Alkalated Transition Metal Chalcogenide Component Is Active Material Patents (Class 429/231.1)
  • Patent number: 10014521
    Abstract: Provided is a cathode active material including a complex coating layer, which includes M below, formed on a surface of the cathode active material through reaction of a lithium transition metal oxide represented by Formula 1 below with a coating precursor: LixMO2??(1) wherein M is represented by MnaM?1-b, M? is at least one selected from the group consisting of Al, Mg, Ni, Co, Cr, V, Fe, Cu, Zn, Ti and B, 0.95?x?51.5, and 0.5?a?1. The lithium secondary battery including the cathode active material exhibits improved lifespan and rate characteristics due to superior stability.
    Type: Grant
    Filed: January 15, 2015
    Date of Patent: July 3, 2018
    Assignee: LG Chem, Ltd.
    Inventors: Bo Ram Lee, Hye Lim Jeon, Sun Sik Shin, Sangwook Lee, Wang Mo Jung
  • Patent number: 10003075
    Abstract: The present invention relates to carbon nanotubes-metal nano composite by chemical route and the corresponding development of strong and flexible, light weight, self-supporting anode through simple vacuum filtration technique, which is favored by the high aspect ratio of the Multi-walled carbon nanotubes. The self-supported anode has an added advantage that it can be used as electrodes without binder and electrical conductor (unlike other carbonaceous powder materials) that helps us to elucidate the precise electrochemical properties. The metals used can be Sn, Si, Al, etc. The developed high capacity, free-standing anode can be used in rechargeable Li-ion batteries and is demonstrated successfully in powering solar lantern.
    Type: Grant
    Filed: June 11, 2015
    Date of Patent: June 19, 2018
    Assignee: Council of Scientific and Industrial Research
    Inventors: Heda Priyanka Maheshwari, Indu Elizabeth, Bhanu Pratap Singh, Chanchal Gupta, Rakesh Behari Mathur, Gopukumar Sukumaran
  • Patent number: 9997743
    Abstract: It is an object of the present invention to provide a nonaqueous electrolyte secondary battery with superior high-temperature charge-discharge cycle characteristics as well as superior low-temperature high-rate charge-discharge cycle characteristics. A nonaqueous electrolyte secondary battery 100 according to the present invention has an electrode body 80 which includes a positive electrode and a negative electrode, and a battery case 50 which houses the electrode body 80 together with a nonaqueous electrolyte, wherein among the nonaqueous electrolyte housed in the battery case 50, an electrolyte amount ratio (A/B) between a surplus electrolyte amount (A) that exists outside the electrode body 80 and an intra-electrode body electrolyte amount (B) impregnating the electrode body 80 ranges from 0.05 to 0.2, and DBP absorption of a positive electrode active material that constitutes the positive electrode is equal to or higher than 30 (ml/100 g).
    Type: Grant
    Filed: March 3, 2011
    Date of Patent: June 12, 2018
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Hiroki Nagai, Masahiro Morita, Takashi Iwao, Yukihiro Okada
  • Patent number: 9997777
    Abstract: This invention discloses an electrochemical device having a multilayer structure and methods for making such a device. Specifically, this invention discloses a multilayer electrochemical device having nano-sized cobalt oxyhydroxide conductive agents and/or active materials within the polymer layers.
    Type: Grant
    Filed: June 18, 2014
    Date of Patent: June 12, 2018
    Assignee: THE REGENTS OF THE UNIVERSITY OF MICHIGAN
    Inventors: Binay Prasad, Levi T. Thompson, Paul G. Rasmussen
  • Patent number: 9991566
    Abstract: Provided herein is an electrode active material comprising a lithium metal oxide and an overcharge protection additive having an operating voltage higher than the operating voltage of the lithium metal oxide.
    Type: Grant
    Filed: October 30, 2012
    Date of Patent: June 5, 2018
    Assignee: Johnson Controls Technology Company
    Inventors: Peter B. Hallac, Sung-Jin Cho, Frederic C. Bonhomme, Mohamed Taggougui, David R. Boone, Qingfang Shi, Alexandre Ndedi Ntepe
  • Patent number: 9985282
    Abstract: A positive electrode active material for a non-aqueous electrolyte secondary battery according to an example of an embodiment of the present disclosure includes a lithium composite oxide as a main component. The ratio of a number of moles of Ni in the lithium composite oxide to a total number of moles of metal elements in the lithium composite oxide other than Li is larger than 30 mol %. The lithium composite oxide includes particles each including aggregated primary particles having a volumetric average particle size of 0.5 ?m or more and at least one element selected from W, Mo, Nb, and Ta is dissolved in the lithium composite oxide.
    Type: Grant
    Filed: May 19, 2017
    Date of Patent: May 29, 2018
    Assignee: PANASONIC CORPORATION
    Inventors: Hidekazu Hiratsuka, Akihiro Maeda
  • Patent number: 9979014
    Abstract: A composite cathode active material including a core comprising a lithium compound, and a coating layer formed on at least one portion of the core and including at least two oxide phases having different structures, a cathode and a lithium battery including the same, and a method of preparing the composite cathode active material.
    Type: Grant
    Filed: August 28, 2014
    Date of Patent: May 22, 2018
    Assignee: SAMSUNG SDI Co., LTD.
    Inventors: Min-Han Kim, Joong-Ho Moon, Han-Eol Park, Kyoung-Hyun Kim, Do-Hyung Park, Yu-Mi Song, Ming-Zi Hong, Jeong-Hoon Kim, Dong-Jin Kim, Jeon-Jin Choi, Gyu-Ran Jeon, Sun-Ho Kang
  • Patent number: 9979012
    Abstract: A lithium ion secondary battery includes a positive electrode; a negative electrode; a separator disposed between the positive electrode and the negative electrode; and a non-aqueous electrolyte, wherein the positive electrode contains, as a positive electrode active material, a lithium-containing transition metal compound that belongs to space group Fd3-m and that contains lithium and transition metal M (M represents Mo, or Mo and at least one selected from the group consisting of Mn, Co, Ni, W, and V), a molar ratio of the lithium to the transition metal M is 2.7 or more and 3.3 or less, and a ratio of a mass of the lithium-containing transition metal compound to a total mass of the positive electrode active material in the positive electrode is 0.8 or more.
    Type: Grant
    Filed: August 1, 2014
    Date of Patent: May 22, 2018
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Ryuichi Natsui, Kensuke Nakura
  • Patent number: 9972835
    Abstract: Disclosed are a positive active material for a rechargeable lithium battery including a nickel-containing lithium transition metal composite oxide and a coating layer positioned on the surface of the lithium transition metal composite oxide, wherein the coating layer includes vanadium oxide, lithium vanadium oxide, or a combination thereof, a method of manufacturing the same, and a rechargeable lithium battery including the same.
    Type: Grant
    Filed: October 16, 2014
    Date of Patent: May 15, 2018
    Assignee: UNIST (ULSAN NATIONAL INSTITUTE OF SCIENCE AND TECHNOLOGY)
    Inventors: Jaephil Cho, Mi-Jung Noh
  • Patent number: 9960414
    Abstract: A lithium ion secondary battery includes a positive electrode, a negative electrode, and an electrolytic solution. The positive electrode contains a lithium composite oxide. The negative electrode contains a material including at least one of silicon Si and tin Sn as a constituent element. The lithium composite oxide includes lithium Li having a composition ratio a, a first element having a composition ratio b, and a second element having a composition ratio c as a constituent element. The first element including two kinds or more selected from among manganese Mn, nickel Ni, and cobalt Co, and including at least manganese. The second element including at least one kind selected from among aluminum Al, titanium Ti, magnesium Mg, and boron B. The composition ratios a to c satisfy the relationships of 1.1<a<1.3, 0.7<b+c<1.1, 0<c<0.1, and a>b+c.
    Type: Grant
    Filed: January 5, 2016
    Date of Patent: May 1, 2018
    Assignee: MURATA MANUFACTURING CO., LTD.
    Inventors: Akira Takamuku, Kazuaki Endoh, Masaharu Senoue, Guohua Li, Yosuke Hosoya, Kenichi Kawase
  • Patent number: 9960424
    Abstract: Positive electrode active materials are described that have a high tap density and high specific discharge capacity upon cycling at room temperature and at a moderate discharge rate. Some materials of interest have the formula Li1+xNi?Mn?Co?O2, where x ranges from about 0.05 to about 0.25, ? ranges from about 0.1 to about 0.4, ? ranges from about 0.4 to about 0.65, and ? ranges from about 0.05 to about 0.3. The materials can be coated with a metal fluoride to improve the performance of the materials especially upon cycling. Also, the coated materials can exhibit a very significant decrease in the irreversible capacity lose upon the first charge and discharge of the battery.
    Type: Grant
    Filed: March 21, 2013
    Date of Patent: May 1, 2018
    Assignee: Zenlabs Energy, Inc.
    Inventors: Herman Lopez, Subramanian Venkatachalam, Sujeet Kumar, Deepak Kumaar K. Karthikeyan
  • Patent number: 9954221
    Abstract: The present invention relates to a cathode active material for a lithium rechargeable battery, a method of manufacturing the same, and a lithium rechargeable battery including the same, and provides the cathode active material for the lithium rechargeable battery, including a core including a compound represented by the following Chemical Formula 1, and a coating layer positioned on the core and including a compound represented by the following Chemical Formula 2. xLi2MnO3—(1-x)LiM1O2??[Chemical Formula 1] In Chemical Formula 1, 0<x<1 and M1 is a transition metal. yMnOz—(1-y)LiM2O2??[Chemical Formula 2] In Chemical Formula 2, 0<y<1, 1?z?4, and M2 is a transition metal.
    Type: Grant
    Filed: April 11, 2014
    Date of Patent: April 24, 2018
    Assignee: UNIST (ULSAN NATIONAL INSTITUTE OF SCIENCE AND TECHNOLOGY)
    Inventors: Jaephil Cho, Pilgun Oh
  • Patent number: 9947930
    Abstract: A positive active material, a method of preparing the same, and a lithium battery including the positive active material, the positive active material including a core, the core including an overlithiated lithium transition metal oxide; and a coating layer on the core, the coating layer including Li3VO4.
    Type: Grant
    Filed: November 10, 2014
    Date of Patent: April 17, 2018
    Assignee: SAMSUNG SDI CO., LTD.
    Inventors: Jay-Hyok Song, Byong-Yong Yu, Andrei Kapylou, Sol Choi, Yong-Chan You, Sun-Ho Kang
  • Patent number: 9929402
    Abstract: A power storage device including a positive electrode in which a positive electrode active material is formed over a positive electrode current collector and a negative electrode which faces the positive electrode with an electrolyte interposed therebetween is provided. The positive electrode active material includes a first region which includes a compound containing lithium and one or more of manganese, cobalt, and nickel; and a second region which covers the first region and includes a compound containing lithium and iron. Since a superficial portion of the positive electrode active material includes the second region containing iron, an energy barrier when lithium is inserted into and extracted from the surface of the positive electrode active material can be decreased.
    Type: Grant
    Filed: December 11, 2014
    Date of Patent: March 27, 2018
    Assignee: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
    Inventor: Takahiro Kawakami
  • Patent number: 9929403
    Abstract: A method of producing an active material powder includes (i) an attachment step of obtaining a powder including an active material particle, which stores and releases lithium ions at a potential of 4.5 V or higher based on Li, and a coating layer precursor, which is attached to a surface of the active material particle, by attaching an alkoxide solution containing lithium ions and niobium ions to the surface of the active material particle and drying the attached alkoxide solution; and (ii) a heating step of forming a coating layer on the surface of the active material particle by heating the powder obtained in the attachment step to be within a temperature range of 120° C. to 200° C.
    Type: Grant
    Filed: March 6, 2015
    Date of Patent: March 27, 2018
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Yuki Kato, Takamasa Ohtomo, Hisatsugu Yamasaki, Masatsugu Kawakami
  • Patent number: 9923197
    Abstract: A composite negative active material including a piezoelectric material; and a negative active material. Also a negative electrode including the composite negative active material, and a lithium secondary battery including the negative electrode.
    Type: Grant
    Filed: October 1, 2015
    Date of Patent: March 20, 2018
    Assignees: SAMSUNG ELECTRONICS CO., LTD., SAMSUNG SDI CO., LTD.
    Inventors: Byoungsun Lee, Heechul Jung, Kanghee Lee, Jinhwan Park, Changhoon Jung, Kihong Kim, Yoonsok Kang, Dongyoung Kim
  • Patent number: 9923203
    Abstract: A positive electrode active material includes LiMn1-xMxPO4 (wherein M represents at least one element selected from Mg, Fe, Ni, Co, Ti, and Zr; and 0?x<0.5) and has an average pore diameter of 8 nm or more and not more than 25 nm and a total pore volume of 0.05 cm3/g or more and not more than 0.3 cm3/g.
    Type: Grant
    Filed: October 3, 2014
    Date of Patent: March 20, 2018
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Keigo Hoshina, Hiroki Inagaki, Norio Takami, Kiyoshi Kanamura
  • Patent number: 9917305
    Abstract: In one aspect, a positive electrode active material is provided, a method of manufacturing the positive electrode active material, and a lithium battery employing the positive electrode active material. The positive electrode active material may have high thermal stability and low capacity deterioration despite repetitive charging and discharging.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: March 13, 2018
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Chang-Hyuk Kim, Do-Hyung Park, Seon-Young Kwon, Min-Han Kim, Ji-Hyun Kim, Jeong-Seop Lee, Yoon-Chang Kim
  • Patent number: 9912006
    Abstract: Provided are a method of manufacturing a composite positive active material, a composite positive active material manufactured by the method, and a positive electrode and a lithium battery including the composite positive active material. The method may include acid-treating an overlithiated lithium transition metal oxide; and applying fluorine onto the acid-treated overlithiated lithium transition metal oxide using a fluorine compound.
    Type: Grant
    Filed: August 11, 2014
    Date of Patent: March 6, 2018
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Jay-Hyok Song, Andrei Kapylou, Jun-Seok Park, Chang-Wook Kim, Yong-Chan You, Sun-Ho Kang
  • Patent number: 9908786
    Abstract: The present invention relates to a cathode active material for a lithium secondary battery, a method for preparing the same, and a lithium secondary battery including the same. Provided is a cathode active material composed of a lithium-excess lithium metal composite compound including Li2MnO3 having a layered structure, and doped with a fluoro compound, wherein an FWHM (half value width) value is within a range from 0.164 degree to 0.185 degree.
    Type: Grant
    Filed: November 19, 2013
    Date of Patent: March 6, 2018
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Misun Lee, Jongseok Moon, Taehyeon Kim, Shin Jung Choi
  • Patent number: 9911538
    Abstract: The invention concerns an electrical energy storage assembly (capacitor or battery) comprising: -an envelope (20) including: *at least one lateral wall (21), and *an open end, -an electrochemical element (30) intended to be contained in the envelope (20) and -at least one cover (40) intended to be positioned at the open end of the envelope (20), each cover (40) including: *a cover wall (41, 45) intended to cover the open end of the envelope (20), *a lateral face (42, 43) at the periphery of the cover wall (41, 45) and intended to be facing the lateral wall (21) of the envelope (20), -at least one electrically insulating elastic annular ring (50) intended to be positioned between the lateral wall (21) of the envelope (20) and the lateral wall (42, 43) of the cover (40).
    Type: Grant
    Filed: March 21, 2013
    Date of Patent: March 6, 2018
    Assignee: BLUE SOLUTIONS
    Inventors: Arnaud Jourdren, Eric Baylard
  • Patent number: 9911972
    Abstract: The non-aqueous electrolyte secondary battery 10 provided by the present invention comprises a positive electrode 30, a negative electrode 50 and a non-aqueous electrolyte. The negative electrode 50 includes a negative electrode current collector 52 and a negative electrode active material layer 54 formed on the current collector 52, the negative electrode active material layer 54 containing a negative electrode active material 55 capable of storing and releasing charge carriers and having shape anisotropy so that the charge carriers are stored and released along a predefined direction. The negative electrode active material layer 54 includes, at a bottom thereof contacting the current collector 52, a minute conductive material 57 with granular shape and/or minute conductive material 57 with fibrous shape having an average particle diameter that is smaller than that of the negative electrode active material 55, and includes, at the bottom thereof; a part of the negative electrode active material 55.
    Type: Grant
    Filed: December 14, 2011
    Date of Patent: March 6, 2018
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Koji Takahata, Tatsuya Hashimoto, Yoshiyuki Ozaki, Yukihiro Okada, Kenji Tsuchiya, Masanori Kitayoshi, Naoyuki Wada
  • Patent number: 9905887
    Abstract: The present invention relates to a secondary battery cg a positive electrode capable of absorbing and releasing lithium, and a electrolyte solution containing a non-aqueous electrolytic solvent, wherein the positive electrode has a positive electrode active material which operates at 4.5 V or more relative to lithium, and wherein the non-aqueous electrolytic solvent contains a sulfone compound represented by a predetermined formula and a fluorinated ether compound represented by a predetermined formula.
    Type: Grant
    Filed: June 4, 2013
    Date of Patent: February 27, 2018
    Assignee: NEC Corporation
    Inventors: Makiko Takahashi, Takehiro Noguchi, Hideaki Sasaki, Yuukou Katou, Akinobu Nakamura
  • Patent number: 9905372
    Abstract: Provided is an electrochemical capacitor which has low DC internal resistance, and which minimizes increase in the DC internal resistance due to a high temperature experience. The electrochemical capacitor is provided with a positive electrode having a positive electrode active material layer containing activated carbon, a negative electrode having a negative electrode active material layer containing a spinel-type lithium titanate, and a separator holding a non-aqueous electrolytic solution containing a lithium salt between the positive electrode active material layer and the negative electrode active material layer, a 100% discharge capacity of lithium titanate being set to within a range of 2.2 to 7.0 times a 100% discharge capacity of activated carbon. During charging and discharging of the electrochemical capacitor, only the area near the surfaces of lithium titanate particles are utilized, lowering the DCIR and improving the stability of the DCIR.
    Type: Grant
    Filed: August 11, 2014
    Date of Patent: February 27, 2018
    Assignee: NIPPON CHEMI-CON CORPORATION
    Inventors: Satoru Tsumeda, Kazuma Okura, Kazunori Takaki, Shuichi Ishimoto
  • Patent number: 9896346
    Abstract: A method for synthesizing lithium-titanium oxide using a solid state method includes: mixing lithium oxide (Li2O) and titanium oxide (TiO2) in a solvent; separating a solid material which includes lithium oxide and titanium oxide from the solvent; drying the solid material separated from the solvent; and performing a heat treatment on the solid material.
    Type: Grant
    Filed: March 24, 2016
    Date of Patent: February 20, 2018
    Assignee: KOREA BASIC SCIENCE INSTITUTE
    Inventors: Yi-Hyun Park, Seungyon Cho, Mu-Young Ahn, Kyung-Mi Min
  • Patent number: 9899671
    Abstract: Provided herein is a method for preparing a metal oxide nanoparticle/graphene composite using a supercritical fluid and the metal oxide nanoparticle/graphene composite prepared thereby, the method including preparing a dispersed solution by dispersing graphene oxide and a metal oxide precursor in an organic solvent and forming the metal oxide nanoparticle/graphene composite by reacting the dispersed solution under a supercritical condition, thereby uniformly dispersing the metal oxide nanoparticles on a graphene sheet.
    Type: Grant
    Filed: October 7, 2015
    Date of Patent: February 20, 2018
    Assignee: Research & Business Foundation Sungkyunkwan University
    Inventors: Jaehoon Kim, Do Hyeon Yoon, Wenying Li, Ji Eun Hwang
  • Patent number: 9882213
    Abstract: A nonaqueous electrolyte battery includes a positive electrode, a negative electrode and a nonaqueous electrolyte. The positive electrode includes a lithium/manganese-containing oxide represented by LiaMnbMcOZ (M is at least one selected from the group consisting of Ni, Co, Al and F, and a, b, c and Z satisfy the following equations: 0?a?2.5, 0<b?1, 0?c?1 and 2?Z?3) and a Fe-containing phosphorous compound having an olivine structure. The negative electrode includes a titanium-containing metal oxide into which lithium ions are inserted and from which lithium ions are extracted.
    Type: Grant
    Filed: March 23, 2010
    Date of Patent: January 30, 2018
    Assignee: KABUSHIKI KAISHA TOSHIBA
    Inventors: Norio Takami, Hiroki Inagaki, Shinsuke Matsuno
  • Patent number: 9882206
    Abstract: A new high performing lithium ion cell having new carbon based anode and new dual doped layered cathode materials. The anode is a self standing carbon fibrous material and the cathode is a dual doped Lithium cobalt oxide of general formula LiMxNyCo1?x?yO2 (0.01?x, y?0.2) wherein M is a divalent alkaline earth metal cation and N is a divalent transition metal cation. Lithium ion cells of 2016 coin cells were assembled using the above materials deliver specific capacity of 60-85 mAhg?1 at 1 C rate and exhibit excellent cycling stability of 90-95% even after 200 cycles when cycled between 2.9-4.1V.
    Type: Grant
    Filed: March 29, 2011
    Date of Patent: January 30, 2018
    Assignee: COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH
    Inventors: Sukumaran Gopukumar, Chandrasekaran Nithya, Ramasamy Thirunakaran, Arumugam Sivashanmugam, Sundeep Kumar Dhawan, Rakesh Behari Mathur, Priyanka Heda Maheshwari
  • Patent number: 9876226
    Abstract: Aluminum dry-coated and heat treated cathode material precursors. A particulate precursor compound for manufacturing an aluminum coatedlithium transition metal (M)-oxide powder usable as an active positive electrode material in lithium-ion batteries includes a transition metal (M)-oxide core and a non-amorphous aluminum oxide coating layercovering the core. By providing a heat treatment process for mixed metal precursors that may be combined with an aluminum dry-coating process, novel aluminum containing precursors that may be used to form high quality nickel based cathode materials are obtained. The aluminum dry-coated and heat treated precursors include particles have, compared to prior art precursors, relatively low impurity levels of carbonate and/or sulfide, and can be produced at lower cost.
    Type: Grant
    Filed: August 4, 2011
    Date of Patent: January 23, 2018
    Assignee: Umicore
    Inventors: Jens Paulsen, JiHye Kim, HeonPyo Hong
  • Patent number: 9870873
    Abstract: Mixture of particles comprising a non-conducting or semi-conducting nucleus covered with a hybrid conductor coating and hybrid conductor chains located between the particles of the mixture to constitute a conductivity network, that is prepared by mechanical crushing. Due to a very good conductivity of the network, a low resistivity, a very good capacity under elevated current and/or a good density of energy, these mixtures of particles are advantageously incorporated in anodes and cathodes of electrochemical generators, resulting in highly performing electrochemical systems.
    Type: Grant
    Filed: March 20, 2014
    Date of Patent: January 16, 2018
    Assignee: HYDRO-QUEBEC
    Inventors: Karim Zaghib, Patrick Charest, Abdelbast Guerfi, Michel Perrier, Kimio Kinoshita
  • Patent number: 9859560
    Abstract: The present invention is directed to electrochemical devices and materials thereof. More specifically, embodiments set forth herein provide a low-porosity electrode that includes large particles and small particles. The large particles include electrochemically active material. The small particles include ion conductive electrolyte materials. In some examples, the large particles and small particles are characterized by a dispersity of no higher than 0.5. There are other embodiments as well.
    Type: Grant
    Filed: May 28, 2015
    Date of Patent: January 2, 2018
    Assignee: QuantumScape Corporation
    Inventors: Tim Holme, Ken Desmond, Weston Arthur Hermann, Joseph Han, Zhebo Chen
  • Patent number: 9853286
    Abstract: A positive electrode active material for a non-aqueous electrolyte secondary battery according to an embodiment of the present disclosure is represented by a general formula of LixNiyM1-yO2 (where M includes at least one metal element selected from Co and Mn, 0.1?x?1.2, 0.3<y<1), has a volumetric average particle size (D50) of 7 ?m or more and 30 ?m or less, and has an average surface roughness of 4% or less.
    Type: Grant
    Filed: September 9, 2014
    Date of Patent: December 26, 2017
    Assignee: PANASONIC CORPORATION
    Inventor: Hidekazu Hiratsuka
  • Patent number: 9843042
    Abstract: Provided are a cathode active material composition including an xLi2MO3.(1?x)LiMeO2 composite (where 0<x<1, and M and Me represent metal ions and may be the same or different from each other) and a conductive polymer material, and a secondary battery including the cathode active material composition in a cathode. Since the conductivity of the secondary battery of the present invention may be improved, the cathode active material composition may improve life characteristics, output characteristics, and rate capability of the secondary battery.
    Type: Grant
    Filed: March 5, 2014
    Date of Patent: December 12, 2017
    Assignee: LG Chem, Ltd.
    Inventors: Hyeok Moo Lee, Song Taek Oh, Jung Seok Choi, Ji Hye Park
  • Patent number: 9837665
    Abstract: A lithium ion battery includes an anode and a cathode. The cathode includes a lithium, manganese, nickel, and oxygen containing compound. An electrolyte is disposed between the anode and the cathode. A protective layer is deposited between the cathode and the electrolyte. The protective layer includes pure lithium phosphorus oxynitride and variations that include metal dopants such as Fe, Ti, Ni, V, Cr, Cu, and Co. A method for making a cathode and a method for operating a battery are also disclosed.
    Type: Grant
    Filed: January 26, 2017
    Date of Patent: December 5, 2017
    Assignee: UT-BATTELLE, LLC
    Inventors: Nancy J. Dudney, Chengdu Liang, Jagjit Nanda, Gabriel M. Veith, Yoongu Kim, Surendra Kumar Martha
  • Patent number: 9831493
    Abstract: Disclosed is a cathode active material comprising a lithium manganese composite oxide with a spinel structure represented by the following Formula 1, wherein the lithium manganese composite oxide is surface-coated with a conductive polymer in an area of 30 to 100%, based on the surface area of the lithium manganese composite oxide: LixMyMn2-yO4-zAz??(1) wherein 0.9?x?1.2, 0<y<2, and 0?z<0.2; M is at least one element selected from the group consisting of Al, Mg, Ni, Co, Fe, Cr, V, Ti, Cu, B, Ca, Zn, Zr, Nb, Mo, Sr, Sb, W, Ti and Bi; and A is at least one monovalent or bivalent anion. Disclosed is also a secondary battery comprising the cathode active material.
    Type: Grant
    Filed: April 18, 2013
    Date of Patent: November 28, 2017
    Assignee: LG CHEM, LTD.
    Inventors: SooHyun Lim, Jihyun Kim, MinHee Lee
  • Patent number: 9831496
    Abstract: Provided is a nonaqueous electrolytic solution secondary battery in which a positive electrode active material layer includes a phosphate compound, the nonaqueous electrolytic solution secondary battery having a low battery resistance. The nonaqueous electrolytic solution secondary battery disclosed herein includes an electrode body including a positive electrode provided with a positive electrode active material layer and a negative electrode, and a nonaqueous electrolytic solution. The positive electrode active material layer includes a positive electrode active material and a phosphate compound represented by M3PO4 where M is Li, Na, or H. The positive electrode active material is in the form of hollow particles, each having a shell configured of a layered lithium transition metal oxide, a hollow portion formed inside the shell, and a through hole passing through the shell. A DBP oil absorption amount of the positive electrode active material is 34 mL/100 g to 49 mL/100 g.
    Type: Grant
    Filed: November 1, 2016
    Date of Patent: November 28, 2017
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Ryuta Sugiura
  • Patent number: 9825338
    Abstract: A non-aqueous secondary battery includes a cathode, an anode, and an electrolytic solution. The electrolytic solution includes a non-aqueous solvent, an electrolyte salt, and one or both of a disulfonyl compound represented by a following Formula (1) and a disulfinyl compound represented by a following Formula (2), where R1 is one of a hydrocarbon group, a halogenated hydrocarbon group, an oxygen-containing hydrocarbon group, a halogenated oxygen-containing hydrocarbon group, and a group obtained by bonding two or more thereof to one another; and X1 is a halogen group, where R2 is one of a hydrocarbon group, a halogenated hydrocarbon group, an oxygen-containing hydrocarbon group, a halogenated oxygen-containing hydrocarbon group, and a group obtained by bonding two or more thereof to one another; and X2 is a halogen group.
    Type: Grant
    Filed: December 5, 2016
    Date of Patent: November 21, 2017
    Assignee: Sony Corporation
    Inventors: Tomomi Sakuma, Midori Sugawara, Toru Odani
  • Patent number: 9825294
    Abstract: Provided is a method for preparing a positive electrode active material for a lithium secondary battery, the method comprising: mixing and reacting a nickel source, a cobalt source, and an aluminum source, ammonia water, sucrose, and a pH adjusting agent to prepare a mixed solution; drying and oxidizing the mixed solution to prepare a positive electrode active material precursor; and adding a lithium source to the positive electrode active material precursor and firing them to prepare a positive electrode active material for a lithium secondary battery.
    Type: Grant
    Filed: September 8, 2011
    Date of Patent: November 21, 2017
    Assignee: SK Innovation Co., Ltd.
    Inventors: Sung Woo Oh, Hee Young Sun, Yu Rim Do, Hyung Bok Lee
  • Patent number: 9825333
    Abstract: An electrolyte comprising an organic solvent, a lithium salt, and a polymer additive comprised of repeating vinyl units joined to one or more heterocyclic amine moieties is described. The heterocyclic amine contains five to ten ring atoms, inclusive. An electrochemical cell is also disclosed. The preferred cell comprises a negative electrode which intercalates with lithium, a positive electrode comprising an electrode active material which intercalates with lithium, and the electrolyte of the present invention activating the negative and the positive electrodes.
    Type: Grant
    Filed: September 29, 2014
    Date of Patent: November 21, 2017
    Assignee: Greatbatch Ltd.
    Inventor: Chi-Kyun Park
  • Patent number: 9825299
    Abstract: Provided is a nonaqueous electrolyte secondary cell in which heat generation is suppressed. The nonaqueous electrolyte secondary cell according to the invention has a positive electrode including positive electrode active material particles and a negative electrode including negative electrode active material particles. The negative electrode active material particles are carbon-black-adhered carbon-based negative electrode active material particles which are constituted by a carbon material having a graphite structure in at least part thereof and which have carbon black (CB) particles that have adhered to at least part of a surface portion. The positive electrode active material particles are of a hollow structure having a shell and a hollow portion.
    Type: Grant
    Filed: August 2, 2016
    Date of Patent: November 21, 2017
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Ryuta Morishima, Ryo Hanazaki, Nobuo Matsui
  • Patent number: 9806340
    Abstract: According to one embodiment, a nonaqueous electrolyte battery including a positive electrode and a negative electrode is provided. The positive electrode includes LiNixM1-xO2 wherein M is a metal element including Mn, and x is within a range of 0.5?x?1. The negative electrode includes graphitized material particles and a layer. The graphitized material particles have an interplanar spacing of (002), according to an X-ray diffraction method, of 0.337 nm or less. The layer includes a titanium-containing oxide. The layer covers at least a part of a surface of the graphitized material particles.
    Type: Grant
    Filed: June 14, 2017
    Date of Patent: October 31, 2017
    Assignee: KABUSHIKI KAISHA TOSHIBA
    Inventors: Norio Takami, Wen Zhang, Hiroki Inagaki
  • Patent number: 9806317
    Abstract: The electric storage device disclosed herein is a stacked type electric storage device. The electric storage device includes a separator insulating a first electrode from a second electrode. The electric storage device includes a first conductive path from a first electrode terminal to the first electrode, a second conductive path from a second electrode terminal to the second electrode, and a current interruption device disposed between the second electrode terminal and the second electrode, the current interruption device being configured to interrupt the second conductive path. The separator includes a first surface part covering the one surface of the first electrode, a second surface part covering the other surface of the first electrode, and a connection part connected to both the first and second surface parts. The connection part is disposed between the current interruption device and an end of the first electrode on a current interruption device side.
    Type: Grant
    Filed: July 16, 2013
    Date of Patent: October 31, 2017
    Assignee: KABUSHIKI KAISHA TOYOTA JIDOSHOKKI
    Inventors: Atsushi Minagata, Motoaki Okuda, Hiroyasu Nishihara, Takayuki Kato
  • Patent number: 9799924
    Abstract: An electrolyte for a lithium secondary battery including a lithium salt, a non-aqueous organic solvent, and a pyrrolidine derivative represented by Formula 1, wherein, in Formula 1, X is hydrogen, a formyl group or a salt thereof, a carboxyl group or a salt thereof, a C1-C20 alkyl group, a C1-C20 hydroxyalkyl group, a C1-C20 aminoalkyl group, a C1-C20 thioalkyl group, or a C1-C20 cyanoalkyl group, and R1 to R4 are each independently hydrogen, deuterium, a halogen atom, a hydroxyl group, a thio group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine, a hydrazone, a formyl group or a salt thereof, a carboxyl group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid or a salt thereof, a C1-C20 hydroxyalkyl group, a C2-C20 heteroaryl group, or a C6-C20 aryl group.
    Type: Grant
    Filed: September 29, 2014
    Date of Patent: October 24, 2017
    Assignee: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Yoonsok Kang, Insun Park, Junyoung Mun, Minsik Park, Jinhwan Park, Byungjin Choi
  • Patent number: 9780363
    Abstract: This disclosure provides a positive electrode active lithium-excess metal oxide with composition LixMyO2 (0.6?y?0.85 and 0?x+y?2) for a lithium secondary battery with a high reversible capacity that is insensitive with respect to cation-disorder. The material exhibits a high capacity without the requirement of overcharge during the first cycles.
    Type: Grant
    Filed: October 2, 2013
    Date of Patent: October 3, 2017
    Assignee: Massachusetts Institute of Technology
    Inventors: Gerbrand Ceder, Jinhyuk Lee, Alexander Urban, Xin Li, Sangtae Kim, Geoffroy Hautier
  • Patent number: 9761875
    Abstract: The present disclosure relates to a cathode active material, and more particularly, to a cathode active material doped with a trivalent metal (Me) and a lithium secondary battery comprising the same. According to one aspect, there is provided the cathode active material doped with the trivalent metal (Me), represented by the formula LixMn2MeyO4 (here, x is from 0.5 to 1.3, and y is from 0.01 to 0.1). According to the present disclosure, release of manganese ions of the cathode active material greatly reduces, and consequently, capacity and cycle life of the battery may be significantly improved.
    Type: Grant
    Filed: February 14, 2014
    Date of Patent: September 12, 2017
    Assignee: LG Chem, Ltd.
    Inventors: Yong-Seok Lee, Duk-Hyun Ryu, Jung-Jin Kim
  • Patent number: 9761880
    Abstract: [Problem] A non-aqueous electrolyte battery is provided that shows good cycle performance and good storage performance under high temperature conditions and exhibits high reliability even with a battery configuration featuring high capacity. A method of manufacturing the battery is also provided.
    Type: Grant
    Filed: June 3, 2015
    Date of Patent: September 12, 2017
    Assignee: SANYO Electric Co., Ltd.
    Inventors: Takeshi Ogasawara, Hiroshi Minami, Naoki Imachi, Atsushi Kaiduka, Yasunori Baba, Yoshinori Kida, Shin Fujitani
  • Patent number: 9748559
    Abstract: A positive electrode active material for non-aqueous secondary battery includes core particles containing a lithium transition metal composite oxide, and a covering layer covering, that covers a surface of the core particle. The covering layer contains niobium and carbonate ions, and the carbonate ions are present at a concentration of from 0.2 weight % to 0.4 weight %. The positive electrode active material for non-aqueous secondary battery exhibits infrared absorption peaks at a wavenumber range of from 1320 cm?1 to 1370 cm?1, and at a wavenumber range of from 1640 cm?1 to 1710 cm?1.
    Type: Grant
    Filed: August 22, 2016
    Date of Patent: August 29, 2017
    Assignee: NICHIA CORPORATION
    Inventor: Hideki Yoshida
  • Patent number: 9735451
    Abstract: Disclosed herein is a battery module including two or more battery cells, wherein the battery module is configured in a structure in which a sensor (a “temperature sensor”) to measure the temperature of at least one of the battery cells is disposed between the at least one of the battery cells and a corresponding member contacting the at least one of the battery cells, the corresponding member is provided at a region thereof contacting the at least one of the battery cells with a groove formed in a shape corresponding to the temperature sensor, and the temperature sensor is disposed in contact with the outside of the at least one of the battery cells in a state in which the temperature sensor is mounted in the groove.
    Type: Grant
    Filed: October 17, 2011
    Date of Patent: August 15, 2017
    Assignee: LG CHEM, LTD.
    Inventors: Minjung Kim, Jinkyu Lee, Dal Mo Kang, Hee Soo Yoon
  • Patent number: 9711790
    Abstract: According to one embodiment, a nonaqueous electrolyte battery including a positive electrode and a negative electrode is provided. The positive electrode includes LiNixM1?xO2 wherein M is a metal element including Mn, and x is within a range of 0.5?x?1. The negative electrode includes graphitized material particles and a layer. The graphitized material particles have an interplanar spacing of (002), according to an X-ray diffraction method, of 0.337 nm or less. The layer includes a titanium-containing oxide. The layer covers at least a part of a surface of the graphitized material particles.
    Type: Grant
    Filed: September 18, 2014
    Date of Patent: July 18, 2017
    Assignee: KABUSHIKI KAISHA TOSHIBA
    Inventors: Norio Takami, Wen Zhang, Hiroki Inagaki
  • Patent number: 9698412
    Abstract: A decomposition reaction of an electrolyte solution and the like caused as a side reaction of charge and discharge is minimized in repeated charge and discharge of a lithium ion battery or a lithium ion capacitor, and thus the lithium ion battery or the lithium ion capacitor can have long-term cycle performance. A negative electrode for a power storage device includes a negative electrode current collector and a negative electrode active material layer which includes a plurality of particles of a negative electrode active material. Each of the particles of the negative electrode active material has an inorganic compound film containing a first inorganic compound on part of its surface. The negative electrode active material layer has a film in contact with an exposed part of the negative electrode active material and part of the inorganic compound film. The film contains an organic compound and a second inorganic compound.
    Type: Grant
    Filed: October 5, 2016
    Date of Patent: July 4, 2017
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventors: Nobuhiro Inoue, Kai Kimura, Sachiko Kataniwa, Ryota Tajima