By Coalescing Or Aggregating Patents (Class 430/137.14)
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Patent number: 7867683Abstract: A toner that when the complex elastic modulus measured at an angular frequency of 6.28 rad/sec., and a strain amount of 0.3% is 1×106 Pa or more and 1×108 Pa or less, the tangent loss is 0.5 or more and 1.8 or less.Type: GrantFiled: April 20, 2007Date of Patent: January 11, 2011Assignee: Fuji Xerox Co., Ltd.Inventors: Masanobu Ninomiya, Toyofumi Inoue, Masataka Kuribayashi, Masashi Ikeda, Takafumi Koide
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Publication number: 20110003244Abstract: The toner includes a binder resin; a colorant; and a release agent. The first inter-particle force Fp(A) of the toner, which is measured under an environmental condition of 23° C. and 60% RH after the toner is pressed for 1 minute at 25° C. under a compression stress of 15 kg/cm2, is from 1.0×10?9 (N) to 1.0×10?6 (N). The difference (Fp(B)?Fp(A)) between the second inter-particle force Fp(B) of the toner, which is measured under the environmental condition of 23° C. and 60% RH after the toner is pressed for 1 minute at 50° C. under a compression stress of 15 kg/cm2, and the first inter-particle force Fp(A) is 0 (N) to 1.0×10?7 (N).Type: ApplicationFiled: June 23, 2010Publication date: January 6, 2011Inventors: Daisuke INOUE, Fumihiro Sasaki, Osamu Uchinokura, Satoshi Kojima, Hideki Sugiura, Naoko Morisawa
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Patent number: 7862978Abstract: The invention provides a process for the manufacture of a toner which comprises the steps of: a) providing a latex dispersion containing primary resin particles and surfactant; b) providing a colorant dispersion containing primary colorant particles and surfactant; c) optionally providing a wax dispersion containing primary wax particles and surfactant; d) providing at least one carboxy functional compound of Formula (1), which may be in acid, salt and/or complex form: wherein R is a carbocyclic or heterocyclic radical which may be optionally substituted and Z1 is a bond or linker group and wherein the amount of carboxy functional compound of Formula (1) provided is greater than 3% by weight, the amount of carboxy functional compound being calculated according to the following equation: amount ? ? of ? ? carboxy ? ? functional ? ? ? compound ? ? ( % ? ? weight ) = 100 × weight ? ? ? of ? ? carboxy ? ? functional ? ? compound ( weightType: GrantFiled: November 6, 2006Date of Patent: January 4, 2011Assignee: Fujifilm Imaging Colorants LimitedInventors: Daniel Patrick Morris, Martin Russell Edwards, Mohammed Nawaz, Oliver Callaghan, Simon Pickard
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Patent number: 7862979Abstract: The invention provides a process for the manufacture of a toner which comprises the steps of: a) providing a latex dispersion containing primary resin particles and surfactant; b) providing a colorant dispersion containing primary colorant particles and surfactant; c) optionally providing a wax dispersion containing primary wax particles and surfactant; d) providing at least one carboxy functional compound of Formula (1), which may be in acid, salt and/or complex form: wherein R is a carbocyclic or heterocyclic radical which may be optionally substituted and Z1 is a bond or linker group, on condition that the amount of carboxy functional compound of Formula (1) provided in acid and/or salt form is at least 1.Type: GrantFiled: November 6, 2006Date of Patent: January 4, 2011Assignee: Fujifilm Imaging Colorants LimitedInventors: Daniel Patrick Morris, Martin Russell Edwards, Mohammed Nawaz, Oliver Callaghan, Simon Pickard
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Patent number: 7862971Abstract: An emulsion aggregation toner having toner particles comprising a gel latex, a high Tg latex and at least one wax, wherein the toner fuses at about 170° C. to about 220° C. at process speeds of from about 560 mm/s to about 870 mm/s, wherein the toner exhibits a crease fix property of less than about 60 and a half-toner rub fix property of less than about 0.15. The toner exhibits excellent half-tone rub fix performance and crease fix at high print speeds.Type: GrantFiled: January 31, 2007Date of Patent: January 4, 2011Assignee: Xerox CorporationInventors: Karen A. Moffat, Edward G. Zwartz, T. Brian McAneney, Fernando P. Yulo
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Patent number: 7862970Abstract: A toner composition includes core particles including a polymeric latex and an optional colorant, and amino-containing polymer particles dispersed on an external surface of the particles.Type: GrantFiled: May 13, 2005Date of Patent: January 4, 2011Assignee: Xerox CorporationInventors: Michael S. Hawkins, Eric M. Strohm, Richard P. N. Veregin, Vladislav Skorokhod, Clive R. Daunton, Robert D. Bayley
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Publication number: 20100330486Abstract: A toner including at least one amorphous polyester, at least one crystalline polyester and at least one ester wax, wherein the linear polyester and the at least one ester wax have a difference in solubility parameter of from about 0.1 to about 1.7.Type: ApplicationFiled: June 24, 2009Publication date: December 30, 2010Applicant: Xerox CorporationInventors: Ke Zhou, Edward Graham Zwartz, Maria N.V. McDougall, John L. Pawlak, Paul Gerroir, Karen A. Moffat, Richard P.N. Veregin
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Publication number: 20100330484Abstract: Black particles include a black pigment; and a cyan pigment, wherein when the reflectance to light of wavelength of 420 nm and the reflectance to light of wavelength of 770 nm of plural samples are measured, the standard deviations (1?) of the measured values are about 1 or less with respect to both wavelengths.Type: ApplicationFiled: December 4, 2009Publication date: December 30, 2010Applicant: FUJI XEROX CO., LTD.Inventor: Shigeru SEITOKU
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Publication number: 20100330485Abstract: A toner that includes at least one polyester resin wherein the amount of free polyvalent acid monomer in the polyester resin is less than 4 mg/gram, and wherein the percentage of the at least one polyester resin with a Mw less than 1500 is less than about 10%.Type: ApplicationFiled: June 24, 2009Publication date: December 30, 2010Applicant: Xerox CorporationInventors: John L. PAWLAK, Timothy L. LINCOLN, William H. HOLLENBAUGH, JR., Yuhua TONG, Brendan H. WILLIAMSON
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Patent number: 7858285Abstract: An emulsion aggregation toner including an amorphous resin and a crystalline resin, wherein the toner has an acid value of from about 16 mg/eq. KOH to about 40 mg/eq. KOH and a relative humidity sensitivity ratio of from about 1 to about 2, and wherein the crystalline resin has a melting point of at least about 60° C. The process for forming particles including generating an emulsion of a polyester resin having an acid value of from about 16 mg/eq. KOH to about 40 mg/eq. KOH and generating aggregate particles from the emulsion. Increased charge maintainability and resistivity of the toner result, thereby generating high print quality and high gloss, and provide stable xerographic charging in all ambient environments.Type: GrantFiled: November 6, 2006Date of Patent: December 28, 2010Assignee: Xerox CorporationInventors: Guerino G. Sacripante, Allan K. Chen
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Publication number: 20100316947Abstract: The present invention relates to a resin emulsion which has a good emulsification performance even when produced by using a crosslinked polyester resin having a good fusing ability and a good durability, and also is capable of producing a toner having an excellent heat-resistant storage property therefrom; and a process for producing the resin emulsion. The process for producing a resin emulsion according to the present invention, includes the steps of: (a) mixing a resin containing a polyester having a constitutional unit derived from at least one component selected from the group consisting of a trivalent or higher-valent alcohol component and a trivalent or higher-valent carboxylic acid component, an anionic surfactant, and a nonionic surfactant with each other at a temperature which is not lower than a temperature lower by 10° C. than a softening point of the resin, the nonionic surfactant being used in an amount of more than 1.Type: ApplicationFiled: January 25, 2008Publication date: December 16, 2010Applicant: KAO CORPORATIONInventors: Hiroshi Mizuhata, Nobumichi Kamiyoshi, Shinichi Sata
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Publication number: 20100316946Abstract: A process for making a self-emulsifying composite suitable for use in forming latex emulsions includes contacting a resin with a solid or highly concentrated surfactant, a solid neutralizing agent in the absence of water and an organic solvent to form a mixture, melt mixing the mixture, and forming a self-emulsifying composite of the melt mixed mixture such as a granule. Self-emulsifying granules are also provided and configured to form a latex emulsion when added to water, which may then be utilized to form a toner.Type: ApplicationFiled: June 16, 2009Publication date: December 16, 2010Applicant: XEROX CORPORATIONInventors: Santiago Faucher, Rina Carlini, Joo T. Chung, Fumii Higuchi, Shigang Qiu, Allan K. Chen, Edward Graham Zwartz, Michael Steven Hawkins, Brian J. Andaya, Joseph L. Leonardo
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Patent number: 7851116Abstract: Toner including toner particles having a calcium-containing material at least in a surface portion of the toner particle, wherein the toner particles contain calcium in an amount of from 20 ppm to about 300 ppm of calcium by dry weight of the toner. Developer including a carrier and a toner, wherein the toner includes toner particles having a calcium-containing material at least in a surface portion of the toner particles. In an emulsion aggregation process for making toner particles, the toner particles are treated with calcium. The addition of calcium to the toner particles improves toner performance by lowering cohesion and charging, thereby generating an image of high gloss.Type: GrantFiled: October 30, 2006Date of Patent: December 14, 2010Assignee: Xerox CorporationInventors: Richard P. N. Veregin, Allan K. Chen, Cuong Vong, Vladislav Skorokhod, Eric M. Strohm, Michael S. Hawkins, Christine D. Anderson, Richard Fong, Nancy S. Hunt, Vincenzo G. Marcello
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Publication number: 20100310981Abstract: According to one embodiment, a method for producing a developing agent includes pulverizing a mixture in the form of coarse particles of a toner material including a coloring agent and a binder resin by mechanical shearing, aggregating and fusing the resulting fine particles. The solid content concentration in a dispersion liquid including the aggregated particles is from 5.0% to 40.0%, the volume average particle diameter of the aggregated particles is from 1.0 ?m to 10.0 ?m, and the ratio of the standard deviation to the volume average particle diameter is 30.0% or less.Type: ApplicationFiled: June 2, 2010Publication date: December 9, 2010Applicants: KABUSHIKI KAISHA TOSHIBA, TOSHIBA TEC KABUSHIKI KAISHAInventors: Junichi Ishikawa, Takayasu Aoki, Tsuyoshi Itou, Yasuhito Noda, Motonari Udo, Satoshi Araki, Masahiro Ikuta, Takafumi Hara, Takashi Urabe, Taishi Takano, Yasuo Goto
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Publication number: 20100310983Abstract: A process for making particles is provided. In embodiments, a suitable process includes adding a rheology modifier to an emulsion utilized to form toner particles. The rheology modifier permits the use of a higher solid content in the emulsion, with a resulting higher yield of toner particles, without requiring the use of powerful mixing equipment.Type: ApplicationFiled: June 5, 2009Publication date: December 9, 2010Applicant: XEROX CORPORATIONInventors: Zhaoyang Ou, Zhen Lai, Christopher D. Blair, Chieh-Min Cheng
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Publication number: 20100310984Abstract: A process for making toner particles is provided. In embodiments, a suitable process includes adding a defoamer to an emulsion utilized to form toner particles. Utilization of the defoamer allows for a reduction in the overall aggregation/coalescence cycle time and slurry viscosity, while producing a toner with improved GSDs, low coarse and target circularities.Type: ApplicationFiled: July 14, 2010Publication date: December 9, 2010Applicant: XEROX CORPORATIONInventors: Kimberly D. Nosella, Allan K. Chen, Zhen Lai, Zhaoyang Ou, Daryl W. Vanbesien
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Patent number: 7846636Abstract: The present invention relates to a process for readily producing a toner for electrophotography which contains toner particles having a small particle size and a narrow particle size distribution, and a toner for electrophotography having a small particle size and a narrow particle size distribution which is produced by the above process.Type: GrantFiled: March 7, 2007Date of Patent: December 7, 2010Assignee: Kao CorporationInventor: Kazuhiro Ishikawa
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Publication number: 20100297546Abstract: Toner particles are provided which may, in embodiments, include a core and a shell. In embodiments, charge control agents may be co-emulsified with a resin utilized to form a shell. The shell may prevent a crystalline resin in the core from migrating to the toner surface. Inclusion of the charge control agent in the shell itself may provide the resulting toner particles with desirable charge characteristics and sensitivity to relative humidity.Type: ApplicationFiled: May 20, 2009Publication date: November 25, 2010Applicant: Xerox CorporationInventors: Ke Zhou, Maria N.V. McDougall, Karen A. Moffat, Richard P.N Veregin, Enno E. Agur
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Patent number: 7833446Abstract: The aggregated particles are manufactured through a method of manufacturing aggregated particles, which includes an aggregating step, a depressurizing step, and a cooling step. In the aggregating step, a slurry is prepared which contains aggregated particles obtained by flowing an aqueous slurry of resin fine particles having a volume average particle diameter in the range of 0.4 ?m to 3 ?m through a coiled piping in a heated and pressurized state and thereby aggregating the resin fine particles. In the depressurizing step, the slurry containing the aggregated particles is depressurized, and a particle size control is conducted by disintegrating coarse particles so as to homogenize particle diameters of the aggregated particles. In the cooling step, the slurry containing the aggregated particles of which particle diameters have been homogenized is cooled.Type: GrantFiled: August 1, 2007Date of Patent: November 16, 2010Assignee: Sharp Kabushiki KaishaInventors: Nobuhiro Maezawa, Katsuru Matsumoto, Keiichi Kikawa
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Patent number: 7833684Abstract: A toner having charge control agents which impart excellent triboelectric charging characteristics.Type: GrantFiled: November 14, 2007Date of Patent: November 16, 2010Assignee: Xerox CorporationInventors: Timothy L. Lincoln, Yuhua Tong, Robert D. Bayley
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Publication number: 20100285403Abstract: Processes for producing emulsion aggregation toners are provided. In embodiments, methods of the present disclosure may be utilized to produce toners suitable for low melt applications, including use in flexible packaging applications, where low pile height is desired for low cost and flexibility. In embodiments, the EA toners may be prepared by optimizing the particle size of the emulsion, the choice of and amount of aggregating agent utilized, and the solids content of the emulsion.Type: ApplicationFiled: May 8, 2009Publication date: November 11, 2010Applicant: Xerox CorporationInventors: Guerino G. Sacripante, Nathan C. Dyck, Daryl W. Vanbesien, Edward G. Zwartz, Cuong Vong
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Patent number: 7829255Abstract: Emulsion aggregation toners comprising a polyester-wax resin, wherein the polyester-wax resin includes a wax that is chemically incorporated into the main chain of the polyester.Type: GrantFiled: December 3, 2007Date of Patent: November 9, 2010Assignee: Xerox CorporationInventors: Guerino G. Sacripante, Richard P. N. Veregin, Edward G. Zwartz, Maria N. V. McDougall
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Publication number: 20100266949Abstract: A process for making toner particles is provided. In embodiments, a suitable process includes melt mixing a resin in the absence of an organic solvent, optionally adding a surfactant to the resin, adding to the resin at least one colorant and other optional toner additives, adding to the resin a basic agent and water to form a mixture, and subjecting the mixture to acoustic mixing at a suitable frequency to form to form an emulsion. A phase inversion may then be performed to create a phase inversed emulsion including a disperse phase comprising molten resin and the optional ingredients of the toner composition, at which time toner-sized droplets may be solidified from the disperse phase into toner particles, which can be recovered for use.Type: ApplicationFiled: June 25, 2010Publication date: October 21, 2010Applicant: XEROX CORPORATIONInventors: Zhen Lai, Chieh-Min Cheng, Shigang Qiu, Emily L. Moore, Tie Hwee Ng
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Publication number: 20100266948Abstract: A process for making a resin emulsion suitable for use in forming toner particles is provided. In embodiments, a suitable process includes melt mixing a resin in the absence of an organic solvent, optionally adding a surfactant to the resin, adding to the resin a basic agent and water, and subjecting the resin, basic agent and water to acoustic mixing at a suitable frequency to form an emulsion of resin particles. In embodiments, the resin emulsion thus produced may be utilized to form a toner.Type: ApplicationFiled: April 20, 2009Publication date: October 21, 2010Applicant: Xerox CorporationInventors: Zhen Lai, Chieh-Min Cheng, Shigang Qiu, Emily L. Moore, Tie Hwee Ng
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Publication number: 20100261114Abstract: A magenta electrostatic developing toner includes binder resin particles that do not contain a coloring agent or a release agent and has a shape factor SF1 of about 110 or less, the number of the binder resin particles being about 50 or less per 5,000 electrostatic developing toner particles; and inorganic particles that have a median diameter of about 5 nm to about 70 nm in an amount of about 0.01 mass % to about 0.4 mass % based on the mass of the electrostatic developing toner; and a magenta coloring agent that has an azo group.Type: ApplicationFiled: November 17, 2009Publication date: October 14, 2010Applicant: FUJI XEROX CO., LTD.Inventors: Hitomi AKIYAMA, Junichi TOMONAGA, Yasunobu KASHIMA
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Publication number: 20100261115Abstract: A yellow toner includes binder resin particles that do not contain a coloring agent or a release agent and have a shape factor SF1 of about 110 or less, the number of the binder resin particles being about 50 or less per 5,000 electrostatic developing toner particles; inorganic particles that have a median diameter of about 5 nm to about 70 nm in an amount of about 0.01 mass % to about 0.4 mass % based on the mass of the yellow toner; and a yellow coloring agent that has an azo group.Type: ApplicationFiled: November 27, 2009Publication date: October 14, 2010Applicant: FUJI XEROX CO., LTD.Inventors: Junichi TOMONAGA, Hitomi AKIYAMA, Yasunobu KASHIMA
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Patent number: 7811739Abstract: The present invention relates to a process for producing a resin emulsion which includes the steps of (a) dispersing a resin containing acidic group in a basic aqueous medium at a temperature lower than a softening point of the resin; (b) neutralizing a dispersion obtained in the step (a) at a temperature not lower than a glass transition point of the resin and not higher than the softening point of the resin; and (c) adding an aqueous liquid to the dispersion neutralized in the step (b) at the temperature not lower than the glass transition point of the resin and not higher than the softening point of the resin to emulsify the resin in the aqueous medium. According to the present invention, the resin emulsion suitably usable for production of a toner for electrophotography can be efficiently produced without using an organic solvent and a special apparatus.Type: GrantFiled: October 11, 2006Date of Patent: October 12, 2010Assignee: KAO CorporationInventors: Nobumichi Kamiyoshi, Shinichi Sata, Yoshinobu Ishikawa
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Patent number: 7807327Abstract: A method for producing an electrophotographic toner comprising the step of polymerizing two or more polymerizable monomers under existence of a non-polar liquid hydrocarbon, wherein at least one of the polymerizable monomers comprises a polar group; a kinematic viscosity of the liquid hydrocarbon at 40° C. is in the range of 7-300 mm2/s.Type: GrantFiled: January 17, 2006Date of Patent: October 5, 2010Assignee: Konica Minolta Business Technologies, Inc.Inventors: Kenji Hayashi, Mikio Koyama, Hiroyuki Yasukawa
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Publication number: 20100248119Abstract: Compounds and methods of forming compounds useful as a toner or toner precursor are disclosed. The compounds may include an aqueous dispersion, the dispersion including: (A) at least one thermoplastic resin; and (B) 0 to 5 weight percent of a stabilizing agent, based on the total weight of (A) and (B). The dispersion may have an average volume diameter particle size from about 0.05 to about 10 microns. A combined amount of the thermoplastic resin and the stabilizing agent may have an acid number of less than 25 mg KOH/g.Type: ApplicationFiled: November 26, 2008Publication date: September 30, 2010Applicant: DOW GLOBAL TECHNOLOGIES INC.Inventors: Timothy J. Young, Richard A. Lundgard, Michael J. Johnson, Qichun Wan, Matthew J. Kalinowski, Mechelle A. Churchfield, Gary M. Strandburg
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Publication number: 20100248115Abstract: Provided is a method for producing a toner having excellent particle size distribution and storage stability. The method set forth in the present specification is a method for producing a toner by aggregating and fusing base microparticles whose main component is a binder resin including anionic groups, wherein an aggregate is produced by aggregating the base microparticles in a base microparticle suspension, in a presence of a non-ionic surfactant such that a surface tension of an aqueous solution thereof is not lower than 45 mN/m at any concentration at or above a critical micelle concentration, and the toner is produced through fusion of the aggregate. According to this method, drops in a glass transition temperature of the toner can be curbed, and the toner having excellent storage stability and good particle size distribution can be obtained.Type: ApplicationFiled: March 30, 2010Publication date: September 30, 2010Applicant: BROTHER KOGYO KABUSHIKI KAISHAInventors: Jun IKAMI, Masateru KAWAMURA, Yasutomo IMAI
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Publication number: 20100248118Abstract: The present disclosure provides toners and processes for making said toners. In embodiments, the toners are invisible when viewed under natural light, but possess a UV additive that renders them visible when exposed to UV light of a specific wavelength. By selecting the appropriate UV additive and ionic crosslinker, with optional chelating agent, the gloss of the toner may be tailored to match the gloss of any substrate, such as paper, to which the toner is to be applied, thereby further enhancing its invisibility under visible light.Type: ApplicationFiled: March 26, 2009Publication date: September 30, 2010Applicant: Xerox CorporationInventors: Yi Xin Gong, Shigang Qiu, Daryl W. Vanbesien, Gabriel Iftime, Edward Graham Zwartz, Karen Ann Moffat, Richard P.N. Veregin
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Patent number: 7799502Abstract: A process including mixing a sulfonated polyester resin, a colorant, and a coagulant; heating the resulting sulfonated polyester mixture; adding a polymetal halide and an anionic latex to form coated toner particles; and heating the coated toner particles is disclosed.Type: GrantFiled: March 31, 2005Date of Patent: September 21, 2010Assignee: Xerox CorporationInventors: Raj Patel, Mike Hawkins, Paul Gerroir, Richard P. N. Veregin
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Publication number: 20100233604Abstract: An electrostatic image developing toner, includes: a block copolymer that contains: a block A that has a glass transition temperature of about 60° C. or more; and a crystalline block B that has a melting point of about 25° C. or more derived from an ethylenically unsaturated compound, wherein the block copolymer satisfies the following equations (1) to (3): 30° C.?[T(0.5 MPa)?T(30 MPa)]?80° C. ??( 1 ) 60° C.?T( 0.5 MPa) ??( 2 ) T(30 MPa)?80° C. ??( 3 ) wherein T( 0.5 MPa) represents a temperature at which a viscosity of the block copolymer is 104 Pa·s when a pressure applied by a flow tester is 0.5 MPa; and T(30 MPa) represents a temperature at which a viscosity of the block copolymer is 104 Pa·s when a pressure applied by a flow tester is 30 MPa.Type: ApplicationFiled: August 7, 2009Publication date: September 16, 2010Applicant: FUJI XEROX CO., LTD.Inventors: Hideo MAEHATA, Yasuo MATSUMURA, Takashi IMAI
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Patent number: 7794911Abstract: A toner having a core with a first latex having a specific glass transition temperature, and further having a shell surrounding the core with a second latex having a specific glass transition temperature and possessing functional groups, and processes for producing the same.Type: GrantFiled: September 5, 2006Date of Patent: September 14, 2010Assignee: Xerox CorporationInventors: Zhen Lai, Yuhua Tong, Chieh-Min Cheng, Peter V. Nguyen, Jon T. Owens
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Publication number: 20100227267Abstract: A method for producing a toner, containing: ultrasonically vibrating a liquid toner composition in which a toner material containing at least a binder resin and a colorant is dissolved or dispersed in a solvent; introducing the liquid toner composition to a liquid chamber, and ejecting the liquid toner composition as droplets from an ejecting plate having a plurality of holes and disposed on one surface of the liquid chamber; and drying and solidifying the droplets so as to produce a toner, wherein the ultrasonically vibrating is performed before the introducing the liquid toner composition to the liquid chamber.Type: ApplicationFiled: March 5, 2010Publication date: September 9, 2010Inventors: Yasutada SHITARA, Yoshihiro Norikane, Yohichiroh Watanabe, Andrew Mwaniki Mulwa
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Publication number: 20100227268Abstract: Provided is a method of manufacturing an electrostatic charge image developing toner exhibiting reduced variation in charging amount among manufacturing lots, which is capable of generating no fog, and acquiring high density print images. Disclosed is a method of manufacturing an electrostatic charge image developing toner, possessing the step of washing toner mother particles having been formed in an aqueous medium with washing water, wherein the washing water has a total dissolution component amount of at least 0.05 mg/liter and less than 0.5 mg/liter.Type: ApplicationFiled: February 22, 2010Publication date: September 9, 2010Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.Inventors: Eiichi YOSHIDA, Kenichi ONAKA
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Patent number: 7785763Abstract: A process for preparing a toner, includes solvent flashing wax and resin together to emulsify the resin and wax to a sub-micro size; mixing the wax and resin emulsion with a colorant, and optionally a coagulant to form a mixture; heating the mixture at a temperature below a glass transition temperature of the resin to aggregate the resin, colorant, and wax, to form aggregated particles; heating the aggregated particles and coalescent agent at a temperature above the glass transition temperature of said resin, to coalesce the aggregated particles to form toner particles, optionally cooling the mixture; and isolating the toner particles.Type: GrantFiled: October 13, 2006Date of Patent: August 31, 2010Assignee: Xerox CorporationInventors: Enno E. Agur, Guerino G. Sacripante, Michael S. Hawkins, Edward G. Zwartz
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Publication number: 20100216069Abstract: Provided is a method of preparing a toner, the method including: preparing a solvent emulsion by stirring a medium including a polar medium, an organic solvent, and a surfactant; adding toner components including a resin and a pigment to the solvent emulsion; removing the organic solvent from the solvent emulsion including the toner components; and collecting a toner particle from the solvent emulsion from which the organic solvent is removed.Type: ApplicationFiled: September 19, 2008Publication date: August 26, 2010Applicant: Samsung Fine Chemicals Co. LTdInventors: Woo Young Yang, Keon Il Kim, Dae Il Hwang, Il Hyuk Kim, Jae Bum Park, Il Sun Hwang, Jae Kwang Hwang, Dae Woong Choi, Dong Won Kim, Duck Kyun Ahn
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Patent number: 7781138Abstract: A process for preparing toner particles and compositions adapted for use in preparing toners that comprise a blend of a first polyester resin with a second sharp melting polyester resin. The process includes forming an emulsion resin comprising a branched polyester resin, a crystalline polyester resin, a colorant, and optionally a wax. The resin mixture is aggregated using an aggregating agent, such as a zinc acetate solution, to form an aggregate mixture. The aggregate mixture is then coalesced at a temperature of from about 5 to about 20° C. above the Tg of the emulsion resin to produce the resultant toner particles.Type: GrantFiled: October 6, 2009Date of Patent: August 24, 2010Assignee: Xerox CorporationInventors: Guerino G. Sacripante, Fatima M. Mayer, Kimberly D. Nosella, Valerie M. Farrugia, Raj D. Patel, Milan Maric, Allen K. Chen, Edward G. Zwartz, T. Hwee Ng
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Publication number: 20100209839Abstract: A method for producing a developing agent including preparing a dispersion liquid containing first fine particles containing a binder resin and second fine particles containing a color developable compound, a color coupler, and a color eraser, and aggregating the first and second fine particles in the dispersion liquid to form aggregated particles.Type: ApplicationFiled: February 11, 2010Publication date: August 19, 2010Applicant: TOSHIBA TEC KABUSHIKI KAISHAInventors: Takahito Kabai, Tsuyoshi Itou
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Publication number: 20100209835Abstract: The invention provides a transparent toner for electrostatic latent image development, containing a polyester resin and a release agent, the difference between an endothermic peak Tm of the release agent in a temperature increasing process and an exothermic peak Tc of the release agent in a temperature decreasing process when measured by an ASTM method with a differential scanning calorimeter (DSC) is from about 40° C. to about 50° C., and the degree of exposure of the release agent at the surface of the toner as determined quantitatively by X-ray photoelectron spectroscopy (XPS) is about 10% or less.Type: ApplicationFiled: October 20, 2009Publication date: August 19, 2010Applicant: FUJI XEROX CO., LTD.Inventors: Masaru TAKAHASHI, Atsushi SUGAWARA, Yasuo KADOKURA, Masanobu NINOMIYA
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Publication number: 20100203442Abstract: Disclosed is a manufacturing method of a magenta toner including the steps of dispersing an oil phase containing a radical polymerizable monomer for forming the binder resin and the colorant in an aqueous medium to form dispersion liquid in which the oil phase is dispersed in a form of droplets in the aqueous medium, and polymerizing the radical polymerizable monomer in the droplets in dispersion liquid to form resin particles containing colorant, in which the colorant comprises C.I. Solvent Red 48.Type: ApplicationFiled: February 2, 2010Publication date: August 12, 2010Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.Inventors: Ken OHMURA, Hiroshi YAMAZAKI
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Publication number: 20100203439Abstract: Environmentally friendly toner particles are provided which may, in embodiments, include a bio-based amorphous polyester resin, optionally in combination with another amorphous resin and/or a crystalline resin. Toner particles may, in embodiments, have a core-shell configuration, with the shell formed of the bio-based amorphous polyester resin, the amorphous polyester resin, the crystalline polyester resin, or combinations thereof.Type: ApplicationFiled: February 6, 2009Publication date: August 12, 2010Applicant: Xerox CorporationInventors: Ke Zhou, Richard P.N. Veregin, Gwynne McAneney-Lannen, Edward G. Zwartz, Maria N.V. McDougall, Guerino Sacripante, Karen A. Moffat
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Publication number: 20100190102Abstract: A process for preparing a toner comprising a binder resin and a colorant, wherein the binder resin comprises a polyester resin having an acid value (AV) greater than 5 mg KOH/g, the process comprising: providing an aqueous dispersion of self-dispersed polyester resin particles and associating the polyester resin particles by means of a change in the pH of the dispersion.Type: ApplicationFiled: June 20, 2008Publication date: July 29, 2010Inventors: Daniel Patrick Morris, John Dylan Morgan, Martin Russell Edwards, Miguel Angel Rodriguez-Vazquez, Mohammed Nawaz, Zoonia Mehmood
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Patent number: 7763408Abstract: A dispersion containing a coloring agent particle is mixed in a dispersion of a radical polymerizable monomer, and a reducing agent containing an iron(II) salt is added in the presence of a polymerization initiator to polymerize the dispersed radical polymerizable monomer by the action of a generated radical, thereby not only forming a binder resin fine particle but coagulating the binder resin fine particle and the coloring agent particle to form a coagulated particle.Type: GrantFiled: November 29, 2007Date of Patent: July 27, 2010Assignees: Kabushiki Kaisha Toshiba, Toshiba Tec Kabushiki KaishaInventors: Motonari Udo, Takashi Urabe, Tsuyoshi Itou, Masahiro Ikuta
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Publication number: 20100183969Abstract: The present invention relates to a toner for electrophotography which has a small particle size and is excellent in all of low-temperature fusing ability, anti-hot offset property and image characteristics and a process for producing the toner, as well as to a dispersion of crosslinked resin particles which is used for production of the toner for electrophotography and a process for producing the dispersion of crosslinked resin particles. The dispersion of crosslinked resin particles having a volume median particle size (D50) of from 0.05 to 0.7 ?m according to the present invention is produced by a process including the steps of (A) neutralizing a resin containing an acid group-containing polyester in an aqueous medium to obtain a dispersion of resin particles; and (B) mixing the dispersion of resin particles obtained in the step (A) with an oxazoline group-containing polymer at a temperature of from 60 to 100° C.Type: ApplicationFiled: September 5, 2008Publication date: July 22, 2010Applicant: Kao CorporationInventors: Manabu Suzuki, Yutaka Murai
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Patent number: 7759432Abstract: The emulsion herein is of an epoxy resin having a glass transition temperature of at least about 40° C., wherein the average diameter of the epoxy resin particles in the emulsion is 500 nm or less. The emulsion may include an epoxy resin, a sulfonated polyester resin and a nonionic surfactant. The emulsion may be used to produce a toner particle in an emulsion aggregation method.Type: GrantFiled: October 13, 2005Date of Patent: July 20, 2010Assignee: Xerox CorporationInventors: Ke Zhou, Anna-Karin Eriksson, Guerino G. Sacripante
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Patent number: 7754409Abstract: The present invention is a method of manufacturing toner particles that includes providing a first emulsion of a first aqueous phase comprising a pore stabilizing hydrocolloid dispersed in an organic solution containing a polymer. The first emulsion is dispersed in a second aqueous phase to form a second emulsion that is sheared in the presence of a stabilizing agent to form droplets of the first emulsion in the second aqueous phase. The organic solution is evaporated from the droplets to form porous toner particles.Type: GrantFiled: January 18, 2007Date of Patent: July 13, 2010Assignee: Eastman Kodak CompanyInventors: Mridula Nair, David C. Boris, Charles P. Lusignan, Dennis J. Massa, Tamara K. Jones, Anita M. Fees
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Patent number: 7754406Abstract: Toner compositions comprising toner particles including an amorphous resin, a crystalline resin and a charge control agent. The toner compositions having the charge control agent exhibit improved charge performance in the C-zone and the A-zone, and improved RH sensitivity.Type: GrantFiled: February 8, 2007Date of Patent: July 13, 2010Assignee: Xerox CorporationInventors: Daryl W. Vanbesien, Cuong Vong, Paul J. Gerroir, Richard P. N. Veregin, Karen A. Moffat, Peter J. G. Rehbein
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Publication number: 20100173240Abstract: A positively charged developer for development of electrostatic images, comprising positively charged toner particles and an external additive, wherein the positively charged toner particles are colored resin particles composed of aggregated and fusion-bonded particles of fine binder resin particles and fine colorant particles and having a shape factor SF-1 of 115 to 150 and a shape factor SF-2 of 110 to 140, and the external additive is an external additive containing positively charged inorganic particles subjected to a hydrophobization treatment with an amino group-containing compound, and a production process thereof.Type: ApplicationFiled: March 30, 2007Publication date: July 8, 2010Applicant: ZEON CORPORATIONInventor: Keita Sensui