Manganese Component Is Active Material Patents (Class 429/224)
  • Patent number: 8883345
    Abstract: Provided is a prismatic battery comprising stacked positive electrode plates, negative electrode plates and separator layers therebetween. The positive and negative electrode plates extend beyond a periphery of the electrode stack. The positive electrode plates are fused to form a positive current collector, and the negative electrode plates are fused to form a negative current collector. Both the positive and negative electrode plates comprise a metal foam and are compressed between about 42 and 45% of the original thickness.
    Type: Grant
    Filed: December 23, 2008
    Date of Patent: November 11, 2014
    Assignee: Encell Technology LLC
    Inventor: Randy Ogg
  • Patent number: 8883346
    Abstract: Provided is a method of manufacturing a prismatic battery, or a series of prismatic batteries. The method comprises stacking positive electrode plates, negative electrode plates and separator layers therebetween. The positive and negative electrode plates extend beyond a periphery of the electrode stack. The positive electrode plates are fused to form a positive current collector, and the negative electrode plates are fused to form a negative current collector.
    Type: Grant
    Filed: March 14, 2013
    Date of Patent: November 11, 2014
    Assignee: Encell Technology
    Inventor: Randy Gene Ogg
  • Publication number: 20140329144
    Abstract: An anode and battery including the anode capable of improving the cycle characteristics while securing the input and output characteristics is provided. The battery includes a cathode, an anode, and an electrolytic solution. The anode includes an anode active material layer on an anode current collector, wherein the anode active material layer includes an anode active material capable of intercalating and deintercalating an electrode reactant, wherein a thickness of the anode active material layer ranges from 60 ?m to 120 ?m, and wherein the anode active material includes a carbon material and at least part of a surface is covered by a covering, the covering including at least one of an alkali metal salt and an alkali earth metal salt.
    Type: Application
    Filed: July 21, 2014
    Publication date: November 6, 2014
    Inventors: Shinya WAKITA, Izaya OKAE
  • Patent number: 8877381
    Abstract: A composite oxide is produced via the following: a raw-material mixture preparation step of preparing a raw-material mixture by mixing a metallic-compound raw material and a molten-salt raw material with each other, the metallic-compound raw material at least including one or more kinds of Mn-containing metallic compounds being selected from the group consisting of oxides, hydroxides and metallic salts that include one or more kinds of metallic elements in which Mn is essential, the molten-salt raw material including lithium hydroxide and lithium nitrate, and exhibiting a proportion of the lithium hydroxide with respect to the lithium nitrate (i.e., (Lithium Hydroxide)/(Lithium Nitrate)) that falls in a range of from 0.05 or more to less than 1 by molar ratio; a molten reaction step of reacting said raw-material mixture at from 300° C. or more to 550° C. or less by melting it: and a recovery step of recovering said composite oxide being generated from said raw-material mixture that has undergone the reaction.
    Type: Grant
    Filed: March 7, 2011
    Date of Patent: November 4, 2014
    Assignee: Kabushiki Kaisha Toyota Jidoshokki
    Inventors: Naoto Yasuda, Hitotoshi Murase, Ryota Isomura
  • Patent number: 8877375
    Abstract: An aqueous active material composition, an electrode, and a rechargeable lithium battery including the same, the aqueous active material composition including an active material; a binder; and a water-soluble cellulose mixture, wherein the water-soluble cellulose mixture includes a first cellulose compound having a degree of substitution of about 0.5 to about 0.9 and a second cellulose compound having a degree of substitution of about 1.1 to about 1.5.
    Type: Grant
    Filed: January 24, 2012
    Date of Patent: November 4, 2014
    Assignees: Samsung SDI Co., Ltd., Robert Bosch GmbH
    Inventors: Kwang-Soo Kim, Su-Jin Yoon, Joong-Woo Nam
  • Patent number: 8877380
    Abstract: A positive active material, a method of preparing the same, and a lithium secondary battery including the positive active material.
    Type: Grant
    Filed: August 2, 2011
    Date of Patent: November 4, 2014
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Hyun-Deok Lee, Yong-Chul Park, Mi-Ran Song, Na-Leum Yoo, Jin-Hyoung Seo, Min-Ju Kim, Gyeong-Jae Heo, Jae-Dong Byun, Sun-Youn Ryou
  • Patent number: 8877379
    Abstract: Disclosed is a positive active material for a rechargeable lithium battery and a rechargeable lithium battery including the same, and the positive active material includes a carbon material having a structure with “n” polycyclic nano sheets, wherein “n” is an integer of 1 to 30 with hexagonal rings having six carbon atoms condensed and substantially aligned in a plane, the polycyclic nano sheets are laminated in a vertical direction to the plane; and a lithium-containing olivine-based compound attached to the surface of the carbon material is formed with a carbon-coating layer on its surface.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: November 4, 2014
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Woon-Suk Jang, Chae-Woong Cho, Bum-Jin Chang, Ki-Jun Kim, Kwi-Seok Choi
  • Publication number: 20140322603
    Abstract: The disclosure is related to battery systems. More specifically, embodiments of the disclosure provide a nanostructured conversion material for use as the active material in battery cathodes. In an implementation, a nanostructured conversion material is a glassy material and includes a metal material, one or more oxidizing species, and a reducing cation species mixed at a scale of less than 1 nm. The glassy conversion material is substantially homogeneous within a volume of 1000 nm3.
    Type: Application
    Filed: June 29, 2014
    Publication date: October 30, 2014
    Inventors: Timothy Holme, Jagdeep Singh, Rainer Fasching, Weston Arthur Hermann, Cheng Chieh Chao, Bradley O. Stimson, Karl Brown
  • Publication number: 20140322607
    Abstract: A lithium-metal-oxide positive electrode having a layered or spinel structure for a non-aqueous lithium electrochemical cell and battery is disclosed comprising electrode particles that are protected at the surface from undesirable effects, such as electrolyte oxidation, oxygen loss or dissolution by one or more lithium-metal-polyanionic compounds, such as a lithium-metal-phosphate or a lithium-metal-silicate material that can act as a solid electrolyte at or above the operating potential of the lithium-metal-oxide electrode. The surface protection significantly enhances the surface stability, rate capability and cycling stability of the lithium-metal-oxide electrodes, particularly when charged to high potentials.
    Type: Application
    Filed: July 9, 2014
    Publication date: October 30, 2014
    Applicant: UCHICAGO ARGONNE, LLC
    Inventors: Michael M. THACKERAY, Sun-Ho KANG
  • Publication number: 20140322608
    Abstract: A method of graphitic petal synthesis includes a step of providing a flexible carbon substrate, such as that including carbon microfibers. The method further includes the step of subjecting flexible carbon substrate to microwave plasma enhanced chemical vapor deposition. The resulting synthesized graphitic petal structure may optionally be coated with PANI.
    Type: Application
    Filed: February 14, 2014
    Publication date: October 30, 2014
    Applicant: PURDUE RESEARCH FOUNDATION
    Inventors: Jonathan Clay Claussen, Anurag Kumar, Timothy S. Fisher, Ronald G. Reifenberger, Guoping Xiong, David Benjamin Jaroch, David Marshall Porterfield
  • Patent number: 8871384
    Abstract: There is provided a non-aqueous electrolytic solution comprising an electrolyte salt, a specific fluorine-containing solvent and a fluorine-containing cyclic carbonate represented by the formula (A1): wherein X1 to X4 are the same or different and each is —H, —F, —CF3, —CHF2, —CH2F, —CF2CF3, —CH2CF3 or —CH2OCH2CF2CF3; at least one of X1 to X4 is —F, —CF3, —CF2CF3, —CH2CF3 or —CH2OCH2CF2CF3, and the non-aqueous electrolytic solution has further excellent noncombustibility and is suitable for lithium secondary batteries.
    Type: Grant
    Filed: February 5, 2008
    Date of Patent: October 28, 2014
    Assignee: Daikin Industries, Ltd.
    Inventors: Meiten Koh, Hideo Sakata, Hitomi Nakazawa, Michiru Tanaka, Akiyoshi Yamauchi
  • Patent number: 8871389
    Abstract: A non-aqueous electrolyte secondary battery uses as its positive electrode active material a mixture of a first lithium-containing transition metal oxide containing nickel and manganese as transition metals and having a crystal structure belonging to the space group R3m and a second lithium-containing transition metal oxide containing nickel, cobalt, and manganese as transition metals and having a crystal structure belonging to the space group R3m, or a mixture of the first lithium-containing transition metal oxide and a lithium cobalt oxide. The first lithium-containing transition metal oxide is LiaNixMnyO2 wherein 1?a?1.5, 0.5?x+y?1, 0<x<1, and 0<y<1. The second lithium-containing transition metal oxide is LibNipMnqCorO2 wherein 1?b?1.5, 0.5?p+q+r?1, 0<p<1, 0<q<1, and 0<r<1.
    Type: Grant
    Filed: June 23, 2009
    Date of Patent: October 28, 2014
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Hideki Kitao, Yoshinori Kida, Noriyuki Shimizu
  • Publication number: 20140315085
    Abstract: Several embodiments related to batteries having electrodes with nanostructures, compositions of such nanostructures, and associated methods of making such electrodes are disclosed herein. In one embodiment, a method for producing an anode suitable for a lithium-ion battery comprising preparing a surface of a substrate material and forming a plurality of conductive nanostructures on the surface of the substrate material via electrodeposition without using a template.
    Type: Application
    Filed: June 2, 2012
    Publication date: October 23, 2014
    Applicant: WASHINGTON STATE UNIVERSITY
    Inventors: M. Grant Norton, Uttara Sahaym
  • Publication number: 20140315083
    Abstract: The present invention provides a graphene coating-modified electrode plate for lithium secondary battery, characterized in that, the electrode plate comprises a current collector foil, graphene layers coated on both surfaces of the current collector foil, and electrode active material layers coated on the graphene layers. A graphene coating-modified electrode plate for lithium secondary battery according to the present invention comprises a current collector foil, graphene layers coated on both surfaces of the current collector foil, and electrode active material layers coated on the graphene layers. The graphene-modified electrode plate for lithium secondary battery thus obtained increases the electrical conductivity and dissipation functions of the electrode plate due to the better electrical conductivity and thermal conductivity of graphene. The present invention further provides a method for producing a graphene coating-modified electrode plate for lithium secondary battery.
    Type: Application
    Filed: November 2, 2011
    Publication date: October 23, 2014
    Applicant: NINGBO INSTITUTE OF MATERIAL TECHNOLOGY AND ENGINEERING, CHINESE ACADEMY OF SCIENCES
    Inventors: Zhaoping Liu, Changlin Tang, Jiangang Zhang, Xufeng Zhou, Huasheng Hu
  • Publication number: 20140315087
    Abstract: A method of preparing a positive active material for a rechargeable lithium battery includes dry-coating a surface of a material capable of doping and dedoping lithium with a carbon nanotube.
    Type: Application
    Filed: November 5, 2013
    Publication date: October 23, 2014
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Dong-Hwan YU, Young-Jin CHOI, Young-Soo JUNG, Ji-Yong LEE, Sung-Hoon KIM
  • Publication number: 20140315100
    Abstract: A rechargeable lithium-sulfur cell comprising an anode, a separator and/or electrolyte, a sulfur cathode, an optional anode current collector, and an optional cathode current collector, wherein the cathode comprises (a) exfoliated graphite worms that are interconnected to form a porous, conductive graphite flake network comprising pores having a size smaller than 100 nm; and (b) nano-scaled powder or coating of sulfur, sulfur compound, or lithium polysulfide disposed in the pores or coated on graphite flake surfaces wherein the powder or coating has a dimension less than 100 nm. The exfoliated graphite worm amount is in the range of 1% to 90% by weight and the amount of powder or coating is in the range of 99% to 10% by weight based on the total weight of exfoliated graphite worms and sulfur (sulfur compound or lithium polysulfide) combined. The cell exhibits an exceptionally high specific energy and a long cycle life.
    Type: Application
    Filed: April 22, 2013
    Publication date: October 23, 2014
    Inventors: Yanbo Wang, Bor Z. Jang, Hui He, Aruna Zhamu, Yi-jun Lin
  • Publication number: 20140315066
    Abstract: The invention relates to an electrolyte battery electrode component having a layer having a surface adjoined by electrolyte in the battery and provided with a fluid-conducting channel structure. In this context, it is envisaged that through the fluid-conducting structure has channels having channel depths in the range from 10 to 200 ?m and/or at least 50% of the thickness of the active layer.
    Type: Application
    Filed: April 12, 2012
    Publication date: October 23, 2014
    Applicant: KARLSRUHER INSTITUT FUR TECHNOLOGIE
    Inventors: Wilhelm Pfleging, Robert Kohler, Johannes Proll
  • Patent number: 8865349
    Abstract: The present invention provides a positive electrode active material that has rate characteristics suitable for nonaqueous electrolyte batteries and particularly nonaqueous electrolyte secondary batteries, a method by which this positive electrode active material can be easily mass produced, and a high-performance nonaqueous electrolyte battery that has a positive electrode active material obtained by this method. The present invention relates to a method of producing a positive electrode active material, the method comprising a step of mixing a carbon source with lithium manganese phosphate LiMnPO4 or a compound LiMn1-xMxPO4 (where, 0?x<1 and M is at least one metal element selected from the group consisting of Co, Ni, Fe, Zn, Cu, Ti, Sn, Zr, V, and Al) containing lithium manganese phosphate LiMnPO4 as a solid solution composition, and heat treating the obtained mixture under an inert gas atmosphere.
    Type: Grant
    Filed: September 20, 2006
    Date of Patent: October 21, 2014
    Assignees: Kanto Denka Kogyo Co., Ltd., Kyushu University, National University Corporation
    Inventors: Shigeto Okada, Tomoyuki Shiratsuchi, Tomoko Iwanaga, Jun-ichi Yamaki, Shinji Iizuka, Osamu Omae, Kumiko Sueto, Takeshi Shimada
  • Publication number: 20140308544
    Abstract: A system and method for stabilizing electrodes against dissolution and/or hydrolysis including use of cosolvents in liquid electrolyte batteries for three purposes: the extension of the calendar and cycle life time of electrodes that are partially soluble in liquid electrolytes, the purpose of limiting the rate of electrolysis of water into hydrogen and oxygen as a side reaction during battery operation, and for the purpose of cost reduction.
    Type: Application
    Filed: March 31, 2014
    Publication date: October 16, 2014
    Applicant: Alveo Energy, Inc.
    Inventors: Colin Deane Wessells, Ali Firouzi, Shahrokh Motallebi, Sven Strohband
  • Publication number: 20140308584
    Abstract: An active material for a nonaqueous electrolyte secondary battery contains a lithium transition metal composite oxide having an ?-NaFeO2-type crystal structure and being represented by the compositional formula: Li1+?Me1??O2 wherein Me is a transition metal element containing Co, Ni and Mn and ?>0. In the lithium transition metal composite oxide, the molar ratio of Li to the transition metal element Me (Li/Me) is 1.2 to 1.4, D10 is 6 to 9 ?m, D50 is 13 to 16 ?m and D90 is 18 to 32 ?m where particle sizes at cumulative volumes of 10%, 50% and 90% in a particle size distribution of secondary particles are D10, D50 and D90, respectively, and the particle size of a primary particle is 1 ?m or less.
    Type: Application
    Filed: October 24, 2012
    Publication date: October 16, 2014
    Applicant: GS Yuasa International Ltd.
    Inventor: Daisuke Endo
  • Publication number: 20140306151
    Abstract: Provided is an active material for a nonaqueous electrolyte secondary battery containing a lithium transition metal composite oxide which has a crystal structure of an ?-NaFeO2 type and is represented by a compositional formula Li1+?Me1??O2 (Me is a transition metal element including Co, Ni and Mn, ?>0). In the lithium transition metal composite oxide, a compositional ratio Li/Me of lithium Li to the transition metal element Me is 1.25 to 1.425, and an oxygen positional parameter, determined from crystal structure analysis by Rietveld method at the time of using a space group R3-m as a crystal structure model based on an X-ray diffraction pattern in a state of a discharge end, is 0.262 or less.
    Type: Application
    Filed: December 5, 2012
    Publication date: October 16, 2014
    Inventor: Daisuke Endo
  • Patent number: 8859148
    Abstract: Provided is an electrode active material comprising a nickel-based lithium transition metal oxide (LiMO2) wherein the nickel-based lithium transition metal oxide contains nickel (Ni) and at least one transition metal selected from the group consisting of manganese (Mn) and cobalt (Co), wherein the content of nickel is 50% or higher, based on the total weight of transition metals, and has a layered crystal structure and an average primary diameter of 3 ?m or higher, wherein the amount of Ni2+ taking the lithium site in the layered crystal structure is 5.0 atom % or less.
    Type: Grant
    Filed: June 2, 2010
    Date of Patent: October 14, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Sinyoung Park, Sung kyun Chang, Hong-Kyu Park, Seung Tae Hong, Youngsun Choi
  • Patent number: 8852806
    Abstract: Disclosed is a novel cathode active material for secondary batteries. More specifically, disclosed is a cathode active material for secondary batteries that reduces deintercalation of oxygen from a crystal structure of Li2MnO3 at a high voltage of 4.3V to 4.6V through incorporation of excess lithium in a transition metal cation layer.
    Type: Grant
    Filed: April 2, 2013
    Date of Patent: October 7, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Sung-Kyun Chang, ByungChun Park, Song Taek Oh, SungJin Kim
  • Patent number: 8852805
    Abstract: The present invention provides an electrode active material, an electrode and a non-aqueous electrolyte secondary battery. The electrode active material contains the following powder (A) and powder (B): (A) a powder of a lithium mixed metal oxide that is represented by the following formula (1) and has a layered rock-salt type crystal structure, the powder having a BET specific surface area of from 3 m2/g to 30 m2/g, Li(Ni1?(x+y)MnxFey)O2??(1) wherein x is within a range of more than 0 to less than 1, y is within a range of more than 0 to not more than 0.1, and x+y is within a range of more than 0 to less than 1; (B) a powder of a lithium mixed metal oxide that has a spinel type crystal structure. The electrode contains the electrode active material. The non-aqueous electrolyte secondary battery includes the electrode as a positive electrode.
    Type: Grant
    Filed: December 15, 2010
    Date of Patent: October 7, 2014
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Maiko Saka, Yuichiro Imanari
  • Patent number: 8852811
    Abstract: According to the present invention, there is provided a process for producing lithium manganate particles having a high output and an excellent high-temperature stability. The present invention relates to a process for producing lithium manganate particles comprising the steps of mixing a lithium compound, a manganese compound and a boron compound with each other; and calcining the resulting mixture in a temperature range of 800 to 1050° C., wherein an average particle diameter (D50) of the boron compound is not more than 15 times an average particle diameter (D50) of the manganese compound, and wherein the lithium manganate particles have a composition represented by the following chemical formula: Li1+xMn2-x-yY1yO4+B in which Y1 is at least one element selected from the group consisting of Ni, Co, Mg, Fe, Al, Cr and Ti, and x and y satisfy the conditions of 0.03?x?0.15 and 0?y?0.20, respectively.
    Type: Grant
    Filed: September 16, 2009
    Date of Patent: October 7, 2014
    Assignee: Toda Kogyo Corporation
    Inventors: Kazumichi Koga, Masayuki Uegami, Hiroaki Masukuni, Kazutoshi Matsumoto
  • Publication number: 20140295280
    Abstract: A cathode active material for a battery includes a material of the formula MgxMn2O4 wherein 0?x?1 and the material has a crystal structure having an open channel formed in a single dimension or along a single dimensional axis. The crystal structure may be an analogue to CaFe2O4, CaMn2O4 or CaTi2O4.
    Type: Application
    Filed: March 27, 2013
    Publication date: October 2, 2014
    Inventors: Chen Ling, Fuminori Mizuno
  • Publication number: 20140295281
    Abstract: The invention relates to a lithiated manganese phosphate and to a composite material comprising same. The lithiated manganese phosphate of the invention has formula I: Li1-xMn1-yDyPO4, wherein D represents a dopant and 0?x?1.0?y<0.15, and it is formed by non-agglomerated particles in the form of small plates. The invention is particularly suitable for use in the field of lithium batteries.
    Type: Application
    Filed: July 11, 2012
    Publication date: October 2, 2014
    Applicant: COMMISSARIAT A L'ENEGIE ATOMIQUE ET AUZ ENERGIES AL TERNATIVES
    Inventors: Thibaut Gutel, Etienne Radvanyi
  • Publication number: 20140295277
    Abstract: A lithium secondary battery is provided which can exhibit excellent battery performances for a long period of time and has an excellent crystal structure stability. The positive electrode of the lithium secondary battery provided according to the present invention includes positive electrode active material particles mainly containing a lithium-containing phosphate compound represented by the general formula: LixM[P(1-y)Ay]O4, where M is one or two or more elements selected from the group consisting of Ni, Mn, Fe and Co; A is a pentavalent metal element; and x and y are real numbers satisfying 0<x?2 and 0<y?0.15.
    Type: Application
    Filed: October 30, 2012
    Publication date: October 2, 2014
    Inventors: Jun Yoshida, Kunihiro Nobuhara, Yoshiumi Kawamura
  • Publication number: 20140295278
    Abstract: A MnO2 electrode active material of high capacity is provided. The high capacity MnO2 has a surface area which is greater than 60 m2/g and the MnO2 is obtained by a process comprising a redox reaction of a Mn (II) salt and permanganate at a reaction temperature less than 30° C. and a pH of 2 to 4. Also provided are a magnesium electrochemical cell having a cathode containing the MnO2 and a rechargeable magnesium battery having a cathode containing the MnO2.
    Type: Application
    Filed: March 26, 2013
    Publication date: October 2, 2014
    Applicant: Toyota Motor Engineering & Manufacturing North America, Inc.
    Inventors: Fuminori MIZUNO, Ruigang Zhang
  • Publication number: 20140295272
    Abstract: Provided is a metal oxygen battery 1 including a positive electrode 2 having oxygen as an active material, a negative electrode 3 having metallic lithium as an active material, and an electrolyte layer 4 interposed between the positive electrode 2 and negative electrode 3. The positive electrode 2 contains oxygen storage material including mixed crystal of hexagonal composite metal oxide expressed by the general formula AxByOz (in which, A is one type of metal selected from a group of Y, Sc, La, Sr, Ba, Zr, Au, Ag, Pt, Pd, B is one type of metal selected from a group of Mn, Ti, Ru, Zr, Ni, Cr, and x=1, 1?y?2, 1?z?7, provided that a case where both A and B are Zr is excluded) and one or more non-hexagonal composite metal oxide expressed by the general formula AxByOz.
    Type: Application
    Filed: August 30, 2013
    Publication date: October 2, 2014
    Inventors: Kiyoshi Tanaami, Bunichi Saito, Takuya Taniuchi, Akihisa Tanaka
  • Publication number: 20140295279
    Abstract: An electrode active material, containing ?-MnO2 which is stabilized with a stabilizing cation or molecule with a radius of from 1.35 to 1.55 ?, and wherein a molar ratio of the stabilizing ion or molecule to Mn is from 0.1 to 0.125, is provided. Also provided are a magnesium electrochemical cell having a cathode containing the stabilized ?-MnO2 and a rechargeable magnesium battery having a cathode containing the stabilized ?-MnO2.
    Type: Application
    Filed: March 26, 2013
    Publication date: October 2, 2014
    Applicant: Toyota Motor Engineering & Manufacturing North America, Inc.
    Inventor: Toyota Motor Engineering & Manufacturing North America, Inc.
  • Publication number: 20140295275
    Abstract: The invention relates to a lithium manganese phosphate/carbon nanocomposite as cathode material for rechargeable electrochemical cells with the general formula LixMnyM1-y(PO4)z/C where M is at least one other metal such as Fe, Ni, Co, Cr, V, Mg, Ca, Al, B, Zn, Cu, Nb, Ti, Zr, La, Ce, Y, x=0.8-1.1, y=0.5-1.0, 0.9<z<1.1, with a carbon content of 0.5 to 20% by weight, characterized by the fact that it is obtained by milling of suitable precursors of LixMnyM1-y(PO4)z with electro-conductive carbon black having a specific surface area of at least 80 m2/g or with graphite having a specific surface area of at least 9.5 m2/g or with activated carbon having a specific surface area of at least 200 m2/g. The invention also concerns a process for manufacturing said nanocomposite.
    Type: Application
    Filed: June 11, 2014
    Publication date: October 2, 2014
    Inventor: Andreas Kay
  • Patent number: 8846249
    Abstract: The positive electrode of a lithium ion secondary battery includes active material particles represented by LixNi1?yMyMezO2+?, and the active material particles include a lithium composite oxide represented by LixNi1?yMyO2, (where 0.95?x?1.1, 0<y?0.75, 0.001?z?0.05). The element M is selected from the group consisting of alkaline-earth elements, transition elements, rare-earth elements, IIIb group elements and IVb group elements. The element Me is selected from the group consisting of Mn, W. Nb, Ta, In, Mo, Zr and Sn, and the element Me is included in a surface portion of the active material particles. The lithium content x in the lithium composite oxide in an end-of-discharge state when a constant current discharge is performed at a temperature of 25° C. with a current value of 1C and an end-of-discharge voltage of 2.5 V satisfies 0.85?x??0.013Ln(z)+0.871.
    Type: Grant
    Filed: June 12, 2006
    Date of Patent: September 30, 2014
    Assignee: Panasonic Corporation
    Inventor: Kensuke Nakura
  • Patent number: 8846224
    Abstract: Disclosed herein is a battery system including two or more kinds of cell lines having different charge and discharge characteristics, wherein each cell line includes one or more battery cells connected in series with each other. In the battery system according to the present invention, the battery cells of at least one cell line exhibit a high-rate charge characteristic, whereas the battery cells of at least another cell line exhibit a high-rate discharge characteristic. Consequently, the high-rate charge and discharge characteristics are improved, and the balance between the charge and discharge characteristics is maintained, whereby the battery system according to the present invention is used as a power source having a high power.
    Type: Grant
    Filed: November 2, 2010
    Date of Patent: September 30, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Jens M. Paulsen, Songhun Yoon, Hong-Kyu Park
  • Patent number: 8846250
    Abstract: Disclosed is a cathode active material comprising a lithium-free metal oxide and a material with high irreversible capacity. A novel lithium ion battery system using the cathode active material is also disclosed. The battery, comprising a cathode using a mixture of a Li-free metal oxide and a material with high irreversible capacity, and an anode comprising carbon instead of Li metal, shows excellent safety compared to a conventional battery using lithium metal as an anode. Additionally, the novel battery system has a higher charge/discharge capacity compared to a battery using a conventional cathode active material such as lithium cobalt oxide, lithium nickel oxide or lithium manganese oxide.
    Type: Grant
    Filed: April 24, 2006
    Date of Patent: September 30, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Eun Young Goh, Seung Tae Hong
  • Publication number: 20140287309
    Abstract: A nonaqueous electrolyte battery includes a positive electrode, a negative electrode and a nonaqueous electrolyte. The negative electrode contains a lithium compound and a negative electrode current collector supporting the lithium compound. A log differential intrusion curve obtained when a pore size diameter of the negative electrode is measured by mercury porosimetry has a peak in a pore size diameter range of 0.03 to 0.2 ?m and attenuates with a decrease in pore size diameter from an apex of the peak. A specific surface area (excluding a weight of the negative electrode current collector) of pores of the negative electrode found by mercury porosimetry is 6 to 100 m2/g. A ratio of a volume of pores having a pore size diameter of 0.05 ?m or less to a total pore volume is 20% or more.
    Type: Application
    Filed: June 11, 2014
    Publication date: September 25, 2014
    Applicant: Kabushiki Kaisha Toshiba
    Inventors: Hidesato SARUWATARI, Hideaki MORISHIMA, Hiroki INAGAKI, Norio TAKAMI
  • Publication number: 20140287310
    Abstract: An electrode material which can improve the mobility of electrons and the mobility of ions at the same time, and, furthermore, does not have a problem of the impairment of the diffusion of lithium ions in a thin layer containing a carbonaceous electron-conductive substance so as to be excellent in terms of load characteristics and energy density, and an electrode and a lithium ion battery are provided. The electrode material of the invention is produced by forming a thin layer made of a carbonaceous electron-conductive substance on surfaces of primary particles made of an electrode active material, in which the carbonaceous electron-conductive substance contains nitrogen atoms.
    Type: Application
    Filed: March 20, 2014
    Publication date: September 25, 2014
    Applicant: SUMITOMO OSAKA CEMENT CO., LTD.
    Inventors: Koji OONO, Takao KITAGAWA, Tatsuya NAKABEPPU, Kazuyo YAMAMOTO
  • Publication number: 20140287311
    Abstract: Hetero-nanostructure materials for use in energy-storage devices are disclosed. In some embodiments, a hetero-nanostructure material (100) includes a silicide nanoplatform (110), ionic host nanoparticles (120) disposed on the silicide nanoplatform (110) and in electrical communication with the silicide nanoplatform (110), and a protective coating (130) disposed on the silicide nanoplatform (110) between the ionic host nanoparticles (120). In some embodiments, the silicide nanoplatform (110) includes a plurality of connected and spaced-apart nanobeams comprising a silicide core (110), ionic host nanoparticles (120) formed on the silicide core, and a protective coating (130) formed on the silicide core (110) between the ionic host nanoparticles (120).
    Type: Application
    Filed: October 31, 2012
    Publication date: September 25, 2014
    Inventors: Dunwei Wang, Sa Zhou
  • Patent number: 8841026
    Abstract: A cathode, a method of preparing the same, and a lithium battery including the cathode. The cathode includes: a current collector; a first cathode active material layer disposed on the current collector; and a second cathode active material layer disposed on the first cathode active material layer, wherein the first cathode active material layer comprises a lithium transition metal oxide having a layered structure, and the second cathode active material layer comprises a lithium transition metal oxide having a spinel structure and an average working potential of 4.5 V or more.
    Type: Grant
    Filed: March 17, 2011
    Date of Patent: September 23, 2014
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Kyu-sung Park, Seung-sik Hwang
  • Publication number: 20140272587
    Abstract: Disclosed are precursor particles of a lithium composite transition metal oxide for lithium secondary batteries, wherein the precursor particles of a lithium composite transition metal oxide are composite transition metal hydroxide particles including at least two transition metals and having an average diameter of 1 ?m to 8 ?m, wherein the composite transition metal hydroxide particles exhibit monodisperse particle size distribution and have a coefficient of variation of 0.2 to 0.7, and a cathode active material including the same.
    Type: Application
    Filed: May 29, 2014
    Publication date: September 18, 2014
    Applicant: LG CHEM, LTD.
    Inventors: Seong Hoon Kang, Byung Chun Park, Ho Suk Shin, Sang Min Park, Hong Kyu Park
  • Publication number: 20140272584
    Abstract: A Li-ion battery is disclosed, the Li-ion battery including an anode, a cathode, a lithium donor formed from a Li-containing material, and an electrolyte in communication with the anode, the cathode, and the lithium donor. The lithium donor may be incorporated into the anode, incorporated into the cathode, a layer formed on either an anode side or a cathode side of a separator of the battery. The lithium donor is formed from Li-containing material insensitive to oxygen and aqueous moisture.
    Type: Application
    Filed: March 15, 2013
    Publication date: September 18, 2014
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Meng Jiang, Xingcheng Xiao, Mei Cai, Li Yang, Bob R. Powell, JR.
  • Publication number: 20140272585
    Abstract: An electrode for an electrochemical energy store, including an active material layer having an active material, a protective layer being at least partially applied to the active material, and the protective layer at least partially including a fluorophosphate-based material. Such an electrode offers a particularly high stability, even when high voltages are present. Also described is a method for manufacturing an electrode, to an electrochemical energy store and to the use of a fluorophosphate-based material for generating a protective layer for an active material of an electrode of an electrochemical energy store.
    Type: Application
    Filed: March 14, 2014
    Publication date: September 18, 2014
    Applicant: Robert Bosch GmbH
    Inventor: Ingo KERKAMM
  • Publication number: 20140272555
    Abstract: A lithium ion battery cathode material, and an electrode prepared from such material, is described. The cathode material has a layered-spinel composite structure. The lithium ion battery operates at a high voltage (i.e. up to about 5 V) and has a desirably high cycling performance and rate capability.
    Type: Application
    Filed: March 15, 2013
    Publication date: September 18, 2014
    Inventors: MARK GERRIT ROELOFS, Jun J. Liu
  • Publication number: 20140272570
    Abstract: A composition for use in a battery electrode including lithium-sulfur particles coated with a transition metal species bonded to a sulfur species. Methods and materials for preparing such a composition. Use of such a compound in a battery.
    Type: Application
    Filed: March 19, 2014
    Publication date: September 18, 2014
    Applicant: Wildcat Discovery Technologies, Inc.
    Inventors: Marissa Caldwell, Steven Kaye, David Keogh
  • Publication number: 20140272588
    Abstract: An alkali metal oxyanion cathode material comprising particles, where the particles carry, on at least a portion of the particle surface, carbon deposit by pyrolysis is described. The particles have the general formula A:M:M?:XO4 where the average valency of M is +2 or greater; A is at least one alkali metal selected from Li, Na and K; M is at least Fe and/or Mn; and M? is a metal of valency of 2+ or more.
    Type: Application
    Filed: March 6, 2014
    Publication date: September 18, 2014
    Applicant: CLARIANT CORPORATION
    Inventors: Guoxian Liang, Steeve Rousselot, Jasmin Dufour
  • Patent number: 8835027
    Abstract: This invention provides lithium-rich compounds as precursors for positive electrodes for lithium cells and batteries. The precursors comprise a Li2O-containing compound as one component, and a second charged or partially-charged component, selected preferably from a metal oxide, a lithium-metal-oxide, a metal phosphate or metal sulfate compound. Li2O is extracted from the above-mentioned electrode precursors to activate the electrode either by electrochemical methods or by chemical methods. The invention also extends to methods for synthesizing and activating the precursor electrodes and to cells and batteries containing such electrodes.
    Type: Grant
    Filed: September 19, 2008
    Date of Patent: September 16, 2014
    Assignee: UChicago Argonne, LLC
    Inventors: Michael M. Thackeray, Sun-Ho Kang, Christopher S. Johnson
  • Patent number: 8835041
    Abstract: The present invention provides an electrode material suitable for use as a cathode in a sodium electrochemical cell or battery, the electrode comprising a layered material of formula NacLidNieMnfMzOb, wherein M comprises one or more metal cation, 0.24?c/b?0.5, 0<d/b?0.23, 0?e/b?0.45, 0?f/b?0.45, 0?z/b?0.45, the combined average oxidation state of the metal components (i.e., NacLidNieMnfMz) is in the range of about 3.9 to 5.2, and b is equal to (c+d+Ve+Xf+Yz)/2, wherein V is the average oxidation state of the Ni, X is the average oxidation state of the Mn, and Y is the average oxidation state of the M in the material. The combined positive charge of the metallic elements is balanced by the combined negative charge of the oxygen anions, the Na is predominately present in a sodium layer, and the Mn, Ni, and M are predominately present in a transition metal layer.
    Type: Grant
    Filed: January 14, 2011
    Date of Patent: September 16, 2014
    Assignee: Uchicago Argonne, LLC
    Inventors: Christopher S. Johnson, Sun-Ho Kang, Donghan Kim, Mahalingam Balasubramanian
  • Patent number: 8835053
    Abstract: Negative active materials and rechargeable lithium batteries including the negative active materials are provided. The negative active material includes an intermetallic compound of Si and a metal, and a metal matrix including Cu and Al. The negative active material may provide a rechargeable lithium battery having high capacity and excellent cycle-life and cell efficiency.
    Type: Grant
    Filed: March 18, 2008
    Date of Patent: September 16, 2014
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Min-Seok Sung, Goo-Jin Jeong, Yong-Mook Kang, Sang-Min Lee, Wan-Uk Choi, Sung-Soo Kim
  • Publication number: 20140255781
    Abstract: A method of forming a carbon coating includes heat treating lithium transition metal composite oxide Li0.9+aMbM?cNdOe, in an atmosphere of a gas mixture including carbon dioxide and compound CnH(2n+2?a)[OH]a, wherein n is 1 to 20 and a is 0 or 1, or compound CnH(2n), wherein n is 2 to 6, wherein 0?a?1.6, 0?b?2, 0?c?2, 0?d?2, b, c, and d are not simultaneously equal to 0, e ranges from 1 to 4, M and M? are different from each other and are selected from Ni, Co, Mn, Mo, Cu, Fe, Cr, Ge, Al, Mg, Zr, W, Ru, Rh, Pd, Os, Ir, Pt, Sc, Ti, V, Ga, Nb, Ag, Hf, Au, Cs, B, and Ba, and N is different from M and M? and is selected from Ni, Co, Mn, Mo, Cu, Fe, Cr, Ge, Al, Mg, Zr, W, Ru, Rh, Pd, Os, Ir, Pt, Sc, Ti, V, Ga, Nb, Ag, Hf, Au, Cs, B, Ba, and a combination thereof, or selected from Ti, V, Si, B, F, S, and P, and at least one of the M, M?, and N comprises Ni, Co, Mn, Mo, Cu, or Fe.
    Type: Application
    Filed: March 7, 2014
    Publication date: September 11, 2014
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: In Hyuk SON, Jun Young MUN, Jin-Hwan PARK, Chan Ho PAK, Seung Jae LEE, Hyo Rang KANG
  • Publication number: 20140255783
    Abstract: The non-aqueous electrolyte secondary battery provided by this invention comprises a positive electrode and a negative electrode, wherein the positive electrode has a positive electrode active material layer comprising a positive electrode active material as a primary component, and the negative electrode has a negative electrode active material layer comprising a negative electrode active material as a primary component, having a negative electrode active material's linseed oil absorption number B (mL/100 g) to positive electrode active material's DBP absorption number A (mL/100 g) ratio B/A of 1.27 to 1.79.
    Type: Application
    Filed: October 20, 2011
    Publication date: September 11, 2014
    Inventors: Koji Takahata, Akihiro Ochiai