With Specified Electrode Structure Or Material Patents (Class 429/405)
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Patent number: 8895197Abstract: The present application relates to an electrochemical metal-air cell in which a low temperature ionic liquid is used.Type: GrantFiled: May 10, 2010Date of Patent: November 25, 2014Assignee: Arizona Board of Regents for and on behalf of Arizona State UniversityInventors: Cody A. Friesen, Daniel A. Buttry
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Patent number: 8889312Abstract: An electrochemical device (such as a battery) includes at least one electrode having a fluid surface and one or more sensors configured to detect an operating condition of the device. Fluid-directing structures may modulate flow or retain fluid in response to the sensors. An electrolyte within the device may also include an ion-transport fluid, for example infiltrated into a porous solid support.Type: GrantFiled: June 17, 2010Date of Patent: November 18, 2014Assignee: The Invention Science Fund I, LLCInventors: Geoffrey F. Deane, Bran Ferren, William Gates, W. Daniel Hillis, Roderick A. Hyde, Muriel Y. Ishikawa, Edward K. Y. Jung, Jordin T. Kare, Nathan P. Myhrvold, Clarence T. Tegreene, David B. Tuckerman, Thomas Allan Weaver, Charles Whitmer, Lowell L. Wood, Victoria Y. H. Wood
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Publication number: 20140335429Abstract: A membrane electrode assembly includes a gas diffusion layer, a catalytic layer in fluid communication with the gas diffusion layer, an anodic layer and a bipolar solid electrolyte disposed between the catalytic and anodic layers. The bipolar solid electrolyte inhibits carbonate formation in air breathing alkaline cells and inhibits dendritic growth between the anodic and catalytic layers.Type: ApplicationFiled: May 10, 2013Publication date: November 13, 2014Applicant: Zinc Air Fuel Cells, Inc.Inventors: Ronald D. Brost, Kristine M. Brost, Howard F. Wilkins, Randolph M. Kosted, Paula J. Kosted, Adam Weisenstein, William A. Garcia, David Wilkins
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Patent number: 8883358Abstract: An object of the invention is to reduce the charging overvoltage by using a positive electrode member which does not contain a carbon material that causes the generation of lithium carbonate (Li2CO3), and which comprises a metal porous material, thereby suppressing the formation of lithium carbonate (Li2CO3). The metal air secondary battery of the invention is characterized by having a negative electrode member which has metal ions occluded therein and emits metal ions, a positive electrode member which ionizes oxygen, and a separator which is impregnated with an electrolyte and disposed between the negative electrode member and the positive electrode member, wherein the carbon weight in the total weight of a carrier, a catalyst, and a binder constituting the positive electrode member is 50% or less.Type: GrantFiled: July 2, 2010Date of Patent: November 11, 2014Assignee: Hitachi, Ltd.Inventors: Shin Takahashi, Kazuhiro Yoshida, Kazushige Kohno
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Publication number: 20140318106Abstract: A metal-gas battery that utilizes an exhaust gas stream from a combustion engine as reactive gases is provided. Almost constant concentration of exhaust gases are supplied to the metal-gas battery via an existing engine systematic combustion system. The systematic combustion system keeps a definite air fuel mixture (A/F) that acts to enhance the fuel efficiency of the vehicle, and the metal-gas battery leverages the existing vehicle air management system. Exhaust heat of the exhaust gases is sometimes utilized for the heat control of the vehicle, and then the cooled exhaust gases are introduced into the metal-air battery to be consumed during a cathode reduction reaction to create and store electrical energy. The metal-gas battery supports the cleaning of exhausted gases using existing emission catalysts.Type: ApplicationFiled: April 29, 2013Publication date: October 30, 2014Applicant: Toyota Motor Engineering & Manufacturing North America, Inc.Inventors: Fuminori Mizuno, Paul T. Fanson
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Patent number: 8871394Abstract: A metal-air battery according to the present disclosure includes an electrode assembly with a first electrode layer having a length and being folded lengthwise, and a gas diffusion layer having a length that is approximately half the length of the first electrode layer. Furthermore, the gas diffusion layer is positioned proximate the first electrode layer or between first and second portions of the first electrode layer.Type: GrantFiled: March 7, 2014Date of Patent: October 28, 2014Assignee: ZAF Energy Systems, IncorporatedInventors: William A. Garcia, Howard F. Wilkins
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Publication number: 20140315106Abstract: An air battery includes a cathode layer and an anode layer sandwiching an electrolyte layer, and an electrically insulative outer case. The cathode layer has a cathode member, a cathode current collector and a liquid tight/gas permeable member. The cathode layer is provided with a contact member between the outer case and the cathode layer, in which the inner end thereof is in contact with the periphery of the cathode current collector, and the outer end thereof is exposed on a cathode-side surface. The outer end of the contact member protrudes outward with respect to a surface of the liquid tight/gas permeable member to an extent reaching at least a plane including an end face of the outer case. Therefore, this air battery can be directly connected to another battery in series, and is suitable for an on-vehicle power source.Type: ApplicationFiled: October 30, 2012Publication date: October 23, 2014Applicant: Nissan Motor Co., Ltd.Inventors: Atsushi Miyazawa, Mori Nagayama, Yoshiko Tsukada, Nobutaka Chiba
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Publication number: 20140315107Abstract: Provided is a metal-air battery which has higher discharge capacity than conventional metal-air batteries. The present invention is a metal-air battery, which comprises a positive electrode layer, a negative electrode layer and an electrolyte layer that is arranged between the positive electrode layer and the negative electrode layer, and wherein the positive electrode layer contains a carbon material and is provided with two or more through holes that penetrate the positive electrode layer in the thickness direction.Type: ApplicationFiled: December 9, 2011Publication date: October 23, 2014Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Yutaka Hirose
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Publication number: 20140315105Abstract: This invention relates to a cathode for a lithium-air battery, a method of manufacturing the same and a lithium-air battery including the same. The method of manufacturing the cathode for a lithium-air battery includes 1) stirring a cobalt salt, triethanolamine and distilled water, thus preparing a cobalt solution, 2) electroplating the cobalt solution on a porous support, thus preparing a cobalt plated porous support, 3) reacting the cobalt plated porous support with a mixture solution including oxalic acid, water and ethanol, thus forming cobalt oxalate on the porous support, and 4) thermally treating the cobalt oxalate.Type: ApplicationFiled: August 14, 2013Publication date: October 23, 2014Applicant: Korea Institute of Energy ResearchInventors: JONG-WON LEE, Kyu-Nam Jung, Kyung-Hee Shin, Rak-Hyun Song, Seok-Joo Park, Seung-Bok Lee, Tak-Hyoung Lim, Su-Keun Yoon, Ahmer Riaz
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Patent number: 8865361Abstract: An electrochemical device (such as a battery) includes at least one electrode having a fluid surface and one or more sensors configured to detect an operating condition of the device. Fluid-directing structures may modulate flow or retain fluid in response to the sensors. An electrolyte within the device may also include an ion-transport fluid, for example infiltrated into a porous solid support.Type: GrantFiled: February 16, 2010Date of Patent: October 21, 2014Assignee: The Invention Science Fund I, LLCInventors: Geoffrey F. Deane, Bran Ferren, William Gates, W. Daniel Hillis, Roderick A. Hyde, Muriel Y. Ishikawa, Edward K. Y. Jung, Jordin T. Kare, Nathan P. Myhrvold, Clarence T. Tegreene, David B. Tuckerman, Thomas Allan Weaver, Charles Whitmer, Lowell L. Wood, Victoria Y. H. Wood
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Publication number: 20140308592Abstract: A method of manufacturing a dispersion liquid for an electrode catalyst, the method comprising a step of supporting a precious metal on the surface of a carrier by an electrodeposition process using a raw material mixed solution in which a particulate carrier is dispersed in a solvent and a compound including the precious metal element is dissolved in the solvent, wherein the carrier has oxygen reduction capability and is free of precious metal elements.Type: ApplicationFiled: September 5, 2012Publication date: October 16, 2014Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Hajime Maki, Yutaka Ito, Yoshinari Sawabe, Kenichiro Ota
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Publication number: 20140308593Abstract: A cell system using air as a positive-electrode active material and a metal substance as a negative-electrode active material includes a thin film of the metal substance, a pair of reels, each end being connected to the thin film, an electrode positioned in a vicinity of a path of the thin film between each of the reels, and a molten solution that is positioned downstream of the electrode and melts the metal substance oxidized when power is generated. The metal substance may include, for example, magnesium, aluminum, zinc, lithium and iron, the electrode may include a copper electrode, and the molten solution may include a hydrochloric acid solution, a sulfuric acid solution and an acetic acid solution. The cell system includes the pair or reels to which the thin film is connected, where the pair of reels may be configured by a cartridge type.Type: ApplicationFiled: December 28, 2011Publication date: October 16, 2014Applicant: YABE SCIENCE PROMOTION LLCInventor: Setsuko Yabe
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Publication number: 20140308594Abstract: A cathode for a metal air battery includes a cathode structure having pores. The cathode structure has a metal side and an air side. The porosity decreases from the air side to the metal side. A metal air battery and a method of making a cathode for a metal air battery are also disclosed.Type: ApplicationFiled: April 11, 2013Publication date: October 16, 2014Inventors: Nancy J. DUDNEY, James W. KLETT, Jagjit NANDA, Chaitanya Kumar NARULA, Sreekanth PANNALA
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Publication number: 20140308591Abstract: An alkali metal-oxygen cell includes a negative electrode, an oxygen electrode, and a separator configured to conduct alkali metal ions. To improve the cycling stability of the negative electrode and also the cycling stability, the life, the high-current loading capability, the pulse loading capability and the safety behavior of the cell, the negative electrode includes at least one alkali metal titanate. In particular the at least one alkali metal titanate is one into or from which an alkali metal can reversibly be intercalated and deintercalated.Type: ApplicationFiled: March 20, 2014Publication date: October 16, 2014Applicants: Samsung SDI Co., Ltd., Robert Bosch GmbHInventors: Ulrich Alkemade, Thomas Wöhrle, Joachim Fetzer
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Publication number: 20140302407Abstract: This invention proposes metal complexes of polyphenylenediamines as the precursors of carbonized materials used as air electrode catalysts. Method of production includes mixing phenylenediamine monomer with a catalyst carrier in a solvent and adding an oxidant with metal salt to produce a metal complex of polyphenylenediamine. After drying the precursor is heat treated in the temperature range 400° C.-1000° C.° in nitrogen. Then the catalyst is leached and heat treated once again. In a modified procedure the heat treatment is carried out in air while leaching and subsequent thermal treatment are eliminated. The catalyst has demonstrated high performance and stability as the component of the air electrode of a metal-air battery.Type: ApplicationFiled: March 6, 2014Publication date: October 9, 2014Applicant: Panisolar IncInventors: Iakov Kogan, Anna Khomenko
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Publication number: 20140295293Abstract: Provided is an electrode that contributes to higher performance improvement of batteries and capacitors by selecting a dispersant not only for uniformalizing an electrode structure but also playing the performance improvement role for the batteries or capacitors. An electrode 1 includes an active material 2 and a conductive additive 3. The electrode 1 also includes a dispersant 5, and the dispersant 5 is adsorbed onto the surfaces of the conductive additive 3 and the active material 2. More preferably, the electrode 1 includes the dispersant 5 having at least one kind selected from a group consisting of molecular structures, atoms, and ions which acts as a charge transfer medium, and most preferably, the electrode 1 includes the dispersant 5 having the same charge as the charge transfer medium contained in the active material 2.Type: ApplicationFiled: March 24, 2014Publication date: October 2, 2014Applicant: HONDA MOTOR CO., LTD.Inventors: Hidefumi NIKAWA, Toshio TOKUNE
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Publication number: 20140295294Abstract: A lithium air battery 1 includes: a cathode 11 in which oxygen is used as a cathode active material; an anode 12 that has an anode active material capable of storing and releasing lithium ions; and an electrolytic solution that is held between the cathode 11 and the anode 12, in which the electrolytic solution includes a solvent represented by the following formula (1): (wherein x represents an integer of 1 to 3; m and n each independently represent an integer of 1 to 2x+1, a and b each independently represent an integer of 0 to 2, and m+n+a+b?3).Type: ApplicationFiled: March 26, 2014Publication date: October 2, 2014Applicant: HONDA MOTOR CO., LTD.Inventor: Mahito CHIBA
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Publication number: 20140295297Abstract: A storage element for a solid electrolyte energy store and a method of producing a storage element are provided. The storage element has a three-dimensional grid structure made of a material that comprises an electron-conducting redox pair.Type: ApplicationFiled: October 17, 2012Publication date: October 2, 2014Applicant: SIEMENS AKTIENGESELLSCHAFTInventors: Carsten Schuh, Thomas Soller
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Publication number: 20140295295Abstract: A rechargeable electrochemical battery cell includes a molten carbonate salt electrolyte whose anion transports oxygen between a metal electrode and an air electrode on opposite sides of the electrolyte, where the molten salt electrolyte is retained inside voids of a porous electrolyte supporting structure sandwiched by the electrodes, and the molten salt includes carbonate including at least one of the alkaline carbonate including Li2Co2, NA2CO2, and K2CO2, having a melting point between 400° C. and 800° C.Type: ApplicationFiled: November 2, 2012Publication date: October 2, 2014Inventor: Chun Lu
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Publication number: 20140295296Abstract: There is provided a lithium-air secondary cell having an air electrode, a negative electrode containing metal lithium or a lithium-containing material and a gel-form solid electrolyte, wherein the gel-form solid electrolyte contains a solid electrolyte salt, a solvent, and a specific lipid peptide-type gelator composed.Type: ApplicationFiled: October 12, 2012Publication date: October 2, 2014Inventors: Tatsumi Ishihara, Shigeru Mitsui, Nobuhide Miyachi
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Publication number: 20140295298Abstract: Some batteries can exhibit greatly improved performance by utilizing electrodes having randomly arranged graphene nanosheets forming a network of channels defining continuous flow paths through the electrode. The network of channels can provide a diffusion pathway for the liquid electrolyte and/or for reactant gases. Metal-air batteries can benefit from such electrodes. In particular Li-air batteries show extremely high capacities, wherein the network of channels allow oxygen to diffuse through the electrode and mesopores in the electrode can store discharge products.Type: ApplicationFiled: May 6, 2014Publication date: October 2, 2014Applicant: BATTELLE MEMORIAL INSTITUTEInventors: Jiguang Zhang, Jie Xiao, Jun Liu, Wu Xu, Xiaolin Li, Deyu Wang
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Patent number: 8846256Abstract: A selectively oxygen-permeable substrate has a magnetic material dispersion layer having carbon as the main component and a magnetic material dispersed therein. The magnetic material dispersion layer has a gas introduction face for introducing gas into the inside thereof, and the magnetic material dispersion layer is preferably a layer where a magnetic material is dispersed in a porous carbon membrane and can be used as a substrate for a metal-air battery positive electrode. More preferably, the selectively oxygen-permeable substrate has the magnetic material dispersion layer and a porous substrate. A selectively oxygen-permeable substrate can selectively introduce oxygen in the air and have high durability against an electrolytic solution.Type: GrantFiled: July 18, 2012Date of Patent: September 30, 2014Assignee: NGK Insulators, Ltd.Inventor: Toshihiro Tomita
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Publication number: 20140272610Abstract: An active material composition includes a porous graphene nanocage and a source material. The source material may be a sulfur material. The source material may be an anodic material. A lithium-sulfur battery is provided that includes a cathode, an anode, a lithium salt, and an electrolyte, where the cathode of the lithium-sulfur battery includes a porous graphene nanocage and a sulfur material and at least a portion of the sulfur material is entrapped within the porous graphene nanocage. Also provided is a lithium-air battery that includes a cathode, an anode, a lithium salt, and an electrolyte, where the cathode includes a porous graphene nanocage and where the cathode may be free of a cathodic metal catalyst.Type: ApplicationFiled: March 12, 2013Publication date: September 18, 2014Applicant: UCHICAGO ARGONNE, LLCInventors: Khalil Amine, Jun Lu, Peng Du, Jianguo Wen, Larry A. Curtiss
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Publication number: 20140272611Abstract: In one embodiment, a metal/oxygen battery with an oxygen management system includes a negative electrode, a positive electrode, a separator positioned between the negative electrode and the positive electrode, a first oxygenated gas supply reservoir, a compressor with an outlet fluidly coupled to the first oxygenated gas supply reservoir, and a valve and pressure regulator fluidly coupled to the first oxygenated gas supply reservoir and to the positive electrode and configured to place the first oxygenated gas supply reservoir in fluid communication with the positive electrode during a discharge cycle, and place the positive electrode in fluid communication with an inlet of the compressor during a charge cycle.Type: ApplicationFiled: July 26, 2013Publication date: September 18, 2014Applicant: Robert Bosch GmbHInventors: Paul Albertus, John F. Christensen, Boris Kozinsky
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Patent number: 8835060Abstract: Silicon-oxygen batteries comprising a silicon anode as chemical fuel, an air-cathode for dissociating oxygen, and an electrolyte, and applications using the same are provided. The silicon-batteries may utilize air for generating oxygen.Type: GrantFiled: February 11, 2010Date of Patent: September 16, 2014Assignees: Technion Research & Development Foundation Limited, The Penn State Research FoundationInventors: Yair Ein-Eli, Digby Donald MacDonald
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Patent number: 8835061Abstract: There is provided a metal oxygen battery which uses an oxygen-storing material containing YMnO3 as a positive electrode material, and can reduce the discharge overpotential. The metal oxygen battery 1 has a positive electrode 2 to which oxygen is applied as an active substance, a negative electrode 3 to which metallic lithium is applied as an active substance, and an electrolyte layer 4 interposed between the positive electrode 2 and the negative electrode 3. The positive electrode 2 contains, as an oxygen-storing material, a composite metal oxide obtained by crushing and mixing a yttrium salt, a manganese salt and an organic acid, primarily calcining the mixture, and thereafter, adding a zirconium salt to the obtained primarily calcined material, and secondarily calcining the mixture, the composite metal oxide containing YMnO3 and ZrO2.Type: GrantFiled: July 4, 2012Date of Patent: September 16, 2014Assignee: Honda Motor Co., Ltd.Inventors: Satoshi Nakada, Yuji Isogai, Kiyoshi Tanaami, Takuya Taniuchi, Taichi Goto
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Publication number: 20140255801Abstract: An electrode, in particular a gas diffusion electrode, for a metal-oxygen battery. To achieve an improved performance output, e.g., an improved energy density or an improved capacity, the electrode includes a porous carrier substrate on which a porous active material is situated, the electrode having a gradient of medium pore sizes between the carrier substrate and the active material. Also described is an energy store including the electrode as described.Type: ApplicationFiled: June 15, 2012Publication date: September 11, 2014Inventors: Timm Lohmann, Sebastian Maass, Ralf Liedtke
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Publication number: 20140255799Abstract: A lithium-air battery cathode having increased mesopore and macropore volume and methods of making the cathode are provided. In at least one embodiment, a plurality of mesopores is present in the cathode having a porosity of 1 to 70 percent. In another embodiment, a plurality of macropores are present in the cathode having a porosity of 5 to 99 percent. In one embodiment, the mesopores and macropores are imprinted using a sacrificial material. In another embodiment, the mesopores and macropores are imprinted by applying a template. In another embodiment, the mesopores and macropores are formed by coating cathode material onto a porous substrate.Type: ApplicationFiled: March 8, 2013Publication date: September 11, 2014Applicant: FORD GLOBAL TECHNOLOGIES, LLCInventors: Venkataramani Anandan, Andrew Robert Drews
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Publication number: 20140255802Abstract: The present invention relates to a lithium-air battery including: a negative electrode containing a negative-electrode active material; a positive electrode using oxygen as a positive-electrode active material; and an electrolyte medium arranged between the negative electrode and the positive electrode; wherein the electrolyte medium includes as primary solvent one or more compounds having an —N—CO— group in the molecule.Type: ApplicationFiled: October 10, 2011Publication date: September 11, 2014Applicants: TOYOTA MOTOR EUROPE NV/SA, THE UNIVERSITY COURT OF THE UNIVERSITY OF ST ANDREInventors: Fanny Jeanne Julie Barde, Peter George Bruce, Yuhui Chen, Stefan Freunberger
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Publication number: 20140255800Abstract: A positive electrode for a lithium air battery includes a current collector, and a positive electrode catalyst layer on the current collector. The positive electrode catalyst layer includes a first conductive material supported on a binder, a second conductive material on the first conductive material, and a catalyst supported on the second conductive material.Type: ApplicationFiled: November 5, 2013Publication date: September 11, 2014Applicant: Samsung SDI Co., Ltd.Inventor: In KIM
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Publication number: 20140255803Abstract: The present disclosure discloses graphene supported bifunctional catalysts and metal-air batteries comprising the same. In one aspect, a metal-air battery comprises a metal anode, a cathode, an electrolyte disposed between the metal anode and the cathode, and a catalyst on the cathode. The catalyst reduces both the charge overpotential and discharge overpotential of the battery. The catalyst is disposed on a graphene support.Type: ApplicationFiled: October 9, 2012Publication date: September 11, 2014Applicant: WAYNE STATE UNIVERSITYInventors: K. Y. Simon Ng, Steve O. Salley, Kapila Wadumesthrige
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Publication number: 20140255798Abstract: A cathode includes a carbon material having a surface, the surface having a first thin layer of an inert material and a first catalyst overlaying the first thin layer, the first catalyst including metal or metal oxide nanoparticles, wherein the cathode is configured for use as the cathode of a lithium-air battery.Type: ApplicationFiled: March 6, 2013Publication date: September 11, 2014Applicant: UCHICAGO ARGONNE LLCInventors: Khalil Amine, Jun Lu, Peng Du, Yu Lei, Jeffrey W. Elam
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Publication number: 20140248544Abstract: This disclosure relates generally to cathode materials for electrochemical energy cells, more particularly to metal/air electrochemical energy cell cathode materials containing silver vanadium oxide and methods of making and using the same. The metal/air electrochemical energy cell can be a lithium/air electrochemical energy cell. Moreover the silver vanadium oxide can be a catalyst for one or more of oxidation and reduction processes of the electrochemical energy cell.Type: ApplicationFiled: February 7, 2014Publication date: September 4, 2014Inventors: Weibing Xing, Joshua Buettner-Garrett
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Patent number: 8822088Abstract: A power storage device which has high charge/discharge capacity and less deterioration in battery characteristics due to charge/discharge and can perform charge/discharge at high speed is provided. A power storage device includes a negative electrode. The negative electrode includes a current collector and an active material layer provided over the current collector. The active material layer includes a plurality of protrusions protruding from the current collector and a graphene provided over the plurality of protrusions. Axes of the plurality of protrusions are oriented in the same direction. A common portion may be provided between the current collector and the plurality of protrusions.Type: GrantFiled: September 12, 2012Date of Patent: September 2, 2014Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Ryota Tajima, Shunpei Yamazaki, Teppei Oguni, Takeshi Osada, Shinya Sasagawa, Kazutaka Kuriki
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Patent number: 8822087Abstract: The present invention is to provide a metal-air battery which can inhibit decrease of discharge capacity and increase of battery's internal resistance caused by the repeated charge and discharge. The metal-air battery comprises: a cathode; an electrolyte layer; and an anode, wherein the cathode, the electrolyte layer, and the anode are laminated in the order mentioned; the cathode comprises a plurality of cathode material layers arranged at intervals; and the direction for laminating the cathode, the electrolyte layer, and the anode intersect with the array direction of the plurality of cathode material layers.Type: GrantFiled: October 30, 2008Date of Patent: September 2, 2014Assignee: Toyota Jidosha Kabushiki KaishaInventors: Yukinari Kotani, Fuminori Mizuno
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Patent number: 8815443Abstract: Dry process based energy storage device structures and methods for using a dry adhesive therein are disclosed.Type: GrantFiled: March 10, 2010Date of Patent: August 26, 2014Assignee: Maxwell Technologies, Inc.Inventors: Porter Mitchell, Xiaomei Xi, Linda Zhong, Bin Zou
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Publication number: 20140234731Abstract: A metal/air electrochemical cell in one embodiment includes a negative electrode, a positive electrode, an oxygen supply, and a closed oxygen conducting membrane less than about 50 microns thick located between the oxygen supply and the positive electrode.Type: ApplicationFiled: June 19, 2013Publication date: August 21, 2014Inventors: Timm Lohmann, John F. Christensen, Boris Kozinsky, Paul Albertus, Roel Sanchez-Carrera
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Publication number: 20140234733Abstract: An air battery cathode including an organic-inorganic composite material including lyophobic nanopores, the organic-inorganic composite material including a porous metal oxide, and a lyophobic layer on a surface of a pore of the porous metal oxide and having a contact angle of greater than about 90°; and a binder. Also a lithium air battery including the cathode, and a method of manufacture the cathode.Type: ApplicationFiled: February 20, 2014Publication date: August 21, 2014Applicant: Samsung Electronics Co., Ltd.Inventors: Victor ROEV, Dong-min IM, Sang-bok MA, Won-sung CHOI, Min-sik PARK, Dong-joon LEE
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Publication number: 20140234732Abstract: Provided is an anode for a lithium secondary battery capable of improving the performance and the life of a lithium air battery by forming the anode so that lithium metal is sealed, but migration of lithium ions is possible, and thus, preventing corrosion of a lithium metal and the generation of hydrogen gas caused by permeation of moisture and oxygen gas into the anode, a manufacturing method thereof, and a lithium air battery containing the same.Type: ApplicationFiled: February 19, 2014Publication date: August 21, 2014Applicant: SK INNOVATION CO., LTD.Inventors: Myounggu PARK, Kyongsik KIM, Seongho CHUN, Heeyoung SUN, Sangjin KIM, Sangwon YOON
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Patent number: 8808930Abstract: Provided are a liquid air electrode for a metal-air battery that has superior discharge capacity and includes an electrolyte solution and an electrically conductive material, the electrically conductive material being dispersed in the electrolyte solution, and a metal-air battery that includes the liquid air electrode.Type: GrantFiled: August 12, 2011Date of Patent: August 19, 2014Assignee: Toyota Jidosha Kabushiki KaishaInventors: Fuminori Mizuno, Yukinari Kotani, Kenichi Hamamoto
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Patent number: 8808929Abstract: An electrochemical cell comprising an electrolyte comprising water and a hydrophobic ionic liquid comprising positive ions and negative ions. The electrochemical cell also includes an air electrode configured to absorb and reduce oxygen. A hydrophilic or hygroscopic additive modulates the hydrophobicity of the ionic liquid to maintain a concentration of the water in the electrolyte is between 0.001 mol % and 25 mol %.Type: GrantFiled: April 13, 2011Date of Patent: August 19, 2014Inventors: Cody A. Friesen, Ramkumar Krishnan, Toni Tang, Derek Wolfe
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Patent number: 8802303Abstract: Implementations and techniques for metal air batteries including a composite anode are generally disclosed.Type: GrantFiled: October 16, 2013Date of Patent: August 12, 2014Assignee: Empire Technology Development LLCInventors: Ezekiel Kruglick, Thomas Yager, Seth Adrian Miller
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Patent number: 8802304Abstract: Performance, properties and stability of bifunctional air electrodes may be improved by using modified current collectors, and improving water wettability of air electrode structures. This invention provides information on creating non-corroding, electrically rechargeable, bifunctional air electrodes. In some embodiments, this bifunctional air electrode includes a corrosion-resistant outer layer and an electrically conductive inner layer. In some embodiments, this bifunctional air electrode includes titanium suboxides formed by reducing titanium dioxide. Titanium suboxides may be corrosion-resistant and electrically conductive.Type: GrantFiled: August 10, 2010Date of Patent: August 12, 2014Assignee: Eos Energy Storage, LLCInventors: Steven Amendola, Michael Binder, Phillip J. Black, Stefanie Sharp-Goldman, Lois Johnson, Michael Kunz, Michael Oster, Tesia Chciuk, Regan Johnson
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Publication number: 20140220458Abstract: The invention provides magnesium fuel cells which can prevent the self-discharge of negative electrode materials and can produce electricity stably for a long term. A magnesium fuel cell includes a negative electrode material including a magnesium alloy, and an electrolytic solution for eluting magnesium ions from the negative electrode material. The magnesium alloy contains aluminum and calcium. The electrolytic solution is preferably an aqueous sodium chloride solution, an aqueous sodium hydroxide solution, an aqueous sodium hydrogencarbonate solution, an aqueous sodium percarbonate solution, or a mixture including two or more of these solutions.Type: ApplicationFiled: March 27, 2012Publication date: August 7, 2014Applicant: Tohoku UniversityInventors: Yasuaki Kohama, Michiru Sakamoto, Toshihiko Abe
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Publication number: 20140220460Abstract: Provided is a battery comprising an iron electrode and an electrolyte comprised of sodium hydroxide, lithium hydroxide and a soluble metal sulfide. In one embodiment, the concentration of sodium hydroxide in the electrolyte ranges from 6.0 M to 7.5 M, the amount of lithium hydroxide present in the electrolyte ranges from 0.5 M to 2.0 M, and the amount of metal sulfide present in the electrolyte ranges from 1 to 2% by weight.Type: ApplicationFiled: February 6, 2014Publication date: August 7, 2014Applicant: Encell Technology, Inc.Inventors: Randy Gene Ogg, Phil Bennett, Alan Seidel, Paul Gifford
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Publication number: 20140220461Abstract: An object of the invention is to provide an air battery that can avoid anode corrosion and withstand long-term use and storage, a mobile object including the air battery, and a method for using an air battery. Disclosed is an air battery including an air electrode, an anode, a liquid electrolyte layer and an outer case, the liquid electrolyte layer being present between the air electrode and the anode, and the outer case housing one or two or more laminates each comprising the air electrode, the anode and the liquid electrolyte layer, wherein the anode includes at least an anode active material layer and an anode current collector in order from the closest to the liquid electrolyte layer, and wherein the anode active material layer and the anode current collector are present on the upper side of the vertical direction and above the liquid electrolyte layer.Type: ApplicationFiled: October 13, 2011Publication date: August 7, 2014Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Sanae Okazaki
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Publication number: 20140220459Abstract: An electrode includes a plant-derived porous carbon material having an ability to catalyze oxygen reduction.Type: ApplicationFiled: January 29, 2014Publication date: August 7, 2014Applicant: SONY CORPORATIONInventors: Hironori Iida, Kenichi Murata, Takaaki Nakagawa, Shinichiro Yamada
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Publication number: 20140205917Abstract: To provide a metal-air battery which allows rapid and efficient supply of a liquid electrolyte to an air electrode and an increase in charge-discharge capacity. Disclosed is a metal-air battery including an air electrode layer, a negative electrode layer and an electrolyte layer, the electrolyte layer being present between the air electrode layer and the negative electrode layer, wherein the electrolyte layer includes a separator and a liquid electrolyte, the separator having insulating properties and a porous structure, and the liquid electrolyte being infiltrated in the separator, and wherein a liquid electrolyte reservoir layer is present between the separator and the air electrode layer, the liquid electrolyte reservoir layer having a porous structure which is larger in pore diameter than the separator.Type: ApplicationFiled: September 29, 2011Publication date: July 24, 2014Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Fuminori Mizuno
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Publication number: 20140205918Abstract: A storage element for a solid electrolyte battery is provided. The storage element has a main member having a porous matrix of sintered ceramic particles in which particles that are made of a metal and/or a metal oxide and jointly form a redox couple are embedded. Along a preferred direction, the storage element has a certain concentration gradient of the particles made of the metal and/or the metal oxide and/or a certain gradient of a pore density and/or a pore size, thereby allowing the diffusion behavior of oxygen ions within the main member to be controlled and thus the charge and discharge kinetics, the life and the capacity of the battery to be improved.Type: ApplicationFiled: September 3, 2012Publication date: July 24, 2014Applicant: SIEMENS AKTIENGESELLSCHAFTInventors: Carsten Schuh, Thomas Soller
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Publication number: 20140193720Abstract: The preset invention is to provide an air battery including, in an air electrode layer, a needle-shaped carbon material having more reaction starting points of oxygen reduction reaction than conventional carbon materials. Disclosed is an air battery including at least an air electrode, a negative electrode and an electrolyte layer disposed between the air electrode and the negative electrode, wherein the air electrode is provided with at least an air electrode layer, and the air electrode layer contains a needle-shaped carbon material having an average aspect ratio of 10 or more and a DIG ratio of 0.1 or more.Type: ApplicationFiled: June 15, 2011Publication date: July 10, 2014Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Fuminori Mizuno