Nickel Component Is Active Material Patents (Class 429/223)
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Patent number: 10403882Abstract: The present invention provides a secondary battery-use active material that allows for an improvement in thermal stability after charge and discharge are repeated. The secondary battery-use active material of the present invention includes a cathode active material that includes (A) a main phase and a sub-phase, (B) the main phase containing a first lithium compound represented by LiaNibMcAldOe (where M is an element such as cobalt, and 0.8<a<1.2, 0.45?b?1, 0?c?1, 0?d?0.2, 0<e?1.98, (c+d)>0, and (b+c+d)?1), and (C) the sub-phase containing a second lithium compound that contains lithium, aluminum, and oxygen as constituent elements.Type: GrantFiled: October 26, 2015Date of Patent: September 3, 2019Assignee: Murata Manufacturing Co., Ltd.Inventors: Takaaki Matsui, Kyohei Ogawa, Masaki Kuratsuka
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Patent number: 10374227Abstract: The present invention provides a positive electrode active material prepared using a preparation method including mixing lithium complex metal oxide particles with a nanosol of a ceramic-based ion conductor and heat treating the resultant to form a coating layer including the ceramic-based ion conductor on the lithium complex metal oxide particles, thereby forming a coating layer including a ceramic-based ion conductor to a uniform thickness on a lithium complex metal oxide particle surface, and as a result, capable of minimizing capacity decline and enhancing a lifespan property when used in a secondary battery, a method for preparing the same, and a lithium secondary battery including the same.Type: GrantFiled: December 4, 2015Date of Patent: August 6, 2019Assignee: LG Chem, Ltd.Inventors: Dong Kwon Lee, Seung Beom Cho, Jun Seok Nho, Byung Hyun Min, Bae Jung Kim
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Patent number: 10374231Abstract: The present invention relates to a lithium secondary battery, and more specifically, to a lithium secondary battery including a cathode, an anode and a non-aqueous electrolyte solution, where the cathode includes a cathode active material including a lithium-metal oxide which is doped with a transition metal and includes at least one type of metal having a concentration gradient region between a central portion and a surface portion, and thus having a significantly increased charge/discharge capacity and output at a low temperature to exhibit excellent properties in the low-temperature environment.Type: GrantFiled: December 14, 2015Date of Patent: August 6, 2019Assignee: SK Innovation Co., Ltd.Inventors: Kyung-Bin Yoo, Kook-Hyun Han, Duck-Chul Hwang
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Patent number: 10361435Abstract: Provided is a nonaqueous electrolyte secondary battery including a positive electrode, a negative electrode, and a nonaqueous electrolytic solution. The positive electrode includes a positive electrode current collector and a positive electrode active material layer that is formed on the positive electrode current collector. The positive electrode active material layer contains a positive electrode active material, an inorganic phosphate compound having ion conductivity, and a conductive material. The volatile component content in the conductive material is at least 0.15 mass % when measured according to JIS K 6221 (1982).Type: GrantFiled: June 16, 2016Date of Patent: July 23, 2019Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Yoshitomo Takebayashi
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Patent number: 10355275Abstract: Disclosed are a precursor for preparation of a lithium composite transition metal oxide, a method for preparing the same and a lithium composite transition metal oxide obtained from the same. More particularly, the transition metal precursor which has a composition represented by Formula 1 below and is prepared in an aqueous transition metal solution, mixed with a transition metal-containing salt, including an alkaline material, the method for preparing the same and the lithium composite transition metal oxide obtained from the same are disclosed. MnaMb(OH1-x)2-yAy??(1) wherein M is at least one selected form the group consisting of Ni, Ti, Co, Al, Cu, Fe, Mg, B, Cr, Zr, Zn and Period II transition metals; A is at least one selected form the group consisting of anions of PO4, BO3, CO3, F and NO3, and 0.5?a?1.0; 0?b?0.5; a+b=1; 0<x<1.0; and 0?y?0.02.Type: GrantFiled: August 18, 2014Date of Patent: July 16, 2019Assignee: LG Chem, Ltd.Inventors: Sang Min Park, Sun Sik Shin, Byung Chun Park, Hye Lim Jeon, Bo Ram Lee
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Patent number: 10340548Abstract: Process for the fabrication of a solid electrolyte thin film for an all-solid state Li-ion battery comprising steps to: a) Procure a possibly conducting substrate film, possibly coated with an anode or cathode film, b) Deposit an electrolyte thin film by electrophoresis, from a suspension of particles of electrolyte material, on said substrate and/or said previously formed anode or cathode film, c) Dry the film thus obtained, d) Consolidate the electrolyte thin film obtained in the previous step by mechanical compression and/or heat treatment.Type: GrantFiled: October 30, 2012Date of Patent: July 2, 2019Assignee: I-TENInventors: Fabien Gaben, Frédéric Bouyer, Bruno Vuillemin
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Patent number: 10340517Abstract: The present invention provides a positive electrode active material prepared using a preparation method including mixing a precursor of a metal for a positive electrode active material with a nanosol of a ceramic-based ion conductor to adsorb the nanosol of the ceramic-based ion conductor on the precursor surface, and mixing the nanosol of the ceramic-based ion conductor-adsorbed precursor with a lithium raw material, and heat treating the resultant to prepare a positive electrode active material, and thereby having greatly increased structural stability by the lithium complex metal oxide present on the surface as a metal element forming the ceramic-based ion conductor being uniformly doped, and as a result, capable of significantly enhancing capacity, a rate property and a cycle property of a battery, a method for preparing the same, and a lithium secondary battery including the same.Type: GrantFiled: December 4, 2015Date of Patent: July 2, 2019Assignee: LG Chem, Ltd.Inventors: Dong Kwon Lee, Seung Beom Cho, Jun Seok Nho, Byung Hyun Min, Bae Jung Kim
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Patent number: 10319991Abstract: An alkaline electrochemical cell, preferably a zinc/air cell which includes a container; a negative electrode, a positive electrode, wherein said negative electrode and said positive electrode are disposed within the container, and an alkaline electrolyte, wherein the negative electrode comprises zinc, a branched chain fluorosurfactant, barium sulfate (and, more specifically, amino- and/or epoxy-functionalized barium sulfate) and nano sized zinc oxide. The negative electrode composition supports high zinc to electrolyte weight ratios.Type: GrantFiled: October 23, 2015Date of Patent: June 11, 2019Assignee: Energizer Brands, LLCInventor: Jack W. Marple
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Patent number: 10319986Abstract: A positive electrode for nonaqueous electrolyte secondary batteries includes a positive electrode current collector and a positive electrode mix layer, formed on the current collector, containing a positive electrode active material. The positive electrode active material mainly contains a lithium transition metal oxide in which the molar ratio of nickel (Ni) to a transition metal component is 20% or more. The positive electrode mix layer contains a plurality of pores and has a first peak of a logarithmic differential pore volume distribution (dV/dlogD) that appears in the range where the pore diameter D is less than 1 ?m and a second peak of the logarithmic differential pore volume distribution (dV/dlogD) that appears in the range where the pore diameter D is 1 ?m or more in a pore distribution determined by mercury intrusion porosimetry. According to this configuration, a nonaqueous electrolyte secondary battery having excellent output characteristics can be provided.Type: GrantFiled: November 18, 2015Date of Patent: June 11, 2019Assignee: SANYO Electric Co., Ltd.Inventors: Kouhei Tuduki, Atsushi Fukui
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Patent number: 10312513Abstract: A lithium composite metallic oxide expressed by: LiaNibCocMndDeOf (where 0.2?“a”?1.5, “b”+“c”+“d”+“e”=1, 0<“e”<1, “D” is at least one of the following elements: Fe, Cr, Cu, Zn, Ca, Mg, Zr, S, Si, Na, K, Al, Ti, P, Ga, Ge, V, Mo, Nb, W, La, Hf and Rf, and 1.7?“f”?2.1), and including: a high manganese portion, which is made of a metallic oxide including Ni, Co and Mn at least and of which the composition ratio between Ni, Co and Mn is expressed by Ni:Co:Mn=g:h:i (note that “g”+“h”+“i”=1, 0<“g”<1, 0<“h”<“c”, and “d”<“i”<1), in a superficial layer thereof; and a metallic oxidation portion in an outermost superficial layer of the high manganese portion.Type: GrantFiled: April 7, 2015Date of Patent: June 4, 2019Assignee: KABUSHIKI KAISHA TOYOTA JIDOSHOKKIInventors: Tsukasa Sugie, Dai Matsushiro, Masanori Harata
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Patent number: 10305104Abstract: A lithium-ion battery having over-discharge protection includes an anode comprising at least an electrochemically active anode material, said anode having an anode irreversible capacity loss during a first charge of the lithium-ion battery; and a cathode comprising at least an electrochemically active cathode material characterized by the formula: xLi2MnO3.(1?x)LiMnaNibCocO2, where 0<x<1 and a+b+c=1, and x, a, b, and c are selected to provide a cathode irreversible capacity loss during a first charge of the lithium-ion battery that is greater than or equal to the anode irreversible capacity loss, and wherein the cathode possesses a voltage step less than about 2 V versus Li.Type: GrantFiled: April 4, 2011Date of Patent: May 28, 2019Assignee: A123 Systems, LLCInventor: Young-Il Jang
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Patent number: 10305144Abstract: Disclosed is a lithium secondary battery, including a cathode, an anode and a non-aqueous electrolyte, wherein the cathode includes a cathode active material containing lithium-metal oxide of which at least one of metals has a concentration gradient region between a core part and a surface part thereof, and the non-aqueous electrolyte includes a lithium salt, a polyfunctional nitrile compound and an organic solvent, such that the high-temperature storage and lifespan properties may be improved.Type: GrantFiled: December 2, 2015Date of Patent: May 28, 2019Assignee: SK INNOVATION CO., LTD.Inventors: Duck-Chul Hwang, Kyung-Bin Yoo, Kook-Hyun Han
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Patent number: 10297814Abstract: A positive electrode includes first positive electrode active material particles and second positive electrode active material particles. The first positive electrode active material particles include 0.1% by mass or more and 1% by mass or less of lithium carbonate and a first lithium transition metal oxide as a remainder. The first lithium transition metal oxide is represented by LiM1(1-z1)Mnz1O2 (0.05?z1?0.20). The second positive electrode active material particles include 0.01% by mass or more and 0.05% by mass or less of lithium carbonate and a second lithium transition metal oxide as a remainder. The second lithium transition metal oxide is represented by LiM2(1-z2)Mnz2O2 (0.40?z2?0.60). An electrolytic solution includes 1% by mass or more and 5% by mass or less of an overcharging additive and a solvent and a lithium salt as a remainder.Type: GrantFiled: November 21, 2017Date of Patent: May 21, 2019Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Hiroshi Tsubouchi, Motoshi Isono, Masaki Kato, Naoyuki Wada, Keiichi Takahashi, Yukihiro Okada, Tatsuya Hashimoto
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Patent number: 10297869Abstract: Provided is a highly reliable nickel-zinc battery including a separator exhibiting hydroxide ion conductivity and water impermeability. The separator is disposed in a hermetic container to separate a positive-electrode chamber accommodating a positive electrode and a positive-electrode electrolyte from a negative-electrode chamber accommodating a negative electrode and a negative-electrode electrolyte. The positive-electrode chamber has an extra positive-electrode space having a volume that meets a variation in amount of water in association with reaction at the positive electrode during charge and discharge of the battery, and the negative-electrode chamber has an extra negative-electrode space having a volume meeting a variation in amount of water in association with reaction at the negative electrode during charge and discharge of the battery.Type: GrantFiled: December 21, 2016Date of Patent: May 21, 2019Assignee: NGK Insulators, Ltd.Inventors: Hiroshi Hayashi, Naohito Yamada, Kenshin Kitoh
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Patent number: 10297825Abstract: Disclose herein are processes for producing a nickel cobalt aluminum composite hydroxide and producing a positive electrode active material for non-aqueous electrolyte secondary batteries. Nucleation is performed by controlling an aqueous solution for nucleation containing a nickel-containing metal compound, cobalt-containing metal compound, ammonium ion supplier, and aluminum source so that the aqueous solution's pH for nucleation is 12.0 to 13.4, and then in a particle growth step, particle growth is performed in an aqueous solution for particle growth obtained by controlling the aqueous solution for nucleation obtained in the nucleation step so that the pH of aqueous solution for nucleation is 10.5 to 12.0. Further, in nucleation step, an aqueous solution containing aluminum and sodium is used as the aluminum source contained in aqueous solution for nucleation, and the mole ratio of sodium to aluminum in aqueous solution containing aluminum and sodium is adjusted to 1.5 to 3.0.Type: GrantFiled: October 20, 2015Date of Patent: May 21, 2019Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Kazuomi Ryoshi, Koji Yamaji, Kensaku Mori
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Patent number: 10290862Abstract: A composite cathode active material includes: a first metal oxide including a plurality of layered crystalline phases comprising a first layered crystalline phase and a second layered crystalline phase, wherein the first and second layered crystalline phases have a different compositions than each other, and a second metal oxide different from the first metal oxide and including a composite crystalline phase, that is different from the first metal oxide, wherein the second metal oxide is represented by Formula 1, wherein at least a portion of the second metal oxide is disposed on a first layered crystalline phase of the plurality of layered crystalline phases of the first metal oxide, and wherein the first layer crystalline phase is in a space group of R-3m: LixMyOz??Formula 1 wherein, in Formula 1, 0?x?3, 1?y?3, and 2?z?8, and M is at least one selected from a Group 4 element to a Group 13 element.Type: GrantFiled: June 14, 2016Date of Patent: May 14, 2019Assignees: SAMSUNG ELECTRONICS CO., LTD., SAMSUNG SDI CO., LTD.Inventors: Sungjin Ahn, Byongyong Yu, Jayhyok Song, Andrei Kapylou, Jinhwan Park
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Patent number: 10280092Abstract: A disorder rock salt composition for use as a cathode active material. The stoichiometry of the lithium, niobium, oxygen, and transition metal components of the disordered rock salt is varied to improved performance in an electrochemical cell while substantially maintaining the disordered rock salt crystallographic structure.Type: GrantFiled: July 28, 2016Date of Patent: May 7, 2019Assignee: Wildcat Discovery Technologies, IncInventors: Kyler Carroll, Bin Li
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Patent number: 10276894Abstract: The present invention provides a lithium secondary battery comprising a non-aqueous liquid electrolyte comprising lithium bis(fluorosulfonyl)imide (LiFSI) and a fluorinated benzene-based compound as additives, a positive electrode comprising a lithium-nickel-manganese-cobalt-based oxide as a positive electrode active material, a negative electrode, and a separator. With the non-aqueous liquid electrolyte for a lithium secondary battery of the present invention, a solid SEI film is formed on a negative electrode when initially charging a lithium secondary battery comprising the non-aqueous liquid electrolyte, and an output property of the lithium secondary battery is improved, and an output property and stability after high temperature storage are capable of being enhanced as well.Type: GrantFiled: September 25, 2015Date of Patent: April 30, 2019Assignee: LG Chem, Ltd.Inventors: Chul Haeng Lee, Shul Kee Kim, Gwang Yeon Kim, Doo Kyung Yang
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Patent number: 10270143Abstract: An electrolyte for metal-air batteries, which is able to inhibit the self-discharge of metal-air batteries, and a metal-air battery using the electrolyte. The electrolyte for metal-air batteries having an anode containing at least one kind of metal element selected from aluminum and magnesium, may comprise an aqueous solution comprising a self-discharge inhibitor containing at least one kind of ion selected from the group consisting of an H2P2O72? anion and a Ca2+ cation and at least one kind of ion selected from the group consisting of a CH3S? anion, an S2O32? anion and an SCN? anion.Type: GrantFiled: September 7, 2016Date of Patent: April 23, 2019Assignee: Toyota Jidosha Kabushiki KaishaInventors: Hiroshi Suyama, Tomohiro Kuroki, Kazushi Wakayama, Gen Ikeda
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Patent number: 10270124Abstract: A lithium secondary battery including a cathode, an anode and a non-aqueous electrolyte. The cathode includes a cathode active material containing lithium-metal oxide of which at least one of metals has a concentration gradient region between a core part and a surface part thereof. The lithium-metal oxide includes elements M1, M2, and M3. M3 has a concentration gradient region with increased concentration between the core part and the surface part, M1 has a concentration gradient region with decreased concentration between the core part and the surface part, and M2 has a constant concentration from the core part and the surface part. The anode includes graphite having an average lattice distance d002 of 3.356 to 3.365 ?.Type: GrantFiled: December 22, 2015Date of Patent: April 23, 2019Assignee: SK INNOVATION CO., LTD.Inventors: Duck-Chul Hwang, Kyung-Bin Yoo, Kook-Hyun Han
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Patent number: 10263246Abstract: An electrode material includes a lithium active material composition. The lithium active material composition includes lithium and an active anode material. The lithium active material composition is coated with a lithium ion conducting passivating material, such that the electrode material is lithiated and pre-passivated. An electrode and a battery are also disclosed. Methods of making an electrode material, electrode and battery that are lithiated and pre-passivated are also disclosed.Type: GrantFiled: November 20, 2015Date of Patent: April 16, 2019Assignee: UT-BATTELLE, LLCInventors: Nancy J. Dudney, Edward W. Hagaman, Gabriel M. Veith, Lance W. Gill, Robert L. Sacci
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Patent number: 10263292Abstract: Provided is a highly reliable nickel-zinc battery including a separator exhibiting hydroxide ion conductivity and water impermeability. The nickel-zinc battery includes a positive electrode containing nickel hydroxide and/or nickel oxyhydroxide; a positive-electrode electrolytic solution in which the positive electrode is immersed, the electrolytic solution containing an alkali metal hydroxide; a negative electrode containing zinc and/or zinc oxide; a negative-electrode electrolytic solution in which the negative electrode is immersed, the electrolytic solution containing an alkali metal hydroxide; a hermetic container accommodating the positive electrode, the positive-electrode electrolytic solution, the negative electrode, and the negative-electrode electrolytic solution; and the separator exhibiting hydroxide ion conductivity and water impermeability and disposed in the hermetic container so as to separate a positive-electrode chamber from a negative-electrode chamber.Type: GrantFiled: November 22, 2016Date of Patent: April 16, 2019Assignee: NGK Insulators, Ltd.Inventors: Hiroshi Hayashi, Naohito Yamada, Kenshin Kitoh
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Patent number: 10263256Abstract: Relating to a 5 V-class spinel type lithium nickel manganese-containing composite oxide having an operating potential of 4.5 V or more with respect to a Li metal reference potential, the present invention proposes a composite oxide being capable of improving cycle properties while suppressing the amount of gas generation under high temperature environments and of increasing thermodynamical stability of a positive electrode in a fully charged state. Proposed is a spinel type lithium nickel manganese-containing composite oxide represented by a general formula [Li(LiaNiyMn2-a-b-y-z-?TibAlzM?)O4-?] (where 0<a, 0<b, 0.30?y<0.60, 0<z, 0??, 2-a-b-y-z-?<1.7, 3?b/a?8, 0.1<b+z+?, 0<z/b?1, and M represents one or two or more metal elements selected from the group consisting of Mg, Fe, Co, Ba, Cr, W, Mo, Y, Zr, Nb, and Ce).Type: GrantFiled: September 16, 2016Date of Patent: April 16, 2019Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Tetsuya Mitsumoto, Hideaki Matsushima, Shinya Kagei
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Patent number: 10256459Abstract: A prelithiated and surface-stabilized anode active material for use in a lithium battery, comprising a protected anode active material particle comprising a surface-stabilizing layer embracing a core particle, wherein the surface-stabilizing layer comprises a lithium- or sodium-containing species chemically bonded to the core particle and the lithium- or sodium-containing species is selected from Li2CO3, Li2O, Li2C2O4, LiOH, LiX, ROCO2Li, HCOLi, ROLi, (ROCO2Li)2, (CH2OCO2Li)2, Li2S, LixSOy, Li4B, Na4B, Na2CO3, Na2O, Na2C2O4, NaOH, NaiX, ROCO2Na, HCONa, RONa, (ROCO2Na)2, (CH2OCO2Na)2, Na2S, NaxSOy, or a combination thereof, wherein X=F, Cl, I, or Br, R=a hydrocarbon group, 0<x?1, and 1?y?4; wherein the lithium- or sodium-containing species is preferably derived from an electrochemical decomposition reaction and the core particle is prelithiated to contain an amount of lithium from 1% to 100% of the maximum lithium content that can be included in the core particle of anode active material.Type: GrantFiled: September 18, 2017Date of Patent: April 9, 2019Assignee: Nanotek Instruments, Inc.Inventors: Aruna Zhamu, Bor Z. Jang
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Patent number: 10232520Abstract: A primary battery includes a cathode having a non-stoichiometric metal oxide including transition metals Ni, Mn, Co, or a combination of metal atoms, an alkali metal, and hydrogen; an anode; a separator between the cathode and the anode; and an alkaline electrolyte.Type: GrantFiled: April 22, 2016Date of Patent: March 19, 2019Assignee: DURACELL U.S. OPERATIONS, INC.Inventors: Paul Albert Christian, Yichun Wang, Nikolay Krastev Iltchev, Kirakodu S. Nanjundaswamy, Jennifer Anne Nelson, Fan Zhang
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Powder for negative electrode of lithium ion secondary battery, and method for producing such powder
Patent number: 10236531Abstract: This invention provides a powder for a negative electrode of a lithium ion secondary battery, which is a powder that includes a silicon oxide powder containing Li. When a molar ratio between Li, Si and O is taken as y:1:x, the average composition of the powder overall satisfies the relation 0.5<x<1.5 and the relation 0.1<y/x<0.8. The volume median diameter of the powder for a negative electrode is within a range from 0.5 to 30 ?m. When X-ray diffraction measurement of the powder is performed using a Cu K? ray, a relation P2/P1?1.0 and a relation P3/P1?1.0 are satisfied, where P1 represents a height of a peak attributed to Li2SiO3, P2 represents a height of a peak attributed to crystalline Si, and P3 represents a height of a peak attributed to Li4SiO4.Type: GrantFiled: December 7, 2015Date of Patent: March 19, 2019Assignee: OSAKA TITANIUM TECHNOLOGIES CO., LTD.Inventors: Shingo Kizaki, Yusuke Kashitani, Kohki Takeshita -
Patent number: 10230132Abstract: A secondary zinc-manganese dioxide secondary cell is disclosed. The cell includes a zinc gel anode, high manganese content cathode in either prismatic or jelly roll form. An aqueous based continuous reel to reel process for formulation and fabrication of the anode and cathode is provided. The cell is contained in a box assembly.Type: GrantFiled: June 30, 2017Date of Patent: March 12, 2019Assignee: Urban Electric Power IncInventors: Melissa Menard, David Kaplin, Ryan Cammarata
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Patent number: 10224539Abstract: Surface modification of LiNi0.4Mn0.4Co0.2O2 (442) compound with certain inert (MxOy) metal oxides viz., Al2O3, Bi2O3, In2O3, Cr2O3, ZrO2, ZnO, MgO has been attempted with a view to improve the structural and cycling stability, especially upon high voltage and high rate cycling conditions. In addition to HF scavenging effect, the protective metal oxide inter-connect layer restricts the number of oxide ion vacancies eliminated during the initial cycling of cathode, resulting in the reduced irreversible capacity loss of the first cycle. Among the surface modified cathodes, Bi2O3 coated LiNi0.4Mn0.4Co0.2O2 cathode exhibits appreciable specific capacity values of 196 (Qdc1) and 175 (Qdc100) mAh g?1 with 89% capacity retention, thus evidencing the superiority of Bi2O3 modifier in improving the electrochemical behavior of pristine LiNi0.4Mn0.4Co0.2O2 cathode. Further, suitability of Bi2O3 coated LiNi0.4Mn0.4Co0.2O2 cathode for high voltage (5.Type: GrantFiled: August 7, 2014Date of Patent: March 5, 2019Assignee: COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESEARCHInventors: Nallathamby Kalaiselvi, Dharmarajan Bhuvaneswari, Ganguli Babu
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Patent number: 10217995Abstract: An active material containing a monoclinic ?-type titanium oxide or a monoclinic ?-type titanium complex oxide. A carbonate ion is disposed on at least a part of a surface of the active material. The active material has a peak belonging to a carbonate ion in at least a. region of 1430±30 cm?1, 1500±30 cm?1 and 2350±30 cm ?1 in an infrared diffuse reflection spectrum obtained using a Fourier transform infrared spectrophotometer.Type: GrantFiled: September 17, 2014Date of Patent: February 26, 2019Assignee: KABUSHIKI KAISHA TOSHIBAInventors: Hiroki Inagaki, Wen Zhang, Takuya Iwasaki, Norio Takami
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Patent number: 10214422Abstract: A method of producing interlayer distance controlled graphene, an interlayer distance controlled graphene composition, and a supercapacitor are provided. A method of producing an interlayer distance controlled graphene involves dispersing a graphene oxide in a solution by using a surfactant, forming a reduced graphene oxide by adding a reducing agent into the solution containing the dispersed graphene oxide, and adding a pillar material that is activated at its both ends by a N2+ group into the solution containing the reduced graphene oxide to control an interlayer distance of the reduced graphene oxide.Type: GrantFiled: October 15, 2014Date of Patent: February 26, 2019Assignee: Research & Business Foundation Sungkyunkwan UniversityInventors: Hyoyoung Lee, Keun Sik Lee
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Patent number: 10217991Abstract: A lithium secondary battery includes a positive electrode, a negative electrode, and a non-aqueous electrolyte, and more particularly, the positive electrode includes a positive active material including lithium-metal oxide in which at least one metal has a continuous concentration gradient from the center to the surface, and the negative electrode includes a negative active material including graphite having an average lattice distance (d002) in the range of 3.356 to 3.365 ?, thereby improving storage characteristics at a high temperature and lifetime characteristics.Type: GrantFiled: June 2, 2015Date of Patent: February 26, 2019Assignee: SK INNOVATION CO., LTD.Inventors: Duck-Chul Hwang, Jin-Sub Lim, Kook-Hyun Han
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Patent number: 10177385Abstract: A nickel-hydrogen secondary battery includes an electrode group including a separator, a positive electrode and a negative electrode, the positive electrode includes a positive electrode active material, the positive electrode active material includes a composite particle including a compound of Co and a compound of Ni, and the ratio R represented by A/B satisfies a relationship of R?0.3, when the amount of jumping in the X-ray absorption fine structure spectrum of the Co in 7600 to 7800 eV and the amount of jumping in the X-ray absorption fine structure spectrum of the Ni in 8300 to 8500 eV obtained by measurement according to a conversion electron yield method are defined as A and B, respectively.Type: GrantFiled: November 11, 2016Date of Patent: January 8, 2019Assignees: FDK CORPORATION, FUJITSU LIMITEDInventors: Yuzo Imoto, Takeshi Ito, Shigekazu Yasuoka, Shuuichi Doi, Takashi Yamazaki, Yuji Kataoka
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Patent number: 10177411Abstract: A nonaqueous electrolyte secondary battery includes: a wound electrode body that is formed by laminating an elongated sheet-shaped positive electrode current collector foil, an elongated sheet-shaped negative electrode current collector foil, and an elongated sheet-shaped separator to obtain a laminate and winding the obtained laminate; a nonaqueous electrolytic solution; and a case that accommodates the wound electrode body and the nonaqueous electrolytic solution. A solid electrolyte interface film derived from an oxalato borate complex is formed on at least a surface of the negative electrode active material layer.Type: GrantFiled: August 18, 2015Date of Patent: January 8, 2019Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Ryo Hanazaki
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Patent number: 10170763Abstract: A lithium metal oxide powder for use as a cathode material in a rechargeable battery, consisting of a core material and a surface layer, the core having a layered crystal structure consisting of the elements Li, a metal M and oxygen, wherein the Li content is stoichiometrically controlled, wherein the metal M has the formula M=Co1-aM?a, with 0?a?0.05, wherein M? is either one or more metals of the group consisting of Al, Ga and B; and the surface layer consisting of a mixture of the elements of the core material and inorganic N-based oxides, wherein N is either one or more metals of the group consisting of Mg, Ti, Fe, Cu, Ca, Ba, Y, Sn, Sb, Na, Zn, Zr and Si.Type: GrantFiled: May 29, 2012Date of Patent: January 1, 2019Assignee: UmicoreInventors: Maxime Blangero, Kyubo Kim, Hyun-Joo Je
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Patent number: 10170760Abstract: The present invention relates to a secondary battery, specifically, a secondary battery having excellent stability and improved output characteristic and low temperature characteristic by including a cathode active material in which at least one of metals forming the cathode active material has a concentration gradient in an entire region from a central portion up to a surface portion; and a conductive material mixture in which carbon nanotube is mixed with carbon black at an appropriate ratio, the carbon black being a spherical nanoparticle.Type: GrantFiled: November 13, 2015Date of Patent: January 1, 2019Assignee: SK Innovation CO., LTD.Inventors: Jin-Sub Lim, Kook-Hyun Han, Duck-Chul Hwang
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Patent number: 10164260Abstract: Provided is a method for producing a positive electrode for a nonaqueous electrolyte secondary battery having superior electrical conductivity with high productivity. The production method disclosed herein includes the following steps: a first kneading step (S10) for kneading electrically conductive carbon fine particles and a hydrophobic binder that gels when contacted by water, in N-methyl-2-pyrrolidone (NMP); a second kneading step (S20) for adding a positive electrode active material and water to a first kneaded product obtained in the first kneading step followed by additional kneading; and a step (S30) for forming a positive electrode active material layer on the surface of a positive electrode current collector by coating a second kneaded product obtained in the second kneading step on the positive electrode current collector. The first kneaded product contains moisture, and the ratio of the mass of the moisture to the mass of the NMP is 0.Type: GrantFiled: April 9, 2015Date of Patent: December 25, 2018Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Ryo Hanazaki
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Patent number: 10164302Abstract: The present invention concerns a process for the recovery of metals and of heat from spent rechargeable batteries, in particular from spent Li-ion batteries containing relatively low amounts of cobalt. It has in particular been found that such cobalt-depleted Li-ion batteries can be processed on a copper smelter by: feeding a useful charge and slag formers to the smelter; adding heating and reducing agents; whereby at least part of the heating and/or reducing agents is replaced by Li-ion batteries containing one or more of metallic Fe, metallic Al, and carbon. Using spent LFP or LMO batteries as a feed on the Cu smelter, the production rate of Cu blister is increased, while the energy consumption from fossil sources is decreased.Type: GrantFiled: November 25, 2014Date of Patent: December 25, 2018Assignee: UmicoreInventors: Sybolt Brouwer, Jeroen Heulens, David Van Horebeek
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Positive electrode active material and non-aqueous electrolyte secondary battery containing the same
Patent number: 10153485Abstract: A positive electrode active material includes particles composed of a compound oxide; and coating layers composed of a compound oxide formed on at least parts of the surfaces of the particles. The particles have a layered structure and include a first compound oxide mainly composed of lithium and nickel. The coating layers include a second compound oxide mainly composed of lithium and titanium. The ratio by weight of the first compound oxide to the second compound oxide is between 96:4 and 65:35. The positive electrode active material has a mean particle diameter of 5 to 20 ?m.Type: GrantFiled: April 9, 2004Date of Patent: December 11, 2018Assignee: MURATA MANUFACTURING CO., LTD.Inventors: Yosuke Hosoya, Yoshikatsu Yamamoto -
Patent number: 10141610Abstract: Provided is a non-aqueous electrolyte secondary battery combining high battery performance in normal use and endurance against overcharge. The non-aqueous electrolyte secondary battery comprises a positive electrode, a negative electrode, and a non-aqueous electrolyte. The positive electrode comprises a positive electrode active material 16. Positive electrode active material 16 is formed of a particulate lithium composite oxide 16c comprising at least lithium, nickel, cobalt, manganese and tungsten; and a nickel oxide layer 16s formed on the lithium composite oxide surface. With the non-lithium metals in lithium composite oxide 16c being 100% by mole, tungsten accounts for 0.05% by mole or greater, but 2% by mole or less. With lithium composite oxide 16c being 100 parts by mass, the nickel oxide content is 0.01 part by mass or greater, but 2 parts by mass or less.Type: GrantFiled: December 4, 2015Date of Patent: November 27, 2018Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Hideyuki Saka, Keiichi Takahashi
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Patent number: 10135066Abstract: A positive electrode active material of the present invention includes lithium cobalt oxide particles; and a surface treatment layer positioned on a surface of the lithium cobalt oxide particle, and the lithium cobalt oxide particle includes lithium deficient lithium cobalt oxide having a Li/Co molar ratio of less than 1, included in an Fd-3m space group, and having a cubic-type crystal structure, in a surface side of the particle. The surface treatment layer includes at least one element selected from the group consisting of transition metals and elements in group 13.Type: GrantFiled: October 2, 2015Date of Patent: November 20, 2018Assignee: LG Chem, Ltd.Inventors: Min Suk Kang, Chi Ho Jo, Ji Hoon Ryu, Sun Sik Shin, Wang Mo Jung
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Patent number: 10128492Abstract: A positive electrode for alkaline storage batteries that enables to improve the active material utilization rate, while suppressing the self-discharge. The positive electrode for alkaline storage batteries includes a support having conductivity, and a positive electrode active material adhering to the support. The positive electrode active material includes particles of a nickel oxide. The particles of the nickel oxide include a first particle group having a particle diameter of 20 ?m or more, and a second particle group having a particle diameter of less than 20 ?m. The first particle group includes a first component with cracks, and a second component without cracks. The proportion of the first particle group in the particles of the nickel oxide is 15 vol % or more, and the proportion by number of the first component in the first particle group is 15% or more.Type: GrantFiled: December 4, 2014Date of Patent: November 13, 2018Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Kiyoshi Hayashi, Yasushi Nakamura, Fumio Kato
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Patent number: 10122012Abstract: The present invention provides a positive electrode active material for lithium ion batteries having excellent battery property. The positive electrode active material for lithium ion batteries is represented by composition formula: LixNi1?yMyO2+?, wherein M is Co as an essential component and at least one species selected from a group consisting of Sc, Ti, V, Cr, Mn, Fe, Cu, Zn, Ga, Ge, Al, Bi, Sn, Mg, Ca, B and Zr, 0.9?x?1.2, 0<y?0.7, ?>0.05, and an average particle size (D50) is 5 ?m to 15 ?m.Type: GrantFiled: April 18, 2016Date of Patent: November 6, 2018Assignee: JX Nippon Mining & Metals CorporationInventors: Shunsuke Kobayashi, Yoshio Kajiya
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Patent number: 10103367Abstract: Present embodiments include a lithium ion battery module having a lineup of prismatic lithium ion battery cells positioned within a cell receptacle area of a housing of the lithium ion battery module. The prismatic battery cells of the lineup are spaced apart from one another in a spaced arrangement by fixed protrusions extending from internal surfaces of the housing forming the cell receptacle area, and the fixed protrusions extend inwardly to form a plurality of discontinuous slots across a width of the cell receptacle area.Type: GrantFiled: August 4, 2015Date of Patent: October 16, 2018Assignee: Johnson Controls Technology CompanyInventors: Richard M. DeKeuster, Robert J. Mack, Jennifer L. Czarnecki
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Patent number: 10079385Abstract: Provided is a positive electrode for an alkaline storage battery, capable of achieving a high charge efficiency over a wide range of temperature including high temperatures. The positive electrode includes a positive electrode material mixture including: a nickel oxide as a positive electrode active material; a first additive; and a second additive differing from the first additive. An amount of sulfate ions SO42? remaining in the nickel oxide is 0.45 mass % or less. The first additive is a compound including at least one selected from the group consisting of ytterbium, indium, calcium, barium, beryllium, antimony, erbium, thulium, and lutetium. The second additive is a compound including at least one selected from the group consisting of titanium, vanadium, scandium, niobium, zirconium, and zinc.Type: GrantFiled: March 4, 2013Date of Patent: September 18, 2018Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventor: Kiyoshi Hayashi
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Patent number: 10050261Abstract: Provided are a cathode material for a lithium secondary battery, and a lithium secondary battery containing the same. The cathode material for a lithium secondary battery comprises: a cathode active material, which is a lithium-transition metal oxide, and a lithium phosphate layer coated on a surface of the cathode active material.Type: GrantFiled: August 8, 2014Date of Patent: August 14, 2018Assignee: INDUSTRY-ACADEMIA COOPERATION GROUP OF SEJONG UNIVERSITYInventors: Seungtaek Myung, Changheum Jo
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Patent number: 10050274Abstract: A power storage device of the present invention includes a positive electrode, a negative electrode, and an electrolyte. At least one of the positive electrode and the negative electrode includes an organic compound as an active material having a portion contributing to an oxidation-reduction reaction. The organic compound is crystalline in both a charged state and a discharged state.Type: GrantFiled: May 11, 2007Date of Patent: August 14, 2018Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Nobuhiko Hojo, Yu Ohtsuka, Taisuke Yamamoto
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Patent number: 10044034Abstract: A negative electrode material for a nonaqueous electrolyte secondary battery of the embodiment include a granular composite product that includes: an organic resin composition; a metal dispersed in the organic resin composition or a metal and an oxide of the metal dispersed in the organic resin composition; an electroconductive carbonaceous material, wherein an elemental ratio A/B (mass/mass) of carbon (A) and hydrogen (B) is 1 or lower.Type: GrantFiled: September 15, 2015Date of Patent: August 7, 2018Assignee: Kabushiki Kaisha ToshibaInventors: Yasuyuki Hotta, Takashi Kuboki, Tomokazu Morita, Sara Yoshio
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Patent number: 10044066Abstract: Electrolyte compositions comprising novel fluorine-containing carboxylic acid ester solvents are described. The fluorine-containing carboxylic acid ester solvents are represented by the formula R1—C(O)O—R2, wherein R1 is CH3CH2— and R2 is —CH2CHF2, R1 is CH3— and R2 is —CH2CH2CHF2, R1 is CH3CH2— and R2 is —CH2CH2CHF2, R1 is CHF2CH2CH2— and R2 is —CH2CH3, or R1 is CHF2CH2— and R2 is —CH2CH3. The electrolyte compositions are useful in electrochemical cells, such as lithium ion batteries.Type: GrantFiled: March 8, 2013Date of Patent: August 7, 2018Assignee: Solvary SAInventors: Charles J. Dubois, George K. Kodokian, Barbara S Nyland
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Patent number: 10026957Abstract: Li-ion cathode materials with improved performance characteristics and precursors to prepare such materials are disclosed. The precursors consist of complex, mixed alkali transition metal oxides of the formula LixAy(MnaNibMc)O2+d, where M represents one or more selected from transition metal elements beside Ni and Mn, and the groups IIA and IIIA elements of the periodic table, x is between 1 and 1.4, y is between 0.1 and 0.5, and x+y is between 1.1 and 1.5, a+b+c=1, the value of d depends on the proportions and average oxidation states of the cation elements Li, A, Mn, Ni and M such that the combined positive charge of the cation elements is balanced by the number of oxygen anions, A represents one or more elements selected from Na, K and Cs. The Li-ion cathode materials are produced by exchange of element(s) A for Li under mild conditions to limit the degree of structural reorganization that occurs during the reaction.Type: GrantFiled: April 24, 2015Date of Patent: July 17, 2018Assignee: Farasis Energy (Ganzhou) Co., Ltd.Inventors: Keith D. Kepler, Hongjian Liu, Floris Tsang, Robbert Vermeulen, Phillip Hailey, Michael Slater
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Patent number: 10017875Abstract: Provided are nickel manganese composite hydroxide particles having a small and uniform particle size and having a double structure which enables to obtain a cathode active material having a hollow structure, and a manufacturing method thereof. When obtaining the nickel manganese composite hydroxide by a reaction crystallization, using an aqueous solution for nucleation, which includes at least a metallic compound that contains nickel, a metallic compound that contains manganese and an ammonium ion donor and controlling the pH value that is measured at a standard solution temperature of 25° C. is 10.5 to 12.0, nucleation is performed in an oxidizing atmosphere in which the oxygen concentration is greater than 1% by volume, and then nuclei are grown by switching the atmosphere from the oxidizing atmosphere to a mixed atmosphere of oxygen and inert gas in which the oxygen concentration is 1% by volume or less.Type: GrantFiled: March 28, 2011Date of Patent: July 10, 2018Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Hiroyuki Toya, Kensaku Mori, Shin Imaizumi, Kenji Ikeuchi, Toshiyuki Osako