Organic Nitrogen Or Organic Phosphorus Compound Adjuvant Patents (Class 430/108.2)
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Patent number: 8563627Abstract: A process for making a self-emulsifying granule suitable for use in forming latex emulsions includes contacting a resin with a solid or highly concentrated surfactant, a solid neutralization agent and water in the absence of an organic solvent to form a mixture, melt mixing the mixture, and forming self-emulsifying granules of the melt mixed mixture. Self-emulsifying granules are also provided and configured to form a latex emulsion when added to water, which may then be utilized to form a toner.Type: GrantFiled: July 30, 2009Date of Patent: October 22, 2013Assignee: Xerox CorporationInventors: Santiago Faucher, Joo T. Chung, Shigang Qiu, Fumii Higuchi
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Patent number: 8557490Abstract: Disclosed is a cyan toner for developing an electrostatic image containing a cyan colorant, and the cyan colorant comprises colorant compound X represented by Formula (1) and colorant compound Y represented by Formula (2). wherein M1 is a metal atom of Group 14, Q is independently a monovalent substituent, m and n are each 0 or 1, at least one of m and n is 1, and A is independently an atomic group forming an aromatic ring which may have a substituent, wherein, M2 is Zn or Al, and A is independently an atomic group forming an aromatic ring which may have a substituent.Type: GrantFiled: July 29, 2011Date of Patent: October 15, 2013Assignee: Konica Minolta Business Technologies, Inc.Inventors: Hiroyuki Yasukawa, Hajime Tadokoro, Kaori Matsushima, Ito Koga, Yohei Ohno
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Patent number: 8557496Abstract: The present invention relates to a chemical toner composition and a method for preparing the same. The chemical toner composition includes: a resin emulsion; a pigment dispersion; a wax dispersion; and a dispersible polymer coagulant, wherein the dispersible polymer coagulant is a copolymer comprising unsaturated ester monomers and amino-containing monomers. Accordingly, the present invention uses a novel dispersible polymer coagulant to prepare uniform toner particles with excellent roundness and improved flowability and to reduce moisture absorption.Type: GrantFiled: April 9, 2012Date of Patent: October 15, 2013Assignee: Trend Tone Imaging, Inc.Inventors: Kuei-Ying Chiu, Kuo-Tong Huang, Ju-Feng Liao, I-Jein Cheng, Jui-Fa Chang, Chien-Sheng Huang, Yi-Ling Liu
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Publication number: 20130260302Abstract: A toner, including: crystalline resin; non-crystalline resin; and a composite resin, wherein the crystalline resin is crystalline polyester resin (A), the non-crystalline resin comprises: non-crystalline resin (B) containing chloroform insoluble matter; and non-crystalline resin (C) having a softening temperature (T½) lower than that of the non-crystalline resin (B) by 25° C. or more, an absolute value |Tgc?Tgb| of a difference between a glass transition temperature (Tgc) of non-crystalline resin (C) and a glass transition temperature (Tgb) of non-crystalline resin (B) is 10° C. or lower, wherein the composite resin is composite resin (D) containing a condensation polymerization resin unit and an addition polymerization resin unit, and the toner has a molecular weight distribution having a main peak in 1,000 to 10,000 and a half width of 15,000 or less, where the molecular weight distribution is obtained by gel permeation chromatography (GPC) of tetrahydrofuran (THF) soluble matter of the toner.Type: ApplicationFiled: March 14, 2013Publication date: October 3, 2013Inventors: Hisashi Nakajima, Saori Yamada, Masashi Nagayama, Mariko Takii, Shinya Hanatani
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Publication number: 20130252160Abstract: A toner for forming an electrophotographic image is provided, wherein the toner includes at least four types of binder resins, wherein the binder resins includes at least: a crystalline polyester resin (A); a non-crystalline resin (B); a non-crystalline resin (C); and a composite resin (D) which includes a condensation polymerization resin unit and an addition polymerization resin unit, wherein the non-crystalline resin (B) includes a chloroform insoluble matter, wherein the non-crystalline resin (C) has a softening temperature (T½) lower than that of the non-crystalline resin (B) by 25° C. or more, and wherein the toner has a main peak between 1,000 to 10,000 in a molecular weight distribution obtained by GPC from a tetrahydrofuran soluble matter, and the toner has a half-value width of the molecular weight distribution of 15,000 or less.Type: ApplicationFiled: September 14, 2012Publication date: September 26, 2013Inventors: Masashi NAGAYAMA, Mitsuo Aoki, Hisashi Nakajima, Saori Yamada, Mariko Takii
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Publication number: 20130244162Abstract: A toner, including: a binder resin; and a colorant, wherein the binder resin contains: a crystalline polyester resin (A); a non-crystalline resin (B); and a composite resin (C), where the composite resin (C) contains a condensation polymerization resin unit and an addition polymerization resin unit, wherein the toner contains chloroform insoluble matter in an amount of 1% by mass to 30% by mass, wherein the toner has a molecular weight distribution having a main peak in a range of 1,000 to 10,000 and a half width of 15,000 or less, where the molecular weight distribution is obtained through gel permeation chromatography (GPC) of tetrahydrofuran soluble matter of the toner, and wherein the toner has an endothermic peak in a range of 90° C. to 130° C. in measurement through differential scanning calorimetry (DSC).Type: ApplicationFiled: March 14, 2013Publication date: September 19, 2013Inventors: Saori Yamada, Hisashi Nakajima, Masashi Nagayama, Shinya Hanatani, Mariko Takii, Yoshitaka Sekiguchi
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Publication number: 20130244161Abstract: An electrostatic charge image developing toner includes toner particles containing a colorant, a binder resin, and a release agent, and an external additive, wherein the external additive includes particles having oil-treated surfaces and composite particles containing silica and titania, and the toner has a content ratio of titania with respect to silica on the surface of the toner, as measured by X-ray photoelectron spectroscopy, of equal to or less than 5 atomic %.Type: ApplicationFiled: July 31, 2012Publication date: September 19, 2013Applicant: FUJI XEROX CO., LTD.Inventors: Yutaka SAITO, Hiroki OHMORI, Hirokazu HAMANO
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Patent number: 8535865Abstract: An emissive toner composition for producing an emissive image component of an image indicia on a substrate. The emissive toner composition includes a photoluminescent agent, a charge control agent, and one or more additives, each selected and present in an amount such that when the toner composition is printed to produce an image component on a substrate, the toner composition has stable spectral characteristics. In one embodiment, the emission spectra of the image component printed on the substrate, for irradiation with an excitation energy includes only dominant emission peaks corresponding to one or more emission peaks of the photoluminescent agent. In another embodiment, the image component has a photoluminescent toner stability factor of about greater than or equal to 25.Type: GrantFiled: August 20, 2008Date of Patent: September 17, 2013Assignee: Angstrom Technologies, Inc.Inventors: William Coyle, Anthony Stramondo
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Patent number: 8518623Abstract: A toner includes a toner particle, which contains at least a binding resin, a colorant, and two types of polar resins, i.e., a polar resin H and a polar resin L, and which is obtained with granulation in a water-based medium, wherein solubility parameters, glass transition points, and weight-average molecular weights of the binding resin, the polar resin H, and the polar resin L, as well as amounts of the added resins satisfy respective specific relationships.Type: GrantFiled: March 30, 2011Date of Patent: August 27, 2013Assignee: Canon Kabushiki KasihaInventors: Kenta Kamikura, Shinya Yachi, Kazumi Yoshizaki, Yasushi Katsuta, Takeshi Kaburagi
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Publication number: 20130177843Abstract: The present invention provides a charge control agent containing, as an active substance(s), one or two or more thiazolidinedione derivatives represented by the following formula (1), where R1 represents a hydrogen atom, etc.; R2 represents a hydrogen atom, a linear or branched alkyl group having 1 to 8 carbon atoms which may have a substituent, etc.; R3 to R7, which may be identical to or different from each other, represent a hydrogen atom, a chlorine atom, a linear or branched alkyl group having 1 to 8 carbon atoms which may have a substituent, etc., and may be joined to each other to form a ring; and V, W, X, Y and Z represent a carbon atom or a nitrogen atom, and 0 to 3 of any of V, W, X, Y and Z are nitrogen atoms which do not have the substituents of R3 to R7.Type: ApplicationFiled: September 1, 2011Publication date: July 11, 2013Applicant: HODOGAYA CHEMICAL CO., LTD.Inventors: Ikuo Kimura, Motonori Tsuji, Masami Ito, Masaya Tojo, Kanae Hiraishi
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Publication number: 20130177844Abstract: The present invention provides a positive-charge control agent containing, as an active substance(s), one or two or more rhodanine compounds represented by the following formula (1). wherein R1 represents a hydrogen atom, etc.; R2 represents a hydrogen atom, etc.; and R3 to R7, which may be identical to or different from each other, represent a hydrogen atom, a cyano group, a trifluoromethyl group, a nitro group, etc. R2 to R7 may be joined to each other to form a ring. V, W, X, Y and Z represent a carbon atom or a nitrogen atom and 0 to 3 of V, W, X, Y and Z are nitrogen atoms, with the proviso that at least one of R3 to R7 is a linear or branched alkyl group having 1 to 4 carbon atoms substituted with three or more fluorine atoms etc.Type: ApplicationFiled: November 22, 2011Publication date: July 11, 2013Applicant: HODOGAYA CHEMICAL CO., LTD.Inventors: Masateru Yasumura, Masami Ito, Ikuo Kimura, Masaya Tojo, Kanae Hiraishi, Masaki Okubo
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Publication number: 20130164665Abstract: A toner including a mother particle and an external additive covering a surface of the mother particle is provided. The mother particle includes a binder resin, a colorant, and a release agent. The external additive includes a particulate cellulose having a number average particle diameter within a range of 15 to 105 nm.Type: ApplicationFiled: November 16, 2012Publication date: June 27, 2013Inventors: Masayuki ISHII, Toyoshi Sawada
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Publication number: 20130157185Abstract: A toner includes a binder resin, a coloring agent, and a releasing agent containing two or more kinds of alkyl monoester compounds having a different number of carbon atoms in a range of from 30 to 50 carbon atoms. The toner has a crystallinity of 10% or more as measured by x-ray diffraction and/or the binder resin is a crystalline resin in an amount of 50% by weight or more of the binder resin. The two or more kinds of alkyl monoester compounds include a component A accounting for the largest amount ranging from 30% by weight to less than 50% by weight of the releasing agent and a component B accounting for the second largest amount ranging from 10% by weight to less than 50% by weight of the releasing agent.Type: ApplicationFiled: December 5, 2012Publication date: June 20, 2013Inventors: Shingo SAKASHITA, Hiroshi Yamashita, Masahide Yamada, Shinya Nakayama, Atsushi Yamamoto, Yukiko Nakajima
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Patent number: 8466206Abstract: A process for forming polymer particles with aligned pores and controlled narrow particle size distribution, including: a) forming an oil phase by dissolving a polymeric binder in a solvent; b) dispersing the oil phase into a water phase containing a controlled amount of particulate stabilizer and forming an oil-in-water emulsion of controlled narrow dispersed oil phase droplet size distribution; c) freezing the emulsion to freeze solvent in the oil droplets to form frozen solvent domains within the polymeric binder, and also the water in the continuous water phase; and d) removing the frozen solvent from the polymeric binder and the frozen water in the continuous water phase, thereby forming porous polymer particles of controlled narrow particle size distribution and containing directional aligned non-spherical pore structures. Optionally, the porous particles may contain encapsulated functional ingredients.Type: GrantFiled: December 22, 2011Date of Patent: June 18, 2013Assignee: Eastman Kodak CompanyInventors: Xiqiang Yang, James R. Bennett
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Patent number: 8460845Abstract: Provided is a cyan toner which, while being a capsule-type toner having excellent low-temperature fixability, has excellent offset resistance and charging performance and can obtain high-quality images. A cyan toner having at least a resin (a) having a polyester as a main component, a colorant, and a wax, in which glass transition temperatures (° C.) Tg(0.5) and Tg(4.0) obtained at a rate of temperature increase of 0.5° C./min or 4.0° C./min satisfy 40.0?Tg(0.5)?60.0 and 2.0?Tg(4.0)?Tg(0.5)?10.0, and wherein, when the concentration of the cyan toner in an ethyl acetate dispersion is Cc1 (mg/ml), and the light absorbance at a wavelength of 712 nm of the dispersion is A(ethyl acetate)712, A(ethyl acetate)712/Cc1<0.15 is satisfied, and wherein, when the concentration of the cyan toner in a chloroform solution is Cc2 (mg/ml), and the light absorbance at a wavelength of 712 nm of the solution is A(chloroform)712, 2.00<A(chloroform)712/Cc2<8.15 is satisfied.Type: GrantFiled: November 12, 2009Date of Patent: June 11, 2013Assignee: Canon Kabushiki KaishaInventors: Takaaki Kaya, Ayako Sekikawa, Ryoichi Fujita, Shigeto Tamura, Makoto Kambayashi
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Publication number: 20130122411Abstract: A developer includes a toner containing at least a binder resin, wherein the toner has a molecular weight distribution Mz/Mw of 2.0 or smaller and a phase angle of viscoelasticity of 65° or greater.Type: ApplicationFiled: November 15, 2012Publication date: May 16, 2013Applicant: OKI DATA CORPORATIONInventor: Oki Data Corporation
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Patent number: 8431294Abstract: Provided is an electrostatic charge image developing toner capable of reproducing color exhibiting high lightness and chroma, and obtaining a wide color reproduction range. Disclosed is the toner possessing a toner particle containing at least a binder resin and a colorant, wherein the colorant possesses a yellowish color nonfluorescent dye exhibiting a peak wavelength of an absorption spectrum being in a wavelength range of 400-480 nm, and a fluorescent dye exhibiting a peak wavelength of an emission spectrum being in a wavelength range of 480-560 nm, wherein the nonfluorescent dye has a content of 2-8 parts by weight, based on 100 parts by weight of the binder resin, and the fluorescent dye has a content of 0.05-0.2 parts by weight, based on 100 parts by weight of the resin, provided that a content ratio of the nonfluorescent dye to the fluorescent dye is 15-150.Type: GrantFiled: December 7, 2010Date of Patent: April 30, 2013Assignee: Konica Minolta Business Technologies, Inc.Inventors: Hidehito Haruki, Hiroyuki Yasukawa, Shinya Obara
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Patent number: 8426093Abstract: An electrophotographic photoreceptor including a photosensitive layer provided including a first functional layer including a compound represented by the following Formula (I). In Formula (I), F represents an n-valent organic group having hole transportation ability; R1, R2, and R3 each independently represents a hydrogen atom, a halogen atom, or a monovalent organic group; L represents a divalent organic group; n represents an integer of 1 to 4; and j represents an integer of 0 or 1.Type: GrantFiled: September 28, 2007Date of Patent: April 23, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Wataru Yamada, Katsumi Nukada, Masahiro Iwasaki, Kazuhiro Koseki
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Patent number: 8409775Abstract: The present invention relates to a toner for electrophotography which has a small particle size and is excellent in all of low-temperature fusing ability, anti-hot offset property and image characteristics and a process for producing the toner, as well as to a dispersion of crosslinked resin particles which is used for production of the toner for electrophotography and a process for producing the dispersion of crosslinked resin particles. The dispersion of crosslinked resin particles having a volume median particle size (D50) of from 0.05 to 0.7 ?m according to the present invention is produced by a process including the steps of (A) neutralizing a resin containing an acid group-containing polyester in an aqueous medium to obtain a dispersion of resin particles; and (B) mixing the dispersion of resin particles obtained in the step (A) with an oxazoline group-containing polymer at a temperature of from 60 to 100° C.Type: GrantFiled: September 5, 2008Date of Patent: April 2, 2013Assignee: Kao CorporationInventors: Manabu Suzuki, Yutaka Murai
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Publication number: 20130078565Abstract: An electrostatic charge image developing toner contains a binder resin, a release agent, a black colorant, a methylglycine diacetate, and an aluminum element, the content of the methylglycine diacetate is in the range of from 5 ppm to 500 ppm, and the content of the aluminum element is in the range of from 0.07 atomic % to 0.18 atomic % in total element analysis using fluorescent X-rays.Type: ApplicationFiled: February 15, 2012Publication date: March 28, 2013Applicant: FUJI XEROX CO., LTD.Inventors: Satoshi YOSHIDA, Tsuyoshi MURAKAMI, Eisuke IWAZAKI, Shinya SAKAMOTO
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Publication number: 20130071162Abstract: A color toner for optical fixing containing an infrared light absorbent and being compatible with an optical fusing device to irradiate an unfixed toner attached on a surface of a recording medium with infrared light to melt and fix the unfixed toner on the recording medium, wherein an optical absorptance of the color toner is set to be lower than an optical absorptance of a black toner in a wavelength region of the infrared light emitted from the optical fusing device.Type: ApplicationFiled: July 31, 2012Publication date: March 21, 2013Inventor: Tomohiro MAEDA
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Publication number: 20130065173Abstract: An electrostatic charge image developing toner includes: a polyester resin that has a glass transition temperature of about 45° C. or higher and in which a proportion of repeating units derived from fumaric acid in repeating units derived from acid components is 10 mol % or greater and a proportion of repeating units derived from alkenylsuccinic acid in the repeating units derived from acid components is 10 mol % or greater; and a photopolymerization initiator, wherein a content of the photopolymerization initiator is from about 0.5% by weight to about 10% by weight.Type: ApplicationFiled: February 15, 2012Publication date: March 14, 2013Applicant: FUJI XEROX CO., LTD.Inventor: Yasuhiro ARIMA
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Patent number: 8394566Abstract: A toner composition with a novel surface additive package for developing images. The additive package includes sol-gel silica, a PDMS silica, an organic spacer such as PMMA and HMDS silica. The toner composition exhibits improved control of voltage, higher print density, lower toner amount remaining on the roll, lower toner usage, and reduced drum contamination. The toner composition also exhibits improved dry theological properties. These improved properties make this toner composition useful for higher speed printing while using less toner.Type: GrantFiled: November 24, 2010Date of Patent: March 12, 2013Assignee: Xerox CorporationInventors: Grazyna E. Kmiecik-Lawrynowicz, Maura A. Sweeney, Daniel W. Asarese, Samir Kumar, Juan A. Morales-Tirado, Michael F. Zona
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Patent number: 8394567Abstract: There is provided a toner for electrostatic latent image developing, which includes a binder resin; a carbon black-surface treated with an isocyanate compound including a plurality of isocyanate groups which include one or more isocyanate groups that are not bonded to the carbon black; and a release agent having an acid value of about 5 mgKOH/g or higher and/or a hydroxyl value of about 5 mgKOH/g or higher.Type: GrantFiled: March 17, 2010Date of Patent: March 12, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Satoshi Kamiwaki, Akira Matsumoto, Sakon Takahashi
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Patent number: 8394565Abstract: A positively charged developer for development of electrostatic images, comprising positively charged toner particles and an external additive, wherein the positively charged toner particles are colored resin particles composed of aggregated and fusion-bonded particles of fine binder resin particles and fine colorant particles and having a shape factor SF-1 of 115 to 150 and a shape factor SF-2 of 110 to 140, and the external additive is an external additive containing positively charged inorganic particles subjected to a hydrophobization treatment with an amino group-containing compound, and a production process thereof.Type: GrantFiled: March 30, 2007Date of Patent: March 12, 2013Assignee: Zeon CorporationInventor: Keita Sensui
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Publication number: 20130059245Abstract: The present invention relates to a polymerized toner and a method for preparing the same, wherein the toner can realize an excellent offset feature, high transfer efficiency, and a uniform image and thus can exhibit excellent performances in the applications of high speed copying, development of transferred photos, etc.Type: ApplicationFiled: February 22, 2011Publication date: March 7, 2013Applicant: LG CHEM, LTD.Inventors: Wook Jang, Hak-Soo Kim, Chang-Soon Lee
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Patent number: 8367288Abstract: To provide a yellow toner satisfying good toner particles and a superior coloring power, the toner has toner base particles having at least a binder resin, a colorant and a wax component, and contains as the colorant at least a coloring matter compound represented by the following general formula (1) and a pigment represented by the following formula (2).Type: GrantFiled: April 23, 2010Date of Patent: February 5, 2013Assignee: Canon Kabushiki KaishaInventors: Yutaka Tani, Yasuaki Murai, Takayuki Toyoda, Masahiro Suenaga, Masatake Tanaka, Taichi Shintou, Kei Inoue, Masashi Kawamura, Masashi Hirose, Takeshi Miyazaki
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Publication number: 20130029261Abstract: The present invention relates to a polymerized toner prepared by suspension polymerization. In particular, the polymerized toner comprises a plurality of toner particles that each comprising a binder resin, a pigment, a pigment stabilizer, a charge control agent, and a wax. The polymerized toner maintains a ratio of toner particles containing at least two wax domains per particle within a defined range. Thereby, the polymerized toner achieves high glossiness and good transfer efficiency.Type: ApplicationFiled: July 26, 2012Publication date: January 31, 2013Applicant: LG CHEM, LTD.Inventors: Wook JANG, Chang-Soon LEE, Woo-Cheul JUNG, Joo-Yong PARK
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Patent number: 8349531Abstract: Compounds and methods of forming compounds useful as a toner or toner precursor are disclosed. The compounds may include an aqueous dispersion, the dispersion including: (A) at least one thermoplastic resin; and (B) 0 to 5 weight percent of a stabilizing agent, based on the total weight of (A) and (B). The dispersion may have an average volume diameter particle size from about 0.05 to about 10 microns. A combined amount of the thermoplastic resin and the stabilizing agent may have an acid number of less than 25 mg KOH/g.Type: GrantFiled: November 26, 2008Date of Patent: January 8, 2013Assignee: Dow Global Technologies LLCInventors: Timothy J. Young, Richard A. Lundgard, Michael J. Johnson, Qichun Wan, Matthew J. Kalinowski, Mechelle A. Churchfield, Gary M. Strandburg
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Publication number: 20120315576Abstract: The present invention provides a charge control agent containing, as an active substance(s), one or two or more rhodanine compounds represented by the following formula (1). where R1 represents a hydrogen atom, etc.; R2 represents a hydrogen atom, a linear or branched alkyl group having 1 to 8 carbon atoms which may have a substituent, a substituted or unsubstituted heterocyclic group, etc.; R3 to R7, which may be identical to or different from each other, represent a hydrogen atom, a linear or branched alkyl group having 1 to 10 carbon atoms which may have a substituent, a linear or branched alkyloxy group having 1 to 20 carbon atoms which may have a substituent, etc., and may be joined to each other to form a ring; and V, W, X, Y and Z represent a carbon atom or a nitrogen atom, and 0 to 3 of any of V, W, X, Y and Z are nitrogen atoms which do not have the substituents of R3 to R7.Type: ApplicationFiled: February 21, 2011Publication date: December 13, 2012Applicant: HODOGAYA CHEMICAL CO., LTD.Inventors: Masateru Yasumura, Masami Ito, Masaya Tojo, Kanae Hiraishi, Masaki Okubo, Hideyuki Otsuka
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Patent number: 8313881Abstract: A toner for an electrophotographic image forming process or an electrostatic printing process, and a polyester resin for the toner are disclosed. The polyester resin comprises: acid components including 70 to 96 mol % of aromatic dibasic acid component, 3 to 20 mol % of cycloaliphatic dibasic acid component, and 1 to 10 mol % of trivalent or higher acid component; alcohol components including 10 to 50 mol % of cycloaliphatic diol component, 2 to 20 mol % of trihydric or higher alcohol component, and 30 to 88 mol % of aliphatic diol component; and a heat stabilizer.Type: GrantFiled: July 10, 2008Date of Patent: November 20, 2012Assignee: SK Chemicals Co., Ltd.Inventors: Young-Man Yoo, Jae-Kyoung Roh, Kye-Yune Lee, Tae-Woong Lee
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Publication number: 20120288790Abstract: The present disclosure describes processes for making clear, high-gloss toners, including toner compositions resulting from such processes that find applications in overcoating and gloss enhancement.Type: ApplicationFiled: May 13, 2011Publication date: November 15, 2012Applicant: XEROX CORPORATIONInventors: Maura Sweeney, Grazyna E. Kmiecik-Lawrynowicz, Robert D. Bayley, Dan Asarese
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Publication number: 20120288789Abstract: Environmentally friendly latex particles are provided which include a gelling agent and a pigment encapsulated in an amorphous resin which may be utilized in forming EA super low melt toners. Methods for providing these resins and toners are also provided.Type: ApplicationFiled: May 11, 2011Publication date: November 15, 2012Applicant: XEROX CORPORATIONInventors: Hadi K. Mahabadi, Ke Zhou, Michelle N. Chrétien, Edward Graham Zwartz, Guerino G. Sacripante
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Patent number: 8298736Abstract: Provided is a toner comprising toner particles containing a binder resin and coloring matters, wherein the coloring matters comprise a dye represented by Formula (X-1), a metal compound represented by Formula (1) and a quinacridone pigment represented by Formula (2):Type: GrantFiled: May 15, 2009Date of Patent: October 30, 2012Assignee: Konica Minolta Business Technologies, Inc.Inventors: Naohiro Hirose, Hiroyuki Yasukawa, Natsuko Kusaka, Miyuki Murakami, Yohei Ohno
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Patent number: 8293443Abstract: A toner formulation is disclosed comprising a binder and an IR absorbing black pigment at a concentration of 0.25-2.0% by weight, including one or more infrared transmissive pigments, wherein the infrared transmissive pigments are configured to provide a black color. Such toner formulation may provide a response to a toner patch sensor to indicate a mass per unit area of 0.1-1.5 mg/cm2 or a reflectance relative to a substrate to define a reflectance ratio that varies relative to L* values for the toner over the range L*=0-50 or a bulk reflectivity of greater than 6.0% for a portion of the wavelength range of 850-2000 nanometers.Type: GrantFiled: October 12, 2007Date of Patent: October 23, 2012Assignee: Lexmark International, Inc.Inventors: Albert Mann Carter, Jr., Gary Allen Denton, Joseph Edward Johnson, John Melvin Olson, Trent Peter, Cary Patterson Ravitz, Tao Yu
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Publication number: 20120237868Abstract: A toner including a binder resin, a colorant, and a release agent is provided. The toner has a peak loss tangent (tan ?) value of 3 or more within a temperature range of 80 to 160° C. Here, the loss tangent (tan ?) is a ratio (G?/G?) of a loss elastic modulus (G?) to a storage elastic modulus (G?). The toner provides a good combination of low-temperature fixability, hot offset resistance, storage stability, coloring power and/or opacifying power, and gloss.Type: ApplicationFiled: February 24, 2012Publication date: September 20, 2012Inventors: Saori Yamada, Mitsuo Aoki, Hisashi Nakajima, Masashi Nagayama, Shigenori Yaguchi
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Patent number: 8252494Abstract: A fluorescent particle includes a fluorescent pigment, such as a trans-dicarboxylic-indenofluorenone, and at least one stabilizing wax chemically attached to the fluorescent pigment. The stabilizing wax includes an amine group at its terminal end and the fluorescent pigment includes at least one carboxylic acid group, where the amine group reacts with the carboxylic acid group to form an amide bond. A method for making fluorescent particles for use in toners by chemically attaching at least one stabilizing wax to a fluorescent pigment where the at least one stabilizing wax includes an amine group at its terminal end and the fluorescent pigment includes at least one carboxylic acid group. A toner may include a resin and the fluorescent particle.Type: GrantFiled: May 3, 2010Date of Patent: August 28, 2012Assignee: Xerox CorporationInventors: Daryl W. Vanbesien, Maria M. Birau, C. Geoffrey Allen, Carol A. Jennings, Peter G. Odell
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Patent number: 8247145Abstract: A magenta toner for developing an electrostatic image, the magenta toner comprising at least a binder resin and a magenta colorant, wherein the magenta colorant comprises a compound represented by Formula (1), wherein D is represented by one of Formulas (2) to (4):Type: GrantFiled: August 8, 2008Date of Patent: August 21, 2012Assignee: Konica Minolta Business Technologies, Inc.Inventors: Natsuko Kusaka, Mikio Kouyama, Kenji Hayashi, Hiroaki Obata
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Publication number: 20120189951Abstract: A toner including: a binder resin component; crystal nucleating agent; releasing agent; and colorant, wherein the binder resin component contains a crystalline polyester resin and a non-crystalline polyester resin, the crystal nucleating agent is at least one of an aliphatic ester compound and an aliphatic amide compound each having a melting point of 60° C. or higher but lower than 150° C., and wherein the toner satisfies Expressions (I) and (II): Tc>Tp+10??Expression (I) Tm>Tp+2??Expression (II) where Tp denotes lowest exothermic peak temperature [° C.] in 0° C. to 200° C. in DSC curve obtained DSC of the crystalline polyester resin, Tc denotes lowest exothermic peak temperature [° C.] in 0° C. to 200° C. in DSC curve obtained DSC of the crystal nucleating agent, and Tm denotes lowest exothermic peak temperature [° C.] in 0° C. to 200° C. in DSC curve through DSC of the mixture of the crystalline polyester resin and the crystal nucleating agent.Type: ApplicationFiled: December 23, 2011Publication date: July 26, 2012Inventors: Tsuyoshi SUGIMOTO, Hiroshi Yamashita, Daisuke Asahina, Masaki Watanabe, Satoyuki Sekiguchi, Rintaro Takahashi
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Patent number: 8227164Abstract: A toner, including a colorant; a binder resin; a release agent; and a fixing supplemental component, wherein the toner has a storage elastic modulus G? (Pa) satisfying the following conditions: 5.0×104<G?<5.0×105 at 80° C. 1.0×104<G?<1.0×105 at 90° C. 5.0×103<G?<5.0×104 at 100° C. 1.0×103<G?<1.0×104 at 120° C. 1.0×103<G?<1.0×104 at 150° C.Type: GrantFiled: May 11, 2010Date of Patent: July 24, 2012Assignee: Ricoh Company, LimitedInventors: Tsuyoshi Sugimoto, Naohito Shimota, Hiroshi Yamashita, Satoshi Ogawa, Masana Shiba, Junichi Awamura, Tsuneyasu Nagatomo, Masaki Watanabe
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Patent number: 8221951Abstract: A toner and method for making a toner that includes an amorphous resin, a crystalline resin, and a cyanine dye. The cyanine dye improves heat cohesion without negatively effecting other desirable properties.Type: GrantFiled: March 5, 2010Date of Patent: July 17, 2012Assignee: Xerox CorporationInventors: Ke Zhou, Cuong Vong, Edward Graham Zwartz, Karen A. Moffat
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Patent number: 8211604Abstract: A process for making a self-emulsifying composite suitable for use in forming latex emulsions includes contacting a resin with a solid or highly concentrated surfactant, a solid neutralizing agent in the absence of water and an organic solvent to form a mixture, melt mixing the mixture, and forming a self-emulsifying composite of the melt mixed mixture such as a granule. Self-emulsifying granules are also provided and configured to form a latex emulsion when added to water, which may then be utilized to form a toner.Type: GrantFiled: June 16, 2009Date of Patent: July 3, 2012Assignee: Xerox CorporationInventors: Santiago Faucher, Rina Carlini, Joo T. Chung, Fumii Higuchi, Shigang Qiu, Allan K. Chen, Edward Graham Zwartz, Michael Steven Hawkins, Brian J. Andaya, Joseph L. Leonardo
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Publication number: 20120164569Abstract: A resin for toner containing a resin component having both a polyester unit produced by polycondensation of a polyhydric alcohol component and a polycarboxylic acid component, and an aryl group having a sulfonic ester group as a substituent; and a toner that contains the resin for toner.Type: ApplicationFiled: February 27, 2012Publication date: June 28, 2012Applicant: CANON KABUSHIKI KAISHAInventors: Norikazu Fujimoto, Hitoshi Itabashi, Atsushi Tani, Tetsuya Yano, Takeshi Ikeda, Takashi Kenmoku, Tatsuki Fukui
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Publication number: 20120156606Abstract: The present disclosure provides polymeric additives for use with toner particles. The polymeric additive of the present disclosure includes a copolymer possessing at least one monomer having a high carbon to oxygen ratio and at least a second amine-functional monomer. Toners possessing this polymeric additive exhibit excellent stability with respect to relative humidity and excellent charging characteristics.Type: ApplicationFiled: December 21, 2010Publication date: June 21, 2012Applicant: XEROX CORPORATIONInventors: Daryl W. Vanbesien, Richard P.N. Veregin, Suxia Yang, Corey L. Tracy, Karen Ann Moffat, Cuong Vong, Eric Rotberg, Michael S. Hawkins
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Publication number: 20120156605Abstract: The present disclosure provides polymeric additives for use with toner particles. The polymeric additive of the present disclosure includes a copolymer possessing at least one monomer having a high carbon to oxygen ratio, a monomer having more than one vinyl group, and at least one amine-functional monomer. Toners possessing this polymeric additive exhibit excellent stability with respect to relative humidity and excellent charging characteristics.Type: ApplicationFiled: December 21, 2010Publication date: June 21, 2012Applicant: XEROX CORPORATIONInventors: Daryl W. Vanbesien, Richard P.N. Veregin, Suxia Yang, Corey L. Tracy, Karen Ann Moffat, Cuong Vong, Eric Rotberg, Michael S. Hawkins
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Publication number: 20120135343Abstract: Provided is a toner for an electrostatic charge image development having toner particles which contain: a binder resin; a colorant; and a compound represented by Formula (1) in an amount of 0.1 to 65 ppm based on the total weight of the toner particles: wherein R1 and R2 each respectively represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or an aryl group.Type: ApplicationFiled: February 1, 2012Publication date: May 31, 2012Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.Inventors: Natsuko KUSAKA, Naohiro HIROSE, Tatsuya NAGASE, Hiroyuki YASUKAWA
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Patent number: 8178270Abstract: A toner for development of electrostatic images, comprising colored resin particles containing a binder resin and a colorant, and an external additive, wherein the external additive contains fine particles of an inorganic layered clay compound, and the inorganic layered clay compound is an intercalation compound with a quaternary ammonium ion intercalated between layers of the inorganic layered clay compound or has an interlayer distance of 1.5 to 4 nm.Type: GrantFiled: June 19, 2007Date of Patent: May 15, 2012Assignee: Zeon CorporationInventor: Kazuya Shiokawa
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Patent number: 8178274Abstract: The present disclosure provides toners and processes for preparing toner particles possessing excellent charging characteristics. The process includes forming a dispersion including at least one organic and/or organometallic charge control agent, and then combining that dispersion with an emulsion suitable for use in forming toner particles.Type: GrantFiled: July 21, 2008Date of Patent: May 15, 2012Assignee: Xerox CorporationInventors: Enno E. Agur, Daryl W. Vanbesien, Ke Zhou, Michael S. Hawkins, Maria N. V. McDougall, Richard P. N. Veregin, Edward G. Zwartz
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Polymer having a sulfonic group or a sulfonate group and an amide group and method of producing same
Patent number: 8178271Abstract: A polymer is provided in which a sulfonic group or a derivative thereof is introduced. The polymer includes a unit represented by the following chemical formula (1): wherein R represents -A1-SO2R1; A1 is selected from an alkylene group, a heterocyclic ring, an aromatic ring; and —SO2R1 is a sulfonic group or of a derivative of a sulfonic acid.Type: GrantFiled: May 20, 2010Date of Patent: May 15, 2012Assignee: Canon Kabushiki KaishaInventors: Tatsuki Fukui, Takashi Kenmoku, Ako Kusakari, Chieko Mihara, Tetsuya Yano, Norikazu Fujimoto -
Publication number: 20120107737Abstract: Toner particles are provided which may, in embodiments, include a core and a shell formed in situ. The resins utilized to form the core, the shell, or both, may be contacted with a water soluble initiator. The resin, in embodiments present in the shell, cross-links at a temperature near the temperature for coalescence, and may prevent a crystalline resin in the core from migrating to the toner surface.Type: ApplicationFiled: January 6, 2012Publication date: May 3, 2012Applicant: XEROX CORPORATIONInventors: Ke Zhou, Edward G. Zwartz, Karen Ann Moffat