Alkalated Transition Metal Chalcogenide Component Is Active Material Patents (Class 429/231.1)
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Patent number: 12206096Abstract: An anode active material for a secondary battery according to an embodiment of the present invention includes first particles serving as a core active material and second particles attached on surfaces of the first particles. A weight of the second particles based on 100 weight parts of a total weight of the first particles and the second particles satisfies a predetermined relation. A secondary battery including the anode active material is provided.Type: GrantFiled: December 16, 2021Date of Patent: January 21, 2025Assignee: SK On Co., Ltd.Inventors: Mi Ryeong Lee, Hee Gyoung Kang, Jong Hyuk Lee
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Patent number: 12199271Abstract: A porous silicon-containing composite includes: a porous core including a porous silicon composite secondary particle; and a shell on at least one surface of the porous core, the shell including a first graphene, wherein the porous silicon composite secondary particle includes an aggregate of a first primary particle including silicon, a second primary particle including a structure and second graphene on at least one surface of the first primary particle and the second primary particle, and wherein at least one of a shape and a degree of oxidation of the first primary particle and the second primary particle are different. Also an electrode including the porous silicon-containing composite, a lithium battery including the electrode, and a device including the porous silicon-containing composite or the carbon composite.Type: GrantFiled: May 12, 2023Date of Patent: January 14, 2025Assignees: SAMSUNG ELECTRONICS CO., LTD., SAMSUNG SDI CO., LTD.Inventors: Junghyun Choi, Inhyuk Son, Mijong Kim, Sangkook Mah, Jumyeung Lee, Minwoo Lim, Sungsoo Han
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Patent number: 12199281Abstract: The present invention relates to a positive electrode active material and a lithium secondary battery including the same, and more particularly, to a positive electrode active material which includes an overlithiated lithium manganese-based oxide including at least lithium, nickel, manganese and a doping metal, and in which the degradation in stability caused by excessive amounts of lithium and manganese in the lithium manganese-based oxide is mitigated and/or prevented by controlling the concentration of a transition metal in the lithium manganese-based oxide for each region, and a lithium secondary battery including the same.Type: GrantFiled: March 23, 2023Date of Patent: January 14, 2025Assignee: ECOPRO BM CO., LTD.Inventors: Ra Na Lim, A Reum Yang, Gyun Joong Kim, Kyung Min Lim, Hye Bin Kim
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Patent number: 12191490Abstract: The purpose of the present disclosure is to provide a nonaqueous electrolyte secondary battery which is provided with a negative electrode mixture layer that exhibits excellent electrolyte absorbing properties.Type: GrantFiled: April 14, 2020Date of Patent: January 7, 2025Assignee: SANYO Electric Co., Ltd.Inventors: Takao Tsuda, Takuya Shinomiya, Takamitsu Tashita, Fumikazu Mizukoshi
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Patent number: 12176530Abstract: A positive electrode plate that has a positive electrode active material layer formed on a positive electrode core, wherein the positive electrode core has, on an edge side, a thick portion which has a thickness that is greater than the thickness of a portion of the positive electrode core that has the positive electrode active material layer formed on both sides, and the positive electrode plate has a first region that extends into the thick portion from the portion of the positive electrode core that has the positive electrode active material layer formed on both sides and a second region that is positioned outside the first region in the thick portion. The average maximum diameter of the metal crystal grains that compose the first region is smaller than those of the second region.Type: GrantFiled: December 24, 2019Date of Patent: December 24, 2024Assignee: SANYO Electric Co., Ltd.Inventors: Kazuaki Tamura, Yoshifumi Magari, Atsutoshi Ako, Akira Nishida, Kentaro Tsukamoto, Tomoyuki Yamada
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Patent number: 12166201Abstract: An electrode structure includes a base layer including a first active material, and a plurality of active material plates on a first surface of the base layer and spaced apart from one another, the plurality of active material plates including a second active material. An active material density of the base layer is less than an active material density of an active material plate of the plurality of active material plates.Type: GrantFiled: June 15, 2023Date of Patent: December 10, 2024Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Hwiyeol Park, Huisu Jeong, Kyounghwan Kim, Jeongkuk Shon, Junhyeong Lee, Sungjin Lim, Jin S. Heo
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Patent number: 12148875Abstract: A lithium secondary battery including a positive electrode, a negative electrode comprising a negative electrode current collector, and an electrolyte disposed between the positive electrode and the negative electrode; and a lithium metal layer on the negative electrode current collector in the negative electrode. The electrolyte includes a first electrolyte layer and a second electrolyte disposed on the first electrolyte layer, wherein the first electrolyte layer faces the negative electrode, and the second electrolyte layer faces the positive electrode. The first electrolyte layer has higher ion conductivity than the second electrolyte layer, and wherein the lithium metal layer is formed by migration of lithium ions from the positive electrode after charging.Type: GrantFiled: October 31, 2019Date of Patent: November 19, 2024Assignee: LG ENERGY SOLUTION, LTD.Inventors: Eunkyung Park, Minchul Jang, Suk Il Youn, Byoungkuk Son, Changhun Park, Doyeon Kim, Bora Jung, Yeilin Ham
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Patent number: 12119490Abstract: Provided is a positive electrode active material including a first lithium oxide represented by Li2+xNi1?yA1yO2?zA2z, where ?0.5?x?0.3, 0?y?0.1, and 0?z?0.3. Here, at least one of y and z is not 0. A1 includes at least one selected from the group consisting of Ga, Bi, Ba, Y, Sn, Ca, W, and Ta. A2 includes at least one selected from the group consisting of halogen elements and S.Type: GrantFiled: February 21, 2019Date of Patent: October 15, 2024Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Kosuke Kuroda, Hiroshi Kawada, Atsushi Fukui
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Patent number: 12119452Abstract: An all-inorganic electrolyte formulation for use in a lithium ion battery system comprising at least one of each a phosphoranimine, a phosphazene, a monomeric organophosphate and a supporting lithium salt. The electrolyte preferably has a melting point below 0° C., and a vapor pressure of combustible components at 60.6° C. sufficiently low to not produce a combustible mixture in air, e.g., less than 40 mmHg at 30° C. A solid electrolyte interface layer formed by the electrolyte with an electrode is preferably thermally stable ?80° C.Type: GrantFiled: July 6, 2020Date of Patent: October 15, 2024Assignee: New Dominion Enterprises, Inc.Inventors: Mason K. Harrup, Jay Fraser
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Patent number: 12113187Abstract: The present invention provides a method for recovering valuable metals from waste lithium ion batteries. The method comprises: short-circuit discharging, dismantling, crushing, roasting, and screening on waste lithium ion batteries to obtain active electrode powders; using alkaline solution to wash the active electrode powders, then filtering to remove copper and aluminum; drying the activated electrode powder after alkaline washing treatment, mix the dried activated electrode powder with starch and concentrated sulfuric acid and stir evenly to obtain the mixed material; calcining the mixed material with controlling the atmosphere; taking out the product obtained from calcination and using deionized water to extract the leachate and leaching residue with valence metal ions, and then obtaining the leachate after filtering.Type: GrantFiled: October 31, 2023Date of Patent: October 8, 2024Assignees: GEM CO., LTD., JINGMEN GEM CO., LTD.Inventors: Kaihua Xu, Liangxing Jiang, Jian Yang, Kun Zhang, Chenwei Li, Yongan Chen, Yanqing Lai
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Patent number: 12113164Abstract: Metal-ion battery cells are provided that take advantage of the disclosed “doping” process. The cells may be fabricated from anode and cathode electrodes, a separator, and an electrolyte. A metal-ion additive may be incorporated into (i) one or more of the electrodes, (ii) the separator, or (iii) the electrolyte. The metal-ion additive provides additional donor ions corresponding to the metal ions stored and released by anode and cathode active material particles. An activation potential may then be applied to the anode and cathode electrodes to release the additional donor ions into the battery cell.Type: GrantFiled: May 10, 2023Date of Patent: October 8, 2024Assignee: SILA NANOTECHNOLOGIES, INC.Inventors: Gleb Yushin, Bogdan Zdyrko, Alexander Thomas Jacobs, Eugene Michael Berdichevsky
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Patent number: 12113176Abstract: An all-solid battery includes: a solid electrolyte layer mainly composed of oxide-based solid electrolyte; a first electrode layer formed on a first principal face of the solid electrolyte layer, the first electrode layer containing an active material; a second electrode layer formed on a second principal face of the solid electrolyte layer, the second electrode layer containing another active material, wherein no collector layer that is in contact with the second electrode layer is provided in a direction in which the solid electrolyte layer, the first electrode layer, and the second electrode layer are stacked, and the second electrode layer includes board-shaped carbon.Type: GrantFiled: August 12, 2020Date of Patent: October 8, 2024Assignee: TAIYO YUDEN CO., LTD.Inventors: Sachie Tomizawa, Daigo Ito, Chie Kawamura
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Patent number: 12107222Abstract: Disclosed is a liquid electrolyte for use in lithium-ion, lithium-metal, and lithium-sulfur batteries, in which the liquid electrolyte comprises at least one organic nonlinear carbonate, at least one lithium salt, and at least one cyclic sulfoxide, and in which the liquid electrolyte does not comprise a combination of propylene carbonate, tetrahydrothiophene-1-oxide, and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI). Also disclosed is a lithium secondary battery comprising an anode, a cathode, a separator, and the liquid electrolyte for use in lithium-ion, lithium-metal, and lithium-sulfur batteries.Type: GrantFiled: July 20, 2019Date of Patent: October 1, 2024Assignee: FORSCHUNGSZENTRUM JUELICH GMBHInventors: Kristina Oldiges, Gunther Brunklaus, Mariano Gruenebaum, Isidora Cekic-Laskovic, Martin Winter
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Patent number: 12087907Abstract: An electrolyte including an imidazolium salt compound and a pyridine compound. The electrolyte, includes a compound of Formula I and a compound of Formula II: where R1 is selected from halo, cyano, substituted or unsubstituted C1-C12 alkyl, substituted or unsubstituted C2-C12 alkenyl, substituted or unsubstituted C2-C12 alkynyl, substituted or unsubstituted C2-C12 alkoxy, substituted or unsubstituted C3-C12 cycloalkyl, and substituted or unsubstituted C6-C12 aryl; and R11, R12, R13, R14 and R15 are each independently selected from H, halo, cyano, substituted or unsubstituted C1-C12 alkyl, substituted or unsubstituted C2-C12 alkenyl, substituted or unsubstituted C2-C12 alkynyl, substituted or unsubstituted C2-C12 alkoxy, substituted or unsubstituted C3-C12 cycloalkyl, and substituted or unsubstituted C6-C12 aryl; when substituted, the substituent is halo or cyano.Type: GrantFiled: March 3, 2020Date of Patent: September 10, 2024Assignee: NINGDE AMPEREX TECHNOLOGY LIMITEDInventors: Junfei Liu, Lilan Zhang, Chao Tang, Jianming Zheng
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Patent number: 12074317Abstract: A rechargeable electrochemical battery cell with a housing, a positive electrode, a negative electrode and an electrolyte which contains SO2 and a conducting salt of the active metal of the cell, whereby at least one of the electrodes contains a binder chosen from the group: Binder A, which consists of a polymer, which is made of monomeric structural units of a conjugated carboxylic acid or of the alkali salt, earth alkali salt or ammonium salt of this conjugated carboxylic acid or a combination thereof or binder B which consists of a polymer based on monomeric styrene structural units or butadiene structural units or a mixture of binder A and B.Type: GrantFiled: December 13, 2020Date of Patent: August 27, 2024Assignee: Innolith Technology AGInventors: Christian Pszolla, Laurent Zinck, Markus Borck, Claudia Wollfarth, Julia Thümmel, Heide Biollaz
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Patent number: 12074300Abstract: The invention provides a method of charging and/or discharging an electrochemical cell at a high rate, wherein the electrochemical cell has a working electrode comprising a niobium tungsten oxide and/or a niobium molybdenum oxide. The invention also provides an electrode comprising a niobium tungsten oxide wherein, the ratio of Nb2O5 to WO; is from 8:5 to 11:20, and an electrode comprising niobium molybdenum oxide, wherein the ratio of Nb2O5 to MoO3 is from 6:1 to 1:3.Type: GrantFiled: June 7, 2019Date of Patent: August 27, 2024Assignee: CAMBRIDGE ENTERPRISE LIMITEDInventors: Clare Grey, Kent Griffith
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Patent number: 12068458Abstract: According to one embodiment, provided is an electrode group including a stack that includes a positive electrode and a negative electrode. A first width of the positive electrode active material-containing layer of the positive electrode in a first direction is smaller than a second width of the negative electrode active material-containing layer of the negative electrode in the first direction. The electrode group has a wound structure where the stack is wound along the first direction. A length L corresponding to a difference between the second and first widths, a mass per unit area Ma of the negative electrode active material-containing layer, and a ratio p/n of a capacity p of the positive electrode to a capacity n of the negative electrode satisfy a relationship of 40 mg/m?(L×Ma)/(p/n)?60 mg/m.Type: GrantFiled: August 12, 2021Date of Patent: August 20, 2024Assignee: KABUSHIKI KAISHA TOSHIBAInventors: Asuna Hagiwara, Masanori Tanaka
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Patent number: 12053630Abstract: The subject matter of this specification can be embodied in, among other things, an implantable pulse generator device having one or more electrodes, and circuitry that includes one or more processors and memory, the memory having instructions stored thereon which, when executed by the one or more processors, cause the one or more processors to perform operations including driving the one or more electrodes to deliver a first set of stimulation sessions having a first duty cycle, and subsequently driving the one or more electrodes to deliver a second set of stimulation sessions having a second duty cycle that is less frequent than the first duty cycle.Type: GrantFiled: May 5, 2021Date of Patent: August 6, 2024Assignee: Coloplast A/SInventors: Peter Jacobson, Alan Ostroff
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Dual board-to-board connector battery management circuit module utilizing a switch-back service loop
Patent number: 12055973Abstract: The disclosed technology relates to a dual board-to-board connector battery management circuit module utilizing a switch-back service loop for a battery pack. The management circuit module is coupled to a first and second terminal of a battery pack and includes a first board-to-board connector disposed proximal to a first end of the management circuit module; and a second board-to-board connector disposed proximal to a second end of the management circuit module. The second board-to-board connector is positioned opposite the first board-to-board connector.Type: GrantFiled: September 11, 2020Date of Patent: August 6, 2024Assignee: Apple Inc.Inventors: Depeng Wang, Andrew U. Leopold, Gregory N. Stevens, Jonathan C. Wilson, James B. Smith -
Patent number: 12040441Abstract: A method of forming a battery electrode includes spraying a suspension of nanoparticle sized metal oxide to create an active layer.Type: GrantFiled: November 1, 2021Date of Patent: July 16, 2024Assignee: HHeLi, LLCInventors: Paige L. Johnson, James Dean Fleetwood, II
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Patent number: 12040455Abstract: An electrochemical energy storage apparatus and a device are provided. The electrochemical energy storage apparatus includes a positive electrode plate, a negative electrode plate, a separator, and an electrolyte, where the positive electrode plate includes a positive electrode current collector, a positive electrode active substance layer disposed on at least one surface of the positive electrode current collector, and a safety layer disposed between the positive electrode active substance layer and the positive electrode current collector; the positive electrode active substance layer includes a positive electrode active substance; the safety layer includes a binding substance, a conductive substance, and an overcharge sensitive substance; the overcharge sensitive substance is a polymer containing monosaccharide structural units and containing at least one of carbonate groups or phosphate groups; the electrolyte includes a solvent and an electrolytic salt; and the solvent includes a carbonate-based solvent.Type: GrantFiled: January 31, 2022Date of Patent: July 16, 2024Assignee: CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITEDInventor: Yang Yu
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Patent number: 12015141Abstract: A non-aqueous electrolyte secondary battery comprises a positive electrode, a negative electrode, a separator, and an electrolyte solution. At least part of the separator is interposed between the positive electrode and the negative electrode. The negative electrode includes a negative electrode substrate and a negative electrode active material layer. The negative electrode active material layer is placed on a surface of the negative electrode substrate. Voids are formed in the negative electrode active material layer. In a cross section parallel to a thickness direction of the negative electrode active material layer, the voids have an average equivalent circle diameter from 9.6 ?m to 35.8 ?m, an average circularity of 0.26 or more, and an area percentage from 3.1% to 30.9%.Type: GrantFiled: September 24, 2021Date of Patent: June 18, 2024Assignee: Prime Planet Energy & Solutions, Inc.Inventors: Atsushi Obayashi, Hikaru Yoshida
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Patent number: 12014632Abstract: The invention relates to a method for detecting beacons (4) in the surroundings of an ego vehicle (5), comprising the steps of: capturing (S1) a sequence of camera images (1) of a section of the surroundings by means of a-camera system (6) of the ego vehicle (5), detecting (S2) bright light spots in the recorded camera image (1), cutting out (S3) regions (3) containing the detected bright light spots in the camera image (1), classifying (S4) the cut-out regions (3), classing (S5) the bright light spots as beacons (4) if the classified bright light spots are detected repeatedly and therefore a threshold value of a counter is exceeded.Type: GrantFiled: May 8, 2019Date of Patent: June 18, 2024Assignee: CONTI TEMIC MICROELECTRONIC GMBHInventors: Elias Strigel, Martin Pfitzer, Stefan Heinrich, Dieter Kroekel
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Patent number: 12002961Abstract: The present disclosure relates to an electrode for a lithium secondary battery which includes: an electrode current collector; a primer coating layer disposed on at least one surface of the electrode current collector and including a binder and a conductive material; and an electrode active material layer disposed on the primer coating layer, wherein the binder includes poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) containing vinylidene fluoride (VDF)-derived repeating units and hexafluoropropylene (HFP)-derived repeating units, the content of HFP-derived repeating units in PVDF-HFP is 2-13 wt %, and the primer coating layer has a thickness of 0.8-10 ?m.Type: GrantFiled: July 31, 2019Date of Patent: June 4, 2024Assignee: LG Energy Solution, Ltd.Inventors: Jun-Soo Park, Bum-Young Jung
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Patent number: 11996564Abstract: The present disclosure relates to a nano-engineered coating for cathode active materials, anode active materials, and solid state electrolyte materials for reducing corrosion and enhancing cycle life of a battery, and various process for applying the disclosed coating.Type: GrantFiled: May 27, 2016Date of Patent: May 28, 2024Assignee: Forge Nano Inc.Inventors: Fabio Albano, Kevin Dahlberg, Erik Anderson, Subhash Dhar, Srinivasan Venkatesan
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Patent number: 11973212Abstract: The present invention relates to a positive electrode active material and a lithium secondary battery including the same, and more particularly, to a bimodal-type positive electrode active material including a first lithium composite oxide, which is a small particle, and a second lithium composite oxide, which is a large particle, these particles having different particle diameters, wherein the positive electrode active material makes it possible to prevent deterioration in electrochemical properties and stability thereof, which are generated due to non-uniform formation of a coating layer at least partially coating surfaces of the small and large particles, a positive electrode including the positive electrode active material, and a lithium secondary battery using the same.Type: GrantFiled: June 23, 2021Date of Patent: April 30, 2024Assignee: ECOPRO BM CO., LTD.Inventors: Jung Bae Park, Hyun Jong Yu, Moon Ho Choi
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Patent number: 11962005Abstract: The present disclosure provides a positive electrode active material having a spinel-type crystal structure that can reduce an increase in resistance and a decrease in capacity retention rate due to repeated charging and discharging of a non-aqueous electrolyte secondary battery. The positive electrode active material disclosed herein is configured of a lithium manganese composite oxide having a spinel-type crystal structure, wherein the lithium manganese composite oxide includes secondary particles in which a plurality of primary particles are aggregated, an average particle diameter of the secondary particles based on a SEM image is 10 ?m or more and 20 ?m or less, an average particle diameter of the primary particles based on a SEM image is 4 ?m or more and 8 ?m or less, and nickel atoms are provided in the surface layer portion of the secondary particles.Type: GrantFiled: October 12, 2021Date of Patent: April 16, 2024Assignee: Prime Planet Energy & Solutions, Inc.Inventors: Yoshinari Makimura, Hiroyuki Yamaguchi, Masataka Tomita
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Patent number: 11949071Abstract: Ionic liquids that can be used to solvate cyclic carbonate esters and halogenated analogues thereof are disclosed.Type: GrantFiled: May 15, 2015Date of Patent: April 2, 2024Assignee: NOHMs Technologies, Inc.Inventors: Surya Moganty, Gabriel Torres, Jonathan Lee
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Patent number: 11942632Abstract: A positive electrode active material particle includes a core that contains lithium cobalt oxide represented by the following Chemical Formula LiaCo(1-x)MxO2-yAy and a shell that is coated on the surface of the core and contains composite metal oxide of a metal with an oxidation number of +2 and a metal with an oxidation number of +3. In particular, M is at least one selected from the group consisting of Ti, Mg, Zn, Si, Al, Zr, V, Mn, Nb and Ni. A is oxygen-substitutional halogen and 1.00?a?1.05, 0?x?0.05, and 0?y?0.001.Type: GrantFiled: October 4, 2017Date of Patent: March 26, 2024Assignee: LG Energy Solution, Ltd.Inventors: Hyuck Hur, Chi Ho Jo, Bo Ram Lee, Sung bin Park, Young uk Park, Wang Mo Jung
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Patent number: 11878605Abstract: Described herein are battery modules comprising integrated module converters, electric-vehicle battery systems comprising such modules, and methods of operating thereof. An electric-vehicle battery system comprises a high-voltage battery pack and high-voltage contactors that controllably isolate the pack's high-voltage area from other areas in the vehicle. The pack comprises multiple battery modules with battery cells and a primary module converter constantly connected to these cells. Each module has a lower voltage than the entire pack. The power output from the primary module converters is used to operate a battery controller and to close/activate the contactors in response to the switch position (e.g., an ignition switch). The primary module converters can be either constantly activated or controllably activated in response to the switch moving into an activated position. For example, a secondary module converter, with a lower power rating, can be used for this primary module converter activation.Type: GrantFiled: May 18, 2023Date of Patent: January 23, 2024Assignee: DIMAAG-AI, Inc.Inventors: Ian Wright, George Fellingham
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Patent number: 11870040Abstract: According to the present disclosure, a technique capable of suppressing an internal short circuit caused by a peeled metal piece and obtaining a safer secondary battery is provided. An electrode plate (negative electrode plate) disclosed herein includes a negative electrode core including copper or a copper alloy, a negative electrode active material layer applied to a surface of the negative electrode core, and a negative electrode tab protruding to the outside from one end side in a width direction. In the negative electrode plate, a first region having an oxide film having a thickness of 40 nm to 200 nm is formed in a region of 0.01 mm to 0.2 mm from an outer end side of the negative electrode tab toward the inside in the width direction, and the first region 22t1 extends along the outer end side 22ta of the negative electrode tab 22t.Type: GrantFiled: January 14, 2022Date of Patent: January 9, 2024Assignee: Prime Planet Energy & Solutions, Inc.Inventors: Kentaro Tsukamoto, Yoshifumi Magari
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Patent number: 11855282Abstract: Provided are compositions, systems, and methods of making and using pre-lithiated cathodes for use in lithium ion secondary cells as the means of supplying extra lithium to the cell. The chemically or electrochemically pre-lithiated cathodes include cathode active material that is pre-lithiated prior to assembly into an electrochemical cell. The process of producing pre-lithiated cathodes includes contacting a cathode active material to an electrolyte, the electrolyte further contacting a counter electrode lithium source and applying an electric potential or current to the cathode active material and the lithium source thereby pre-lithiating the cathode active material with lithium. An electrochemical cell is also provided including the pre-lithiated cathode, an anode, a separator and an electrolyte.Type: GrantFiled: June 16, 2022Date of Patent: December 26, 2023Assignee: CAMX Power LLCInventors: David Ofer, Jane Rempel, Suresh Sriramulu
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Patent number: 11848411Abstract: A cathode configured to use oxygen as a cathode active material, the cathode comprising a lithium-containing metal oxide comprising at least one of: a spinel compound represented by Formula 1 Li1±xM2±yO4????Formula 1 wherein, in Formula 1, M is at least one metal element belonging to Group 2 to Group 16 of the periodic table of the elements, 0<x<1, 0<y<1, 0<?1?1, 0<a<2, 0.3<b<5, and 0<??3; a spinel compound represented by Formula 2 Li4±aM5±bO12????Formula 2 wherein, in Formula 2, M is at least one metal element belonging to Group 2 to Group 16 of the periodic table of the elements, 0<x<1, 0<y<1, 0<?1?1, 0<a<2, 0.3<b<5, and 0<??3; or a perovskite compound represented by Formula 3 LixAyGzO3??.Type: GrantFiled: October 7, 2019Date of Patent: December 19, 2023Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Sangbok Ma, Hyukjae Kwon, Hyunpyo Lee, Myungjin Lee, Donghwa Seo, Dongmin Im
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Patent number: 11804637Abstract: The present application relates to a battery module, comprising a first type of battery cells and a second type of battery cells electrically connected at least in series, wherein the first type of battery cells and the second type of battery cells are battery cells with different chemical systems, the first type of battery cells comprises N first battery cells, the second type of battery cells comprises M second battery cells, N and M are positive integers, the first battery cell comprises a first separator and a first electrolyte, the second battery cell comprises a second separator and a second electrolyte, a kinetic characteristic factor x1 of the first battery cell is: x1=1000×(?1×r1)/(?1×t1×?1), a kinetic characteristic factor x2 of the second battery cell is: x2=1000×(?2×r2)/(?2×t2×?2), and x1 and x2 satisfy: 0.01?x1/x2?160.Type: GrantFiled: August 18, 2022Date of Patent: October 31, 2023Assignee: Contemporary Amperex Technology Co., LimitedInventors: Qian Liu, Yonghuang Ye, Chengdu Liang, Haizu Jin
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Patent number: 11791464Abstract: Provided is a cathode active material comprising particles each containing a lithium composite oxide; and a coating layer containing an ammonium phosphate compound and coating each of the particles.Type: GrantFiled: April 13, 2020Date of Patent: October 17, 2023Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventor: Hirotetsu Suzuki
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Patent number: 11791494Abstract: A nonaqueous electrolyte secondary battery according to an embodiment of the present disclosure includes a separator which contains a first region located in a flat part of an electrode body and second regions located in a pair of curved parts, the ratio (B/A) of the air permeability (B) in each of the second regions to the air permeability (A) in the first region being 0.5 or more and 0.9 or less. Further, in a section passing through the center in the axial direction of the electrode body and being perpendicular to the axial direction, the ratio (SB/SA) of the sectional area (SB) of the pair of curved parts to the sectional area (SA) of the flat part is 0.28 or more and 0.32 or less.Type: GrantFiled: September 25, 2019Date of Patent: October 17, 2023Assignee: SANYO Electric Co., Ltd.Inventors: Junichi Yogo, Masashi Muraoka, Keisuke Minami
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Patent number: 11777145Abstract: A battery includes a substrate; a composite cathode disposed on the substrate; a solid-state electrolyte disposed on the composite cathode; and a lithium anode disposed on the solid-state electrolyte, such that the composite cathode comprises a gel polymer electrolyte layer and a porous cathode active material layer. A method of forming a cathode for a solid-state battery includes mixing an active cathode material, at least one of a conductive carbon component and an electronic conductive component, and a polymer binder to form a slurry; immersing the slurry in an alcohol reagent to form a porous disc structure by phase conversion; and immersing the porous disc structure in a liquid electrolyte to form the cathode.Type: GrantFiled: June 24, 2021Date of Patent: October 3, 2023Assignees: CORNING INCORPORATED, Shanghai Institute of Ceramics Chinese Academy of SciencesInventors: Michael Edward Badding, Mingli Cai, Jun Jin, Zhen Song, Zhaoyin Wen, Tongping Xiu, Liu Yao
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Patent number: 11757134Abstract: Provided is a secondary lithium battery including: a positive electrode plate that is a sintered lithium complex oxide plate; a negative electrode containing carbon and styrene butadiene rubber (SBR); and an electrolytic solution containing lithium borofluoride (LiBF4) in a non-aqueous solvent composed of ?-butyrolactone (GBL), or composed of ethylene carbonate (EC) and ?-butyrolactone (GBL).Type: GrantFiled: March 4, 2020Date of Patent: September 12, 2023Assignee: NGK INSULATORS, LTD.Inventors: Yuki Fujita, Chiori Suzuki
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Patent number: 11749832Abstract: Lithiated electrodes, electrochemical cells including lithiated electrodes, and methods of making the same are provided. The method includes lithiating at least one electrode in an electrochemical cell by applying current across a first current collector of the at least one electrode to a second current collector of an auxiliary electrode. The electrochemical cell may be disposed within a battery packaging and the auxiliary electrode may be disposed within the battery packaging adjacent to an edge of the electrochemical cell. The at least one electrode may include a first electroactive layer disposed on or near one or more surfaces of the first current collector, and the auxiliary electrode may include a second electroactive layer disposed at or near one or more surfaces of the second current collector. The method may further include extracting the auxiliary electrode from the battery packaging and sealing the battery packaging, which includes the pre-lithiated electrochemical cell.Type: GrantFiled: November 20, 2019Date of Patent: September 5, 2023Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Xingcheng Xiao, Xingyi Yang, Mark W. Verbrugge, Raghunathan K, Qinglin Zhang
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Patent number: 11749833Abstract: A bipolar battery having a solid ionically conductive polymer material as its electrolyte enabling high voltage discharge.Type: GrantFiled: June 6, 2016Date of Patent: September 5, 2023Assignee: IONIC MATERIALS, INC.Inventors: Michael A. Zimmerman, Randy Leising
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Patent number: 11742479Abstract: Provided is a precursor of a positive electrode active material containing, in a reduced amount, impurities which do not contribute to a charge/discharge reaction but rather corrode a firing furnace and peripheral equipment and thus having excellent battery characteristics and safety, and production method thereof. A method for producing a precursor of a positive electrode active material for nonaqueous electrolyte secondary batteries having a hollow structure or porous structure includes obtaining the precursor by washing nickel-manganese composite hydroxide particles having a particular composition ratio and a pore structure in which pores are present within the particles with an aqueous carbonate solution having a carbonate concentration of 0.1 mol/L or more.Type: GrantFiled: July 12, 2019Date of Patent: August 29, 2023Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Taira Aida, Hiroyuki Toya
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Patent number: 11742481Abstract: A nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The positive electrode includes lithium composite oxide particles A and B containing Ni and Mn. The lithium composite oxide particles A include secondary particles a2 that are aggregations of primary particles a1, and contain at least one of zirconium and boron. The lithium composite oxide particles B include at least one of primary particles b1 and secondary particles b2, the primary particles b1 having a larger particle size than the primary particles a1, the secondary particles b2 being aggregations of the primary particles b1 and having a smaller particle size than the secondary particles a2. The mass ratio of the lithium composite oxide particles A to the lithium composite oxide particles B is within the range of 8:2 to 4:6.Type: GrantFiled: January 22, 2019Date of Patent: August 29, 2023Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Kazunori Donoue, Hiroki Watanabe, Shinya Miyazaki
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Patent number: 11735761Abstract: The present invention relates to the application of a force to enhance the performance of an electrochemical cell. The force may comprise, in some instances, an anisotropic force with a component normal to an active surface of the anode of the electrochemical cell. In the embodiments described herein, electrochemical cells (e.g., rechargeable batteries) may undergo a charge/discharge cycle involving deposition of metal (e.g., lithium metal) on a surface of the anode upon charging and reaction of the metal on the anode surface, wherein the metal diffuses from the anode surface, upon discharging. The uniformity with which the metal is deposited on the anode may affect cell performance. For example, when lithium metal is redeposited on an anode, it may, in some cases, deposit unevenly forming a rough surface. The roughened surface may increase the amount of lithium metal available for undesired chemical reactions which may result in decreased cycling lifetime and/or poor cell performance.Type: GrantFiled: August 4, 2021Date of Patent: August 22, 2023Assignee: Sion Power CorporationInventors: Chariclea Scordilis-Kelley, John D. Affinito, Lowell D. Jones, Yuriy V. Mikhaylik, Igor P. Kovalev, William F. Wilkening, Christopher T. S. Campbell, John A. Martens
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Patent number: 11735768Abstract: The present disclosure relates to solid-state batteries and methods for forming solid-state batteries. The method includes contacting a polymeric precursor and an assembled battery including two or more electrodes defining a space therebetween, where the polymeric precursor fills the space defined between the two or more electrodes and any voids between the solid-state electroactive particles of each electrode; and reacting the polymeric precursor to form a polymeric gel electrolyte that forms a solid-state electrolyte layer in the space between the two or more electrodes and fills the voids between the solid-state electroactive particles of the electrodes. In other instances the method includes disposing the polymeric precursor on exposed surfaces of an electrode and reacting the polymeric precursor to form the solid-state electrolyte.Type: GrantFiled: February 9, 2021Date of Patent: August 22, 2023Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventor: Bradley R. Frieberg
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Patent number: 11728478Abstract: Provided is a positive electrode active material for a lithium ion secondary battery having favorable cycle characteristics and high capacity. A covering layer containing aluminum and a covering layer containing magnesium are provided on a superficial portion of the positive electrode active material. The covering layer containing magnesium exists in a region closer to a particle surface than the covering layer containing aluminum is. The covering layer containing aluminum can be formed by a sol-gel method using an aluminum alkoxide. The covering layer containing magnesium can be formed as follows: magnesium and fluorine are mixed as a starting material and then subjected to heating after the sol-gel step, so that magnesium is segregated.Type: GrantFiled: June 30, 2020Date of Patent: August 15, 2023Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Yohei Momma, Takahiro Kawakami, Teruaki Ochiai, Masahiro Takahashi
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Patent number: 11695107Abstract: A porous silicon-containing composite includes: a porous core including a porous silicon composite secondary particle; and a shell on at least one surface of the porous core, the shell including a first graphene, wherein the porous silicon composite secondary particle includes an aggregate of a first primary particle including silicon, a second primary particle including a structure and second graphene on at least one surface of the first primary particle and the second primary particle, and wherein at least one of a shape and a degree of oxidation of the first primary particle and the second primary particle are different. Also an electrode including the porous silicon-containing composite, a lithium battery including the electrode, and a device including the porous silicon-containing composite or the carbon composite.Type: GrantFiled: October 8, 2019Date of Patent: July 4, 2023Assignees: SAMSUNG ELECTRONICS CO., LTD., SAMSUNG SDI CO., LTD.Inventors: Junghyun Choi, Inhyuk Son, Mijong Kim, Sangkook Mah, Jumyeung Lee, Minwoo Lim, Sungsoo Han
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Patent number: 11682908Abstract: Described is an apparatus for extending cycle-life of a battery cell, where the apparatus comprises: a monitor to monitor a rate of degradation of a battery cell overtime; a comparator to compare the rate of degradation with a threshold; and logic to adjust one or more charge parameters of the battery cell when the rate of degradation crosses the threshold. Described is a method which comprises: monitoring a rate of degradation of a battery cell overtime; comparing the rate of degradation with a threshold; and adjusting one or more charge parameters of the battery cell when the rate of degradation crosses the threshold. Described is a machine-readable storage media having machine executable instructions stored thereon that, when executed, causes one or more processors to perform the method described above.Type: GrantFiled: December 26, 2017Date of Patent: June 20, 2023Assignee: Tahoe Research, Ltd.Inventor: Andrew Keates
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Patent number: 11670765Abstract: Provided are a positive electrode active material that can provide a nonaqueous electrolyte secondary battery having high energy density and excellent output characteristics, a nickel-manganese composite hydroxide as a precursor thereof, and methods for producing these. A nickel-manganese composite hydroxide is represented by General Formula (1): NixMnyMz(OH)2+? and contains a secondary particle formed of a plurality of flocculated primary particles. The nickel-manganese composite hydroxide has a half width of a diffraction peak of a (001) plane of at least 0.35° and up to 0.50° and has a degree of sparsity/density represented by [(a void area within the secondary particle/a cross section of the secondary particle)×100](%) within a range of greater than 10% and up to 25%.Type: GrantFiled: July 28, 2017Date of Patent: June 6, 2023Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Haruki Kaneda, Yuki Koshika, Takaaki Ando
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Patent number: 11664533Abstract: A lithium ion battery electrolyte comprising a glyceryl ether epoxy resin gel is provided. The glyceryl ether epoxy resin gel comprises a glyceryl ether epoxy resin and an electrolyte. The glyceryl ether epoxy resin is a cross-linked polymer obtained by a ring-opening reaction of a glyceryl ether polymer and a polyamine compound. The glyceryl ether polymer is a glycidyl ether polymer comprising at least two epoxy groups, and the polyamine compound comprises at least two amine groups. The cross-linked polymer comprises a main chain and a plurality of hydroxyl groups, and the plurality of hydroxyl groups are located on the main chain. The electrolyte comprises a lithium salt and a non-aqueous solvent. The lithium salt and the glyceryl ether epoxy resin are dispersed in the non-aqueous solvent. A method of making the lithium ion battery electrolyte is also provided.Type: GrantFiled: June 1, 2021Date of Patent: May 30, 2023Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.Inventors: Zhen-Han Fang, Jia-Ping Wang, Shou-Shan Fan
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Patent number: 11664526Abstract: Cathode materials for lithium ion batteries, lithium ion batteries incorporating the cathode materials, and methods of operating the lithium ion batteries are provided. The materials, which are composed of lithium iron oxides, are able to undergo reversible anionic and cationic redox reactions with no O2(g) generation.Type: GrantFiled: December 6, 2018Date of Patent: May 30, 2023Assignees: Northwestern University, UChicago Argonne, LLCInventors: Christopher M. Wolverton, Zhenpeng Yao, Chun Zhan, Jun Lu, Khalil Amine