Abstract: A nonaqueous electrolyte secondary battery is prevented from decreasing the remaining capacity and returned capacity at the time of continuous charge at high voltages and high temperatures. The battery has positive and negative electrodes, and a nonaqueous electrolytic solution containing ethylene carbonate and fluoroethylene carbonate as a solvent. The positive electrode contains a positive-electrode active material with the fine particles of a rare earth element compound deposited on its surface in a dispersed state.

Abstract: The invention relates to An active material for a rechargeable lithium ion battery, comprising metal (M) based particles and a silicon oxide SiOx with 0<x<2, wherein said SiOx is an intimate mixture of amorphous silicon (Si) and crystalline silicon dioxide (SiO2); wherein the metal (M) is preferably selected from the group consisting of Si, Sn, In, Al, Fe and combinations thereof.

Abstract: An active material for a nonaqueous electrolyte energy storage device contains a lithium-transition metal composite oxide having a crystal structure attributable to space group Fm-3m and represented by the compositional formula (1): Li1+xNbyMezApO2??(1) wherein Me is a transition metal including Fe and/or Mn, 0<x<1, 0<y<0.5, 0.25?z<1, A is an element other than Nb and Me, and 0?p?0.2.

Abstract: To provide a positive electrode for nonaqueous secondary batteries having improved charge/discharge cycle characteristics, the positive electrode contains in its active material layer a compound represented by formula: LizNi1-x-yTix(MpLiq)yO2 wherein x is a positive number less than 0.3; y is a positive number less than 0.25; z is a number from 0.95 to 1.05; M is a polyvalent metal satisfying the relation: prM+qrL=54 to 69 pm (where rM is the ionic radius of M, and rL is the ionic radius of Li+); p is a positive number; q is 0 or greater; p and q satisfy the relations: p+q=1 and pv+q=3; and v is the valence of the metal M. When analyzed by XRD, the compound shows diffraction peaks assigned to the planes (003) and (104). The ratio of the area of the peak of the (003) plane to that of the (104) plane is 0.5 to 0.75.

Abstract: A positive active material for a lithium secondary battery, a method of preparing the same, and a lithium secondary battery including the positive active material. The positive active material includes a core part and a shell part that include a nickel-based composite oxide, and a content of nickel in the core part is larger than that in the shell part.

Abstract: To provide a carbonate compound and a cathode active material, whereby a lithium ion secondary battery having excellent cycle characteristics can be obtained. A process for producing a carbonate compound, which comprises mixing a sulfate (A) comprising a sulfate comprising a sulfate of Mn and a sulfate of Ni, or a sulfate comprising a sulfate of Mn, a sulfate of Ni and a sulfate of Co, and a carbonate (B) which is at least one carbonate selected from the group consisting of sodium carbonate and potassium carbonate, in the form of aqueous solutions and controlling the proportion of Mn to the total of Ni, Co and Mn contained in the sulfate (A) to be higher than 65 mol % at the initiation of the mixing, to precipitate a carbonate compound having a proportion of Mn of from 33.3 to 65 mol %, a proportion of Ni of from 17.5 to 50 mol % and a proportion of Co of from 0 to 33.3 mol % to the total of Ni, Co and Mn in the total average composition.

Abstract: A battery includes: a cylindrical battery case; and an electrode body disposed in the battery case, and including a positive plate, a negative plate, and a separator disposed between the positive plate and the negative plate. A spacer formed of a dense body and an electrolyte storage space storing an electrolyte are provided between the electrode body and the battery case on one end or both ends of the battery case in an axial direction of the electrode body.

Abstract: Provided is a lithium metal compound oxide having a layered structure, which is very excellent as a positive electrode active material of a battery that is mounted on, particularly, an electric vehicle or a hybrid vehicle. Suggested is a lithium metal compound oxide having a layered structure which is expressed by general formula of Li1+xM1?xO2 (M represents metal elements including three elements of Mn, Co, and Ni). In the lithium metal compound oxide having a layered structure, D50 is more than 4 ?m and less than 20 ?m, a ratio of a primary particle area to a secondary particle area of secondary particles having a size corresponding to the D50 (“primary particle area/secondary particle area”) is 0.004 to 0.035, and the minimum value of powder crushing strength that is obtained by crushing a powder using a microcompression tester is more than 70 MPa.

Abstract: According to one embodiment, a positive electrode includes a positive electrode layer and a positive electrode current collector. The positive electrode layer includes a positive electrode active material including a first oxide represented by the following formula (?) and/or a second oxide represented by the following formula (?). The positive electrode layer has an intensity ratio falling within a range of 0.25 to 0.7. The ratio is represented by the following formula (1) in an X-ray diffraction pattern obtained by using CuK? radiation for a surface of the positive electrode layer.

Abstract: Disclosed herein is a cathode active material based on lithium nickel oxide represented by Formula 1, wherein the lithium nickel oxide has a nickel content of at least 40% among overall transition metals and is coated with a compound not reacting with an electrolyte (“non-reactive material”), which is selected from a group consisting of oxides, nitrides, sulfides and a mixture or combination thereof not reacting with an electrolyte, as well as a carbon material, at a surface of the lithium nickel oxide.

Abstract: According to one embodiment, a solid electrolyte secondary battery includes a positive electrode containing an active material, a negative electrode containing an active material, and a solid electrolyte layer. The solid electrolyte layer includes a lithium-ion conductive sulfide containing at least one element selected from a group consisting of Al, Si, Fe, Ni, and Zr, the total content of the element in the lithium-ion conductive sulfide is 0.03% by mass or more and 0.3% by mass or less.

Abstract: The present invention provides a nickel-zinc secondary battery, including: a battery case; an electrode assembly, disposed in the battery case; and an electrolyte solution, positioned in the battery case, and filled around the electrode assembly, wherein the electrode assembly includes a nickel positive electrode, a zinc negative electrode, and a membrane separator disposed between the nickel positive electrode and the zinc negative electrode; the nickel positive electrode includes: a substrate and positive electrode material coated on the surface of the substrate; the positive electrode material includes: 68 wt %˜69 wt % positive electrode active material, 0.6 wt %˜1 wt % yttrium oxide, 0.2 wt %˜0.6 wt % calcium hydroxide, 3.5 wt %˜4 wt % nickel powder, and a binder in balance; and the positive electrode active material is a spherical nickel hydroxide coated with Co3+.

Abstract: The present invention is a negative electrode material for a secondary battery with a non-aqueous electrolyte comprising at least a silicon-silicon oxide composite and a carbon coating formed on a surface of the silicon-silicon oxide composite, wherein at least the silicon-silicon oxide composite is doped with lithium, and a ratio I(SiC)/I(Si) of a peak intensity I(SiC) attributable to SiC of 2?=35.8±0.2° to a peak intensity I(Si) attributable to Si of 2?=28.4±0.2° satisfies a relation of I(SiC)/I(Si)?0.03, when x-ray diffraction using Cu-K? ray. As a result, there is provided a negative electrode material for a secondary battery with a non-aqueous electrolyte that is superior in first efficiency and cycle durability to a conventional negative electrode material.

Abstract: A power storage device a positive electrode including a positive electrode active material layer and a negative electrode including a negative electrode active material layer. The positive electrode active material layer includes a plurality of particles of x[Li2MnO3]-(1?x)[LiCo1/3Mn1/3Ni1/3O2] (obtained by assigning 0.5 to x, for example) which is a positive electrode active material, and multilayer graphene with which the plurality of particles of the positive electrode active material are at least partly connected to each other. In the multilayer graphene, a plurality of graphenes are stacked in a layered manner. The graphene contains a six-membered ring composed of carbon atoms, a poly-membered ring which is a seven or more-membered ring composed of carbon atoms, and an oxygen atom bonded to one or more of the carbon atoms in the six-membered ring and the poly-membered ring, which is a seven or more-membered ring.

Abstract: The present invention provides a cathode active material that makes possible a high capacity nonaqueous electrolyte secondary battery that has excellent discharge load characteristics that provide both good cycle characteristics and thermal stability. The cathode active material comprises a lithium nickel composite oxide having the compositional formula LiNi1?aMaO2 (where, M is at least one kind of element that is selected from among a transitional metal other than Ni, a group 2 element, and group 13 element, and 0.01?a?0.5) to which fine lithium manganese composite oxide particle adhere to the surface thereof. This lithium nickel composite oxide is obtained by adding manganese salt solution to a lithium nickel composite oxide slurry, causing manganese hydroxide that contains lithium to adhere to the surface of the lithium nickel composite oxide particles, and then baking that lithium nickel composite oxide.

Abstract: A lithium transition metal oxide composition. The composition has the formula Lia[LibNicMndCoe]O2, where a?0.9, b?0, c>0, d>0, e>0, b+c+d+e=1, 1.05?c/d?1.4, 0.05?e?0.30, 0.9?(a+b)/M?1.06, and M=c+d+e. The composition has an O3 type structure.

Abstract: The invention relates to a negative electrode powder for a lithium-ion rechargeable battery comprising a mixture comprising carbon and SiOx, with 0<x<1, wherein the SiOx consists of a nanometric composite of crystalline SiO2 and amorphous Si. The method for preparing the powder comprises the steps of providing an aqueous solution comprising an anti-agglomeration agent, dispersing a silicon comprising organic compound in the aqueous solution, hydrothermally treating the aqueous solution at a temperature between 90 and 180° C. for a period of 0.5 to 24 h, preferably between 110 and 140° C. for a period of 0.5 to 4 h, thereby forming a suspension of SiO2 and Si in the aqueous solution, evaporating the solution, thereby obtaining a slurry, subjecting the slurry to a coking process whereby a solid residue is formed, calcining the solid residue at a temperature between 500 and 1300° C., preferably between 600 and 1000° C., in a non-oxidizing atmosphere.

Abstract: High energy density lithium secondary batteries are disclosed herein. In some embodiments, a high energy density lithium secondary battery includes a cathode, an anode, and a separator. The cathode includes a first cathode active material having a layered structure and a second cathode active material having a spinel structure, wherein the amount of the first cathode active material is between 40 and 100 wt % based on the total weight of the cathode active materials. The anode includes crystalline graphite and amorphous carbon as anode active materials, wherein the amount of the crystalline graphite is between 40 and 100 wt % based on the total weight of the anode active materials.

Abstract: Lithiated composite materials and methods of manufacture are provided that are capable of imparting excellent capacity and greatly improved cycle life in lithium-ion secondary cells. By supplementing a high nickel content lithium storage material with a transition metal oxide lithium storage material or a dopant at relatively low levels, the capacity of the high nickel content lithium storage materials is maintained while cycle life is dramatically improved. These characteristics are promoted by methods of producing the materials that intermix unlithiated precursor materials with a lithium source and sintering the materials together in a single sintering reaction. The resulting lithiated composite materials provide for the first time both high capacity and excellent cycle life to predominantly high nickel content electrodes.

Abstract: A rechargeable battery includes an electrode assembly including a positive electrode and a negative electrode, a case receiving the electrode assembly, a cap plate coupled to the case, a vent plate under the cap plate, the vent plate including a notch, a middle plate under the vent plate, and a laminating insulating layer between the vent plate and the middle plate, the laminating insulating layer being laminated to the vent plate or the middle plate.

Abstract: Lithiated composite materials and methods of manufacture are provided that are capable of imparting excellent capacity and greatly improved cycle life in lithium-ion secondary cells. By supplementing a high nickel content lithium storage material with a transition metal oxide lithium storage material or a dopant at relatively low levels, the capacity of the high nickel content lithium storage materials is maintained while cycle life is dramatically improved. These characteristics are promoted by methods of producing the materials that intermix unlithiated precursor materials with a lithium source and sintering the materials together in a single sintering reaction. The resulting lithiated composite materials provide for the first time both high capacity and excellent cycle life to predominantly high nickel content electrodes.

Abstract: Disclosed are a cathode active material for lithium secondary batteries and a lithium secondary battery including the same and, more particularly, the present invention relates to a cathode active material for lithium secondary batteries that includes a mixture of an overlithiated transition metal oxide represented by Formula 1 below and a lithium composite transition metal oxide represented by Formula 2 below: Li1+aNibMncCo1-(a+b+c+d)MdO2-sAs??(1) LiNixMnyCo1-(x+y+z)M?zO2-tA?t??(2) wherein 0.1?a?0.2, 0.1?b?0.4, 0.3?c?0.7, 0?d?0.1, 0.5?x?0.8, 0.1?y?0.4, 0?z?0.1, 0?s<0.2, and 0?t<0.2; M and M? are each independently at least one divalent or trivalent metal; and A and A? are each independently at least one monovalent or divalent anion.

Abstract: A lithium-ion secondary battery of the present invention comprises a positive electrode including a positive electrode active material composite formed by compositing a lithium silicate-based material and a carbon material, a negative electrode including a negative electrode active material containing a silicon, and an electrolyte. The lithium-ion secondary battery satisfies 0.8<B/A<1.2, where A is irreversible capacity of the positive electrode and B is irreversible capacity of the negative electrode.

Abstract: Provided is a cathode active material containing a Ni-based lithium mixed transition metal oxide. More specifically, the cathode active material comprises the lithium mixed transition metal oxide having a composition represented by Formula I of LixMyO2 wherein M, x and y are as defined in the specification, which is prepared by a solid-state reaction of Li2CO3 with a mixed transition metal precursor under an oxygen-deficient atmosphere, and has a Li2CO3 content of less than 0.07% by weight of the cathode active material as determined by pH titration. The cathode active material in accordance with the present invention and substantially free of water-soluble bases such as lithium carbonates and lithium sulfates and therefore has excellent high-temperature and storage stabilities and a stable crystal structure.

Abstract: When producing a nickel composite hydroxide that is a precursor to the cathode active material for a non-aqueous electrolyte secondary battery by supplying an aqueous solution that includes at least a nickel salt, a neutralizing agent and a complexing agent into a reaction vessel while stirring and performing a crystallization reaction, a nickel composite hydroxide slurry is obtained while controlling the ratio of the average particle size per volume of secondary particles of nickel composite hydroxide that is generated inside the reaction vessel with respect to the average particle size per volume of secondary particles of nickel composite hydroxide that is finally obtained so as to be 0.2 to 0.6, after which, while keeping the amount of slurry constant and continuously removing only the liquid component, the crystallization reaction is continued until the average particle size per volume of secondary particles of the nickel composite hydroxide becomes 8.0 ?m to 50.0 ?m.

Abstract: A battery, which is provided with a pressure-type current interrupt mechanism, is provided with: a gas-generating material placed outside an electrode body and within a battery case; a positive electrode potential member that is placed outside the electrode body and within the battery case in a manner contacting the gas-generating material, and conducts with the positive electrode of the electrode body; and a negative electrode potential member that is placed outside the electrode body and within the battery case in a manner contacting the gas-generating material while being spaced from the positive electrode potential member, and conducts with the negative electrode of the electrode body. The gas-generating material includes a gas-generating agent that generates a gas when the potential of the positive electrode potential member exceeds a gas generation potential.

Abstract: A lithium-ion secondary battery (100A) includes a positive electrode current collector (221A) and a positive electrode active material layer (223A) retained on the positive electrode current collector (221A). The positive electrode active material layer (223A) contains positive electrode active material particles, a conductive agent, and a binder. The positive electrode active material particles (610A) each include a shell portion (612) made of primary particles (800) of a layered lithium-transition metal oxide, a hollow portion (614) formed inside the shell portion (612), and a through-hole (616) penetrating through the shell portion (612). The primary particles (800) of the lithium-transition metal oxide have a major axis length of less than or equal to 0.8 ?m in average of the positive electrode active material layer (223A).

Abstract: An air cell includes a positive electrode and a negative electrode, and an outer frame member located at outer peripheries of the positive electrode and the negative electrode. The positive electrode and the outer frame member are integrally joined together. An assembled battery includes a plurality of air cells, the air cells being stacked on top of each other. This configuration can increase mechanical strength and improve sealing performance for an electrolysis solution in the positive electrode. In addition, a reduction in thickness of the entire air cell can be achieved so that the assembled battery suitable for use in a vehicle can be provided.

Abstract: Electrode structures and methods for making the same are generally described. In certain embodiments, the electrode structures can include a plurality of particles, wherein the particles comprise indentations relative to their convex hulls. As the particles are moved proximate to or in contact with one another, the indentations of the particles can define pores between the particles. In addition, when particles comprising indentations relative to their convex hulls are moved relative to each other, the presence of the indentations can ensure that complete contact does not result between the particles (i.e., that there remains some space between the particles) and that void volume is maintained within the bulk of the assembly. Accordingly, electrodes comprising particles with indentations relative to their convex hulls can be configured to withstand the application of a force to the electrode while substantially maintaining electrode void volume (and, therefore, performance).

Abstract: A cathode material for a lithium secondary battery, including fibrous carbon and a plurality of cathode active material particles bonded to a surface of the fibrous carbon. The cathode active material particles are composed of olivine-type LiMPO4 where M represents one or more kinds of elements selected from Fe, Mn, Ni, and Co. Also disclosed is a method of producing the cathode material and a lithium secondary battery.

Abstract: A method and apparatus for forming a reliable and cost efficient battery or electrochemical capacitor electrode structure that has an improved lifetime, lower production costs, and improved process performance are provided. In one embodiment a method for forming a three dimensional porous electrode for a battery or an electrochemical cell is provided. The method comprises depositing a columnar metal layer over a substrate at a first current density by a diffusion limited deposition process and depositing three dimensional metal porous dendritic structures over the columnar metal layer at a second current density greater than the first current density.

Abstract: [Problem] To provide a lithium ion secondary battery having excellent high-rate discharge characteristics. [Solution] Excellent high-rate discharge characteristics are obtained by a lithium ion secondary battery in which a compound represented by Lia(NixCoyAl1-x-y)O2 (where 0.95?a?1.05, 0.5?x?0.9, 0.05?y?0.2, and 0.7?x+y?1.0) is used as a positive electrode active material in a positive electrode, the positive electrode has an electrode density of 3.75 to 4.1 g/cm3, and the positive electrode has a BET specific surface area of 1.3 to 3.5 m2/g as an electrode.

Abstract: A primary battery includes a cathode having an alkali-deficient nickel oxide including metals such as Ca, Mg, Al, Co, Y, Mn, and/or non-metals such as B, Si, Ge, or a combination of metal and/or non-metal atoms; a combination of metal atoms; an anode; a separator between the cathode and the anode; and an alkaline electrolyte.

Abstract: Process for manufacturing nickel-cobalt composite represented by Ni1-x-yCoxMnyMz(OH)2 (where, 0.05?x?0.95, 0?y?0.55, 0?z?0.1, x+y+z<1, and M is at least one metal element selected from Al, Mg, and the like), includes: forming seed particle, while reaction solution having mixed solution containing metal compounds and ammonia solution containing ammonium ion supply source at discharge head of an impeller from 50-100 m2/s2, the concentration of nickel ions is maintained within range 0.1-5 ppm by mass, whereby seed particles are formed; and growing seed particle wherein solution is obtained by supplying mixed and ammonium solutions to reaction solution is agitated with a concentration of nickel ions being maintained within range 5-300 ppm by mass and higher than the concentration of nickel ions in seed particle formation, whereby seed particles are grown up.

Abstract: Disclosed are a precursor for a rechargeable lithium battery, a positive active material including the same, a preparation method thereof, and a rechargeable lithium battery including the positive active material. More particularly, the present invention relates to a precursor including a sheet-shaped plate having a thickness of about 1 nm to about 30 nm and that is represented by the following Chemical Formula 1. NixCoyMn1-x-y-zMz(OH)2??[Chemical Formula 1] In the above Chemical Formula 1, 0<x<1, 0?y<1, 0.5?1-x-y-z, and 0?z<1, and M is at least one kind of metal selected from the group consisting of Al, Mg, Fe, Cu, Zn, Cr, Ag, Ca, Na, K, In, Ga, Ge, V, Mo, Nb, Si, Ti, and Zr.

Abstract: Disclosed is a lithium ion secondary battery which includes a positive electrode, a negative electrode and a nonaqueous electrolyte solution. The positive electrode contains, as the positive electrode active material, a lithium-transition metal composite oxide having a layered structure. The positive electrode active material includes at least one metal element M0 from among Ni, Co and Mn, and includes at least one metal element M? from among Zr, Nb and Al, and further includes W. When 2 g of a powder of the positive electrode active material and 100 g of pure water are stirred together to prepare a suspension and the suspension is filtered to obtain a filtrate, the amount of W eluted into the filtrate, as measured by inductively coupled plasma mass spectrometry, is 0.025 mmol or less per gram of filtrate.

Abstract: A galvanic element includes at least one lithium-intercalating and at least one lithium-deintercalating electrode. A positive electrode and a negative electrode are separated by a polyimide-based separator that has a labyrinth porosity. The polyimide-based separator is configured at least on one side with a porous, ceramically-based coating that comprises a binder and ceramic particles.

Abstract: The present invention relates to a method of preparing a cathode active material precursor for a lithium rechargeable battery, the cathode active material precursor for the lithium rechargeable battery prepared thereby, and a cathode active material formed using the cathode active material precursor. According to the present invention, the method of preparing a cathode active material precursor for a lithium secondary battery controls the concentration of a concentration gradient part and a shell part in a precursor to obtain a desired concentration of a transition metal in the shell part. As a result, a metal composition is distributed in a continuous concentration gradient from the interface between the core part and the shell part to the surface of the cathode active material, thereby a cathode active material with excellent thermal stability.

Abstract: The present invention relates to positive electrode active substance particles for non-aqueous electrolyte secondary batteries, comprising an oxide having a spinel structure and comprising at least Li and Mn as main components and an oxide comprising at least Li and Zr, in which the oxide comprising at least Li and Zr forms a mixed phase comprising two or more phases, and a content of the oxide comprising at least Li and Zr in the positive electrode active substance particles is 0.1 to 4% by weight. The present invention provides positive electrode active substance particles for non-aqueous electrolyte secondary batteries which are excellent in high-temperature characteristics and a process for producing the positive electrode active substance particles, and a non-aqueous electrolyte secondary battery.

Abstract: A biosensor component is provided that provides enhanced characteristics for use in biosensors, such as blood glucose sensors. The biosensor component comprises a substrate and a conductive layer coated on the substrate. The conductive layer includes nickel and chromium, such that a combined weight percent of the nickel and chromium in the conductive layer is in the range of 50 to 99 weight percent.

Abstract: Provided is a lithium ion secondary battery capable of realizing a high energy density while maintaining output. A lithium ion secondary battery D1 according to the present invention includes an electrode having an active material mix layer 31 on both surfaces of a current collector 35. The active material mix layer 31 has a smaller void ratio in a current collector side region 34 of the active material mix layer 31 and a surface side region 32 of the active material mix layer 31 than in an intermediate region 33 between the current collector side region 34 and the surface side region 32 of the active material mix layer 31.

Abstract: Provided is a lithium secondary battery that comprises a positive electrode having a positive electrode active material, a negative electrode having a negative electrode active material, and a non-aqueous electrolyte. The positive electrode active material is a nickel-containing lithium complex oxide having a layered structure. The oxide has a composition in which W and Zr are added, and contains no Nb.

Abstract: [Object] Provided is a means capable of suppressing a decrease in capacity and improving output characteristics of a non-aqueous electrolyte secondary battery when the battery is used for a long period of time. [Solving Means] Disclosed is a positive electrode active substance for a non-aqueous electrolyte secondary battery, in which the true density/tap density of secondary particles of a lithium composite oxide containing nickel as the main component is within the range of 1.6 to 2.3, and in the secondary particles, the average porosity on the center side of the half (R/2 [?m]) of the particle radius (R) of D50 of the secondary particles is larger than the average porosity on the surface side.

Abstract: An alkaline, rechargeable electrochemical cell includes a pasted electrode structure in which a composition comprising a paste matrix component includes cobalt in an amount greater than 6 weight percent ranging up to 14 weight percent. The matrix may also include a rare earth such as yttrium. The composition further includes particles of nickel hydroxide dispersed in the matrix, and these particles include cobalt levels ranging from greater than 8 atomic percent up to 15 atomic percent. Cells incorporating these materials have good charging efficiency at elevated temperatures.

Abstract: Provided is a lithium mixed transition metal oxide having a composition represented by Formula I of LixMyO2 (M, x and y are as defined in the specification) having mixed transition metal oxide layers (“MO layers”) comprising Ni ions and lithium ions, wherein lithium ions intercalate into and deintercalate from the MO layers and a portion of MO layer-derived Ni ions are inserted into intercalation/deintercalation layers of lithium ions (“reversible lithium layers”) thereby resulting in the interconnection between the MO layers. The lithium mixed transition metal oxide of the present invention has a stable layered structure and therefore exhibits improved stability of the crystal structure upon charge/discharge. In addition, a battery comprising such a cathode active material can exhibit a high capacity and a high cycle stability.

Abstract: An alkaline, rechargeable electrochemical cell includes a pasted electrode structure in which a composition comprising a paste matrix component includes cobalt in an amount greater than 6 weight percent ranging up to 14 weight percent. The matrix may also include a rare earth such as yttrium. The composition further includes particles of nickel hydroxide dispersed in the matrix, and these particles include cobalt levels ranging from greater than 8 atomic percent up to 15 atomic percent. Cells incorporating these materials have good charging efficiency at elevated temperatures.

Abstract: A particle, including: a plurality of crystallites including a first composition having a layered ?-NaFeO2-type structure and including lithium in an amount of about 0.1 to about 1.3 moles, per mole of the first composition, nickel in an amount of about 0.1 to about 0.79 mole, per mole of the first composition, cobalt in an amount of 0 to about 0.5 mole, per mole of the first composition, and oxygen in an amount of about 1.7 to about 2.3 moles, per mole of the first composition; and a grain boundary between adjacent crystallites of the plurality of crystallites and including a second composition having the layered ?-NaFeO2-type structure, a cubic structure, or a combination thereof, wherein a concentration of cobalt in the grain boundary is greater than a concentration of cobalt in the crystallites.

Abstract: A positive electrode active material is provided to contain: a solid solution lithium-containing transition metal oxide (A) represented by Li1.5[NiaCobMnc[Li]d]O3 (where a, b, c and d satisfy the relations of 0.1?d?0.4, a+b+c+d=1.5, and 1.1?a+b+c?1.4.); and a lithium-containing transition metal oxide (B) represented by Li1.0Nia?Cob?Mnc?O2 (where a?, b? and c? satisfy the relation of a?+b?+c?=1.0.).

Abstract: Positive electrode for lithium-ion electrochemical cells are provided that have capacity retentions of greater than about 95% after 50 charge-discharge cycles when comparing the capacity after cycle 52 with the capacity after cycle 2 when cycled between 2.5 V and 4.7 V vs. Li/Li+ at 30° C. Compositions useful in the provided positive electrodes can have the formula, Li1+x(NiaMnbCoc)1?x O2, wherein 0.05?x?0.10, a+b+c=1, 0.6?b/a?1.1, c/(a+b)<0.25, and a, b, and c are all greater than zero. The process of making these positive electrodes includes firing the compositions at 850° C. to 925° C.

Abstract: Multi-layer electrochromic structures comprising an anodic electrochromic layer comprising a lithium nickel oxide composition on a first substrate, the anodic electrochromic layer comprising lithium, nickel and a Group 4 metal selected from titanium, zirconium, hafnium and a combination thereof, wherein (i) the atomic ratio of lithium to the combined amount of nickel and such Group 4 metal(s) in the anodic electrochromic layer is at least 0.4:1, respectively, (ii) the atomic ratio of the amount of such Group 4 metal(s) to the combined amount of nickel and such Group 4 metal(s) in the anodic electrochromic layer is at least about 0.025:1, respectively, and (iii) the anodic electrochromic layer exhibits an interplanar distance (d-spacing) of at least 2.5 ? as measured by X-ray diffraction (XRD), comprises at least 0.05 wt. % carbon, and/or has a coloration efficiency absolute value of at least 19 cm2/C.