At Least Two Couplers Patents (Class 430/173)
-
Patent number: 8935101Abstract: A method for matching precursor ions to product ions generated in a chromatography—mass spectrometry experiment comprises: choosing a time window defining a region of interest for precursor ion data and product ion data generated by the experiment; constructing a plurality of extracted ion chromatograms (XICs) for the precursor ion data and the product ion data within the region of interest; automatically detecting and characterizing chromatogram peaks within each XIC and automatically generating synthetic analytical fit peaks thereof; discarding a subset of the synthetic analytical peaks which do not satisfy noise reduction rules; performing a respective cross-correlation score calculation between each pair of synthetic analytical fit peaks; and recognizing matches between precursor ions and product ions based on the cross correlation scores.Type: GrantFiled: December 16, 2010Date of Patent: January 13, 2015Assignee: Thermo Finnigan LLCInventor: David A. Wright
-
Patent number: 6297058Abstract: A small sample of a refractory material, e.g., about 0.1 g to about 10 g, is heated to at least 1000° C., generally under a pressure of less than about 10−5 Torr. Evolved hydrogen-containing gases and/or carbon-containing gases are monitored, e.g., by mass spectrometry, and, based on the amount of the evolved gases, the concentration of hydrogen and/or carbon in the sample is calculated. It is therefore possible to accurately determine the hydrogen and carbon concentration from a small sample of a material, by a process much less burdensome than conventional techniques.Type: GrantFiled: January 14, 1999Date of Patent: October 2, 2001Assignee: Agere Systems Optoelectronics Guardian Corp.Inventor: William David Reents, Jr.
-
Patent number: 6190823Abstract: A diazo-containing photosensitive material comprising a transparent support, and a diazo-containing photosensitive layer provided over a surface of the support and containing a binder, a diazo compound and a coupler, wherein the diazo compound is represented by the following formula: (wherein R1 and R2 stand, independently from each other, for a lower alkyl group and X stands for an anionic group), wherein the coupler comprises phenylphenol and 3,5-dihydroxy-4-bromobenzoic acid, and wherein the binder comprises a cellulose ester cross-linked with a lower-alkylated urea resin.Type: GrantFiled: June 9, 2000Date of Patent: February 20, 2001Assignee: Somar CorporationInventors: Yoko Suzukawa, Nobue Abiko, Hiroshi Maruyama
-
Patent number: 5683850Abstract: A diazo heat-sensitive recording material having excellent raw stock storability and image storage characteristics, which comprises a support having thereon a recording layer comprising a diazo compound, a coupling component and an organic base. The diazo compound is a 4-disubstituted amino-2-alkoxybenzenediazonium salt and the coupling component is a compound represented by the following general formula: ##STR1## wherein R.sub.4, R.sub.5, R.sub.6 and R.sub.7 each represents a hydrogen atom, an alkyl group, an aryl group, an aralkyl group, an alkyloxy group, an aryloxy group, an alkylthio group, an arylthio group, an acyl group, an alkoxycarbonyl group, an acyloxy group, a carbamoyl group, a sulfamoyl group, a halogen atom, a cyano group or a nitro group.Type: GrantFiled: December 2, 1996Date of Patent: November 4, 1997Assignee: Fuji Photo Film Co., Ltd.Inventors: Tetunori Matushita, Hiroshi Sato, Sadao Ishige, Kimiatsu Nomura, Mitsuyuki Tsurumi
-
Patent number: 5407777Abstract: A diazo-type recording material comprising a support having thereon a recording layer comprising a photosensitive diazo compound enclosed in microcapsules, a coupling component which reacts with said diazo compound by heating at a basic pH to develop a color, and a 1-phenyl-3-pyrazolidone compound represented by the formula: ##STR1## wherein the substituents X, and R.sub.1 -R.sub.4 are defined in the specification.Type: GrantFiled: November 17, 1992Date of Patent: April 18, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Hirokazu Shimada, Akihiro Shimomura
-
Patent number: 5338642Abstract: A novel diazo type recording material is provided comprising a recording layer containing at least one light-sensitive diazo compound incorporated in microcapsules and a coupling component which undergoes reaction with said diazo compound in a basic atmosphere to develop a color on a support, wherein said coupling component is a mixture of at least one compound represented by the following general formula [I] and at least one compound represented by the following general formula [II]: ##STR1## wherein A represents an alkylene group having from 1 to 22 carbon atoms containing an ether or thioether bond; B represents hydrogen atom, cyclohexyl group, morpholino group or piperidino group; and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represent hydrogen atom, an alkyl group having from 1 to 5 carbon atoms, alkoxy group having from 1 to 5 carbon atoms or halogen atom.Type: GrantFiled: December 28, 1992Date of Patent: August 16, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiharu Tanaka, Sadao Ishige, Takekatsu Sugiyama, Hirokazu Shimada
-
Patent number: 5053288Abstract: An optical recording medium, particularly a magneto-optical recording medium, resistant to oxidation deterioration even in a hot and humid atmosphere, is provided by forming an organic protecting adhesive layer of a UV-curved resin having (1) an acid value of not more than 1.5; and (2) a softening point of not less than 50.degree. C. The UV-curved resin layer comprises 15 to 85% by weight of acrylate and/or methacrylate having at least three functionalities; 15 to 70% by weight of a compound having a linear structure and having a molecular weight of at least 300, the compound preferably having at least one ethylenically unsaturated bond and a molecular weight of at least 150 per ethylenically unsaturated bond; and (3) a photopolymerization initiator.Type: GrantFiled: November 18, 1988Date of Patent: October 1, 1991Assignee: Teijin LimitedInventors: Eiichi Hashimoto, Tetsuo Sato, Kiyoshi Chiba
-
Patent number: 4929534Abstract: A positive-working photosensitive mixture containing an o-quinone diazide and a binder is disclosed wherein the mixture contains a compound which is able to form an azo coupling with the o-quinone diazide. A copying material produced with the photosensitive mixture has a high photosensitivity and an exceptional developer resistance. The photosensitive mixture is used in reproduction technique, and also in the field of resists.Type: GrantFiled: August 26, 1988Date of Patent: May 29, 1990Assignee: Hoechst AktiengesellschaftInventors: Trutz-Ulrich Stephani, Dieter Mohr, Britta Maisel, Werner Frass
-
Patent number: 4916042Abstract: A multicolor imaging material comprises a substrate and a photosensitive layer comprising a heat-meltable microcapsule layer. The heat-meltable microcapsule has a capsule wall including an infrared absorbent and a coupling component as core material.The photosensitive layer comprises a heat-meltable microcapsule layer and a color forming layer comprising a diazonium compound and a basic substance. The color forming layer is formed between the substrate and the heat-meltable microcapsule layer.Type: GrantFiled: October 2, 1987Date of Patent: April 10, 1990Assignee: Seiko Instruments Inc.Inventors: Hiromichi Sakojiri, Hiroshi Takahashi
-
Patent number: 4842979Abstract: A heat-sensitive recording material comprising a support having provided thereon a heat-sensitive layer containing microcapsules containing at least one diazonium salt capable of azo-coupling with 2-hydroxy-3-naphthoic acid anilide to develop a blue color, a 2-hydroxy-3-naphthoic acid amide derivative, a benzoylacetic amide derivative represented by the following formula and a basic substance: ##STR1## wherein X represents a hydrogen atom, a halogen atom, a lower alkyl group or an alkoxy, aralkyloxy, phenoxy or acylamino group having up to 18 carbon atoms; Y represents an alkyl or aralkyl group having from 7 to 18 carbon atoms, an alkoxy, aralkyloxy, phenoxy, naphthyloxy, alkylthio, aralkylthio or phenylthio group having from 6 to 18 carbon atoms, a naphthylthio group, a sulfonyloxy group, a sulfamoyl gorup, a ureido group, a thioureido group or an acylamino group; X' and Y' each represents a hydrogen atom, a halogen atom, a lower alkyl group or a lower alkoxy group; and Y and Y' may combine to form a substitType: GrantFiled: November 30, 1987Date of Patent: June 27, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Sadao Ishige, Toshimasa Usami, Hiroshi Kamikawa, Toshiharu Tanaka
-
Patent number: 4743524Abstract: Diazotypes with new yellow coupler with an active methylene group are disclosed; the couplers do not migrate and excel by their relatively reduced coupling speed for greatly improved shelf life of diazotypes. In preferred embodiments the improved new diazotypes contain acetoacetoxyethyl methacrylate or acrylate as yellow coupler.Type: GrantFiled: October 17, 1986Date of Patent: May 10, 1988Assignee: Andrews Paper & Chemical Co., Inc.Inventors: Peter Muller, Henry Mustacchi, Leonard Kreicas
-
Patent number: 4540648Abstract: The present invention relates to a two-component diazotype material comprising a support and one or several light-sensitive layers, each of which contains at least one light-sensitive diazonium salt, a coupler component and an acid stabilizer, and at least one of the layers contains a compound which absorbs light in the ultraviolet spectral region. The light-absorbing compound is present in the form of a dye salt of at least one benzothiazole which is converted into its leuco base under the action of an alkaline medium. It thus partially or completely loses its absorptivity toward radiation in the long-wave ultraviolet and short-wave visible spectral regions. The light-absorbing compound comprises a benzothiazole, in particular according to the general formula: ##STR1## wherein R.sub.1 denotes hydrogen, alkyl or aralkyl,R.sub.2 denotes hydrogen or an optionally substituted alkyl, aralkyl, aryl, pyridylalkyl, carbalkyl, carboxyalkyl, carboxyaryl, carbamoyl, or sulfamoyl radical, orR.sub.1 and R.sub.Type: GrantFiled: February 28, 1984Date of Patent: September 10, 1985Assignee: Hoechst AktiengesellschaftInventor: Siegfried Scheler
-
Patent number: 4492749Abstract: This invention relates to a derivative of 2-hydroxy-naphthalene of the general formula ##STR1## wherein A is ##STR2## and X is --OH or ##STR3## and R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are identical or different and are hydrogen, cycloalkyl having up to eight carbon atoms, which is optionally substituted by lower alkyl groups, aralkyl having up to 10 carbon atoms or aryl which is substituted by lower alkyl, lower alkoxy, halogenalkyl or alkyl-substituted amino groups or by halogen, or R.sub.1 and R.sub.2 or R.sub.3 and R.sub.4 in each case are, conjointly with the nitrogen atom to which they are attached, identical or different heterocyclic groups which are optionally substituted by lower alkyl.Type: GrantFiled: September 15, 1983Date of Patent: January 8, 1985Assignee: Hoechst AktiengesellschaftInventor: Siegfried Scheler
-
Patent number: 4421839Abstract: A heat-sensitive recording sheet is proposed which has a heat-sensitive recording layer laminated on one surface of a support body and containing a diasosulfonate; a acid coupling agent comprising a compound having aromatic ring, hetroaromatic ring or substituted aromatic ring bonded thereto OH group and COOH group; and a thermoplastic resin having a glass transition point of 70.degree.-150.degree. C. or a photocuring resin.Type: GrantFiled: March 3, 1982Date of Patent: December 20, 1983Assignees: Dai Nippon Printing Co., Ltd., Tokyo Shibaura Denki Kabushiki KaishaInventors: Ryohei Takiguchi, Masayoshi Nagashima
-
Patent number: 4400458Abstract: It is the purpose and object of the present invention to make better use of the emission range of light sources and to create the diazonium salts necessary for such purpose. The diazonium salts of the present invention of the general formula ##STR1## wherein Y is ##STR2## R.sub.1, R.sub.2 are equal or different and are, alkyl having 1 to 10 carbon atoms, aryl having 6 to 10 carbon atoms in a mono or polycylic ring;R.sub.3 is hydrogen, halogen, alkyl, alkoxy, cyano;R.sub.4 is hydrogen, halogen, alkyl, alkoxy; andX.sup.e is an anion,can be employed with all known couplers and additives in diazotype materials. They have an absorption range of 480 to 550 nm.Type: GrantFiled: September 14, 1981Date of Patent: August 23, 1983Assignee: VEB Filmfabrik WolfenInventors: Fred Walkow, Peter Czerney, Horst Hartmann, Jorg Marx
-
Patent number: 4334004Abstract: This invention relates to 2-hydroxy-3-naphthoic acid amides of the general formula: ##STR1## wherein R.sub.1 is hydrogen, a substituted or unsubstituted alkyl, cycloalkyl, aralkyl, or aryl group, and R.sub.2 and R.sub.3 are identical or different and are hydrogen, a substituted or unsubstituted alkyl, cycloalkyl, aralkyl, or aryl group, or, together with the nitrogen atom to which they are attached, a substituted or unsubstituted heterocyclic group.Type: GrantFiled: March 16, 1979Date of Patent: June 8, 1982Assignee: Hoechst AktiengesellschaftInventor: Siegfried Scheler
-
Patent number: 4304831Abstract: A two-component type diazo copying material according to this invention, which comprises a support and a photosensitive layer formed thereon, said layer consisting essentially of a diazo compound expressed by the following general formula I and a coupler mixture consisting of a compound expressed by the following formula II, a compound expressed by the following general formula III and a compound expressed by the following general formula IV, can form a genuine black-color image and is especially optimum for preparing a secondary original used in electrophotographic copying machines. General formula I ##STR1## (wherein R represents alkyl radical having 1 to 5 carbon atoms; R.sub.1 and R.sub.2 represent substituted or non-substituted alkyl radical, aralkyl radical or cycloalkyl radical, or R.sub.1 and R.sub.2 may form a heterocyclic ring together with the nitrogen atom to which they bond; and X represents anion.) ##STR2## (wherein X is of no account or represents O, S, SO or SO.sub.2.) ##STR3## [wherein R.sub.Type: GrantFiled: August 2, 1979Date of Patent: December 8, 1981Assignee: Ricoh Co., Ltd.Inventors: Tsutomu Matsuda, Masanori Rimoto
-
Patent number: 4273850Abstract: This invention relates to an improvement in a two-component diazotype material, composed of a support and of a light-sensitive layer applied to the support, the layer containing at least one benzene diazonium salt as the light-sensitive component and at least one coupler, the improvement comprising the combination of at least one 2,5-dialkoxy-4-mercaptobenzene diazonium salt and at least one compound of the general formula ##STR1## in which R.sub.1 and R.sub.2 are identical or different and denote hydrogen or alkyl, alkenyl, aralkyl, aryl or cycloalkyl groups, which can be further substituted.Type: GrantFiled: February 25, 1980Date of Patent: June 16, 1981Assignee: Hoechst AktiengesellschaftInventor: Hans-Dieter Frommeld
-
Patent number: 4230789Abstract: Thermal diazotype sheets having substituted imidazoline acid-neutralizers are shown to have shelf stability and short development times.Type: GrantFiled: March 13, 1978Date of Patent: October 28, 1980Assignee: Minnesota Mining and Manufacturing CompanyInventor: Herbert J. Fish
-
Patent number: 4225662Abstract: This invention provides yellow-developing couplers for use in diazo copying materials, which couplers are superior in light fastness and are expressed by the general formula: ##STR1## wherein X and Y represent hydrogen atom, halogen, or alkyl radical or alkoxy radical having 1 to 6 carbon atoms.Type: GrantFiled: April 11, 1979Date of Patent: September 30, 1980Assignee: Ricoh Company, Ltd.Inventors: Tsutomu Matsuda, Masanori Rimoto, Chihiro Hayashi
-
Patent number: 4220701Abstract: A method of photographic trichromatic printing comprises the steps ofA. applying to the substrate a photosensitive emulsion comprising(a) a binder;(b) three types of grains of semiconductor oxides dispersed in the binder, each adapted to desorb OH.sup.- ions under the action of a primary color radiation; and either(c) a diazo system comprising a diazonium salt and three couplers each being adsorbed onto, or dispersed in the immediate vicinity of, one of said three types of grain; or(d) a diazo system comprising a coupler and three diazonium salts each being adsorbed onto, or dispersed in the immediate vicinity of, one of said three types of grain;B. exposure,C. development by heating; andD. decomposition of unreacted diazonium salts by exposure to UV light, to fix the image.An emulsion so produced and substrates carrying such an emulsion are also produced.Type: GrantFiled: May 1, 1979Date of Patent: September 2, 1980Assignee: Roval S.A.Inventor: Jean J. Robillard
-
Patent number: 4207110Abstract: This invention relates to an improvement in a diazotype material comprising, in the light-sensitive layer, a diazo component and a coupling component which yields a black dyestuff image, the improvement that the diazo component is a 2,5-dialkoxy-4-morpholino-benzene diazonium salt and the coupling component is a combination of(a) 6-methoxy-2-hydroxy-3-naphthoic acid-N(.omega.-aminoalkyl)-amide as a blue coupler,(b) a 2-alkyl- or 2-aryl-1,3-dihydroxybenzene or a cyanoacetoamide as a yellow coupler, and(c) at least one compound of the general formula ##STR1## wherein X is zero, =S, =SO, or =SO.sub.2, as a reddish-brown coupler, the molar ratio of blue coupler to yellow coupler being in the range of about (0.7 to 0.9):1, and the molar ratio of blue coupler to reddish-brown coupler being in the range of about (6 to 12):1.Type: GrantFiled: October 13, 1978Date of Patent: June 10, 1980Assignee: Hoechst AktiengesellschaftInventors: Siegfried Scheler, Heinz Schafer