By Coalescing Or Aggregating Patents (Class 430/137.14)
  • Patent number: 7507513
    Abstract: Copolymer encapsulated wax particles and their use in forming toner compositions having particles with a desired circularity and size are provided.
    Type: Grant
    Filed: December 13, 2005
    Date of Patent: March 24, 2009
    Assignee: Xerox Corporation
    Inventors: Yuhua Tong, Chieh-Min Cheng, Louis V. Isganitis, Eunhee Lee, Zhen Lai
  • Patent number: 7507516
    Abstract: Disclosed is a method of manufacturing toner comprising the steps of adding oil-droplets containing a radically polymerizable monomer into an associated particle dispersion formed by association-fusing resin particles and colorant particles, and forming a shell by coating a resin produced via polymerization on a surface of the associated particle by polymerizing the radically polymerizable monomer in the associated particle dispersion, wherein a hydrophilicity degree of the resin contained in the shell is larger than a hydrophilicity degree of a resin contained in the associated particle.
    Type: Grant
    Filed: June 1, 2006
    Date of Patent: March 24, 2009
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Kenji Hayashi, Kenji Yamane, Ryuji Kitani, Kouji Sugama
  • Patent number: 7507514
    Abstract: Toner containing binder resin constituted of plural types of copolymers comprising a vinyl type polymerizing monomer, wherein at least one of the copolymers comprising a vinyl type polymerizing monomer is one formed by utilizing a monomer provided with at least two polar groups.
    Type: Grant
    Filed: June 6, 2005
    Date of Patent: March 24, 2009
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Tomoko Tanma, Meizo Shirose, Asao Matsushima
  • Patent number: 7504189
    Abstract: A method for making toner particles having reduced toner charge transfer sensitivity when used in electrophotographic printers. The method includes preparing a dispersion of pigment, a fuser release agent, and a polymeric dispersant. The polymeric dispersant has a hydrophilic polymeric segment and at least one segment selected from the group consisting of a protective colloid segment and reactive surfactant segment. The polymeric dispersant also has a weight average molecular weight ranging from about 5,000 to about 30,000 as determined by gel permeation chromatography, and a hydrophobicity ranging from about 10 to about 90 percent by weight. The dispersion is mixed with a latex binder dispersion to provide a toner mixture. The toner mixture is agglomerated while stirring the mixture at an elevated temperature to provide toner particles.
    Type: Grant
    Filed: October 6, 2005
    Date of Patent: March 17, 2009
    Assignee: Lexmark International, Inc.
    Inventors: Jing X. Sun, Bradley Leonard Beach
  • Publication number: 20090061342
    Abstract: The present disclosure provides processes for reducing the particle size of latex resins and toners produced with such resins. In embodiments, a buffer may be added to materials utilized to produce a latex and reduce the particle size of the resulting latex particles and toner particles. In accordance with the present disclosure, one may be able to utilize materials for the production of latex resins and toners which may otherwise produce particles that are too large in the absence of the buffer.
    Type: Application
    Filed: September 5, 2007
    Publication date: March 5, 2009
    Inventors: Zhen Lai, Chieh-Min Cheng, Robert D. Bayley, Emily I. Moore, Shigang Qiu, Tie Hwee Ng
  • Publication number: 20090061343
    Abstract: A toner having its surface functionalized with functional groups, and processes for producing the same, are provided.
    Type: Application
    Filed: September 4, 2007
    Publication date: March 5, 2009
    Inventors: Zhen Lai, Yuhua Tong, Chieh-Min Cheng
  • Publication number: 20090061349
    Abstract: A process for preparing toner particles and compositions adapted for use in preparing toners that comprise a blend of a first polyester resin with a second sharp melting polyester resin. The process includes forming an emulsion resin comprising a branched polyester resin, a crystalline polyester resin, a colorant, and optionally a wax. The resin mixture is aggregated using an aggregating agent, such as a zinc acetate solution, to form an aggregate mixture. The aggregate mixture is then coalesced at a temperature of from about 5 to about 20° C. above the Tg of the emulsion resin to produce the resultant toner particles.
    Type: Application
    Filed: June 17, 2008
    Publication date: March 5, 2009
    Applicant: XEROX CORPORATION
    Inventors: Guerino G. Sacripante, Fatima M. Mayer, Kimberly D. Nosella, Valerie M. Farrugia, Raj D. Patel, Milan Maric, Allan K. Chen, Edward G. Zwartz, T. Hwee Ng
  • Patent number: 7498112
    Abstract: Disclosed is a toner particle having at least binder and colorant. The colorant is a dye complex comprising a dye, a nonionic surfactant and a complexing agent. The toner having this colorant exhibits improved color gamut.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: March 3, 2009
    Assignee: Xerox Corporation
    Inventor: Maura A Sweeney
  • Publication number: 20090053640
    Abstract: A toner is obtained in an aqueous medium by dispersing second resin particles into a core particles dispersion including at least first resin particles, and fusing the second resin particles with core particles. A second resin particle dispersion in which the second resin particles are dispersed is added after adjusting the pH value in the range of HS+2 to HS?5, where HS represents the pH value of the core particle dispersion in which the core particles are dispersed, so that toner particles have a volume-average particle size of 3 to 7 ?m, a content of the toner particles having a particle size of 2.52 to 4 ?m in a number distribution is 10 to 75% by number, the toner particles having a particle size of 4 to 6.06 ?m in a volume distribution is 25 to 75% by volume, and the toner particles having a particle size of not less than 8 ?m in the volume distribution is not more than 5% by volume.
    Type: Application
    Filed: February 10, 2006
    Publication date: February 26, 2009
    Applicant: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yasuhito Yuasa, Masahisa Maeda
  • Patent number: 7494757
    Abstract: A toner having an amorphous resin, a crystalline resin, and a colorant, wherein the crystalline resin has a melting temperature of at least 70° C. and a recrystallization point of at least 47° C. exhibits improved document offset properties and improved heat cohesion. Annealing the toner further improves the heat cohesion and morphology of the toner.
    Type: Grant
    Filed: March 25, 2005
    Date of Patent: February 24, 2009
    Assignee: Xerox Corporation
    Inventors: Guerino G. Sacripante, Ke Zhou, Michael S. Hawkins, Kimberly D. Nosella, Edward G. Zwartz, Nicoleta D. Mihai, Valerie M. Farrugia, Stephan V. Drappel, Paul J. Gerroir
  • Publication number: 20090047593
    Abstract: An emulsion aggregation toner including a core and a shell wherein the core includes an amorphous polyester, a wax, a crystalline polyester and an optional colorant and wherein the shell includes an amorphous polyester and a wax and is substantially free of crystalline polyester.
    Type: Application
    Filed: August 15, 2007
    Publication date: February 19, 2009
    Applicant: XEROX CORPORATION
    Inventors: Daryl W. VANBESIEN, Guerino G. SACRIPANTE, Michael S. HAWKINS, Peter J. G. REHBEIN
  • Publication number: 20090047595
    Abstract: A method for making toners to include clay composites. The clay composites are incorporated into emulsion of toner and used in making toner via emulsion aggregation. Such toners may have a core and/or a shell and the clay composites may be included with the core, the shell or both.
    Type: Application
    Filed: August 17, 2007
    Publication date: February 19, 2009
    Applicant: XEROX CORPORATION
    Inventors: Maria N. V. MCDOUGALL, Richard P. N. VEREGIN, Guerino G. SACRIPANTE, Valerie M. FARRUGIA
  • Publication number: 20090042119
    Abstract: A method of manufacturing toner particles capable of decreasing the manufacturing costs by simplifying the manufacturing apparatus and by decreasing the number of the steps, as well as to provide toner particles, a two-component developer, a developing apparatus and an image forming apparatus are provided. A high-pressure homogenizer is constituted by a tank, a feed pump, a high-pressure pump, a heat exchanger, a nozzle, a first depressurizing module, a cooling unit, a second depressurizing module and a take-out port arranged in this order. A flow path constituted in the first depressurizing module has a straight portion tilted with respect to a direction in which the aqueous slurry passes and a portion for relaxing the flow of the aqueous slurry.
    Type: Application
    Filed: August 8, 2008
    Publication date: February 12, 2009
    Inventors: Katsuru MATSUMOTO, Keiichi KIKAWA, Nobuhiro MAEZAWA
  • Publication number: 20090035682
    Abstract: A toner of the present invention includes a first wax and a second wax. The endothermic peak temperature of the first wax by the DSC method is 50° C. to 90° C. The endothermic peak temperature of the second wax is 5° C. to 50° C. higher than that of the first wax. Jmw1/Jw1 is 0.5 or less and Jmw2/Jw2 is 0.5 to 1.2, where Jw1 represents the endotherm of the first wax, Jw2 represents the endotherm of the second wax, Jmw1 represents the melting endotherm of the first wax by the MDSC method, and Jmw2 represents the melting endotherm of the second wax. The first wax and the second wax are mixed into a dispersion beforehand, the dispersion is then mixed with a resin particle dispersion and a colorant particle dispersion, and the particles are aggregated to form core particles. Thus, a toner having a small particle size and a sharp particle size distribution can be produced without requiring a classification process.
    Type: Application
    Filed: December 5, 2006
    Publication date: February 5, 2009
    Applicant: MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.
    Inventors: Michihiro Shima, Hidekazu Arase, Yasuhito Yuasa
  • Publication number: 20090035681
    Abstract: A toner or two-component developer is obtained by mixing, aggregating, and heating resin particles, colorant particles, and wax particles in an aqueous medium. A gel permeation chromatography (GPC) measurement of the resin particles shows that a weight-average molecular weight is 10000 to 60000, and the ratio of the weight-average molecular weight to a number-average molecular weight is 1.5 to 6. The wax particles include at least a first wax and a second wax. An endothermic peak temperature (melting point Tmw1 (° C.)) of the first wax based on a DSC method is 50° C. to 90° C. An endothermic peak temperature (melting point Tmw2 (° C.)) of the second wax based on the DSC method is at least 5° C. to 50° C. higher than Tmw1. Thus, the toner can have a smaller particle size and a sharp particle size distribution without requiring a classification process, can achieve a longer life, and can suppress transfer voids or scattering during transfer.
    Type: Application
    Filed: November 11, 2005
    Publication date: February 5, 2009
    Applicant: MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.
    Inventors: Yasuhito Yuasa, Hidekazu Arase, Masahisa Maeda
  • Publication number: 20090029282
    Abstract: The present disclosure relates to chemically processed toner. The toner may be prepared by an emulsion aggregation method by forming a polyester dispersion wherein the polyester has an acid value of about 5 to about 50 and a particle size of about 50 to about 500 nanometers. The polyester dispersion may then be combined with a pigment and/or release agent dispersion wherein the pigment and/or release agent dispersion may contain a dispersant. This may then be followed by heating and recovering agglomerated toner particles wherein the toner particles may have a mean particle size of about 3 to about 15 microns and an average degree of circularity of between about 0.90 to about 1.0.
    Type: Application
    Filed: July 26, 2007
    Publication date: January 29, 2009
    Inventors: Craig Michael Bertelsen, Ligia Aura Bejat, Michael James Bensing, John Joseph Kraseski, Matthew T. Martinkovic, Jing X. Sun
  • Publication number: 20090017396
    Abstract: The present invention is a method for the preparation of electrostatographic toner including the following steps. A first dispersion is prepared with a solvent, a silicone wax, and a hyperdispersant. The first dispersion is added to an organic solvent containing a polymer material to form an organic phase. The organic phase is dispersed in an aqueous phase containing a particulate stabilizer to form a second dispersion. The second dispersion is homogenized. The organic solvent is evaporated from the second dispersion and the resultant product is recovered, washed and dried. In an alternate method the hyperdispersant is added directly to the organic phase before mixing with the aqueous phase.
    Type: Application
    Filed: July 13, 2007
    Publication date: January 15, 2009
    Inventors: Xiqiang Yang, Dinesh Tyagi
  • Publication number: 20090017393
    Abstract: Disclosed herein are emulsion aggregation toner particles having less than about 15 atomic percent oxygen in relation to a total atomic percent of 100 for all elements on the surface thereof. Such toner particles exhibit lower marks on print defects.
    Type: Application
    Filed: July 12, 2007
    Publication date: January 15, 2009
    Applicant: XEROX CORPORATION
    Inventors: Karen A. MOFFAT, Juan A. MORALES-TIRADO, Thomas P. DEBIES, William H. HOLLENBAUGH, Jr., Emily L. MOORE, Nancy S. HUNT
  • Patent number: 7476481
    Abstract: An electrostatic charge image developing toner comprises core particles formed by flocculating and fusion-bonding at least polyester resin particles containing wax and colorant particles, and a coating layer containing a resin formed over the core particles.
    Type: Grant
    Filed: November 5, 2004
    Date of Patent: January 13, 2009
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Yasumitsu Fujino, Hideaki Ueda, Seishi Ojima, Fumie Motoori
  • Patent number: 7476480
    Abstract: Herein is disclosed a process for producing emulsion aggregation toner including (i) adding a base to an emulsion aggregation toner to increase the pH of the toner to from about 7 to about 12; (ii) sieving and filtering the toner; (iii) washing the toner with an enzyme selected from the group consisting of carboxylic ester hydrolase and sulfuric ester hydrolase; (iv) filtering the toner; (v) washing the toner with reverse osmosis or deionized water; and (vi) adding an acid to reduce the pH of the toner to from about 3 to about 8.
    Type: Grant
    Filed: January 9, 2007
    Date of Patent: January 13, 2009
    Assignee: Xerox Corporation
    Inventors: Steven M. Malachowski, Amy A. Grillo, Eugene F. Young
  • Publication number: 20090011352
    Abstract: The invention relates to a versatile process for preparing composite powders that can be used as novel electrostatic charge control agents, dry or liquid toners, and specialty imaging materials. The process involves impregnating specific sized, porous, inorganic core particles with chemical compositions that include one or more polymers or waxes and at least one additional chemical chosen from dyes, pigments, carbon black, inorganic chemicals or organic chemicals. The impregnated core may optionally be coated with additional components to produce a core/shell structure.
    Type: Application
    Filed: January 17, 2008
    Publication date: January 8, 2009
    Inventor: John Francis Cooper
  • Publication number: 20090011355
    Abstract: There are provided a toner that allows prevention of environmental contamination and is nevertheless free from toner durability degradation, wherein a sufficiently wide color reproduction range can be secured even when it is applied to color toner, and variation in characteristics among toner particles can be suppressed, as well as a method of manufacturing a toner, a developing device, and an image forming apparatus. In the toner particle is formed the biomass resin-containing domain.
    Type: Application
    Filed: July 7, 2008
    Publication date: January 8, 2009
    Inventor: Yasuhiro SHIBAI
  • Publication number: 20090011351
    Abstract: A toner capable of forming high quality images of excellent image reproducibility at high definition and high resolution, being decreased for the bleed-out of a wax ingredient to the surface, causing less filming to a photoreceptor and offset phenomenon in a high temperature region, is provided. The toner is manufactured by a method including a preliminary pulverizing step of pulverizing a melt-kneaded product of toner raw materials in a liquid to obtain a coarse powder slurry containing a coarse toner powder, a finely pulverizing step of passing the coarse powder slurry through a pressure resistant nozzle under heating and pressurization thereby further pulverizing the coarse toner powder to obtain a fine powder slurry containing a fine toner powder and in a heated and pressurized state, a cooling step of cooling the fine powder slurry, and a depressurizing step of depressurizing the fine powder slurry.
    Type: Application
    Filed: July 3, 2008
    Publication date: January 8, 2009
    Inventors: Keiichi Kikawa, Katsuru Matsumoto
  • Publication number: 20090011358
    Abstract: A method of manufacturing a toner in which uneven distribution of toner ingredients by subjecting them to fine dispersion is prevented and which is excellent in transferability, cleaning properties, anti-filming properties, anti-blocking properties, high-temperature offset resisting properties and transparency is provided. Melt-kneaded substances include binder resins, colorants and release agents, respectively. The colorant and the release agent are dispersed in the binder resin. The melt-kneaded substance is negatively charged by an anionic dispersant, whereas the melt-kneaded substance is positively charged by a cationic dispersant. An aggregate is formed by heteroaggregation of the melt-kneaded substances. The aggregate is fused by heating and formed into a spherical toner.
    Type: Application
    Filed: July 2, 2008
    Publication date: January 8, 2009
    Inventors: Keiichi Kikawa, Yasuhiro Shibai, Katsuru Matsumoto
  • Patent number: 7473511
    Abstract: The invention provides a particle dispersion for an electrostatic image-developing toner containing either polycondensation resin particles, which are prepared by polycondensation of polycondensable monomers in an aqueous medium, or condensation compound particles, which are prepared by dehydration condensation of a condensable compound in an aqueous medium. The particles have a median diameter of approximately 0.05 to 2.0 ?m. A dispersion containing the polycondensation resin particles is produced by dispersing resin particles, aggregating the resin particles, and coalescing the aggregated particles by heating.
    Type: Grant
    Filed: May 3, 2005
    Date of Patent: January 6, 2009
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yasuo Matsumura, Hirotaka Matsuoka, Hideo Maehata, Satoshi Hiraoka, Yuki Sasaki, Fumiaki Mera
  • Publication number: 20090004589
    Abstract: The present invention provides toner containing core particles prepared by mixing and aggregating in an aqueous medium at least a first resin particle dispersion in which first resin particles are dispersed, a colorant particle dispersion in which particles of colorant are dispersed and a wax particle dispersion in which particles of wax are dispersed. The colorant contains carbon black having a DBP oil absorption of 45 to 70 (ml/100 g) and the wax contains a wax having an endothermic peak temperature (referred to as melting point Tmw1 (° C.)) according the DSC method of 50 to 90° C. It is thus possible to prepare toner that has a small particle size and a sharp particle size distribution without requiring a classification process and that can prevent transfer void and toner scattering during transfer and obtain high transfer efficiency. The present invention provides also a method for producing the toner.
    Type: Application
    Filed: November 28, 2006
    Publication date: January 1, 2009
    Applicant: MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.
    Inventors: Yasuhito Yuasa, Mamoru Soga, Hidekazu Arase, Masahisa Maeda
  • Publication number: 20090004593
    Abstract: A liquid developer which includes toner particles having small particle size distribution, uniform shape, and excellent fixing properties to a recording medium is provided, a liquid developer which includes toner particles having small particle size distribution and uniform shape and being capable of exhibiting a property of each of materials constituting the toner particles sufficiently is also provided, and a liquid developer having excellent anti-offset properties (mold release properties) is also provided, and further a method of producing a liquid developer capable of producing such a liquid developer efficiently is also provided. In particular, a producing method capable of producing such a liquid developer as described above in a method harmless to the environment is provided.
    Type: Application
    Filed: January 16, 2006
    Publication date: January 1, 2009
    Applicant: SEIKO EPSON CORPORATION
    Inventors: Hiroshi Kaiho, Satoru Miura
  • Publication number: 20090004591
    Abstract: Disclosed is a toner for developing electrostatic image containing toner particles prepared with a method containing a step of: coagulating resin particle A, resin particle B and a colorant, wherein resin particle A and resin particle B respectively have volume average particle diameters Da and Db which are different in value from each other; and Da and Db satisfy the following relationship: 0.05?Db/Da?0.7.
    Type: Application
    Filed: March 6, 2008
    Publication date: January 1, 2009
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Tsuyoshi UCHIDA, Masahiro ANNO, Yukio HOSOYA, Masaharu SHIRAISHI
  • Publication number: 20080318151
    Abstract: A method for preparing latex for a toner includes heating a mixture of distilled deionized water and poly (ethylene glycol)-ethyl ether methacrylate (PEG-EEM) with stirring, adding a monomer mixture, 1-dodecanethiol and an ester wax to the mixture, dispersing the mixture with ultrasonic vibration, adding potassium persulfate (KPS) to the dispersion and allowing to react for 4 to 6 hours, and allowing the reaction mixture to cool with stirring. The dry toner prepared by the method enables easy control over the molecular weight of latex, has superior durability and excellent low-temperature fixation, contains a small amount of wastewater and is composed of small-diameter particles, thus being suitable for use in high-definition printers.
    Type: Application
    Filed: May 9, 2008
    Publication date: December 25, 2008
    Inventors: Yoda Shin, Kyung Yol Yon, Jun Young Lee, Tae Hoe Koo
  • Publication number: 20080318141
    Abstract: A method of preparing toner, the method including preparing a latex for a core by polymerizing a composition for a core including a macromonomer having a hydrophilic group, a hydrophobic group and at least one reactive functional group, at least one polymerizable monomer, and a wax; agglomerating the latex for a core by adding a pigment dispersion dispersed by the macromonomer and an inorganic salt to the prepared latex for a core; and coating the agglomerated latex for a core using a latex for a shell layer, wherein the latex for a shell layer is prepared by polymerizing a composition for a shell layer including at least one polymerizable monomer, a macroinitiator having polydimethyl siloxane units, and a macromonomer, and toner prepared according to the method.
    Type: Application
    Filed: January 23, 2008
    Publication date: December 25, 2008
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Yo-da SHIN, Kyung-yol YON, Kyeong PANG, Tae-hoe KOO
  • Patent number: 7468232
    Abstract: A process for preparing a latex includes polymerizing at least one monomer in the presence of an initiator to form a polymer emulsion; and adding an odor-scavenging bismuth compound to the formed polymer emulsion.
    Type: Grant
    Filed: April 27, 2005
    Date of Patent: December 23, 2008
    Assignee: Xerox Corporation
    Inventors: Robert D. Bayley, Maura A. Sweeney, Grazyna Kmiecik-Lawrynowicz
  • Publication number: 20080311504
    Abstract: A method of manufacturing toner including adding an oil phase comprising an organic solvent in which a binder resin, a coloring agent and a releasing agent are dissolved or dispersed and an aqueous phase to an emulsification device equipped with a stirrer, continuously dispersing or emulsifying the oil phase and the aqueous phase in the emulsification device equipped with a stirrer to form a liquid dispersion or emulsion comprising oil phase particles, transporting the liquid dispersion or emulsion to a tank, removing the organic solvent from the liquid dispersion or emulsion followed by drying to form mother toner particles, wherein the releasing agent has been preliminarily prepared to have a dispersion diameter of from 0.15 to 0.
    Type: Application
    Filed: May 21, 2008
    Publication date: December 18, 2008
    Inventors: Mizuki HATTORI, Shinzo Higuchi, Takahiro Kadota, Daisuke Misawa, Hiroshi Takahashi, Toshihiko Usami, Masashi Miyakawa
  • Publication number: 20080311503
    Abstract: A toner composed of small particles excellent in a cleaning property, a transferring property, and charge uniformity is provided as well as a method of manufacturing the toner, and two-component developer, developing device, and image forming apparatus using the toner. The toner contains binder resin and colorant, and includes a particle which has an outline having one or more and three or less bending points in its projection image on a plane. The toner thus contains a non-spherical particle and therefore is caught easily by a cleaning blade as well as coming into point-contact with a to-be-transferred member, therefore being capable of having both of cleaning property and transferring property.
    Type: Application
    Filed: June 17, 2008
    Publication date: December 18, 2008
    Applicant: SHARP KABUSHIKI KAISHA
    Inventors: Ayae Nagaoka, Satoru Ariyoshi, Tadashi Iwamatsu, Katsuru Matsumoto
  • Publication number: 20080305422
    Abstract: A chemical toner is described as well as methods of preparing the same.
    Type: Application
    Filed: June 6, 2008
    Publication date: December 11, 2008
    Inventors: Anne K. Shim, Eugene N. Step, Agathagelos Kyrlidis
  • Patent number: 7459258
    Abstract: Processes for continuously forming latex emulsions and preparing toners with said emulsions are provided.
    Type: Grant
    Filed: June 17, 2005
    Date of Patent: December 2, 2008
    Assignee: Xerox Corporation
    Inventors: Joo T. Chung, Chieh-Min Cheng, Hui Chang
  • Patent number: 7459254
    Abstract: Toner includes aggregated and associated particles formed by mixing in an aqueous medium at least a resin particle dispersion in which resin particles are dispersed, a colorant particle dispersion in which colorant particles are dispersed, and a wax particle dispersion in which wax particles are dispersed and heat-treating the mixed dispersion for aggregation. The aggregated and associated particles include first particles having a capsule structure in which aggregated wax with an average particle size of greater than 1 ?m is incorporated into the resin, and second particles formed of the resin and the wax in a mixed and dispersed state. The toner can achieve oilless fixing that prevents offset without using oil while maintaining high OHP transmittance and also can eliminate spent of the toner components on a carrier to make the life longer.
    Type: Grant
    Filed: November 2, 2004
    Date of Patent: December 2, 2008
    Assignee: Panasonic Corporation
    Inventors: Yasuhito Yuasa, Mamoru Soga, Hidekazu Arase
  • Patent number: 7459253
    Abstract: A toner is provided which is excellent in low-temperature fixability and offset resistance, has a wide fixing temperature range, provides fixed images with high gloss, and can form toner images having high quality. The toner is composed of toner particles having toner base particles each containing a binder resin and a colorant. When the viscosities of each of the toner particles measured at 100° C. and 110° C. by a flow tester heat-up method are represented by ?100 (Pa·s) and ?110 (Pa·s), respectively, an average variation in viscosity A?T represented by the following equation (1) satisfies the relationship of 0?A?T??0.064: A?T=(log(?110)?log(?100)/(110?100); and??(1) ?100 is 15,000 to 40,000 Pa·s.
    Type: Grant
    Filed: April 25, 2007
    Date of Patent: December 2, 2008
    Assignee: Canon Kabushiki Kaisha
    Inventors: Koji Abe, Shinya Yachi, Emi Tosaka, Satoshi Handa, Kazumi Yoshizaki, Yasuhiro Hashimoto, Yushi Mikuriya
  • Patent number: 7455943
    Abstract: The toner includes emulsion aggregation toner particles of a binder including a non-crosslinked styrene acrylate polymer, at least one colorant, at least one wax, and aluminized silica, wherein an amount of aluminum metal in the toner particles is from about 50 ppm to about 600 ppm. Such toner is able to provide a high level of gloss while maintaining a low minimum fixing temperature. The aluminized silica acts as a coagulant during the emulsion aggregation formation process of the toner.
    Type: Grant
    Filed: October 17, 2005
    Date of Patent: November 25, 2008
    Assignee: Xerox Corporation
    Inventors: Raj D. Patel, Daryl W. Vanbesien, David J. Sanders, Allan K. Chen
  • Patent number: 7455944
    Abstract: The present invention provides a toner for developing electrostatic latent images, including resin particles containing a crystalline polymer and an amorphous polymer, wherein the amorphous polymer and the crystalline polymer satisfy the relationship represented by the following formula (1), and a method for manufacturing the toner of the invention. The present invention also provides a developer for electrostatic latent images including the toner of the invention and a carrier; and an image forming method using the toner of the invention. Further the invention provides a method for manufacturing a dispersion of resin particles. ?a??c?1.05[(cal/ml)1/2(25° C.)]??Formula (1) In formula (1), ?a represents a solubility parameter of the amorphous polymer, and ?c represents a solubility parameter of the crystalline polymer.
    Type: Grant
    Filed: September 9, 2005
    Date of Patent: November 25, 2008
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Hideo Maehata, Yasuo Yamamoto, Satoshi Hiraoka, Yasuo Matsumura, Hirotaka Matsuoka, Yuki Sasaki, Fumiaki Mera
  • Publication number: 20080286674
    Abstract: A method for producing a toner is described. The method for producing a toner may include the steps of: preparing a resin solution by mixing a binder resin, a colorant and a wax into an organic solvent; preparing an emulsion by heating the resin solution and an aqueous medium to a temperature of not less than a level allowing the wax to dissolve and less than the boiling point of the organic solvent, and mixing the resin solution and the aqueous medium with each other; and preparing a suspension by removing the organic solvent from the emulsion, and aggregating and fusing the suspension.
    Type: Application
    Filed: May 16, 2008
    Publication date: November 20, 2008
    Applicant: BROTHER KOGYO KABUSHIKI KAISHA
    Inventors: Masateru Kawamura, Jun Ikami
  • Publication number: 20080286680
    Abstract: A method for manufacturing a toner, including periodically forming liquid droplets of a toner constituent liquid comprising a resin and a colorant by vibrating a thin film having a plurality of holes provided on a retention part thereof to discharge the liquid droplets of the toner constituent liquid from the plurality of holes and forming toner particles by solidifying the liquid droplets discharged from the plurality of holes. In periodically forming the liquid droplets of the toner constituent liquid, a flow of gas in a direction of discharge of the liquid droplets is formed by a gas flow generation unit provided downstream from the thin film relative to the direction of discharge of the liquid droplets, including a tapered part forming an aperture corresponding to a hole formation area of the thin film.
    Type: Application
    Filed: May 15, 2008
    Publication date: November 20, 2008
    Inventors: Yoshihiro Norikane, Shinji Ohtani, Yohichiroh Watanabe, Kazumi Suzuki
  • Publication number: 20080286679
    Abstract: A method of preparing a toner, including periodically dripping and discharging droplets of a toner constituent liquid comprising a resin and a colorant with a dripper comprising a thin film comprising plural nozzles configured to discharge the droplets, and an electromechanical converter configured to oscillate the thin film; and solidifying the droplets to form toner particles, wherein the nozzle has an aperture discharging the droplet, having a circular or an ellipsoidal cross-sectional shape and cross-sectional area smaller than a cross-sectional area of another aperture contacting the toner constituent liquid.
    Type: Application
    Filed: May 14, 2008
    Publication date: November 20, 2008
    Applicant: Ricoh Company, Ltd.
    Inventors: Yoshihiro NORIKANE, Shinji Ohtani, Yohichiroh Watanabe, Kazumi Suzuki, Takahiro Honda
  • Patent number: 7452654
    Abstract: A toner production method includes the step of: controlling a shape of toner particles in a shape controlling region to control the shape of toner particles in a water based medium, wherein the shape controlling region has a toner channel for the toner particles and a temperature controller capable of controlling at least two zones.
    Type: Grant
    Filed: September 23, 2005
    Date of Patent: November 18, 2008
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Naohiro Hirose, Ken Ohmura
  • Patent number: 7452653
    Abstract: A process for producing a polymerized toner, which comprises steps of forming an aqueous dispersion comprising the colored polymer particles, subjecting the aqueous dispersion comprising the colored polymer particles to stripping treatment in the presence of a nonionic surfactant, dehydrating and washing the aqueous dispersion, wherein washing is carried out by using a washing water a temperature of which is controlled to lower than the cloud point of the nonionic surfactant, drying the wet colored polymer particles, and then getting the colored polymer particles.
    Type: Grant
    Filed: August 26, 2004
    Date of Patent: November 18, 2008
    Assignee: Zeon Corporation
    Inventor: Katsutomo Tanaka
  • Publication number: 20080268368
    Abstract: Toner of the present invention includes aggregated particles formed by aggregating at least resin particles, pigment particles, and wax particles in an aqueous medium in the presence of a water-soluble inorganic salt. The wax includes at least one selected from the following: ester wax that has an iodine value of not more than 25, a saponification value of 30 to 300, and an endothermic peak temperature (melting point) of 50° C. to 100° C. based on a DSC method; and wax that is obtained by a reaction of alkyl alcohol having a carbon number of 4 to 30, unsaturated polycarboxylic acid or its anhydride, and synthetic hydrocarbon wax, and has an acid value of 1 to 80 mgKOH/g and an endothermic peak temperature (melted point) of 50° C. to 120° C. based on the DSC method.
    Type: Application
    Filed: June 19, 2008
    Publication date: October 30, 2008
    Applicant: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yasuhito Yuasa, Mamoru Soga, Hidekazu Arase
  • Publication number: 20080268365
    Abstract: A process for preparing a toner for electrophotography containing mother toner particles which contain a resin binder containing a crystalline polyester and a linear amorphous polyester and an external additive, wherein the process includes an external addition step of mixing the mother toner particles and at least a part of the external additive and the step of carrying out a heat-treating step at the external addition step or later. The toner for electrophotography obtained according to the present invention is suitably used for, for example, developing a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method, or the like.
    Type: Application
    Filed: April 22, 2008
    Publication date: October 30, 2008
    Applicant: KAO CORPORATION
    Inventors: Masahito YAMAZAKI, Satoshi Kunii
  • Patent number: 7442740
    Abstract: A toner process that includes a first heating of a colorant dispersion, a first polyester resin free latex emulsion, a second polyester latex emulsion, and a wax dispersion in the presence of a coagulant containing a metal ion; adding a third polyester free latex; adding an organic sequestering compound or a silicate salt sequestering compound, followed by a second heating.
    Type: Grant
    Filed: April 8, 2008
    Date of Patent: October 28, 2008
    Assignee: Xerox Corporation
    Inventors: Raj D Patel, Guerino G Sacripante, Edward G Zwartz, Enno E Agur, Allan K Chen, T. Hwee Ng, Kimberly D Nosella, Cuong Vong, Karen A Moffat
  • Publication number: 20080261142
    Abstract: The present invention pertains to a process for the preparation of a toner powder, in which particles of one or more toner base compositions are combined into larger particles. The toner base compositions may be in the form of dry powders, e.g., manufactured by jet milling or by freeze drying powder dispersions. In that case, the combination of the toner base compositions into larger particles may be done by, e.g., mechanofusion. The toner base composition may also be in the form of an aqueous emulsion or dispersion. In that case, the combination of the base compositions into larger particles can be effected by spray-drying the emulsion or dispersion. In a preferred embodiment, the toner base composition in aqueous form is prepared via phase inversion emulsification, which preferably is carried out in an extruder.
    Type: Application
    Filed: July 11, 2006
    Publication date: October 23, 2008
    Inventors: Kevin Jeffrey Kittle, Andrew Robert Morgan
  • Publication number: 20080261144
    Abstract: A method for producing a developing agent, includes preparing a dispersion of particles containing a binder resin and a coloring agent and forming toner particles by aggregating and fusing the particles, in which the number of coarse particles having a particle size of 0.6 ?m or larger after the solid concentration of the dispersion of particles is adjusted to 1 ppm is less than 3,000 per ?L.
    Type: Application
    Filed: April 16, 2008
    Publication date: October 23, 2008
    Applicants: KABUSHIKI KAISHA TOSHIBA, TOSHIBA TEC KABUSHIKI KAISHA
    Inventors: Masahiro Ikuta, Takayasu Aoki, Takashi Urabe, Tsuyoshi Ito, Motonari Udo, Satoshi Araki
  • Patent number: 7439004
    Abstract: Methods include washing and de-watering toner particles using a horizontal filter press.
    Type: Grant
    Filed: November 30, 2004
    Date of Patent: October 21, 2008
    Assignee: Xerox Corporation
    Inventors: Steven M Malachowski, Chieh-Min Cheng, David Kurceba, Tie Hwee Ng, Abdisamed Sheik-Qasim, Melanie Davis