By Coalescing Or Aggregating Patents (Class 430/137.14)
  • Publication number: 20100173244
    Abstract: A process for preparing a toner comprising a binder resin and a colorant, wherein the binder resin comprises a polyester resin having an acid value greater than 5 mg KOH/g, the process comprising: providing an aqueous dispersion of polyester resin particles stabilised by an ionic surfactant and then associating the polyester resin particles.
    Type: Application
    Filed: June 20, 2008
    Publication date: July 8, 2010
    Inventors: Daniel Patrick Morris, John Dylan Morgan, Martin Russell Edwards, Miguel Angel Rodriguez-Vazquez, Mohammed Nawaz, Zoonia Mehmood
  • Patent number: 7749672
    Abstract: An emulsion aggregation polyester toner including a polyester resin having modified end groups, wherein the polyester resin includes at least one carboxylic end group. A process of making the toner by oxidation of a polyester resin including reacting the polyester with a hypohalite and a phase transfer catalyst results in a polyester resin endcapped with at least one acidic group. Stable xerographic charging in all ambient environments for all colors, and excellent resistivity and cohesion of the toner, may be achieved.
    Type: Grant
    Filed: December 21, 2006
    Date of Patent: July 6, 2010
    Assignee: Xerox Corporation
    Inventor: Valerie M. Farrugia
  • Patent number: 7749673
    Abstract: A toner process comprising the aggregation and coalescence of an amorphous polyester, a crystalline polyester and a colorant, and wherein the coalescence is conducted at a temperature that is about lower than the melting point temperature of the crystalline polyester.
    Type: Grant
    Filed: March 29, 2007
    Date of Patent: July 6, 2010
    Assignee: Xerox Corporation
    Inventors: Ke Zhou, Guerino G. Sacripante, Karen A. Moffat, Michael S. Hawkins, Paul J. Gerroir, Richard P. N. Veregin
  • Publication number: 20100167197
    Abstract: A toner includes aggregated particles produced by preparing in an aqueous medium a mixed dispersion including at least a first resin particle dispersion in which first resin particles are dispersed, a colorant particle dispersion in which colorant particles are dispersed, and a wax particle dispersion in which wax particles are dispersed, heating the mixed dispersion so that at least part of the wax particles is melted, and aggregating the first resin particles, the colorant particles, and the wax particles at least part of which is melted by the addition of an aqueous solution containing an aggregating agent. Thus, the toner can have a smaller particle size and a sharp particle size distribution without requiring a classification process. Moreover, the toner can achieve a longer life and suppress transfer voids or scattering during transfer.
    Type: Application
    Filed: July 27, 2006
    Publication date: July 1, 2010
    Applicant: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yasuhito Yuasa, Masahisa Maeda, Hidekazu Arase
  • Patent number: 7745085
    Abstract: A toner for developing an electrostatic latent image that includes a crystalline polyester resin and a release agent, wherein structures in which the crystalline polyester resin contacts the release agent exist in a ruthenium-stained cross section of the toner, and if the cross-sectional area of these structures is labeled A, the cross-sectional area of lone portions of the release agent is labeled B, and the cross-sectional area of lone portions of the crystalline polyester resin is labeled C, then 40?100×A/(A+B+C)?70, 10?100×B/(A+B+C)?30, and 20?100×C/(A+B+C)?30.
    Type: Grant
    Filed: March 27, 2007
    Date of Patent: June 29, 2010
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Takao Ishiyama, Takashi Inukai, Akitsugu Seto, Tomohito Nakajima
  • Publication number: 20100159386
    Abstract: A method for producing a developing agent, wherein in the formation of aggregated particles, particles in a dispersion liquid have a volume average particle diameter of 2 ?m or less when the pH of the dispersion liquid is 7, and also the pH of the dispersion liquid is from 3.0 to 6.9 when the zeta potential of the particles is ?30 mV.
    Type: Application
    Filed: December 15, 2009
    Publication date: June 24, 2010
    Applicants: KABUSHIKI KAISHA TOSHIBA, TOSHIBA TEC KABUSHIKI KAISHA
    Inventors: Takashi Urabe, Takayasu Aoki, Tsuyoshi Itou, Motonari Udo, Satoshi Araki, Masahiro Ikuta, Takafumi Hara
  • Publication number: 20100159375
    Abstract: Disclosed is a toner composition comprising toner particles which comprise a resin, an optional colorant, and a polyhedral oligomeric silsesquioxane compound.
    Type: Application
    Filed: December 18, 2008
    Publication date: June 24, 2010
    Applicant: Xerox Corporation
    Inventors: Ke Zhou, Karen A. Moffat, Maria N. V. McDougall, Richard P. N. Veregin, Edward G. Zwartz
  • Publication number: 20100159387
    Abstract: The present disclosure provides processes for preparing toner particles, in which fewer coarse particles are generated. The process includes introducing a buffer solution during coalescence of the toner slurry. The amount of coarse particles in the resulting toner particles may, in embodiments, be reduced to less than about 5 percent by weight of the total toner particles generated.
    Type: Application
    Filed: March 4, 2010
    Publication date: June 24, 2010
    Applicant: XEROX CORPORATION
    Inventors: Kimberly D. Nosella, Guerino G. Sacripante
  • Publication number: 20100159376
    Abstract: Disclosed is a toner composition comprising toner particles which comprise (a) a resin having chemically bonded thereto a polyhedral oligomeric silsesquioxane, (b) and an optional colorant.
    Type: Application
    Filed: December 18, 2008
    Publication date: June 24, 2010
    Applicant: Xerox Corporation
    Inventors: Ke Zhou, Maria N. V. McDougall, Yu Qi, Jordan Wosnick, Karen A. Moffat, Paul J. Gerroir, Richard P. N. Veregin
  • Publication number: 20100159379
    Abstract: Disclosed are a toner for developing an electrostatic latent image and a method of preparing the same. The toner may include latex, a pigment and a releasing agent. The lowest crossover temperature of the toner at which the storage modulus (G?) and the loss modulus (G?) of the toner are substantially equal to each other may be in the range of about 65 to about 80° C. The weight average molecular weight (Mw) of the toner may be in the range of about 65,000 to about 75,000. The z-average molecular weight (Mz) of the toner may be in the range of about 110,000 to about 220,000.
    Type: Application
    Filed: December 7, 2009
    Publication date: June 24, 2010
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Jun-Young LEE, Min-Young Cheong, Jae-Hwan Kim, Yo-Da Shin, Tae-Hoe Koo
  • Patent number: 7741002
    Abstract: The present invention provides a method for producing a toner including preparing an emulsified dispersion which contains emulsion particles by emulsifying or dispersing an oil phase containing at least a pigment and any one of a binder resin and a binder resin precursor in an aqueous medium, and granulating toner base particles by converging the emulsified dispersion, wherein the Casson yield value of the single oil phase before being emulsified or dispersed in the aqueous medium is 0.5 Pa to 20 Pa; and the temperature Tn of the emulsified dispersion in the preparation of the emulsified dispersion, the temperature Ts of the emulsified dispersion in the granulation of the toner base particles, and the glass transition temperature Tg of the toner base particles satisfy the relation Tn<Ts<Tg.
    Type: Grant
    Filed: November 10, 2006
    Date of Patent: June 22, 2010
    Assignee: Ricoh Company, Ltd.
    Inventors: Osamu Uchinokura, Fumihiro Sasaki, Satoshi Mochizuki, Hidetoshi Noda, Tsuyoshi Fukushima, Koutaro Kitano
  • Patent number: 7741001
    Abstract: A process for preparing a toner for electrostatic image development, the process comprising the steps of: (S1) mixing an aqueous pigment dispersion and an aqueous resin particle dispersion containing self-dispersible polyester resin particles as a binder resin to prepare a mixture; and (S2) adding a polyvalent metal salt as a flocculant to the mixture while stirring to form aggregates of the pigment bonded to the resin particles, wherein the self-dispersible polyester resin is prepared by reacting a carboxylic acid compound with an alcohol compound inclusive of a polyhydric alcohol, the carboxylic acid compound being one or more of a polycarboxylic acid having three or more carboxyl groups and its anhydride.
    Type: Grant
    Filed: April 3, 2006
    Date of Patent: June 22, 2010
    Assignee: Sharp Kabushiki Kaisha
    Inventor: Takanori Kamoto
  • Publication number: 20100151377
    Abstract: Disclosed is a toner, comprising: a noncrystalline polyester resin; a crystalline polyester resin; a release agent; and a coloring agent, wherein the toner has a domain matrix structure in which the matrix comprises the noncrystalline polyester resin and the domain comprises the crystalline polyester resin and the release agent, and wherein the crystalline polyester resin includes within the release agent.
    Type: Application
    Filed: December 10, 2009
    Publication date: June 17, 2010
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Yasuko UCHINO, Mikihiko SUKENO, Tomomi OSHIBA, Nagayuki UEDA, Makoto KOBAYASHI, Ken OHMURA
  • Patent number: 7736832
    Abstract: Toners made by the emulsion aggregation process comprising an amorphous resin and a nucleated crystalline resin. Such toners demonstrate improved charging performance in the A-zone and the C-zone, improved heat cohesion and improved resistivity.
    Type: Grant
    Filed: January 29, 2007
    Date of Patent: June 15, 2010
    Assignee: Xerox Corporation
    Inventors: Valerie M. Farrugia, Michael S. Hawkins, Rosa M. Duque, Britawit Asfaw, Richard P. N. Veregin, Guerino G. Sacripante
  • Patent number: 7736831
    Abstract: A process for preparing a toner includes mixing a polymeric resin emulsion, a colorant dispersion, and a wax to form a mixture; optionally adding a coagulant to the mixture; heating the mixture at a temperature below a glass transition temperature of the polymeric resin to aggregate the polymeric resin, colorant, and wax, to form aggregated particles; adding a coalescent agent to the aggregated particles; heating the aggregated particles and coalescent agent at a temperature above the glass transition temperature of the polymeric resin, to coalesce the aggregated particles to form toner particles, optionally cooling the mixture, and isolating the tone particles.
    Type: Grant
    Filed: September 8, 2006
    Date of Patent: June 15, 2010
    Assignee: Xerox Corporation
    Inventors: Zhen Lai, Richard Fong, Yuhua Tong, Chieh-Min Cheng, Amy A. Grillo, Paul F. Smith, Paul J. Gerroir, Beng S. Ong
  • Publication number: 20100143839
    Abstract: The present disclosure provides processes for increasing the shelf life and stability of resin emulsions suitable for use in forming toner particles. In embodiments, the pH of the resin emulsion is monitored, and a base is added as needed to maintain the pH of the emulsion at from about 6.5 to about 8. Maintaining the pH at from about 6.5 to about 8 prevents the degradation of the resin in the emulsion, including its molecular weight.
    Type: Application
    Filed: December 9, 2008
    Publication date: June 10, 2010
    Applicant: Xerox Corporation
    Inventors: Kimberly D. Nosella, Enno E. Agur, Shigang Qiu, Ke Zhou
  • Patent number: 7732115
    Abstract: The present invention relates to toner compositions comprising a resin and a colorant. Various embodiments of the colorant used in the toner compositions are disclosed, including a modified pigment comprising a pigment having attached at least one organic group having the formula -X-I, wherein X, which is directly attached to the pigment, represents an arylene or heteroarylene group, or an alkylene group, and I represents a non-polymeric group comprising at least one ionic group or at least one ionizable group. Processes for preparing toner compositions are also described.
    Type: Grant
    Filed: December 16, 2009
    Date of Patent: June 8, 2010
    Assignee: Cabot Corporation
    Inventors: Eugene N. Step, Agathagelos Kyrlidis
  • Publication number: 20100136470
    Abstract: The present invention relates to a resin emulsion which has a good emulsification performance even when produced by using a crosslinked polyester resin as a binder resin, and also is capable of producing a toner having an excellent storage property therefrom; and a process for producing the resin emulsion. The process for producing a resin emulsion according to the present invention, includes the steps of: (a) mixing a resin containing a polyester having at least one constitutional unit selected from the group consisting of a constitutional unit derived from a trivalent or higher-valent alcohol component and a constitutional unit derived from a trivalent or higher-valent carboxylic acid component, an anionic surfactant, a nonionic surfactant and an aqueous medium with each other at a temperature not lower than a softening temperature (Ts) of the resin as measured by a flow tester method, the nonionic surfactant and the aqueous medium being used in amounts of from 0.1 to 1.
    Type: Application
    Filed: April 17, 2008
    Publication date: June 3, 2010
    Applicant: KAO Corporation
    Inventors: Hiroshi Mizuhata, Nobumichi Kamiyoshi, Shinichi Sata
  • Publication number: 20100136472
    Abstract: Toner particles are provided which may, in embodiments, include a high molecular weight branched or cross-linked polyester to decrease image gloss and to increase toner elasticity to prevent surface additives impaction. In embodiments, the toner particles may have a core-shell configuration, with the high molecular weight polyester in the core, the shell, or both.
    Type: Application
    Filed: December 1, 2008
    Publication date: June 3, 2010
    Applicant: Xerox Corporation
    Inventors: Maria N.V. McDougall, Ke Zhou, Edward G. Zwartz, Daryl W. Vanbesien, John L. Pawlak, Paul J. Gerroir, Suxia Yang, Richard P.N. Veregin, Karen Ann Moffat
  • Patent number: 7727699
    Abstract: The present invention relates to a process for producing a toner for electrophotography, including: (a) a step of aggregating resin particles containing a resin binder in an aqueous medium; and (b) a step of unifying the aggregated resin particles, the step (a) including: (a-1) a step of adding a monovalent salt as an aggregating agent; and (a-2) a step of adding at least one compound selected from the group consisting of alkylethersulfates represented by the formula (1): R—O—(CH2CH2O)nSO3M??(1) wherein R is an alkyl group; n represents an average molar number of addition and is a number of more than 0 and not more than 15 (0<n?15), and M is a monovalent cation, alkylsulfates and linear alkylbenzenesulfonates. The toner of the present invention has a small particle size which is controlled with a high accuracy, and a sharp particle size distribution, and a particle shape of the toner is readily controlled even at a low temperature, and further the obtained toner exhibits a high circularity.
    Type: Grant
    Filed: September 7, 2007
    Date of Patent: June 1, 2010
    Assignee: Kao Corporation
    Inventors: Nobumichi Kamiyoshi, Manabu Suzuki, Yutaka Murai
  • Patent number: 7727700
    Abstract: A toner is disclosed, for developing electrostatic images by means of image forming apparatuses, that comprises toner particles, and an external additive, wherein the toner particles comprise a binder resin and a colorant, the external additive is introduced onto the surface of the toner particles, the external additive liberates from the surface of the toner particles in a rate of 7% to 50% under the condition that the toner is dispersed within a surfactant-containing electrolyte at 20 W output power and 20 kHz frequency for one minute by means of an ultrasonic homogenizer.
    Type: Grant
    Filed: September 8, 2008
    Date of Patent: June 1, 2010
    Assignee: Ricoh Company, Ltd.
    Inventor: Hideki Sugiura
  • Patent number: 7727696
    Abstract: A toner having its surface functionalized with alkaline resins is provided, and processes for producing the same.
    Type: Grant
    Filed: December 8, 2006
    Date of Patent: June 1, 2010
    Assignee: Xerox Corporation
    Inventors: Zhen Lai, Yuhua Tong, Chieh-Min Cheng, Christopher M. Wolfe
  • Publication number: 20100129751
    Abstract: A process for the manufacture of a toner comprising toner particles which comprise at least resin and colorant, the process comprising the steps of: providing a mixed dispersion of at least primary resin particles and primary colorant particles stabilised by two or more surfactants in a liquid medium, the surfactants comprising at least a first ionic surfactant and a second ionic surfactant of the same polarity as the first ionic surfactant, wherein the first and second ionic surfactants have different linear chain lengths; and causing the primary particles to associate.
    Type: Application
    Filed: April 29, 2008
    Publication date: May 27, 2010
    Inventors: Daniel Patrick Morris, Martin Russell Edwards, Mohammed Nawaz, Simon Pickard
  • Patent number: 7723006
    Abstract: The present invention relates to a toner for electrostatic development produced by a suspension process accompanied with reverse-neutralization and the method of producing the toner.
    Type: Grant
    Filed: December 14, 2002
    Date of Patent: May 25, 2010
    Assignee: Samsung Electronics Co., Ltd.
    Inventor: Do-Gyun Kim
  • Publication number: 20100124716
    Abstract: A method of manufacturing a toner including manufacturing a coarse toner containing a binder resin and a coloring agent, and screening the coarse toner with a screen device including a top screen having an opening 5 of from 26 to 43 ?m and a bottom screen situated below the top screen having an opening of from 54 to 150 ?m to screen the coarse toner with the top screen by ultrasonic vibration and mechanical vibration at 50° C. or lower, and with the bottom screen by mechanical vibration at 35° C. or lower.
    Type: Application
    Filed: November 16, 2009
    Publication date: May 20, 2010
    Applicant: RICHO COMPANY, LTD.
    Inventors: Yasuaki TOMIOKA, Yousuke Suzuki
  • Patent number: 7713674
    Abstract: An emulsion polymerization process comprising polymerizing monomer in an emulsion in a reaction vessel at a first temperature to form a resin; cooling the reaction vessel to a second temperature that is above the softening point of the resin yet below the temperature required for significant depolymerization reaction to occur; and adding water to the cooled reaction vessel in an amount sufficient to effect phase inversion with mixing for a sufficient time to form an aqueous latex emulsion in the absence of a surfactant.
    Type: Grant
    Filed: September 9, 2005
    Date of Patent: May 11, 2010
    Assignee: Xerox Corporation
    Inventors: Allan Kwok-Wai Chen, Milan Maric, Tie Hwee Ng, George Liebermann, Enno Eric Agur, Hadi Khan Mahabadi
  • Patent number: 7713668
    Abstract: A toner composition having toner particles comprising a gel latex, a high Tg latex, a wax, and a colorant. The gel latex is present in an amount of from about 3 weight percent to about 30 weight percent of the toner composition, the high Tg latex is present in an amount of from about 50 weight percent to about 95 weight percent of the toner composition, the wax is present in an amount of from about 2 weight percent to about 40 weight percent of the toner composition, and the colorant is present in an amount of from about 1 weight percent to about 25 weight percent of the toner composition.
    Type: Grant
    Filed: December 13, 2006
    Date of Patent: May 11, 2010
    Assignee: Xerox Corporation
    Inventors: Karen A. Moffat, Emily L. Moore, Daryl W. Vanbesien, Shigang S. Qui, Vladislav Skorokhod, Edward G. Zwartz, Juan A. Morales-Tirado, William H. Hollenbaugh, Jr.
  • Publication number: 20100104970
    Abstract: A method and an apparatus for producing toner are provided. A fluid comprising a resin and a colorant is supplied to a retention member that includes a film on which multiple discharge openings are formed. The fluid which is supplied to the retention member is resonated so that liquid droplets thereof are discharged from the multiple openings. The liquid droplets which are discharged from the multiple openings are solidified to form mother particles of a toner.
    Type: Application
    Filed: October 23, 2009
    Publication date: April 29, 2010
    Inventors: Yoshihiro Norikane, Shinji Aoki, Masaru Ohgaki, Yohichiroh Watanabe, Takahiro Honda, Andrew Mwaniki Mulwa, Yuko Sekiguchi
  • Publication number: 20100104967
    Abstract: An electrostatic-image-developing toner includes: a binder resin; and a yellow pigment in an amount of from about 5 to about 50 ppm.
    Type: Application
    Filed: May 19, 2009
    Publication date: April 29, 2010
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Yusuke IKEDA, Susumu YOSHINO, Masanobu NINOMIYA, Yukiaki NAKAMURA, Yasuo KADOKURA
  • Publication number: 20100104971
    Abstract: First toner of the present invention includes colored particles and an external additive. The colored particles are produced by heating and aggregating a mixture that includes a resin particle dispersion in which first resin particles are dispersed and a pigment particle dispersion in which pigment particles are dispersed, so that at least part of the first resin particles is melted. The colored particles have a finely roughened surface. Second toner of the present invention includes aggregated particles including at least first resin particles and pigment particles, and colored particles having a finely roughed surface formed by fusing at least part of wax and at least part of second resin particles on the surface of the aggregated particles.
    Type: Application
    Filed: December 30, 2009
    Publication date: April 29, 2010
    Applicant: PANASONIC CORPORATION
    Inventors: Yasuhito YUASA, Hidekazu ARASE
  • Patent number: 7704662
    Abstract: A toner for use in a single component development system, said toner including emulsion aggregation toner particles with a styrene acrylate polymer binder resin having a molecular weight Mw of from about 50 to about 100 Kpse and a number average molecular weight (Mn) of from about 10 to about 30 Kpse, a wax selected from the group consisting of polypropylene and polyethylene, and at least one colorant, wherein the toner particles have an onset glass transition temperature of from about 50° C. to about 60° C., and a circularity of from about 0.950 to about 0.990.
    Type: Grant
    Filed: September 26, 2007
    Date of Patent: April 27, 2010
    Assignee: Xerox Corporation
    Inventors: Grazyna E Kmiecik-Lawrynowicz, Daniel W Asarese, Maura A Sweeney, Robert D Bayley
  • Patent number: 7704665
    Abstract: A method for developing toner for use in a single component development system, wherein the process includes a) contacting a styrene acrylate polymer binder resin having a weight average molecular weight (Mw) of from about 50 to about 100 Kpse, and a number average molecular weight (Mn) of from about 10 to about 30 Kpse, a wax selected from the group consisting of polypropylene and polyethylene, and at least one colorant to produce a toner blend, b) aggregating the blend by heating at a temperature at or above the glass transition temperature of the styrene acrylate resin to form an aggregated toner core; c) adding a second binder resin to the aggregated toner core to form a shell over said toner core thereby forming a core-shell toner; d) growing said core-shell toner to a desired size; e) coalescing the core-shell toner by heating at a temperature above the glass transition temperature of the second latex; and f) recovering toner particles, wherein the toner particles have an onset glass transition temperat
    Type: Grant
    Filed: September 26, 2007
    Date of Patent: April 27, 2010
    Assignee: Xerox Corporation
    Inventors: Grazyna E Kmiecik-Lawrynowicz, Daniel W Asarese, Maura A Sweeney, Robert D Bayley
  • Patent number: 7704664
    Abstract: In a method of manufacturing a toner in which toner particles are obtained by mixing resin particles and at least a colorant with each other to be coagulated, and heating an obtained coagulated product, binder resin is granulated into fine particles by a granulating method including a coarse particle preparing step, a slurry preparing step, a pulverizing step, a cooling step, and a depressurizing step. Slurry containing coarse particles of binder resin obtained by way of the coarse particle preparing step and the slurry preparing step is made to pass under heat and pressure through a pressure-resistant nozzle whereby the coarse particles of binder resin are pulverized into resin particles. By providing the cooling step and the depressurizing step immediately after the pulverizing step, the resin particles are prevented from coarsening.
    Type: Grant
    Filed: February 13, 2007
    Date of Patent: April 27, 2010
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Katsuru Matsumoto, Yasuhiro Shibai
  • Publication number: 20100099037
    Abstract: Environmentally friendly toner particles are provided which may, in embodiments, include a biodegradable semi-crystalline polyester resin and a biodegradable amorphous polyester resin.
    Type: Application
    Filed: October 21, 2008
    Publication date: April 22, 2010
    Applicant: XEROX CORPORATION
    Inventors: Gwynne McAneney - Lannen, Guerino G. Sacripante, Edward G. Zwartz, Maria N.V. McDougall
  • Publication number: 20100099040
    Abstract: The present invention relates to toner compositions comprising a resin and a colorant. Various embodiments of the colorant used in the toner compositions are disclosed, including a modified pigment comprising a pigment having attached at least one organic group having the formula ?X-I, wherein X, which is directly attached to the pigment, represents an arylene or heteroarylene group, or an alkylene group, and I represents a non-polymeric group comprising at least one ionic group or at least one ionizable group. Processes for preparing toner compositions are also described.
    Type: Application
    Filed: December 16, 2009
    Publication date: April 22, 2010
    Inventors: Eugene N. Step, Agathagelos Kyrlidis
  • Publication number: 20100098462
    Abstract: A method of preparing a toner using a micro-suspension particle, includes preparing a mixture by mixing a resin having acidic groups, a master batch of coloring pigment, and at least one additive with an organic solvent, and then neutralizing the acid groups of the resin with a base; forming a micro-suspension by adding the prepared mixture to a dispersion medium; and forming a toner composition by removing the organic solvent from the prepared micro-suspension. Therefore, the method of preparing a toner using the disclosed micro-suspension particle and a toner prepared using the same can save manufacturing costs, and can improve charging ability and cleaning properties of the toner.
    Type: Application
    Filed: February 20, 2008
    Publication date: April 22, 2010
    Applicant: Samsung Fine Chemicals Co., Ltd.
    Inventors: Woo Young Yang, Keon Il Kim, Dae Il Hwang, Jae Bum Park, Il Sun Hwang, Jun Hee Lee, Jae Kwang Hwang, Dong Won Kim, Duck Kyun Ahn
  • Patent number: 7700253
    Abstract: An electrophotographic toner is disclosed, comprising a binding resin, a colorant and a releasing agent, wherein the releasing agent comprises a first releasing agent component of a monoester compound represented by formula (1) and a second releasing agent component composed of a hydrocarbon compound having a branched chain structure, and the first releasing agent component accounting for 40% to 98% by mass of the total amount of the first and second releasing agent components: R1—COO—R2??(1) wherein R1 and R2 are each independently a hydrocarbon group having 13 to 30 carbon atoms.
    Type: Grant
    Filed: January 22, 2007
    Date of Patent: April 20, 2010
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Takao Yamanouchi, Shingo Fujimoto, Makoto Kobayashi, Kazuya Isobe, Hirofumi Koga
  • Publication number: 20100092886
    Abstract: The present disclosure provides processes for producing toners by emulsion aggregation where the resulting toner particles have high pigment loadings and desired circularity. The methods include adding a metal, in embodiments a metal salt, at the beginning of coalescence, which surprisingly speeds the coalescence process and produces toner particles having a desired size and circularity for use in electrophotographic imaging systems.
    Type: Application
    Filed: October 10, 2008
    Publication date: April 15, 2010
    Applicant: XEROX CORPORATION
    Inventors: Daryl W. Vanbesien, Yixin Gong, Karen A. Moffat, Richard P.N. Veregin, Cuong Vong, Jordan H. Wosnick, Suxia Yang
  • Publication number: 20100092884
    Abstract: Single component toners are provided with at least one surface additive including a large polymeric spacer, and processes for producing the same. In embodiments, the toner is a non-magnetic single component toner produced by emulsion aggregation methods. The large polymeric spacer additives provide excellent flow characteristics to the resulting toners, and reduce the incidence of clogging failure and print defects such as ghosting, white bands, and low toner density compared with conventionally produced toners.
    Type: Application
    Filed: October 15, 2008
    Publication date: April 15, 2010
    Applicant: XEROX CORPORATION
    Inventors: Samir Kumar, Grazyna L. Kmiecik-Lawrynowicz, Maura A. Sweeney, Michael L. Grande, Julie C. Pickering, Timothy L. Lincoln
  • Patent number: 7695886
    Abstract: A process for producing a resin particle liquid dispersion for an electrostatic image developing toner, the process comprising: polycondensing a polycondensable monomer by utilizing an acid having a surface activating effect as a polycondensation catalyst, so as to obtain a polycondensed resin; and dispersing the polycondensed resin in an aqueous medium to which a base is added, so as to obtain a resin particle liquid dispersion in which a median diameter of resin particles is from 0.05 to 2.0 ?m, or the process comprising: polycondensing a polycondensable monomer by utilizing an acid having a surface activating effect as a polycondensation catalyst in a co-presence of a polycondensed resin, so as to obtain a polycondensed resin-containing material; and dispersing the polycondensed resin-containing material in an aqueous medium, so as to obtain a resin particle liquid dispersion in which a median diameter of resin particles is from 0.05 to 2.0 ?m.
    Type: Grant
    Filed: September 21, 2005
    Date of Patent: April 13, 2010
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yasuo Matsumura, Hirotaka Matsuoka, Satoshi Hiraoka, Yuki Sasaki, Fumiaki Mera, Hideo Maehata
  • Patent number: 7695884
    Abstract: An emulsion aggregation toner including a core and a shell wherein the core includes an amorphous polyester, a wax, a crystalline polyester and an optional colorant and wherein the shell includes an amorphous polyester and a wax and is substantially free of crystalline polyester.
    Type: Grant
    Filed: August 15, 2007
    Date of Patent: April 13, 2010
    Assignee: Xerox Corporation
    Inventors: Daryl W. Vanbesien, Guerino G. Sacripante, Michael S. Hawkins, Peter J. G. Rehbein
  • Publication number: 20100086867
    Abstract: A method for making toners to include at least one nanoscale fluorescent pigment particle composition and/or a fluorescent organic nanoparticle composition. The particles are incorporated into emulsion of toner and used in making toner via emulsion aggregation. Such toners may have a core and/or a shell and the clay composites may be included within the core, the shell or both. The fluorescent organic nanoparticle composition includes a polymeric matrix obtained by modified EA latex process and/or emulsion polymerization and one or more fluorescent dyes and the nanoscale fluorescent pigment particle composition includes pigment molecules with at least one functional moiety, and a sterically bulky stabilizer compound including at least one functional group, the functional moiety of the pigment associates non-covalently with the functional group of the stabilizer, and the presence of the associated stabilizer limits the extent of particle growth and aggregation, to afford nanoscale-sized pigment particles.
    Type: Application
    Filed: October 6, 2008
    Publication date: April 8, 2010
    Applicant: XEROX CORPORATION
    Inventors: Gabriel IFTIME, Daryl W. VANBESIEN, Maria M. BIRAU, Jordan H. WOSNICK, Peter M. KAZMAIER
  • Patent number: 7687218
    Abstract: The present invention is a method for the preparation of electrostatographic toner including the following steps. A first dispersion is prepared with a solvent, a silicone wax, and a hyperdispersant. The first dispersion is added to an organic solvent containing a polymer material to form an organic phase. The organic phase is dispersed in an aqueous phase containing a particulate stabilizer to form a second dispersion. The second dispersion is homogenized. The organic solvent is evaporated from the second dispersion and the resultant product is recovered, washed and dried. In an alternate method the hyperdispersant is added directly to the organic phase before mixing with the aqueous phase.
    Type: Grant
    Filed: July 13, 2007
    Date of Patent: March 30, 2010
    Assignee: Eastman Kodak Company
    Inventors: Xiqiang Yang, Dinesh Tyagi
  • Publication number: 20100075240
    Abstract: An electrostatic-image-developing toner includes toner particles containing a binder resin, a colorant, and a release agent, wherein the toner contains colorless binder resin particles and, of the colorless binder resin particles, particles having a volume-average particle size diameter 1.5 times as large as, or larger than that of, D50 of the toner particles are in a proportion of about 30 particles or less particles per 5,000 toner particles, with D50 being a volume-average particle size diameter of the toner particles.
    Type: Application
    Filed: September 11, 2009
    Publication date: March 25, 2010
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Hitomi AKIYAMA, Junichi TOMONAGA, Yasunobu KASHIMA
  • Patent number: 7682767
    Abstract: Provided can be easily producible toner containing polyester resin particles, exhibiting excellent fixability and fine line reproduction, in which high quality images can stably be formed for a long duration, the toner manufacturing method, and the image forming method. Also disclosed is a manufacturing method of toner possessing the steps of conducting a polymerization process for acquiring polyester resin particles via condensation-polymerization of carboxylic acid and alcohol employing oil droplets after forming the oil droplets including a polymerizable composite containing at least one kind of carboxylic acid with divalence or more and at least one kind of alcohol with divalence or more in an aqueous medium containing a surfactant including a compound having a long chain hydrocarbon group and acidic group, and conducting a coagulation process for acquiring toner particles by coagulating at least the polyester particles in the aqueous medium.
    Type: Grant
    Filed: April 28, 2006
    Date of Patent: March 23, 2010
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Mikio Koyama, Hiroshi Yamazaki, Kenji Hayashi
  • Patent number: 7678520
    Abstract: A method for producing an electrophotographic toner comprising the steps of: (1) mixing a water-insoluble organic solvent, an oil-soluble dye capable of chelating with a metal, a metal compound and water to form an oil-soluble dye dispersion, (2) removing the organic solvent from the oil-soluble dye dispersion to form colored microscopic particles, and (3) adding an emulsion thermoplastic resin to the colored microscopic particles so as to associate the particles with slow coagulation.
    Type: Grant
    Filed: October 12, 2006
    Date of Patent: March 16, 2010
    Assignee: Konica Minolta Holdings, Inc.
    Inventors: Koji Daifuku, Kaori Ono
  • Publication number: 20100062359
    Abstract: An emulsion aggregation toner formulation for electrophotography and a method for preparation thereof. The emulsion aggregation toner formulation includes a polyester resin emulsion formed using an extruded polyester binder resin having a broad molecular weight distribution. The extruded polyester binder resin is formed using a plurality of polyester binder resins. Further, the emulsion aggregation toner formulation comprises at least one colorant dispersion and a wax dispersion.
    Type: Application
    Filed: September 8, 2008
    Publication date: March 11, 2010
    Inventors: Michael James Bensing, Craig Michael Bertelsen, John Joseph Kraseski, Bryan Patrick Livengood, Jing X. Sun, Vincent Wen-Hwa Ting
  • Publication number: 20100055598
    Abstract: Toner particles are provided which may, in embodiments, include a gel. In embodiments, the toner particles may have a core-shell configuration, with the gel in the core, the shell, or both. The gel may prevent a crystalline resin in the core of the toner particles from migrating to the toner surface.
    Type: Application
    Filed: August 27, 2008
    Publication date: March 4, 2010
    Applicant: XEROX CORPORATION
    Inventors: Ke Zhou, Karen Ann Moffat, Edward G. Zwartz, Richard P.N. Veregin, Maria N.V. McDougall
  • Publication number: 20100055600
    Abstract: Disclosed is a method of manufacturing a toner, wherein a liquid drop forming part including a storage part configured to store a toner composition liquid in which a toner composition including at least a resin and a coloring agent is dispersed or dissolved, a thin film on which a nozzle facing the storage part is formed, and a vibration generating part configured to vibrate the thin film via the toner composition liquid in the storage part are used, wherein plural storage chambers partitioned by a partition wall(s) are formed in the storage part and a width of each storage chamber in a direction of arrangement of the plural storage chambers and a width of each storage chamber in a direction orthogonal to the direction of arrangement of the storage chambers are formed to be one-half or less of a wavelength ? of a sonic wave generated in the storage part.
    Type: Application
    Filed: August 26, 2009
    Publication date: March 4, 2010
    Inventors: Yoshihiro NORIKANE, Shinji Aoki, Tetsuya Sonoda, Keisuke Uchida, Andrew Mwaniki Mulwa, Yuko Sekiguchi
  • Publication number: 20100055591
    Abstract: The present invention relates to a chemical toner composition and a method for preparing the same. The chemical toner composition includes: a resin emulsion; a pigment dispersion; a wax dispersion; and a dispersible polymer coagulant, wherein the dispersible polymer coagulant is a copolymer comprising unsaturated ester monomers and amino-containing monomers. Accordingly, the present invention uses a novel dispersible polymer coagulant to prepare uniform toner particles with excellent roundness and improved flowability and to reduce moisture absorption.
    Type: Application
    Filed: December 16, 2008
    Publication date: March 4, 2010
    Applicant: Trend Tone Imaging, Inc.
    Inventors: Kuei-Ying Chiu, Kuo-Tong Huang, Ju-Feng Liao, I-Jein Cheng, Jui-Fa Chang, Chien-Sheng Huang, Yi-Ling Liu