Nitrogen Is Ring Member Of The Hetero Ring Patents (Class 429/328)
  • Patent number: 8420266
    Abstract: A nonaqueous secondary battery comprising: a positive electrode; a negative electrode; and a nonaqueous electrolyte solution, wherein the nonaqueous electrolyte solution contains at least a cyclic nitrogen-containing compound represented by the general formula (1): wherein X represents an optionally branched divalent group derived from a chain saturated hydrocarbon and having 1 to 5 carbon atoms, ?C?CH2, ?C?O, ?C?S?O, ?O or ?S; and A1 and A2 may be the same or different and each represent an optionally substituted methylene group, ?C?O or ?SO2.
    Type: Grant
    Filed: May 15, 2009
    Date of Patent: April 16, 2013
    Assignee: Sharp Kabushiki Kaisha
    Inventor: Hisayuki Utsumi
  • Publication number: 20130089792
    Abstract: An electrochemical cell is described. The electrochemical cell includes an anode, a cathode, a separator between said anode and said cathode, and an electrolyte. The electrolyte includes a salt dissolved in an organic solvent. The separator in combination with the electrolyte has an area specific resistance less than 2 ohm-cm2. The electrochemical cell has an interfacial anode to cathode ratio of less than about 1.1.
    Type: Application
    Filed: November 30, 2012
    Publication date: April 11, 2013
    Applicant: THE GILLETTE COMPANY
    Inventor: THE GILLETTE COMPANY
  • Publication number: 20130071758
    Abstract: The nonaqueous electrolyte for an electrochemical device of the present invention includes at least one selected from an imide compound represented by the general formula (1) and an imide compound represented by the general formula (2): where R1 is an organic residue or an F-containing organic residue, X1 and X2 are each H, F, an organic residue or an F-containing organic residue, and X1 and X2 may be the same or different from each other; and where R2 is an organic residue or an F-containing organic residue, and H of a benzene ring may be partially or entirely replaced with F.
    Type: Application
    Filed: September 13, 2012
    Publication date: March 21, 2013
    Applicant: HITACHI MAXELL ENERGY, LTD.
    Inventors: Masayuki OYA, Mitsuhiro KISHIMI, Fusaji KITA
  • Patent number: 8399127
    Abstract: A nonaqueous electrolyte secondary battery, comprising a positive electrode having a positive-electrode active material layer reversibly inserting and extracting lithium ions on a positive-electrode current collector, a negative electrode having a negative-electrode active material layer reversibly inserting and extracting lithium ions on a negative-electrode current collector, and a nonaqueous electrolyte solution, wherein at least one of the positive and negative electrodes has a film on the surface and at least one of the positive electrode, the negative electrode and the nonaqueous electrolyte solution contains a nitrogen-containing cyclic compound. Such a nonaqueous electrolyte secondary battery is superior in high-temperature storage stability allowing preservation of favorable discharge rate even after high-temperature storage.
    Type: Grant
    Filed: February 20, 2008
    Date of Patent: March 19, 2013
    Assignee: Panasonic Corporation
    Inventors: Masaki Deguchi, Tooru Matsui, Hiroshi Yoshizawa
  • Patent number: 8394540
    Abstract: A secondary battery capable of improving the cycle characteristics is provided. The secondary battery includes a cathode and an anode oppositely arranged with a separator in between, and an electrolytic solution. At least one of the cathode, the anode, the separator, and the electrolytic solution contains a sulfone compound having a carbonate group and a sulfonyl group.
    Type: Grant
    Filed: December 16, 2008
    Date of Patent: March 12, 2013
    Assignee: Sony Corporation
    Inventors: Hiroyuki Yamaguchi, Masayuki Ihara, Tadahiko Kubota
  • Patent number: 8389162
    Abstract: An electrolyte for a rechargeable lithium battery that includes a non-aqueous organic solvent, a lithium salt, and an electrolyte additive. The electrolyte additive includes 2 to 6 wt % of succinonitrile, 2 to 6 wt % of alkane sultone, and 1 to 3 wt % of vinylethylene carbonate based on the total weight of the electrolyte.
    Type: Grant
    Filed: September 15, 2009
    Date of Patent: March 5, 2013
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Duck-Chul Hwang, Sang-Min Lee, Kyoung-Han Yew, Sang-Jin Kim
  • Patent number: 8304117
    Abstract: A gel polymer electrolyte precursor and a rechargeable cell comprising the same are provided. The gel polymer electrolyte precursor comprises a bismaleimide monomer or bismaleimide oligomer, a compound having formula (I): a non-aqueous metal salt electrolyte, a non-protonic solvent, and a free radical initiator, wherein the bismaleimide oligomer is prepared by reaction of barbituric acid and bismaleimide, X comprises oxygen, organic hydrocarbon compounds, organic hydrocarbon oxide compounds, oligomers or polymers, n is 2 or 3, and A independently comprises wherein m is 0˜6, X comprises hydrogen, cyano, nitro or halogen, and R1 independently comprises hydrogen or C1˜4 alkyl.
    Type: Grant
    Filed: December 28, 2007
    Date of Patent: November 6, 2012
    Assignee: Industrial Technology Research Institute
    Inventors: Yueh-Wei Lin, Tsung-Hsiung Wang, Jing-Pin Pan, Chang-Rung Yang, Jung-Mu Hsu
  • Publication number: 20120276456
    Abstract: Electrolyte, comprising an aprotic solvent, a lithium salt as conducting salt, and an additive, characterized in that the additive is a compound which contains a protonable nitrogen atom and is hydrolysable by water.
    Type: Application
    Filed: August 27, 2010
    Publication date: November 1, 2012
    Applicant: LI-TEC BATTERY GMBH
    Inventors: Peter Pilgram, Rolf-Walter Terwonne, Denny Thiemig, Joerg Kaiser, Andreas Gutsch
  • Patent number: 8273484
    Abstract: Nitrogen silylated compounds are useful as additives in a nonaqueous electrolytic solution. The electrolytic solution including such additives is suitable for use in electrochemical cells such as lithium and lithium ion batteries. Batteries using this electrolytic solution have long cycle life and high capacity retention.
    Type: Grant
    Filed: May 26, 2005
    Date of Patent: September 25, 2012
    Assignee: Novolyte Technologies, Inc.
    Inventors: Wu Xu, Zhongyi Deng, Pascal Bolomey
  • Patent number: 8257870
    Abstract: A non-aqueous electrolyte for a battery comprises a non-aqueous solvent containing a specified cyclic phosphazene compound and a specified difluorophosphate compound, a specified aniline derivative and a support salt.
    Type: Grant
    Filed: July 13, 2007
    Date of Patent: September 4, 2012
    Assignee: Bridgestone Corporation
    Inventor: Yasuo Horikawa
  • Patent number: 8247117
    Abstract: The present invention relates to ionic liquids having low melting points, low viscosities and high electrical conductivities; and more specifically, to ionic liquids including at least one organic onium ion and at least one anion represented by the formula: [Z—BF3]?, wherein Z is an alkyl group, an alkenyl group, or a fluoroalkenyl group. The ionic liquids according to the invention are capable of easily dissolving electrolytes such as lithium salts, and are also nonflammable and have low viscosities; therefore, the ionic liquids are suitable for use as electrolyte solvents for lithium batteries such as lithium secondary batteries, electric double-layer capacitors, and the like. The ionic liquids according to the invention are suitable for use in electrochemical devices such as lithium secondary batteries, fuel cells, solar batteries, electrical double-layer capacitors and the like; as solvents for chemical reactions; and as lubricants.
    Type: Grant
    Filed: November 22, 2005
    Date of Patent: August 21, 2012
    Assignee: National Institute of Advanced Industrial Science and Technology
    Inventors: Hajime Matsumoto, Zhi-Bin Zhou
  • Patent number: 8232471
    Abstract: A squarylium dye represented by formula (1): wherein A1 and B1 each independently represents a ring structure, and R1 and R2 each independently represents a substituent having a carbon number of 1 to 12.
    Type: Grant
    Filed: June 2, 2008
    Date of Patent: July 31, 2012
    Assignee: FUJIFILM Corporation
    Inventors: Kimiatsu Nomura, Tetsu Kitamura, Tetsuro Mitsui
  • Publication number: 20120171579
    Abstract: A non-aqueous electrolyte including a lithium salt, an organic solvent, and an electrolyte additive is provided. The electrolyte additive is a meta-stable state nitrogen-containing polymer formed by reacting Compound (A) and Compound (B). Compound (A) is a monomer having a reactive terminal functional group. Compound (B) is a heterocyclic amino aromatic derivative as an initiator. A molar ratio of Compound (A) to Compound (B) is from 10:1 to 1:10. A lithium secondary battery containing the non-aqueous electrolyte is further provided. The non-aqueous electrolyte of this disclosure has a higher decomposition voltage than a conventional non-aqueous electrolyte, such that the safety of the battery during overcharge or at high temperature caused by short-circuit current is improved.
    Type: Application
    Filed: December 29, 2011
    Publication date: July 5, 2012
    Applicant: Industrial Technology Research Institute
    Inventors: Li-Duan Tsai, Yueh-Wei Lin, Chia-Chen Fang, Cheng-Liang Cheng, Jing-Pin Pan, Tsung-Hsiung Wang
  • Publication number: 20120171577
    Abstract: An electrolytic solution including: a magnesium salt; a non-aqueous organic solvent; and an anion receptor, wherein the anion receptor comprises at least one compound selected from the group consisting of compounds represented by Formulae 1 and 2 below: where A, m, p1, P2, P3, q1, RA, Ra, R1 through R6, and Ry are the same as described in the detailed description section.
    Type: Application
    Filed: June 10, 2011
    Publication date: July 5, 2012
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Young-gyoon Ryu, Sang-ho Park, Myung-dong Cho, Young-min Choi, Seok-soo Lee
  • Publication number: 20120171576
    Abstract: A non-aqueous electrolyte including a lithium salt, an organic solvent, and an electrolyte additive is provided. The electrolyte additive is a meta-stable state nitrogen-containing polymer formed by reacting Compound (A) and Compound (B). Compound (A) is a monomer having a reactive terminal functional group. Compound (B) is a heterocyclic amino aromatic derivative as an initiator. A molar ratio of Compound (A) to Compound (B) is from 10:1 to 1:10. A lithium secondary battery containing the non-aqueous electrolyte is further provided. The non-aqueous electrolyte of this disclosure has a higher decomposition voltage than a conventional non-aqueous electrolyte, such that the safety of the battery during overcharge or at high temperature caused by short-circuit current is improved.
    Type: Application
    Filed: May 19, 2011
    Publication date: July 5, 2012
    Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Li-Duan Tsai, Yueh-Wei Lin, Jason Fang, Cheng-Liang Cheng, Jing-Pin Pan, Tsung-Hsiung Wang
  • Patent number: 8211277
    Abstract: The present invention relates to compounds containing organofluorochlorophosphate anions, the preparation thereof and the use thereof, in particular as ionic liquids.
    Type: Grant
    Filed: December 7, 2007
    Date of Patent: July 3, 2012
    Assignee: Merck Patent GmbH
    Inventors: Nikolai Ignatyev, German Bissky, Helge Willner
  • Patent number: 8173305
    Abstract: The invention relates to an electrolyte separator system comprising an ionic liquid, a conductive salt and a ceramic separator, and the use of the electrolyte separator system according to the invention in electrochemical energy storage systems, in particular of lithium metal and lithium ion batteries.
    Type: Grant
    Filed: April 27, 2006
    Date of Patent: May 8, 2012
    Assignee: Evonik Degussa GmbH
    Inventors: Michael Holzapfel, Petr Novák, Carsten Jost, Anna Prodi-Schwab, Volker Hennige, Christian Hying
  • Publication number: 20120107697
    Abstract: An electrolyte for a lithium ion battery includes a non-aqueous organic solvent and a lithium salt. The non-aqueous organic solvent includes a flame-retardant solvent and a carbonate-based solvent. The flame-retardant solvent includes an ionic liquid including a fluorinated cation and a phosphorus-based solvent.
    Type: Application
    Filed: September 6, 2011
    Publication date: May 3, 2012
    Inventors: Sae-Weon Roh, Man-Seok Han, Sung-Soo Kim
  • Publication number: 20120088160
    Abstract: The present technology relates to stabilizing additives and electrolytes containing the same for use in electrochemical devices such as lithium ion batteries and capacitors. The stabilizing additives include triazinane triones and bicyclic compounds comprising succinic anhydride, such as compounds of Formulas I and II described herein.
    Type: Application
    Filed: October 7, 2010
    Publication date: April 12, 2012
    Inventors: Lu Zhang, Zhengcheng Zhang, Khalil Amine
  • Publication number: 20120082903
    Abstract: An ionic liquid that is a salt has a Formula: Such ionic liquids may be used in electrolytes and in electrochemical cells.
    Type: Application
    Filed: September 30, 2010
    Publication date: April 5, 2012
    Inventors: Zhengcheng Zhang, Wei Weng, Lu Zhang, Khalil Amine
  • Publication number: 20120082901
    Abstract: Li-based anodes for use in an electric current producing cells having long life time and high capacity are provided. In certain embodiments, the Li-based anode comprises at least one anode active Li-containing compound and a composition comprising at least one polymer, at least one ionic liquid, and optionally at least one lithium salt. The composition may be located between the at least one Li-containing compound and the catholyte used in the electric current producing cell. In some embodiments, the at least one polymer may be incompatible with the catholyte. This configuration of components may lead to separation between the lithium active material of the anode and the catholyte. Processes for preparing the Li-based anode and to electric current producing cells comprising such an anode are also provided.
    Type: Application
    Filed: September 30, 2011
    Publication date: April 5, 2012
    Applicants: BASF SE, Sion Power Corporation
    Inventors: Rudiger Schmidt, Daher Michael Badine, Helmut Moehwald, Igor Kovalev, Yuriy V. Mikhaylik
  • Publication number: 20120082872
    Abstract: Spiro ammonium salts as an additive for electrolytes in electric current producing cells, in particular electric current producing cells comprising a Li-based anode, are provided. In some embodiments, the electric current producing cell comprises a cathode, a Li-based anode, and at least one electrolyte wherein the electrolyte contains at least one spiro ammonium salt.
    Type: Application
    Filed: September 30, 2011
    Publication date: April 5, 2012
    Applicants: BASF SE, Sion Power Corporation
    Inventors: Rudiger Schmidt, Daher Michael Badine, Xiao Steimle, Helmut Moehwald, Igor Kovalev, Yuriy V. Mikhaylik
  • Patent number: 8124282
    Abstract: A nonaqueous electrolyte having maleimide additives and rechargeable cells employing the same are provided. The nonaqueous electrolyte having maleimide additives comprises an alkali metal electrolyte, a nonaqueous solvent, and maleimide additives. Specifically, the maleimide additives comprise maleimide monomer, bismaleimide monomer, bismaleimide oligomer, or mixtures thereof. The maleimide additives comprise functional groups, such as a maleimide double bond, phenyl group carboxyl, or imide, enhancing the charge-discharge efficiency, safety, thermal stability, chemical stability, flame-resistance, and lifespan of the secondary cells of the invention.
    Type: Grant
    Filed: December 27, 2007
    Date of Patent: February 28, 2012
    Assignee: Industrial Technology Research Institute
    Inventors: Jing-Pin Pan, Chang-Rung Yang, Tsung-Hsiung Wang, Yueh-Wei Lin, Pin-Chi Chiang, Jung-Mu Hsu
  • Patent number: 8124284
    Abstract: Disclosed are an additive for improving charge/discharge characteristics of a lithium-ion cell, a nonaqueous electrolytic solution containing the additive, and a lithium-ion cell using the additive and/or the nonaqueous electrolytic solution. The additive serves as a solvent for a fluorine resin, such as poly(vinylidene fluoride), which is incorporated as an adhesive in a positive electrode containing a lithium-transition metal oxide capable of absorbing and releasing lithium and a negative electrode containing a carbon material capable of absorbing and releasing lithium. The additive comprises three compounds selected, respectively, from a 2-pyrrolidinone compound group, a cyclic alkyl compound group, and a cyclic pentanone compound group.
    Type: Grant
    Filed: March 10, 2006
    Date of Patent: February 28, 2012
    Assignee: Japan Aerospace Exploration Agency
    Inventors: Xianming Wang, Yoshitsugu Sone, Saburo Kuwajima, Kenichi Kuwajima
  • Publication number: 20120045697
    Abstract: Disclosed are an electrolyte for a rechargeable lithium battery that includes a lithium salt, a non-aqueous organic solvent, and an additive including a triazine-based compound represented by the following Chemical Formula 1 and fluoroethyl carbonate, and a rechargeable lithium battery including the electrolyte. where R1, R2, and R3 are the same as described in the detailed description.
    Type: Application
    Filed: August 15, 2011
    Publication date: February 23, 2012
    Applicants: TECHNO SEMICHEM CO., LTD., SAMSUNG SDI CO., LTD.
    Inventors: Na-Rae PARK, Jin-Hyunk LIM, Su-Hee HAN, Mi-Hyeun OH, Eun-Gi SHIM
  • Patent number: 8119293
    Abstract: A non-aqueous electrolyte secondary cell can be charged at a high voltage of 4.3V or more and has excellent cycle characteristics and excellent high-temperature storage characteristics. The cell includes positive and negative electrodes capable of inserting and extracting lithium, and a non-aqueous electrolyte. The non-aqueous electrolyte contains a non-aqueous solvent, 1,3-dioxane and a dinitrile compound additives, and an electrolyte salt. The non-aqueous solvent contains ethylene carbonate in the range of 25% to 40% by volume under the conditions of 25° C. and 1 atm.
    Type: Grant
    Filed: February 23, 2010
    Date of Patent: February 21, 2012
    Assignee: SANYO Electric Co., Ltd.
    Inventors: Masato Iwanaga, Noriko Yamashita
  • Publication number: 20120021300
    Abstract: A nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, containing a hydantoin compound represented by the following general formula (I) in an amount of from 0.01 to 5% by mass of the nonaqueous electrolytic solution, and excellent in battery characteristics such as high-temperature storage property and cycle property. (In the formula, R1 and R2 each represent a methyl group or an ethyl group; R3 and R4 each represent a hydrogen atom, a methyl group or an ethyl group.
    Type: Application
    Filed: August 4, 2009
    Publication date: January 26, 2012
    Applicant: UBE INDUSTRIES, LTD.
    Inventors: Koji Abe, Masahide Kondo
  • Patent number: 8026339
    Abstract: A polysulfone is provided with a nitrogen-containing functional group having an affinity to an acid, an electrolyte membrane using the polysulfone, and a fuel cell including the electrolyte membrane. In particular, the polysulfone includes a nitrogen-containing functional group that has an affinity to an acid, such as a phosphoric acid, thereby having an excellent acid retaining ability. In an electrolyte membrane including the polysulfone and an acid, the amount of the retained acid can be controlled. Therefore, the electrolyte membrane has a high ionic conductivity and a high mechanical strength. A polysulfone blend of polysulfone and a thermoplastic resin prevents the dissolution of polysulfone by phosphoric acid, so that an electrolyte membrane using the polysulfone blend has an improved durability. A cross-linked reaction product of polysulfone, a cross-linking agent and a polymerization product of polysulfone, a thermoplastic resin, and a cross-linking agent strongly resist a phosphoric acid.
    Type: Grant
    Filed: June 1, 2007
    Date of Patent: September 27, 2011
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Chung-kun Cho, Myung-jin Lee, Myeong-soon Kang
  • Publication number: 20110189547
    Abstract: Disclosed are an additive for improving charge/discharge characteristics of a lithium-ion cell, a nonaqueous electrolytic solution containing the additive, and a lithium-ion cell using the additive and/or the nonaqueous electrolytic solution. The additive serves as a solvent for a fluorine resin, such as poly(vinylidene fluoride), which is incorporated as an adhesive in a positive electrode containing a lithium-transition metal oxide capable of absorbing and releasing lithium and a negative electrode containing a carbon material capable of absorbing and releasing lithium. The additive comprises three compounds selected, respectively, from a 2-pyrrolidinone compound group, a cyclic alkyl compound group, and a cyclic pentanone compound group.
    Type: Application
    Filed: April 13, 2011
    Publication date: August 4, 2011
    Inventors: Xianming Wang, Yoshitsugu Sone, Saburo Kuwajima, Kenichi Kuwajima
  • Patent number: 7981551
    Abstract: The present invention relates to an electrolyte for a lithium ion rechargeable battery and a lithium ion rechargeable battery including the same. The electrolyte includes a non-aqueous organic solvent, a lithium salt, and triphenyl phosphate. A lithium ion rechargeable battery including the electrolyte has improved overcharge stability and shows excellent chemical properties including reducing swelling, high-temperature storage stability, and cycle life characteristics.
    Type: Grant
    Filed: May 31, 2005
    Date of Patent: July 19, 2011
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Cheon Soo Kim, Hyung Bok Lee, Kwang Sup Kim, Sang Ho Lee, Joong Heon Kim, Tae Shik Earmme, Kwang Soo Yeo, Chan Hee Lee
  • Publication number: 20110117444
    Abstract: Disclosed is an electrolytic solution including an organic solvent, a lithium salt, and an additive. The additive includes maleimide compound and vinylene carbonate. The maleimide compound can be maleimide, bismaleimide, polymaleimide, polybismaleimide, maleimide-bismaleimide copolymer, or combinations thereof. The lithium battery employing the described electrolytic solution has a higher capacity of confirmation, higher cycle efficiency, and longer operational lifespan.
    Type: Application
    Filed: January 28, 2011
    Publication date: May 19, 2011
    Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Fu-Ming Wang, Chang-Rung Yang, Jing-Pin Pan, Hung-Chun Wu
  • Publication number: 20110117443
    Abstract: An electrolyte for a lithium battery and a lithium battery including the electrolyte.
    Type: Application
    Filed: September 3, 2010
    Publication date: May 19, 2011
    Inventors: Yong-Beom Lee, Sun-Young Kim, Bo-Ra Lee, Sin-Young Park
  • Publication number: 20110111286
    Abstract: A nonaqueous electrolytic solution containing magnesium ions which shows excellent electrochemical characteristics and which can be manufactured in a general manufacturing environment such as a dry room, and an electrochemical device using the same are provided. A Mg battery has a positive-electrode can 1, a positive-electrode pellet 2 made of a positive-electrode active material or the like, a positive electrode 11 composed of a metallic net supporting body 3, a negative-electrode cup 4, a negative electrode 12 made of a negative-electrode active material 5, and a separator 6 impregnated with an electrolytic solution 7 and disposed between the positive-electrode pellet and the negative-electrode active material.
    Type: Application
    Filed: June 4, 2009
    Publication date: May 12, 2011
    Applicant: SONY CORPORATION
    Inventors: Kenta Yamamoto, Yuri Nakayama, Yui Senda
  • Publication number: 20110076572
    Abstract: A non-aqueous electrolyte includes an ionic electrolyte salt, and a non-aqueous electrolyte solvent that includes a mixture of siloxane or a silane or a mixture thereof, a sulfone, and a fluorinated ether or fluorinated ester or a mixture thereof, an ionic liquid, or a carbonate.
    Type: Application
    Filed: September 23, 2010
    Publication date: March 31, 2011
    Inventors: Khalil Amine, Zonghai Chen, Zhengcheng Zhang
  • Publication number: 20110070504
    Abstract: This invention relates to a highly safe secondary battery. In the secondary battery of this invention, a positive electrode is formed of an oxide which adsorbs/desorbs lithium ions; a negative electrode is formed of a carbon material which adsorbs/desorbs lithium ions; and an electrolyte solution is formed of an ion liquid and a phosphoric acid ester derivative. Consequently, the secondary battery can be highly safe. Since a phosphate ester and an ion liquid are contained at the same time, high discharge capacity can be maintained even when the phosphate ester is used at a high concentration.
    Type: Application
    Filed: May 14, 2009
    Publication date: March 24, 2011
    Applicants: NEC CORPORATION, NEC ENERGY DEVICES, LTD.
    Inventors: Kazuaki Matsumoto, Kentaro Nakahara, Shigeyuki Iwasa, Hitoshi Ishikawa, Shinako Kaneko, Koji Utsugi
  • Patent number: 7875393
    Abstract: An organic electrolytic solution and a lithium battery employing the same are provided. The organic electrolytic solution includes a lithium salt, an organic solvent containing a first solvent having a high dielectric constant and a second solvent having a low boiling point, and a surfactant including a hydrophobic portion having an aromatic group. The organic electrolytic solution effectively prevents the electrolytic solution from contacting the anode, thereby suppressing side reactions on the anode surface and improving discharge capacity, charge/discharge efficiency, lifespan, and battery reliability.
    Type: Grant
    Filed: February 17, 2006
    Date of Patent: January 25, 2011
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Young-gyoon Ryu, Jae-young Choi, Eun-sung Lee, Seok-soo Lee, Do-yun Kim, Sang-hoon Song
  • Patent number: 7867294
    Abstract: A process is provided to produce non-aqueous electrolytic solution for use in batteries having low acid content and low water content. The invention involves removing acids and water from non-aqueous electrolytic solutions typically found in lithium or lithium-ion batteries by using nitrogen-containing compounds such as triazines. After treatment by a triazine such as melamine, the concentrations of acids and water in the electrolytic solutions are substantially decreased. The present invention provides a process to prepare extremely pure electrolytic solutions having low (<20 ppm) concentrations of both water and acids.
    Type: Grant
    Filed: April 14, 2010
    Date of Patent: January 11, 2011
    Assignee: Novolyte Technologies Inc.
    Inventors: Zhongyi Deng, Jerry L. Decker, Wu Xu, John R. Sans, Pascal Bolomey
  • Patent number: 7807301
    Abstract: Disclosed is a lithium battery including a silicon negative electrode, a lithium mixed metal oxide positive electrode, a separator disposed between the negative and positive electrodes to define a reservoir region, an electrolytic solution filled in the reservoir region, and a sealant structure wrapped around the silicon negative electrode, the lithium mixed metal oxide positive electrode, the separator, and the electrolytic solution. The electrolytic solution includes an organic solvent, a lithium salt, and an additive. The additive includes a maleimide compound and vinylene carbonate. The silicon negative electrode of the lithium battery employing the described electrolytic solution has higher cycle efficiency and longer operating lifespan.
    Type: Grant
    Filed: December 24, 2008
    Date of Patent: October 5, 2010
    Assignee: Industrial Technology Research Institute
    Inventors: Hung-Chun Wu, Fu-Ming Wang, Ching-Yi Su, Chang-Rung Yang, Jing-Pin Pan, Yu-Chan Yen, Nae-Lih Wu
  • Patent number: 7736812
    Abstract: Disclosed is an electrolyte for a rechargeable lithium battery including an additive for overcharge inhibition comprising a compound represented by formula 1; a lithium salt; and a non-aqueous organic solvent: where R1, R2 and R3 are the same or independently selected from H, CH3, C2H5, CH?CH2, CH?CHCH3, or a functional group with N, P, or S.
    Type: Grant
    Filed: July 1, 2004
    Date of Patent: June 15, 2010
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Won-Chull Han, Takaki Mori, Cheon-Soo Kim, You-Mee Kim
  • Patent number: 7727669
    Abstract: A process is provided to produce non-aqueous electrolytic solution for use in batteries having low acid content and low water content. The invention involves removing acids and water from non-aqueous electrolytic solutions typically found in lithium or lithium-ion batteries by using nitrogen-containing compounds such as triazines. After treatment by a triazine such as melamine, the concentrations of acids and water in the electrolytic solutions are substantially decreased. The present invention provides a process to prepare extremely pure electrolytic solutions having low (<20 ppm) concentrations of both water and acids.
    Type: Grant
    Filed: May 26, 2005
    Date of Patent: June 1, 2010
    Assignee: Novolyte Technologies Inc.
    Inventors: Zhongyi Deng, Jerry L. Decker, Wu Xu, John R. Sans, Pascal Bolomey
  • Patent number: 7722988
    Abstract: A lithium electrochemical cell design incorporating a low molality electrolyte including LiI is disclosed. The resulting cell delivers excellent performance under a wide range of temperatures, conditions and drain rates.
    Type: Grant
    Filed: July 14, 2008
    Date of Patent: May 25, 2010
    Assignee: Eveready Battery Company, Inc.
    Inventor: Andrew Webber
  • Patent number: 7709154
    Abstract: Disclosed is an electrolyte of a lithium secondary battery comprising a lithium salt, an organic solvent, and at least one additive compound selected from the group consisting of compounds represented by the following formula (1) and derivatives thereof: where R1 is selected from the group consisting of hydrogen radicals, alkyls, aryls, cycloalkyls, alkenyls, alkynyls, ester radicals, and aliphatic carbonate radicals. The electrolyte improves both swelling inhibition properties at high temperature and capacity characteristics of a lithium secondary battery.
    Type: Grant
    Filed: February 13, 2009
    Date of Patent: May 4, 2010
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Hyung-Gon Noh
  • Patent number: 7709142
    Abstract: A battery capable of obtaining a high energy density and obtaining superior cycle characteristics is provided. The thickness of a cathode active material layer is from 100 ?m to 130 ?m. The thickness of an anode active material layer is from 85 ?m to 120 ?m, and the volume density of the anode active material layer is from 1.7 g/cm3 to 1.85 g/cm3. An electrolytic solution contains 4-fluoro-1,3-dioxolane-2-one. Thereby, even when the thicknesses of the cathode active material layer and the anode active material layer are increased, the diffusion and acceptance of lithium in an anode are improved, and superior cycle characteristics can be obtained.
    Type: Grant
    Filed: December 7, 2006
    Date of Patent: May 4, 2010
    Assignee: Sony Corporation
    Inventors: Shinya Wakita, Izaya Okae, Yosuke Ushio, Yoshiaki Takeuchi, Saori Tokuoka
  • Patent number: 7615312
    Abstract: A rechargeable lithium-ion cell contains a positive electrode, negative electrode, charge-carrying electrolyte containing charge carrying medium and lithium salt, and an N-substituted or C-substituted phenothiazine compound dissolved in or dissolvable in the electrolyte. The substituted phenothiazine compound has an oxidation potential above the positive electrode recharged potential and serves as a cyclable redox chemical shuttle providing cell overcharge protection.
    Type: Grant
    Filed: May 17, 2005
    Date of Patent: November 10, 2009
    Assignee: 3M Innovative Properties Company
    Inventors: Jeffrey R. Dahn, Claudia Buhrmester, Richard L. Wang, William M. Lamanna
  • Patent number: 7615317
    Abstract: A rechargeable lithium-ion cell contains a positive electrode, negative electrode, charge-carrying electrolyte containing charge carrying medium and lithium salt, and cycloaliphatic N-oxide compound dissolved in or dissolvable in the electrolyte. The N-oxide compound has an oxidation potential above the positive electrode recharged potential and serves as a cyclable redox chemical shuttle providing cell overcharge protection.
    Type: Grant
    Filed: May 17, 2005
    Date of Patent: November 10, 2009
    Assignee: 3M Innovative Properties Company
    Inventors: Jeffrey R. Dahn, Claudia Buhrmester
  • Publication number: 20090226819
    Abstract: A secondary battery is provided and includes a cathode, an anode and an electrolytic solution, in which the anode includes an anode active material layer including a plurality of anode active material particles, the plurality of anode active material particles including silicon as a constituent element. The anode active material layer includes at least one of an oxide-containing film and a metal material as a constituent element. The oxide-containing film with which surfaces of the anode active material particles are covered. The metal material includes a metal element which is not alloyed with an electrode reactant, and being arranged in a gap in the anode active material layer. The electrolytic solution includes a solvent including at least one kind selected from the group consisting of specific isocyanate compounds.
    Type: Application
    Filed: March 10, 2009
    Publication date: September 10, 2009
    Applicant: SONY CORPORATION
    Inventors: Masayuki Ihara, Hiroyuki Yamaguchi, Tadahiko Kubota
  • Patent number: 7585590
    Abstract: Provided is a rechargeable lithium-ion cell that contains a positive electrode, a negative electrode, a charge-carrying electrolyte containing a charge carrying medium and a lithium salt, and a triphenylamine compound dissolved in or dissolvable in the electrolyte. The triphenylamine compound has an oxidation potential above the positive electrode recharged potential and serves as a cyclable redox chemical shuttle providing cell overcharge protection. Also provided are methods for manufacturing a rechargeable lithium-ion cell.
    Type: Grant
    Filed: February 5, 2007
    Date of Patent: September 8, 2009
    Assignee: 3M Innovative Properties Company
    Inventors: Richard L. Wang, Claudia Buhrmester, William M. Lamanna, Jeffrey R. Dahn, Lee Moshurchak
  • Patent number: 7579116
    Abstract: A fuel cell having a polymer electrolyte membrane containing fluorine atoms distributed along the polymer chains, and metal conductors and/or catalysts, is protected from fluoride ion degradation of the metal components by a fluoride ion sequestering agent fixed in the cell or flowing through the cell. In a preferred embodiment, the fluoride ion scavenger comprises a suitable number of azacrown moieties attached to polymer constituents in the electrolyte membrane or in electrodes.
    Type: Grant
    Filed: April 1, 2005
    Date of Patent: August 25, 2009
    Assignee: GM Global Technology Operations, Inc.
    Inventors: Andrew M. Mance, Belabbes Merzougui, Ion C. Halalay
  • Patent number: 7553588
    Abstract: An electrolyte for a lithium secondary battery includes lithium salts, a non-aqueous organic solvent, and additive compounds. The additive compounds added to the electrolyte of the present invention decompose earlier than the organic solvent to form a conductive polymer layer on the surface of a positive electrode, and prevent decomposition of the organic solvent. Accordingly, the electrolyte inhibits gas generation caused by decomposition of the organic solvent at initial charging, and thus reduces an increase of internal pressure and swelling during high temperature storage, and also improves safety of the battery during overcharge.
    Type: Grant
    Filed: September 10, 2003
    Date of Patent: June 30, 2009
    Assignees: Samsung SDI Co., Ltd., Cheil Industries Inc.
    Inventors: Jin-Hee Kim, Jin-Sung Kim, Sang-Moon Hwang, Meen-Seon Paik, Hak-Soo Kim
  • Patent number: 7524587
    Abstract: An aluminum secondary battery exhibiting favorable characteristics is provided. The present invention relates to a non-aqueous electrolyte comprising an electrolyte containing Al(CF3SO3)3 and a room temperature molten salt of a quaternary ammonium salt where CF3SO3? is anion, and to an aluminum secondary battery containing that non-aqueous electrolyte.
    Type: Grant
    Filed: May 11, 2007
    Date of Patent: April 28, 2009
    Assignee: Panasonic Corporation
    Inventor: Atsushi Omote