Abstract: The present disclosure relates to a cathode for a lithium air battery and a method of manufacturing the same, and more particularly to a method of manufacturing a cathode for a lithium air battery, in which a hollow structure including a carbon material having a nitrogen functional group is synthesized through electrospinning of a thermally decomposable polymer, coating with a nitrogen-containing polymer and heat treatment, and is utilized without a binder as a cathode carbon material for a lithium air battery, thereby increasing the performance and lifespan of a lithium air battery.

Abstract: A zinc-air battery cell assembly comprising: a cathode can that includes: a planar base, and an elongated cathode sidewall that extends to a terminal cathode sidewall end, and an anode can that includes: a planar top end, and an elongated anode sidewall that extends to a terminal anode sidewall end, the anode can disposed nested within the cathode can with the elongated anode sidewall disposed parallel and adjacent to the elongated cathode sidewall. The zinc-air battery assembly further includes a cavity defined by the cathode can and the anode can disposed nested within the cathode can, and a grommet that provides a seal between the cathode can and the anode can while also keeping the anode can and the cathode can separate.

Abstract: Provided is a lithium secondary battery comprising a cathode, an anode, and an electrolyte or separator-electrolyte assembly disposed between the cathode and the anode, wherein the anode comprises: (a) An anode current collector, initially having no lithium or lithium alloy as an anode active material when the battery is made and prior to a charge or discharge operation; and (b) a thin layer of a high-elasticity polymer in ionic contact with the electrolyte and having a recoverable tensile strain from 2% to 700%, a lithium ion conductivity no less than 10?8 S/cm, and a thickness from 0.5 nm to 100 ?m. Preferably, the high-elasticity polymer contains a cross-linked network of polymer chains having an ether linkage, nitrile-derived linkage, benzo peroxide-derived linkage, ethylene oxide linkage, propylene oxide linkage, vinyl alcohol linkage, cyano-resin linkage, triacrylate monomer-derived linkage, tetraacrylate monomer-derived linkage, or a combination thereof in the cross-linked network of polymer chains.

Abstract: In an aspect, provided is an alkaline rechargeable battery comprising: i) a battery container sealed against the release of gas up to at least a threshold gas pressure, ii) a volume of an aqueous alkaline electrolyte at least partially filling the container to an electrolyte level; iii) a positive electrode containing positive active material and at least partially submerged in the electrolyte; iv) an iron negative electrode at least partially submerged in the electrolyte, the iron negative electrode comprising iron active material; v) a separator at least partially submerged in the electrolyte provided between the positive electrode and the negative electrode; vi) an auxiliary oxygen gas recombination electrode electrically connected to the iron negative electrode by a first electronic component, ionically connected to the electrolyte by a first ionic pathway, and exposed to a gas headspace above the electrolyte level by a first gas pathway.

Abstract: A lithium battery and method for fabricating the same are provided herein. The battery cathode comprises a carbon structure filled with a catalyst, such as palladium-catalyst-filled carbon nanotubes (CNTs). The carbon structure provides a barrier between the catalyst and the electrolyte providing an increased stability of the electrolyte during both discharging and charging of a battery.

Abstract: A metal-gas battery including: a battery core, gas container and a movable member. The battery core including a metal anode; a non-aqueous electrolyte; a porous cathode; and terminals for providing electrical power from the battery core. The gas container being configured to hold a pressurized gas. The movable member being configured to be movable from a non-activated position in which the pressurized gas in the container is sealed from entering the porous cathode and an activated position in which the pressurized gas flows into the porous cathode to activate the battery core.

Abstract: An air-metal secondary battery has an electrode including a porous carbon material, wherein the porous carbon material has a specific surface area of 280 m2/g or more, preferably 700 m2/g or more, more preferably 1,500 m2/g or more, as determined by a nitrogen BET method, and the air-metal secondary battery has an average charging voltage of 4.4 V or less, preferably 4.3 V or less, more preferably 4.1 V or less.

Abstract: A lithium ion conducting protective film is produced using a layer-by-layer assembly process. The lithium ion conducting protective film is assembled on a substrate by a sequential exposure of the substrate to a first poly(ethylene oxide) (PEO) layer including a cross-linking silane component on the first side of the substrate, a graphene oxide (GO) layer on the first PEO layer, a second poly(ethylene oxide) (PEO) layer including a cross-linking silane component on the GO layer and a poly(acrylic acid) (PAA) layer on the second PEO layer. The film functions as a lithium ion conducting protective film that isolates the lithium anode from the positive electrochemistry of the cathode in a lithium-air battery, thereby preventing undesirable lithium dendrite growth.

Abstract: A cathode of a metal-air battery includes an electrically conductive metal oxide in a three-dimensional (3D) network structure, wherein the electrically conductive metal oxide of the three-dimensional network structure is in a form of a plurality of strands, wherein a strand of the plurality of strands has an aspect ratio in a range of about 10 to about 107, and wherein the three-dimensional network structure has a porosity of about 70 volume percent to about 95 volume percent, based on a total volume of the three-dimensional network structure.

Abstract: Provided is a rechargeable lithium-air battery that improves charge-discharge energy efficiency and has good charge-discharge cycle performance. The rechargeable lithium-air battery includes: an air electrode including carbon; a negative electrode including metallic lithium or a lithium-containing substance; and an electrolyte in contact with the air electrode and the negative electrode. The electrolyte includes a salen-based metal complex and a quinone. The quinone includes any one or more of anthraquinone, 2,5-dihydroxy-1,4-benzoquinone, 7,7,8,8-tetracyanodimethane, 2,3-dichloro-5,6-dicyano-1,4-benzoquinone, tetrahydroxy-1,4-benzoquinone, and 2,5-di-tert-butyl-1,4-benzoquinone.

Abstract: A lithium air battery including a composite cathode including a porous material and a first solid electrolyte; a lithium metal anode; an oxygen blocking layer adjacent to the anode; and a cathode interlayer disposed between the cathode and the oxygen blocking layer, wherein the cathode interlayer includes a lithium ion conducting second solid electrolyte.

Abstract: A humic acid-bonded metal foil current collector in a battery or supercapacitor, comprising: (a) a thin metal foil having two opposed but parallel primary surfaces; and (b) a thin film of humic acid (HA) or a mixture of HA and graphene, having hexagonal carbon planes, wherein HA or both HA and graphene are chemically bonded to at least one of the two primary surfaces; wherein the thin film has a thickness from 10 nm to 10 ?m, an oxygen content from 0.01% to 10% by weight, an inter-planar spacing of 0.335 to 0.50 nm between hexagonal carbon planes, a physical density from 1.3 to 2.2 g/cm3, all hexagonal carbon planes being oriented substantially parallel to each other and parallel to the primary surfaces, exhibiting a thermal conductivity greater than 500 W/mK, and/or electrical conductivity greater than 1,500 S/cm when measured alone without the metal foil.

Abstract: A thin film electrode involving a nanostructured catalytic material deposited onto a surface of a conducting substrate and method of making is described. The nanostructured catalytic material contains cobalt oxide nanoflowers having a central core and nanopetals extending from the central core. The method of making the thin film electrode involves contacting the conducting substrate with an aerosol containing a cobalt complex and a solvent. A method of using the thin film electrode in an electrochemical cell for water splitting is also provided.

Abstract: While lithium-air batteries have been known, in which oxygen in the air is used as a positive electrode active material and lithium is used as a negative electrode active material, it is desired to provide a battery system capable of efficient utilization of oxygen. A battery system is provided, including: a lithium-oxygen battery; an oxygen compressing unit configured to compress oxygen released from the lithium-oxygen battery; a storage unit configured to store oxygen compressed by the oxygen compressing unit; and an oxygen supplying unit configured to supply oxygen stored in the storage unit to the lithium-oxygen battery.

Abstract: Provided is an all-solid-state sodium ion secondary battery in which a current collector is difficult to peel from an electrode layer and which can suppress the decreases in discharge capacity and discharge voltage.

Abstract: A composite cathode including: a cathode conductor layer including a mixed conductor; and a cathode junction layer adjacent to the cathode conductor layer, the cathode junction layer including a solid electrolyte, wherein the mixed conductor has a lithium-ion conductivity and an electrical conductivity, and wherein the solid electrolyte has a lithium-ion conductivity. In addition, the present disclosure provides a lithium-air battery including the composite cathode.

Abstract: An electrochemical device includes an air cathode using air as the cathodic gas; a discharge product of sodium peroxide dihydrate; an anode comprising sodium metal; a porous fiber separator; and a non-aqueous electrolyte comprising a sodium salt and a solvent.

Abstract: An object of the present invention is to improve the performance of a metal-air battery. The metal-air battery includes an air electrode, an anode, and an electrolyte sandwiched between the air electrode and the anode. The air electrode includes a co-continuous body having a three dimensional network structure formed by an integrated plurality of nanostructures having branches. A magnesium alloy is used for the anode, and a weak acidic salt containing no chloride ion or a salt considered to have a buffering capacity is used for the electrolyte. Consequently, the present invention can efficiently utilize electrons and suppress passivation and self corrosion of the anode, thereby improving the performance of the metal-air battery.

Abstract: A method for preparing a catalyst for a fuel cell including performing a first supporting; separating particles unsupported in the first supporting; heat treating; and performing a second supporting, and a catalyst for a fuel cell prepared using the same.

Abstract: State-of-the-art flow batteries suffer from drawbacks such as congestion of their electrodes, defects in liquid tightness, or shunt currents, all of which may lead to efficiency drop. Solution The problem is solved by a flow battery comprising multi-chambered ducts (100) mutually plugged together, each duct containing an integrated air electrode (111) and partition walls being partly ion-permeably perforated and partly impermeable, and nonconducting joining elements with integrated passages, the joining elements plugged bilaterally onto the ducts (100).

Abstract: A battery includes an electrode group including an air electrode and a negative electrode stacked with a separator therebetween, and a battery case accommodating the electrode group along with an alkali electrolyte solution, wherein the air electrode includes an air electrode mixture containing a pyrochlore-type composite oxide and a manganese oxide, and the pyrochlore-type composite oxide is a bismuth-ruthenium oxide.

Abstract: In the process of producing a lithium ion battery, one or more compounds of Formula 1, 2, 3 or 4 (e.g., N,N-dimethylpropionamide), is used as the solvent in the step of forming a slurry from an active material (e.g., lithium cobalt oxide), a conductive agent (e.g., carbon black), and a binder polymer (e.g., polyvinylidene fluoride).

Abstract: An all-solid lithium ion secondary battery has a pair of electrode layers and a solid electrolyte layer between the pair of electrode layers. In the all-solid lithium ion secondary battery, at least one electrode of the pair of electrodes has an active material layer and an intermediate layer on the surface of the active material layer on the side of the solid electrolyte layer, and each of the solid electrolyte layer, the intermediate layer, and the active material layer includes a compound containing Li and two or more shared types of metal elements other than Li, the two or more shared types of metal elements in the solid electrolyte layer, the intermediate layer, and the active material layer are identical between the solid electrolyte layer, the intermediate layer, and the active material layer.

Abstract: A metal-air battery includes a metal negative electrode (12), an oxygen-generating electrode placed on a surface of the metal negative electrode, and an air electrode placed on another surface of the metal negative electrode. The metal negative electrode includes at least a negative electrode active material layer facing the oxygen-generating electrode. A first separator placed in contact with the negative electrode active material layer is placed between the negative electrode active material layer and the oxygen-generating electrode.

Abstract: Methods of forming a battery include forming a thin graphene cathode on a substrate. A lithium anode is formed and an electrolyte is formed between the thin graphene cathode and the lithium anode.

Abstract: A fuel cell module includes: a cell stack apparatus including a cell stack including an array of a plurality of fuel cells, a manifold which feeds a fuel gas to each of the fuel cells, and a reformer which reforms a raw fuel; an oxygen-containing gas introduction plate which feeds an oxygen-containing gas to each of the fuel cells; and a housing which houses the cell stack apparatus and the oxygen-containing gas introduction plate. The housing includes a box having an open side and a lid which closes the open side of the box, and the box has a length of the open side which is greater than a maximum length of a projected plane of the cell stack apparatus as viewed from a lateral side of the cell stack apparatus.

Abstract: A lithium battery as a secondary battery includes a positive electrode composite material containing a solid electrolyte and a positive electrode active material containing lithium, a negative electrode as an electrode provided at one face of the positive electrode composite material, and a current collector provided at another face of the positive electrode composite material, wherein the solid electrolyte is a garnet-type fluorine-containing lithium composite metal oxide that is represented by the following compositional formula (1) or (2) and that conducts lithium. (Li7?3xGax)(La3?yNdy)Zr2O12?zFz ??(1) (Li7?3x+yGax)(La3?yCay)Zr2O12?zFz ??(2) Provided that 0.1?x?1.0, 0<y?0.2, and 0<z?1.0.

Abstract: A secondary battery recombination system includes catalyst and hydrophobic gas diffusion layers defining an electrode that recombines hydrogen and oxygen into water, and a scaffold encapsulating and in non-bonded contact with the electrode. The electrode may be carbon cloth, carbon felt, carbon foam, or carbon paper. The scaffold may be expanded metal or perforated foil.

Abstract: The present disclosure provides an electrochemical device system including an electrochemical device and a controller. The electrochemical device includes a negative electrode capable of occluding and releasing lithium ion, a positive electrode using oxygen as a positive electrode active material and reducing oxygen during discharge, and a solid electrolyte disposed between the negative electrode and the positive electrode and capable of conducting lithium ion. The controller performs current control during discharge of the electrochemical device.

Abstract: A method for manufacturing a composite electrode for a metal-air electrochemical cell with a liquid electrolyte of basic pH. A liquid solution comprising a fluoropolymer suspended in a solvent is synthesized, then deposited on the outer surface of a porous structure forming an air electrode. The fluoropolymer comprises SO2N groups suitable for conducting hydroxyl ions and is capable of forming a membrane impermeable to at least the liquid electrolyte of basic pH. When the liquid solution is applied to the porous structure, the solvent flows through the porous structure and the fluoropolymer is deposited by aggregating into a layer on the outer surface of the porous structure.

Abstract: A hybrid electrolyte includes: an inorganic solid electrolyte; and an organic electrolyte, wherein the organic electrolyte includes an organic salt including an organic cation and an organic anion, and the organic cation includes a halogen. An electrode and a solid-state secondary battery each includes the hybrid electrolyte.

Abstract: Compositions and process for optimizing oxygen reduction and oxygen evolution reactions are provided. Oxygen reduction and oxygen evolution catalysts include oxide compositions having a general formula a formula A2-xMOy, where x is electrochemically tuned to find optimal A content that delivers the best catalytic performance in a chemical system. The process provides the ability to find the optimal catalytic performance by tuning A and hence, the binding strength of O.

Abstract: An anode can include: an electrode substrate; a first region of the substrate having a catalyst composition located thereon, wherein the catalyst composition includes an inorganic or metallic catalyst; and a second region of the substrate having an enzyme composition located thereon, wherein the combination of the catalyst composition and enzyme composition converts a fuel reagent to carbon dioxide at neutral pH. The first region and second region can be separate regions. The catalyst of the catalyst composition can include gold nanoparticles. The catalyst can include an inorganic or metallic catalyst selected from vanadium oxide, titanium (III) chloride, Pd(OAc)2, MnO, zeolite, alumina, graphitic carbon, palladium, platinum, gold, ruthenium, rhodium, iridium, or combinations thereof. The catalyst can be nanoparticle, nanorod, nanodot, or combination thereof. The catalyst can have sizes that range from about 10 to 20 nm.

Abstract: An air supply indicator apparatus for indicating an amount of breathing air remaining in a cylinder, the apparatus including a housing member having a first side integrally formed with an attachment member, the attachment member configured to be detachably coupled to an emergency breathing safety system (EBSS) or universal emergency breathing safety system (UEBBS) and a second side form with an enclosure, an air status management status indicator having a plurality of indicator light sources disposed on the housing member, and a processor disposed within the enclosure, the processor coupled to the air status management status indicator and configured to emit light from the plurality of indicator light sources based on received signals corresponding to an amount of air remaining in a cylinder.

Abstract: The present invention provides a refrigeration and freezing device, including a case body, a door body, an oxygen-enrichment membrane assembly, an air pump, and a refrigeration system. For the refrigeration and freezing device, temperature within an appropriate storage range and a nitrogen-rich and oxygen-deficient atmosphere cooperate, thereby effectively extending the shelf life of foods.

Abstract: A lithium battery and method for fabricating the same are provided herein. The battery cathode comprises a carbon structure filled with a catalyst, such as palladium-catalyst-filled carbon nanotubes (CNTs). The carbon structure provides a barrier between the catalyst and the electrolyte providing an increased stability of the electrolyte during both discharging and charging of a battery.

Abstract: An electrochemical reaction unit cell including an electrolyte layer containing a solid oxide; a cathode and an anode which face each other in a first direction with the electrolyte layer intervening therebetween; and an intermediate layer disposed between the electrolyte layer and the cathode and containing a first cerium oxide. In the electrochemical reaction unit cell, the cathode includes an active layer containing a strontium-containing perovskite oxide, a second cerium oxide, sulfur, and strontium sulfate and having ion conductivity and electron conductivity, and a grain of the strontium sulfate covers at least a portion of the surface of a grain of the second cerium oxide.

Abstract: The present invention relates to a rechargeable battery, and a rechargeable battery including: a liquid cathode portion including a sodium-containing solution and a cathode current collector impregnated in the sodium-containing solution; an anode portion including a liquid organic electrolyte, an anode current collector impregnated in the liquid organic electrolyte, and an anode active material provided in the surface of the anode current collector; and a solid electrolyte provided between the cathode portion and the anode portion can be provided.

Abstract: Coatings for components of electrochemical cells (e.g., layers for protecting electrodes) are generally described. Associated compounds, articles, systems, and methods are also generally described.

Abstract: A battery employing lithium-oxygen chemistry may include an anode comprising lithium, an electrolyte, and a porous cathode. The electrolyte may include a lithium-containing salt; a partially fluorinated ether, such as 2,2-bis(trifluoromethyl)-1,3-dioxolane; and a co-solvent selected from the group consisting of ethers, amides, nitriles, and combinations thereof. In some examples, the electrolyte does not include a cyclic carbonate ester, a sulfolane, or a sulfolane derivative. The porous cathode allows oxygen to come into contact with the electrolyte.

Abstract: Provided are an air cell that has a reduced environmental impact and has favorable discharge characteristics as well as a patch equipped with the air cell. An air cell of the present invention includes, an outer case, which contains a positive electrode having a catalyst layer containing a catalyst and a binder, a negative electrode containing a metal material, a separator, and an electrolytic solution. The electrolytic solution is an aqueous solution with a pH of 3 or more and less than 12. The separator has an air permeability of 10 sec/100 ml or more, or the positive electrode has a porous sheet made of carbon as a current collector. A patch of the present invention includes the air cell of the present invention as a power supply.

Abstract: The present invention relates to a secondary battery and a method for supplementing an electrolyte of the secondary battery. The secondary battery according to the present invention comprises a battery case comprising an accommodation part accommodating an electrode and an electrolyte therein and a sealing member for additionally injecting the electrolyte, which is disposed on a portion of the battery case to additionally inject the electrolyte into the accommodation part of the battery case and seals an injection portion.

Abstract: A nickel-hydrogen battery includes a plurality of electrodes each including a current collector made of a metal, and disposed in a manner stacked in a first direction; a separator disposed between adjacent electrodes of the plurality of electrodes; a plurality of resin members disposed on peripheral portions of the plurality of electrodes to ensure a clearance between the adjacent electrodes; and a surface treatment layer covering one surface of the current collector at least in the peripheral portion of the plurality of electrode. The surface treatment layer includes a plurality of protrusions from the one surface. Widest parts of the protrusions are located above base ends thereof, and parts of the resin members are interposed between adjacent protrusions, across a range from tip ends to the base ends thereof.

Abstract: A zinc-air secondary battery includes an air positive electrode part, a separator, and a zinc gel negative electrode part. The zinc gel negative electrode part includes therein at least one middle layer made of mesh or foam. In a zinc-air secondary battery, oxygen discharging efficiency that is present in a zinc gel negative electrode part is high, and thus charging performance of the zinc-air secondary battery can be improved.

Abstract: A liquid electrolyte for a lithium metal battery comprises 45-65 mol % of an aprotic solvent, 5-15 mol % of an ionic liquid, 28-44 mol % of a lithium salt and up to 5 mol % additives. The aprotic solvent consists of one or more of a linear carbonate and a linear ether and the ionic liquid consists of one or more of PYR13FSI, PYR14FSI, PYR13TFSI, and PYR14TFSI. The lithium salt is selected from the group consisting of LiFSI, LiTFSI, and LiBET. The liquid electrolyte can have a flash point of greater than 60° C. and a dynamic viscosity of less than 120 mPa·s.

Abstract: A Li—O2 battery and method for fabricating the same are provided herein. The battery cathode comprises a carbon structure filled with a palladium nanoparticle catalyst, including palladium-filled carbon nanotubes (CNTs). The carbon structure provides a barrier between the catalyst and the electrolyte providing an increased stability of the electrolyte during both discharging and charging of a battery.

Abstract: Provided are a slurry for a solid electrolyte, which can reduce the usage of a polymer binder, a method for producing a solid electrolyte layer, and a method for producing an all-solid-state battery. Disclosed is a slurry for a solid electrolyte, the slurry comprising a solvent, a lithium compound, and crystal particles of a garnet-type ion-conducting oxide represented by a general formula (Lix?3y?z,Ey,Hz)L?M?O? (where E is at least one kind of element selected from the group consisting of Al, Ga, Fe and Si; L is at least one kind of element selected from an alkaline-earth metal and a lanthanoid element; M is at least one kind of element selected from a transition element that can be six-coordinated with oxygen and typical elements in groups 12 to 15 of the periodic table; 3?x?3y?z?7; 0?y?0.25; 0<z?2.8; 2.5???3.5; 1.5???2.5; and 11???13).

Abstract: An air electrode has a plurality of carbon nanotubes and a plurality of layered double hydroxide particles. The plurality of layered double hydroxide particles is supported on the plurality of carbon nanotubes.

Abstract: Provided are a slurry for a solid electrolyte, which can reduce the usage of a polymer binder, a method for producing a solid electrolyte layer, and a method for producing an all-solid-state battery. Disclosed is a slurry for a solid electrolyte, the slurry comprising a solvent, a lithium compound, and crystal particles of a garnet-type ion-conducting oxide represented by a general formula (Lix?3y?z,Ey,Hz)L?M?O? (where E is at least one kind of element selected from the group consisting of Al, Ga, Fe and Si; L is at least one kind of element selected from an alkaline-earth metal and a lanthanoid element; M is at least one kind of element selected from a transition element that can be six-coordinated with oxygen and typical elements in groups 12 to 15 of the periodic table; 3?x?3y?z?7; 0?y?0.25; 0<z?2.8; 2.5???3.5; 1.5???2.5; and 11???13).

Abstract: A rechargeable lithium air battery is provided. The battery contains a ceramic separator forming an anode chamber, a molten lithium anode contained in the anode chamber, an air cathode, and a non-aqueous electrolyte. The cathode has a temperature gradient comprising a low temperature region and a high temperature region, and the temperature gradient provides a flow system for reaction product produced by the battery.