganese composite hydroxide particles having a particular composition ratio and a pore structure in which pores are present within the particles with an aqueous carbonate solution having a carbonate concentration of 0.1 mol/L or more.Type: GrantFiled: July 12, 2023Date of Patent: September 10, 2024Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Taira Aida, Hiroyuki Toya
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Patent number: 12080882Abstract: Provided are a cathode active material for a lithium secondary battery, a method of preparing the same, and a lithium secondary battery including a cathode including the cathode active material. The cathode active material includes: a secondary particle of a nickel-based active material, wherein the secondary particle including a plurality of primary particles, wherein the secondary particle includes a radial arrangement structure and an irregular porous structure, the radial arrangement structure is located closer to a surface of the secondary particle than the irregular porous structure, and a lithium fluoride-based compound is present on a surface of the nickel-based active material.Type: GrantFiled: October 5, 2021Date of Patent: September 3, 2024Assignee: Samsung SDI Co., Ltd.Inventors: Donggyu Chang, Jongmin Kim
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Patent number: 12071356Abstract: The present disclosure relates to the technical field of positive electrode materials of lithium ion batteries. Disclosed a positive electrode material having a multi-cavity structure and a preparation method therefor, and a lithium ion battery. The positive electrode material is formed by aggregation of a plurality of primary particles, and some of the primary particles grow in an oriented manner to form supporting structures, the supporting structures overlapping each other inside the positive electrode material to form a plurality of cavities. The particle strength of the positive electrode material is significantly improved, so that the positive electrode material has the advantage of a long service life. In addition, the impedance of the positive electrode material is reduced, thereby improving the power performance of the positive electrode material.Type: GrantFiled: May 11, 2022Date of Patent: August 27, 2024Assignee: Beijing Easpring Material Technology Co., LtdInventors: Yongqiang Zhang, Liguo Sun, Xuequan Zhang, Yafei Liu, Yanbin Chen
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Patent number: 12074338Abstract: A battery pack includes battery cell including the exhaust valve that opens when an internal pressure exceeds a set pressure and case housing battery cell. Case includes inner case housing battery cell and outer case incorporating inner case, inner case includes a plurality of inner smoke vent holes through which the exhaust gas ejected from the exhaust valve passes, and outer case includes a plurality of outer smoke vent holes through which the exhaust gas including passed through inner smoke vent holes passes. In a state where inner case is disposed in outer case, inner smoke vent holes and outer smoke vent holes are disposed at positions not facing each other, and inner smoke vent holes and outer smoke vent holes are opened at positions allowing the exhaust gas to pass in different directions.Type: GrantFiled: December 9, 2019Date of Patent: August 27, 2024Assignee: Panasonic Energy Co., Ltd.Inventors: Takeaki Wakabayashi, Kensaku Takeda
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Patent number: 12057577Abstract: A lithium complex oxide and method of manufacturing the same, more particularly, a lithium complex oxide effective in improving the characteristics of capacity, resistance, and lifetime with reduced residual lithium and with different interplanar distances of crystalline structure between a primary particle locating in an internal part of secondary particle and a primary particle locating on the surface part of the secondary particle, and a method of preparing the same.Type: GrantFiled: October 13, 2022Date of Patent: August 6, 2024Assignee: ECOPRO BM CO., LTD.Inventors: Moon Ho Choi, Jong Seung Shin, Dong Hee Kim, Suk Yong Jeon, Hyun Jong Yu, Kyoung Jun Lee, Young Nam Park