Aceto-aceto Or Heterocyclic Coupler Included Patents (Class 430/182)
  • Patent number: 7300738
    Abstract: A recording material having, on a support, a recording layer containing an azolinyl acetic acid derivative and a diazo compound. The azolinyl acetic acid derivative is preferably is a compound represented by the following general formula (1): wherein X represents an oxygen atom or a sulfur atom; R11 represents an alkyl group, an aryl group, a heterocyclic group, —OR13 or —NR14R15; R12 represents a substituent; R13 represents an alkyl group, an aryl group or a heterocyclic group; R14 and R15 each independently represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group; n represents an integer from 0 to 4; and, when n is an integer of 2 or greater, two or more R12s may be linked with each other to form a ring.
    Type: Grant
    Filed: February 9, 2004
    Date of Patent: November 27, 2007
    Assignee: Fujifilm Corporation
    Inventors: Naoki Saito, Tetsunori Matsushita, Akinori Fujita, Yohsuke Takeuchi, Satoshi Higuchi, Kimi Ikeda
  • Patent number: 6927007
    Abstract: A heat-sensitive recording material including a substrate having disposed thereon a heat-sensitive recording layer containing a diazo compound and a coupler compound capable of reacting with the diazo compound to develop color, wherein the coupler compound includes at least one of anilide derivatives represented by the following formula (1) or tautomers thereof: wherein R1 represents an alkyl group or an aryl group; R2, R3 and R4 each independently represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an acyl group, an alkoxy group, an alkoxycarbonyl group, a hydroxycarbonyl group, an aminocarbonyl group, an acylamino group, a cyano group, a nitro group, an arylthio group or an alkylthio group; L represents a group which can leave upon coupling with the diazo compound; m represents 1 or 2; and n represents 1 or 2.
    Type: Grant
    Filed: October 27, 2003
    Date of Patent: August 9, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yohsuke Takeuchi, Akinori Fujita, Daisuke Arioka, Tetsunori Matsushita
  • Patent number: 6864032
    Abstract: The present invention provides a method for forming an azo colorant by reaction of a diazo compound and a coupler. The coupler has a leaving group at the coupling position thereof, such that a coupling reaction rate is faster than it would be if the coupler did not have the leaving group. The coupling reaction rate constant k is preferably 0.1 (s?1) or more.
    Type: Grant
    Filed: April 18, 2001
    Date of Patent: March 8, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisao Yamada, Mitsuyuki Tsurumi, Kazunori Nigorikawa
  • Publication number: 20040048185
    Abstract: A heat-sensitive recording material containing a support and a heat-sensitive recording layer formed on the support, the heat-sensitive recording layer including a diazonium salt and a coupler that thermally reacts with the diazonium salt to develop color.
    Type: Application
    Filed: August 29, 2003
    Publication date: March 11, 2004
    Applicant: FUJI PHOTO FILM CO., LTD
    Inventors: Hisao Yamada, Hiroshi Sato, Yoshimitsu Arai, Kimi Ikeda
  • Patent number: 6346359
    Abstract: Disclosed are a pyrrolopyrimidineone compound represented by the following general formula (1) and a heat-sensitive recording material using the pyrrolopyrimidineone compound as a coupler: General formula (1) wherein R1 and R2 each independently represents a hydrogen atom, a halogen atom, an aryl group, an alkyl group, a cyano group, an acyl group, a carbamoyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkylsulfonyl group, or an arylsulfonyl group; R3 represents an amino group, a substituted amino group, a hydroxyl group, an acyloxy group, an arylcarboxyl group, an alkoxy group, an aryloxy group, an alkylthio group, or an arylthio group; R4 represents a hydrogen atom, a halogen atom, or an electron attracting group whose Hammett substituent constant &sgr;p is 0.2 or more; and L represents a substituent group which can leave when the compound reacts with a diazonium salt.
    Type: Grant
    Filed: April 24, 2000
    Date of Patent: February 12, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisao Yamada, Mitsuyuki Tsurumi, Kazunori Nigorikawa
  • Patent number: 6329116
    Abstract: An object of the present invention is to provide a pyrrolo[1,2-a]pyrimidine compound that is useful as a coupler providing excellent hue of a cyan system and sufficient density of formed color. The pyrrolo[1,2-a]pyrimidine compound of the present invention for achieving the object is represented by one of following general formulae (1), (2) and (3).
    Type: Grant
    Filed: November 17, 1999
    Date of Patent: December 11, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Sato, Tatsuo Kawabuchi, Mitsuyuki Tsurumi, Tetsunori Matsushita, Hisato Nagase, Kimiatsu Nomura, Yoshihiro Jimbo, Kazunori Nigorikawa
  • Patent number: 6268104
    Abstract: A heat-sensitive recording material comprising a support and a heat-sensitive recording layer thereon, which contains a diazonium salt compound and a coupling component, is provided. The diazonium salt compound contains a benzenediazonium salt compound represented by formula (1) and the coupling component contains a uracil compound represented by formula (2) or a barbituric acid compound represented by formula (3).
    Type: Grant
    Filed: November 10, 1999
    Date of Patent: July 31, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masatoshi Yumoto, Kimi Ikeda, Hiroshi Yamamoto
  • Patent number: 6060206
    Abstract: Disclosed is a photo- and heat-sensitive recording material comprising a substrate and a photo- and heat-sensitive recording layer formed thereon containing a diazo compound and a coupler, wherein the coupler is a compound represented by the general formula (1) or the general formula (2): ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each independently a hydrogen atom or a substituent group; and R.sup.1 and R.sup.2 may join with each other to form a ring. The reaction between the coupler represented by the general formula (2) and a specific diazo compound produces a magenta colorant having very sharp absorption characteristics. In short, the present invention provides a photo- and heat-sensitive recording material which does not inhibit the fixing and which exhibits excellent color formation, color reproduction, and image durability. Further, the present invention provides a magenta colorant which exhibits excellent absorption characteristics.
    Type: Grant
    Filed: October 1, 1998
    Date of Patent: May 9, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Hanaki, Yasuhiro Mitamura, Atsuhiro Ohkawa
  • Patent number: 6017672
    Abstract: A heat-sensitive recording material having formed on a support a heat-sensitive recording layer containing a diazonium salt and a coupling component, wherein the diazonium salt is a compound represented by the following formula (1): ##STR1## wherein R.sup.1 represents an alkyl group or an aryl group; R.sup.2, R.sup.3, R.sup.4 and R.sup.5 each independently represents a hydrogen atom or an alkyl group, at least one of R.sup.2, R.sup.3, R.sup.4, and R.sup.5 represents an alkyl group, and R.sup.2 and R.sup.3, or R.sup.4 and R.sup.5, or R.sup.1 and R.sup.3, or R.sup.1 and R.sup.4, may combine with each other to form a ring; and X.sup.- represents an anion.
    Type: Grant
    Filed: September 1, 1998
    Date of Patent: January 25, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshimitsu Arai, Masatoshi Yumoto, Kimiatsu Nomura
  • Patent number: 5925489
    Abstract: Disclosed is a heat-sensitive recording material comprising a substrate having thereon a heat-sensitive recording layer containing a diazonium salt compound and a coupler, pyrrolo?1,2-a! pyrimidine compound, as the coupler, being represented by the following general formula (1): ##STR1## wherein R.sup.1 to R.sup.4 each represents a hydrogen atom, a halogen atom, an aryl group, an alkyl group, a cyano group, an acyl group, a substituted carbamoyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an acyloxy group, an alkoxy group, an aryloxy group, an alkylthio group, or an arylthio group.The diazo-type heat-sensitive recording material, which develops a violet to cyan color, has excellent image stability and image fixing characteristics.
    Type: Grant
    Filed: February 13, 1998
    Date of Patent: July 20, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tatsuo Kawabuchi, Hiroshi Sato, Kimiatsu Nomura, Masanobu Takashima
  • Patent number: 5866293
    Abstract: A heat-sensitive recording material having excellent light-fastness and raw stock storability is disclosed. The material includes a support and a heat-sensitive recording layer provided on the support, and the heat-sensitive recording layer contains a diazo compound and a coupler. The coupler contains at least one species of pyrazolone compounds represented by the following formula (1): ##STR1## wherein Ar represents a phenyl group, a naphthyl group, or an aromatic heterocyclic group, any one of which may have a substituent bonded to the nucleus, said substituent may be a halogen atom, a cyano group, a trifluoromethyl group, an alkyl group, an aryl group, an alkoxycarbonyl group, a carbamoyl group, or a sulfamoyl group; R.sup.1 and R.sup.2 independently represent an alkyl group, an alkenyl group, or an aryl group, or R.sup.1 and R.sup.2 may be linked to each other so as to form a heterocycle.
    Type: Grant
    Filed: May 21, 1997
    Date of Patent: February 2, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kimiatsu Nomura, Hiroshi Sato, Naoto Yanagihara, Tetsunori Matsushita, Shojiro Sano
  • Patent number: 5683850
    Abstract: A diazo heat-sensitive recording material having excellent raw stock storability and image storage characteristics, which comprises a support having thereon a recording layer comprising a diazo compound, a coupling component and an organic base. The diazo compound is a 4-disubstituted amino-2-alkoxybenzenediazonium salt and the coupling component is a compound represented by the following general formula: ##STR1## wherein R.sub.4, R.sub.5, R.sub.6 and R.sub.7 each represents a hydrogen atom, an alkyl group, an aryl group, an aralkyl group, an alkyloxy group, an aryloxy group, an alkylthio group, an arylthio group, an acyl group, an alkoxycarbonyl group, an acyloxy group, a carbamoyl group, a sulfamoyl group, a halogen atom, a cyano group or a nitro group.
    Type: Grant
    Filed: December 2, 1996
    Date of Patent: November 4, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetunori Matushita, Hiroshi Sato, Sadao Ishige, Kimiatsu Nomura, Mitsuyuki Tsurumi
  • Patent number: 5582952
    Abstract: A photosensitive lithographic printing plate which provides a wide range of proper conditions for development, high impression capacity, a flexible film sufficient in adhesion to a support and excellent processing suitability with a weakly alkaline developer (pH 12.5 or less) is disclosed. The photosensitive lithographic printing plate comprises a support and a photosensitive layer provided thereon, wherein the photosensitive layer is formed from a photosensitive composition containing at least a two-equivalent coupler residue-containing compound and a photosensitive compound or a photosensitive mixture acting as a positive type.
    Type: Grant
    Filed: March 7, 1995
    Date of Patent: December 10, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Kawamura, Keiji Akiyama, Toshifumi Inno, Katsuji Kitatani
  • Patent number: 5561019
    Abstract: Magnetic toner used for electrophotographic development includes additives such as inorganic fine particles, having a particular particle diameter and specific surface area, and hydrophobic silica having a particular specific surface area and surface treatment, so that the magnetic toner can provide images of high quality without generating photoconductor filming. The magnetic toner is applied to the electrophotographic method including the developing step of forming electrostatic latent images on a photoconductor containing a stationary magnet, magnetically attracting the magnetic toner to the surface of the photoconductor in a toner sump, and collecting toner at a non-image section by an electrode roller; the transferring step of transferring the toner to transfer paper; the cleaning step of removing residual magnetic toner left on the photoconductor in the transferring step; and the recycling step of recycling the residual magnetic toner.
    Type: Grant
    Filed: April 11, 1995
    Date of Patent: October 1, 1996
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yasuhito Yuasa, Noriaki Hirota, Akinori Toyoda, Hideki Tatematsu
  • Patent number: 5424164
    Abstract: A recording material which comprises a support having provided thereon capsules containing a photosensitive diazonium salt, and a polymerizable coupler. The recording material can give a predetermined hue when light, pressure, heat and the like are applied alone or in combination. The main advantages of the recording material are that a specific hue can be selected safely, mixing of colors can be avoided, desensitization problem does not occur and a fixed image can be obtained.
    Type: Grant
    Filed: November 10, 1994
    Date of Patent: June 13, 1995
    Assignee: Fuji Photo Film Co., Ltd
    Inventors: Masato Satomura, Ken Iwakura, Akira Igarashi
  • Patent number: 5407777
    Abstract: A diazo-type recording material comprising a support having thereon a recording layer comprising a photosensitive diazo compound enclosed in microcapsules, a coupling component which reacts with said diazo compound by heating at a basic pH to develop a color, and a 1-phenyl-3-pyrazolidone compound represented by the formula: ##STR1## wherein the substituents X, and R.sub.1 -R.sub.4 are defined in the specification.
    Type: Grant
    Filed: November 17, 1992
    Date of Patent: April 18, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hirokazu Shimada, Akihiro Shimomura
  • Patent number: 5338642
    Abstract: A novel diazo type recording material is provided comprising a recording layer containing at least one light-sensitive diazo compound incorporated in microcapsules and a coupling component which undergoes reaction with said diazo compound in a basic atmosphere to develop a color on a support, wherein said coupling component is a mixture of at least one compound represented by the following general formula [I] and at least one compound represented by the following general formula [II]: ##STR1## wherein A represents an alkylene group having from 1 to 22 carbon atoms containing an ether or thioether bond; B represents hydrogen atom, cyclohexyl group, morpholino group or piperidino group; and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represent hydrogen atom, an alkyl group having from 1 to 5 carbon atoms, alkoxy group having from 1 to 5 carbon atoms or halogen atom.
    Type: Grant
    Filed: December 28, 1992
    Date of Patent: August 16, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiharu Tanaka, Sadao Ishige, Takekatsu Sugiyama, Hirokazu Shimada
  • Patent number: 5296329
    Abstract: A diazo heat-sensitive recording material which comprises a support having thereon a heat-sensitive recording layer comprising a diazo compound, a coupling component, a basic substance, and a binder; wherein the coupling component is an acylacetanilide represented by the formula (I): ##STR1## wherein R.sub.1 is substituted or unsubstituted alkyl or aryl; R.sub.2 is substituted or unsubstituted alkyl or aralkyl; R.sub.3 is substituted of unsubstituted alkyl, alkoxy, aralkyloxy, alkylthio, or aralkylthio, substituted amino, or halogeno; the total number of carbon atoms in R.sub.2 and (R.sub.3).sub.n is 5 or more; n is zero or an integer of from 1 to 4; and the R.sub.3 's may be the same or different when n is 2 or more, which is useful for forming a yellow color image and providing a developed color image with higher light-fastness, less soiling of a non-image area, and improved uniformity in color-developing layer due to the use of a more oil-soluble coupling component.
    Type: Grant
    Filed: July 26, 1993
    Date of Patent: March 22, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takekatsu Sugiyama, Akira Igarashi
  • Patent number: 5225309
    Abstract: Disclosed is a light-sensitive litho printing plate comprising:a support, a light-sensitive layer and a silicone rubber layer provided thereon,wherein said light-sensitive layer contains a substance,whereby said substance forms a color during developing or after developing.
    Type: Grant
    Filed: March 19, 1992
    Date of Patent: July 6, 1993
    Assignees: Konica Corporation, Mitsubishi Kasei Corporation
    Inventors: Norihito Suzuki, Kiyoshi Goto, Hiroshi Tomiyasu, Kazuo Noguchi, Akeo Kasakura
  • Patent number: 4957847
    Abstract: A heat-sensitive recording material comprising a base and, on top of the said base, a heat-sensitive layer containing a cyclic diazo component and a coupling component, the cyclic diazo component being a benzotriazine compound of the formula ##STR1## wherein Q is --CH.sub.2 --, --CO-- or --SO.sub.2 --, R is hydrogen, hydroxyl, or aryl or alkenyl, each unsubstituted or substituted by halogen, hydroxyl, cyano, lower alkoxy, lower alkylthio, acyloxy, lower alkoxycarbonyl or lower alkylsulfonyl, or is acyl, acyloxy or acylamino, cycloalkyl, or is aryl or aralkyl such as phenyl, phenylalkyl or naphthyl each unsubstituted or substituted on the ring by cyano, halogen, nitro, trifluoromethyl, lower alkyl, lower alkylthio, lower alkoxy, lower alkylcarbonyl or lower alkoxycarbonyl, or is a heterocyclic radical, and the benzene ring A is unsubstituted or substituted by halogen, cyano, nitro, lower alkyl, lower alkoxy, lower alkylthio, lower alkylcarbonyl or lower alkoxycarbonyl.
    Type: Grant
    Filed: December 2, 1988
    Date of Patent: September 18, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Jean-Marie Adam, Hans Baumann
  • Patent number: 4929534
    Abstract: A positive-working photosensitive mixture containing an o-quinone diazide and a binder is disclosed wherein the mixture contains a compound which is able to form an azo coupling with the o-quinone diazide. A copying material produced with the photosensitive mixture has a high photosensitivity and an exceptional developer resistance. The photosensitive mixture is used in reproduction technique, and also in the field of resists.
    Type: Grant
    Filed: August 26, 1988
    Date of Patent: May 29, 1990
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Trutz-Ulrich Stephani, Dieter Mohr, Britta Maisel, Werner Frass
  • Patent number: 4895826
    Abstract: A heat-sensitive recording material is disclosed, which comprises a support having thereon a heat-sensitive recording layer comprising a diazo compound and a coupler precursor compound, said coupler precursor compound being capable of forming a compound having an ability of coupling with said diazo compound upon heating.
    Type: Grant
    Filed: April 25, 1988
    Date of Patent: January 23, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsuhiko Watanabe, Takayuki Hayashi, Hiroshi Kamikawa, Masato Satomura, Takekatsu Sugiyama
  • Patent number: 4842979
    Abstract: A heat-sensitive recording material comprising a support having provided thereon a heat-sensitive layer containing microcapsules containing at least one diazonium salt capable of azo-coupling with 2-hydroxy-3-naphthoic acid anilide to develop a blue color, a 2-hydroxy-3-naphthoic acid amide derivative, a benzoylacetic amide derivative represented by the following formula and a basic substance: ##STR1## wherein X represents a hydrogen atom, a halogen atom, a lower alkyl group or an alkoxy, aralkyloxy, phenoxy or acylamino group having up to 18 carbon atoms; Y represents an alkyl or aralkyl group having from 7 to 18 carbon atoms, an alkoxy, aralkyloxy, phenoxy, naphthyloxy, alkylthio, aralkylthio or phenylthio group having from 6 to 18 carbon atoms, a naphthylthio group, a sulfonyloxy group, a sulfamoyl gorup, a ureido group, a thioureido group or an acylamino group; X' and Y' each represents a hydrogen atom, a halogen atom, a lower alkyl group or a lower alkoxy group; and Y and Y' may combine to form a substit
    Type: Grant
    Filed: November 30, 1987
    Date of Patent: June 27, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sadao Ishige, Toshimasa Usami, Hiroshi Kamikawa, Toshiharu Tanaka
  • Patent number: 4770973
    Abstract: In a heat-sensitive recording material which comprises a substrate and a heat-sensitive recording layer thereon containing a diazonium salt and coupler compound, the heat-sensitive recording material characterized in that the coupler compound comprises at least one compound represented by the formula [I] below ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 are each hydrogen atom, halogen atom, alkyl or alkoxyl; R.sub.9 is hydrogen atom or alkyl; X and Y are each hydrogen atom, --OR.sub.10 or --N(R.sub.11)(R.sub.12), R.sub.10, R.sub.11 and R.sub.12 being each hydrogen atom, alkyl, alicyclic group, aryl or aralkyl, these R.sub.10, R.sub.11 and R.sub.12 may have a substituent selected from among halogen atom, alkyl and alkoxy, R.sub.11 and R.sub.12 may link together to form a heteroring, or, one or both of R.sub.11 and R.sub.12 may form a heteroring together with an adjacent benzene ring; n is 0 or 1.
    Type: Grant
    Filed: November 7, 1986
    Date of Patent: September 13, 1988
    Assignee: Kanzaki Paper Manufacturing Limited
    Inventors: Nobuo Kanda, Katsuhiko Ishida, Tosaku Okamoto, Mitsuru Kondo
  • Patent number: 4743524
    Abstract: Diazotypes with new yellow coupler with an active methylene group are disclosed; the couplers do not migrate and excel by their relatively reduced coupling speed for greatly improved shelf life of diazotypes. In preferred embodiments the improved new diazotypes contain acetoacetoxyethyl methacrylate or acrylate as yellow coupler.
    Type: Grant
    Filed: October 17, 1986
    Date of Patent: May 10, 1988
    Assignee: Andrews Paper & Chemical Co., Inc.
    Inventors: Peter Muller, Henry Mustacchi, Leonard Kreicas
  • Patent number: 4659644
    Abstract: A diazo-type thermosensitive recording material is disclosed, which comprises a support material and a thermosensitive coloring layer formed on the support material, which thermosensitive coloring layer comprises a diazonium compound, a coupler and a thermo-fusible or thermo-softening material, the coupler being a combination of a hydrazone-type coupler of the formula of R.sup.1 --NH--N.dbd.CH--R.sup.2 (wherein R.sup.1 and R.sup.2 are defined in detail in the specification) and a two-valence metal compound capable of chelating with the coupled product produced by the coupling of the diazonium compound and the hydrazone-type coupler.
    Type: Grant
    Filed: December 19, 1984
    Date of Patent: April 21, 1987
    Assignee: Ricoh Company, Ltd.
    Inventors: Takayuki Hoshina, Michihisa Takahashi, Masanori Rimoto, Masanaka Nagamoto
  • Patent number: 4652512
    Abstract: This invention provides a heat-sensitive recording material comprising a substrate and a heat-sensitive recording layer which is formed over the substrate and which contains a diazonium salt, a coupler and at least one of specific heat-fusible basic amidine and diamidine compounds in which the nitrogen atom(s) of ##STR1## moiety(moieties) has(have) a substituent and the nitrogen atom(s) or ##STR2## moiety(moieties) has(have) at least one substituent, the substituent being independently selected from the group consisting of phenyl, naphthyl, phenyl-C.sub.1 -C.sub.4 alkyl and naphthyl-C.sub.1 -C.sub.4 alkyl, each optionally substituted with C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, phenyloxy, nitro or halogen, and in which amidine compounds are other than formamidines. The heat-sensitive recording material is especially excellent in storage stability.
    Type: Grant
    Filed: January 29, 1986
    Date of Patent: March 24, 1987
    Assignee: Kanzaki Paper Manufacturing Company, Limited
    Inventors: Katsuhiko Ishida, Masaharu Nojima, Tosaku Okamoto
  • Patent number: 4650740
    Abstract: A heat-sensitive recording material is described, comprising a support having provided thereon a recording layer comprising a binder containing a diazonium compound and a coupling component, said diazonium compound being a diazonium salt represented by formula (I)ArN.sub.2.sup.+ X.sup.- (I)wherein Ar represents a substituted or unsubstituted aromatic moiety; and X.sup.- represents an acid anion containing an alkyl group having three or more fluorine atoms.
    Type: Grant
    Filed: September 13, 1984
    Date of Patent: March 17, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshimasa Usami, Toshiharu Tanaka, Fumiaki Shinozaki
  • Patent number: 4642283
    Abstract: A negative working light-sensitive lithographic plate requiring no dampening solution and a plate making process are described, the negative working light-sensitive lithographic plate comprising a support having, in sequence, on said support, (A) a light-sensitive layer containing (1) an o-quinonediazide compound and (2) a coupling component which causes a diazo coupling reaction under a basic environment, and (B) a silicone rubber layer, and the plate making process comprising imagewise exposing the negative working light-sensitive lithographic plate and developing said exposed plate to obtain a lithographic plate requiring no dampening solution, wherein a step of processing with base is carried out after imagewise exposure.
    Type: Grant
    Filed: March 14, 1985
    Date of Patent: February 10, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Takahashi, Yasuhisa Narutomi, Yoshimasa Aotani, Keisuke Shiba
  • Patent number: 4590263
    Abstract: Novel diazonium salts which possess excellent photo speed, good thermal stability, exceptional resistance to discoloration in the D.sub.min areas, rapid development, and allow a wide range of azo dye colors are provided. The diazonium salts are of the following formula: ##STR1## wherein R.sub.1 is tertiary butyl or tertiary amyl; Y is hydrogen, alkyl, hydroxyalkyl, cyanoalkyl, cycloalkyl, aralkyl, alkoxy, aryloxy, aralkoxy, aralkylthio, arylthio, alkylthio, halogen, allyl, allyloxy, allylthio, cyanoalkoxy, hydroxyalkoxy, methoxyalkoxy, trifluoroalkyl, alkylacetylamino, morpholino, or dialkyl carbonamido;R.sub.2 and R.sub.3 are the same or different, and are alkyl, aralkyl, allyl, cyanoalkyl, hydroxyalkyl, hydrogen, acyl, cycloalkyl, beta-chloroalkyl, branched alkyl, or a structure wherein R.sub.2 and R.sub.3 may be linked together to form a heterocyclic structure; andX is an anion.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: May 20, 1986
    Assignee: James River Graphics, Inc.
    Inventors: Robert C. Desjarlais, Everett W. Bennett
  • Patent number: 4446218
    Abstract: This invention relates to proof film-type light sensitive diazonium materials containing accelerators selected from sulfur and/or amide-containing compounds which are capable of accelerating the contact exposure of negative-working diazonium compounds when such diazonium compounds are subjected to UV radiation. These accelerators enhance essentially photosensitivity speed. The invention also relates to presensitized reproduction materials comprising diazonium materials containing these accelerators.
    Type: Grant
    Filed: March 18, 1982
    Date of Patent: May 1, 1984
    Assignee: American Hoechst Corporation
    Inventor: Major S. Dhillon
  • Patent number: 4401744
    Abstract: Disclosure is made of a light-sensitive diazo coating composition and a light-sensitive diazotype reproduction material comprising a base with at least one coating layer comprising a light sensitive diazo compound, coupling component, a stabilizing acid and salt, and a development accelerating and stabilizing composition of 1,3-dimethylurea with urea or with thiourea, which also improves sensitizing solution compatibility and increases printing speed.
    Type: Grant
    Filed: May 6, 1981
    Date of Patent: August 30, 1983
    Assignee: Andrews Paper & Chemical Co., Inc.
    Inventor: Peter Muller
  • Patent number: 4400458
    Abstract: It is the purpose and object of the present invention to make better use of the emission range of light sources and to create the diazonium salts necessary for such purpose. The diazonium salts of the present invention of the general formula ##STR1## wherein Y is ##STR2## R.sub.1, R.sub.2 are equal or different and are, alkyl having 1 to 10 carbon atoms, aryl having 6 to 10 carbon atoms in a mono or polycylic ring;R.sub.3 is hydrogen, halogen, alkyl, alkoxy, cyano;R.sub.4 is hydrogen, halogen, alkyl, alkoxy; andX.sup.e is an anion,can be employed with all known couplers and additives in diazotype materials. They have an absorption range of 480 to 550 nm.
    Type: Grant
    Filed: September 14, 1981
    Date of Patent: August 23, 1983
    Assignee: VEB Filmfabrik Wolfen
    Inventors: Fred Walkow, Peter Czerney, Horst Hartmann, Jorg Marx
  • Patent number: 4304831
    Abstract: A two-component type diazo copying material according to this invention, which comprises a support and a photosensitive layer formed thereon, said layer consisting essentially of a diazo compound expressed by the following general formula I and a coupler mixture consisting of a compound expressed by the following formula II, a compound expressed by the following general formula III and a compound expressed by the following general formula IV, can form a genuine black-color image and is especially optimum for preparing a secondary original used in electrophotographic copying machines. General formula I ##STR1## (wherein R represents alkyl radical having 1 to 5 carbon atoms; R.sub.1 and R.sub.2 represent substituted or non-substituted alkyl radical, aralkyl radical or cycloalkyl radical, or R.sub.1 and R.sub.2 may form a heterocyclic ring together with the nitrogen atom to which they bond; and X represents anion.) ##STR2## (wherein X is of no account or represents O, S, SO or SO.sub.2.) ##STR3## [wherein R.sub.
    Type: Grant
    Filed: August 2, 1979
    Date of Patent: December 8, 1981
    Assignee: Ricoh Co., Ltd.
    Inventors: Tsutomu Matsuda, Masanori Rimoto
  • Patent number: 4225662
    Abstract: This invention provides yellow-developing couplers for use in diazo copying materials, which couplers are superior in light fastness and are expressed by the general formula: ##STR1## wherein X and Y represent hydrogen atom, halogen, or alkyl radical or alkoxy radical having 1 to 6 carbon atoms.
    Type: Grant
    Filed: April 11, 1979
    Date of Patent: September 30, 1980
    Assignee: Ricoh Company, Ltd.
    Inventors: Tsutomu Matsuda, Masanori Rimoto, Chihiro Hayashi