Abstract: A nonaqueous electrolyte battery which is capable of minimizing damage if the battery is crushed with pressure is disclosed.

Abstract: The present invention provides a secondary electrochemical cell comprising a body of aprotic, non-aqueous electrolyte, first and second electrodes in effective electrochemical contact with the electrolyte, the first electrode comprising active materials such as a lithiated intercalation compound serving as the positive electrode or cathode and the second electrode comprising a carbon material on carbon-based substrate and serving as the negative electrode or anode; whereby they provide a secondary non-aqueous electrochemical cell having improved overdischarge and overcharge acceptance ability as compared with similar secondary non-aqueous electrochemical cells having carbon anodes with metal substrate.

Abstract: A secondary power source, which comprises a positive electrode containing activated carbon, a negative electrode containing Li4Ti5O12, and an organic electrolyte containing a lithium salt.

Abstract: A rechargeable lithium battery has a positive electrode, a negative electrode and a non-aqueous electrolyte. The positive or negative electrode contains, as its active material, a complex oxide comprising a material represented by the compositional formula MxTi1−xO2 and including an anatase-form crystal structure phase, wherein M is at least one metallic element selected from V, Mn, Fe, Co, Ni, Mo and Ir and x satisfies the relationship 0<x≦0.11. Lithium may further be added to the complex oxide.

Abstract: A secondary power source, which comprises a positive electrode containing activated carbon, a negative electrode containing a carbon material capable of doping and undoping lithium ions, and an organic electrolyte containing a lithium salt, wherein the negative electrode has a density of from 0.6 to 1.2 g/cm3.

Abstract: The present invention provides a non-aqueous electrolyte secondary cell including: a cathode containing a manganese oxide or a lithium-manganese composite oxide; an anode containing a lithium metal, a lithium alloy, or a material capable of doping/dedoping lithium; and an electrolyte containing at least two electrolyte salts, one of which is LiBF4 contained in the range from 0.005 mol/l to 0.3 mol/l. This enables to increase the cycle characteristic, preventing deterioration of the cell characteristic caused by a repeated use.

Abstract: A negative electrode active material for a lithium-based secondary battery includes a graphite-like carbon material having an intensity ratio I(110)/I(002) of an X-ray diffraction peak intensity I(002) at a (002) plane to an X-ray diffraction peak intensity I(110) at a (110) plane of less than 0.2.

Abstract: A graphite particle obtained by assembling or binding together a plurality of flat-shaped particles so that the planes of orientation are not parallel to one another, or a graphite particle in which aspect ratio is 5 or less or specific surface area is 8 m2/g or less or the size of crystallite in the direction of c-axis of the crystal is 500 Å or more and the size of crystallite in the direction of plane is 1,000 Å or less as measured by X ray broad angle diffraction, or a graphite particle in which pore volume of the pores having a size falling in a range of 102 to 106 Å is 0.4 to 2.0 cc/g per weight of graphite particle or pore volume of the pores having a size falling in a range of 1×102 to 2×104 Å is 0.08 to 0.4 cc/g per weight of graphite particle is suitable for production of negative electrode of lithium secondary battery, and a lithium secondary battery obtained therefrom is excellent in rapid charge-discharge characteristics, cycle characteristics, etc.

Abstract: A lithium battery having a separator capable of storing excess lithium ions. As lithium ions are irreversibly adsorbed by the battery electrodes, they are replenished from the excess lithium stored in the separator material, thereby extending battery life. In an example of the present invention, molecular sieves, such as 13X molecular sieves, are used as the separator material. Molecular sieves are hydroscopic and therefore also react with moisture in the battery, thereby reducing cell impedance.

Abstract: A graphite particle obtained by assembling or binding together a plurality of flat-shaped particles so that the planes of orientation are not parallel to one another, or a graphite particle in which aspect ratio is 5 or less or specific surface area is 8 m2/g or less or the size of crystallite in the direction of c-axis of the crystal is 500 Å or more and the size of crystallite in the direction of plane is 1,000 Å or less as measured by X ray broad angle diffraction, or a graphite particle in which pore volume of the pores having a size falling in a range of 102 to 106 Å is 0.4 to 2.0 cc/g per weight of graphite particle or pore volume of the pores having a size falling in a range of 1×102 to 2×104 Å is 0.08 to 0.4 cc/g per weight of graphite particle is suitable for production of negative electrode of lithium secondary battery, and a lithium secondary battery obtained therefrom is excellent in rapid charge-discharge characteristics, cycle characteristics, etc.

Abstract: The loss in delivered capacity (fade) after cycling non-aqueous rechargeable lithium batteries can be reduced by incorporating a cathode powder that has been mixed and heat-treated with a small amount of lithium borate. The invention is particularly suited to lithium ion batteries.

Abstract: The present invention relates to a negative active material for a lithium secondary battery and a manufacturing method thereof, wherein the negative active material comprises a crystalline or amorphous carbon core, a catalyst layer formed on the core, and carbon vapor growing fiber or carbon nanotubes. The negative active material not only forms a fine path between active materials but also improves conductivity between neighboring active materials so that a battery having improved high rate and cycle life characteristics can be provided, since carbon vapor growing fiber or carbon nanotubes are formed on a surface layer of the negative active material.

Abstract: The present invention provides a secondary electrochemical cell comprising a body of aprotic, non-aqueous electrolyte, first and second electrodes in effective electrochemical contact with the electrolyte, the first electrode comprising active materials such as a lithiated intercalation compound serving as the positive electrode or cathode and the second electrode comprising a carbon-carbon composite material and serving as the negative electrode or anode; whereby they provide a secondary non-aqueous electrochemical cell having improved cycle life and shelf-life characteristics as compared with similar secondary non-aqueous electrochemical cells having carbon anodes that are not carbon-carbon composite.

Abstract: According to the present invention, there are disclosed: a process for producing an anode material for lithium secondary battery, comprising graphite particles and a crystalline carbon layer covering the whole surfaces of the graphite particles, wherein the whole surfaces of the graphite particles are covered with a carbon layer in a state that the surfaces of the graphite particles and the carbon 002 plane of the carbon layer are parallel, which process comprises subjecting graphite particles to a treatment for chemical vapor deposition in a fluidized bed type reactor at 900 to 1,200° C., using a mixed gas consisting of an organic substance gas and an inert gas, the molar concentration of the organic substance gas in the mixed gas being 2 to 50%; and an anode material for lithium secondary battery, produced by the above process.

Abstract: The invention relates to negative electrodes for high-energy lithium-ion batteries, which contain Li—Me oxide with Me═Mn, Cr, Ni or Co as active cathode material, and to their production. The electrode composition contains a latex additive based on an acrylic acid derivative copolymer and a polymer binder containing butadiene units. The electrodes are produced by dispersing the carbon black, homogenized with the latex additive, in a solvent and mixing it with the graphite, and by stirring it to form a homogeneous composition, and not incorporating the polymer binder and applying the electrode composition thus obtained to the support substrate until the final stage.

Abstract: A lithium ion battery that includes: (a) a cathode; (b) an anode in the form of a thin film which, when lithiated, does not exhibit sustained self-heating at temperatures up to about 100° C.; and (c) an electrolyte separating the anode and the cathode. The battery has a capacity of at least 600 milliamp-hours, a specific energy of at least 100 watt-hours/kg, and a volumetric energy of at least 250 watt-hours/liter.

Abstract: A lithium ion secondary battery having an anode comprised of substantially crystalline graphitic carbon nanofibers composed of graphite sheets. The graphite sheets are preferably substantially perpendicular or parallel to the longitudinal axis of the carbon nanofiber. This invention also relates to the above-mentioned electrode for use in lithium ion secondary batteries.

Abstract: A nonaqueous electrolytic secondary battery includes a negative electrode, a positive electrode, and a nonaqueous electrolytic solution including an electrolytic salt dissolved in a nonaqueous solvent. A polymer is added to the nonaqueous electrolytic solution. Also, a method of making a nonaqueous electrolytic secondary battery includes the steps of placing a negative electrode, a positive electrode, and a nonaqueous electrolytic solution including an electrolytic salt dissolved in a nonaqueous solvent, in a battery housing to assemble a battery; and charging and discharging the battery under overcharge conditions or applying a pulse voltage to the battery.

Abstract: Using a graphite material capable of intercalating and de-intercalating lithium ions as the anode, the peak intensity ratio R(=I(110)/I(004)) corresponding to lattice planes (110) and (004) of graphite material obtained by wide angle X-ray diffraction measurement of this anode is in a range of 0.05 to 0.5. Hence, edges of graphite crystals exist adequately on the electrode surface at the interface to the electrolyte, and therefore intercalation of lithium proceeds smoothly, polarization at the time of charging and discharging is suppressed, and a nonaqueous electrolyte secondary battery excellent in high rate discharging characteristic is obtained. The obtained battery is small in deterioration if charging and discharging are repeated.

Abstract: The present invention discloses a composite material for anode of lithium secondary battery, comprising:

Abstract: Disclosed is a nonaqueous electrolyte secondary battery, comprising a nonaqueous electrolyte containing ethylene carbonate and &ggr;-butyrolactone, wherein, when a charge-discharge cycle test satisfying conditions (A) to (D) given below is performed under an environment of 45° C., the capacity retention rate at 100-th charge-discharge cycle is at least 85% based on the discharge capacity in the first charge-discharge cycle, (A) for the charging, the constant current-constant voltage charging to 4.2V is performed for 3 hours under a current of 1C, (B) the discharging is performed to 3V under a current of 1C, (C) after the charging, the secondary battery is left to stand for 10 minutes, followed by performing the discharging, and (D) after the discharging, the secondary battery is left to stand for 10 minutes, followed by performing the charging.

Abstract: Disclosed is a secondary battery in which the characteristic can be improved by optimizing the relation between the thickness of a positive electrode mixture layer and the thickness of a negative electrode mixture layer. The secondary battery comprises a rolled electrode body in which a band-shaped positive electrode and negative electrode are rolled with a separator in between. Lithium metal is to be precipitated in the negative electrode during charging. The capacity of the negative electrode is expressed by the sum of a capacity component by occluding/releasing lithium and a capacity component by precipitating/dissolving lithium metal. The ratio of the thickness of the positive electrode mixture layer to the thickness of the negative electrode mixture layer is 0.92 or more. Thereby, stable precipitation of lithium metal in the negative electrode can be achieved and a high energy density and an excellent cycle characteristic can be obtained.

Abstract: A rechargeable battery cell (10) having high operating voltage and significantly increased specific capacity comprises a positive electrode member (13), a negative electrode member (17), and an interposed separator member (15) containing an electrolyte comprising a solution of a polyvalent aluminum cation solute in a non-aqueous solvent. The positive electrode member comprises an active material which reversibly takes up and releases the reactive polyvalent cation species during operation of the cell while the active material of the negative electrode contemporaneously reversibly releases into and takes up from the electrolyte solvent a monovalent cation species. Preferred cation species are those of aluminum, such as Al3+, and alkali metals, such as Li+.

Abstract: To provide a battery capable of obtaining an excellent electrolyte and improved characteristics. The battery has a battery device where a positive electrode and a negative electrode are laminated with a separator in-between inside a package member. The electrolyte containing a polymer compound synthesized by polymerizing a monomer is impregnated in the separator. The synthesis of the polymer compound is inhibited by existence of Cu, thereby a negative electrode collector layer consists of foil including a metal (e.g., Ni, Cr, Au), which is not copper and does not form an alloy with lithium, or Cu foil covering the above metal. Therefore, even if the polymer compound is synthesized after fabricating the battery, polymerization can smoothly progress and content of a remained monomer can be reduced. This can prevent deterioration of battery characteristics because decomposition or reaction of the monomer is controlled even if charge and discharge are repeatedly conducted.

Abstract: Enhancement of the storage property at a high temperature and discharge characteristics at a low temperature of a nonaqueous electrolyte secondary cell is intended. A negative electrode material which is prepared by covering the surface of a nucleus made of a graphite powder with a carbonaceous matter, the graphite powder having a specified plane interval, spectrum value, mean particle size, specific surface area, tapping density, and (110)/(004) X-ray peak intensity ratio, is used in the nonaqueous electrolyte secondary cell.

Abstract: The invention relates to a lithium-rich carbonaceous substance which can be used as a negative electrode in a lithium accumulator. This substance has the following formula: LiNaxCyOz  (I) in which x, y and z are such that 0.4≦x≦0.6 2.5≦y≦3.5 0.2≦z≦1 It can be prepared by the insertion of lithium electrochemically in a graphite-sodium-oxygen compound.

Abstract: A water-soluble binder useful for preparing an electrode for either primary or secondary batteries, having either aqueous or non-aqueous electrolyte, contains polyacrylamide and at least one copolymer selected from carboxylated styrene-butadiene copolymer and styrene-acrylate copolymer. The water-dispersible binder eliminates or reduces the need for organic solvents during preparation of an electrode made of a particulate active electrode material. The binder exhibits good chemical resistance, adhesive properties, flexibility and resilience, making it well suited for use in preparing batteries having a spirally wound electrode assembly.

Abstract: A negative active material for a lithium secondary battery includes a crystalline graphite core and a carbon shell. The carbon shell includes at least one material selected from a transition metal, an alkali metal, an alkaline earth metal, an element of Group 3B of the Periodic table, an element of Group 4B, an element of Group 5B or a mixture thereof. The carbon shell is a turbostratic carbon layer, or am amorphous or crystalline carbon layer having different physical properties from the core. The negative active material can be used in a lithium secondary battery such that the battery has a large discharge capacity and a high charge/discharge efficiency.

Abstract: A negative electrode for a lithium rechargeable battery includes a carbon material in which lithium intercalation occurs, and at least one metallic oxide selected from yttrium oxide, cerium oxide, and titanium oxide.

Abstract: A non-aqueous electrolyte cell having improved cyclic characteristics at elevated temperatures. The non-aqueous electrolyte cell includes a positive electrode, a negative electrode and a non-aqueous electrolyte. The positive electrode contains, as a positive electrode active material, a lithium transition metal composite oxide represented by the general formula LiCoxAyBzO2 where A denotes at least one selected from the group consisting of Al, Cr, V, Mn and Fe, B denotes at least one selected from the group consisting of Mg and Ca and x, y and z are such that 0.9≦x<1, 0.001≦y≦0.05 and 0.001≦z≦0.05.

Abstract: A process for producing an electrode for a battery, wherein electrode active material layers are firmly formed on both surfaces of a current collector for the electrode. An electrode coating containing an electrode active material, a binder, a solvent and an acid is applied to one surface of an electrode current collector, then dried, and the other surface of the current collector is cleaned with water, and the electrode active material layer is formed on the other surface of the current collector.

Abstract: Disclosed is an electrolyte capable of obtaining an excellent quality of electrolyte, and a battery using the electrolyte. A battery device in which a positive electrode and a negative electrode are stacked with a separator being interposed therebetween is enclosed inside an exterior member. The separator is impregnated with an electrolyte. The electrolyte contains a high polymer, a plasticizer, a lithium and at least either carboxylic acid or carboxylate. Therefore, when preparing a high polymer by means of polymerization of monomers, the polymerization of monomers can be smoothly processed even if there is a factor for inhibiting reaction such as copper. As a result, the amount of non-reacted monomers remained in the electrolyte can be suppressed to be extremely small. Therefore, decomposition and reaction of monomers are suppressed even after repeating charging/discharging, so that the deterioration in the charging/discharging efficiency and the charging/discharging characteristic can be prevented.

Abstract: This invention provides a lithium secondary battery comprising a positive electrode, a negative electrode comprising a carbonaceous material which is capable of absorbing and desorbing lithium ions, and a nonaqueous electrolyte, wherein the carbonaceous material has a region of amorphous carbon structure and a region of graphite structure, and the carbonaceous material has a true density of 1.8 g/cm3 or more and a peak in powder X-ray diffraction which corresponds to not more than 0.340 nm in an interplanar spacing d002 derived from (002) reflection.

Abstract: A nonaqueous electrolyte secondary battery includes a positive electrode having a positive electrode active material, a negative electrode containing a negative electrode active material capable of being doped/undoped with lithium, and a nonaqueous electrolyte. The nonaqueous electrolyte contains at least one of thiols, thiophenes, thioanisoles, thiazoles, thioacetates, aromatic sulfones, and the derivatives thereof. The capacity of the battery is not significantly degraded after cycling and its cycle life is significantly long.

Abstract: This invention provides a nonaqueous electrolyte secondary battery including a negative electrode containing a carbonaceous material aggregate having a structure in which carbonaceous material plates are three-dimensionally distributed, the carbonaceous material plates being capable of absorbing and desorbing lithium ions and having a molar ratio of hydrogen to carbon of 0.2 to 0.4.

Abstract: A graphite particle obtained by assembling or binding together a plurality of flat-shaped particles so that the planes of orientation are not parallel to one another, or a graphite particle in which aspect ratio is 5 or less or specific surface area is 8 m2/g or less or the size of crystallite in the direction of c-axis of the crystal is 500 Å or more and the size of crystallite in the direction of plane is 1,000 Å or less as measured by X ray broad angle diffraction, or a graphite particle in which pore volume of the pores having a size falling in a range of 102 to 106 Å is 0.4 to 2.0 cc/g per weight of graphite particle or pore volume of the pores having a size falling in a range of 1×102 to 2×104 Å is 0.08 to 0.4 cc/g per weight of graphite particle is suitable for production of negative electrode of lithium secondary battery, and a lithium secondary battery obtained therefrom is excellent in rapid charge-discharge characteristics, cycle characteristics, etc.

Abstract: A non-aqueous electrochemical cell comprising a cathode, non-aprotic or polymeric electrolyte and an anode of carbon-based bonded particles coated with a thin (less than 1 micron thick) solid electrolyte interphase which is a M conductor and electronic insulator consisting of alkali metal or alkaline earth salts, oxides or sulfides, said cell being assembled in the non-charged state.

Abstract: A method and system for fabricating solid-state energy-storage devices including fabrication films for devices without an anneal step. A film of an energy-storage device is fabricated by depositing a first material layer to a location on a substrate. Energy is supplied directly to the material forming the film. The energy can be in the form of energized ions of a second material. Supplying energy directly to the material and/or the film being deposited assists in controlling the growth and stoichiometry of the film. The method allows for the fabrication of ultrathin films such as electrolyte films and dielectric films.

Abstract: A carbonaceous electrode having improved capacities for doping and dedoping of a cell active substance, such as lithium, and suitable for a non-aqueous solvent secondary battery, is constituted by a carbonaceous material having a true density as measured by a butanol substitution method of at most 1.46 g/cm3, a true density as measured by a helium substitution method of at least 1.7 g/cm3, a hydrogen-to-carbon atomic ratio H/C of at most 0.15 as measured according to elementary analysis, a BET specific surface area of at most 50 m2/g as measured by nitrogen adsorption BET method, and a carbon dioxide adsorption capacity of at least 10 ml/g. The carbonaceous material is advantageously produced by carbonizing an organic material originated from bamboo genera of family Gramineae, particularly genus Pleioblastus or Bambusa, at 1000-1400° C. under a reduced pressure or under a flowing inert gas stream to provide an appropriate porous structure.

Abstract: Disclosed is an electrode material for secondary battery, wherein the discharge capacity is large and the change in potential during the charge/discharge is small. A carbonaceous material, wherein a value of R (degree of raphitization ), which is defined as a ratio of a Raman spectrum intensity at 1580 cm−1 to a Raman spectrum intensity at 1360 cm−1 in the Raman spectrum analysis, is not more than 4.0 and a length of crystallite (Lc) oriented along a crysatllographic c axis obtained by a wide angle X-ray diffraction method is from 25 to 35 nm, of the electrode material is obtained by calcining a material, which can be carbonized by a heat treatment, in the presence of boron nitride or silicon.

Abstract: A lithium cell, having positive and negative electrodes capable of occluding and releasing lithium and a non-aqueous electrolyte. The cell of the present invention includes a positive electrode, a negative electrode and a gelated electrolyte composed of a polyacrylonitrile containing high molecular material, a &ggr;-caprolactone containing non-aqueous solvent and an electrolyte salt mainly comprised of LiPF6, with the content of &ggr;-caprolactone in the gelated electrolyte being 30 mol % or less. With the gelated electrolyte composed of the polyacrylonitrile containing high molecular material, non-aqueous solvent and the electrolyte salt mainly composed of LiPF6, a carbide film is formed on the electrode surface, on contact with the flame, as a result of the carbonization of the high molecular material and the carbonization accelerating operation of LiPF6. This carbide film inhibits inflammation for realizing superior combustion retardant properties.

Abstract: A rechargeable lithium-ion cell capable of being discharged to deliver high power pulses sufficient for implantable defibrillation applications and the like, is described. The cell is housed in a casing having an external volume of 5 cm3, or less. Both the negative and positive electrodes are less than about 0.15 mm in total thickness. Negative and positive electrodes of a reduced thickness provide the cell with high electrode surface area relative to its volume. As such, the present cell is capable of providing pulses in excess of 30 C. with minimal voltage drop.

Abstract: A non-aqueous electrolyte cell in which the cell capacity is improved and positioning accuracy of external terminals is assured. An unit cell is housed in an exterior packaging material of a laminated film and encapsulated on heat sealing. To elongated positive and negative terminals of the unit cell are electrically connected electrode terminal leads which are exposed to outside of the exterior packaging material as the leads are surrounded by heat fused portions. The unit cell is a wound assembly of the positive and negative electrodes each of which is comprised of a current collector carrying a layer of an active material. The electrode terminal leads are mounted on the current collectors of the positive and negative electrodes in the vicinity of the innermost turn of the wound assembly. In manufacturing the unit cell, the positions of the electrode terminal leads are detected and positioned with respect to the flat winding arbor. The positive and negative electrodes then are wound on the winding arbor.

Abstract: A method for forming lithium electrodes having protective layers involves plating lithium between a lithium ion conductive protective layer and a current collector of an “electrode precursor.” The electrode precursor is formed by depositing the protective layer on a very smooth surface of a current collector. The protective layer is a glass such as lithium phosphorus oxynitride and the current collector is a conductive sheet such as a copper sheet. During plating, lithium ions move through the protective layer and a lithium metal layer plates onto the surface of the current collector. The resulting structure is a protected lithium electrode. To facilitate uniform lithium plating, the electrode precursor may include a “wetting layer” which coats the current collector.

Abstract: Carbonaceous insertion compounds and methods for preparation are described wherein the compounds comprise a highly disordered, impurity free, hard pre-graphitic carbonaceous host. Carbonaceous insertion compounds can be prepared which have large reversible capacity for lithium yet low irreversible capacity and voltage hysteresis. Such insertion compounds can be prepared by simple pyrolysis of suitable epoxy, phenolic resin, or carbohydrate precursors at an appropriate temperature. These insertion compounds may be suitable for use as high capacity anodes in lithium ion batteries.

Abstract: A graphite particle obtained by assembling or binding together a plurality of flat-shaped particles so that the planes of orientation are not parallel to one another, or a graphite particle in which aspect ratio is 5 or less or specific surface area is 8 m2/g or less or the size of crystallite in the direction of c-axis of the crystal is 500 Å or more and the size of crystallite in the direction of plane is 1,000 Å or less as measured by X ray broad angle diffraction, or a graphite particle in which pore volume of the pores having a size falling in a range of 102 to 106 Å is 0.4 to 2.0 cc/g per weight of graphite particle or pore volume of the pores having a size falling in a range of 1×102 to 2×104 Å is 0.08 to 0.4 cc/g per weight of graphite particle is suitable for production of negative electrode of lithium secondary battery, and a lithium secondary battery obtained therefrom is excellent in rapid charge-discharge characteristics, cycle characteristics, etc.

Abstract: A lithium ion battery electrode formed by the pyrolysis of a silane polymer followed by introducing lithium ions. These electrodes can be used to form batteries with large capacities, low irreversible capacity, high density and good safety behavior.

Abstract: Carbon fiber having cross sectional shape which satisfies area replenishment rate of 0.8 or more is used as anode material for non-aqueous electrolyte secondary battery. Alternatively, since value of fractal dimension of cross section high order structure of the random radial type carbon fiber can be utilized as material parameter for evaluating the cross sectional structure, carbon fiber in which the value of the fractal dimension is caused to fall within the range from 1.1 to 1.8 and the crystallinity has been controlled such that it falls within reasonable range is used as anode material for non-aqueous electrolyte secondary battery. Further, carbon fiber having cross section high order structure such that the central portion is radial type structure and the surface layer portion is random radial type structure is used as anode material for non-aqueous electrolyte secondary battery. Furthermore, it is also effective to use carbon fiber having notch structure at the cross section.

Abstract: A non-aqueous electrolytic secondary battery that can prevent a drop in the power even in a large current discharge is provided. Porosity of a separator is larger than or the same as porosity of a positive electrode mixture and a porosity of a negative electrode mixture. Particularly, the porosity of the positive electrode mixture is 20% to 50%, the porosity of the negative electrode mixture is 20% to 50%, and the porosity of the separator is 20% to 60%. The separator becomes rich in the volume of the electrolytic solution that infiltrates into interfacial aperture between the separator and the negative electrode. When the large current discharge is carried out in a short time, lithium-ions are released/occluded from the electrodes and the electrolytic solution can gain the released/occluded lithium-ions with a small interfacial resistance.

Abstract: A carbonaceous electrode having improved capacities for doping and dedoping of a cell active substance, such as lithium, and suitable for a non-aqueous solvent-type secondary battery, is constituted by a carbonaceous material having a pore volume of at least 0.55 ml/g of pores having a pore diameter of at most 5 &mgr;m as measured by mercury injection method, a potassium content of at most 0.5 wt. % as measured by fluorescent X-ray analysis, and a specific surface area of at most 100 m2/g as measured by nitrogen adsorption BET method. The carbonaceous material is advantageous produced by carbonizing a carbon precursor of plant origin having a potassium content of at most 0.5 wt. % as measured by fluorescent X-ray analysis, in contact with a stream of an inert gas optionally containing a halogen gas at a temperature of 700-1500° C.