Nickel Component Is Active Material Patents (Class 429/223)
  • Patent number: 11728470
    Abstract: A negative electrode for an electrochemical cell of a secondary lithium metal battery is manufactured by a method in which a precursor solution is applied to a major surface of a lithium metal substrate to form a precursor coating thereon. The precursor solution includes an organophosphate, a nonpolar organic solvent, and a lithium-containing inorganic ionic compound dissolved therein. At least a portion of the nonpolar organic solvent is removed from the precursor coating to form a protective interfacial layer on the major surface of the lithium metal substrate. The protective interfacial layer exhibits a composite structure including a carbon-based matrix component and a lithium-containing dispersed component. The lithium-containing dispersed component is embedded in the carbon-based matrix component and includes a plurality of lithium-containing inorganic ionic compounds, e.g., lithium phosphate (Li3PO4) and lithium nitrate (LiNO3).
    Type: Grant
    Filed: December 21, 2020
    Date of Patent: August 15, 2023
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Xingcheng Xiao, Mengyuan Chen, Qinglin Zhang, Mei Cai
  • Patent number: 11721831
    Abstract: Metal-ion battery cells are provided that take advantage of the disclosed “doping” process. The cells may be fabricated from anode and cathode electrodes, a separator, and an electrolyte. A metal-ion additive may be incorporated into (i) one or more of the electrodes, (ii) the separator, or (iii) the electrolyte. The metal-ion additive provides additional donor ions corresponding to the metal ions stored and released by anode and cathode active material particles. An activation potential may then be applied to the anode and cathode electrodes to release the additional donor ions into the battery cell.
    Type: Grant
    Filed: August 21, 2014
    Date of Patent: August 8, 2023
    Assignee: Sila Nanotechnologies, Inc.
    Inventors: Gleb Yushin, Bogdan Zdyrko, Alexander Thomas Jacobs, Eugene Michael Berdichevsky
  • Patent number: 11721807
    Abstract: Provided is a nickel-based active material precursor for a lithium secondary battery, including: a secondary particle including a plurality of particulate structures, wherein each of the particulate structures includes a porous core portion and a shell portion including primary particles radially arranged on the porous core portion, and in 50% or more of the primary particles constituting a surface of the secondary particle, a major axis of each of the primary particles is aligned along a normal direction of the surface of the secondary particle. When the nickel-based active material precursor for a lithium secondary battery is used, it is possible to obtain a nickel-based active material which intercalates and deintercalates lithium and has a short diffusion distance of lithium ions.
    Type: Grant
    Filed: August 13, 2019
    Date of Patent: August 8, 2023
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Doyu Kim, Wooyoung Yang
  • Patent number: 11715823
    Abstract: An electrode structure includes a base layer including a first active material, and a plurality of active material plates on a first surface of the base layer and spaced apart from one another, the plurality of active material plates including a second active material. An active material density of the base layer is less than an active material density of an active material plate of the plurality of active material plates.
    Type: Grant
    Filed: October 21, 2019
    Date of Patent: August 1, 2023
    Assignee: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Hwiyeol Park, Huisu Jeong, Kyounghwan Kim, Jeongkuk Shon, Junhyeong Lee, Sungjin Lim, Jin S. Heo
  • Patent number: 11682755
    Abstract: A positive active material for a rechargeable lithium battery includes a first positive active material including a secondary particle including at least two agglomerated primary particles, where at least one part of the primary particles has a radial arrangement structure, as well as a second positive active material having a monolith structure. The first and second positive active materials may both include nickel-based positive active materials. A method of preparing the positive active material, and a rechargeable lithium battery including a positive electrode including the positive active material are also provided.
    Type: Grant
    Filed: October 16, 2020
    Date of Patent: June 20, 2023
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Jongmin Kim, Jiyoon Kim, Jinhwa Kim
  • Patent number: 11682761
    Abstract: A nickel hydroxide includes stacked nickel hydroxide layers. Each of the nickel hydroxide layers includes Ni2+ and OH?. At least one of the nickel hydroxide layers further includes a type of polyatomic anions. The polyatomic anions include a type of anions that are not SO42? or CO32?.
    Type: Grant
    Filed: June 26, 2020
    Date of Patent: June 20, 2023
    Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, NATIONAL RESEARCH COUNCIL OF CANADA
    Inventors: Kenji Takahashi, Christina Bock, Nafiseh Ebrahimi, Olga Naboka
  • Patent number: 11682803
    Abstract: A sulfide all-solid-state battery which is capable of absorbing heat by a heat absorbing layer at abnormal heat generation and maintaining capacity of a battery at a high level for a long time use is provided. The sulfide all-solid-state battery contains at least one unit cell, at least one heat absorbing layer, a battery case which accommodates the unit cell and the heat absorbing layer, the unit cell contains sulfide solid electrolyte, the heat absorbing layer contains at least one organic heat absorbing material selected from the group consisting of sugar alcohols and hydrocarbons, and the heat absorbing layer does not contain an inorganic hydrate.
    Type: Grant
    Filed: October 18, 2017
    Date of Patent: June 20, 2023
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Hajime Hasegawa, Yuki Matsushita, Yusuke Okuhata, Mitsuru Tateishi
  • Patent number: 11670768
    Abstract: A nickel-based active material precursor for a lithium secondary battery includes: a secondary particle including a plurality of particulate structures, wherein each particulate structure includes a porous core portion and a shell portion, the shell portion including primary particles radially arranged on the porous core portion; and the secondary particle has a plurality of radial centers. When the nickel-based active material precursor is used, a nickel-based positive active material having a short lithium ion diffusion distance, in which intercalation and deintercalation of lithium are facilitated, may be obtained. A lithium secondary battery manufactured using the positive active material may exhibit enhanced lithium availability, and may exhibit enhanced capacity and lifespan due to suppression of crack formation in the active material during charging and discharging.
    Type: Grant
    Filed: June 25, 2019
    Date of Patent: June 6, 2023
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Pilsang Yun, Jangsuk Hyun, Wooyoung Yang
  • Patent number: 11670760
    Abstract: The present invention is directed towards a process for making a lithiated transition metal oxide, said process comprising the following steps: (a) providing a precursor selected from mixed oxides, hydroxides, oxyhydroxides, and carbonates of nickel and at least one transition metal selected from manganese and cobalt, wherein at least 45 mole-% of the cations of the precursor are Ni cations, (b) mixing said precursor with at least one lithium salt selected from LiOH, Li2O, Li2CO3, and LiNO3, thereby obtaining a mixture, (c) adding at least one phosphorus compound of general formula (I) XyH3-yPO4??(I) wherein X is selected from NH4 and Li, y is 1 or 2, to the mixture obtained in step (b), wherein steps (b) and (c) may be performed consecutively or simultaneously, (d) treating the mixture so obtained at a temperature in the range of from 650 to 950° C.
    Type: Grant
    Filed: March 4, 2020
    Date of Patent: June 6, 2023
    Inventors: Aleksei Volkov, Martin Schulz-Dobrick, Simon Schroedle, Jordan Lampert
  • Patent number: 11670758
    Abstract: An alkaline secondary battery negative electrode and a composition forming the negative electrode, containing an active material, a binder resin, and an electrically conductive agent containing an electrically conductive carbon material. When a value of D50 is defined to be an average particle size X and a value of D20 is defined to be a particle size Y in a cumulative particle size distribution obtained by measuring the active material using a laser diffractometry particle size distribution meter, the average particle size X is 10 ?m or less, and the particle size Y is in the range of 30% to 70% of the average particle size X.
    Type: Grant
    Filed: October 28, 2020
    Date of Patent: June 6, 2023
    Assignee: TOPPAN PRINTING CO., LTD.
    Inventor: Masahiro Serikawa
  • Patent number: 11664488
    Abstract: A positive electrode active material which can improve cycle characteristics of a secondary battery is provided. Two kinds of regions are provided in a superficial portion of a positive electrode active material such as lithium cobaltate which has a layered rock-salt crystal structure. The inner region is a non-stoichiometric compound containing a transition metal such as titanium, and the outer region is a compound of representative elements such as magnesium oxide. The two kinds of regions each have a rock-salt crystal structure. The inner layered rock-salt crystal structure and the two kinds of regions in the superficial portion are topotaxy; thus, a change of the crystal structure of the positive electrode active material generated by charging and discharging can be effectively suppressed.
    Type: Grant
    Filed: March 7, 2022
    Date of Patent: May 30, 2023
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventors: Teruaki Ochiai, Takahiro Kawakami, Mayumi Mikami, Yohei Momma, Masahiro Takahashi, Ayae Tsuruta
  • Patent number: 11658342
    Abstract: A non-aqueous electrolyte solution and a lithium secondary battery including the same are disclosed herein. In some embodiments, the non-aqueous electrolyte solution includes an ionic solution containing at least one anion selected from the group consisting of a bis(fluorosulfonyl)imide anion and a bis(trifluoromethane)sulfonylimide anion, a cation, a non-aqueous solvent, a lithium salt, a phosphite-based additive, and a surfactant including an oligomer represented by Formula 1.
    Type: Grant
    Filed: March 6, 2019
    Date of Patent: May 23, 2023
    Inventors: Won Kyung Shin, Kyoung Ho Ahn, Chul Haeng Lee, Jeong Woo Oh
  • Patent number: 11646415
    Abstract: The present application discloses a secondary battery and a battery module, a battery pack and an apparatus containing the secondary battery.
    Type: Grant
    Filed: December 10, 2021
    Date of Patent: May 9, 2023
    Assignee: Contemporary Amperex Technology Co., Limited
    Inventors: Maohua Li, Chuanmiao Yan, Xin Sun
  • Patent number: 11637285
    Abstract: The present disclosure relates to over-lithiated positive electroactive materials for use within an electrochemical cell. For example, the electrochemical cell includes a positive electrode that includes an over-lithiated positive electroactive material that includes one of LixMn2O4 (where 1.05?x?1.30) and LiMn(2?x)NixO4 (where 0?x?0.5). The electrochemical cell can include a negative electrode that includes a silicon-containing negative electroactive material having a Columbic Efficiency greater than or equal to about 80% and less than or equal to about 90%.
    Type: Grant
    Filed: October 2, 2020
    Date of Patent: April 25, 2023
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Mary E. Fortier, Bing Tan, Li Yang, Umamaheswari Viswanathan, Vijay P. Saharan, Sherman H. Zeng
  • Patent number: 11637272
    Abstract: An active material and a surface treatment method of the active material are provided. A surface of the active material may be treated with a coating layer including a first metal oxide containing lithium, and a second metal oxide.
    Type: Grant
    Filed: September 19, 2017
    Date of Patent: April 25, 2023
    Assignee: SM LAB CO., LTD.
    Inventors: Jae Phil Cho, Seung Jun Myeong
  • Patent number: 11637323
    Abstract: A lithium battery including: a cathode; an anode; and an electrolyte between the cathode and the anode, wherein the electrolyte includes a lithium salt and a non-aqueous solvent including ethylene carbonate (EC), an amount of the EC per 100 parts by volume of the non-aqueous solvent is about 5 parts by volume to about 15 parts by volume, and wherein the cathode includes a cathode active material represented by Formula 1, LixNiyM1-yO2-zAz??Formula 1 wherein, in Formula 1, 0.9?x?1.2, 0.7?y?0.98, and 0?z?0.2, M is Al, Mg, Mn, Co, Fe, Cr, V, Ti, Cu, B, Ca, Zn, Zr, Nb, Mo, Sr, Sb, W, Bi, or a combination thereof, and A is an element having an oxidation number of ?1 or ?2, wherein each element of M is independently present in an amount of 0<(1?y)?0.3, wherein an total content of M is 0.02?(1?y)?0.3.
    Type: Grant
    Filed: October 15, 2019
    Date of Patent: April 25, 2023
    Assignees: SAMSUNG ELECTRONICS CO., LTD., SAMSUNG SDI CO., LTD.
    Inventors: Jihyun Jang, Myongchun Koh, Jinah Seo
  • Patent number: 11621418
    Abstract: A lithium complex oxide includes a mixture of first particles of n1 (n1>40) aggregated primary particles and second particles of n2 (n2?20) aggregated primary particles, the lithium complex oxide represented by Chemical Formula 1 and having FWHM (deg., 2?) of 104 peak in XRD, defined by a hexagonal lattice having R-3m space group, in a range of Formula 1: LiaNixCoyMnzM1-x-y-zO2,??[Chemical Formula 1] where M is selected from: B, Ba, Ce, Cr, F, Mg, Al, Cr, V, Ti, Fe, Zr, Zn, Si, Y, Nb, Ga, Sn, Mo, W, P, Sr, and any combination thereof, 0.9?a?1.3, 0.6?x?1.0, 0.0?y?=0.4, 0.0?z?0.4, and 0.0?1?x?y?z?0.4, ?0.025?FWHM(104)?{0.04+(xfirst particle?0.6)×0.25}?0.025,??[Formula 1] where FWHM(104) is represented by Formula 2, FWHM(104)={(FWHMChemical Formula 1 powder(104)?0.1×mass ratio of second particles)/mass ratio of first particles}?FWHMSi powder(220).
    Type: Grant
    Filed: October 30, 2020
    Date of Patent: April 4, 2023
    Assignee: ECOPRO BM CO., LTD.
    Inventors: Jung Han Lee, Seung Woo Choi, Moon Ho Choi, Jun Won Suh, Jin Kyeong Yun, Mi Hye Yun, Kwang Seok Choi, Joong Ho Bae, Jin Oh Son
  • Patent number: 11616230
    Abstract: A method of forming an improved calcined lithium metal oxide is provided wherein the metal comprises at least one of nickel, manganese and cobalt. The method comprises forming a first solution in a first reactor wherein the first solution comprises at least one first salt of at least one of lithium, nickel, manganese or cobalt in a first solvent. A second solution is formed wherein the second solution comprises a second salt of at least one of lithium, nickel, manganese or cobalt in a second solvent wherein the second salt is not present in the first solution. A gas in introduced into said first solution to form a gas saturated first solution. A second solution is added to the gas saturated first solution without bubbling to form a lithium metal salt. The lithium metal salt dried and calcined to form the calcined lithium metal oxide.
    Type: Grant
    Filed: April 12, 2022
    Date of Patent: March 28, 2023
    Assignee: Nano One Materials Corp.
    Inventors: Russell H. Barton, Yingzi Feng, Casey A. Larson, Majid Talebiesfandarani, Stephen A. Campbell, Daniel J. Blondal
  • Patent number: 11613474
    Abstract: The present application discloses a positive electrode active material including a lithium nickel cobalt manganese oxide, the molar content of nickel in the lithium nickel cobalt manganese oxide accounts for 60%-90% of the total molar content of nickel, cobalt and manganese, and the lithium nickel cobalt manganese oxide has a layered crystal structure of a space group R 3m; a transition metal layer of the lithium nickel cobalt manganese oxide includes a doping element, and the local mass concentration of the doping element in particles of the positive electrode active material has a relative deviation of 20% or less; and in a differential scanning calorimetry spectrum of the positive electrode active material in a 78% delithiation state, an initial exothermic temperature of a main exothermic peak is 200° C. or more, and an integral area of the main exothermic peak is 100 J/g or less.
    Type: Grant
    Filed: March 1, 2022
    Date of Patent: March 28, 2023
    Assignee: Contemporary Amperex Technology Co., Limited
    Inventors: Shushi Dou, Chunhua Hu, Yao Jiang, Qi Wu, Jinhua He, Bin Deng
  • Patent number: 11616235
    Abstract: Systems and methods for batteries comprising a cathode, an electrolyte, and an anode, wherein one or both electrodes contain a functional lithiated agent-containing additive.
    Type: Grant
    Filed: April 27, 2020
    Date of Patent: March 28, 2023
    Assignee: Enevate Corporation
    Inventors: Liwen Ji, Younes Ansari, Benjamin Park
  • Patent number: 11611074
    Abstract: The present invention relates to a positive active material for lithium secondary battery, its manufacturing method, and lithium secondary battery including the same, and it provides that a positive active material for lithium secondary battery, comprising: a core and a coating layer, wherein, the core is lithium metal oxide, the coating layer comprises boron, the boron compound in the coating layer comprises a lithium boron oxide and a boron oxide, the lithium boron oxide is included 70 wt % or more and 99 wt % in the entire coating layer, the lithium boron oxide comprises Li2B4O7, with respect to the lithium boron oxide 100 wt %, the content of Li2B4O7 is 55 wt % or more and 99 wt % or less.
    Type: Grant
    Filed: December 18, 2018
    Date of Patent: March 21, 2023
    Assignees: POSCO HOLDINGS INC., RESEARCH INSTITUTE OF INDUSTRIAL SCIENCE & TECHNOLOGY, POSCO CHEMICAL CO., LTD.
    Inventors: Sung Hwan Min, Jeong Han Kim, Jung Hoon Song
  • Patent number: 11611078
    Abstract: The present invention provides a positive active material for a rechargeable lithium battery, the active material including a dopant and having a crystalline structure in which metal oxide layers (MO layers) including metals and oxygen and reversible lithium layers are repeatedly stacked, wherein in a lattice configured by oxygen atoms of the MO layers adjacent to each other, the dopant time of charge, thereby forming a lithium trap and/or lithium dumbbell structure.
    Type: Grant
    Filed: June 8, 2021
    Date of Patent: March 21, 2023
    Inventors: Sung Bin Park, Young Uk Park, Ji Young Park, Bo Ram Lee, Chi Ho Jo, Young Cheol Choi, Hyuck Hur, Wang Mo Jung
  • Patent number: 11605811
    Abstract: A negative electrode active material including a core containing SiOx (0?x<2) and a lithium-containing compound, and a shell disposed on the core and containing SiOx (0?x<2) and magnesium silicate.
    Type: Grant
    Filed: January 30, 2019
    Date of Patent: March 14, 2023
    Assignee: LG ENERGY SOLUTION, LTD.
    Inventors: Su Min Lee, Yong Ju Lee, Rae Hwan Jo, Dong Hyuk Kim
  • Patent number: 11594733
    Abstract: Systems and methods utilizing aqueous-based polymer binders for silicon-dominant anodes may include an electrode coating layer on a current collector, where the electrode coating layer is formed from silicon and an aqueous-based suspension-solution binder composition comprising a water soluble (aqueous-based) polymer as part of a multi-component binder composition that also contains an water insoluble polymer. The electrode coating layer may include more than 70% silicon and the anode may be in a lithium ion battery.
    Type: Grant
    Filed: April 29, 2022
    Date of Patent: February 28, 2023
    Assignee: Enevate Corporation
    Inventors: Sanjaya Perera, Benjamin Yong Park, Rahul Kamath, Younes Ansari
  • Patent number: 11588153
    Abstract: A positive electrode active material for a non-aqueous electrolyte secondary battery according to an embodiment of the present disclosure is represented by a general formula of LixNiyM1-yO2 (where M includes at least one metal element selected from Co and Mn, 0.1?x?1.2, 0.3<y<1), has a volumetric average particle size (D50) of 7 ?m or more and 30 ?m or less, and has an average surface roughness of 4%, or less.
    Type: Grant
    Filed: February 13, 2020
    Date of Patent: February 21, 2023
    Assignee: PANASONIC HOLDINGS CORPORATION
    Inventor: Hidekazu Hiratsuka
  • Patent number: 11581535
    Abstract: A method for producing a positive electrode active material, a positive electrode active material produced thereby, and a positive electrode and a lithium secondary battery including the same are provided. The method includes preparing a nickel-manganese-aluminum precursor having an atomic fraction of nickel of 90 atm % or greater in all transition metals, and mixing the nickel-manganese-aluminum precursor, a cobalt raw material, and a lithium raw material and heat treating the mixture.
    Type: Grant
    Filed: December 3, 2019
    Date of Patent: February 14, 2023
    Inventors: Jin Tae Hwang, Dong Hun Lee, Sung Bin Park, Hyung Man Cho, Jung Min Han, Wang Mo Jung
  • Patent number: 11581612
    Abstract: Set forth herein are compositions comprising A.(LiBH4).B.(LiX).C.(LiNH2), wherein X is fluorine, bromine, chloride, iodine, or a combination thereof, and wherein 0.1?A?3, 0.1?B?4, and 0?C?9 that are suitable for use as solid electrolyte separators in lithium electrochemical devices. Also set forth herein are methods of making A.(LiBH4).B.(LiX).C.(LiNH2) compositions. Also disclosed herein are electrochemical devices which incorporate A.(LiBH4).B.(LiX).C.(LiNH2) compositions and other materials.
    Type: Grant
    Filed: April 13, 2021
    Date of Patent: February 14, 2023
    Assignee: QuantumScape Battery, Inc.
    Inventors: Zhebo Chen, Tim Holme, Marie Mayer, Nick Perkins, Eric Tulsky, Cheng-Chieh Chao, Christopher Dekmezian, Shuang Li
  • Patent number: 11569499
    Abstract: Electrodes, production methods and mono-cell batteries are provided, which comprise active material particles embedded in electrically conductive metallic porous structure, dry-etched anode structures and battery structures with thick anodes and cathodes that have spatially uniform resistance. The metallic porous structure provides electric conductivity, a large volume that supports good ionic conductivity, that in turn reduces directional elongation of the particles during operation, and may enable reduction or removal of binders, conductive additives and/or current collectors to yield electrodes with higher structural stability, lower resistance, possibly higher energy density and longer cycling lifetime. Dry etching treatments may be used to reduce oxidized surfaces of the active material particles, thereby simplifying production methods and enhancing porosity and ionic conductivity of the electrodes.
    Type: Grant
    Filed: November 27, 2019
    Date of Patent: January 31, 2023
    Assignee: STOREDOT LTD.
    Inventors: Eran Sella, Ohad Goldbart, Daniel Aronov
  • Patent number: 11569493
    Abstract: A positive electrode including a positive electrode current collector, an intermediate layer disposed on the positive electrode current collector and including a conductive agent and inorganic particles, and a positive electrode mixture layer disposed on the intermediate layer and including a positive electrode active material and a hydrogen phosphate salt represented by the general formula MaHbPO4 (wherein a satisfies 1?a?2, b satisfies 1?b?2, and M includes at least one element selected from alkali metals and alkaline earth metals), the positive electrode satisfying 0.5?X?3.0, 1.0?Y?7.0, and 0.07?X/Y?3.0 wherein X is the mass ratio (mass %) of the hydrogen phosphate salt relative to the total mass of the positive electrode active material and Y is the mass ratio (mass %) of the conductive agent relative to the total mass of the intermediate layer.
    Type: Grant
    Filed: September 28, 2018
    Date of Patent: January 31, 2023
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Takashi Ko, Yasunori Baba, Katsunori Yanagida, Nobuhiro Hirano, Fumiharu Niina
  • Patent number: 11569503
    Abstract: A nickel-based active material for a lithium secondary battery, a method of preparing the nickel-based active material, and a lithium secondary battery including a positive electrode including the nickel-based active material, the nickel-based active material comprising a secondary particle having an outer portion with a radially arranged structure and an inner portion with an irregular porous structure, wherein the inner portion of the secondary particle has a larger pore size than the outer portion of the secondary particle.
    Type: Grant
    Filed: July 19, 2017
    Date of Patent: January 31, 2023
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Jongmin Kim, Jiyoon Kim, Pilsang Yun, Donggyu Chang, Kwanghwan Cho, Jangsuk Hyun, Jinhwa Kim
  • Patent number: 11569505
    Abstract: A cathode material, containing a crystal with a superlattice structure, is provided. A chemical formula of the crystal is xLi2MO3.(1-x)LiNiaCobMn(1-a-b)O2, where 0<x?0.1, 0.8?a<1, b?0.1, and M is selected from one or more of Mn, Co, and Ni. A preparation method of the cathode material and a battery or a capacitor containing the cathode material are also provided.
    Type: Grant
    Filed: September 3, 2020
    Date of Patent: January 31, 2023
    Assignees: CALB Technology Co., Ltd., CALB Co., Ltd.
    Inventors: Kai Cao, Zhimin Wang, Ning Wang, Xuyi Shan
  • Patent number: 11563205
    Abstract: The present disclosure relates to a multilayer electrode and a method of manufacturing the same, and more specifically to a multilayer electrode comprising an electrode collector; and two or more electrode active material layers which are sequentially coated on one surface or both surfaces of the electrode current collector, wherein the electrode active material layers each include a carbon-based material, a binder, and a silicon-based material, wherein in the mutually adjacent electrode active material layers based on the direction of formation of the electrode active material layers, the content of the carbon-based material and the content of the binder in the electrode active material layer located relatively close to the electrode collector are larger than the content of the carbon-based material and the content of the binder in the electrode active material layers located relatively far away from the electrode current collector.
    Type: Grant
    Filed: November 28, 2018
    Date of Patent: January 24, 2023
    Assignee: LG Energy Solution, Ltd.
    Inventor: Yejin Nam
  • Patent number: 11557760
    Abstract: A positive-electrode active material contains a lithium composite oxide containing at least one selected from the group consisting of F, Cl, N, and S. The crystal structure of the lithium composite oxide belongs to a space group C2/m. An XRD pattern of the lithium composite oxide comprises a first peak within the first range of 44 degrees to 46 degrees of a diffraction angle 2? and a second peak within the second range of 18 degrees to 20 degrees of the diffraction angle 2?. The ratio of the second integrated intensity of the second peak to the first integrated intensity of the first peak is within a range of 0.05 to 0.90.
    Type: Grant
    Filed: October 9, 2019
    Date of Patent: January 17, 2023
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Ryuichi Natsui, Kensuke Nakura, Junko Matsushita, Issei Ikeuchi
  • Patent number: 11557754
    Abstract: A positive electrode active material for a lithium secondary battery, comprising a lithium-containing composite metal oxide in the form of secondary particles formed by aggregation of primary particles capable of being doped and undoped with lithium ions, each of the secondary particles having on its surface a coating layer, the positive electrode active material satisfying the following requirements (1) to (3): (1) the metal oxide has an ?-NaFeO2 type crystal structure of following formula (A): Lia(NibCocM11-b-c)O2??(A) wherein 0.9?a?1.2, 0.9?b<1, 0<c?0.1, 0.9<b+c?1, and M1 represents at least one optional metal selected from Mg, Al, Ca, Sc, Ti, V, Cr, Mn, Fe, Cu, Zn, Ga, Ge, Sr, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, In and Sn; (2) the coating layer comprises Li and M2, wherein M2 represents at least one optional metal selected from Al, Ti, Zr and W; and (3) the active material has an average secondary particle diameter of 2 to 20 ?m, a BET specific surface area of 0.1 to 2.
    Type: Grant
    Filed: January 26, 2015
    Date of Patent: January 17, 2023
    Assignees: SUMITOMO CHEMICAL COMPANY, LIMITED, TANAKA CHEMICAL CORPORATION
    Inventors: Tetsuri Nakayama, Kenji Takamori, Kyousuke Doumae, Takashi Kitamoto
  • Patent number: 11552293
    Abstract: A positive active material for a rechargeable lithium battery includes a first compound represented by Chemical Formula 1, and a second compound having a smaller particle diameter than the first compound and represented by Chemical Formula 2, wherein the first compound and the second compound have a Ni content of about 50 at % to about 60 at % based on a total amount of metal elements excluding Li. A rechargeable lithium battery including the first compound and the second compound satisfies Relation 1: Vs<V1?3.6.??[Relation 1] In Relation 1, V1 is a voltage value at a point where a tangent line to a value corresponding to 50% of the first peak value intersects the line dQ/dV=0, and Vs is a charge start voltage, as determined from a differential capacity (dQ/dV)-voltage charge/discharge plot.
    Type: Grant
    Filed: March 4, 2020
    Date of Patent: January 10, 2023
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Young-Ki Kim, Jungjoon Park, Soonrewl Lee, Youngjoo Chae, Ickkyu Choi, Mingzi Hong, Soonkie Hong
  • Patent number: 11545657
    Abstract: A cathode active material includes a lithium composite oxide having a crystal structure which belongs to a layered structure. The lithium composite oxide has a BET specific surface area of not less than 5 m2/g and not more than 10 m2/g. The lithium composite oxide has an average particle size of not less than 3 ?m and not more than 30 ?m. The lithium composite oxide, an average crystallite size calculated by an X-ray diffraction method is not less than 150 ? and not more than 350 ?.
    Type: Grant
    Filed: March 16, 2020
    Date of Patent: January 3, 2023
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Takanori Omae, Ryuichi Natsui, Yu Otsuka, Shuhei Uchida
  • Patent number: 11539041
    Abstract: Silicon particles for use in an electrode in an electrochemical cell are provided. The silicon particles may have outer regions extending about 20 nm deep from the surfaces, the outer regions comprising an amount of aluminum such that a bulk measurement of the aluminum comprises at least about 0.01% by weight of the silicon particles. The bulk measurement of the aluminum may provide the amount of aluminum present at least in the outer regions.
    Type: Grant
    Filed: April 15, 2022
    Date of Patent: December 27, 2022
    Assignee: ENEVATE CORPORATION
    Inventors: Benjamin Yong Park, Jill R. Pestana, Xiaohua Liu, Frederic Bonhomme
  • Patent number: 11539037
    Abstract: A positive active material for a rechargeable lithium battery includes a first positive active material including a secondary particle including at least two agglomerated primary particles, where at least one part of the primary particles has a radial arrangement structure, as well as a second positive active material having a monolith structure. The first and second positive active materials may both include nickel-based positive active materials. A method of preparing the positive active material, and a rechargeable lithium battery including a positive electrode including the positive active material are also provided.
    Type: Grant
    Filed: October 16, 2020
    Date of Patent: December 27, 2022
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Jongmin Kim, Jiyoon Kim, Jinhwa Kim
  • Patent number: 11532834
    Abstract: Disclosed are an all-solid battery and a method of manufacturing the same. The all-solid battery as disclosed herein may include current collectors having the same size for a cathode and an anode, the elongation areas of the cathode and the anode may be controlled due to the ductility of the current collectors during a pressing process. Thus, areas of the anode and the cathode may become different from each other upon the pressing, thus preventing a short-circuit fault from being formed at the edge portion thereof in the pressing process.
    Type: Grant
    Filed: February 16, 2021
    Date of Patent: December 20, 2022
    Assignees: Hyundai Motor Company, Kia Motors Corporation
    Inventors: Pil Gun Oh, Yong Sub Yoon
  • Patent number: 11532807
    Abstract: A spinel-structured lithium manganese-based positive electrode active material includes a lithium manganese oxide represented by Formula 1, and a coating layer which is disposed on a surface of the lithium manganese oxide and includes at least one coating element selected from the group consisting of aluminum, titanium, tungsten, boron, fluorine, phosphorus, magnesium, nickel, cobalt, iron, chromium, vanadium, copper, calcium, zinc, zirconium, niobium, molybdenum, strontium, antimony, bismuth, silicon, and sulfur, and a positive electrode and a lithium secondary battery which include the positive electrode active material, Li1+aMn2?bM1bO4?cAc??[Formula 1] wherein, in Formula 1, M1 is at least one metallic element including lithium (Li), A is at least one element selected from the group consisting of fluorine, chlorine, bromine, iodine, astatine, and sulfur, 0?a?0.2, 0<b?0.5, and 0?c?0.1.
    Type: Grant
    Filed: November 6, 2018
    Date of Patent: December 20, 2022
    Inventors: So Ra Baek, Wang Mo Jung, Min Suk Kang, Sang Wook Lee, Eun Sol Lho, Wen Xiu Wang
  • Patent number: 11522170
    Abstract: Provided is an aqueous battery configured to use hydroxide ions (OH?) as carrier ions. The aqueous battery is an aqueous battery comprising a cathode layer, an anode layer and an aqueous liquid electrolyte, wherein the cathode layer contains, as a cathode active material, a graphite having a rhombohedral crystal structure; wherein the anode layer contains, as an anode active material, at least one selected from the group consisting of an elemental Zn, an elemental Cd, an elemental Fe, a Zn alloy, a Cd alloy, an Fe alloy, ZnO, Cd(OH)2, Fe(OH)2 and a hydrogen storage alloy; and wherein, as an electrolyte, at least one selected from the group consisting of KOH and NaOH is dissolved in the aqueous liquid electrolyte.
    Type: Grant
    Filed: November 17, 2020
    Date of Patent: December 6, 2022
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Hiroshi Suyama
  • Patent number: 11515524
    Abstract: A positive active material for a rechargeable lithium battery includes: a core having a layered structure; and a surface layer on at least one portion of the surface of the core and including an oxide, wherein the oxide includes at least one first element and at least one second element each selected from Ti, Zr, F, Mg, Al, P, and a combination thereof, the first element and the second element being different from one another, the first element included in the positive active material in an amount of about 0.01 mol % to about 0.2 mol % based on a total weight of the positive active material, and the second element included in the positive active material in an amount of about 0.02 mol % to about 0.5 mol % based on a total weight of the positive active material. A rechargeable lithium battery includes the positive active material.
    Type: Grant
    Filed: January 9, 2019
    Date of Patent: November 29, 2022
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Yongmok Cho, Young-Hun Lee, Hyunjei Chung
  • Patent number: 11515537
    Abstract: An energy storage device includes a negative electrode having a negative active material layer containing amorphous carbon as an active material, a curve attained by determining a rate of change (dQ/dV) in a potential (V) of the amorphous carbon in a discharge capacity (Q) of the amorphous carbon per unit quantity based on a result attained by measuring the potential (V) with respect to the discharge capacity (Q) and representing the rate of change (dQ/dV) with respect to the potential (V) has one or more peaks in a range in which the potential of the amorphous carbon is 0.8 V or more and 1.5 V or less, and a potential of the negative electrode at time of full charge is 0.25 V or more with respect to a lithium potential.
    Type: Grant
    Filed: November 21, 2018
    Date of Patent: November 29, 2022
    Assignee: GS YUASA INTERNATIONAL LTD.
    Inventors: Tomonori Kako, Akihiko Miyazaki, Masashi Takano, Kenta Nakai, Ukyo Harinaga
  • Patent number: 11515535
    Abstract: A positive active material for a rechargeable lithium battery includes a first compound represented by Chemical Formula 1, and a second compound having a smaller particle diameter than the first compound and represented by Chemical Formula 2, wherein the first compound and the second compound have a Ni content of about 50 at % to about 60 at % based on a total amount of metal elements excluding Li. A rechargeable lithium battery including the first compound and the second compound satisfies Relation 1: Vs<V1?3.6.??[Relation 1] In Relation 1, V1 is a voltage value at a point where a tangent line to a value corresponding to 50% of the first peak value intersects the line dQ/dV=0, and Vs is a charge start voltage, as determined from a differential capacity (dQ/dV)-voltage charge/discharge plot.
    Type: Grant
    Filed: March 4, 2020
    Date of Patent: November 29, 2022
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Young-Ki Kim, Jungjoon Park, Soonrewl Lee, Youngjoo Chae, Ickkyu Choi, Mingzi Hong, Soonkie Hong
  • Patent number: 11499228
    Abstract: An anode includes: (1) a current collector; and (2) an interfacial layer disposed over the current collector. The interfacial layer includes a film of a layered material and a reinforcing material selectively disposed over certain regions of the film, while other regions of the film remain exposed from the reinforcing material.
    Type: Grant
    Filed: June 19, 2018
    Date of Patent: November 15, 2022
    Assignee: The Board of Trustees of the Leland Stanford Junior University
    Inventors: Yi Cui, Jin Xie, Lei Liao
  • Patent number: 11495796
    Abstract: A positive active material for a rechargeable lithium battery includes a lithium nickel-based composite oxide including a secondary particle in which a plurality of plate-shaped primary particles are agglomerated; and a lithium manganese composite oxide having at least two crystal lattice structures, wherein the secondary particle has a regular array structure in which (003) planes of the primary particles are oriented in a vertical direction with respect to the surface of the secondary particle.
    Type: Grant
    Filed: November 13, 2019
    Date of Patent: November 8, 2022
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Jongmin Kim, Donghyun Kil, Wooyoung Yang, Seung Joon Lee
  • Patent number: 11489156
    Abstract: A positive electrode active material includes a lithium transition metal oxide represented by Formula 1, and a lithium-containing inorganic compound layer formed on a surface of the lithium transition metal oxide, Li1+a(NibCocXdM1eM2f)1?aO2??[Formula 1] in Formula 1, X is at least one selected from the group consisting of manganese (Mn) and aluminum (Al), M1 is at least one selected from the group consisting of sulfur (S), fluorine (F), phosphorus (P), and nitrogen (N), M2 is at least one selected from the group consisting of zirconium (Zr), boron (B), cobalt (Co), tungsten (W), magnesium (Mg), cerium (Ce), tantalum (Ta), titanium (Ti), strontium (Sr), barium (Ba), hafnium (Hf), F, P, S, lanthanum (La), and yttrium (Y), 0?a?0.1, 0.6?b?0.99, 0?c?0.2, 0?d?0.2, 0<e?0.1, and 0<f?0.1. A method of preparing the positive electrode active material, a positive electrode and a lithium secondary battery are also provided.
    Type: Grant
    Filed: October 19, 2018
    Date of Patent: November 1, 2022
    Inventor: Seo Hee Ju
  • Patent number: 11482702
    Abstract: A method for preparing a positive electrode active material and a positive electrode active material prepared by the method are provided. The method includes preparing a lithium composite transition metal oxide represented by Formula 1, and washing the lithium composite transition metal oxide with a cleaning liquid containing cleaning water and a surfactant. The cleaning liquid contains cleaning water in an amount of no less than 50 parts by weight and less than 400 parts by weight based on 100 parts by weight of the lithium composite transition metal oxide.
    Type: Grant
    Filed: February 26, 2019
    Date of Patent: October 25, 2022
    Inventors: Jun Ho Eom, Sung Ho Ban, Hyeon Hui Baek, Na Ri Park
  • Patent number: 11462725
    Abstract: A cathode active material for a lithium secondary battery includes a nickel-based lithium metal oxide particle doped with Zr and Al. The nickel-based lithium metal oxide particle includes a core portion having a constant molar content of nickel, and a shell portion surrounding an outer surface of the core portion and having a concentration gradient in which a molar content of nickel gradually decreases in a direction from an interface with the core portion to an outermost periphery. The core portion and the shell portion are doped with Al and Zr.
    Type: Grant
    Filed: December 8, 2017
    Date of Patent: October 4, 2022
    Assignees: POSCO, RESEARCH INSTITUTE OF INDUSTRIAL SCIENCE & TECHNOLOGY
    Inventors: Sang Cheol Nam, Sang Hyuk Lee
  • Patent number: 11462721
    Abstract: The present invention provides a method of finely depositing lithium metal powder or thin lithium foil onto a substrate while avoiding the use of a solvent. The method includes depositing lithium metal powder or thin lithium foil onto a carrier, contacting the carrier with a substrate having a higher affinity for the lithium metal powder as compared to the affinity of the carrier for the lithium metal powder, subjecting the substrate while in contact with the carrier to conditions sufficient to transfer the lithium metal powder or lithium foil deposited on the carrier to the substrate, and separating the carrier and substrate so as to maintain the lithium metal powder or lithium metal foil, deposited on the substrate.
    Type: Grant
    Filed: May 28, 2019
    Date of Patent: October 4, 2022
    Assignee: Livent USA Corp.
    Inventors: Marina Yakovleva, Yuan Gao, Yangxing Li, Kenneth Brian Fitch