Abstract: An organic electrolytic solution comprising a nonaqueous solvent and a lithium salt, wherein the organic electrolytic solution comprises a compound of Formula 1 and at least one selected from compounds of Formulas 2 through 5: wherein R1 a C1˜C10 alkoxy group, wherein R2 and R3 are independently unsubstituted C1˜C5 alkyl group or C1˜C5 alkyl group substituted with halogen atom, wherein n is an integer between 1 and 6.

Abstract: Organic electrolytic solutions and lithium batteries using the organic electrolytic solutions are provided. One organic electrolytic solution includes a lithium salt, a mixed organic solvent consisting of a high-dielectric constant solvent and a low-boiling point solvent, and a compound represented by Formula 1 or 2 as an additive. The organic electrolytic solution and the lithium battery using the organic electrolytic solution may inhibit the reductive cleavage reaction of a polar solvent, thereby increasing capacity retention of the battery, and improving charge-discharge efficiency and battery lifetime.

Abstract: A nonaqueous electrolyte battery is provided and includes: a negative electrode including a lithium titanium composite oxide showing an X-ray diffraction pattern in which each of main peak intensities of rutile TiO2, anatase TiO2 and Li2TiO3 is 5 or less with respect to a main peak intensity of ramsdellite lithium titanate of 100; a positive electrode; and a nonaqueous electrolyte.

Abstract: An electrolyte for a lithium ion secondary battery and a lithium ion secondary battery comprising the electrolyte. The electrolyte comprises a non-aqueous organic solvent, a lithium salt, and at least one aromatic phosphate compound. Exothermic reactions are inhibited in the battery upon overcharge or during high-temperature storage to prevent an increase in the temperature of the battery, resulting in an improvement in safety. In addition, the battery exhibits good swelling stability during high-temperature storage as well as improved cycle life characteristics. The electrolyte further comprises an ethylene carbonate-based compound. The presence of the ethylene carbonate-based compound leads to further improvements in the overcharge safety, high-temperature safety and cycle life characteristics of the battery.

Abstract: A positive electrode material is provided which is a blended combination of lithium nickel cobalt oxide (and aluminum substituted compounds thereof) and lithium nickel manganese cobalt oxide. Also provided Is a non-aqueous electrolyte lithium secondary battery having high specific capacity and good thermal stability characteristics.

Abstract: A non-aqueous electrolyte secondary battery that includes a non-aqueous electrolyte solution containing a non-aqueous solvent and an electrolyte, and vinylene carbonate (C3H2O3) and Li[M(C2O4)xRy] at 0.6 parts by weight or more and 3.9 parts by weight or less in total to 100 parts by weight of the non-aqueous electrolyte solution, wherein M is selected from the group consisting of P, Al, Si, and C; R is selected from the group consisting of a halogen group, an alkyl group, and a halogenated alkyl group; x is a positive integer; and y is 0 or a positive integer.

Abstract: There are disclosed electrolytes comprising solutions of lithium salts with large anions in polar aprotic solvents with a particular concentration of background salts. The concentration of the background salts is selected to be equal or close to the concentration of a saturated solution of these salts in the aprotic solvents used. The electrolytes disclosed can be used in chemical sources of electric energy such as secondary (rechargeable) cells and batteries comprising sulphur-based positive active materials. The use of such electrolytes increases cycling efficiency and cycle life of the cells and batteries.

Abstract: The present invention provides an electrolyte solution including: a solvent composed primarily of a BF3-cyclic ether complex; and a supporting electrolyte. For example, preferred is an electrolyte solution in which the cyclic ether is one or two or more selected from optionally substituted tetrahydrofuran and optionally substituted tetrahydropyran.

Abstract: The preservation performance of a nonaqueous electrolyte secondary cell charged to high potential is improved while the initial capacity and the cycle property of the cell are also improved. The nonaqueous electrolyte secondary cell includes: a positive electrode having lithium phosphate and a positive electrode active material containing lithium cobalt compound oxide and lithium manganese nickel compound oxide having a layer structure, the lithium cobalt compound oxide having at least zirconium and magnesium added in LiCoO2; a negative electrode having a negative electrode active material; and a nonaqueous electrolyte having a nonaqueous solvent and an electrolytic salt. The potential of the positive electrode is more than 4.3 V and 5.1 V or less based on lithium. The nonaqueous electrolyte contains vinylene carbonate as the nonaqueous solvent and, as the electrolytic salt, at least one of lithium bis(pentafluoroethane sulfonyl)imide and lithium bis(trifluoromethane sulfonyl)imide at 0.1 M or more and 0.

Abstract: A nonaqueous electrolyte battery includes: a positive electrode; a negative electrode; a nonaqueous electrolyte that includes a solvent and an electrolyte salt, the solvent including a halogenated cyclic carbonate of the Formula (1) below, or at least one of unsaturated cyclic carbonates of the Formulae (2) and (3) below; and a polyacid and/or a polyacid compound contained in the battery, where X is a F group or a Cl group, R1 and R2 are each independently a CnH2n+1 group (0?n?4), and R3 is CnH2n+1?mXm (0?n?4, 0?m?2n+1), where R4 and R5 are each independently a CnH2n+1 group (0?n?4), where R6 to R11 are each independently a CnH2n+1 group (0?n?4).

Abstract: A nonaqueous electrolyte secondary battery includes a case, a nonaqueous electrolyte provided in the case, a positive electrode provided in the case, and a negative electrode provided in the case, the negative electrode comprising a negative electrode current collector and a negative electrode layer that is carried on the negative electrode current collector and contains negative electrode active material particles, and the negative electrode current collector comprising an aluminum foil having an average crystal grain size of 50 ?m or less or an aluminum alloy foil having an average crystal grain size of 50 ?m or less.

Abstract: The present invention has for its object to provide an electrolyte solution which can dramatically suppress the time degradation in performance of an electrochemical device, especially an electrochemical capacitor. The present invention relates to an electrolyte solution for electrochemical device which comprises an imidazolium salt (A) represented by the general formula (1) as a main component, wherein the content of the imidazolium salt (B) represented by the general formula (2) is not more than 15% by weight to the total weight of the imidazolium salt (A) and imidazolium salt (B); (in the formula, R1, R2 and R3 may be the same or different and each represents an alkyl group containing 1 to 3 carbon atoms; R4 and R5 may be the same or different and each represents an hydrogen atom or an alkyl group containing 1 to 3 carbon atoms; and X? represents a counter anion) (in the formula, R1, R3, R4, R5 and X? are the same as the definition for the general formula (1)).

Abstract: An organic electrolytic solution for a lithium primary or secondary battery includes a lithium salt; an organic solvent; a radical initiator represented by Formula 1 below; and a polymerizable monomer represented by Formula 2 below: R1—N2+X???<Formula 1> wherein R1, R2, R3, R4, and X? are described herein. The organic electrolytic solution improves charge-discharge efficiency and increases cell capacity of the lithium primary or secondary battery.

Abstract: Disclosed is a non-aqueous electrolyte including an electrolyte salt and an electrolyte solvent, the non-aqueous electrolyte further including a compound containing both a carboxy group and a (meth)acrylic group, and a secondary battery including the non-aqueous electrolyte. The use of the compound containing both the carboxy group and the (meth)acrylic group as a component for an electrolyte significantly reduces the increase of battery thickness at high temperature storage.

Abstract: A positive electrode active material has an average particle diameter of 4.5 to 15.5 ?m and a specific surface area of 0.13 to 0.80 m2/g. A positive electrode mixture layer contains at least one of a silane coupling agent and/or at least one of aluminum, titanium, or zirconium based coupling agent having an alkyl or an alkoxy groups having 1 to 18 carbon atoms at a content of 0.003% by mass or more and 5% by mass or less with respect to the mass of the positive electrode active material. The nonaqueous electrolyte contains a 1,3-dioxane derivative at a content of 0.05% by mass or more with respect to the total mass of the nonaqueous electrolyte. Thus a nonaqueous secondary battery that has good high-temperature cycle characteristics and suppresses an increase in self-discharge after repetition of charge and discharge cycles at high temperature is provided.

Abstract: A new cathode design is provided comprising a cathode active material mixed with a binder and a conductive diluent in at least two differing formulations. Each of the formulations exists as a distinct cathode layer. After each layer is pressed or sheeted individually, a first one of the layers is contacted to a current collector. The other layer is then contacted to the opposite side of the layer contacting the current collector. Therefore, by using electrodes comprised of layers, where each layer is optimized for a desired characteristic (i.e. high capacity, high power, high stability), the resulting battery will display improved function over a wide range of applications. Such an exemplary cathode is comprised of: SVO (100?x %)/SVO (100?y %)/current collector/SVO (100?y %)/SVO (100?x %), wherein x and y are different and represent percentages of non-active materials.

Abstract: A battery capable of improving battery characteristics such as cycle characteristics and high temperature storage characteristics is provided. An anode includes an anode active material which includes Sn or Si as an element. A separator is impregnated with an electrolyte solution, and the electrolyte solution includes an acid anhydride such as succinic anhydride or a derivative thereof. Thereby, a coating is formed on the anode, and the decomposition of the electrolyte solution in the anode can be prevented. An electrolyte solution to which 4-fluoro-1,3-dioxolane-2-one is mixed is more preferably used.

Abstract: A magnesium battery electrode assembly is described, including a current collector comprising a carbonaceous material and an electrode layer comprising an electrode active material disposed on the current collector.

Abstract: The present invention relates to non-aqueous electrolytes having stabilization additives and electrochemical devices containing the same. Thus the present invention provides electrolytes containing an alkali metal salt, a polar aprotic solvent, a first additive that is a substituted or unsubstituted organoamine, substituted or unsubstituted alkane, substituted or unsubstituted alkene, or substituted or unsubstituted aryl compound, and/or a second additive that is a metal(chelato)borate. When used in electrochemical devices with, e.g., lithium manganese oxide spinel electrodes, the new electrolytes provide batteries with improved calendar and cycle life.

Abstract: A cathode active material composition of a cathode of a lithium battery includes a conducting agent, a binder, and a cathode active material coated on one surface of a current collector, wherein the cathode active material composition is coated with a vanadium oxide.

Abstract: The present invention includes small molecule organic additives for lead acid batteries, a lead acid battery and components thereof containing the small molecule organic additives of the invention, and methods for the use of such compounds. The batteries of the invention may optionally further contain carbon foam. The presence of carbon in the battery may generate some of the organic agents of the invention.

Abstract: An electrochemical cell is described. The electrochemical cell includes an anode, a cathode, a separator between said anode and said cathode, and an electrolyte. The electrolyte includes a salt dissolved in an organic solvent. The separator in combination with the electrolyte has an area specific resistance less than 2 ohm-cm2.

Abstract: An electrochemical cell is described. The electrochemical cell includes an anode, a cathode, a separator between said anode and said cathode, and an electrolyte. The electrolyte includes a salt dissolved in an organic solvent. The separator in combination with the electrolyte has an area specific resistance less than 2 ohm-cm2. The electrochemical cell has an interfacial anode to cathode ratio of less than about 1.1.

Abstract: A new design for a cathode having a configuration of: SVO/first current collector/CFx/second current collector/SVO is described. The two cathode current collectors are vertically aligned one on top of the other in a middle region or zone of the cathode. This coincides to where a winding mandrel will be positioned to form a wound electrode assembly with an anode. The overlapping region of the two current collectors helps balance the expansion forces of the exemplary SVO and CFx active material layers. This, in turn, helps maintain a planar cathode that is more amenable to downstream processing. The use of two current collectors on opposite sides of an intermediate cathode active material also provides for enhanced reliability when cathodes are wound from the center as they lend structural integrity to outer portions of the wind.

Abstract: A primary electrochemical cell and electrolyte incorporating a linear asymmetric ether is disclosed. The ether may include EME, used in combination with DIOX and DME, or have the general structural formula R1—O—CH2—CH2—O—R2 or R1—O—CH2—CH(CH3)—O—R2, where a total of at least 7 carbon atoms must be present in the compound, and R1 and R2 consist alkyl, cyclic, aromatic or halogenated groups but cannot be the same group (i.e., R1?R2).

Abstract: Disclosed is an electrochemical cell comprising a lithium anode and a sulfur-containing cathode and a non-aqueous electrolyte. The cell exhibits high utilization of the electroactive sulfur-containing material of the cathode and a high charge-discharge efficiency.

Abstract: The invention relates to reactive ionic liquids containing organic cations with groups or substituents which are susceptible to electrochemical reduction and anions obtained from fluoroalkyl phosphates, fluoroalkyl phosphinates, fluoroalkyl phosphonates, acetates, triflates, imides, methides, borates, phosphates and/or aluminates, for use in electrochemical cells, such as lithium ion batteries and double-layer capacitors.

Abstract: A nonaqueous electrolyte secondary battery includes a case, a nonaqueous electrolyte provided in the case, a positive electrode provided in the case, and a negative electrode provided in the case, the negative electrode comprising a negative electrode current collector and a negative electrode layer that is carried on the negative electrode current collector and contains negative electrode active material particles, and the negative electrode current collector comprising an aluminum foil having an average crystal grain size of 50 ?m or less or an aluminum alloy foil having an average crystal grain size of 50 ?m or less.

Abstract: The present invention has an objective to improve the storage characteristics and pulse discharge characteristics, especially in the high temperature region of 100° C. or more, of a lithium battery comprising a positive electrode including manganese oxide, a negative electrode, and a non-aqueous electrolyte. To achieve this objective, the lithium battery of the present invention includes a positive electrode (3) including manganese oxide in mixed crystal state, a negative electrode (4) desorbing lithium ions during discharging, and a non-aqueous electrolyte having lithium ion conductivity. The aforementioned manganese oxide in mixed crystal state includes at least ?-type manganese oxide and ?-type manganese oxide. The aforementioned non-aqueous electrolyte includes at least one additive selected from the group consisting of cyclic sultone compounds and sulfone compounds.

Abstract: An organic electrolytic solution and a lithium battery employing the same are provided. The organic electrolytic solution includes a lithium salt, an organic solvent containing a first solvent having a high dielectric constant and a second solvent having a low boiling point, and a surfactant including a hydrophobic portion having an aromatic group. The organic electrolytic solution effectively prevents the electrolytic solution from contacting the anode, thereby suppressing side reactions on the anode surface and improving discharge capacity, charge/discharge efficiency, lifespan, and battery reliability.

Abstract: The invention discloses a method of increasing the cycle life of rechargeable battery with a negative electrode (anode) made of lithium or lithium-containing alloys and electrolyte/salt solution which comprises one or more non-aqueous organic solvents and one or more lithium salts, the method comprising adding to the electrolyte/salt solution a lithium dendrite scavenging additive in an amount sufficient that a rate of lithium dendrite formation is equal to or lower than a rate of lithium dissolution occurring due to interaction with the dendrite scavenging additive dissolved in the electrolyte.

Abstract: A process is provided to produce non-aqueous electrolytic solution for use in batteries having low acid content and low water content. The invention involves removing acids and water from non-aqueous electrolytic solutions typically found in lithium or lithium-ion batteries by using nitrogen-containing compounds such as triazines. After treatment by a triazine such as melamine, the concentrations of acids and water in the electrolytic solutions are substantially decreased. The present invention provides a process to prepare extremely pure electrolytic solutions having low (<20 ppm) concentrations of both water and acids.

Abstract: The object of the present invention is to provide a reliable alkaline storage battery having a structure by which a short circuit between the electrodes can be prevented in the manufacturing procedures. To achieve this object, the present invention provides a cylindrical battery that includes an electrode assembly including a positive electrode plate and a negative electrode plate spirally wound together and sandwiching a separator. The collector plate includes a main body. One or more convex parts, each having a top extending linearly, are formed on a main surface of the main body by bending processing. A part of at least one of the convex part is cut out to form a cutout region. The collector plate is welded to the end part of the electrode assembly at the top of each convex part.

Abstract: There is provided an electrolytic solution which may significantly improve performance deterioration with time of an electrochemical capacitor. There is provided an electrolytic solution, comprising an electrolyte salt (A) shown as the following formula (1). In the formula, “R1,” “R2,” and “R3” independently represent an alkyl group having a carbon number of 1 to 3, “R4” and “R5” independently represent hydrogen atom or an alkyl group having a carbon number of 1 to 3, and “X?” represents a counterpart anion.

Abstract: A negative electrode is provided. The negative electrode includes a negative electrode current collector, and a negative electrode active material layer formed over the negative electrode current collector, and including a plurality of columnar bodies. An organic material layer having ion conductivity is held by said negative electrode active material layer, said organic material layer is formed at least in an inside of each of said columnar bodies. The active material layer may include silicon.

Abstract: The present invention relates to additives for electrolytes of lithium ion secondary batteries that include one or more of the following: 1,3-propane sultone, succinic anhydride; ethenyl sulfonyl benzene, and halobenzene. It can also include biphenyl, cyclohexylbenzene; and vinylene carbonate. The weight of said 1,3-propane sultone is between 0.5 wt. % and 96.4 wt. %, said succinic anhydride is between 0.5 wt. % and 96.4 wt. %; said ethenyl sulfonyl benzene is between 0.5 wt. % and 95.2 wt. %; and said halobenzene is between 0.5 wt. % and 95.2 wt. % of the weight of the additive. Batteries with electrolytes containing said additives have improved over-charge characteristics and low temperature properties, and reduced gas generation during charging and discharging.

Abstract: An electrochemical cell includes a cathode capable of reversibly releasing and receiving an alkali metal; an anode capable of reversibly releasing and receiving the alkali metal; and a non-aqueous electrolyte including one or more dissolved lithium salts, one or more nitriles, sulfur dioxide, and one or more other polar aprotic solvents.

Abstract: A non-aqueous electrolyte for a lithium battery includes a non-aqueous organic solvent, the organic solvent including one or more of a carbonate-based solvent, an ester-based solvent, an ether-based solvent, and/or a ketone-based solvent, a lithium salt, and a hexafluoroacetylacetone in an amount of about 0.02 parts by weight to about 10 parts by weight, based on 100 parts by weight of the non-aqueous organic solvent.

Abstract: A nonaqueous electrolyte battery includes a positive electrode, a negative electrode and a case formed of a film and including a heat sealed section formed on at least one edge portion of the case. The negative electrode contains a negative electrode active material having a lithium ion insertion potential not lower than 0.4V (vs. Li/Li+). The nonaqueous electrolyte battery also includes positive and negative electrode terminals. A first alumina layer having projections and recesses is formed on at least one part of a seal portion of the positive electrode terminal. A second alumina layer having projections and recesses is formed on at least one part of a seal portion of the negative electrode terminal. Further, the positive and negative electrode terminals have a cross sectional area S (mm2) which satisfies 0.6Q?S?2Q.

Abstract: A nonaqueous electrolyte solution in which an electrolyte salt is dissolved in an organic solvent includes, includes at least one or more compounds selected from the silicon compounds represented by general formula (1), (2), or (3) below: (In the formulae, each of R1, R2, and R3 independently represents a C1-8 alkyl, C2-8 alkenyl, C2-8 alkynyl, or C6-8 aryl group; R4 represents a C1-8 alkylene, C2-8 alkenylene, C2-8 alkynylene, or C6-8 arylene group; and n represents 1 or 2. When n is 1, X represents a fluorine atom, trifluoromethyl group, C1-8 alkoxy group, C2-8 alkenyloxy group, C6-8 aryloxy group, or C2-8 acyloxy group, C1-8 sulfonyloxy group, isocyanato group, isothiocyanato group, or cyano group. When n is 2, X represents a C1-8 alkylene group, C1-8 alkylenedioxy group, C2-8 alkenylene group, C2-8 alkenylenedioxy group, C2-8 alkynylene group, C2-8 alkynylenedioxy group, C6-8 arylene group, C6-8 arylenedioxy group, C2-8 diacyloxy group, oxygen atom, or direct bond.

Abstract: The object is to provide a nonaqueous-electrolyte battery having high charge/discharge efficiency and excellent high-rate performance. This subject is accomplished by using a nonaqueous electrolyte which comprises an organic solvent and a lithium salt dissolved therein and is characterized by containing at least one quaternary ammonium salt in an amount of 0.06 mol/L or larger and 0.5 mol/L or smaller. This effect is thought to be attributable to the following mechanism: in a relatively early stage (stage in which the negative-electrode potential is relatively noble) in a first charge step, a satisfactory protective coating film is formed on the negative electrode by the action of the quaternary ammonium salt and, hence, the organic solvent employed in the nonaqueous electrolyte is inhibited from decomposing.

Abstract: An electrolyte for a lithium secondary battery includes lithium salts, a non-aqueous organic solvent, and additive compounds, which initiates decomposition at 4V to 5V and show a constant current maintenance plateau region of more than or equal to 0.5V at measurement of LSV (linear sweep voltammetry). The additive compounds added to the electrolyte of the present invention decompose earlier than the organic solvent to form a conductive polymer layer on the surface of a positive electrode by increased electrochemical energy and heat at overcharge. The conductive polymer layer prevents decomposition of the organic solvent. Accordingly, the electrolyte inhibits gas generation caused by decomposition of the organic solvent during high temperature storage, and also improves safety of the battery during overcharge.

Abstract: A nonaqueous electrolyte secondary battery includes a case, a nonaqueous electrolyte provided in the case, a positive electrode provided in the case, and a negative electrode provided in the case, the negative electrode comprising a negative electrode current collector and a negative electrode layer that is carried on the negative electrode current collector and contains negative electrode active material particles, and the negative electrode current collector comprising an aluminum foil having an average crystal grain size of 50 ?m or less or an aluminum alloy foil having an average crystal grain size of 50 ?m or less.

Abstract: Disclosed is a rechargeable lithium polymer battery comprising a negative electrode including a negative active material layer deposited on a substrate, a positive electrode including a positive active material; and a polymer electrolyte including a lithium salt, an organic solvent, and a polymer.

Abstract: A method of making a lithium electrochemical cell includes treating the cathode active material with an agent that includes lithium but not sodium. A cathode including the cathode active material, an anode, a separator, and an electrolyte are assembled in a housing to provide a cell containing less than 1500 ppm by weight of sodium.

Abstract: A secondary battery is provided that is capable of improving the cycle characteristics. The secondary battery includes a cathode, an anode, and an electrolytic solution. The electrolytic solution is impregnated into a separator provided between the cathode and the anode. In the anode, an anode active material layer and a compound layer are provided on both faces of an anode current collector. The anode active material layer contains a plurality of anode active material particles. The anode active material particles have a multilayer structure of an anode active material containing silicon as an element. The thickness of each layer in the multilayer structure ranges from 50 nm to 1050 nm. Thus, contact characteristics between each layer, contact characteristics between the anode active material layer and the anode current collector, and current collectivity are improved.

Abstract: The battery has an electrolyte that includes an organoborate additive and one or more salts in a solvent. The organoborate additive can be present in a concentration less than 0.2 M or less than 0.05 M. A molar ratio of the organoborate additive:one or more salts is in a range of 4:1 to 400:1. In some instances, the solvent includes one or more organic solvents.

Abstract: Disclosed is a rechargeable lithium ion battery including a positive electrode comprising a first current collector and a positive active material layer on the first current collector; a negative electrode comprising a second current collector and a negative active material layer on the second current collector; and an electrolyte comprising a non-aqueous organic solvent and a lithium salt. At least one of the first and the second current collectors includes a rigid polymer film with a metal deposited on the rigid polymer film.

Abstract: A mixture of low-acid lithium borate salts and lithium hydride, to methods for producing the same and to the use thereof for battery electrolytes.

Abstract: This invention relates to overcharge protection and molecular redox shuttles in rechargeable lithium-ion cells. For this, specific nitroxyls or oxoammonium salts are used in the electrolyte. This invention also relates to a method of producing such lithium-ion cells and to a method of recharging such lithium-ion cells. This invention also pertains to some nitroxyls compounds and oxoammonium salts.