And Monomeric Processing Ingredient Patents (Class 430/196)
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Patent number: 12179157Abstract: This disclosure relates to blended polymeric membranes containing a polyimide polymeric matrix blended with a crosslinked polymer of intrinsic microporosity and methods of using the membranes for gas separation applications, such as removal of CO2 from natural gas.Type: GrantFiled: October 28, 2021Date of Patent: December 31, 2024Assignee: Saudi Arabian Oil CompanyInventor: Junyan Yang
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Patent number: 12018127Abstract: In various aspects, a polymer resin is provided for vat photopolymerization. The resin can include a polyamic acid salt formed from the addition of a photocrosslinkable amine to a polyamic acid. The resin can include a photoinitiator suitable for initiating crosslinking of the photocrosslinkable amine when exposed to a light source of a suitable wavelength and intensity. The polyamic acid can be formed, for instance, by the addition of a diamine to a suitable dianhydride. Methods of additive manufacturing using the resins are also provided.Type: GrantFiled: February 13, 2019Date of Patent: June 25, 2024Assignee: Virginia Tech Intellectual Properties, Inc.Inventors: Jana Herzberger, Timothy E. Long, Viswanath Meenakshisundaram, Christopher B. Williams
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Patent number: 11764061Abstract: Water soluble organic-inorganic hybrid masks and mask formulations, and methods of dicing semiconductor wafers are described. In an example, a mask for a wafer singulation process includes a water-soluble matrix based on a solid component and water. A p-block metal compound, an s-block metal compound, or a transition metal compound is dissolved throughout the water-soluble matrix.Type: GrantFiled: November 17, 2021Date of Patent: September 19, 2023Assignee: Applied Materials, Inc.Inventors: Wenguang Li, James S. Papanu
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Patent number: 11550223Abstract: The present disclosure provides a coating method and a coating system. The coating method comprises: providing a substrate, and dropping a first liquid onto the substrate; dropping, onto the first liquid, a second liquid which is immiscible with the first liquid and has a density greater than that of the first liquid; and rotating the substrate, such that the first liquid is diffused on the surface of the substrate, and the second liquid is diffused on the surface of the first liquid.Type: GrantFiled: July 16, 2021Date of Patent: January 10, 2023Assignee: CHONGQING KONKA PHOTOELECTRIC TECHNOLOGY RESEARCH INSTITUTE CO., LTD.Inventor: Chaochao Xiong
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Patent number: 10815388Abstract: Curable compositions, such as by way of exposure to radiation in the electromagnetic spectrum, for use as a primer composition for injection molding applications, are provided.Type: GrantFiled: November 25, 2015Date of Patent: October 27, 2020Assignee: Henkel IP & Holding GmbHInventors: Mark M. Konarski, Nicholas Penrose, Darren Nolan, Brian Deegan
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Patent number: 10781341Abstract: This disclosure relates to a polyimide polymer that includes the reaction product of: (a) at least one diamine selected from the group consisting of a diamine of Structure (Ia) and a diamine of Structure (Ib), (b) at least one diamine of Structure (II), (c) at least one tetracarboxylic acid dianhydride, and (d) at least one compound containing a first functional group reactive with an amine or an anhydride and at least a second functional group selected from the group consisting of a substituted or unsubstituted linear alkenyl group and a substituted or unsubstituted linear alkynyl group. Each variable in the above formulas is defined in the specification.Type: GrantFiled: January 28, 2015Date of Patent: September 22, 2020Assignee: Fujifilm Electronic Materials U.S.A., Inc.Inventors: Sanjay Malik, William A. Reinerth, Binod B. De, Ognian Dimov
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Patent number: 10612148Abstract: Copper electroplating compositions which include a diimidazole compound enables the electroplating of copper having uniform morphology on substrates. The composition and methods of enable copper electroplating of photoresist defined features. Such features include pillars, bond pads and line space features.Type: GrantFiled: October 22, 2018Date of Patent: April 7, 2020Assignee: Rohm and Haas Electronic Materials LLCInventor: Ravi Pokhrel
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Patent number: 9809751Abstract: A liquid crystal photo-alignment agent includes a polyimide copolymer including a first structure unit represented by the described Chemical Formula 1 and a second structure unit represented by the described Chemical Formula 2, and, based on a 100 mole % sum total of the first structure unit and the second structure unit, the first structure unit is included in an amount of 70 to 95 mole % and the second structure unit is included in an amount of 5 to 30 mole %. A liquid crystal photo-alignment film may be manufactured using the same, and a liquid crystal display may include the liquid crystal photo-alignment film.Type: GrantFiled: January 15, 2016Date of Patent: November 7, 2017Assignee: Samsung Display Co., Ltd.Inventors: Suk Hoon Kang, Jin-Soo Jung, Jun Woo Lee, Jong Hwan Jeon, In Ok Kim, Baek Kyun Jeon
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Patent number: 9448476Abstract: A photoresist composition includes about 0.1 to about 30 parts by weight of a photo-initiator, about 1 to 50 parts by weight of a first acrylate monomer including at least five functional groups, about 1 to 50 parts by weight of a second acrylate monomer including at most four functional groups with respect to about 100 parts by weight of an acryl-copolymer.Type: GrantFiled: October 24, 2014Date of Patent: September 20, 2016Assignee: SAMSUNG DISPLAY CO., LTD.Inventors: Sung-Kyun Park, Jeong-Min Park, Jung-Soo Lee, Ji-Hyun Kim, Jun Chun, Ki-Hyun Cho, Hyoc-Min Youn, Tai-Hoon Yeo, Jin-Sun Kim, Byung-Uk Kim
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Patent number: 8429573Abstract: A method includes: generating electron beam exposure data, used for electron beam exposure, from design data of a semiconductor device; extracting differential information indicating a difference in shape between an electron beam exposure pattern formed on a substrate through electron beam exposure on the basis of the electron beam exposure data and a photoexposure pattern formed on the substrate through photoexposure on the basis of the design data of the semiconductor device; determining whether the size of the difference in shape between the electron beam exposure pattern and the photoexposure pattern falls within a predetermined reference value; acquiring shape changed exposure data by changing the shape of the pattern of the electron beam exposure data in accordance with the differential information and updating the electron beam exposure data; and repeating the differential extraction, the determination and the updating when the size of the difference falls outside the predetermined reference value.Type: GrantFiled: January 8, 2009Date of Patent: April 23, 2013Assignee: Fujitsu Semiconductor LimitedInventors: Kozo Ogino, Hiromi Hoshino
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Patent number: 6821692Abstract: The present invention relates to novel thin layers for microsystem techniques and microstructuring. It is an object of the invention to provide thin layers which can be manufactured under less problems and more economically than the previous conventional layers, and which permit the use of existing technologies for microstructuring. The object is realized in that the thin layer is formed of an enzymatically degradable biopolymer in a range of layer thicknesses of from 30 nm to 3 &mgr;m. Biopolymeric thin layers manufactured according to the invention permit their application, after a respective structurizing, as test assays or in setting up substance libraries.Type: GrantFiled: February 4, 1999Date of Patent: November 23, 2004Assignee: Clondiag Chip Technologies GmbHInventors: Eugen Ermantraut, Johann Michael Köhler, Torsten Schulz, Klaus Wohlfart, Stefan Wölfl
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Patent number: 6727034Abstract: The present invention is related to a photosensitive composition which comprises 70 to 99 weight % of a vinyl polymer (A) comprising recurring units derived from a monomer (a) of the following general formula (1) and 1 to 30 weight % of at least one photosensitive compound (B) selected from the group consisting of azide compounds and diazo compounds.Type: GrantFiled: May 14, 1999Date of Patent: April 27, 2004Assignee: Sanyo Chemical Industries, Ltd.Inventors: Naohito Ogiso, Tetsuya Watanabe, Tetsuya Yamada
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Patent number: 6444391Abstract: Photosensitive compositions prepared without use of a chromium compound. The compositions exhibit high resolution and satisfactory sensitivity, and do not cause environmental pollution. The photosensitive compositions contain a water-soluble azide compound which serves as a photocrosslinking agent and poly(N-vinylacetamide) that is photocrosslinkable in the presence of the water-soluble azide compound.Type: GrantFiled: January 2, 2001Date of Patent: September 3, 2002Assignees: Toyo Gosei Kogyo Co., Ltd., Showa Denko K.K.Inventors: Masaharu Watanabe, Noriaki Tochizawa
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Patent number: 6440632Abstract: A photosensitive resin composition comprises a base resin (e.g., novolak resins, polyvinylphenol-series polymers), a first photoactive ingredient (e.g., diazobenzoquinone derivatives, diazonaphthoquinone derivatives) and a second photoactive ingredient (e.g., mixtures with azide compounds) each having an absorption range at wavelength &lgr;1 or &lgr;2, the wavelengths thereof being different from each other. Between the first and second photoactive ingredients, at least one photoactive ingredient is substantially inert at the absorption wavelength of the other. After exposing the photosensitive resin composition to a light to form a pattern, the whole surface of the photosensitive layer is exposed to a light of the other wavelength to make the surface hardly soluble (in the case a positive pattern is formed) or readily soluble (in the case a negative pattern is formed) in a developer, and developed, thereby forming a pattern of high resolution.Type: GrantFiled: August 18, 1999Date of Patent: August 27, 2002Assignee: Kansai Research InstituteInventor: Tokugen Yasuda
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Patent number: 6368774Abstract: A radiation sensitive composition comprising (A), a mixture of an isoindolinone pigment and a yellow organic pigment, (B) an alkali-soluble resin, (C) a polyfunctional monomer and (D) a photopolymerization initiator. The composition is useful for production of an additive or subtractive color filter which is used in a reflection-type color liquid crystal display device.Type: GrantFiled: June 2, 2000Date of Patent: April 9, 2002Assignee: JSR CorporationInventors: Kouichi Sakurai, Hiroaki Nemoto, Atsushi Kumano
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Patent number: 6348298Abstract: A radiation sensitive composition comprising (A) a colorant containing a quinacridone pigment, a mixture of an isoindolinone pigment and a yellow organic pigment or a mixture of copper phthalocyanine blue and a green pigment, (B) an alkali-soluble resin, (C) a polyfunctional monomer and (D) a photopolymerization initiator. The composition is useful for production of an additive or subtractive color filter which is used in a reflection-type color liquid crystal display device.Type: GrantFiled: June 2, 2000Date of Patent: February 19, 2002Assignee: JSR CorporationInventors: Kouichi Sakurai, Hiroaki Nemoto, Atsushi Kumano
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Publication number: 20020012867Abstract: A photosensitive resin composition comprises a base resin (e.g., novolak resins, polyvinylphenol-series polymers), a first photoactive ingredient (e.g., diazobenzoquinone derivatives, diazonaphthoquinone derivatives) and a second photoactive ingredient (e.g., mixtures with azide compounds) each having an absorption range at wavelength &lgr;1 or &lgr;2, the wavelengths thereof being different from each other. Between the first and second photoactive ingredients, at least one photoactive ingredient is substantially inert at the absorption wavelength of the other. After exposing the photosensitive resin composition to a light to form a pattern, the whole surface of the photosensitive layer is exposed to a light of the other wavelength to make the surface hardly soluble (in the case a positive pattern is formed) or readily soluble (in the case a negative pattern is formed) in a developer, and developed, thereby forming a pattern of high resolution.Type: ApplicationFiled: August 18, 1999Publication date: January 31, 2002Inventor: TOKUGEN YASUDA
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Patent number: 6342330Abstract: Photosensitive compositions prepared without use of a chromium compound. The compositions exhibit high resolution and satisfactory sensitivity, and do not cause environmental pollution. The photosensitive compositions contain a water-soluble azide compound which serves as a photocrosslinking agent and poly(N-vinylacetamide) that is photocrosslinkable in the presence of the water-soluble azide compound.Type: GrantFiled: January 2, 2001Date of Patent: January 29, 2002Assignees: Toyo Gosei Kogyo Co., Ltd., Showa Denko K.K.Inventors: Masaharu Watanabe, Noriaki Tochizawa, Hirotaka Tagoshi, Tetsuhiko Yamaguchi
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Publication number: 20010012597Abstract: Photosensitive compositions prepared without use of a chromium compound. The compositions exhibit high resolution and satisfactory sensitivity, and do not cause environmental pollution. The photosensitive compositions contain a water-soluble azide compound which serves as a photocrosslinking agent and poly(N-vinylacetamide) that is photocrosslinkable in the presence of the water-soluble azide compound.Type: ApplicationFiled: January 2, 2001Publication date: August 9, 2001Inventors: Masaharu Watanabe, Noriaki Tochizawa, Hirotaka Tagoshi, Tetsuhiko Yamaguchi
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Patent number: 6270939Abstract: A radiation-sensitive resin composition comprising a solution of an alkali-soluble resin and a radiation-sensitive compound in a solvent comprising a monooxymonocarboxylic acid ester. This composition has a high storage stability (i.e., a very small amount of fine particles are formed during storage) and is suited for use as a resist for making integrated circuits.Type: GrantFiled: August 16, 2000Date of Patent: August 7, 2001Assignee: JSR CorporationInventors: Yoshihiro Hosaka, Ikuo Nozue, Masashige Takatori, Yoshiyuki Harita
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Publication number: 20010006752Abstract: A resist composition comprising, in a resist, an additive which has a melting point of 160° C. or above, contains no aromatic ring, has a molecular size of no greater than 50 Å and is soluble in the developing solution for the resist, at 1-50 parts by weight with respect to 100 parts by solid weight of the resist, as well as a pattern forming process employing it. It thereby becomes possible to obtain high-resolution resist patterns.Type: ApplicationFiled: April 9, 1999Publication date: July 5, 2001Applicant: FUJITSU LIMITEDInventors: KEIJI WATANABE, MIWA KOZAWA, EI YANO, TAKAHISA NAMIKI, KOJI NOZAKI, JUNICHI KON, EIICHI HOSHINO, MASAHIRO URAGUCHI, TOSHIKATSU MINAGAWA, YUICHI YAMAMOTO
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Publication number: 20010003633Abstract: Photosensitive compositions prepared without use of a chromium compound. The compositions exhibit high resolution and satisfactory sensitivity, and do not cause environmental pollution. The photosensitive compositions contain a water-soluble azide compound which serves as a photocrosslinking agent and poly(N-vinylacetamide) that is photocrosslinkable in the presence of the water-soluble azide compound.Type: ApplicationFiled: January 2, 2001Publication date: June 14, 2001Inventors: Masaharu Watanabe, Noriaki Tochizawa, Hirotaka Tagoshi, Tetsuhiko Yamaguchi
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Patent number: 6245478Abstract: A resist composition exhibiting an improved profile performance without impairing the resolution, the sensitivity, etc. which comprises a binder component; a radiation-sensitive component; and a succinimide compound represented by the following formula (I): wherein Q1 represents an alkyl group which may be optionally substituted with alkoxy, halogen or nitro, an alicyclic hydrocarbon residue, an aryl group, or an aralkyl group; and Q2, which may be the same as or different from Q1, represents hydrogen, an alkyl group which may be optionally substituted with alkoxy, halogen or nitro, an alicyclic hydrocarbon residue, an aryl group, or an aralkyl group.Type: GrantFiled: September 17, 1999Date of Patent: June 12, 2001Assignee: Sumitomo Chemical Company, LimitedInventors: Yasunori Uetani, Ichiki Takemoto
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Patent number: 6194126Abstract: There are disclosed a photosensitive resin composition which comprises (A) a polyamic acid having recurring units represented by the formula (I): wherein R1 represents and R2 represents a divalent organic group, and (B) an acryl compound having an amino group, and also a photosensitive resin composition for an i-line stepper which further comprises a photoinitiator in addition to the photosensitive resin composition.Type: GrantFiled: August 20, 1998Date of Patent: February 27, 2001Assignee: Hitachi Chemical Co., Ltd.Inventors: Hideo Hagiwara, Makoto Kaji, Masataka Nunomura
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Patent number: 6140007Abstract: Photosensitive compositions prepared without use of a chromium compound. The compositions exhibit high resolution and satisfactory sensitivity, and do not cause environmental pollution. The photosensitive compositions contain a water-soluble azide compound which serves as a photocrosslinking agent and poly(N-vinylformamide) that is photocrosslinkable in the presence of the water-soluble azide compound.Type: GrantFiled: May 12, 1999Date of Patent: October 31, 2000Assignee: Toyo Gosei Kogyo Co., Ltd.Inventors: Masaharu Watanabe, Noriaki Tochizawa, Yukari Imamura, Hideo Kikuchi
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Patent number: 6140019Abstract: A radiation sensitive composition comprising (A) a colorant containing a quinacridone pigment, a mixture of an isoindolinone pigment and a yellow organic pigment or a mixture of copper phthalocyanine blue and a green pigment, (B) an alkali-soluble resin, (C) a polyfunctional monomer and (D) a photopolymerization initiator. The composition is useful for production of an additive or subtractive color filter which is used in a reflection-type color liquid crystal display device.Type: GrantFiled: July 23, 1998Date of Patent: October 31, 2000Assignee: JSR CorporationInventors: Kouichi Sakurai, Hiroaki Nemoto, Atsushi Kumano
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Patent number: 6127074Abstract: The present invention relates to photoresist solution for phosphor slurry for use in the color cathode ray tube. The photoresist solution of the present invention comprises Diazo or Bisazide photosensitizer; polymer. which is mixed with said Diazo or Bisazide photosensitizer, obtained by polymerization of hydroxy ethyl acrylate base. The photoresist solution of the present invention improves the adhesive strength by using of the Diazo or Bisazide photosensitizer and the polymer, thus the green, blue and red phosphor screen being uniformly formed and the color residue being disappeared. Further, since the photosensitizer not containing heavy metal is used, it does not cause any environmental problem. Also, it can be stored for a long time by using the initiator without hydrochloric acid at the time of polymerization.Type: GrantFiled: December 11, 1998Date of Patent: October 3, 2000Assignee: Samsung Display Devices Co., Ltd.Inventors: Seung-Jun You, Eak-Cheol Eam, Young-Jong Kang, Chang-Wook Kim, Gi-Wook Kang, Eun-Ha Heo
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Patent number: 6087070Abstract: The invention relates to organic compounds having a molecular weight of less than 1000 comprising at least one structural unit of the formula (I) ##STR1## in which R.sub.1 is an aromatic or heteroaromatic radical which is capable of absorbing light in the wavelength range from 200 to 650 nm and in doing so brings about cleavage of the adjacent carbon-nitrogen bond.The compounds represent photoinitiators for base-catalyzable reactions. Other subjects of the invention are base-polymerizable or crosslinkable compositions comprising compounds having a structural unit of the formula I, a method of implementing photochemically induced, base-catalyzed reactions, and the use of the compounds as photoinitiators for base-catalyzed reactions.Type: GrantFiled: March 16, 1998Date of Patent: July 11, 2000Assignee: Ciba Specialty Chemicals CorporationInventors: Sean Colm Turner, Gisele Baudin
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Patent number: 6020093Abstract: The photosensitive compound of the present invention contains the following unit: ##STR1## and is particularly expressed by the following formula: ##STR2## Different photosensitive resin compositions can be prepared from this novel photosensitive resin compound, and the resulting photosensitive resin compositions do not raise the problem of environmental pollution, exhibit high resolution, possess a high level of sensitivity, and exhibit excellent adhesion with substrates, coating characteristics and storage stability.Type: GrantFiled: May 13, 1998Date of Patent: February 1, 2000Assignee: Toyo Gosei Kogyo, Ltd.Inventors: Toru Shibuya, Jian Rong Xie, Noriaki Tochizawa
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Patent number: 5942368Abstract: A composition dispersing a colorant is disclosed. The dispersion composition comprises a compound represented by formula; ##STR1## Detailed definition is disclosed in the specification.Type: GrantFiled: April 22, 1997Date of Patent: August 24, 1999Assignee: Konica CorporationInventors: Takeo Akiyama, Shinya Watanabe
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Patent number: 5925492Abstract: A radiation-sensitive resin composition comprising a solution of an alkali-soluble resin and a radiation-sensitive compound in a solvent comprising a monoxymono-carboxylic acid ester. This composition has a high storage stability (i.e., a very small amount of fine particles are formed during storage) and is suited for use as a resist for making integrated circuits.Type: GrantFiled: September 15, 1997Date of Patent: July 20, 1999Assignee: JSR CorporationInventors: Yoshihiro Hosaka, Ikuo Nozue, Masashige Takatori, Yoshiyuki Harita
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Patent number: 5885744Abstract: A photoresist composition containing a photo-curing polymer and a photosensitive agent, wherein the photosensitive agent comprises at least two compounds selected from the group consisting of 4,4'-diazido-2,2'-stilbenedisulfonate sodium salt, 4,4'-diazo-2,2'-dibenzalacetone disulfonate disodium salt, 2,5-bis(4-azido-2-sulfobenzylidene) cyclopentanone disodium salt and 4,4'-diazido-2,2'-dicinnamylideneacetone sulfonate salt. By performing a lithography process using the photoresist composition, the exposure time can be shortened, thereby improving the yield of products.Type: GrantFiled: July 14, 1997Date of Patent: March 23, 1999Assignee: Samsung Display Devices Co., Ltd.Inventors: Seung-joon Yoo, Ik-chul Lim, Chang-wook Kim, Ki-wook Kang
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Patent number: 5866296Abstract: A photosensitive resin composition includes a polymer compound having a component of Formula (I) and a sensitizer having a cationic group in the molecule: ##STR1## (wherein X denotes a cationic species, and n is 0, 1 or 2.) The photosensitive resin composition is high in sensitivity, good in storage stability, and easy to produce, and is suitable for use in a screen printing plate, formation of black matrix or phosphor pattern of a color cathode-ray tube, a CCD or LCD color filter, a printing color proof, and various etching resists.Type: GrantFiled: April 25, 1997Date of Patent: February 2, 1999Assignee: Toyo Gosei Co., Ltd.Inventors: Toru Shibuya, Noriaki Tochizawa, Mitsuharu Miyazaki, Hideo Kikuchi
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Patent number: 5856059Abstract: There are disclosed a photosensitive resin composition which comprises(A) a polyamic acid having recurring units represented by the formula (I): ##STR1## represents a divalent organic group, and (B) an acryl compound having an amino group, and also a photosensitive resin composition for an i-line stepper which further comprises a photoinitiator in addition to the photosensitive resin composition.Type: GrantFiled: June 17, 1996Date of Patent: January 5, 1999Assignee: Hitachi Chemical Co., Ltd.Inventors: Hideo Hagiwara, Makoto Kaji, Masataka Nunomura
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Patent number: 5853928Abstract: A method for electrophotographically forming a Braun tube's fluorescent layer coats conductive and photoconductive layers on the internal surface of a Braun tube's panel. The photoconductive layer is formed of a water soluble photoconductive liquid including a water soluble binder, allowing a part of the photoconductive layer to be selectively exposed to a visible ray. The photoresist of the above photoconductive liquid is substituted with dye, which can be processed through general exposure and solvent, allowing the fluorescent layer to be formed on a Braun tube under the same conditions as a typical Braun tube production process without darkroom processing.Type: GrantFiled: December 18, 1995Date of Patent: December 29, 1998Assignee: Samsung Display Devices Co., Ltd.Inventor: Min-Ho Kim
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Patent number: 5705309Abstract: An infrared imaging composition comprises three essential components: a photocrosslinkable polymeric binder having pendant photopolymerizable olefinic double bonds, a polyazide photoinitiator and an infrared absorbing compound. These compositions are useful in photosensitive elements such as lithographic printing plates that can be used to provide images using lasers, followed by development.Type: GrantFiled: September 24, 1996Date of Patent: January 6, 1998Assignee: Eastman Kodak CompanyInventors: Paul Richard West, Jeffery Allen Gurney
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Patent number: 5650261Abstract: A positive-acting photoresist composition which produces crosslinked images and processes for using the photoresist composition are disclosed. The photoresist composition is prepared from a mixture containing a film forming, polymer-containing, acid hardening resin system, an acid or acid generating material (preferably in the form of a thermal acid generator) for crosslinking the acid hardening resin system, and a photobase generating compound. The photoresist composition is applied as a film onto a substrate surface and selectively imagewise exposed through a photomask to actinic radiation. The actinic radiation causes the photobase generator to produce a base in the imagewise exposed portions of the photoresist film. The photochemically generated base neutralizes the acid in the imagewise exposed areas of the photoresist film.Type: GrantFiled: October 27, 1989Date of Patent: July 22, 1997Assignee: Rohm and Haas CompanyInventor: Mark Robert Winkle
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Patent number: 5641594Abstract: A colored, photosensitive resin composition of a pigment dispersing-type is disclosed.The colored, photosensitive resin composition is characterized by containing (a) a polymer having alcohlic or phenolic hydroxyl groups, (b) a compound capable of producing a nitrene when irradiated with an actinic radiation, (c) a pigment, and (d) a solvent. Preferably, the composition further contains (e) a heat crosslinking agent and/or (f) a compound having a polymerizable double bond in addition to the above ingredients.According to the present invention, the production of a color filter need not be performed in an inert gas atmosphere, does not require an oxygen barrier film and does not require heating during the period of from the exposure step to the development step. Thus, the use of the composition permits the color filter production steps to be made significantly simple so that the composition provides a great value in industrial utilization.Type: GrantFiled: August 25, 1995Date of Patent: June 24, 1997Assignee: Hoechst Japan LimitedInventors: Takanori Kudo, Yuko Nozaki, Kazuya Nagao, Yuki Nanjo, Hiroshi Okazaki, Yoshiaki Kinoshita, Seiya Masuda, Munirathna Padmanaban, Natsumi Suehiro
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Patent number: 5561026Abstract: A photosensitive material comprising a photosensitive-group-containing fullerene such as a photosensitive material which is obtained by adding a photosensitive group to fullerene and/or a photosensitive material which is obtained by combining the fullerene with a photosensitive agent is provided. The photosensitive material according to the present invention has excellent properties as a new resist which is a photosensitive material suitable as a photolithographic resist for the production of semiconductors utilizing such light source as ultraviolet light, deep ultraviolet light, X-ray or electron beam and which meets the requirements for realization of a higher level of resolution and sensitivity.Type: GrantFiled: June 21, 1993Date of Patent: October 1, 1996Assignee: Nippon Oil Co., Ltd.Inventor: Nobuo Aoki
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Patent number: 5518858Abstract: Photochromic compositions comprise a bacteriorhodopsin suspension, at least one organic nitrogen-containing compound and a binder. The composition may further include a detergent. Photochromic materials comprise a support and a photochromic film formed on the support from a photochromic composition as described.Type: GrantFiled: May 26, 1994Date of Patent: May 21, 1996Assignee: The United States of America as represented by the Secretary of CommerceInventors: Tatyana V. Dyukova, Nicolai N. Vsevolodov
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Patent number: 5486447Abstract: Cost-effective, negative resists having high thermal stability based on oligomeric and/or polymeric polybenzoxazole precursors are disclosed. Also disclosed are resist solutions having a high level of storage stability when they contain a photoactive component in the form of a bisazide and when the polybenzoxazole precursors are hydroxypolyamides having the following structure: ##STR1## where R, R*, R.sub.1, R.sub.1 * and R.sub.2 are aromatic groups, R.sub.3 is an aromatic group or a norbornene residue, and wherein n.sub.1, n.sub.2 and n.sub.3, are defined as follows:n.sub.1 =1 to 100, n.sub.2 and n.sub.3 =0 orn.sub.1 and n.sub.2 =1 to 100, n.sub.3 =0 orn.sub.2 =1 to 100, n.sub.1 and n.sub.3 =0 orn.sub.1, n.sub.2 and n.sub.3 =1 to 100 (with R.noteq.R* or R.sub.1 .noteq.R.sub.1 * or both) orn.sub.1 and n.sub.3 =1 to 100, n.sub.2 =0 (with R.noteq.R* or R.sub.1 .noteq.R.sub.1 * or both),on the condition that: n.sub.1 +n.sub.2 +n.sub.3 .gtoreq.3.Type: GrantFiled: October 27, 1994Date of Patent: January 23, 1996Assignee: Siemens AktiengesellschaftInventors: Albert Hammerschmidt, Eberhard Kuhn, Erwin Schmidt
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Patent number: 5472823Abstract: A photosensitive resin composition comprising, as its main ingredient, a poly(amic acid) resin constituted of a diamino compound represented by formula: ##STR1## and optionally used other diamino compound and a tetracarboxylic acid dianhydride as its constituent monomers and/or a poly(amic acid) ester resin obtained by esterifying said poly(amic acid) resin and/or a polyimide resin obtained by a dehydrating or alcohol-eliminating ring-closure reaction of said poly(amic acid) resin or poly(amic acid) ester resin has an excellent developability and a high film strength and can form a relief patter of low thermal expansion.Type: GrantFiled: January 15, 1993Date of Patent: December 5, 1995Assignee: Hitachi Chemical Co., Ltd.Inventors: Hideo Hagiwara, Makoto Kaji, Hiroshi Nishizawa, Kenji Suzuki, Yasunori Kojima
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Patent number: 5389491Abstract: A negative working resist composition comprising (a) an alkali-soluble resin, (b) an aromatic compound having at least two groups of the formula: --OCH.sub.2 OR.sup.1 wherein R.sup.1 is alkyl or aralkyl, (c) a photoacid generator, and (d) a solvent, can form fine patterns with high resolution when exposed to deep UV, KrF excimer laser light, etc. due to high light transmittance and high sensitivity.Type: GrantFiled: June 28, 1993Date of Patent: February 14, 1995Assignees: Matsushita Electric Industrial Co., Ltd., Wako Pure Chemical Industries, Ltd.Inventors: Yoshiyuki Tani, Masayuki Endo, Fumiyoshi Urano, Takanori Yasuda
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Patent number: 5368976Abstract: The present invention provides a pigment dispersed color-filter composition containing a binder polymer such as an alkali-soluble block copolymer; a radiation-sensitive compound; and a pigment. The pigment-dispersed color-filter composition which further contains an organic medium, or an organic medium and a carboxylic acid is also provided.Type: GrantFiled: March 24, 1993Date of Patent: November 29, 1994Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Yusuke Tajima, Nobuo Bessho, Fumitake Takinishi, Yasuaki Yokoyama, Hideaki Masuko
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Patent number: 5362598Abstract: A photoresist composition which comprises a compound of the general formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are the same or different and represent a hydrogen atom, a hydroxyl group, --OCOR.sub.4, --O--R.sub.5, --OSi(R.sub.6).sub.3, a halogen atom, an optionally substituted alkyl group, an optionally substituted alkenyl group, an optionally substituted phenyl group or an optionally substituted aralkyl group; R.sub.4, R.sub.5 and R.sub.6 represent an optionally substituted lower alkyl group or an optionally substituted phenyl group; X and Y are the same or different and represent --CN, --COOR.sub.7, --CONR.sub.8 R.sub.9, ##STR2## R.sub.7 represents an alkyl group; R.sub.8 and R.sub.9 are the same or different and represent a hydrogen atom, an optionally substituted alkyl or phenyl group; R.sub.Type: GrantFiled: October 6, 1993Date of Patent: November 8, 1994Assignee: Sumitomo Chemical Co., Ltd.Inventors: Naoki Takeyama, Yasunori Uetani, Hirotoshi Nakanishi, Ryotaro Hanawa
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Patent number: 5342727Abstract: A copolymer of (a) an unsubstituted 4-hydroxystyrene monomer and (b) a substituted 4-hydroxystyrene monomer of the formula ##STR1## wherein A, B, C, and D are independently H or C.sub.1 to C.sub.4 alkyl and wherein at least one of B and D is C.sub.1 to C.sub.4 alkyl; and wherein said copolymer has a molecular weight of from about 800 to about 100,000; and wherein the mol ratio of monomer (a) to monomer (b) ranges from about 3:1 to about 1:3.Type: GrantFiled: December 20, 1991Date of Patent: August 30, 1994Assignees: Hoechst Celanese Corp., IBM Corp.Inventors: Richard Vicari, Douglas J. Gordon, William D. Hinsberg, Dennis R. McKean, Carlton G. Willson, Ralph Dammel
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Patent number: 5275911Abstract: A radiation-sensitive composition comprising an admixture in a solvent of: at least one alkali-soluble binder resin, at least one photoactive compound and an effective sensitivity enhancing amount of at least one dimeric or trimeric unit formed by the condensation reaction of an aldehyde with sesamol; the amount of said binder resin being about 60 to 95% by weight, the amount of said photoactive component being about 5% to about 40% by weight, based on the total solids content of said radiation-sensitive composition.Type: GrantFiled: February 1, 1993Date of Patent: January 4, 1994Assignee: OCG Microelectronic Materials, Inc.Inventor: Medhat A. Toukhy
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Patent number: 5264318Abstract: A positive type photosensitive composition developable with water or warm water alone of water-soluble photocrosslinking agent, water-soluble resin and synthetic resin emulsion and further a coloring agent, if necessary.Type: GrantFiled: January 7, 1992Date of Patent: November 23, 1993Assignee: Sanyo-Kokusaku Pulp Co., Ltd.Inventors: Norio Yabe, Kuniaki Monden, Hisashi Mino
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Patent number: 5254429Abstract: The present invention provides photopolymerizable coating compositions comprising (a) a photosensitive compound selected from the group consisting of photoinitiators and negative-working photosensitive substances which are present in an amount effective to render the compositions sensitive to radiant energy, and (b) an ethylenically unsaturated, urethane-containing, self-crosslinkable grafted cellulose ester polymer; imaging elements for use in offset printing processes prepared therefrom; and processes employing said imaging elements.Type: GrantFiled: December 14, 1990Date of Patent: October 19, 1993Assignee: AnocoilInventors: Robert F. Gracia, Shek C. Hong, William J. Ryan
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Patent number: RE37033Abstract: The present invention provides a pigment dispersed color-filter composition containing a binder polymer such as an alkali-soluble block copolymer; a radiation-sensitive compound; and a pigment. The pigment-dispersed color-filter composition which further contains an organic medium, or an organic medium and a carboxylic acid is also provided.Type: GrantFiled: January 3, 1997Date of Patent: January 30, 2001Assignee: JSR CorporationInventors: Yusuke Tajima, Nobuo Bessho, Fumitaka Takinishi, Hideaki Masuko, Yasuaki Yokoyama