Abstract: A composite electrode structure and methods of making and using thereof are disclosed. The structure has a metal substrate with a metal oxide layer. The average thickness of the metal oxide layer is less than 150 nm, and comprises at least a first metal and a second metal, wherein the first metal and the second metal are different elements. A plurality of carbon nanotubes is disposed on a first surface of the metal oxide layer. At least a portion of the carbon nanotubes are disposed such that one end of the carbon nanotube is positioned at least 5 nm below the surface of the metal oxide layer.

Abstract: Novel materials comprising a solid support, linker arms and metal-organic complexes, and their use for the electrocatalytic production and oxidation of H2. Such materials can be used for the production of electrodes in the field of electronics, and notably electrodes for fuel cells, electrolysers and photoelectrocatalytical (PEC) devices.

Abstract: The present invention relates to a cermet body composition for the preparation of novel cermet materials to be used in solid oxide fuel cells. The cermet body composition comprises a ceramic component and a metallic component, wherein the ceramic component is in the range of 5% to 95% by wt of the cermet body.

Abstract: The present invention provides an electrode for electrochemistry with a high quality, in which the surface area of the polycrystalline conductive diamond layer is increased and the crystal plane is controlled. In addition, when the catalyst layer of electrode substance is coated on the polycrystalline conductive diamond layer, adherence between the two layers is increased to provide an electrode for electrochemistry with a high durability. The polycrystalline conductive diamond layer is held under an atmosphere of carbon dioxide at a temperature 400 degrees Celsius or higher but 1000 degrees Celsius or lower to make the polycrystalline conductive diamond layer porous and make a specific crystal plane to remain and be formed.

Abstract: The present invention relates to a solid oxide fuel cell which can improve the overall performance of the cell and obtain durability and reliability, and the invention provides a solid oxide fuel cell comprising a reaction preventing layer and a method for manufacturing the same, wherein an anode, an electrolyte, and a cathode are comprised, and a material which is formed between the electrolyte and the anode comprises 35-90 mol % of gadolinia-doped ceria (GDC) and 10-65 mol % metal oxide.

Abstract: [OBJECT] In an SOFC cell comprising a Cr-containing alloy or the like and an air electrode bonded together, the invention is to provide a cell capable of effectively restricting occurrence of Cr poisoning of the air electrode and capable also of effectively restricting occurrence of oxidation deterioration due to Cr depletion in the alloy or the like. [SOLUTION] In a cell for a solid oxide fuel cell (SOFC) comprising a Cr (chrome)-containing alloy or oxide and an air electrode bonded together, wherein on the surface of the alloy or oxide, there is formed a coating layer containing a spinel oxide comprised of a first mono metal oxide and a second mono metal oxide, the first mono metal oxide having an equilibrium dissociated oxygen partial pressure at 750° C. ranging from 1.83×10?20 to 3.44×10?13 atm., the second mono metal oxide having a lower equilibrium dissociated oxygen partial pressure at 750° C. than the first mono metal oxide.

Abstract: Titanium suboxide (TixO2x-1) nanoparticles useful as a support for a catalyst electrode of a fuel cell, and a method for synthesizing the titanium suboxide (TixO2x-1) nanoparticles by using TiO2, a Co catalyst and hydrogen gas at a low temperature ranging from 600 to 900° C. are described Since the titanium suboxide nanoparticles show high corrosion resistance to acid and durability and have excellent thermal and electric conductivities, a catalyst electrode manufactured by using the same as a support exhibits improved catalytic activity and oxidation reduction (redox) properties.

Abstract: A cathode for a metal air battery includes a cathode structure having pores. The cathode structure has a metal side and an air side. The porosity decreases from the air side to the metal side. A metal air battery and a method of making a cathode for a metal air battery are also disclosed.

Abstract: Provided are a method of preparing an electrocatalyst for fuel cells in a core-shell structure, an electrocatalyst for fuel cells having a core-shell structure, and a fuel cell including the electrocatalyst for fuel cells. The method may be useful in forming a core and a shell layer without performing a subsequent process such as chemical treatment or heat treatment and forming a core support in which core particles having a nanosize diameter are homogeneously supported, followed by selectively forming shell layers on surfaces of the core particles in the support. Also, the electrocatalyst for fuel cells has a high catalyst-supporting amount and excellent catalyst activity and electrochemical property.

Abstract: A catalyst includes (i) a primary metal or alloy or mixture including the primary metal, and (ii) an electrically conductive carbon support material for the primary metal or alloy or mixture including the primary metal, wherein the carbon support material: (a) has a specific surface area (BET) of 100-600 m2/g, and (b) has a micropore area of 10-90 m2/g.

Abstract: A support for a fuel cell includes a substrate including highly crystalline carbon, and a crystalline carbon layer on the substrate.

Abstract: The present invention relates to freestanding carbon nanotube paper comprising purified carbon nanotubes, where the purified carbon nanotubes form the freestanding carbon nanotube paper and carbon microparticles embedded in and/or present on a surface of the carbon nanotube paper. The invention also relates to a lithium ion battery, capacitor, supercapacitor, battery/capacitor, and fuel cell containing the freestanding carbon nanotube paper as an electrode. Also disclosed is a method of making a freestanding carbon nanotube paper. This method involves providing purified carbon nanotubes, contacting the purified carbon nanotubes with an organic solvent under conditions effective to form a dispersion comprising the purified carbon nanotubes. The dispersion is formed into a carbon nanotube paper and carbon microparticles are incorporated with the purified carbon nanotubes.

Abstract: A membrane electrode assembly for a polymer electrolyte fuel cell includes: a proton conductive membrane for conducting protons; electrode catalyst layers arranged at both sides of the proton conductive membrane containing catalyst particles and an electrode electrolyte; and gas diffusion layers arranged on the respective electrode catalyst layers, having a porous basic material. Further, intermediate layers each having a thickness of 2-6 ?m are included, with noble metallic nanoparticles, an electrode electrolyte and carbon powder.

Abstract: Implementations and techniques for metal air batteries including a composite anode are generally disclosed.

Abstract: A method of transferring a nanostructured thin catalytic layer from its carrying substrate to a porous transfer substrate and further processing and restructuring the nanostructured thin catalytic layer on the porous transfer substrate is provided. The method includes transferring the nanostructured catalytic layer from its carrying substrate to a transfer substrate. The nanostructured catalytic layer then is processed and reconstructed, including removing the residual materials and adding additional components or layers to the nanostructured catalytic layer, on the transfer substrate. Methods of fabricating catalyst coated membranes with the reconstructed electrode including the nanostructured thin catalytic layer, reconstructed electrode decals, and catalyst coated proton exchange membranes are also described.

Abstract: Catalyst particles includes a catalyst material and carbon particles supporting the catalyst material. The catalyst particles has a water content of 4.8 mass % or more and 20 mass % or less. A manufacturing method of catalyst particles includes exposing catalyst particles, which are carbon particles supporting a catalyst material, to a humidified atmosphere, prior to dispersing the carbon particles and a polymer electrolyte in a solvent for a catalyst ink.

Abstract: An object of the present invention is to provide a fuel electrode doubling as a support of a solid oxide fuel cell, whose conductivity and strength hardly lower through repetitive exposure to a reducing atmosphere/oxidazing atmosphere. Specifically, a fuel electrode 30 doubling as a solid oxide fuel cell according to the present invention includes: a three-dimensional network structure 10 formed by oxide coarse particles 12 connected to one another via an aggregate 14; electrode particles 20 dispersed in gaps 16 of the three-dimensional network structure and having a function as an electrode catalyst; and an aggregate 22 of second oxide fine particles for connecting the electrode particles 20 to a surface in the gap of the three-dimensional network structure, wherein the oxide coarse particles 12 are connected to one another without the electrode particles 20.

Abstract: A manufacturing method for an electrode catalyst layer includes: containing a conductive carrier on which a catalyst is supported, a substrate, an electrolyte resin and a supercritical fluid inside a closed container (S102 to S106); and cooling the substrate to form an electrode catalyst layer, having the conductive carrier on which the catalyst is supported and the electrolyte resin, on the substrate (S 108).

Abstract: A catalyst for a fuel cell includes an active metal catalyst and a composite supporter supporting the active metal catalyst. The composite supporter includes a spherical-shaped supporter and a fibrous supporter, wherein the fibrous supporter is included in an amount of about 5 wt % to about 40 wt % based on the total amount of the composite supporter. In addition, an electrode for a fuel cell using the same, a membrane-electrode assembly for a fuel cell including the electrode, and a fuel cell system including the membrane-electrode assembly are also disclosed.

Abstract: There is provided a fuel cell cathode electrode, comprising a porous skeletal medium, the surface of which medium is modified or otherwise arranged or constructed to induce enhanced activated behaviour, wherein the enhanced activated behaviour is induced by means of increasing the surface area for a given volume of the electrode and/or by increasing the number and/or availability of reactive sites on the electrode. A fuel cell having such a cathode electrode, a method of manufacturing such a cathode electrode, and use of such a cathode electrode in a fuel cell is also disclosed.

Abstract: A catalyst for a fuel cell includes an active metal catalyst and a composite supporter supporting the active metal catalyst. The composite supporter includes a spherical-shaped supporter and a fibrous supporter, wherein the fibrous supporter is included in an amount of about 5 wt % to about 40 wt % based on the total amount of the composite supporter. In addition, an electrode for a fuel cell using the same, a membrane-electrode assembly for a fuel cell including the electrode, and a fuel cell system including the membrane-electrode assembly are also disclosed.

Abstract: This invention provides metal-foam electrodes for batteries and fuel cells. In some variations, an electrode includes a first metal layer disposed on a second metal layer, wherein the first metal layer comprises an electrically conductive, open-cell metal foam with an average cell diameter of about 25 ?m or less. The structure also includes smaller pores between the cells. The electrode forms a one piece monolithic structure and allows thicker electrodes than are possible with current electrode-fabrication techniques. These electrodes are formed from an all-fluidic plating solution. The disclosed structures increase energy density in batteries and power density in fuel cells.

Abstract: Provided is an electrocatalyst for solid polymer fuel cells capable of increasing the active surface area for reactions in a catalyst component, increasing the utilization efficiency of the catalyst, and reducing the amount of expensive precious metal catalyst used. Also provided are a membrane electrode assembly that uses this electrocatalyst and a solid polymer fuel cell. An electrocatalyst for a solid polymer fuel cell is provided with a catalyst and solid proton conducting material. A liquid conductive material retention part that retains a liquid proton conducting material that connects the catalyst and solid proton conducting material is provided between the same. The surface area of the catalyst exposed within the liquid conductive material retention part is larger than the surface area of the catalyst in contact with the solid proton conducting material.

Abstract: Disclosed is a unit cell of a honeycomb-type solid oxide fuel cell (SOFC) having a plurality of channels. The channels include cathode channels and anode channels. The cathode channels and anode channels are set up alternately in the unit cell. A collector is installed inside each of the cathode channels and the anode channels, and a packing material is packed into the channels having the collector. Disclosed also is a stack including the unit cells and methods for manufacturing the unit cell and the stack.

Abstract: An electrocatalytic polymer-based powder has particles of at least one electronically conductive polymer species in which particles are dispersed of at least one catalytic redox species, in which the particles of the polymer species and of the catalytic species are of nanometric dimension.

Abstract: The performance of an ABx type metal hydride alloy is improved by adding an element to the alloy which element is operative to enhance the surface area morphology of the alloy. The alloy may include surface regions of differing morphologies.

Abstract: Disclosed is a method for producing an alloy catalyst supported on carbon, including the steps of: dispersing alloy particles into a mixed solution of water with alcohol, introducing a silica precursor thereto, and carrying out sol-gel reaction in the presence of a basic catalyst to obtain silica-coated alloy particles; supporting the silica-coated alloy particles onto a carbon carrier to obtain silica-coated alloy particles supported on carbon; heat treating the silica-coated alloy particles supported on carbon to increase an alloying degree; and removing silica coating by using inorganic base solution and a surfactant. The method for producing an alloy catalyst provides a high-quality and high-durability alloy catalyst by increasing the alloying degree of a catalyst through a heat treatment step, while forming a silica coating layer effectively on small alloy particles having a size of several nanometers to inhibit growth of the size of alloy particles.

Abstract: A method of fabricating composite filaments is provided. An initial composite filament including a core and a cladding (such as a Pt-group metal) is cut into smaller pieces (or is first mechanically reduced and then cut into smaller pieces). The smaller pieces of the filaments are inserted into a metal matrix, and the entire structure is then further reduced mechanically in a series of reduction steps. The process can be repeated until the desired cross sectional dimension of the filaments is achieved. The matrix can then be chemically removed to isolate the final composite filaments with the cladding thickness down to the nanometer range. The process allows the organization and integration of filaments of different sizes, compositions, and functionalities into arrays suitable for various applications.

Abstract: In one or more embodiments, an electrochemical device includes a substrate having a substrate surface; an amorphous metal oxide layer supported on the substrate surface; and a noble metal catalyst supported on the amorphous metal oxide layer to form a catalyst layer. The amorphous metal oxide layer may contact only 25 to 75 percent of the substrate surface. The amorphous metal oxide layer may include less than 10 weight percent of crystalline metal oxide. In certain instances, the amorphous metal oxide layer is substantially free of crystalline metal oxide.

Abstract: The present disclosure relates to solid oxide fuel cells, and particularly raw powder materials which form a layer in a solid oxide fuel. The raw powder materials include an ionic conductor powder material; and an electronic conductor powder material. The ratio of an average particle diameter of the ionic conductor powder material to an average particle diameter of the electronic conductor powder material is greater than about 1:1, and an average particle diameter of at least one of the electronic conductor powder material or the ionic conductor powder material is coarse.

Abstract: In a fuel cell, one of separators that are opposed to each other and an intermediate body interposed between the separators are sandwiched by a cell monitor. An end portion of the intermediate body extends to an edge portion of a cell monitor mounting portion of the above-indicated one separator. The intermediate body includes at least one of a member that functions to hold an electrolyte body, a spacer (as in the case where the intermediate body is a resin frame), and a seal member or members. A major surface of the separator in the cell monitor mounting portion on which the cell monitor is mounted is in surface contact with a terminal of the cell monitor for conduction therebetween.

Abstract: A product comprising a fuel cell component comprising a substrate and a coating overlying the substrate, the coating comprising nanoparticles having sizes ranging from 2 to 100 nanometers.

Abstract: One embodiment includes at least one of the anode and cathode of a fuel cell comprises a first layer and a second layer in intimate contact with each other. Both the first layer and the second layer comprise a catalyst capable of catalyzing an electrochemical reaction of a reactant gas. The second layer has a higher porosity than the first layer. A membrane electrode assembly (MEA) based on the layered electrode configuration and a process of making a fuel cell are also described.

Abstract: A fuel cell electrode including a catalyst layer including: a catalyst; and a conductor storage material having pores with an average diameter of about 5 nm to about 1000 nm.

Abstract: A cathode for a fuel cell comprising a catalyst layer; a backing layer mounted to an aperture in a fuel chamber of said fuel cell; 1) wherein said catalyst layer is mounted to the backing layer on a face opposed to the aperture, so as to be in fluid communication with atmospheric oxygen in the case of microbial fuel cell; and 2) wherein said catalyst layer is mounted to the backing layer on a face opposed to the aperture, so as to be in fluid communication with water in the case of microbial electrolysis cell.

Abstract: Catalysts comprising porous metal nanoparticles, which are individually encapsulated with a reaction-enhancing material, and their use in fuel cell catalysis are provided.

Abstract: Truncated ditetragonal gold prisms (Au TDPs) are synthesized by adding a dilute solution of gold seeds to a growth solution, and allowing the growth to proceed to completion. The Au TDPs exhibit the face-centered cubic crystal structure and are bounded by 12 high-index {310} facets. The Au TDPs may be used as heterogeneous catalysts as prepared, or may be used as substrates for subsequent deposition of an atomically thin layer of a platinum group metal catalyst. When the Au TDPs are used as substrates, the atomically thin layer of metal reproduces the high-index facets of the Au TDPs.

Abstract: A fuel cell comprises an anode, a cathode, and a proton exchange membrane. The anode and cathode can include a catalyst layer which includes a plurality of generally aligned carbon nanotubes. Methods of making a fuel cell are also disclosed.

Abstract: A nanofibrous catalyst and method of manufacture. A precursor solution of a transition metal based material is formed into a plurality of interconnected nanofibers by electro-spinning the precursor solution with the nanofibers converted to a catalytically active material by a heat treatment. Selected subsequent treatments can enhance catalytic activity.

Abstract: The object of the present invention is to provide carbon fiber material having high electrical conductivity at a low cost. A manufacturing method of carbon fiber material comprises a dispersion liquid preparation step, a centrifugal spinning step and a denaturation step. The dispersion liquid preparation step is a step in which dispersion liquid containing resin and carbon particles is prepared. The centrifugal spinning step is a step in which nonwoven fabric made of a carbon fiber precursor is formed from the dispersion liquid. The denaturation step is a step in which the carbon fiber precursor denatures into carbon fiber.

Abstract: A discharge port is located at a lower portion of the case of a gas-liquid separator. A discharge valve is located at the discharge port. A water retaining portion is located at the bottom of the case. The water retaining portion is located at a position lower than the discharge valve. An upward inclination surface is formed on the bottom of the water retaining portion. The upward inclination surface is inclined upward toward the discharge valve. A downward inclination surface is formed on the bottom of the water retaining portion. The downward inclination surface is inclined downward toward the upward inclination surface. A cover portion is located in an upper portion of the water retaining portion. The cover portion defines a gas passage in an upper portion of the water retaining portion. The gas passage is open at a portion closer to the inlet and connected to the discharge valve.

Abstract: A cathode catalyst for a fuel cell includes a carrier, and an active material including M selected from the group consisting of Ru, Pt, Rh, and combinations thereof, and Ch selected from the group consisting of S, Se, Te, and combinations thereof, with the proviso that the active material is not RuSe when the carrier is C.

Abstract: A membrane electrode assembly including an anode that incorporates a porous support and a hydrogen permeable metal thin film disposed on the porous support; a cathode; and a proton conductive solid oxide electrolyte membrane disposed between the anode and the cathode.

Abstract: An electrocatalyst material comprising a functionalized catalytic substrate, the catalytic substrate comprising an electron-accepting material adsorbed thereto. In one embodiment, the catalytic substrate comprises carbon nanotubes or graphene sheets having a nitrogen-containing or nitrogen-free polyelectrolyte, e.g., poly(diallyldimethylammonium chloride) (PDDA), adsorbed thereto. The electrocatalyst material exhibits excellent catalytic activity, as well as broad fuel selectivity, resistance to poisoning effects, and durability. The electrocatalyst can be used as part of an electrode structure, e.g., a cathode, that can be used in a wide range of electrochemical devices.

Abstract: The present disclosure provides photosynthetic electrochemical cells including photosynthetic compounds and methods of generating an electrical current using the photosynthetic electrochemical cells.

Abstract: A liquid electrolyte fuel cell comprises means to define an electrolyte chamber (208), and two electrodes (10), one on either side of the electrolyte chamber (208), each electrode comprising:—a sheet (11) of metal through which are defined a multiplicity of through-holes (14), and—a gas-permeable layer (16) of fibrous and/or particulate electrically-conductive material which is bonded to and in electrical contact with the sheet of metal (11), and which comprises catalytic material (18). The electrode (10) may be arranged such that the gas-permeable layer (16) faces the electrolyte chamber (208).

Abstract: In some embodiments, the present disclosure provides a fuel cell catalyst having a catalyst surface bearing a non-occluding layer of iridium. In some embodiments, the present disclosure provides a fuel cell catalyst comprising a catalyst surface bearing a sub-monolayer of iridium. In some embodiments, the present disclosure provides a fuel cell catalyst comprising a catalyst surface bearing a layer of iridium having a planar equivalent thickness of between 1 and 100 Angstroms. In some embodiments, the fuel cell catalyst comprises nanostructured elements comprising microstructured support whiskers bearing a thin film of nanoscopic catalyst particles. The layer of iridium typically has a planar equivalent thickness of between 1 and 100 Angstroms and more typically between 5 and 60 Angstroms. The fuel cell catalyst typically comprises no electrically conductive carbon material and typically comprises at least a portion of the iridium in the zero oxidation state.

Abstract: Novel cathode, electrolyte and oxygen separation materials are disclosed that operate at intermediate temperatures for use in solid oxide fuel cells and ion transport membranes based on oxides with perovskite related structures and an ordered arrangement of A site cations. The materials have significantly faster oxygen kinetics than in corresponding disordered perovskites.

Abstract: An oxygen reduction electrode and a fuel cell including the same are provided. A catalyst layer of the oxygen reduction electrode includes a metalloporphyrin derivative as an additive. Accordingly, the oxygen reduction electrode can increase oxygen concentration and can easily form a triple phase boundary by reducing a flooding phenomenon caused by an electrolyte. A fuel cell including the same is also provided.

Abstract: Provided are a solid oxide fuel cell and a method of manufacturing the same. The solid oxide fuel cell in which at least one or more unit modules are stacked and integrated with each other includes first and second solid electrolyte layers in which each of the unit modules includes a plurality of fuel electrodes spaced a predetermined distance from each other and each having a strip shape and first and second supports each including a plurality of slits each having the same strip shape as that of each of the fuel electrodes. The first and second solid electrolyte layers overlap with each other on lower and upper sides of the first support so that the fuel electrodes face each other within the slits of the first support, and the second support overlaps with a lower side of the first or second solid electrolyte layer overlapping with the lower side of the first support so that the slits of the second support are disposed perpendicular to the slits of the first support.