Oxygen Containing Organic Solvent Compound Patents (Class 429/341)
  • Publication number: 20130040209
    Abstract: A non-aqueous electrolyte solution containing a cyclic sulfone compound having a 1,3-dithietane-1,1,3,3-tetraoxide structure is provided. The cyclic sultone compound is preferably a compound represented by formula (I) [wherein in formula (I), R1 to R4 each represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, or the like].
    Type: Application
    Filed: April 25, 2011
    Publication date: February 14, 2013
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Shigeru Mio, Mitsuo Nakamura, Hidenobu Nogi, Takashi Hayashi, Takeshi Kobayashi
  • Publication number: 20130034780
    Abstract: A magnesium battery, having an anode containing magnesium; a cathode stable to a voltage of at least 2.6 V relative to a magnesium reference; and an electrolyte containing an electrochemically active magnesium salt obtained by reaction of a Grignard reagent or Hauser base with a boron compound of formula BR3 is provided. The electrolyte is stable to 2.6 E.V. vs. Mg in the presence of stainless steel.
    Type: Application
    Filed: August 4, 2011
    Publication date: February 7, 2013
    Applicant: Toyota Motor Engin. & Manufact. N.A.(TEMA)
    Inventors: John MULDOON, Claudiu Bogdan Bucur
  • Publication number: 20130029232
    Abstract: A lithium ion secondary battery includes a positive electrode, a negative electrode, a separator and an ionic liquid electrolyte. The separator is a polar porous membrane. The ionic liquid electrolyte and the separator made of the polar porous are used in the lithium ion secondary batteries, which can improve the electrochemical performance of the lithium ion secondary batteries.
    Type: Application
    Filed: July 25, 2012
    Publication date: January 31, 2013
    Applicant: Microvast New Materials (Huzhou) Co., LTD.
    Inventors: ZHUOQUN ZHENG, Bin Gu, Hong Wang, Liaoying Ke, Yunhua Nie
  • Publication number: 20130029230
    Abstract: An electrolyte for the lithium secondary battery having flame retardancy, low negative electrode interfacial resistance, and excellent high temperature properties and life characteristics, and a lithium secondary battery including the same. An electrolyte for lithium secondary battery of the present invention may include a non-aqueous organic solvent, a lithium salt, fluorinated ether or phosphazene, and a resistance-improving additive represented as the following chemical formula (1): RSO2—R1—SO2F??[Chemical Formula 1] wherein R1 is a C1-C12 hydrocarbon unsubstituted or substituted with at least one fluorine.
    Type: Application
    Filed: October 3, 2011
    Publication date: January 31, 2013
    Applicant: SAMSUNG SDI, CO., LTD.
    Inventors: Sinyoung Park, Yongbeom Lee, Sunyoung Kim, Bora Lee
  • Publication number: 20130022879
    Abstract: Provided is a nonaqueous electrolyte secondary battery which, even in the case of using a low-viscosity solvent having a narrow potential window, can increase the electrochemical stability of the nonaqueous electrolyte solution and suppress side reactions of the nonaqueous electrolyte solution during charge and discharge to reduce the degradation of the battery characteristics and has an excellent storage characteristic in high-temperature environments and a nonaqueous electrolyte solution for the nonaqueous electrolyte secondary battery.
    Type: Application
    Filed: April 28, 2011
    Publication date: January 24, 2013
    Applicants: MITSUBISHI CHEMICAL CORPORATION, SANYO Electric Co., Ltd.
    Inventors: Hidekazu Yamamoto, Kouhei Tuduki, Taizou Sunano, Maruo Kamino, Youichi Ohashi, Minoru Kotato
  • Patent number: 8357469
    Abstract: A bipolar battery construction is disclosed comprising a substrate, openings in the substrate, an electrically conductive material placed within the openings, a negative and positive current collector foil placed on opposing sides of the substrate and negative and positive pasting frame members. The electrically conductive material may have a melting point below the thermal degradation temperature of the substrate.
    Type: Grant
    Filed: January 20, 2010
    Date of Patent: January 22, 2013
    Assignee: Advanced Battery Concepts, LLC
    Inventors: Edward Otto Shaffer, II, William Buttfield Brecht
  • Publication number: 20130017418
    Abstract: The present invention relates to electrode material for an electrical cell comprising as component (A) at least one ion- and electron-conductive metal chalcogenide, as component (B) carbon in a polymorph comprising at least 60% sp2-hybridized carbon atoms, as component (C) at least one sulfur-containing component selected from the group consisting of elemental sulfur, a composite produced from elemental sulfur and at least one polymer, a polymer comprising divalent di- or polysulfide bridges and mixtures thereof, and as component (D) optionally at least one binder. The invention further relates to a rechargeable electrical cell comprising at least one electrode which has been produced from or using the inventive electrode material, to the use of the rechargeable electrical cell and to the use of an ion- and electron-conductive metal chalcogenide for production of an inventive rechargeable electrical cell.
    Type: Application
    Filed: July 9, 2012
    Publication date: January 17, 2013
    Applicant: BASF SE
    Inventors: Arnd GARSUCH, Stefan Herzog, Lucas Montag, Andrea Krebs
  • Publication number: 20130011747
    Abstract: There is provided a lithium ion secondary battery excellent in cycle characteristics in which the conductivity of an electrode using a graphite material which is less deformed and oriented by pressurization is improved. A negative electrode mixture which includes at least a negative electrode active material comprising graphite as a main component, a binder, and a conductive aid has a ratio of a peak intensity of a (002) plane to a peak intensity of a (110) plane in an X-ray diffraction spectrum of 30 or more and 70 or less, the spectrum being measured after the negative electrode mixture is pressed at 98 MPa (1000 kgf/cm2), and the conductive aid includes carbon black having a DBP absorption (cm3/100 g) of 250 or more and 500 or less.
    Type: Application
    Filed: March 18, 2011
    Publication date: January 10, 2013
    Applicant: NEC ENERGY DEVICES, LTD.
    Inventors: Hideaki Sasaki, Takehiro Noguchi
  • Patent number: 8349496
    Abstract: A non-aqueous electrolyte secondary battery having a negative electrode, a non-aqueous electrolyte, and a positive electrode having a positive electrode active material comprising sodium oxide, is characterized in that the sodium oxide contains lithium, and the molar amount of the lithium is less than the molar amount of the sodium.
    Type: Grant
    Filed: February 9, 2012
    Date of Patent: January 8, 2013
    Assignee: SANYO Electric Co., Ltd.
    Inventors: Motoharu Saito, Hideyuki Koga, Katsutoshi Takeda, Masahisa Fujimoto
  • Publication number: 20130004859
    Abstract: Disclosed are a nonaqueous electrolyte for a lithium secondary battery containing a hetero polycyclic compound and a lithium secondary battery using the same.
    Type: Application
    Filed: June 29, 2012
    Publication date: January 3, 2013
    Inventors: Sung-Hoon YU, Doo Kyung YANG, Jong-Ho JEON, Min-Jung JOU
  • Publication number: 20130004861
    Abstract: A non-aqueous electrolyte additive for a lithium secondary battery, a non-aqueous electrolyte, and a lithium secondary battery including the same, the additive including dicyanoacetylene or a cyano group-containing unsaturated compound represented by the following Chemical Formula 1, the cyano group-containing unsaturated compound including an unsaturated bond and two or more cyano groups linked in cis- or trans-positions of carbons of the unsaturated bond.
    Type: Application
    Filed: January 26, 2012
    Publication date: January 3, 2013
    Inventors: Jung-Yi YU, Woo-Cheol SHIN, Sang-Il HAN, Mi-Hyun LEE, Tae-Hyun BAE
  • Patent number: 8343374
    Abstract: There is provided an electrolytic solution comprising a chain carbonate (I) represented by the formula (I): wherein Rf is a fluorine-containing ether group (Ia) having, at its end, a moiety represented by the formula: HCFX (X is H or F); R is an alkyl group in which hydrogen atom may be substituted with halogen atom and hetero atom may be contained in its chain, and an electrolyte salt (II), and the electrolytic solution is excellent in flame retardance, low temperature characteristics, withstand voltage and compatibility with a hydrocarbon solvent and is high in solubility of an electrolyte salt.
    Type: Grant
    Filed: March 28, 2006
    Date of Patent: January 1, 2013
    Assignee: Daikin Industries, Ltd.
    Inventors: Meiten Koh, Akiyoshi Yamauchi, Yasuko Takagahara
  • Publication number: 20120315549
    Abstract: A battery electrolyte solution contains from 0.001 to 20% by weight of certain phosphorus-sulfur compounds. The phosphorus-sulfur compound performs effectively as a solid-electrolyte interphase (SEI) forming material. The phosphorus-sulfur compound has little adverse impact on the electrical properties of the battery, and in some cases actually improves battery performance. Batteries containing the electrolyte solution form robust and stable SEIs even when charged at high rates during initial formation cycles.
    Type: Application
    Filed: November 16, 2009
    Publication date: December 13, 2012
    Inventors: Houxiang Tang, William J. Kruper, JR., Ravi B. Shankar, Deidre A. Strand, Peter M. Margl, Andrew J. Pasztor, JR., David R. Wilson, Jerey R. Stajdi
  • Publication number: 20120315550
    Abstract: The invention relates to a graphene-modified lithium iron phosphate positive electrode active material and a method for preparing the same, as well as a lithium-ion secondary cell based on this positive electrode active material. The positive electrode active material is prepared by a method in which graphene or graphene oxide and lithium iron phosphate are dispersed in an aqueous solution, agitated and ultrasonicated to mix homogeneously and for a mixture, dried to obtain a lithium iron phosphate material compounded with graphene or graphene oxide, and annealed at high temperature to obtain finally a graphene-modified lithium iron phosphate positive electrode active material. When compared with conventional modified lithium cells coated with carbon or doped with conductive polymers, the lithium-ion secondary cell based on this positive electrode active material features high cell capacity, good cycling performance of charge and discharge, long life and high cycle stability, and has great utility value.
    Type: Application
    Filed: January 22, 2010
    Publication date: December 13, 2012
    Applicant: Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences
    Inventors: Zhaoping Liu, Xufeng Zhou
  • Publication number: 20120315553
    Abstract: A non-aqueous liquid electrolyte secondary battery, including a cathode, an anode and a non-aqueous liquid electrolyte present between the cathode and the anode. The non-aqueous liquid electrolyte secondary battery has a closed structure in which the cathode, the anode and the non-aqueous liquid electrolyte are insulated from at least carbon dioxide and water. The non-aqueous liquid electrolyte secondary battery has a discharge voltage of 3V or less relative to a Li/Li+ reference electrode. The non-aqueous liquid electrolyte includes two or more kinds of anions, and a non-aqueous liquid electrolyte for the non-aqueous liquid electrolyte secondary battery.
    Type: Application
    Filed: February 22, 2010
    Publication date: December 13, 2012
    Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Fuminori Mizuno, Hirofumi Nakamoto, Kenichi Hamamoto
  • Publication number: 20120315551
    Abstract: Described herein are materials for use in electrolytes that provide a number of desirable characteristics when implemented within batteries, such as high stability during battery cycling up to high temperatures high voltages, high discharge capacity, high coulombic efficiency, and excellent retention of discharge capacity and coulombic efficiency over several cycles of charging and discharging. In some embodiments, a high voltage electrolyte includes a base electrolyte and a set of additive compounds, which impart these desirable performance characteristics.
    Type: Application
    Filed: April 30, 2012
    Publication date: December 13, 2012
    Applicant: WILDCAT DISCOVERY TECHNOLOGIES, INC.
    Inventors: Vinay V. BHAT, Gang CHENG, Steven KAYE, Bin LI, Risa OLUGBILE, Jen Hsien YANG
  • Publication number: 20120315511
    Abstract: The present invention relates to electrode materials for charged electrical cells, comprising at least one polymer comprising polysulfide bridges, and carbon in a polymorph comprising at least 60% sp2-hybridized carbon atoms. The present invention further relates to electrical cells comprising the inventive electrode material, to specific polymers comprising polysulfide bridges, to processes for preparation thereof and to the use of the inventive cells.
    Type: Application
    Filed: June 5, 2012
    Publication date: December 13, 2012
    Applicant: BASF SE
    Inventors: Oliver GRONWALD, Alexander Panchenko, Arnd Garsuch
  • Patent number: 8323839
    Abstract: A nonaqueous electrolyte secondary battery in which the decomposition of an electrolyte solution is reduced exhibits high coulombic efficiency and excellent charge and discharge cycle performance, and has high energy density. This nonaqueous electrolyte secondary battery includes a negative electrode that is formed by depositing a thin film of active material on a collector by a CVD method, sputtering, evaporation, thermal spraying, or plating, wherein the thin film of the active material can lithiate and delithiate and is divided into columns by cracks formed in the thickness direction, and the bottom of each column is adhered to the collector; a positive electrode that can lithiate and delithiate; and a nonaqueous electrolyte solution containing a lithium salt in a nonaqueous solvent. The electrolyte solution contains a compound expressed by a general formula (I).
    Type: Grant
    Filed: September 26, 2005
    Date of Patent: December 4, 2012
    Assignees: SANYO Electric Co., Ltd., Mitsubishi Chemical Corporation
    Inventors: Noriyuki Tamura, Toshikazu Yoshida, Maruo Kamino, Shin Fujitani, Masahiro Takehara, Makoto Ue
  • Patent number: 8318361
    Abstract: Disclosed is a composition for a gel polymer electrolyte, the composition comprising: (i) a cyclic compound as a first crosslinking agent, the cyclic compound containing a cyclic group at the center thereof and having at least three double bonds at the end thereof; (ii) a linear or branched compound as a second crosslinking agent, the linear or branched compound containing an oxyalkylene group at the center thereof and having at least two (meth)acryl groups at the end thereof; (iii) an electrolyte solvent; (iv) an electrolyte salt; and (v) a polymerization initiator. Also, disclosed are a gel polymer electrolyte formed by polymerizing the composition for a gel polymer electrolyte, and an electrochemical device comprising the gel polymer electrolyte.
    Type: Grant
    Filed: September 7, 2007
    Date of Patent: November 27, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Sung-Hoon Yu, Jeong-Ju Cho, Soo-Jin Kim, Soo-Hyun Ha
  • Patent number: 8318037
    Abstract: Disclosed are hydroxy terminated alkylsilane ethers with oligoethylene oxide substituents. They are suitable for use as electrolyte solvents and particularly well suited for use with aqueous environment electrolytic capacitors. Methods for synthesizing these compounds are also disclosed.
    Type: Grant
    Filed: April 30, 2010
    Date of Patent: November 27, 2012
    Assignee: Wisconsin Alumni Research Foundation
    Inventors: Robert C. West, Jose A. Pena Hueso
  • Patent number: 8308971
    Abstract: Described herein are materials for use in electrolytes that provide a number of desirable characteristics when implemented within batteries, such as high stability during battery cycling up to high temperatures high voltages, high discharge capacity, high coulombic efficiency, and excellent retention of discharge capacity and coulombic efficiency over several cycles of charging and discharging. In some embodiments, a high voltage electrolyte includes a base electrolyte and a set of additive compounds, which impart these desirable performance characteristics.
    Type: Grant
    Filed: April 30, 2012
    Date of Patent: November 13, 2012
    Assignee: Wildcat Discovery Technologies, Inc.
    Inventors: Vinay V. Bhat, Gang Cheng, Steven Kaye, Bin Li, Risa Olugbile, Jen-Hsien Yang
  • Publication number: 20120282531
    Abstract: An electrolyte for a rechargeable lithium battery includes a non-aqueous organic solvent, a lithium salt, and an additive. The additive includes a gamma butyrolactone compound substituted with at least one F atom at the ?-position.
    Type: Application
    Filed: September 22, 2011
    Publication date: November 8, 2012
    Inventors: Duck-Chul Hwang, Eun-Gi Shim, Jong-Hyun Lee, Jong-Su Kim, Young-Min Kim
  • Publication number: 20120282530
    Abstract: An energy storage device includes a first electrode comprising a first material and a second electrode comprising a second material, at least a portion of the first and second materials forming an interpenetrating network when dispersed in an electrolyte, the electrolyte, the first material and the second material are selected so that the first and second materials exert a repelling force on each other when combined. An electrochemical device, includes a first electrode in electrical communication with a first current collector; a second electrode in electrical communication with a second current collector; and an ionically conductive medium in ionic contact with said first and second electrodes, wherein at least a portion of the first and second electrodes form an interpenetrating network and wherein at least one of the first and second electrodes comprises an electrode structure providing two or more pathways to its current collector.
    Type: Application
    Filed: July 13, 2012
    Publication date: November 8, 2012
    Applicant: Massachusetts Institute of Technology
    Inventors: Yet-Ming Chiang, William Douglas Moorehead
  • Patent number: 8298709
    Abstract: A secondary battery capable of improving the cycle characteristics while securing the initial charge and discharge characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. The anode has an anode active material layer containing a plurality of anode active material particles having silicon (Si). The anode active material layer contains at least one of an oxide-containing film covering a surface of the anode active material particles and a metal material not being alloyed with an electrode reactant provided in a gap in the anode active material layer. The electrolytic solution contains a solvent containing an organic acid that has a portion including an electron attractive group such as —(O?)C—C(?O)— bond in the center and a hydroxyl group on the both ends.
    Type: Grant
    Filed: March 10, 2009
    Date of Patent: October 30, 2012
    Assignee: Sony Corporation
    Inventors: Masayuki Ihara, Hiroyuki Yamaguchi, Tadahiko Kubota
  • Patent number: 8288040
    Abstract: A battery that includes a cathode, anode and an electrolytic solution containing an organic electrolyte solvent including a compound of the formula: R1—CO—NR2—OR3 wherein R1 is selected from alkanes, alkenes, alkynes, aryls and their substituted derivatives and perfluorinated analogues; R2 is selected from alkanes, alkenes, alkynes, aryls and their substituted derivatives; R3 is selected from alkanes, alkenes, alkynes, aryls and their substituted derivatives wherein the electrolyte is stable at voltages of greater than 4.0 volts.
    Type: Grant
    Filed: February 17, 2009
    Date of Patent: October 16, 2012
    Assignees: Toyota Motor Engineering & Manufacturing North America, Inc., Toyota Motor Corporation, Synthonix Corporation
    Inventors: John Muldoon, Gary Allred, Scott Ankeney, Masaki Matsui, Anthony Dotse, Tsuyoshi Sugimoto
  • Publication number: 20120251896
    Abstract: An energy storage device includes a first electrode comprising a first material and a second electrode comprising a second material, at least a portion of the first and second materials forming an interpenetrating network when dispersed in an electrolyte, the electrolyte, the first material and the second material are selected so that the first and second materials exert a repelling force on each other when combined. An electrochemical device, includes a first electrode in electrical communication with a first current collector; a second electrode in electrical communication with a second current collector; and an ionicaily conductive medium in ionic contact with said first and second electrodes, wherein at least a portion of the first and second electrodes form an interpenetrating network and wherein at least one of the first and second electrodes comprises an electrode structure providing two or more pathways to its current collector.
    Type: Application
    Filed: May 15, 2012
    Publication date: October 4, 2012
    Applicant: Massachusetts Institute of Technology
    Inventors: Yet-Ming Chiang, William Douglas Moorehead
  • Publication number: 20120251895
    Abstract: An electrolyte for a lithium secondary battery, the electrolyte including a lithium salt, a non-aqueous organic solvent, and an additive represented by Formula 1 below: wherein CY1 and R1 through R7 are the same as defined above; and a lithium secondary battery containing the electrolyte
    Type: Application
    Filed: March 27, 2012
    Publication date: October 4, 2012
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Jun-young MUN, Yoon-sok Kang, Jin-hwan Park, Min-sik Park
  • Publication number: 20120251894
    Abstract: The inventors of the subject matter of the present disclosure have developed an electrolyte solution usable in a lithium or lithium-ion battery, among other types of batteries that offers one or more of the following: improved stability (e.g., stable discharge capacities even after several cycles), elimination of the risk of unintentionally producing hydrochloric acid, improved thermal stability, and reduced production costs associated with manufacturing a battery. Indeed, the inventors have discovered an unexpected result that by including an additive to a dinnimitride salt (e.g., LiDN), the discharge capacity of the battery may improve beyond what is available in the prior art, including LiPF6. For example, production costs may be decreased since LiDN is not water-sensitive, so precautions to ensure that the compound is not exposed to water may be avoided. Further benefits include thermal stability since LiDN may be more thermally stable when compared to LiPF6.
    Type: Application
    Filed: March 30, 2011
    Publication date: October 4, 2012
    Applicant: TOYOTA MOTOR ENGINEERING & MANUFACTURING NORTH AMERICA, INC.
    Inventors: Monique N. Richard, Alvaro Masias
  • Publication number: 20120251892
    Abstract: An electrolyte for a lithium secondary battery including a lithium salt, a nonaqueous organic solvent, and an additive, in which the additive is composed of one or more compounds including a purinone or a purinone derivative. The lithium secondary battery with improved life and high-temperature storage may be provided by using the electrolyte for a lithium secondary battery according to an embodiment of the present invention.
    Type: Application
    Filed: March 28, 2012
    Publication date: October 4, 2012
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Yoon-sok KANG, Jun-young Mun, Min-sik Park, Jin-hwan Park, Mi-jeong Song
  • Patent number: 8277973
    Abstract: A nonaqueous electrolyte composition containing an electrolyte salt, a nonaqueous solvent and a compound having a phosphorus-hydrogen bond or a phosphorus-carbon bond is provided. Also provided is a nonaqueous electrolyte secondary battery including: a cathode and an anode having a material capable of occluding and releasing lithium ions as a cathode active material and an anode active material, respectively; a nonaqueous electrolyte composition; a separator; and an outer package member for housing the anode, the cathode, the nonaqueous electrolyte composition and the separator. The nonaqueous electrolyte composition includes an electrolyte salt, a nonaqueous solvent and a compound having a phosphorus-hydrogen bond or a phosphorus-carbon bond.
    Type: Grant
    Filed: June 14, 2007
    Date of Patent: October 2, 2012
    Assignee: Sony Corporation
    Inventor: Atsumichi Kawashima
  • Publication number: 20120244445
    Abstract: In one aspect, a rechargeable lithium battery comprising a non-aqueous electrolyte including an organic solvent; a lithium salt and a substituted 2-fluoroalkoxy-1,3,2-dioxaphospholane 2-oxide is provided. The 2-fluoroalkoxy-1,3,2-dioxaphospholane 2-oxide can be a compound represented by the following Chemical Formula 1.
    Type: Application
    Filed: November 17, 2011
    Publication date: September 27, 2012
    Applicant: Samsung SDI Co., LTd.
    Inventors: Sang-Il Han, Woo-Cheol Shin, Jung-Yi Yu, Tae-Hyun Bae, Mi-Hyun Lee, Denis Chernyshov, Alexey Tereshchenko, Pavel Shatunov, Boris A. Trofimov, Nina K. Gusarova
  • Publication number: 20120237836
    Abstract: An electrolyte for a rechargeable lithium battery includes a first lithium salt; a second lithium salt including a compound represented by Chemical Formula 1, Chemical Formula 3-1 or 3-2, or combinations thereof; a non-aqueous organic solvent; and an additive including a compound represented by Chemical Formula 9.
    Type: Application
    Filed: January 31, 2012
    Publication date: September 20, 2012
    Inventor: Seung Mo Kim
  • Publication number: 20120237837
    Abstract: The present invention generally relates to electrochemical batteries, and more specifically, to the combined additives in the non-aqueous electrolyte for rechargeable lithium-ion batteries containing spinel-based cathode that may enhance the performance of the batteries. The mixed additives comprising of 1,8-bis(dialkylamino)naphthalene, wherein alky group is described by CnH2n+1, n=1 to 3, and vinylene carbonate (VC) are added to the electrolyte of the lithium-ion batteries greatly improve the capacity recovery and reduce AC impedance growth during the high temperature storage. The incorporation of the two kinds of additives within the electrolyte of the battery can also improve the high temperature cycling performance.
    Type: Application
    Filed: March 18, 2011
    Publication date: September 20, 2012
    Applicants: E-ONE MOLI ENERGY (CANADA) LIMITED, E-ONE MOLI ENERGY CORPORATION
    Inventors: Yong-Shou LIN, Li FENG
  • Patent number: 8268486
    Abstract: A positive electrode includes a current collector and a positive electrode active material layer. The positive electrode active material layer includes a positive electrode active material including a core including a compound LiaCO1-bMbO2 and a surface-treatment layer. In the core compound, 0.95?a?1.1, 0.002?b?0.02, and M is one or more elements selected from the group consisting of Mg, Ca, Sr, Ba, Ra, Sc, Y, Ti, Zr, Hf, Rf, V, Nb, Ta, Db, Cr, Mo, W, Sg, Tc, Re, Bh, Fe, Ru, Os, Hs, Rh, Ir, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, Tl, Si, Ge, Sn, P, As, Sb, Bi, S, Se, Te, Po. The surface-treatment layer includes a compound including element of P, and one or more elements selected from the group consisting of Mg, Ca, Sr, Ba, Ra, Sc, Y, Ti, Zr, Hf, Rf, V, Nb, Ta, Db, Cr, Mo, W, Sg, Tc, Re, Bh, Fe, Ru, Os, Hs, Rh, Ir, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, Tl, Si, Ge, Sn, As, Sb, Bi, S, Se, Te, Po.
    Type: Grant
    Filed: August 16, 2007
    Date of Patent: September 18, 2012
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Duck-Chul Hwang, Yong-Chul Park, Jeom-Soo Kim, Jae-Yul Ryu, Jong-Hwa Lee, Euy-Young Jung, So-Hyun Hur
  • Publication number: 20120231352
    Abstract: A lithium- or lithium-ion electrochemical cell of the present invention comprises a lithium-containing cathode, an anode, and a non-aqueous lithium-containing electrolyte therebetween; wherein one or more of the anode and/or the cathode comprises at least one particulate carbon material comprising nanoparticles of the surface of individual carbon particles, wherein the nanoparticles are selected from one or more of (a) a metal oxide or sulfide comprising one or more metal ions selected from the group consisting of Ti, Fe, Mn, Co, Ni, Mo, W, In, and Sn; (b) one or more metals selected from the group consisting of Ti, Fe, Co, Mg, Al, Ga, In, and Sn; and (c) one or more metaloid selected from the group consisting of B, Si, Ge, and Sb.
    Type: Application
    Filed: April 24, 2012
    Publication date: September 13, 2012
    Applicant: UCHICAGO ARGONNE, LLC
    Inventors: Vilas POL, Swati V. POL, Michael M. THACKERAY
  • Publication number: 20120231351
    Abstract: A positive active material for a rechargeable lithium battery including a lithium-nickel cobalt manganese composite metal oxide; and 0.18 to 0.25 wt % of sulfur is provided.
    Type: Application
    Filed: September 23, 2011
    Publication date: September 13, 2012
    Inventors: Suk-Chul Jung, Young-Chul You, Hak-Seok Kang, Heung-Min Oh, Young-Hoon Do, Tae-Jin Jung
  • Publication number: 20120224247
    Abstract: Stretchable electrochromic devices are disclosed including a stretchable electrochromic substrate; and a stretchable and transparent polymeric electrolyte coating or impregnating the stretchable electrochromic substrate. The stretchable electrochromic devices can find utility in the preparation of wearable electronic garments. Other devices using a stretchable and transparent polymeric electrolyte are disclosed.
    Type: Application
    Filed: January 31, 2012
    Publication date: September 6, 2012
    Inventors: Gregory A. Sotzing, Yujie Ding
  • Publication number: 20120225359
    Abstract: This invention described the preparation of a series of compounds selected from the group comprising tris(1,1,1,3,3,3-hexafluoro-iso-propyl)phosphate, tris(perfluoroethyl)phosphate, tris(perfluoro-iso-propyl)phosphate, bis(1,1,1-trifluoroethyl)fluorophosphate, tris(1,1,1-trifluoroethyl)phosphate, hexakis(1,1,1-trifluoroethoxy)phosphazene, tris(1,1,1-trifluoroethoxy)trifluorophosphazene, hexakis(perfluoro-t-butyl)phosphazene and tris(perfluoro-t-butyl)phosphate. These compounds may be used as co-solvents, solutes or additives in non-aqueous electrolytes in various electrochemical devices. The inclusion of these compounds in electrolyte systems can enable rechargeable chemistries at high voltages that are otherwise impossible with state-of-the-art electrolyte technologies. These compounds are chosen because of their beneficial effect on the interphasial chemistries formed at high potentials, such as 5.0 V class cathodes for new Li ion chemistries.
    Type: Application
    Filed: April 13, 2012
    Publication date: September 6, 2012
    Applicant: U.S. Government as represented by the Secretary of the Army
    Inventors: Kang Conrad Xu, Arthur von Wald Cresce
  • Publication number: 20120225346
    Abstract: According to one embodiment, a nonaqueous electrolyte battery is provided. The battery includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The positive electrode includes lithium iron phosphate having an olivine structure as positive electrode active material. The negative electrode includes lithium titanate having a spinel structure and a monoclinic ?-type titanium complex oxide as a negative electrode active material.
    Type: Application
    Filed: September 16, 2011
    Publication date: September 6, 2012
    Inventors: Keigo Hoshina, Hiroki Inagaki, Norio Takami
  • Publication number: 20120219868
    Abstract: The objective of the present invention is to prevent deterioration and expanding of anode active material and to improve charge-discharge cycle characteristics in a non-aqueous electrolyte secondary battery comprising an anode of which current collector has thereon a thin layer of an anode active material containing a metal. To solve this problem, in a non-aqueous electrolyte secondary battery wherein a thin layer of anode active material containing a metal which absorbs and discharges lithium is formed on a current collector and the thin layer of the anode active material is divided into columns by a gap formed along the thickness thereof, a compound represented by the following formula is contained in the non-aqueous electrolyte. A-N?C?O In the above formula, A represents an element or a group other than hydrogen.
    Type: Application
    Filed: May 3, 2012
    Publication date: August 30, 2012
    Applicants: Mitsubishi Chemical Corporation, SANYO Electric Co., Ltd.
    Inventors: Keiji SAISHO, Hidekazu Yamamoto, Masahiro Takehara
  • Publication number: 20120219867
    Abstract: A magnesium secondary battery includes a positive electrode, a negative electrode, a separator membrane and an electrolytic solution. The electrolytic solution includes nitrogen-containing heterocyclic magnesium halide and an organic ether solvent.
    Type: Application
    Filed: February 23, 2012
    Publication date: August 30, 2012
    Applicants: SHANGHAI JIAO TONG UNIVERSITY, TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Yanna NULI, Qingsong ZHAO, Jun YANG, Yongsheng GUO
  • Publication number: 20120214073
    Abstract: To provide a non-aqueous electrolyte solution for secondary batteries which has excellent compatibility even in a state where a lithium salt is dissolved therein and further has excellent nonflammability and cycle properties, and a secondary battery having such a non-aqueous electrolyte solution for secondary batteries. A non-aqueous electrolyte solution for secondary batteries, which comprise a lithium salt, a specific hydrofluoromonoether and a specific hydrofluoropolyether, and a secondary battery containing such a non-aqueous electrolyte solution for secondary batteries.
    Type: Application
    Filed: April 26, 2012
    Publication date: August 23, 2012
    Applicant: Asahi Glass Company, Limited
    Inventors: Masao Iwaya, Yu Onozaki
  • Publication number: 20120214072
    Abstract: The present invention concerns electrode materials capable of redox reactions by electron and alkali-ion exchange with an electrolyte. The applications are in the field of primary (batteries) or secondary electrochemical generators, supercapacitors and light modulating systems of the electrochromic type.
    Type: Application
    Filed: May 4, 2012
    Publication date: August 23, 2012
    Applicants: ACEP Inc., Universite De Montreal, CNRS
    Inventors: Nathalie Ravet, Simon Besner, Martin Simoneau, Alain Vallee, Michel Armand, Jean-Francois Magnan
  • Publication number: 20120208092
    Abstract: An amorphous anode active material, a preparation method of an electrode using the same, a secondary battery containing the same, and a hybrid capacitor are provided. The amorphous anode active material includes at least one of a metal oxide or a metal phosphate, and the metal oxide or the metal phosphate is amorphous. The metal oxide has the form of MOx (0<X?3). M is at least one of molybdenum (Mo), vanadium (V), scandium (Sc), titanium (Ti), chromium (Cr), yttrium (Y), zirconium (Zr), niobium (Nb) and tungsten (W). The metal phosphate has the form of AxBy(PO4) (0?x?2, 0<y?2). A is at least one of lithium (Li), sodium (Na) and potassium (K), and B is at least one of molybdenum (Mo), vanadium (V), scandium (Sc), titanium (Ti), chromium (Cr), yttrium (Y), zirconium (Zr), niobium (Nb) and tungsten (W).
    Type: Application
    Filed: August 12, 2010
    Publication date: August 16, 2012
    Applicant: SNU R&DB FOUNDATION
    Inventors: Jun-Hwan Ku, Kyung-Jin Park, Ji-Sun Kim, Ji-Heon Ryu, Seung-Mo Oh
  • Publication number: 20120202122
    Abstract: A rechargeable lithium battery including a negative electrode, a positive electrode, the positive electrode including a lithium manganese oxide represented by the following Chemical Formula 1a or 1b, and an electrolyte, the electrolyte including an alkylsilyl phosphate represented by the following Chemical Formula 2:
    Type: Application
    Filed: September 21, 2011
    Publication date: August 9, 2012
    Inventor: Su-Hee HAN
  • Publication number: 20120202124
    Abstract: Disclosed is a lithium secondary battery. The lithium secondary battery includes a cathode, an anode, a separator and a non-aqueous electrolyte solution. Either the cathode or the anode or both include metal oxide coating layers on electrode active material particles forming the electrode or a metal oxide coating layer on the surface of an electrode layer formed on a current collector. The non-aqueous electrolyte solution contains an ionizable lithium salt, an organic solvent, and a dinitrile compound having a specific structure. In the lithium secondary battery, degradation of the electrode is prevented and side reactions of the electrolyte solution are inhibited. Therefore, the lithium secondary battery exhibits excellent cycle life and output performance characteristics.
    Type: Application
    Filed: April 16, 2012
    Publication date: August 9, 2012
    Inventors: Jong-Ho JEON, Doo-Kyung Yang, Sung-Hoon Yu, Min-Hyung Lee
  • Publication number: 20120202125
    Abstract: The present invention discloses a rechargeable lithium battery including a positive electrode, a negative electrode including lithium titanate represented by Chemical Formula 1, and an electrolyte impregnating the positive and negative electrodes and including a sultone-based compound and maleic anhydride, wherein the sultone-based compound and the maleic anhydride are respectively included in an amount of about 0.5 wt % to about 5 wt % based on the total weight of the electrolyte. Chemical Formula 1: Li4?xTi5+x?yMyO12. In Chemical Formula 1, M is an element selected from Mg, V, Cr, Nb, Fe, Ni, Co, Mn, W, Al, Ga, Cu, Mo, P, or a combination thereof, 0?x?1, 0?y?1.
    Type: Application
    Filed: September 23, 2011
    Publication date: August 9, 2012
    Applicant: SAMSUNG SDI CO., LTD.
    Inventor: Su-Hee Han
  • Publication number: 20120196158
    Abstract: The present invention provides an electrolyte for electrochemical device and the electrochemical device thereof. The electrolyte comprises 9.95˜19.95 wt % of a salt; 80.0˜90.0 wt % of a non-aqueous solvent; 0.05˜10.00 wt % of an additive comprising a compound represented by below formula (I) or (II): wherein X1, R1, and R4˜R10 is defined as herein. Besides, the present invention also provides a method for enhancing cycle life of electrochemical device which accomplished by adding said additive to an electrolyte of electrochemical device.
    Type: Application
    Filed: January 18, 2012
    Publication date: August 2, 2012
    Applicant: TAIWAN HOPAX CHEMS. MFG. CO., LTD.
    Inventors: Chia-Chin CHANG, Li-Jane Her
  • Publication number: 20120196191
    Abstract: Disclosed is a lithium secondary battery. The lithium secondary battery includes a cathode, an anode, a separator and a non-aqueous electrolyte solution. The separator includes a porous substrate, and a coating layer coated on at least one surface of the porous substrate and including a mixture of inorganic particles and a binder polymer. The non-aqueous electrolyte solution contains an ionizable lithium salt, an organic solvent, and a dinitrile compound having a specific structure. The lithium secondary battery is very safe without side reactions of the electrolyte solution. Therefore, the lithium secondary battery exhibits excellent cycle life and output performance characteristics.
    Type: Application
    Filed: April 16, 2012
    Publication date: August 2, 2012
    Inventors: Jong-Ho JEON, Doo-Kyung Yang, Sung-Hoon Yu, Min-Hyung Lee
  • Publication number: 20120189921
    Abstract: A chemical source of electrical energy may include a positive electrode (cathode) made of an electrically conductive material, a mixture of lithium sulphide and sulphur, a permeable separator or membrane, and a negative electrode (anode) made of an electrically conductive material or a material that is able reversibly to intercalate lithium ions, wherein an aprotic electrolyte comprising at least one lithium salt in at least one solvent is provided between the electrodes.
    Type: Application
    Filed: April 2, 2012
    Publication date: July 26, 2012
    Inventors: Vladimir Kolosnitsyn, Elena Karaseva