Abstract: The invention relates to the use of salt-based compounds as additives in electrolytes for improvinq the properties of electrochemical cells.

Abstract: A non-aqueous electrolytic cell having a positive electrode, which has a positive electrode active material layer containing, at least a positive electrode active material; a negative electrode, which has a negative electrode active material layer containing, at least, a negative electrode active material; and an electrolyte, wherein a sulfur compound is added to at least one of the positive electrode active material and/or the negative electrode active material.

Abstract: The present invention provides a lithium secondary battery comprising a cathode electrode containing a lithium complex oxide; an anode electrode containing metal lithium or its alloy, or carbon material; and a nonaqueous organic electrolyte containing a nonaqueous organic solvent, a lithium salt and an aromatic ether that can react to form dimers or polymers above a certain temperature and voltage and that can be expressed by Formula 1 below: wherein, R1 is independently a single bond or an alkylene group with less than or equal to 2 carbons and R2 is hydrogen or an alkyl group with less than or equal to 2 carbons. The lithium secondary battery has the advantage that its characteristics are maintained, even if it is left in its fully charged state at a high temperature for a long time and, at the same time, its reliability and stability have been improved.

Abstract: The non-aqueous electrolyte battery of the present invention has a negative electrode comprising metallic lithium, a lithium alloy or a material capable of absorbing and desorbing lithium; a positive electrode; a non-aqueous electrolyte comprising a solvent and a solute dissolved in the solvent, wherein the above non-aqueous electrolyte contains at least one additive selected from phthalimide, derivative of phthalimide, phthalimidine, derivative of phthalimidine, tetrahydrophthalimide and derivative of tetrahydrophthalimide. On account of the effect of the above additive, the nonaqueous electrolyte battery of the present invention is not liable to cause an increase in the internal resistance during a long-term storage at high temperatures, and the charge/discharge cycle characteristics are improved in a secondary battery.

Abstract: An organic salt having an alkali metal bound to a disubstituted amide of alkane iminosulfinic acid has the following general formula: 1

Abstract: Provided are a polymeric gel electrolyte comprising a lithium salt, an organic solvent and a thermal curing product of a composition having a terpolymer having a repeating unit represented by formula (1), a repeating unit represented by formula (2) and a repeating unit represented by formula (3): wherein n is an integer from 1 to 12, and R is a C1 to C12 alkyl group, and a lithium battery employing the polymeric electrolyte. Use of a polymeric gel electrolyte according to the present invention can effectively suppress swelling due to an electrolytic solution, and a lithium battery which can prevent reliability and safety from being lowered due to the swelling, can be attained.

Abstract: A non-aqueous electrolyte battery free from considerable change in the structure of a positive electrode active material thereof to enlarge the capacity thereof, incorporating a positive electrode containing a positive-electrode active material; a negative electrode containing a negative-electrode active material to which Li can be doped/dedoped; and a non-aqueous electrolyte disposed between the positive electrode and the negative electrode and containing non-aqueous solvent and an electrolyte, wherein a material expressed by general formula LiMn1−yAlyO2 (0.06≦y<0.25) is contained as the positive-electrode active material and LiMn1−yAlyO2 has a crystalline structure expressed by spatial group C2/m.

Abstract: A nonaqueous electrolyte battery having improved characteristics under a heavy load environment and incorporating nonaqueous electrolytic solution which contains vinylene carbonate in a proper quantity to improve conductivity of the nonaqueous electrolytic solution so that doping/dedoping of lithium ions is performed smoothly and, therefore, the internal resistance is decreased. Hence it follows that the initial capacity of the battery is enlarged and satisfactory heavy load characteristics are realized.

Abstract: A lithium secondary battery exhibiting very high safety, which is ensured by restraining both the generation of flammable gas caused by the decomposition of an electrolyte, and the emission of oxygen from a positive active material even during overcharging. The lithium secondary battery includes a positive electrode of which an active material is a lithium transition metal composite oxide, a negative electrode of which an active material is a carbon material, and a nonaqueous electrolyte containing an organic solvent in which a lithium salt is dissolved. The nonaqueous electrolyte contains at least one kind of conductive polymer-forming monomers which have an alkyl group and is electrochemically polymerizable on the positive electrode within a battery operation voltage, and at least one kind of film-forming agents which electrochemically decompose within the battery operation voltage to form films on a surface of the negative electrode.

Abstract: Disclosed are non-aqueous electrolyte compositions of the present invention that comprise non-aqueous solvents and monomers such as aniline, phenanthrene, ethylenedioxythiophene, benzothiophene or derivatives thereof. The monomers are contained in the electrolytes of the present invention in the amounts of less than about 5.0 weight percent of the non-aqueous solvent. In the present invention, cyclic carbonates, linear carbonates or mixtures thereof can be used as the non-aqueous solvents. The electrolyte compositions of the present invention improve the safety characteristics of the cell by preventing the flow of large currents resulting from overcharge or feed-through, and also improve cell life characteristic by helping the reversible transfer of lithium ions.

Abstract: A non-aqueous secondary organic battery. The battery includes an positive electrode of polyaniline-conductive carbon black composite (PAn-C composite). The PAn-C composite is prepared using a high-speed impingment mill with high-speed fluid striking and grinding functions. The resulting PAn-C composite has higher conductivity than the mixture of conductive carbon and PAn by direct mixing. The non-aqueous secondary organic battery of the present invention exhibits great capacity and energy density.

Abstract: A secondary cell employs a non-aqueous electrolyte solution including a non-aqueous solvent and a salt, and a flame retardant material that is a liquid at room temperature and pressure and substantially immiscible in the non-aqueous electrolyte solution. The non-aqueous electrolyte solution is formed by dissolving a salt, preferably an alkali metal salt, in a non-aqueous solvent. The non-aqueous solvent preferably includes a cyclic carbonate and/or a linear carbonate. The cyclic carbonate preferably contains an alkylene group with 2 to 5 carbon atoms, and the linear carbonate preferably contains a hydrocarbon group with 1 to 5 carbon atoms. Preferred salts include LiPF6 and LiBF4 at a concentration between about 0.1 to 3.0 moles/liter in the non-aqueous solvent.

Abstract: The present invention relates to a positive electrode active material, a negative electrode active material and an electrolyte that are used alone or in combination to improve charge and discharge cycle characteristic, low temperature characteristic and safety of a non-aqueous electrolyic secondary battery, particularly a lithium ion secondary battery. Specifically, a particulate Li-transition metal composite oxide having an average particle size of not less than 10 &mgr;m, wherein [20/(specific surface area×average particle size)]=7-9, is used as a positive electrode active material.

Abstract: An organic electrolytic solution and a lithium secondary battery employing the same, wherein the organic electrolytic solution for a lithium secondary battery includes a polymer adsorbent having an ethylene oxide chain capable of being adsorbed into a lithium metal, a material capable of reacting with lithium to form a lithium alloy, a lithium salt, and an organic solvent. The organic electrolytic solution may be applied to all types of batteries including lithium ion batteries, lithium polymer batteries and lithium metal polymer batteries using a lithium metal for a negative electrode material, and the like. In particular, when the organic electrolytic solution is utilized in a lithium metal polymer battery, it serves to stabilize the lithium metal, and to increase the lithium ionic conductivity, thereby improving the cycle characteristics and charging/discharging efficiency of the battery.

Abstract: A lithium/fluorinated carbon electrochemical cell having the CFx material supported on a titanium current collector screen sputter coated with a noble metal is described. The gold, iridium, palladium, platinum, rhodium and ruthenium-coated titanium current collector provides the cell with higher rate capability, even after exposure to high temperatures, in comparison to cells of a similar chemistry having the CFx contacted to a titanium current collector painted with a carbon coating.

Abstract: A nano-battery or micro-battery produced by a process which includes the steps of providing a membrane with a plurality of pores, filling the membrane pores with an electrolyte, and capping the filled pores with electrodes in communication with the electrolyte to form nano-batteries or micro-batteries.

Abstract: In a rechargeable non-aqueous electrolyte secondary battery using positive electrodes, negative electrodes and a non-aqueous electrolytic solution, additives to the electrolytic solution are used in combination, preferably in combination of at least two compounds selected from o-terphenyl, triphenylene, cyclohexylbenzene and biphenyl, and thus there are provided batteries excellent in safety and storage characteristics.

Abstract: A nonaqueous electrolyte for use in improving overcharge safety in a lithium battery includes an organic solvent, a lithium salt, and a benzyl biphenyl compound, a hydride thereof or a mixture thereof.

Abstract: A method for manufacturing galvanic elements having a liquid organic electrolyte that contain an electrode-separator assembly that has at least one lithium intercalating electrode in whose polymer matrix insoluble, electrochemically active materials are finely distributed in the polymer involved, the electrolyte contains about 2% to about 15% by weight of a hydrocarbon-oxygen compound (carbonate) that has a central carbon atom, to which one oxygen atom is doubly bonded and two oxygen are singly bonded, where the singly bonded oxygen is not saturated by any other atoms or groups and a hydrocarbon chain having a length of four carbon atoms or less is bonded to each of those singly bonded oxygen atoms and these two chains differ by at least one, but no more than three, CH2 groups, and this electrode-separator assembly is initially impregnated with this electrolyte, then cut to size, and subsequently inserted into a housing.

Abstract: Disclosed are a lithium salt expressed by a formula, LiAlXn(OY)4-n, where “X” is an electrophilic substituent group and “Y” is an oligoether group, an ionic conductor with the lithium salt dispersed in a structural member, and a liquid electrolyte with the lithium salt dissolved in a solvent. For example, the ionic conductor exhibits high ionic conductivity as well as high lithium ion transport number.

Abstract: A non-aqueous electric current producing electrochemical cell is provided comprising an anode and a cathode, an ionically permeable separator interposed between the anode and the cathode, and a non-aqueous electrolyte, the electrolyte comprising an ionically conducting salt in a non-aqueous medium, the ionically conducting salt corresponding to the formula:

Abstract: The prevent invention provides a non-aqueous electrolyte for batteries comprising the dissolving of an electrolytic salt in an organic solvent, wherein said organic solvent contains at least one type each of cyclic carbonate compound, alkyl mono-carbonate compound represented by chemical formula (1), alkylene bis-carbonate compound represented by chemical formula (2), glycol diether compound represented by chemical formula (3) (R6O—(R7O)n—R8) and phosphorous-containing organic compound. The use of at least one type of glycol diether represented with this general formula is able to yield satisfactory output characteristics by lowering the internal resistance of the battery as a result of increasing the mobility of lithium ions at the solid-liquid interface.

Abstract: The invention relates to non-aqueous electrochemical cell comprising: a first electrode and a second counterelectrode each capable of reversibly incorporating an alkali metal, preferably lithium; an alkali metal incorporated into at least one of said electrodes; and an electrolyte comprising at least one salt of the alkali metal and a non-aqueous solvent; wherein the said salt is capable of generating HF in the presence of water and the cell includes at least one component, such as a temperature sensitive separator, which precludes complete removal of residual water from the cell, and wherein the cell includes sufficient of an unsaturated cyclic carbonate to reduce the concentration of HF formed by reaction of the electrolyte salt with the residual water.

Abstract: Lithium batteries having excellent high rate characteristics and low-temperature characteristics, and less in evolution of gases and superior in discharge characteristics are provided by using LiCoO2 mixed with CaO or Cr2O3 or the like as an active material of positive electrode in combination with a non-aqueous electrolyte containing a mixed electrolyte salt comprising both a fluorine-containing inorganic anion lithium salt and a lithium imide salt.

Abstract: An electrolyte system suitable for a molten salt electrolyte battery is described where the electrolyte system is a molten nitrate compound, an organic compound containing dissolved lithium salts, or a 1-ethyl-3-methlyimidazolium salt with a melting temperature between approximately room temperature and approximately 250° C. With a compatible anode and cathode, the electrolyte system is utilized in a battery as a power source suitable for oil/gas borehole applications and in heat sensors.

Abstract: An electrolyte for a rechargeable lithium battery is provided. The electrolyte includes a non-aqueous organic solvent and a lithium salt. The non aqueous organic solvent includes cyclic carbonate such as ethylene carbonate and propylene carbonate, chain carbonate such as dimethyl carbonate, diethyl carbonate, methyl ethyl carbonate and methyl propyl carbonate, and alkyl acetate such as n-methyl acetate, n-ethyl acetate and n-propyl acetate. The electrolyte can be used in a rechargeable lithium battery to provide good low temperature characteristics and safety.

Abstract: An electrochemical cell of either a primary or a secondary chemistry, is described. In either case, the cell has a negative electrode of lithium or of an anode material which is capable of intercalating and de-intercalating lithium coupled with a positive electrode of a cathode active material. A phosphonate compound is mixed with either the anode material or the cathode active material prior to contact with its current collector. The resulting electrode couple is activated by a non-aqueous electrolyte. The electrolyte flows into and throughout the electrodes causing the phosphonate additive to dissolve in the electrolyte. The phosphonate solute is then able to contact the lithium to provide an electrically insulating and ionically conducting passivation layer thereon.

Abstract: A secondary power source comprising a positive electrode made mainly of activated carbon, a negative electrode made mainly of a carbon material capable of doping and undoping lithium ions and an organic electrolyte containing a solute of a lithium salt, wherein the lithium salt comprises LiN(SO2Rf1) (SO2Rf2) wherein each of Rf1 and Rf2 which are independent of each other, is a C1-6 perfluoroalkyl group except Rf1═Rf2═CF3.

Abstract: A modified lithium ion polymer battery, comprising a positive electrode sheet and a negative electrode sheet, formed by blending a binder with positive electrode powder and coating the resulting blend on a copper foil or an aluminum foil used as the collector, wherein said binder can be prepared from the following three components: (a) 0.1 wt %˜95 wt % of polyvinylidene fluoride; (b) 0.1 wt %˜90 wt % of a modified polyacrylates; and (c) 0.

Abstract: A rechargeable lithium battery includes a negative electrode with a graphite-based active material with boron as a donor and a positive electrode with a transition metal oxide-based active material. A separator is interposed between the negative and positive electrodes. The positive and negative electrodes and the separator are all saturated with an electrolyte. The electrolyte contains cyclic carbonate and chain carbonate at a ratio of 51:49 by volume percent.

Abstract: Disclosed is an electrolyte for a rechargeable lithium battery. The electrolyte includes non-aqueous solvent and silicon powder. Silicon powder reacts with hydrogen halide produced by reacting a solute with water, thereby removing the hydrogen halide. The solvent may be an organic solvent such as a cyclic or chain carbonates, or a mixture thereof. The amount of silicon powder is 0.01 to 5 wt % of the organic solvent.

Abstract: The present invention relates to a method for dehydrating an aqueous composition comprising lithium bis(pentafluoroethanesulfonyl)imide and at least one organic solvent, wherein said dehydration method of the composition comprising lithium bis(pentafluoroethanesulfonyl)imide is characterized in that a part of solvent is distilled off by distillation.

Abstract: In a polymer electrolyte battery provided with a positive electrode, a negative electrode, and a polymer electrolyte containing a non-aqueous electrolyte solution, a solvent in said non-aqueous electrolyte solution contains vinylene carbonate in a concentration of 0.1 to 90 vol % so that the non-aqueous electrolyte solution contained in the polymer electrolyte is restrained from reacting with the positive electrode and negative electrode.

Abstract: A polymer electrolyte for lithium secondary batteries in which growth of lithium dendrites is suppressed is disclosed, batteries exhibiting excellent discharge characteristics in low to high temperature, comprising a polymer gel holding a nonaqueous solvent containing an electrolyte, wherein the polymer gel comprises (I) a unit derived from at least one monomer having one copolymerizable vinyl group and (II) a unit derived from at least one compound selected from the group consisting of (II-a) a compound having two acryloyl groups and a (poly)oxyethylene group, (II-b) a compound having one acryloyl group and a (poly)oxyethylene group, and (II-c) a glycidyl ether compound, particularly the polymer gel comprises monomer (I), compound (II-a), and a copolymerizable plasticizing compound are disclosed.

Abstract: Graphite sheeting having a thickness of less than 250 micrometers and in-plane conductivity of at least 100 S/cm when employed as a cathode current collector in a lithium or lithium ion cell containing a fluorinated lithium imide or methide electrolyte salt imparts high thermal resistance, excellent electrochemical stability, and surprisingly high capacity retention at high rates of discharge.

Abstract: The present invention pertains to solid composite cathodes which comprise (a)sulfur-containing cathode material which, in its oxidized state, comprises a polysulfide moiety of the formula, -Sm-, wherein m is an integer from 3 to 10; and (b) a non-electroactive particulate material having a strong adsorption of soluble polysulfides. The present invention also pertains to electric current producing cells comprising such solid composite cathodes, and methods of making such solid composite cathodes and electric current producing cells.

Abstract: Systems and methods for providing electrolytes having a multi-salt mixture used in electrochemical systems such as lithium ion batteries. The battery system generally includes a cathode, anode and electrolyte cells. The cells prepared with the multi-salt electrolyte, for instance, a mixed lithium/sodium mixed salt electrolyte, exhibit nearly the same capacity as those using pure lithium salt electrolyte. These cells exhibit improved cyclability, smaller internal resistance and better rate capability than those using pure lithium electrolyte. The multi-salt electrolyte is electrochemically stable within a voltage range of about 4.8 to 2.5 V. The mixed Li/Na salt electrolytes provide a cost alternative to a pure lithium salt and enhance the electrochemical properties of lithium ion batteries.

Abstract: A lithium ion electrochemical cell having high charge/discharge capacity, long cycle life and exhibiting a reduced first cycle irreversible capacity, is described. The stated benefits are realized by the addition of at least one phosphonate additive having the formula (R1O)P(═O) (OR2) (R3) provided in the electrolyte. In the phosphonate formula, R3 is a hydrogen atom and wherein at least one, but not both, of R1 and R2 is a hydrogen atom and the other of R1 and R2 is an organic group containing 1 to 13 carbon atoms. Or, at least one of R1 and R2 is an organic group containing at least 3 carbon atoms and having an sp or sp2 hybridized carbon atom bonded to an sp3 hybridized carbon atom bonded to the oxygen atom bonded to the phosphorous atom, or at least one of R1 and R2 is an unsaturated inorganic group.

Abstract: A negative active material for a lithium secondary battery which is capable of improving packing density and has good high-rate charge/discharge and cycle life characteristics is provided. The negative active material includes a crystalline carbon core and an amorphous carbon shell. Alternatively, the negative active material includes secondary particles prepared by gathering at least one crystalline carbon primary particle. A surface of the secondary particles is coated with an amorphous carbon and the secondary particles has a substantially spherical form. The negative active material has two exothermic peak of the differential thermal analysis at 1000° C. or less. A lithium secondary battery using the negative active material can use propylene carbonate for an organic solvent of an electrolyte.

Abstract: A non-aqueous secondary battery comprising a negative electrode made of an active negative electrode material capable of intercalating/deintercalating lithium ion, a positive electrode made of spinnel type lithium manganese oxide as a main active positive electrode material and an electrolyte containing a non-aqueous solvent is characterized in that said positive electrode comprises lithium cobalt oxide in admixture with spinnel type lithium manganese oxide having crystal lattices partially substituted by magnesium or aluminum and said non-aqueous solvent comprises vinylene carbonate incorporated therein.

Abstract: A non-aqueous electrolyte lithium secondary battery that includes: a carbon capable of intercalating and de-intercalating lithium ion as an anode; a lithium containing material that can reversibly intercalate and de-intercalate lithium ion as a cathode; and a non-aqueous electrolyte including trans-4,5, dialkyl-1,3- dioxolane-2-one substantially free of cis-4,5-dialkyl-1,3-dioxolane-2-one and a lithium salt.

Abstract: A secondary power source, which comprises a positive electrode containing activated carbon, a negative electrode containing a carbon material capable of doping and undoping lithium ions, and an organic electrolyte containing a lithium salt, wherein the negative electrode has a density of from 0.6 to 1.2 g/cm3.

Abstract: A lithium-ion battery having an anode electrode, a cathode electrode and a non-aqueous solvent lithium electrolyte. At least one cyclophosphazene is added to the non-aqueous solvent lithium electrolyte, which cyclophosphazene acts as a flame-retardant material. The non-aqueous solvent lithium electrolyte is preferably a carbonate-based electrolyte and the preferred cyclophosphazene is hexamethoxycyclotriphosphazene.

Abstract: Electrolytic compositions comprising a perfluoropolyether additive of formula (I): 1

Abstract: Improved electrolytes for application in electrical storage devices, such as batteries and capacitors, electrochromic display and other applications requiring tonically conductive medium are disclosed. The electrolytes of the invention contain organic cation salts, also called ionic liquids or molten salts. These improved electrolytes have useful characteristics such as high thermal stability and reduced flammability.

Abstract: A battery cell 10 is attached in an apparatus loaded in a revolving body etc., such that the negative electrode 2 side of the battery cell 10 is oriented, within a prescribed angular range, in the direction in which centrifugal force acts.

Abstract: An alkali metal, solid cathode, nonaqueous electrochemical cell capable of delivering high current pulses, rapidly recovering its open circuit voltage and having high current capacity, is described. The stated benefits are realized by the addition of at least one organic sulfite additive to an electrolyte comprising an alkali metal salt dissolved in a mixture of a low viscosity solvent and a high permittivity solvent. A preferred solvent mixture includes propylene carbonate, dimethoxyethane and a sulfite additive having at least one unsaturated hydrocarbon containing a C(sp2 or sp3)—C(sp3) bond unit having the C(sp3) carbon directly connected to the —OSO2— functional group.

Abstract: A positive active material composition for a lithium-sulfur battery includes a positive active material, a conductive agent, an organic mixing solvent to which solubility of sulfur is equals to or less than 50 mM, and a binder capable of dissolving in the organic mixing solvent.

Abstract: The invention relates to a non-aqueous electrochemical apparatus in which the difference (&ggr;l-&ggr;se) between the surface tension &ggr;l of non-aqueous electrolyte and the surface free energy &ggr;se of electrode is not more than 10 dynes/cm.

Abstract: A nonaqueous electrolyte secondary battery comprises a cathode having a cathode active material capable of electrochemically doping/dedoping lithium, an anode having an anode active material capable of electrochemically doping/dedoping lithium and a nonaqueous electrolyte interposed between the cathode and the anode. The nonaqueous electrolyte includes at least one or more kinds of vinylene carbonate, methoxybenzene compounds or antioxidants. The nonaqueous electrolyte secondary battery has a good cyclic characteristic under any environment of low temperature, ambient temperature and high temperature.