Nonsilver Image Patents (Class 430/17)
  • Patent number: 4463074
    Abstract: Radiation is directed toward a support through an ordered array of lateral walls to form interlaid radiation-exposed and shadowed microareas on the support. A first composition is then located on the support in either the shadowed or unshadowed microareas. At least one additional composition is then positioned on the support in laterally displaced microareas forming an interlaid pattern with the first microareas.
    Type: Grant
    Filed: February 9, 1983
    Date of Patent: July 31, 1984
    Assignee: Eastman Kodak Company
    Inventors: Hugh S. A. Gilmour, Richard N. Blazey
  • Patent number: 4456668
    Abstract: Azo dyes of the formula ##STR1## in which X.sub.1 and X.sub.2 independently of one another are alkyl, cycloalkyl, alkenyl, aryl or aralkyl, Y.sub.1 is hydrogen or alkyl, Y.sub.2 is hydrogen, alkyl, alkenyl or aryl or together with Y.sub.1 stands for the atoms required to complete a ring, Z.sub.1 is hydrogen, alkyl, alkenyl, alkoxy, aryl, aryloxy, alkylmercapto, arylmercapto, halogen, cyano, carbalkoxy or stands for the atoms which together with Y.sub.1 form a ring, and D.sub.1 is the radical of a heterocyclic azo component such as a thienyl, thiazolyl, benzthiazolyl, pyrazolyl or imidazolyl radical, or is phenyl optionally substituted by alkyl, cycloalkyl, alkoxy, alkenyl, electronegative substituents such as halogen, cyano, nitro or carboxylic acyl, alkyl- or phenylsulfone or N-alkyl or N,N-dialkyl-substituted sulfonamido, can be used as image dyes in photographic silver dye-bleach materials, or for dyeing textile materials.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: June 26, 1984
    Assignee: Ciba Geigy AG
    Inventors: John Lenoir, Gerald Jan
  • Patent number: 4447512
    Abstract: An O-epoxyalklyated tetrakis (hydroxyphenyl) alkane resin or the esterified reaction product of about one equivalent thereof with less than one equivalent of an ethylentically unsaturated organic acid can be combined with an aqueous alkali- and radiation sensitive, negative acting substance which when coated on a substrate forms a radiation sensitive negative working element.
    Type: Grant
    Filed: January 25, 1982
    Date of Patent: May 8, 1984
    Assignee: Polychrome Corporation
    Inventors: William Rowe, Eugene Golda, Alan Wilkes
  • Patent number: 4436798
    Abstract: Method of treating a dye image in photographic material which dye image has been formed by the color coupling reaction of a primary aromatic amine color developing agent with a phenolic color coupler of the formula ##STR1## where T is hydroxy or amino, one of R.sub.1 and R.sub.3 is the coupling position and if it is the coupling position the substituent group is hydrogen or halogen, a nitrogen-linked heterocycle or a mercapto group, the other of R.sub.1 and R.sub.3 and R.sub.2 and R.sub.4 are each hydrogen or halogen or optionally substituted organic groups, or one or R.sub.1 and R.sub.2 together or R.sub.2 and R.sub.3 together may represent the atoms necessary to complete a benzannelated ring, which treatment method comprises treating the dye image with an aqueous solution which comprises a salt of a transition (b-sub group) metal, the concentration of the metal ion in the aqueous solution being at least 10.sup.-4 M.
    Type: Grant
    Filed: June 28, 1982
    Date of Patent: March 13, 1984
    Assignee: Ciba-Geigy AG
    Inventors: Christopher D. Shennan, Michael W. Fry
  • Patent number: 4436799
    Abstract: Photographic elements, diffusion transfer assemblages, coordination complexes and processes are described which employ a novel nondiffusible compound capable of releasing at least one diffusible magenta dye moiety comprising a 4-(2-heterocyclylazo)phenol having a heterocyclic ring fused thereto, the compound having the formula: ##STR1## wherein: (a) X represents the atoms necessary to complete a 5- or 6-membered heterocyclic ring;(b) Y represents the atoms necessary to complete a 5- or 6-membered heterocyclic fused ring;(c) CAR represents a ballasted carrier moiety capable of releasing the diffusible magenta dye moiety as a function of development of a silver halide emulsion layer under alkaline conditions;(d) R represents a hydroxy group, a salt thereof, or a hydrolyzable precursor thereof, or CAR which is linked to the dye moiety through an oxygen atom thereon; and(e) n is 0, 1 or 2, with the proviso that when n is 0, then R is CAR which is linked to the dye moiety through an oxygen atom thereon.
    Type: Grant
    Filed: June 15, 1983
    Date of Patent: March 13, 1984
    Assignee: Eastman Kodak Company
    Inventors: Steven Evans, James K. Elwood
  • Patent number: 4435489
    Abstract: Hydrazone derivatives of the formula ##STR1## in which A.sub.1 is an aromatic radical, B.sub.1 is hydrogen, alkyl, cycloalkyl, aralkyl or aryl, R.sub.1, R.sub.2 and R.sub.3 independently of one another are alkyl, cycloalkyl, aralkyl or polyoxyalkylene, Z.sub.1 is arylene, X.sup..crclbar. is an anion and m is 0, 1, 2 or 3.The hydrazone derivatives are suitable as UV absorbers, especially in polymer coatings.
    Type: Grant
    Filed: September 22, 1982
    Date of Patent: March 6, 1984
    Assignee: Ciba-Geigy AG
    Inventors: Beat Muller, Martin Roth
  • Patent number: 4431720
    Abstract: An improved rear-projection viewing screen is disclosed which is characterized by having on the viewed front surface of a lenticulated transparent substrate, a single layer having image-transmitting areas and intervening light-absorbing areas. The improved screen according to the invention includes light-scattering and photographically formed light-absorbing elements in a common binder system in the image-transmitting areas and in the intervening light-absorbing areas. The light-scattering elements provide for the diffusion of the viewed image in the light-transmitting areas. The light-scattering elements in the light-absorbing areas are effective to scatter light falling on the front surface of the screen thereby improving contrast of pictures viewed on the screen.
    Type: Grant
    Filed: July 19, 1982
    Date of Patent: February 14, 1984
    Assignee: Zenith Radio Corp.
    Inventor: Meyer L. Sugarman
  • Patent number: 4423126
    Abstract: A new color-forming 4-(4'-secondary or tertiary-amino)anilino-1-carboxamidonaphthalene dye precursor in a photographic material and process enables formation of a dye image by means of cross-oxidation without the need for a coupling reaction. The color-forming 4-(4'-secondary or tertiary-amino)anilino-1-carboxamidonaphthalene dye precursor is useful in a photographic silver halide material for producing (i) a dye image, or (ii) a dye image and silver image. The exposed photographic material is processed to produce (a) a positive dye image, (b) a negative dye and negative silver image, (c) a negative dye image or (d) a positive dye image and a positive silver image. New naphthoquinoneimide dyes are also described.
    Type: Grant
    Filed: May 27, 1982
    Date of Patent: December 27, 1983
    Assignee: Eastman Kodak Company
    Inventors: James E. Klijanowicz, Csaba A. Kovacs
  • Patent number: 4418131
    Abstract: Photographic elements, diffusion transfer assemblages, coordination complexes and processes are described which employ a novel nondiffusible compound having a releasable yellow dye moiety or precursor thereof, the compound having the formula: ##STR1## wherein: (a) X represents the atoms necessary to complete a 5- or 6-membered aromatic heterocyclic fused ring;(b) Z represents alkyl, substituted alkyl, aryl or substituted aryl;(c) R represents CN or J-L;(d) J represents a bivalent ##STR2## (e) L represents alkyl, substituted alkyl, aryl, substituted aryl, or can be taken together with Z to complete a carbonyl-containing 5- or 6-membered heterocyclic or carbocyclic ring;(f) Z.sup.
    Type: Grant
    Filed: April 14, 1983
    Date of Patent: November 29, 1983
    Assignee: Eastman Kodak Company
    Inventor: Steven Evans
  • Patent number: 4411823
    Abstract: A new initiator system for radiation curable compositions is disclosed.In said system there are incorporated:(a) a compound of the formula: ##STR1## where R.sub.1 =H or a substituted or unsubstituted alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms, a cycloalkyl or cycloalkenyl group having 5 to 8 carbon atoms, a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, a furfuryl group or the group ##STR2## where Y represents a methyl group and Z an alkyl group having 2 to 4 carbon atoms or Y and Z together form a 1,3- or 1,4- alkylene group having 3 or 4 carbon atoms which is substituted or not with an alkoxy group having 1 to 4 carbon atoms; R.sub.2 =a substituted or unsubstituted alkyl group or alkenyl group having 4 to 20 carbon atoms, a cycloalkyl group or cycloalkenyl group having 5 to 8 carbon atoms, an alkaryl group having 4 to 16 carbon atoms in the alkyl group or a furfuryl group; R.sub.3 and R.sub.
    Type: Grant
    Filed: March 23, 1981
    Date of Patent: October 25, 1983
    Assignee: Akzo N.V.
    Inventors: Hendrik J. Hageman, Willem J. de Klein, Egenius A. Giezen
  • Patent number: 4411822
    Abstract: A new initiator system for radiation curable composition is disclosed.In said system there are incorporated:(a) a photoinitiator, with the exception of a compound of the formula: ##STR1## where R.sub.1 =H or an alkyl group, an alkenyl group, a cycloalkyl or cycloalkenyl group, an aryl group, a furfuryl group or the group ##STR2## where Y represents a methyl group and Z an alkyl group or Y and Z together form a 1,3- or 1,4-alkylene group having 3 or 4 carbon atoms; R.sub.2 =an alkyl group or alkenyl group, a cycloalkyl group or cycloalkenyl group, an alkaryl group or a furfuryl group; R.sub.3 and R.sub.
    Type: Grant
    Filed: March 23, 1981
    Date of Patent: October 25, 1983
    Assignee: Akzo N.V.
    Inventors: Hendrik J. Hageman, Egenius A. Giezen, Leonardus G. J. Jansen
  • Patent number: 4408532
    Abstract: A light-sensitive adduct comprising the combination of a diazo resin having a plurality of pendant diazonium groups and a sulfonated polymer having a plurality of sulfonate groups and a presensitized light-sensitive article comprising a substrate having a light-sensitive coating which is comprised of the light-sensitive adduct on a surface thereof. After imagewise exposure, unexposed portions of the coating are removable by water or aqueous developers.
    Type: Grant
    Filed: February 3, 1982
    Date of Patent: October 11, 1983
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Joseph H. Incremona
  • Patent number: 4396704
    Abstract: Solid state devices are produced by dry etching of a resist film to produce a negative resist pattern. The film comprises a polymer typically containing a halogen, and at least one type of silicon-containing or nonsilicon-containing organometallic monomer. The radiation, typically X-ray radiation, locks the monomer or monomers into the polymer, with a subsequent fixing step removing the unlocked monomer or monomers in the unirradiated portion of the resist. The film is then exposed to a plasma comprising oxygen, which removes the unirradiated portion at a faster rate than the radiated portion, producing a negative resist pattern. The plasma development is typically accomplished by reactive ion etching. Sensitizers can be used to extend the wavelength response of the films, typically into the ultraviolet or visible regions.
    Type: Grant
    Filed: April 22, 1981
    Date of Patent: August 2, 1983
    Assignee: Bell Telephone Laboratories, Incorporated
    Inventor: Gary N. Taylor
  • Patent number: 4391884
    Abstract: A process for the production of a photographic color image by the silver dye bleach process, using a photographic material which comprises, on a base, at least one light-sensitive silver halide emulsion layer, which can contain a diffusion-resistant bleachable image dye, and immediately above this layer, on the side facing the light source, a silver halide-free layer containing a diffusion-resistant, bleachable image dye.The process gives very sharp photographic color images.
    Type: Grant
    Filed: April 17, 1981
    Date of Patent: July 5, 1983
    Assignee: Ciba-Geigy AG
    Inventors: Armin Meyer, Carlo Boragine
  • Patent number: 4390606
    Abstract: A color-forming para-sulfonamidodiphenylamine dye precursor in a photographic material and process enables formation of a sulfonimide dye image by means of cross-oxidation without the need for a coupling reaction. The color-forming para-sulfonamidodiphenylamine dye precursor is useful in a photographic silver halide material for producing (i) a dye image, or (ii) a dye image and silver image. The exposed photographic material is processed to produce (a) a positive dye image, (b) a negative dye and negative silver image, (c) a negative dye image or (d) a positive dye image and a positive silver image.
    Type: Grant
    Filed: July 1, 1982
    Date of Patent: June 28, 1983
    Assignee: Eastman Kodak Company
    Inventors: Rolf S. Gabrielsen, Patricia A. Graham, James E. Klijanowicz, Max H. Stern
  • Patent number: 4389473
    Abstract: Transfer material is prepared by applying to a substrate a layer of a photosensitive material which is insoluble but swellable in the solvent used to develop the image and whose adhesion to the substrate increases on exposure to light, imagewise exposing the material and developing the so-exposed material by treatment with a solvent fully to remove unexposed material from the substrate and, if necessary, treating the remaining areas of the exposed material to render them transferable from the substrate. In this manner the full thickness of the photosensitive material layer may be retained in the final transfer material. In particular, adhesive material may be applied to the layer photosensitive material before imagewise exposure, and the adhesive coated material imagewise exposed and developed to remove photosensitive material and adhesive in the non-exposed areas only to leave adhesive coated image indicia.
    Type: Grant
    Filed: November 3, 1980
    Date of Patent: June 21, 1983
    Assignee: Letraset USA, Inc.
    Inventors: Simon L. Scrutton, William F. G. Marwick, David R. Wilson
  • Patent number: 4387158
    Abstract: Photographic silver halide material which comprises at least one silver halide emulsion layer coated on a support, there being present in the silver halide emulsion layer(s), or in a layer in operative contact with at least one silver halide emulsion layer, a compound of the formula ##STR1## wherein W is hydrogen, alkyl, --NHCOR.sup.1 or --COR.sup.1, wherein R.sup.1 is alkyl or alkenyl, cycloalkyl, aralkyl, aryl, phenoxymethylamino or halogen; X is a substituent in the coupling position and is a leaving group selected from hydrogen, chlorine, bromine, --SR.sup.11 wherein R.sup.11 is alkyl, aryl or a heterocyclic group, or X is a nitrogen-containing heterocyclic residue attached at a ring nitrogen atom; Y is a group having the formula ##STR2## wherein Q is selected from the residues: (a) --COOR.sup.4 or --CONR.sup.4 R.sup.5 where R.sup.4 is hydrogen, alkyl optionally interrupted by 1 or more oxygen atoms, alkenyl, cycloalkyl, aralkyl or aryl, and R.sup.5 is hydrogen or alkyl or R.sup.4 and R.sup.
    Type: Grant
    Filed: June 18, 1982
    Date of Patent: June 7, 1983
    Assignee: Ciba-Geigy AG
    Inventor: Stephen R. Postle
  • Patent number: 4385104
    Abstract: Photographic elements, diffusion transfer assemblages and processes are described which employ a novel nondiffusible compound having a releasable 6-(2-thienylazo)-3-pyridinol cyan dye moiety or precursor thereof, the compound containing:(a) in the 3-position of the thienylazo moiety a carboxy group, a salt thereof or a hydrolyzable precursor thereof; and(b) a ballasted carrier moiety which is capable of releasing the diffusible 6-(2-thienylazo)-3-pyridinol dye moiety or precursor thereof under alkaline conditions.
    Type: Grant
    Filed: February 12, 1982
    Date of Patent: May 24, 1983
    Assignee: Eastman Kodak Company
    Inventors: James J. Krutak, Robert J. Maleski, William H. Moore
  • Patent number: 4379819
    Abstract: A color-photographic recording material for the silver dye bleach process, which contains oil-soluble azo dyes of the formula ##STR1## in which R.sub.1 is hydrogen, alkyl, alkoxy, alkenyl, acyl, carbalkoxy, acylamino, carbamide, sulfonamide, alkylsulfone, arylsulfone, aryloxy, arylsulfonic acid ester, hydroxyl, cyano, nitro or halogen, R.sub.2 is hydrogen, alkyl, alkoxy, carbalkoxy, carbamide, sulfonamide, alkylsulfone, arylsulfone, aryloxy, cyano, nitro or halogen, R.sub.3 is hydrogen, alkyl, alkoxy, phenoxy, sulfonamide, alkylsulfone, sulfonic acid ester, cyano, nitro, halogen, carbalkoxy, carbamide or phosphoric acid diester, R.sub.4 is hydrogen, alkyl, alkoxy, carbalkoxy, carbamide, sulfonamide, acylamino, alkylsulfone, arylsulfone, hydroxyl, cyano, nitro or halogen, R.sub.5 is hydrogen, alkyl or carbalkoxy, X.sub.1 is hydrogen, alkyl, alkoxy, acylamino, alkylsulfonamide or hydroxyl, Y.sub.
    Type: Grant
    Filed: April 28, 1981
    Date of Patent: April 12, 1983
    Assignee: Ciba-Geigy AG
    Inventors: John Lenoir, Gerald Jan, Mario Fryberg
  • Patent number: 4374914
    Abstract: Negative color images are produced by the silver dye bleach process, by exposure of a photographic silver dye bleach material, silver developing, dye bleaching, silver bleaching and fixing, the silver bleaching being optionally carried out simultaneously with the dye bleaching and/or the fixing, in a single treatment bath.
    Type: Grant
    Filed: July 13, 1981
    Date of Patent: February 22, 1983
    Assignee: Ciba-Geigy Ltd.
    Inventors: Herbert Mollet, Dieter Wyrsch
  • Patent number: 4369240
    Abstract: Dry nonelectroscopic toners comprising pigmented organic resin particles having a size distribution of 0.2 to 30 micrometers, not more than 50 percent of the particles being less than 1 micrometer surface treated with a combination of at least 1% by weight of an antistatic agent and at least 0.5% of a slip agent as described. The preparation of the toners is described. The toners are useful in colr developing positive and negative-working photosensitive elements particularly in an automatic toning machine. Improved clean-up and low stain propensity are achieved.
    Type: Grant
    Filed: December 29, 1981
    Date of Patent: January 18, 1983
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Michael G. Fickes
  • Patent number: 4368248
    Abstract: Photographic elements, diffusion transfer assemblages and processes are described which employ a novel nondiffusible compound having a releasable, 2-(2-pyridylazo)-4,5-bis(tertiary amino)phenol black dye moiety or precursor thereof, such as: ##STR1## wherein: (a) R represents hydrogen, a hydrolyzable moiety or CAR;(b) R.sup.1 and R.sup.2 each independently represents an alkyl group of 1 to about 6 carbon atoms, CAR, or can be taken together with the nitrogen atom to which they are attached to complete a 5- or 6-membered heterocyclic ring;(c) R.sup.3 and R.sup.4 each independently represents an alkyl group of 1 to about 6 carbon atoms, CAR, or can be taken together with the nitrogen to which they are attached to complete a 5- or 6-membered heterocyclic ring;(d) CAR represents a ballasted carrier moiety capable of releasing the diffusible black dye moiety or precursor thereof under alkaline conditions; and(e) n is 0, 1 or 2, with the proviso that when n is 0, then at least one of R, R.sup.1, R.sup.2, R.sup.
    Type: Grant
    Filed: March 5, 1982
    Date of Patent: January 11, 1983
    Assignee: Eastman Kodak Company
    Inventor: Norman W. Kalenda
  • Patent number: 4368249
    Abstract: Photographic elements, diffusion transfer assemblages and processes are described which employ a novel nondiffusible compound having a releasable, pyridylazo(dialkylamino)phenol magenta dye moiety or precursor thereof, having the formula: ##STR1## wherein: (a) R represents hydrogen, a hydrolyzable moiety, or may be taken together with the NHSO.sub.2 group to which it is attached to form CAR;(b) R.sup.1 represents hydrogen, a hydrolyzable moiety or CAR;(c) R.sup.2 and R.sup.3 each independently represents hydrogen, CAR, an alkyl group of 1 to about 6 carbon atoms, or they can be taken together with the nitrogen to which they are attached to form a 5- or 6-membered heterocyclic ring, or one of R.sup.2 and R.sup.3 can be an aryl group having from 6 to about 10 carbon atoms; and(d) CAR represents a ballasted carrier moiety capable of releasing the diffusible magenta dye moiety or precursor thereof under alkaline conditions;with the proviso that at least one of R, R.sup.1, R.sup.2 and R.sup.3 is CAR.
    Type: Grant
    Filed: March 5, 1982
    Date of Patent: January 11, 1983
    Assignee: Eastman Kodak Company
    Inventors: Richard B. Anderson, Norman W. Kalenda
  • Patent number: 4368247
    Abstract: Oxoindolizine and oxoindolizinium dyes are useful in photographic materials and processes as image dyes. These dyes are formed in unexposed areas of photographic materials, especially photothermographic materials, by the reaction of a photosensitive cyclopropenone with a pyridine compound. Oxoindolizine and oxoindolizinium dyes are alternatively formed by (1) reaction of a photosensitive cyclopropenone with a pyridine compound and (2) reaction of the resulting product with a color forming coupler. The photographic material is imagewise exposed and then heated to a processing temperature to form a dye image. Alternatively, the oxoindolizine and oxoindolizinium dyes are produced by imbibing at least one of the reactants into the photographic material comprising a photosensitive cyclopropenone.
    Type: Grant
    Filed: June 29, 1981
    Date of Patent: January 11, 1983
    Assignee: Eastman Kodak Company
    Inventors: George L. Fletcher, Jr., Steven L. Bender, Donald H. Wadsworth
  • Patent number: 4367272
    Abstract: A photographic print prepared by a color diffusion transfer process comprising at least a support, a mordant layer containing therein a diffusion transfer dye image, and a white reflection layer constituting the background of the dye image and containing therein at least one compound represented by formula (I): ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 may be the same or different and each represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an aralkyl group, an alkoxy group, an aryloxy group, an aralkyloxy group, an alkenyl group, an alkenyloxy group, an alkylthio group, an arylthio group, an acyl group, an acylamino group, a diacylamino group, an alkylamino group, a sulfonamido group, an acyloxy group, an alkoxycarbonyl group, or an aryloxycarbonyl group, and A represents a non-metallic atom group necessary for forming a 5- or 6-membered ring.
    Type: Grant
    Filed: April 28, 1981
    Date of Patent: January 4, 1983
    Assignee: Fuji Photo Film Co., Ltd
    Inventors: Hiroshi Hayashi, Tsutomu Hamaoka, Masakazu Morigaki
  • Patent number: 4366218
    Abstract: Photographic elements, diffusion transfer assemblages and processes are described which employ a novel nondiffusible compound having a releasable, bridged, azoaminophenol magenta dye moiety or precursor thereof having the formula: ##STR1## wherein: (a) R represents hydrogen, a hydrolyzable moiety or CAR;(b) R.sup.1 represents hydrogen;(c) R.sup.2 ;l represents an alkyl group of 1 to about 6 carbon atoms or CAR; orR.sup.1 and R.sup.2 represent an alkylene group which can be taken together with the atoms to which they are attached to complete a 5- or 6-membered heterocyclic ring;(d) R.sup.3 represents an alkyl group of 1 to about 6 carbon atoms or CAR;(e) R.sup.4 represents hydrogen; orR.sup.3 and R.sup.
    Type: Grant
    Filed: March 5, 1982
    Date of Patent: December 28, 1982
    Assignee: Eastman Kodak Company
    Inventors: Richard B. Anderson, Norman W. Kalenda
  • Patent number: 4366230
    Abstract: The invention relates to a method for the preparation of highly heat-resistant relief structures with a base of polymers of heterocyclic structure by applying radiation-sensitive soluble polymer precursor stages in the form of a film or foil to a substrate, irradiating the film or foil through negative patterns with actinic light or by deflecting a light, electron or ion beam, removing the non-irradiated film or foil portions and, optionally, by subsequent annealing, as well as to the use of relief structures prepared in this manner.
    Type: Grant
    Filed: June 4, 1981
    Date of Patent: December 28, 1982
    Assignee: Siemens Aktiengesellschaft
    Inventors: Hellmut Ahne, Eberhard Kuhn, Roland Rubner
  • Patent number: 4366217
    Abstract: A motion picture film having a plurality of digitally coded soundtracks which are colorless and transparent to visible light and which fluoresce when exposed to ultraviolet light, unexposed film for providing the product, and the method for producing the product and methods for producing the exposed and unexposed films. The soundtrack images which overlie at least a portion of the visible image area of the film are digitally coded on the film using an electrostatic imaging system to imprint a fluorescent toner. The toner may comprise a fluorescent polymer having covalently bonded 3-phenyl-7-(amido or imido)-coumarin or certain substituted stilbene or N-alkyl-4-aminonaphalimides.
    Type: Grant
    Filed: June 29, 1981
    Date of Patent: December 28, 1982
    Inventors: George Bird, Peter A. Custer
  • Patent number: 4358404
    Abstract: Nondiffusible compounds are described having a releasable 6-arylazo-3-pyridinol magenta dye moiety or precursor thereof having the formula ##STR1## wherein: (a) R represents hydroxy or amino;(b) R.sup.1 represents hydrogen, a hydrolyzable moiety or CAR;(c) G represents carboxy; a hydrolyzable ester or a sulfamoyl group;(d) CAR represents a ballasted carrier moiety capable of releasing the diffusible 6-arylazo-3-pyridinol dye moiety or precursor thereof under alkaline conditions; and(e) n is 0, 1 or 2, with the proviso that when n is 0, then R.sup.1 is CAR; and wherein the phenyl ring is not substituted with a nitro group.These magenta dye-releasing compounds are used in photographic elements and diffusion transfer assemblages. The magenta dye moiety or precursor thereof is released as a function of development of a silver halide emulsion. The dye moiety then diffuses to an image-receiving layer where it forms a highly stable, metal-complexed dye transfer image.
    Type: Grant
    Filed: February 23, 1981
    Date of Patent: November 9, 1982
    Assignee: Eastman Kodak Company
    Inventors: Derek D. Chapman, James A. Reczek
  • Patent number: 4357403
    Abstract: A photoconductive plate for printing use having imaged and non-imaged portions. The plate comprises an electroconductive support and a photoconductive layer including a photoconductive material comprising an organic photoconductive pigment and a binder comprising an alkaline soluble phenol resin. The photoconductive plate is subjected to heat treatment at a sufficiently elevated temperature prior to removal of portions of the photoconductive layer so that at least 80% by volume of the non-imaged portion of the photoconductive layer is removed when the photoconductive plate is subjected to treatment with a removing solution. A method for preparing a printing plate. An image is formed on a photoconductive layer and the non-imaged portion of the photoconductive layer is removed by treating the layer with a removing solution.
    Type: Grant
    Filed: August 7, 1980
    Date of Patent: November 2, 1982
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Fumio Shimada, Kinu Hiruma
  • Patent number: 4346155
    Abstract: Photographic elements, diffusion transfer assemblages and processes are described which employ a novel nondiffusible compound having a releasable 6-arylazo-3-pyridinol magenta dye moiety or precursor thereof having the formula: ##STR1## wherein: (a) R represents hydroxy or amino;(b) R.sup.1 represents hydrogen, a hydrolyzable moiety or CAR;(c) G represents carboxy; a hydrolyzable ester or a sulfamoyl group;(d) CAR represents a ballasted carrier moiety capable of releasing the diffusible 6-arylazo-3-pyridinol dye moiety or precursor thereof under alkaline conditions; and(e) n is 0, 1 or 2, with the proviso that when n is 0, then R.sup.1 is CAR.
    Type: Grant
    Filed: August 24, 1981
    Date of Patent: August 24, 1982
    Assignee: Eastman Kodak Company
    Inventors: Derek D. Chapman, James A. Reczek
  • Patent number: 4339515
    Abstract: Compounds containing the group ##STR1## are useful in photographic materials for preventing fading of dye images.
    Type: Grant
    Filed: September 4, 1980
    Date of Patent: July 13, 1982
    Assignee: AGFA-Gevaert Aktiengesellschaft
    Inventors: Karl-Wilhelm Schranz, Johannes Sobel
  • Patent number: 4333999
    Abstract: Novel phenolic cyan dye-forming couplers contain in the 2-position a p-cyanophenylureido group. These couplers are useful in photographic emulsions, elements and processes.
    Type: Grant
    Filed: July 10, 1980
    Date of Patent: June 8, 1982
    Assignee: Eastman Kodak Company
    Inventor: Philip T. S. Lau
  • Patent number: 4330604
    Abstract: An improved process is provided for attaching layers of hydrophilic, photosensitive materials onto hydrophobic plastic substrates, which comprises forming a layer of a polycrystalline, optically transparent, moisture barrier material on the substrate, followed by depositing thereon a layer of a hydrophilic, polar material, prior to depositing the photosensitive layer thereon. The process is especially suitable for the fabrication of pre-holographic elements and holograms. Holograms are fabricated by exposing and developing latent images in the photosensitive layer of pre-holographic elements and attaching to the photosensitive layer by an optical adhesive a protective cover layer comprising a plastic substrate coated with the moisture barrier material and the hydrophilic material. Additional moisture barrier protection may optionally be provided by forming a combination of moisture barrier layers and hydrophilic layers on the outer surfaces of the plastic substrates.
    Type: Grant
    Filed: August 4, 1980
    Date of Patent: May 18, 1982
    Assignee: Hughes Aircraft Company
    Inventors: John E. Wreede, Andrejs Graube, Mark A. Mulvihill
  • Patent number: 4330606
    Abstract: Compounds of the formulae ##STR1## are useful as antifading agents in photographic materials.
    Type: Grant
    Filed: September 4, 1980
    Date of Patent: May 18, 1982
    Assignee: AGFA-Gevaert AG
    Inventors: Johannes Sobel, Karl-Wilhelm Schranz
  • Patent number: 4329409
    Abstract: An improved method for fabricating a light weight dichromated gelatin hologram package on plastic or glass substrates is provided. The prior art cover plate protecting the gelatin layer is eliminated by depositing on the gelatin a material providing a barrier to atmospheric moisture and possessing abrasion-resistant properties. In one embodiment, the photosensitive gelatin layer is deposited on a plastic substrate employing at least one subbing layer which provides a barrier to atmospheric moisture. Protection of the gelatin layer is provided by a plasma deposited silicon nitride film thereon.
    Type: Grant
    Filed: August 4, 1980
    Date of Patent: May 11, 1982
    Assignee: Hughes Aircraft Company
    Inventors: John E. Wreede, Andrejs Graube
  • Patent number: 4329410
    Abstract: A method of depositing X-ray absorber patterns on a mask membrane to achieve minimum pattern feature dimensions less than 1 .mu.m. The membrane is covered with an ultraviolet (VU) sensitive photoresist which carries a thin metallic film. The metallic film is coated with an electron beam resist. The electron beam resist is exposed to the desired pattern by an electron beam. After development, the metal film is etched through the remaining electron beam resist. This forms a stencil overlying the lower UV photoresist layer which is then exposed by an ultraviolet or soft X-ray source. After development, an X-ray absorber, such as gold, is deposited on the membrane. The final exposure step may be done by means of a point source of radiation. The X-ray absorbers will then have sloping walls to prevent shadowing of the X-ray source.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: May 11, 1982
    Assignee: The Perkin-Elmer Corporation
    Inventor: W. Derek Buckley
  • Patent number: 4326018
    Abstract: An improved lithographic printing plate prepared by exposing a lithographically suitable photosensitive sheet material through a mask or transparency, to radiation, developing the exposed sheet to remove unexposed light sensitive material and post-curing the developed sheet by exposure to high intensity radiation or air-baking at high temperatures.
    Type: Grant
    Filed: August 15, 1980
    Date of Patent: April 20, 1982
    Assignee: Polychrome Corporation
    Inventor: Paul Jargiello
  • Patent number: 4323633
    Abstract: It is desirable to protect color photographic dye images from ultraviolet radiation which tends to cause dyes to fade.It has been the practice in the art to add materials into or above the silver halide emulsions which will absorb ultraviolet radiation but allow transmission of visible radiation.One of the best classes of compounds are the 2-(2'-hydroxyphenyl)-benzotriazoles. These materials absorb ultraviolet radiation well, but tend to have poor solubility, crystallize out of the coating solution and emulsion, and diffuse through the photographic element.A novel class of substituted 2-(2'-hydroxyphenyl)-benzotriazoles has been found to reduce many of these problems.
    Type: Grant
    Filed: November 13, 1980
    Date of Patent: April 6, 1982
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Paolo Beretta
  • Patent number: 4314011
    Abstract: A color photographic material comprising a support and at least one layer thereon containing at least one compound of formula [I]: Formula [I] ##STR1## wherein R.sub.1 R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 each are defined in the specification and claims of this application.The compound of formula [I] is incorporated in a color photographic material to prevent the discoloration and fading-in-color of the color photographic material.
    Type: Grant
    Filed: June 20, 1980
    Date of Patent: February 2, 1982
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Takashi Uchida, Takashi Sasaki, Shoji Kikuchi, Katsuo Mogaki, Masahiko Taguchi, Syun Takada
  • Patent number: 4308328
    Abstract: Inclusion of a stabilizer selected from phenyl and naphthyl esters of benzene and naphthalene carboxylic acids and mixtures thereof in an article, e.g. a photographic element, comprising an organic dye or precursor thereof increases stability of the dye against ultraviolet radiation. Particularly good results are achieved when the stabilizer is dispersed in a polymer of relatively high solubility parameter and low crystallinity.
    Type: Grant
    Filed: June 18, 1980
    Date of Patent: December 29, 1981
    Assignee: Monsanto Company
    Inventors: Ival O. Salyer, Arthur M. Usmani
  • Patent number: 4301223
    Abstract: A method is described for stabilizing organic substrate materials having an absorption maximum in the range of from about 300 nm to 800 nm to light which comprises making at least one complex represented by the formula (I) coexist with the organic substrate materials in an amount effective to stabilize said organic substrate material: ##STR1## wherein M represents copper, cobalt, nickel, palladium or platinum, and R.sup.1 and R.sup.2 independently represent a hydrogen atom, an alkyl group, an aryl group, an acyl group, an N-alkylcarbamoyl group, an N-arylcarbamoyl group, or an N-alkylsulfamoyl group, an N-arylsulfamoyl group, an alkoxycarbonyl group or an aryloxycarbonyl group.
    Type: Grant
    Filed: May 19, 1980
    Date of Patent: November 17, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kotaro Nakamura, Yoshiaki Suzuki, Hiroshi Hara, Satoru Sawada, Shigeru Oono
  • Patent number: 4299895
    Abstract: A photographic element comprising a support, a layer containing an image dye ligand or dye ligand forming material and a layer containing a dye mordant, wherein the mordant layer has associated therewith:(1) a polymer containing groups which form coordination complexes with metal ions; and(2) a source of metal ions.The polymer holds the metal ions in the vicinity of the dye mordant so that the metal ions can metallize the dye or dye forming material at the image receiving layer. These complexes, elements, and receiving elements are particularly useful in diffusion transfer processes. Novel polymers are also described.
    Type: Grant
    Filed: December 10, 1979
    Date of Patent: November 10, 1981
    Assignee: Eastman Kodak Company
    Inventors: William C. Archie, Jr., Gerald A. Campbell
  • Patent number: 4293626
    Abstract: Electrophotosensitive materials having the structure ##STR1## wherein: M and N may be zero, one or two;L.sup.1, L.sup.2, L.sup.3, L.sup.4, L.sup.5, L.sup.6, and L.sup.7 may be cyano, hydrogen, substituted or unsubstituted alkyl, alkoxy, aralkyl, aryl or heterocycyl and in addition any two of L.sup.1, L.sup.2 and L.sup.3 and any two of L.sup.4, L.sup.5, L.sup.6 and L.sup.7 may together represent the elements needed to complete a carbocyclic or heterocyclic ring having from 5-12 carbon atoms;A.sup.1 may be the same as A.sup.2 and in addition may represent a substituted or unsubstituted aryl group;A.sup.2 represents a basic substituted or unsubstituted heterocyclic nucleus; andB.sup.1 and B.sup.2 represent cyano, cyanoaryl, carboxy, alkoxycarbonyl, aryloxycarbonyl, alkylsulfonyl, acyl, arylcarbonyl, heteroyl groups such as benzofuroyl, nitro, nitro substituted aryl, sulfonyl, fluorosulfonyl, trifluoromethylsulfonyl, carbamoyl, arylcarbamoyl, and alkylcarbamoyl orB.sup.2 may be combined with .dbd.CL.sup.4 -CL.
    Type: Grant
    Filed: October 31, 1980
    Date of Patent: October 6, 1981
    Assignee: Eastman Kodak Company
    Inventors: Frank G. Webster, Michael T. Regan, Louis J. Rossi
  • Patent number: 4292396
    Abstract: A method of increasing the strength, abrasion resistance, solvent resistance, and press life of a lithographic image comprising a layer of light-reacted light sensitive material and an outer layer comprising an epoxy resin overlying the light-reacted layer. In the method, the surface of the outer layer is contacted and wetted with an aqueous solution comprising a least about 7% by weight of a boron trifluoride-amine complex. Solvent is evaporated from the solution on the surface to deposit dry boron trifluoride-amine complex on the outer layer and the outer layer is heated in the presence of the complex to cross-link the epoxy resin and form a hard, tough, abrasion-resistant, solvent-resistant and wear-resistant epoxy resin layer at the outside of the image. Further included in the invention are a curing composition adapted for topical application to a lithographic image in carrying out the method of the invention and a planographic printing plate produced thereby.
    Type: Grant
    Filed: March 3, 1980
    Date of Patent: September 29, 1981
    Assignee: Western Litho Plate & Supply Co.
    Inventors: Lester O. Eime, Edward H. Parker
  • Patent number: 4288510
    Abstract: This invention relates to the production of information carriers on which the information is recorded along a track; the process of making the information carrier comprises a first step of materializing the track itself before recording any information by forming a groove in an auxiliary layer, the track thus being capable of being optically detected, and a second step of recording the information in a photosensitive layer in contact with the auxiliary layer along the track previously formed.
    Type: Grant
    Filed: September 22, 1980
    Date of Patent: September 8, 1981
    Assignee: Thomson-Brandt
    Inventors: Claude Tinet, Claire Lemonon
  • Patent number: 4288511
    Abstract: A photographic element comprises a support having thereon a layer containing a hydrophilic vehicle having dispersed therein a particulate polymeric material encapsulated with a chelating or already chelated polymer, said element, when the polymer is not already chelated, comprising a source of metal ions. The elements are useful in diffusion transfer processes, and particularly useful with chelating acid dyes or dye-forming materials to provide a metallized dye image.
    Type: Grant
    Filed: April 29, 1980
    Date of Patent: September 8, 1981
    Assignee: Eastman Kodak Company
    Inventors: Drewfus Y. Myers, Jr., George H. Hawks, III
  • Patent number: 4287152
    Abstract: Dye fading during archival storage of developed color photographic film (17) is retarded by placing the film in a sealed, opaque vault (10), introducing a dry, pressurized inert gas into the vault while the latter is vented, and sealing the vault after the air within the vault has been purged and replaced by the inert gas. Preferably, the gas is nitrogen; and the vault is stored at a temperature below room temperature to preserve the color photographic emulsions on the film contained within the vault. For short-term storage, sodium thiocyanate pads (36) charged with water are placed within the vault. For long term storage, the interior of the vault is kept at a low relative humidity.
    Type: Grant
    Filed: February 7, 1980
    Date of Patent: September 1, 1981
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Richard B. Hoover, Charles M. Rhodes
  • Patent number: 4286046
    Abstract: Process for preparation of multicolor surprint proofs from a composite photoimaged element, e.g., photopolymer element, having, in order, a sheet support, at least two colored photoimaged elements, and a layer of colloidal silica applied thereon, said colloidal silica being coated from a substantially aqueous dispersion wherein the colloidal silica has an average particle diameter of less than 500 nm and wherein at least 75% of the solids of said dispersion are silica, the silica layer being at least 20 mg/dm.sup.2 when dried. The multicolor proofs obtained contain a sharp image free from any three-dimensional effects and have a delustered, matte appearance which simulates printed press sheets.
    Type: Grant
    Filed: June 4, 1979
    Date of Patent: August 25, 1981
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Abraham B. Cohen, Roxy Fan
  • Patent number: T101601
    Abstract: Novel phenolic cyan dye-forming couplers contain in the 2-position a p-cyanophenylureido group. These couplers are useful in photographic emulsions, elements and processes.
    Type: Grant
    Filed: July 6, 1981
    Date of Patent: March 2, 1982
    Inventor: Philip T. S. Lau