Abstract: A nonaqueous electrolyte secondary battery includes positive and negative electrodes, a separator, a nonaqueous electrolyte provided by dissolving a lithium salt in a nonaqueous solvent.
Abstract: A polymer electrolyte for lithium secondary batteries in which growth of lithium dendrites is suppressed is disclosed, batteries exhibiting excellent discharge characteristics in low to high temperature, comprising a polymer gel holding a nonaqueous solvent containing an electrolyte, wherein the polymer gel comprises (I) a unit derived from at least one monomer having one copolymerizable vinyl group and (II) a unit derived from at least one compound selected from the group consisting of (II-a) a compound having two acryloyl groups and a (poly)oxyethylene group, (II-b) a compound having one acryloyl group and a (poly)oxyethylene group, and (II-c) a glycidyl ether compound, particularly the polymer gel comprises monomer (I), compound (II-a), and a copolymerizable plasticizing compound are disclosed.
Abstract: The present invention pertains to solid composite cathodes which comprise (a)sulfur-containing cathode material which, in its oxidized state, comprises a polysulfide moiety of the formula, -Sm-, wherein m is an integer from 3 to 10; and (b) a non-electroactive particulate material having a strong adsorption of soluble polysulfides. The present invention also pertains to electric current producing cells comprising such solid composite cathodes, and methods of making such solid composite cathodes and electric current producing cells.
Type:
Application
Filed:
June 14, 2002
Publication date:
January 2, 2003
Applicant:
Moltec Corporation
Inventors:
Alexander
Gorkovenko
, Terje
A.
Skotheim
, Zhe-Sheng
Xu
Abstract: Electrolyte systems for lithium batteries with enhanced safety containing at least one lithium-containing conductive salt and at least one electrolyte liquid, in which the electrolyte liquid includes an effective amount of at least one partially fluorinated amide of formula (I)
R1CO—NR2R3 (I)
in which R1 is a linear C1-C6 alkyl group, or a branched C3-C6 alkyl group, in which one or more hydrogen atoms are replaced by fluorine atoms; or a C3-C7 cycloalkyl group optionally substituted one or more times by a linear C1-C6 alkyl group and/or branched C3-C6 alkyl group, in which one or more hydrogen atoms of are replaced by fluorine atoms; and R2 and R3 independently represent an identical or different linear C1-C6 alkyl group, a branched C3-C6 alkyl group or a C3-C7 cycloalkyl group, or R2 and R3 together with the amide nitrogen form a saturated five or six-member nitrogen-containing ring.
Type:
Grant
Filed:
June 19, 2001
Date of Patent:
December 3, 2002
Assignee:
Solvay Fluor und Derivate GmbH
Inventors:
Wolfgang Appel, Sergej Pasenok, Juergen Besenhard, Lars Henning Lie, Martin Winter
Abstract: A lithium secondary battery which is capable of terminating its operation safely with no accompanying rapid change in appearance, no gas generation, nor pressure change when any of an overcharge, overdischarge, and abnormal temperature rise occurs in the secondary battery itself. The lithium secondary battery includes a negative electrode, which is capable of absorbing and desorbing lithium, a positive electrode, which is capable of absorbing and desorbing lithium, and a non-aqueous electrolyte, wherein the non-aqueous electrolyte is solidified by a thermal reaction at a designated temperature.
Abstract: A lithium-ion battery having an anode electrode, a cathode electrode and a non-aqueous solvent lithium electrolyte. At least one cyclophosphazene is added to the non-aqueous solvent lithium electrolyte, which cyclophosphazene acts as a flame-retardant material. The non-aqueous solvent lithium electrolyte is preferably a carbonate-based electrolyte and the preferred cyclophosphazene is hexamethoxycyclotriphosphazene.
Type:
Grant
Filed:
August 24, 2000
Date of Patent:
September 24, 2002
Assignee:
Illinois Institute of Technology
Inventors:
Jai Prakash, Chang Woo Lee, Khalil Amine
Abstract: A new sandwich cathode design is provided having a first cathode structure of a first cathode active material of a relatively low energy density but of a relatively high rate capability, for example SVO, mixed with a second cathode active material having a relatively high energy density but a relatively low rate capability, for example CFx, with the percentage of SVO being less than that of CFx and sandwiched between two current collectors. Then, a second cathode mixture of SVO and CFx active materials is contacted to the outside of the current collectors. However, the percentage of SVO to CFx is greater in the second structure than in the first.
Abstract: An electrolyte composition comprising a compound represented by the following general formula (1):
wherein R represents a substituent containing a —(CR1R2—CR3R4—O)n— bond (in which R1 to R4 are independently a hydrogen atom or an alkyl group, n being an integer of 2 to 20); Q represents an atomic group forming an aromatic cation having a 5- or 6-membered ring structure with a nitrogen atom, which may have a substituent; and X− represents an anion. A photoelectric conversion device comprising the electrolyte composition and a photo-electrochemical cell composed thereof are also provided.
Type:
Grant
Filed:
August 3, 2000
Date of Patent:
April 23, 2002
Assignee:
Fuji Photo Film Co., Ltd.
Inventors:
Koji Wariishi, Chang-yi Qian, Michio Ono
Abstract: A nonaqueous electrolyte secondary battery includes a positive electrode having a positive electrode active material, a negative electrode containing a negative electrode active material capable of being doped/undoped with lithium, and a nonaqueous electrolyte. The nonaqueous electrolyte contains at least one of thiols, thiophenes, thioanisoles, thiazoles, thioacetates, aromatic sulfones, and the derivatives thereof. The capacity of the battery is not significantly degraded after cycling and its cycle life is significantly long.
Abstract: A non-aqueous electrolyte battery excellent in high-temperature storage characteristics is provided by adding to the non-aqueous electrolye a compound represented by the following formula: 1
Abstract: Polymer electrolyte composites for alkali metal electrochemical devices which are formed by coating an inert, lightweight, electrically insulating, non-woven glass fiber net which includes a polyvinyl alcohol binder, with a liquid polymer which may be ionically conductive, and curing the polymer to form a solid or semi-solid state electrolyte composite.
Type:
Grant
Filed:
June 20, 2000
Date of Patent:
December 4, 2001
Assignee:
Lithium Technology Corporation
Inventors:
Joseph B. Kejha, Santha Kolla, Jay Forlino
Abstract: A polycarbonate electrolyte comprising a polycarbonate membrane matrix and a lithium salt-containing electrolytic solution impregnated into the polycarbonate membrane matrix.
Type:
Grant
Filed:
August 27, 1999
Date of Patent:
October 9, 2001
Assignee:
Industrial Technology Research Institute
Abstract: The present invention relates to an organic electrolyte battery configured by sealing power generating elements comprising an organic electrolyte by a positive can, a negative can and a gasket, wherein said organic electrolyte includes a lithium salt containing a sulfonic acid group as a solute and at least one selected from a group consisting of sulfolane, 3-methyl sulfolane and Tetraglyme as a solvent. The aim of the invention is to provide an organic electrolyte battery having an excellent discharge performance in a low temperature environment and a superior reliability during long term storage, as well as a high temperature resistance which enables the battery to be mounted onto a substrate according to the Reflow method.
Type:
Grant
Filed:
July 20, 1999
Date of Patent:
August 14, 2001
Assignee:
Matsushita Electric Industrial Co., Ltd.
Abstract: A nonaqueous secondary battery comprising a positive electrode material, a negative electrode material, and a nonaqueous electrolytic solution containing a lithium salt, which contains at least one triarylamine compound and at least one organoboron compound. The battery has a high capacity and satisfactory charge and discharge cycle characteristics.
Abstract: The present invention consists in a binder for an electrode in an electrochemical system with a non-aqueous electrolyte, characterized in that it contains acrylonitrile-butadiene rubber and carboxymethylcellulose with an average molecular weight of over about 200 000.
Type:
Grant
Filed:
August 3, 1998
Date of Patent:
February 6, 2001
Assignee:
Alcatel
Inventors:
Sylvie Barusseau, Florence Martin, Bernard Simon
Abstract: An electrolyte containing at least one of dihalodicarbonyl compounds, in which hydrogen atoms of a methylene group between the two carbonyl groups are substituted with halogen atoms, and an electric energy generator comprising the electrolyte, an active material for positive electrode and an active material for negative electrode. The electrolyte has high polarity, high resistance to oxidation and flame retardance, and thus possesses excellent characteristics as the electrolyte for electric energy generators.
Abstract: An alkali metal secondary electrochemical cell, and preferably a lithium ion cell, activated with a quaternary solvent system, is described. The solvent system comprises a quaternary mixture of dialkyl carbonates and cyclic carbonates, and preferably dimethyl carbonate, diethyl carbonate, ethylmethyl carbonate and ethylene carbonate. Lithium ion cells activated with this electrolyte have good room temperature cycling characteristics and excellent low temperature discharge behavior.
Abstract: In a non-aqueous lithium ion secondary battery comprising a positive electrode and a negative electrode which are capable of reciprocally receiving and releasing lithium ions, a non-aqueous electrolyte solution containing a lithium salt in a non-aqueous solvent and a separator in a sealed case, the negative electrode comprises an amorphous calcogen compound or an amorphous metal oxide, and the non-aqueous electrolyte solution further contains at least one amine compound selected from the group consisting of a carbazole compound, a phenothiazine compound, a phenoxazine compound, an acridine compound, a dibenzoazepine compound and a phenazine compound. If the non-aqueous solvent comprises a non-cyclic carbonate compound and a cyclic carbonate compound, the amine compound can be a triarylamine.