Alkalated Carbon, Graphite, Or Carbonaceous Component Is Active Material Patents (Class 429/231.4)
  • Patent number: 7662513
    Abstract: A negative electrode active material for a lithium-based secondary battery includes a graphite-like carbon material having an intensity ratio I(110)/I(002) of an X-ray diffraction peak intensity I(002) at a (002) plane to an X-ray diffraction peak intensity I(110) at a (110) plane of less than 0.2.
    Type: Grant
    Filed: February 23, 2001
    Date of Patent: February 16, 2010
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Wan-uk Choi, Jae-yul Ryu, Sang-Young Yoon
  • Patent number: 7658863
    Abstract: A Si—C—O composite powder is obtained by curing a reactive silane or siloxane having crosslinkable groups through heat curing or catalytic reaction into a crosslinked product and sintering the crosslinked product in an inert gas stream at a temperature of 700-1,400° C. into an inorganic state. It exhibits satisfactory cycle performance when used as the negative electrode material for non-aqueous electrolyte secondary cells.
    Type: Grant
    Filed: July 21, 2005
    Date of Patent: February 9, 2010
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Mikio Aramata, Satoru Miyawaki, Hirofumi Fukuoka
  • Patent number: 7651820
    Abstract: A gel electrolyte and a gel electrolyte battery are provided. The gel electrolyte includes a matrix polymer; a nonaqueous solvent; and an electrolytic solution having an electrolyte salt containing lithium dissolved in the nonaqueous solvent, in which the matrix polymer is swollen with the electrolytic solution. The matrix polymer comprises polyvinylidene fluoride copolymerized with at least hexafluoropropylene in an amount of 3 wt % or more and 7.5 wt % or less. The nonaqueous solvent comprises ethylene carbonate; and at least one solvent selected from the group consisting of dimethyl carbonate, ethylmethyl carbonate, diethyl carbonate, ethylpropyl carbonate, ethyl butyl carbonate, and dipropyl carbonate. The content of the ethylene carbonate in the nonaqueous solvent is 15 wt % or more and 55 wt % or less, and the total content of the at least one solvent in the nonaqueous solvent is 30 wt % or more and 85 wt % or less.
    Type: Grant
    Filed: November 3, 2006
    Date of Patent: January 26, 2010
    Assignee: Sony Corporation
    Inventor: Mashio Shibuya
  • Patent number: 7615317
    Abstract: A rechargeable lithium-ion cell contains a positive electrode, negative electrode, charge-carrying electrolyte containing charge carrying medium and lithium salt, and cycloaliphatic N-oxide compound dissolved in or dissolvable in the electrolyte. The N-oxide compound has an oxidation potential above the positive electrode recharged potential and serves as a cyclable redox chemical shuttle providing cell overcharge protection.
    Type: Grant
    Filed: May 17, 2005
    Date of Patent: November 10, 2009
    Assignee: 3M Innovative Properties Company
    Inventors: Jeffrey R. Dahn, Claudia Buhrmester
  • Publication number: 20090269667
    Abstract: This disclosure relates to a porous electrically conductive carbon material having interconnected pores in first and second size ranges from 10 ?m to 100 nm and from less than 100 nm to 3 nm and a graphene structure and to diverse uses of the material such as an electrode in a lithium-ion battery and a catalyst support, e.g. for the oxidation of methanol in a fuel cell. The carbon material has been heat treated to effect conversion to non-graphitic carbon with the required degree of order at a temperature in the range from 600° C. to 1000° C. A lithium-ion battery and an electrode for a lithium-ion battery are also claimed.
    Type: Application
    Filed: May 25, 2007
    Publication date: October 29, 2009
    Applicant: Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.
    Inventors: Markus Antonietti, Bernd Smarsly, Philipp Adelhelm, Joachim Maier, Sarmimala Hore, Yong-Sheng Hu, Yu-Guo Guo
  • Publication number: 20090253040
    Abstract: An alkaline dry battery of this invention includes: a cylindrical battery case with a bottom; a cylindrical positive electrode having a hollow, being in contact with an inner face of the battery case, and containing a manganese dioxide powder and a graphite powder; a negative electrode disposed in the hollow of the positive electrode; a separator interposed between the positive electrode and the negative electrode; and an alkaline electrolyte. The positive electrode has cracks therein, and the cracks are substantially arc-shaped in a cross-section perpendicular to the axial direction of the positive electrode and extend in the axial direction of the positive electrode. The positive electrode has a manganese dioxide density of 2.15 to 2.30 g/cm3.
    Type: Application
    Filed: January 6, 2009
    Publication date: October 8, 2009
    Inventor: Tadaya Okada
  • Patent number: 7585590
    Abstract: Provided is a rechargeable lithium-ion cell that contains a positive electrode, a negative electrode, a charge-carrying electrolyte containing a charge carrying medium and a lithium salt, and a triphenylamine compound dissolved in or dissolvable in the electrolyte. The triphenylamine compound has an oxidation potential above the positive electrode recharged potential and serves as a cyclable redox chemical shuttle providing cell overcharge protection. Also provided are methods for manufacturing a rechargeable lithium-ion cell.
    Type: Grant
    Filed: February 5, 2007
    Date of Patent: September 8, 2009
    Assignee: 3M Innovative Properties Company
    Inventors: Richard L. Wang, Claudia Buhrmester, William M. Lamanna, Jeffrey R. Dahn, Lee Moshurchak
  • Patent number: 7579112
    Abstract: An energy storage device includes a first electrode comprising a first material and a second electrode comprising a second material, at least a portion of the first and second materials forming an interpenetrating network when dispersed in an electrolyte, the electrolyte, the first material and the second material are selected so that the first and second materials exert a repelling force on each other when combined. An electrochemical device, includes a first electrode in electrical communication with a first current collector; a second electrode in electrical communication with a second current collector; and an ionically conductive medium in ionic contact with said first and second electrodes, wherein at least a portion of the first and second electrodes form an interpenetrating network and wherein at least one of the first and second electrodes comprises an electrode structure providing two or more pathways to its current collector.
    Type: Grant
    Filed: July 26, 2002
    Date of Patent: August 25, 2009
    Assignees: A123 Systems, Inc., Massachusetts Institute of Technology
    Inventors: Yet Ming Chiang, William Douglas Moorehead, Antoni S. Gozdz, Richard K. Holman, Andrew Loxley, Gilbert N. Riley, Jr., Michael S. Viola
  • Patent number: 7563542
    Abstract: Subfluorinated graphite fluorides of formula CFx wherein CFx is in the range of 0.06 to 0.63, e.g., 0.10 to 0.46, are used as electrode materials in electrochemical devices that convert chemical energy to electrical current, e.g., batteries. The invention additionally provides methods of manufacturing electrodes with the subfluorinated graphite fluorides, as well as primary and secondary batteries containing such electrodes.
    Type: Grant
    Filed: June 6, 2006
    Date of Patent: July 21, 2009
    Assignees: California Institute of Technology, Centre National de la Recherche Scientifique
    Inventors: Rachid Yazami, André Hamwi
  • Patent number: 7563543
    Abstract: The present invention is characterized in that a negative electrode material for lithium ion secondary batteries containing graphite having high density and high isotropy is produced by pressing a spherical graphite isostatically. Use of said negative electrode material provides a negative electrode for lithium ion secondary batteries and a lithium ion secondary battery excellent in discharge load characteristics, cycle characteristics, and the like.
    Type: Grant
    Filed: July 14, 2004
    Date of Patent: July 21, 2009
    Assignee: The Kansai Coke and Chemicals Co., Ltd.
    Inventors: Koujiro Tenno, Junichi Yasumaru, Shingo Asada, Naoki Matoba, Satoshi Kubota
  • Patent number: 7563540
    Abstract: A cathode active material of formula (1) below, and a lithium secondary battery using the same, have an extended cycle life and effective charging/discharging characteristics and include a compound of formula (1) below: LixCoyM1-yA2??(1) where 0.95?x?1.0; 0?y?1; M is at least one selected from the group consisting of Ni, Fe, Pb, Mg, Al, K, Na, Ca, Si, Ti, Sn, V, Ge, Ga, B, As, Zr, Mn, and Cr; and A is one selected from the group consisting of O, F, S, and P. The cathode active material has, as measured by Raman spectroscopy, a ratio of peak intensities between spinel and hexagonal A1g vibrational modes in an approximate range of 1:0.1-1:0.4, a ratio of peak intensities between hexagonal A1g and Eg vibrational modes in an approximate range of 1:0.9-1:3.5, and a ratio of peak intensities between spinel A1g and F2g vibrational modes in an approximate range of 1:0.2-1:0.4.
    Type: Grant
    Filed: April 29, 2004
    Date of Patent: July 21, 2009
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Hyouk-soo Han, Young-min Choi
  • Patent number: 7550232
    Abstract: A lithium-ion rechargeable battery, comprising a positive electrode capable of absorbing and desorbing lithium ions, a negative electrode capable of absorbing and desorbing lithium ions, a separator interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte, wherein the negative electrode comprises a negative electrode current collector and a negative electrode material mixture layer carried on the negative electrode current collector, the negative electrode material mixture layer comprises graphite and carbon nano-tubes, and an amount of the carbon nano-tubes in the negative electrode material mixture layer is not smaller than 0.1 part by weight and not larger than 10 parts by weight, per 100 parts by weight of the graphite.
    Type: Grant
    Filed: June 2, 2004
    Date of Patent: June 23, 2009
    Assignee: Panasonic Corporation
    Inventors: Fumio Kato, Hizuru Koshina
  • Publication number: 20090123841
    Abstract: A secondary battery electrode ink is adapted to be discharged from a droplet discharge device to make an electrode layer of a secondary battery. The secondary battery electrode ink includes an active substance including at least one of a positive electrode active substance and a negative electrode active substance, and a liquid medium. The liquid medium dissolves and/or disperses the active substance. The liquid medium has a characteristic in which, when a cured epoxy adhesive material is put into the liquid medium under a sealed condition at an atmospheric pressure and a temperature of approximately 50° C. and left for ten days, a weight increase rate of the cured epoxy adhesive material is 130% or less.
    Type: Application
    Filed: November 4, 2008
    Publication date: May 14, 2009
    Applicant: Seiko Epson Corporation
    Inventors: Toshimitsu HIRAI, Hiroshi TAKIGUCHI, Yasushi TAKANO
  • Patent number: 7524588
    Abstract: A nonaqueous secondary battery includes a negative electrode using a negative electrode active material containing a carbonaceous material; a positive electrode using a positive electrode active material capable of reversibly intercalating and deintercalating lithium; and a nonaqueous electrolyte. The nonaqueous electrolyte contains: (1) a vinyl ethylene carbonate derivative represented by Formula (I): wherein R1 to R6 independently represent a hydrogen atom or an alkyl group having a carbon number of 1 to 4; (2) a cyclic acid anhydride; and (3) at least one cyclic ether derivative selected from the group consisting of 1,3-dioxanes, 1,3-dioxolanes and derivatives thereof.
    Type: Grant
    Filed: April 17, 2007
    Date of Patent: April 28, 2009
    Assignee: Sanyo Electric C.o., Ltd.
    Inventor: Kentaro Takahashi
  • Publication number: 20090104528
    Abstract: An electrode for a lithium secondary battery including a sheet-like current collector and an active material layer carried on the current collector. The active material layer is capable of absorbing and desorbing lithium, and the active material layer includes a plurality of columnar particles having at least one bend. An angle ?1 formed by a growth direction of the columnar particles from a bottom to a first bend of the columnar particles, and a direction normal to the current collector is preferably 10° or more and less than 90°. When ?n+1 is an angle formed by a growth direction of the columnar particles from an n-th bend counted from a bottom of the columnar particles to an (n+1)-th bend, and the direction normal to the current collector, and n is an integer of 1 or more, ?n+1 is preferably 0° or more and less than 90°.
    Type: Application
    Filed: November 7, 2006
    Publication date: April 23, 2009
    Inventors: Keiichi Takahashi, Masaya Ugaji, Yusutaka Kogetsu, Shinji Mino, Nobuaki Nagao, Masaki Hasegawa
  • Publication number: 20090104533
    Abstract: Disclosed are an active material for non-aqueous electrolyte secondary battery usable as a power source for backup, which has a large battery capacity and which may prevent the increase in the internal resistance after a storage test; and a non-aqueous electrolyte secondary battery comprising the active material. The active material is used as a positive electrode active material or a negative electrode active material of a non-aqueous electrolyte secondary battery, and this is prepared by adding at least one additive element selected from a group consisting of Al, B, Nb, Ti and W to molybdenum dioxide; and the non-aqueous electrolyte secondary battery comprises the active material.
    Type: Application
    Filed: September 24, 2008
    Publication date: April 23, 2009
    Inventors: Masanobu Takeuchi, Hiroyuki Fujimoto
  • Patent number: 7498101
    Abstract: A nonaqueous electrolyte secondary battery is provided with a positive electrode including a positive-electrode active material, a negative electrode including a negative-electrode active material, and a nonaqueous electrolyte solution. The negative electrode further includes carbon fibers and carbon flakes. The synergistic effects of the improved retention of the electrolyte solution by the carbon fibers and the improved conductivity between the active material particles by the carbon flakes facilitate doping/undoping of lithium in a high-load current mode and increase the capacity of the battery in the high-load current mode.
    Type: Grant
    Filed: November 29, 2006
    Date of Patent: March 3, 2009
    Assignee: Sony Corporation
    Inventors: Akira Yamaguchi, Shinji Hatake, Masayuki Nagamine, Atsuo Omaru
  • Patent number: 7482101
    Abstract: A battery is provided. The battery provides improved battery characteristics such as cycle characteristics. A battery includes a cathode; an anode; and an electrolytic solution, wherein the anode contains a carbon material, the electrolytic solution contains propylene carbonate and 4-fluoroethylene carbonate, and the content of 4-fluoroethylene carbonate is from about 0.0027 g to about 0.056 g per about 1 g of the carbon material.
    Type: Grant
    Filed: June 7, 2005
    Date of Patent: January 27, 2009
    Assignee: Sony Corporation
    Inventors: Karin Tsuda, Gentaro Kano
  • Patent number: 7479351
    Abstract: Disclosed is an electrode material for a lithium secondary battery, a lithium secondary battery comprising the same, and a method for preparing the electrode material for a lithium secondary battery. The electrode material for a lithium secondary battery includes Si as a principal component, wherein the interplanar spacing of an Si(111) surface between 3.15 ? and 3.20 ? using X-ray diffraction. This is achieve by first alloying Si with an element selected from the group consisting of Al, B, P, Ge, Sn, Pb, Ni, Co, Mn, Mo, Cr, V, Cu, Fe, Ni, W, Ti, Zn, alkali metals, alkaline earth metals, and combinations thereof, and then eluting X from the resulting alloy.
    Type: Grant
    Filed: October 8, 2004
    Date of Patent: January 20, 2009
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Keiko Matsubara, Toshiaki Tsuno, Akira Takamuka, Sung-Soo Kim, Bok-Hwan Jung
  • Publication number: 20080305396
    Abstract: An expander formulation for use in a battery paste incorporates an organic component or lignosulfonate characterized by improved resistance to high temperature degradation. Battery plates made from battery pastes which incorporate this expander formulation exhibit considerable improvements in the life of the batteries, especially at high battery operating temperatures. The organic component preferably is a purified, partially desulfonated, high molecular weight sodium lignosulfonate made from softwood.
    Type: Application
    Filed: June 6, 2007
    Publication date: December 11, 2008
    Inventor: David Paul Boden
  • Publication number: 20080274406
    Abstract: A negative-electrode material is provided that can be produced at a low cost and yields a lithium secondary battery with an excellent balance of various battery characteristics even when used in high electrode densities. It has a graphite powder with a tap density of 0.80 g/cm3 or higher and 1.35 g/cm3 or lower, an amount of surface functional groups, O/C value, of 0 or larger and 0.01 or smaller, a BET specific surface area of 2.5 m2/g or larger and 70 m2/g or smaller, a Raman R value of 0.02 or larger and 0.05 or smaller.
    Type: Application
    Filed: June 24, 2005
    Publication date: November 6, 2008
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Tooru Fuse, Hiroyuki Uono, Keita Yamaguchi, Tomiyuki Kamada
  • Patent number: 7438992
    Abstract: The invention provides novel lithium-mixed metal materials which, upon electrochemical interaction, release lithium ions, and are capable of reversibly cycling lithium ions. The invention provides a rechargeable lithium battery which comprises an electrode formed from the novel lithium-mixed metal materials. Methods for making the novel lithium-mixed metal materials and methods for using such lithium-mixed metal materials in electrochemical cells are also provided. The lithium-mixed metal materials comprise lithium and at least one other metal besides lithium. Preferred materials are lithium-mixed metal phosphates which contain lithium and two other metals besides lithium.
    Type: Grant
    Filed: February 16, 2006
    Date of Patent: October 21, 2008
    Assignee: Valence Technology, Inc.
    Inventors: Jeremy Barker, M. Yazid Saidi
  • Patent number: 7438991
    Abstract: The invention provides a non-aqueous electrolyte secondary cell that has high capacity and excels in cycle characteristics. The non-aqueous electrolyte secondary cell functions stably at a high potential of from 4.4 to 4.6 V with respect to lithium and inhibits the decomposition of the electrolytic solution at high potential. This is accomplished as follows. The non-aqueous electrolyte secondary cell has a positive electrode having a positive electrode active material; a negative electrode having a negative electrode active material; and a non-aqueous electrolyte having a non-aqueous solvent and electrolytic salt. The positive electrode active material has: lithium cobalt compound oxide having added therein at least zirconium and magnesium; and lithium-nickel-manganese compound oxide having a layered structure. The positive electrode active material has a potential of from 4.4 to 4.6 V with respect to lithium. The non-aqueous solvent contains diethyl carbonate of 10 vol. % or higher at 25° C.
    Type: Grant
    Filed: November 29, 2005
    Date of Patent: October 21, 2008
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Nobumichi Nishida, Hidetoshi Inoue
  • Patent number: 7438994
    Abstract: A non-aqueous electrolyte secondary battery has a positive electrode, a negative electrode, a separator, and a non-aqueous electrolyte solution. The positive electrode has a theoretical capacity per unit area from 3.0 to 4.5 mAh/cm2. The non-aqueous electrolyte solution contains ethylene carbonate (EC), ethylmethyl carbonate (EMC), and dimethyl carbonate (DMC) as solvents, and LiPF6 as an electrolyte, with volume ratios from 10 to 20% for EC, 10 to 20% for EMC, and 60 to 80% for DMC relative to all the solvents in the electrolyte solution. The concentration of the LiPF6 is from 1.30 to 1.50 mol/L.
    Type: Grant
    Filed: August 17, 2006
    Date of Patent: October 21, 2008
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yoshiyuki Muraoka, Takuya Nakashima, Kiyomi Kouzuki, Masatoshi Nagayama
  • Patent number: 7419747
    Abstract: An electrolyte for a secondary battery containing an aprotic solvent which contains at least imide anion, transition metal ion and a compound containing a sulfonyl group in an aprotic solvent 15. The electrolyte has the performance such as the excellent energy density and electromotive force, and the secondary battery using the electrolyte is excellent in the cycle life and the safety.
    Type: Grant
    Filed: December 3, 2003
    Date of Patent: September 2, 2008
    Assignee: NEC Corporation
    Inventors: Koji Utsugi, Mitsuhiro Mori
  • Patent number: 7416814
    Abstract: A lithium secondary battery, which comprises a positive electrode, a negative electrode containing a lithium ion-storable/dischargeable negative electrode-active material and a lithium ion conductive, non-aqueous electrolytic solution or polymer electrolyte can have distinguished charging/discharging characteristics and a higher safety, when the negative electrode material contains particles comprising carbonaceous materials and at least one of elements capable of forming a compound with Li; the elements have a melting point of at least 900° C. and a thermal expansion coefficient of not more than 9 ppm/K at room temperature; the particles are embedded in a plurality of layers of the carbonaceous materials; the particles being subjected to a mechanical treatment to make particle sizes of the particles smaller than the initial particle size in advance.
    Type: Grant
    Filed: December 31, 2002
    Date of Patent: August 26, 2008
    Assignees: Hitachi, Ltd., Hitachi Chemical Co., Ltd.
    Inventors: Junya Kaneda, Noriyuki Watanabe, Yasuhisa Aono, Seiji Takeuchi, Yasushi Muranaka, Kouichi Takei
  • Patent number: 7413829
    Abstract: In a lithium secondary battery comprising positive and negative electrodes each comprising at least an active material capable of occluding and releasing lithium ions, a binder and a current collector, and an electrolytic solution, the active material in the positive and/or negative electrode has been made conductive by coating its surface with a conductive agent and a binder, and affixed to the surface of the collector by a dry process. The lithium secondary battery is given a higher energy density and a higher output density and will find a wider range of application.
    Type: Grant
    Filed: January 31, 2007
    Date of Patent: August 19, 2008
    Assignee: TDK Corporation
    Inventors: Tadashi Suzuki, Tsuyoshi Iijima, Jun-ichi Satoh, Satoshi Maruyama
  • Patent number: 7410727
    Abstract: A graphite particle obtained by assembling or binding together a plurality of flat-shaped particles so that the planes of orientation are not parallel to one another, or a graphite particle in which aspect ratio is 5 or less or specific surface area is 8 m2/g or less or the size of crystallite in the direction of c-axis of the crystal is 500 ? or more and the size of crystallite in the direction of plane is 1,000 ? or less as measured by X ray broad angle diffraction, or a graphite particle in which pore volume of the pores having a size falling in a range of 102 to 106 ? is 0.4 to 2.0 cc/g per weight of graphite particle or pore volume of the pores having a size falling in a range of 1×102 to 2×104 ? is 0.08 to 0.4 cc/g per weight of graphite particle is suitable for production of negative electrode of lithium secondary battery, and a lithium secondary battery obtained therefrom is excellent in rapid charge-discharge characteristics, cycle characteristics, etc.
    Type: Grant
    Filed: August 31, 2005
    Date of Patent: August 12, 2008
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Yoshito Ishii, Tatsuya Nishida, Atsushi Fujita, Kazuo Yamada
  • Patent number: 7399553
    Abstract: A graphite particle obtained by assembling or binding together a plurality of flat-shaped particles so that the planes of orientation are not parallel to one another, or a graphite particle in which aspect ratio is 5 or less or specific surface area is 8 m2/g or less or the size of crystallite in the direction of c-axis of the crystal is 500 ? or more and the size of crystallite in the direction of plane is 1,000 ? or less as measured by X ray broad angle diffraction, or a graphite particle in which pore volume of the pores having a size falling in a range of 102 to 106 ? is 0.4 to 2.0 cc/q per weight of graphite particle or pore volume of the pores having a size falling in a range of 1×102 to 2×104 ? is 0.08 to 0.4 cc/g per weight of graphite particle is suitable for production of negative electrode of lithium secondary battery, and a lithium secondary battery obtained therefrom is excellent in rapid charge-discharge characteristics, cycle characteristics, etc.
    Type: Grant
    Filed: January 22, 2007
    Date of Patent: July 15, 2008
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Yoshito Ishii, Tatsuya Nishida, Atsushi Fujita, Kazuo Yamada
  • Patent number: 7399552
    Abstract: Provided is a battery capable of improving charge-discharge cycle characteristics. The battery comprises a spirally wound electrode body in which a cathode and an anode are spirally wound with a separator in between. The capacity of the anode includes a capacity component by insertion and extraction of Li and a capacity component by precipitation and dissolution of Li metal, and is represented by the sum of them. Moreover, the anode includes a carbon material capable of obtaining a first peak within a range from 1580 cm?1 to 1620 cm?1 and a second peak within a range of 1350 cm?1 to 1370 cm?1 in a Raman spectrum analysis using argon laser light with a wavelength of 5145 nm, and having an intensity ratio IB/IA between the first peak and the second peak of 0.25 to 0.6, where the intensity of the first peak is IA and the intensity of the second peak is IB. Thereby, precipitation-dissolution efficiency of lithium metal and charge-discharge cycle characteristics can be improved.
    Type: Grant
    Filed: August 17, 2004
    Date of Patent: July 15, 2008
    Assignee: Sony Corporation
    Inventors: Gentaro Kano, Karin Tsuda
  • Publication number: 20080153004
    Abstract: The present invention relates to a lithium rechargeable battery which employs a separator to minimize a short-circuit inside the battery, and has an improved thermal stability. The separator according to the present invention has a maximum thermal shrinkage of vertical direction and horizontal direction within 30%, and the ratio of maximum thermal shrinkage of horizontal direction against vertical direction ranges from 0.8 to 1.3. Therefore, the battery with highly improved thermal stability can be obtained by employing the separator not having excellent thermal shrinkage characteristics.
    Type: Application
    Filed: November 29, 2007
    Publication date: June 26, 2008
    Inventors: Jaewoong Kim, Chanjung Kim, Sukjung Son, Yunkyung Jo
  • Patent number: 7387852
    Abstract: A polymer electrolyte extends the cycle life, improves the safety, and reduces the swelling of a battery, compared with a polymer electrolyte containing a poly(alkylene oxide) polymer. Also, a lithium battery utilizes the polymer electrolyte. The polymer electrolyte contains a polymerized product from a polymer electrolyte forming composition containing a multifunctional isocyanurate monomer of a particular structure, a lithium salt, and a non-aqueous organic solvent.
    Type: Grant
    Filed: May 19, 2003
    Date of Patent: June 17, 2008
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Yong-beom Lee
  • Patent number: 7378191
    Abstract: A graphite particle obtained by assembling or binding together a plurality of flat-shaped particles so that the planes of orientation are not parallel to one another, or a graphite particle in which aspect ratio is 5 or less or specific surface area is 8 m2/g or less or the size of crystallite in the direction of c-axis of the crystal is 500 ? or more and the size of crystallite in the direction of plane is 1,000 ? or less as measured by X ray broad angle diffraction, or a graphite particle in which pore volume of the pores having a size falling in a range of 102 to 106 ? is 0.4 to 2.0 cc/g per weight of graphite particle or pore volume of the pores having a size falling in a range of 1×102 to 2×104 ? is 0.08 to 0.4 cc/a per weight of graphite particle is suitable for production of negative electrode of lithium secondary battery, and a lithium secondary battery obtained therefrom is excellent in rapid charge-discharge characteristics, cycle characteristics, etc.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: May 27, 2008
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Yoshito Ishii, Tatsuya Nishida, Atsushi Fujita, Kazuo Yamada
  • Publication number: 20080113269
    Abstract: In a negative electrode material for lithium secondary batteries, basic material particles include one of phase A having silicon as a main component, and a mixed phase of phase B including an intermetallic compound of a transition metal element and silicon and the phase A. The phase A or the mixed phase is microcrystalline or amorphous. A carbon material is adhered to surfaces of the basic material particles, and a film containing a silicon oxide is formed on remained surface portions.
    Type: Application
    Filed: January 6, 2006
    Publication date: May 15, 2008
    Inventors: Teruaki Yamamoto, Toshitada Sato, Yasuhiko Bito
  • Patent number: 7297442
    Abstract: 1. A non-aqueous electrolytic solution comprising an electrolytic salt in a non-aqueous solvent, which further contains a pentafluorophenoxy compound having the formula (I): in which R represents a substituting group such as an alkylcarbonyl group, an alkoxycarbonyl group, an aryloxy-carbonyl group, and an alkanesulfonyl group, under the condition that at least one hydrogen atom contained in the substituting group can be substituted with a halogen atom or an aryl group.
    Type: Grant
    Filed: March 13, 2003
    Date of Patent: November 20, 2007
    Assignee: Ube Industries, Ltd.
    Inventors: Koji Abe, Takaaki Kuwata, Takashi Hattori, Yasuo Matsumori
  • Publication number: 20070259265
    Abstract: The invention provides a novel polyanion-based electrode active material for use in a secondary or rechargeable electrochemical cell having a first electrode, a second electrode and an electrolyte.
    Type: Application
    Filed: April 30, 2007
    Publication date: November 8, 2007
    Inventors: M. Yazid Saidi, Haitao Huang
  • Patent number: 7288342
    Abstract: A graphite particle obtained by assembling or binding together a plurality of flat-shaped particles so that the planes of orientation are not parallel to one another, or a graphite particle in which aspect ratio is 5 or less or specific surface area is 8 m2/g or less or the size of crystallite in the direction of c-axis of the crystal is 500 ? or more and the size of crystallite in the direction of plane is 1,000 ? or less as measured by X ray broad angle diffraction, or a graphite particle in which pore volume of the pores having a size falling in a range of 102 to 106 ? is 0.4 to 2.0 cc/g per weight of graphite particle or pore volume of the pores having a size falling in a range of 1×102 to 2×104 ? is 0.08 to 0.4 cc/g per weight of graphite particle is suitable for production of negative electrode of lithium secondary battery, and a lithium secondary battery obtained therefrom is excellent in rapid charge-discharge characteristics, cycle characteristics, etc.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: October 30, 2007
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Yoshito Ishii, Tatsuya Nishida, Atsushi Fujita, Kazuo Yamada
  • Patent number: 7285359
    Abstract: An object of the present invention is to provide a negative electrode for a secondary battery which has large capacity and restrains a rise in resistance inside the battery and reduction in capacity even after cycles and the secondary battery using the same. A first active material layer 2a comprising members occluding and releasing Li onto a collector 1a is formed and a second active material layer 3a as an alloy layer containing metal forming alloy with lithium or lithium and metal not-forming alloy with lithium is formed thereon. The secondary battery is constituted using the negative electrode.
    Type: Grant
    Filed: January 22, 2003
    Date of Patent: October 23, 2007
    Assignee: NEC Corporation
    Inventors: Hironori Yamamoto, Mitsuhiro Mori, Jiro Iriyama, Mariko Miyachi, Koji Utsugi, Yutaka Bannai, Tamaki Miura, Ikiko Yamazaki
  • Patent number: 7285357
    Abstract: An electrochemically active material resulting from substituting a portion of the nickel in a single-phase composite oxide of nickel and lithium of the LiNiO2 type, characterized in that the active material satisfies the formula: Li(M1(1-a-b-c)LiaM2bM3c)O2 in which: 0.02<a?0.25; 0?b<0.30; 0?c<0.30; (a+b+c)<0.50; M3 is at least one element selected from Al, B, and Ga; M2 is at least one element selected from Mg and Zn; and M1=Ni(1-x-y-z)CoxMnyM4z in which M4 is at least one element selected from Fe, Cu, Ti, Zr, V, Ga, and Si; and 0?x<0.70; 0.10?y<0.55; 0?z<0.30; and 0.20<(1-x-y-z); b+c+z>0; and in that said active material, regardless of its state of charge, satisfies the relationship: 0.40<R<0.90, where: R=(1-a-b-c)*[3-[(nU/nMA+dox)/(4-2b-3c)]*(2-b-2c)] in which: nU is the lithium content expressed in moles; nMA is the sum of the contents of Ni, Mn, Co, and M4 expressed in moles; and dox is the overall degree of oxidation of M1.
    Type: Grant
    Filed: October 8, 2004
    Date of Patent: October 23, 2007
    Assignee: SAFT
    Inventors: Christian Jordy, Claudette Audry, Jean-Pierre Boeuve, Philippe Biensan, Andre Lecerf
  • Patent number: 7282299
    Abstract: A solid electrolyte battery includes a cathode having a cathode active material and a solid electrolyte and an anode. The solid electrolyte includes a first polymer having a binding force and a second polymer composed of alkali metal ion conducting polymers. Thus, the solid electrolyte battery has a high capacity and is excellent in its battery characteristics.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: October 16, 2007
    Assignee: Sony Corporation
    Inventors: Kazuhiro Noda, Toshikazu Yasuda, Takeshi Horie
  • Patent number: 7276314
    Abstract: The present invention is a secondary battery having a high specific capacity and good cycleability, and that can be used safely. The secondary battery is manufactured to include an anode formed from a host material capable of absorbing and desorbing lithium in an electrochemical system such as a carbonaceous material, and lithium metal dispersed in the host material. The freshly prepared anodes of the invention are combined with a positive electrode including an active material, a separator that a separates the positive electrode and the negative electrode, and an electrolyte in communication with the positive electrode and the negative electrode. The present invention also includes a method of preparing a freshly prepared anode and a method of operating a secondary battery including the anode of the invention.
    Type: Grant
    Filed: January 16, 2004
    Date of Patent: October 2, 2007
    Assignee: FMC Corporation
    Inventors: Yuan Gao, John L. Burba, III
  • Patent number: 7267907
    Abstract: The present invention relates to an electrode for a rechargeable lithium battery comprising an emulsion binder, and a lithium secondary battery including the same. The electrode comprises a current collector coated with an active material layer including active material powders and a cellulose-based polymer binder having an esterification degree greater than or equal to 1.3 and a weight average molecular weight greater than or equal to 100,000. Batteries including electrodes with an active material that includes such a cellulose-based polymer exhibit improved energy density and high reversible capacity.
    Type: Grant
    Filed: November 22, 2004
    Date of Patent: September 11, 2007
    Assignee: Samsung SDI Co., Ltd
    Inventor: Deok-Geun Kim
  • Publication number: 20070160908
    Abstract: Disclosed are an anode material for a secondary battery and a secondary battery using the same. The present invention provides the anode material for a secondary battery, produced by coating a high-crystallinity core carbonaceous material with a coating carbonaceous material and calcining the high-crystallinity core carbonaceous material, wherein the anode material for a secondary battery has a delamination area of 0.1×10?5 to 1.0×10?4 or a volume fraction of water uptake of 0.01 or less. The secondary battery according to the present invention may be useful to improve a charging/discharging capacity and a charging/discharging efficiency of the battery and ensure a stability of the battery since the battery has an improved protection against a degradation reaction of an electrolyte if the battery is produced using the anode material for a secondary battery.
    Type: Application
    Filed: January 8, 2007
    Publication date: July 12, 2007
    Inventors: Ho-Gun Kim, Jong-Sung Kim, Dong-Hun Shin, Chul Youm, Jeong-Hun Oh
  • Patent number: 7241536
    Abstract: A non-aqueous electrolyte for a lithium secondary battery is provided. The electrolyte comprises a lithium salt, a non-aqueous solvent, and an organic compound selected from the group consisting of compounds represented by Formulae (1) to (6): wherein R1 to R12 are each independently selected from the group consisting of primary, secondary, and tertiary alkyl groups, alkenyl groups, and aryl groups; X is hydrogen or halogen; and n and m are numerical values ranging from 0 to 3.
    Type: Grant
    Filed: May 8, 2002
    Date of Patent: July 10, 2007
    Assignee: Samsung SDI Co., Ltd
    Inventors: Jin-Sung Kim, Meen-Seon Paik, Jung-Joon Park, Young-Gyu Kim, Jong-Seob Kim, Hak-Soo Kim, Sang-Jun Lee, Jae-Hou Nah, Sang-Moon Hwang, Chan-Jung Kim
  • Patent number: 7238449
    Abstract: A nonaqueous electrolyte secondary battery having a positive electrode made of a carbonaceous material, an electrolyte containing a lithium salt, and a negative electrode made of metallic lithium or a material capable of occluding and releasing lithium, wherein said positive electrode is formed from a boronized graphitic material containing boron or a boron compound such that the content of boron therein is 0.05-11 wt %. A method for production of the positive electrode of the nonaqueous electrolyte secondary battery.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: July 3, 2007
    Assignee: FDK Corporation
    Inventors: Takashi Suzuki, Masanori Nakanishi, Yoshiro Harada, Hiroto Sagisaka
  • Patent number: 7238453
    Abstract: The use of at least two electrolyte salts in a lithium secondary battery provides improved battery performance such as long cycle life of high discharge capacity and high capacity retention.
    Type: Grant
    Filed: April 25, 2005
    Date of Patent: July 3, 2007
    Assignee: Ferro Corporation
    Inventors: Wu Xu, Zhongyi Deng, Pascal Bolomey, Martin W. Payne
  • Patent number: 7229716
    Abstract: A nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode comprising a graphite as a negative electrode active material, and a nonaqueous electrolyte including at least a saturated cyclic carbonic ester and containing a cyclic carbonic ester having a carbon-carbon double bond such that, when a content of the cyclic carbonic ester having a carbon-carbon double bond is x (g), a content of the graphite in the negative electrode is B (g), a specific surface area of the graphite is A (m2/g), a size of the crystallite of the graphite in a direction of the c axis is Lc, and a size of the crystallite of the graphite in a direction of the a axis is La, a condition expressed by 0.05×10?2?x/[A×B×2Lc/(2Lc+La)]?3×10?2 is satisfied.
    Type: Grant
    Filed: September 30, 2003
    Date of Patent: June 12, 2007
    Assignee: SANYO Electric Co., Ltd.
    Inventors: Katsunori Yanagida, Takao Inoue, Naoya Nakanishi, Atsuhiro Funahashi, Toshiyuki Nohma
  • Patent number: 7229719
    Abstract: A highly safe non-aqueous electrolyte secondary cell with excellent self-extinguishing property or flame retardancy is provided which comprises an anode, a cathode, a non-aqueous electrolyte in which an Li-salt as a supporting salt is dissolved in an organic solvent, and a separator. When a high crystalline carbon material such as graphite is used as cathode active substances, it is possible to provide a non-aqueous electrolyte secondary cell whose charging/discharging life is lengthened, whose interface resistance at the non-aqueous electrolyte can be reduced, and which has excellent discharging characteristics at low temperature.
    Type: Grant
    Filed: May 2, 2001
    Date of Patent: June 12, 2007
    Assignee: Bridgestone Corporation
    Inventors: Masashi Otsuki, Shigeki Endo, Takao Ogino
  • Patent number: 7208248
    Abstract: A lithium secondary battery with high-output/high-input characteristics which has a long life, and is highly safe contains a negative electrode of a negative-electrode active material. In a dispersion prepared by dispersing 100 g of the active-material powder in 200 g of water together with 2 g of carboxymethyl cellulose, the particle diameter at which particles begin to appear is 50 ?m or smaller when the dispersion is examined by the grind gauge method for determining the degree of dispersion in accordance with JIS K5400.
    Type: Grant
    Filed: August 18, 2005
    Date of Patent: April 24, 2007
    Assignee: Mitsubushi Chemical Corporation
    Inventors: Manabu Hayashi, Tomiyuki Kamada, Tadashi Ishihara
  • Patent number: 7192670
    Abstract: A fuel cell has an anode, a cathode, and a polymer electrolyte membrane placed between the anode and the cathode. The anode includes a catalyst which is composed of binary or ternary particulates deposited on a carbon support. The particulate is represented by a general formula: Pt—P, wherein Ru is optionally present. The content of P is in a range of 2 mol % to 50 mol % based on the total moles of Pt or Pt—Ru. The diameter of the catalyst particulates is in range from 1 to 3 nm.
    Type: Grant
    Filed: December 22, 2004
    Date of Patent: March 20, 2007
    Assignee: Hitachi Maxell, Ltd.
    Inventors: Hideo Daimon, Yukiko Yamamoto