The Alkali Metal Is Lithium Patents (Class 429/231.95)
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Patent number: 12043681Abstract: The present invention pertains to vinylidene fluoride copolymers comprising recurring units derived from chlorotrifluoroethylene and from a (meth)acrylic monomer having improved flexibility, to a process for their manufacture, and to their use in applications where outstanding flexibility is required.Type: GrantFiled: December 19, 2019Date of Patent: July 23, 2024Assignee: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.Inventor: Julio A. Abusleme
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Patent number: 12046752Abstract: A positive electrode active material includes a lithium-transition metal composite phosphate including a first crystalline phase having a composition represented by Formula 1 and having an olivine structure, and a second crystalline phase having a composition represented by Formula 2 and having a pyrophosphate-containing structure, wherein the second crystalline phase is in an amount of greater than 0 mole percent and not greater than 50 mole percent with respect to a total number of moles of the first crystalline phase and the second crystalline phase, a positive electrode, a secondary battery: LixM1yPO4??Formula 1 LiaM2b(P2O7)4??Formula 2 In Formulas 1 and 2, 0.9?x?1.1, 0.9?y?1.1, 5.5?a?6.5, and 4.8?b?5.2, and M1 and M2 are each independently an element from Groups 3 to 11 in the 4th period of the Periodic Table of the Elements, or a combination thereof.Type: GrantFiled: December 9, 2021Date of Patent: July 23, 2024Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Sangbok Ma, Joonhee Kim, Jonghoon Ka, Sungjin Lim
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Patent number: 12046748Abstract: A non-aqueous electrolyte secondary battery according to one embodiment of the present disclosure is provided with a positive electrode, a negative electrode, and a non-aqueous electrolyte, wherein the positive electrode includes a positive electrode active material containing a composite oxide particle that includes Ni, Co and Li, and also includes at least one among Mn and Al, and the ratio of Ni to the total number of moles of metal elements excluding Li is 50 mol % or more. In the composite oxide particle, the ratio (A/B) of a BET specific surface area (A) to a theoretical specific surface area (B) determined by the following formula is more than 1.0 and less than 3.3. Theoretical specific surface area (B) (m2/g)=6/(true density (g/cm3)×volume average particle diameter (?m)).Type: GrantFiled: July 19, 2018Date of Patent: July 23, 2024Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Yuta Kuroda, Manabu Takijiri
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Patent number: 12040491Abstract: A binder is for a secondary battery electrode and exhibits high binding properties in an electrode mixture layer and is capable of exhibiting superior cycle characteristics than before. This binder for a secondary battery electrode includes a cross-linked polymer or salt thereof, and the cross-linked polymer or salt thereof has a sol fraction of 5.0 mass % or more and 40 mass % or less. The cross-linked polymer or salt thereof may contain 50 mass % or more and 100 mass % or less of structural units derived from an ethylenic unsaturated carboxylic acid monomer.Type: GrantFiled: December 10, 2019Date of Patent: July 16, 2024Assignee: TOAGOSEI CO. LTD.Inventors: Tomoko Nakano, Ayano Higasayama, Naohiko Saito
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Patent number: 12034152Abstract: A cathode for a lithium-sulfur battery includes a sulfur-based composite layer having a porosity in a range of 60% to 99%; and a conductive polymer disposed atop the composite layer and within pores of the composite layer. Moreover, a method of forming a cathode for a lithium-sulfur battery includes providing a substrate; disposing a sulfur-based slurry layer on the substrate; freeze-drying the slurry layer to form a sulfur-based composite layer having a porosity in a range of 60% to 99%; and disposing a conductive polymer atop the composite layer and within pores of the composite layer.Type: GrantFiled: June 20, 2019Date of Patent: July 9, 2024Assignees: CORNING INCORPORATED, Shanghai Institute of Ceramics, Chinese Academy of SciencesInventors: Michael Edward Badding, Jun Jin, Yang Lu, Zhen Song, Zhaoyin Wen, Tongping Xiu
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Patent number: 12034146Abstract: An electrode for a lithium secondary battery includes an electrode current collector, an electrode active material layer formed on at least one surface of the electrode current collector and including electrode active material particles, and a lithium salt-containing coating formed on at least portions of surfaces of the electrode active material particles or at least a portion of the surface of the electrode active material layer. The electrode for a lithium secondary battery may have a predetermined surface roughness.Type: GrantFiled: July 12, 2023Date of Patent: July 9, 2024Assignee: SK On Co., Ltd.Inventors: Gi Hyeon Moon, Jong Hyuk Lee, Mi Ryeong Lee, Hee Gyoung Kang
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Patent number: 12034155Abstract: The present application relates to a secondary battery, which includes: a cathode sheet, an anode sheet, and an electrolyte; the cathode sheet includes a cathode film layer containing a cathode active material, and the anode sheet includes an anode film layer containing an anode active material; and the secondary battery meets a following function relationship: 0.22?3×(A1/A2)×(B2?B1)/(B1+B2)?1.55, the parameters are referred to the description; and an electrical device including the secondary battery. The secondary battery in the present application has both good cycle life and excellent fast charging capacity.Type: GrantFiled: January 29, 2024Date of Patent: July 9, 2024Assignee: CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITEDInventors: Dejun Xiao, Jiahua Chen, Qian Liu, Quanguo Li, Jingxuan Sun
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Patent number: 12027694Abstract: A nonaqueous electrolyte secondary battery according to an embodiment includes a spirally wound electrode body in which a positive electrode and a negative electrode are spirally wound with a separator interposed therebetween. The negative electrode includes a negative electrode current collector, a first negative electrode mixture layer disposed on a first surface of the negative electrode current collector, and a second negative electrode mixture layer disposed on a second surface of the negative electrode current collector. The first surface and the second surface face outward and inward of the electrode body, respectively. At least the first negative electrode mixture layer includes a Si active material. The content of the Si active material in terms of Si in the second negative electrode mixture layer is lower than the content of the Si active material in terms of Si in the first negative electrode mixture layer.Type: GrantFiled: April 26, 2019Date of Patent: July 2, 2024Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Takamasa Tamura, Nobuhiro Sakitani, Takaharu Morikawa
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Patent number: 12027697Abstract: Disclosed, as a particle for cathode active materials, is a novel one-body particle for cathode active materials, including a core of lithium transition metal oxide containing Ni and a surface-layer portion formed on at least a part of the core, wherein the surface-layer portion contains both Co and a structure-stabilizing element, the core is present as a non-aggregated primary particle, and the structure-stabilizing element has a bond dissociation energy (BDE) with oxygen (O) greater than a bond dissociation energy (BDE) of Co and oxygen (O).Type: GrantFiled: October 22, 2021Date of Patent: July 2, 2024Assignee: L&F CO., LTD.Inventors: Hyun Gyu Han, Han Ah Kim, Gi Hwan Chang, Jeong A Gu, Sung Kyun Chang, Doe Hyoung Kim
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Patent number: 12027671Abstract: Provided is a laminated battery superior in current collection properties. A laminated battery disclosed herein includes a plurality of power generation elements. Each of the power generation elements includes a first electrode layer, a second electrode layer, and a solid electrolyte layer interposed between the first electrode layer and the second electrode layer. The laminated battery includes a first collector. The plurality of power generation elements are laid up via the first collector. A dimension of a main surface of the first collector in at least one direction is smaller than a dimension of a main surface of the first electrode layer in the same direction. An insulating adhesive is disposed at a position straddling an edge of the first collector, such that the insulating adhesive bonds a main surface of one of the power generation elements and a main surface of a power generation element adjacent thereto.Type: GrantFiled: September 21, 2020Date of Patent: July 2, 2024Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Masato Ono, Kazuhito Kato
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Patent number: 12021186Abstract: An all-solid-state battery system having a solid-state electrolyte composite is provided. The solid-state electrolyte composite includes a porous framework providing support and mechanical strength for the solid-state electrolyte composite and a plurality of ionic conductors filling voids of the porous framework for maximizing ionic conductance of the solid-state electrolyte composite. The porous framework may be made of ultra-high-molecular-weight polyethylene (UHMWPE) polymers and the plurality of ionic conductors may be made of poly(ethylene oxide)-LiN(SO2CF3)2 (PEO-LiTFSI) polymers. The all-solid-state battery system includes battery cells each including a cathode current collector, a cathode disposed beneath and connected to the cathode current collector, the solid-state electrolyte composite disposed beneath and connected to the cathode, an anode disposed beneath and connected to the solid-state electrolyte composite, and an anode current collector disposed beneath and connected to the anode.Type: GrantFiled: April 8, 2021Date of Patent: June 25, 2024Assignee: The Hong Kong University of Science and TechnologyInventors: Ping Gao, Minhua Shao, Jiadong Li, Qiao Gu, Jin Li
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Patent number: 12021219Abstract: A method and apparatus for fabricating electrodes used in energy storage devices are provided. In some implementations a surface of the electrode is activated for (a) a pre-treatment process to remove loosely held particles from the electrode surface; (b) a pre-treatment process to activate the surface of the electrode material for improved bonding or wetting for subsequently deposited materials; (c) a post-treatment of the pre-lithiation layer to improve subsequent bonding with additionally deposited layer, for example, passivation layers; and/or (d) a post-treatment of the pre-lithiation layer to improve/accelerate absorption of the lithium into the underlying electrode material.Type: GrantFiled: April 7, 2022Date of Patent: June 25, 2024Assignee: Applied Materials, Inc.Inventors: Subramanya P. Herle, Girish Kumar Gopalakrishnan Nair, Daniel Stock, Sambhu Kundu, Ezhiylmurugan Rangasamy
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Patent number: 12021238Abstract: Batteries, component structures and manufacturing methods, in particular including a glassy embedded battery electrode assembly having a composite material structure composed of interpenetrating material components including a porous electroactive network including a solid electroactive material, and a continuous glassy medium including a Li ion conducting sulfide glass, can achieve enhanced power output, reduced charging time and/or improved cycle life.Type: GrantFiled: June 4, 2021Date of Patent: June 25, 2024Assignee: PolyPlus Battery CompanyInventors: Steven J. Visco, Yevgeniy S. Nimon, Bruce D. Katz, Vitaliy Nimon
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Patent number: 12015124Abstract: A solid-state battery including a battery element that includes one or more battery constitutional units, each battery constitutional unit including a positive electrode layer and a negative electrode layer facing each other and a solid electrolyte layer arranged between the positive electrode layer and the negative electrode layer; a first protective layer covering an upper surface of the battery element; and a second protective layer covering a lower surface of the battery element, wherein the first and second protective layers include an insulating substance other than resin.Type: GrantFiled: March 11, 2021Date of Patent: June 18, 2024Assignee: MURATA MANUFACTURING CO., LTD.Inventors: Makoto Yoshioka, Kenichi Bando
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Patent number: 12015143Abstract: A method of manufacturing a negative electrode for a secondary battery. The method includes forming a first negative electrode active material layer including a carbon-based active material on at least one surface of a negative electrode current collector; and forming a second negative electrode active material layer including a silicon-based active material on a surface of the first negative electrode active material opposite the negative electrode current collector, wherein the silicon-based material is intercalated with lithium by pre-lithiation on the first negative electrode active material layer.Type: GrantFiled: January 16, 2020Date of Patent: June 18, 2024Assignee: LG ENERGY SOLUTION, LTD.Inventors: Ye Ri Kim, Sang Wook Woo, Oh Byong Chae
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Patent number: 12015151Abstract: A composite positive active material represented by Formula 1, LiaNibCOcMndMeO2??Formula 1 wherein, in Formula 1, M is zirconium (Zr), aluminum (Al), rhenium (Re), vanadium (V), chromium (Cr), iron (Fe), gallium (Ga), silicon (Si), boron (B), ruthenium (Ru), titanium (Ti), niobium (Nb), molybdenum (Mo), magnesium (Mg), or platinum (Pt), 1.1?a?1.3, b+c+d+e?1, 0?b?0.3, 0?c?0.3, 0<d?0.6, and 0?e?0.1, wherein, through atomic interdiffusion of lithium and the metal, the composite positive active material has a uniform distribution of lithium excess regions and a uniform degree of disorder of metal cations, and the metal cations have a disordered, irregular arrangement at an atomic scale. Also a method of preparing the composite positive active material, a positive electrode including the composite positive active material, and a lithium battery including the positive electrode.Type: GrantFiled: May 19, 2022Date of Patent: June 18, 2024Assignees: SAMSUNG ELECTRONICS CO., LTD., POSTECH ACADEMY-INDUSTRY FOUNDATIONInventors: Donghee Yeon, Byoungwoo Kang, Junghwa Lee, Byungjin Choi, Sukgi Hong, Jinsu Ha
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Patent number: 12012506Abstract: A method of forming an antistatic plastic includes providing a mixture containing 10 parts by weight of crystalline silicon particles, 1 to 30 parts by weight of an encapsulant, and 0.5 to 25 parts by weight of a backsheet material. The mixture is compounded to form an antistatic plastic, wherein the encapsulant is different from the backsheet material.Type: GrantFiled: February 20, 2023Date of Patent: June 18, 2024Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Chin-Shang Hsu, Pang-Hung Liu, Nien-Tsu Lee, Chien-Wei Lu
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Patent number: 12009478Abstract: Aspects of the disclosure relate to solid state electrolytes which include a composition of Li6PS5Cl having a dopant substituted, in part, for phosphorus (P-site dopant) and an excess molar amount of Cl (i.e., doped, off-stoichiometric compositions). The P-site dopant can be selected among Groups 4, 5, 14, or 15 of the periodic table of elements and has an ionic radius greater than phosphorus (P). Such solid state electrolytes can be used in all solid-state batteries and configured for use in electric vehicles.Type: GrantFiled: July 25, 2023Date of Patent: June 11, 2024Assignee: Rivian IP Holdings, LLCInventors: Rubayyat Mahbub, Chen Chen, Hui Dong, Sonika Rajput, Thomas Andrew Wynn, Forrest Stephen Gittleson, Shyam Dwaraknath
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Patent number: 12009519Abstract: A cathode active material includes a compound represented by Formula 1: Lix(Co1?yMy)z(P2O7)4??Formula 1 wherein in Formula 1, 5?x?7, 0.01?y?0.1, and 4?z?6, and M is a Group 3 to 11 element belonging to 5th and 6th periods in the Periodic Table of the elements, or a combination thereof.Type: GrantFiled: September 23, 2021Date of Patent: June 11, 2024Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Joonhee Kim, Sangbok Ma, Jonghoon Ka
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Patent number: 12009516Abstract: A fast charging lithium-ion battery includes a positive electrode plate, a negative electrode plate, a separator, and an electrolyte. The positive electrode plate includes a positive current collector and a positive active material layers. The negative electrode plate includes a negative current collector and negative active material layers. The negative active material layers include titanium niobium oxide, lithium titanate, or a combination thereof. The separator is disposed between the positive electrode plate and the negative electrode plate. The electrolyte contacts the positive electrode plate and the negative electrode plate. The negative active material layers have an effective area corresponding to the positive electrode plate. The negative active material layers have a thickness on one surface of the negative current collector. A ratio of the effective area to the thickness is greater than 2×105 mm.Type: GrantFiled: September 18, 2020Date of Patent: June 11, 2024Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Deng-Tswen Shieh, Sheng-Fa Yeh, Shih-Chieh Liao, Ching-Yu Chen, Hao-Tzu Huang
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Patent number: 12009512Abstract: A nonaqueous electrolyte secondary battery according to an embodiment includes a negative electrode including a negative electrode current collector, a first negative electrode mixture layer disposed on a first surface of the negative electrode current collector, and a second negative electrode mixture layer disposed on a second surface of the negative electrode current collector. The first surface and the second surface face outward and inward of the electrode body, respectively. The first negative electrode mixture layer includes a Si active material. The content of the Si active material in teens of Si is lower in a portion of the first negative electrode mixture layer which faces the negative electrode current collector in a thickness direction of the first negative electrode mixture layer, than in a portion of the first negative electrode mixture layer which faces the surface of the first negative electrode mixture layer in the thickness direction.Type: GrantFiled: April 26, 2019Date of Patent: June 11, 2024Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Takamasa Tamura, Nobuhiro Sakitani, Takaharu Morikawa
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Patent number: 12002986Abstract: A separator for an electrochemical device. The separator includes a porous substrate made of a porous polymer film having an excellent compressibility and permanent strain. The porous substrate has excellent physical strength and durability, and ensures a high breakdown voltage while using a heat resistant layer having a small thickness, and thus shows a low possibility of short-circuit generation. In addition, the separator may further include a heat resistant layer including inorganic particles, on the surface of the porous substrate. It is possible to further improve the compressibility, maximum compressibility and permanent strain characteristics depending on the types of inorganic particles.Type: GrantFiled: June 21, 2019Date of Patent: June 4, 2024Assignee: LG ENERGY SOLUTION, LTD.Inventors: Su-Jin Park, Chan-Jong Kim, Sang-Joon Lee
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Patent number: 12002990Abstract: The present invention relates to a porous separator comprising a porous layer containing a plurality of plate-type inorganic particles and a first binder polymer positioned on part or all of the surface of the plate-type inorganic particles to connect and fix between the plate-type inorganic particles; and a metal layer formed on any one surface of the porous layer, and a lithium secondary battery comprising the same.Type: GrantFiled: October 11, 2019Date of Patent: June 4, 2024Assignee: LG Energy Solution, Ltd.Inventors: Woongchul Choi, Junghun Choi, Yonghee Kang, Minchul Jang, Suk Il Youn, Byoungkuk Son
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Patent number: 11996539Abstract: A method for producing a secondary battery electrode, according to the present invention, comprises: a slicing step for producing an active material film by slicing an active material bulk; and a binding step for combining a current collector and the active material film. A method for producing a secondary battery electrode according to the present invention produces an active material film by slicing an active material bulk, which is a free-standing molded body or pellet, thus allowing binder-free active material film to be produced, and as no actual restrictions exist for the thickness of the active material film, thick active material film can be produced, and thus electrodes having high-loading and high composite density can be produced.Type: GrantFiled: March 15, 2019Date of Patent: May 28, 2024Assignee: SK ON CO., LTD.Inventors: Jonghyuk Lee, Dockyoung Yoon, Heegyoung Kang
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Patent number: 11996552Abstract: An anode, a lithium battery including the anode, and a method of preparing the anode. The anode includes a current collector; a first anode layer disposed on the current collector; a second anode layer disposed on the first anode layer; and an inorganic protection layer disposed on the second anode layer, wherein an oxidation/reduction potential of the first anode layer and an oxidation/reduction potential of the second anode layer are different from each other.Type: GrantFiled: August 2, 2021Date of Patent: May 28, 2024Assignees: SAMSUNG ELECTRONICS CO., LTD., SAMSUNG SDI CO., LTD.Inventors: Youngeal Kim, Ryounghee Kim, Seokgwang Doo, Satoshi Maruyama, Toshinori Sugimoto, Dongmin Im
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Patent number: 11990601Abstract: A battery can include a separator, a first current collector, a protective layer, and a first electrode. The first current collector and the protective layer can be disposed on one side of the separator. The first electrode can be disposed on an opposite side of the separator as the first current collector and the protective layer. Subjecting the battery to an activation process can cause metal to be extracted from the first electrode and deposited between the first current collector and the protective layer. The metal can be deposited to at least form a second electrode between the first current collector and the protective layer.Type: GrantFiled: December 29, 2022Date of Patent: May 21, 2024Assignee: American Lithium Energy CorporationInventor: Jiang Fan
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Patent number: 11984583Abstract: A positive electrode for an all-solid secondary battery includes a positive active material and a sulfide-based solid electrolyte, wherein the positive active material has a structure containing a core and a shell, the shell includes a nickel-based active material containing cobalt at an amount of about 30 mol % or higher, a surface of the positive active material includes a coating layer including at least one lithium ion conductor selected from a lanthanum oxide and a lithium lanthanum oxide, and an amount of the lithium ion conductor is in a range of about 0.1 parts to about 10 parts by weight based on 100 parts by weight of the total weight of the positive active material and the lithium ion conductor.Type: GrantFiled: March 3, 2021Date of Patent: May 14, 2024Assignee: Samsung SDI Co., Ltd.Inventor: Taeri Kwon
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Patent number: 11984584Abstract: Described herein are improved composite anodes and lithium-ion batteries made therefrom. Further described are methods of making and using the improved anodes and batteries. In general, the anodes include a porous composite having a plurality of agglomerated nanocomposites. At least one of the plurality of agglomerated nanocomposites is formed from a dendritic particle, which is a three-dimensional, randomly-ordered assembly of nanoparticles of an electrically conducting material and a plurality of discrete non-porous nanoparticles of a non-carbon Group 4A element or mixture thereof disposed on a surface of the dendritic particle. At least one nanocomposite of the plurality of agglomerated nanocomposites has at least a portion of its dendritic particle in electrical communication with at least a portion of a dendritic particle of an adjacent nanocomposite in the plurality of agglomerated nanocomposites.Type: GrantFiled: September 24, 2021Date of Patent: May 14, 2024Assignees: GEORGIA TECH RESEARCH CORPORATION, SILA NANOTECHNOLOGIES, INC.Inventors: Gleb Yushin, Oleksandr Magazynskyy, Patrick Dixon, Benjamin Hertzberg
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Patent number: 11984576Abstract: An electrochemical cell with a lithium-metal anode that suppresses dendrite formation and can be fabricated using a simple, inexpensive, and solvent-free process. The anode is coated with a layer of disordered nanomaterial, saturated with lithium ions, that suppresses dendrite formation during charging. The dendrite-suppression coating can be applied simply using a dry, abrasive technique in which the lithium-metal anode is alternately abraded to roughen the surface and polished using a polishing powder of a material that alloys with the lithium.Type: GrantFiled: October 1, 2020Date of Patent: May 14, 2024Assignee: William Marsh Rice UniversityInventors: James M. Tour, Rodrigo Villegas Salvatierra, Duy Xuan Luong
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Patent number: 11984581Abstract: A negative electrode for a lithium metal battery including: a lithium metal electrode including a lithium metal or a lithium metal alloy; and a protective layer on at least portion of the lithium metal electrode, wherein the protective layer has a Young's modulus of about 106 pascals or greater and includes at least one particle having a particle size of greater than 1 micrometer to about 100 micrometers, and wherein the at least one particle include an organic particle, an inorganic particle, an organic-inorganic particle, or a combination thereof.Type: GrantFiled: October 27, 2020Date of Patent: May 14, 2024Assignees: SAMSUNG ELECTRONICS CO., LTD, SAMSUNG SDI CO., LTD.Inventors: Yonggun Lee, Saebom Ryu, Toshinori Sugimoto, Yooseong Yang, Wonseok Chang, Joonseon Jeong
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Patent number: 11978887Abstract: A method of preparing cathode particles using a co-precipitation reaction in a reactor is disclosed. A feed stream (a) containing metal cations is fed into the reactor, and a feed stream (b) containing anions is fed into the reactor, wherein a ratio of the metal cations in the feed stream (a) is continuously changed from A1 at time t1 to A2 at time t2. The feed stream (a) and the feed stream (b) are contacted in the reactor to form precipitated precursor particles, and at least one transition metal component in the particle has a non-linear continuous concentration gradient profile over at least a portion along a thickness direction of the particle.Type: GrantFiled: August 30, 2018Date of Patent: May 7, 2024Assignee: MICROVAST ADVANCED MATERIALS INC.Inventors: Bryan T. Yonemoto, Huijie Guo, Xiao Zhang, Zhifeng Zhang, Xuelei Sun, Tianshu Deng
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Patent number: 11978885Abstract: An electrode for nonaqueous electrolyte secondary batteries, provided with a collector and a positive electrode active material layer arranged on the collector and contains a positive electrode active material. The positive electrode active material contains compound particles which have a layered structure composed of two or more transition metals, and which have an average particle diameter DSEM of from 1 ?m to 7 ?m (inclusive) based on the observation with an electron microscope, a ratio of the 50% particle diameter D50 in a volume-based cumulative particle size distribution to the average particle diameter DSEM, namely D50/DSEM of from 1 to 4 (inclusive), and a ratio of the 90% particle diameter D90 in the volume-based cumulative particle size distribution to the 10% particle diameter D10 in the volume-based cumulative particle size distribution, namely D90/D10 of 4 or less. The positive electrode active material layer has a void fraction of 10-45%.Type: GrantFiled: October 5, 2021Date of Patent: May 7, 2024Assignees: HONDA MOTOR CO., LTD., NICHIA CORPORATIONInventors: Atsushi Ogawa, Toru Sukigara, Hiroto Maeyama, Soshi Kawamura, Kenichi Kobayashi
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Patent number: 11978852Abstract: A lithium electrode and a lithium secondary battery including the same, which includes a first protective layer and a second protective layer sequentially formed on at least one surface of lithium metal layer. The second protective layer contains a cross-linked ion conductive electrolyte in the interior and on the surface of the electrically conductive matrix, and thus the first protective layer has higher ion conductivity than the second protective layer, thereby preventing electrons from being concentrated into lithium dendrites formed from the lithium metal to inhibit the growth of lithium dendrites, and at the same time, physically inhibiting the growth of lithium dendrites by the second protective layer.Type: GrantFiled: October 31, 2019Date of Patent: May 7, 2024Assignee: LG ENERGY SOLUTION, LTD.Inventors: Eunkyung Park, Minchul Jang, Bora Jung, Suk Il Youn, Byoungkuk Son
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Patent number: 11978917Abstract: Batteries including electrochemical cells, associated components, and arrangements thereof are generally described. In some aspects, batteries with housings that undergo relatively little expansion and contraction even in cases where electrochemical cells in the battery undergo a relatively high degree of expansion and contraction during charging and discharging are provided. Batteries configured to apply relatively high magnitudes and uniform force to electrochemical cells in the battery, while in some cases having high energy densities and a relatively low pack burden, are also provided. In certain aspects, arrangements of electrochemical cells and associated components are generally described. In some aspects, thermally conductive solid articles that can be used for aligning components of the battery are described. In some aspects, thermally insulating and compressible components for battery packs are generally described.Type: GrantFiled: November 19, 2020Date of Patent: May 7, 2024Assignee: Sion Power CorporationInventors: Homa Shayan, Jared M. Jennings, Mark Niedzwiecki, Daniel G. Milobar, Ryan Michael Niccum, Glenn Alan Hamblin
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Patent number: 11973213Abstract: In general, a solid-state electrode includes an electrode composite layer comprising a plurality of active material particles mixed with a solid electrolyte buffer material comprising a first plurality of solid electrolyte particles layered onto and directly contacting a current collector foil, and an electrically non-conductive separator layer comprising a second plurality of solid electrolyte particles layered onto and directly contacting the electrode composite layer. In some examples, an interpenetrating boundary layer is disposed between the electrode composite layer and the electrically non-conductive separator layer. In some examples, the electrode composite layer includes one or more conductive additives intermixed with the plurality of active material particles, and the electrode composite layer is electrically conductive. In some examples, the electrode composite layer is adhered together by a binder.Type: GrantFiled: March 24, 2022Date of Patent: April 30, 2024Assignee: EnPower, Inc.Inventor: Adrian Yao
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Patent number: 11973187Abstract: A lithium polymer battery is provided. The lithium polymer battery includes a laminate film as an exterior material including a metal foil. The lithium polymer battery further includes a first electrode including the metal foil and a first electrode active material layer provided on the metal foil; a second electrode including a second electrode current collector and a second electrode active material layer provided on the second electrode current collector, and a polymer electrolyte provided at an interface between the metal foil 11 and the first electrode active material layer.Type: GrantFiled: October 1, 2020Date of Patent: April 30, 2024Assignee: Murata Manufacturing Co., Ltd.Inventors: Koji Hattori, Shuichi Nagaoka, Kenji Oshima
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Patent number: 11973229Abstract: The present disclosure relates to an anode for a lithium-metal battery, a manufacturing method of the same, and a lithium-metal battery including the anode. The anode for a lithium-metal battery includes a complex hierarchical structure current collector which includes an inverted pyramid-shaped micro hole pattern and nanostructures provided within the inverted pyramid-shaped micro hole pattern; and a lithium metal which is electrodeposited on the nanostructure of the current collector. As a result, it is possible to increase the life stability of the battery and increase the coulombic efficiency.Type: GrantFiled: June 23, 2021Date of Patent: April 30, 2024Assignee: KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Jae Young Seok, Sanha Kim, Inyeong Yang, Ji-Hun Jeong, Seung Seob Lee
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Patent number: 11967678Abstract: Electrolyte-infiltrated composite electrode includes an electrolyte component consisting of a polymer matrix with ceramic nanoparticles embedded in the matrix to form a networking structure of electrolyte. Suitable ceramic nanoparticles have the basic formula Li7La3Zr2O12 (LLZO) and its derivatives such as AlxLi7-xLa3Zr2-y-zTayNbzO12 where x ranges from 0 to 0.85, y ranges from 0 to 0.50 and z ranges from 0 to 0.75, wherein at least one of x, y and z is not equal to 0. The networking structure of the electrolyte establishes an effective lithium-ion transport pathway in the electrode and strengthens the contact between electrode layer and solid-state electrolyte resulting in higher lithium-ion electrochemical cell's cycling stability and longer battery life. Sold-state electrolytes incorporating the ceramic particles demonstrate improved performance.Type: GrantFiled: January 16, 2023Date of Patent: April 23, 2024Assignee: Solid Energies, Inc.Inventors: Zhigang Lin, Chunhu Tan, Tianyu Meng
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Patent number: 11967674Abstract: An electrochemical device, including a positive electrode, a negative electrode, a separator and an electrolyte. The electrolyte includes a nitrile compound, and the mass percentage of the nitrile compound in the electrolyte is A %; the negative electrode includes a current collector, wherein the current collector comprises a first region and a second region; the first region is provided with a negative electrode active substance layer; the second region does not comprise a negative electrode active substance layer; the area of the second region is B % of the surface area of the current collector; and A×B<600.Type: GrantFiled: March 3, 2020Date of Patent: April 23, 2024Assignee: NINGDE AMPEREX TECHNOLOGY LIMITEDInventors: Lilan Zhang, Chao Tang, Jianming Zheng
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Patent number: 11965226Abstract: The present invention relates to a lithium metal powder, a preparing method thereof, and an electrode including the same, wherein the method for preparing the lithium metal powder includes: providing a lithium metal material and a ultrasonication solution; mixing the lithium metal material and the ultrasonication solution to form a mixed solution; and ultrasonically vibrating the mixed solution to form a lithium metal powder, wherein the lithium metal powder is covered by a protective layer, and the aforementioned protective layer includes a protective layer material, wherein the protective layer material includes a sulfide, fluoride, or nitride, or a combination thereof.Type: GrantFiled: October 17, 2022Date of Patent: April 23, 2024Assignee: NATIONAL YANG MING CHIAO TUNG UNIVERSITYInventors: Jeng-Kuei Chang, Si-Hao Chen
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Patent number: 11967696Abstract: The invention is directed to a process for forming a particle film on a substrate. Preferably, a series of corona guns, staggered to optimize film thickness uniformity, are oriented on both sides of a slowly translating grounded substrate (copper or aluminum for the anode or cathode, respectively). The substrate is preferably slightly heated to induce binder flow, and passed through a set of hot rollers that further induce melting and improve film uniformity. The sheeting is collected on a roll or can be combined in-situ and rolled into a single-cell battery. The invention is also directed to products formed by the processes of the invention and, in particular, batteries.Type: GrantFiled: December 16, 2020Date of Patent: April 23, 2024Assignee: Dragonfly Energy Corp.Inventors: Denis Phares, Justin S. Ferranto
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Patent number: 11961997Abstract: A negative electrode active material for a non-aqueous electrolyte secondary battery, containing negative electrode active material particles, including silicon compound particles each containing a silicon compound (SiOx: 0.5?x?1.6) and at least one or more of Li2SiO3 and Li2Si2O5, the material includes a phosphate, the negative electrode active material particles each have a surface containing lithium element, and a ratio mp/ml satisfies 0.02?mp/ml?3, where ml represents a molar quantity of the lithium element and contained per unit mass of the particles, and mp represents a molar quantity of phosphorus element contained per unit mass of the particles. Thereby, a negative electrode active material is capable of stabilizing an aqueous negative electrode slurry prepared in producing a negative electrode of a secondary battery, and capable of improving initial charge-discharge characteristics when the negative electrode active material is used for a secondary battery.Type: GrantFiled: September 25, 2019Date of Patent: April 16, 2024Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Takumi Matsuno, Hidekazu Awano, Takakazu Hirose, Kohta Takahashi, Yusuke Osawa
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Patent number: 11958757Abstract: The present disclosure relates to the technical field of lithium ion battery, and discloses a Lithium-Manganese-rich material and a preparation method and a use thereof.Type: GrantFiled: March 3, 2021Date of Patent: April 16, 2024Assignee: BEIJING EASPRING MATERIAL TECHNOLOGY CO., LTD.Inventors: Jun Wang, Yafei Liu, Yanbin Chen
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Patent number: 11955624Abstract: The present disclosure relates to blended cathode materials for use as a positive electrode material of a rechargeable electrochemical cell (or secondary cell) (such as a lithium-ion secondary battery) and also relates to a secondary battery including a cathode having the blended cathode materials. In particular, disclosed are blends of lithium vanadium fluorophosphate (LVPF) or a derivative thereof with one or more conventional cathode active materials in certain weight ratios thereof.Type: GrantFiled: October 29, 2020Date of Patent: April 9, 2024Assignee: SAFT AMERICAInventors: Xilin Chen, Frank Cao
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Composite interlayer for lithium metal based solid state batteries and the method of making the same
Patent number: 11955639Abstract: A solid-state electrochemical cell that cycles lithium ions includes a solid-state electrolyte that defines a first major surface and an electrode that defines a second major surface. The solid-state electrochemical cell also includes an interfacial layer disposed between the first major surface of the solid-state electrolyte and the second major surface of the electrode. The interfacial layer may include an ion-conductor disposed in an organic matrix.Type: GrantFiled: May 4, 2021Date of Patent: April 9, 2024Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Mengyuan Chen, Xingcheng Xiao -
Patent number: 11955633Abstract: This disclosure relates to the electrochemical field, and in particular, to a positive electrode material and a preparation method and usage thereof. The positive electrode material of this disclosure includes a substrate, where a general formula of the substrate is LixNiyCozMkMepOrAm, where 0.95?x?1.05, 0.5?y?1, 0?z?1, 0?k?1, 0?p?0.1, 1?r?5.2, 0?m?2, m+r?2, M is selected from one or more of Mn and Al, Me is selected from one or more of Zr, Zn, Cu, Cr, Mg, Fe, V, Ti, Sr, Sb, Y, W, and Nb, and A is selected from one or more of N, F, S, and Cl; and an oxygen defect level of the positive electrode material satisfies at least one of condition (1) or condition (2): (1) 1.77?OD1?1.90; or (2) 0.69?OD2?0.74.Type: GrantFiled: November 3, 2021Date of Patent: April 9, 2024Assignee: CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITEDInventors: Chongheng Shen, Rui Du, Yongchao Liu, Deyu Zhao, Na Liu
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Patent number: 11949108Abstract: A negative electrode including a negative electrode active material layer and an additive. The additive includes a metal sulfide. The additive is distributed in the negative electrode active material layer, and/or distributed on the surface of the negative electrode active material layer. The negative electrode effectively improves the performance of the lithium ion battery, and greatly improves the capacity and cycle performance of the lithium ion battery.Type: GrantFiled: July 27, 2020Date of Patent: April 2, 2024Assignee: NINGDE AMPEREX TECHNOLOGY LIMITEDInventors: Jing Jiang, Qiao Zeng, Kefei Wang
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Patent number: 11949062Abstract: A pressing jig for removing gas generated in an activation process of a battery cell includes a plate-shaped lower plate on which the battery cell that has undergone the activation process is placed and fixed, and an upper plate that presses the battery cell placed on the lower plate from above. At least one of the upper plate or the lower plate has a structure in which n (n?3) separated sub-plates are assembled to form a single plate, and the sub-plates independently press the battery cell. The pressing jig can suppress trapping of internal gas by sequentially pressing the battery cell.Type: GrantFiled: January 8, 2021Date of Patent: April 2, 2024Assignee: LG ENERGY SOLUTION, LTD.Inventors: Suk Hyun Hong, Joon Sung Bae, Eui Kyung Lee, Sang Jih Kim, Beom Koon Lee, Dong Hun Bae
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Patent number: 11949089Abstract: An energy storage device can include a cathode, an anode, and a separator between the cathode and the anode. At least one of the electrodes can include an electrode film prepared by a dry process. The electrode film and/or the electrode can comprise a prelithiating material. Processes and apparatuses used for fabricating the electrode and/or electrode film are also described.Type: GrantFiled: January 14, 2020Date of Patent: April 2, 2024Assignee: Tesla, Inc.Inventors: Ziying Wang, Hieu Minh Duong
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Patent number: RE49980Abstract: A composite coated form of lithium cobalt oxide is described that can achieve improved cycling at higher voltages. Liquid phase and combined liquid and solid phase coating processes are described to effectively form the composite coated powders. The improved cycling positive electrode materials can be effectively combined with either graphitic carbon negative electrode active materials or silicon based high capacity negative electrode active materials. Improved battery designs can achieve very high volumetric energy densities in practical battery formats and with reasonable cycling properties.Type: GrantFiled: January 22, 2021Date of Patent: May 21, 2024Assignee: Ionblox, Inc.Inventors: Sanjeev Sharma, Deepak Kumaar K. Karthikeyan, Charles A. Bowling, Bing Li, Pedro A. Hernández Gallegos, Subramanian Venkatachalam, Herman A. Lopez, Sujeet Kumar