Silver Halide Colloid Tanning Process, Composition, Or Product Patents (Class 430/264)
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Patent number: 4800150Abstract: A super-high contrast negative type silver halide photographic material is disclosed, comprising a support having provided thereon at least one silver halide emulsion layer, said emulsion layer or layers or other hydrophilic colloidal layer or layers containing a hydrazine derivative, wherein said material further contains an acidic polymer incorporating not less than 20 mol % of a monomer unit containing an acid group and a hydrophobic polymer incorporating not more than 20 mol % of a monomer unit containing an acid group and having a glass transition temperature of not more than 50.degree. C. The material exhibits high contrast and high sensitivity without forming black spots even when processed with a stable developing solution.Type: GrantFiled: April 3, 1987Date of Patent: January 24, 1989Assignee: Fuji Photo Film Co., Ltd.Inventor: Kazunobu Katoh
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Patent number: 4798780Abstract: A silver halide photographic light sensitive emulsion containing a hydrazine of the general formulaR.sup.3 -NR.sup.4 -NR.sup.5 -G-X (I)in which:R.sup.3 represents an aryl group,one of R.sup.4 and R.sup.5 is a hydrogen and the other is selected from hydrogen, aryl sulphonyl and trifluoroacetyl,G represents carbonyl, sulphonyl, sulphoxy, phosphoryl or an N-substituted or unsubstituted imino group andX is a moiety such that at a pH in the range of 9.5 to 12.5 in the presence of an oxidized hydroquinone a cyclization reaction takes place cleaving the moiety -G-X from the remainder of the molecule and forming a cyclic structure comprising atoms of the moiety -G-X.Type: GrantFiled: June 29, 1987Date of Patent: January 17, 1989Assignee: Minnesota Mining and Manufacturing CompanyInventors: Kevin P. Hall, Andrew W. Mott
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Patent number: 4797343Abstract: A light-sensitive material comprising a light-sensitive layer which contains silver halide, a reducing agent and a polymerizable compound and a layer containing a base or base precursor, both of which are provided on the same side of a support. A barrier layer which keeps the base or base precursor from the light-sensitive layer and, when heated, allows transmission of the base or base precursor therethrough can be provided between the light-sensitive layer and the layer containing a base or base precursor.Type: GrantFiled: April 27, 1987Date of Patent: January 10, 1989Assignee: Fuji Photo Film Co., Ltd.Inventor: Taku Nakamura
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Silver halide photographic material and very high contrast negative image-forming process using same
Patent number: 4789618Abstract: A silver halide photographic material having on a support at least one silver halide emulsion layer is disclosed, wherein the silver halide emulsion layer comprises a silver halide emulsion containing an oxidizing agent added thereto before chemical ripening of the emulsion, and the silver halide emulsion or a hydrophilic colloid layer contains a hydrazine derivative.Type: GrantFiled: May 7, 1986Date of Patent: December 6, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuaki Inoue, Senzo Sasaoka, Toshiro Takahashi -
Patent number: 4786587Abstract: A silver halide photographic material comprising at least one negative type silver halide emulsion layer coated on a support, said emulsion comprising two kinds of monodisperse emulsions each having a means grain sizes of not more than 0.5 micron and, differing in mean grain size from each other at least by 0.1 micron, and said photographic material further comprising a hydrazine derivative in at least one photographic layer, whereby negative images of high density and very high contrast can be obtained with a high photographic speed and without black spots.Type: GrantFiled: October 26, 1987Date of Patent: November 22, 1988Assignee: Fuji Photo Film Co., Ltd.Inventor: Ken-ichi Kuwabara
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Patent number: 4777113Abstract: A negative silver halide photographic material comprising a support having provided thereon at least one light-sensitive silver halide emulsion layer and further provided on the light-sensitive halide layer at least two light-insensitive hydrophilic colloidal layers, the uppermost layer of the light-insensitive hydrophilic colloidal layers containing colloidal silica and the emulsion layer or other hydrophilic colloidal layer containing a hydrazine derivative. The material exhibits super-high contrast and is less susceptible to scratch fog.Type: GrantFiled: May 28, 1987Date of Patent: October 11, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuaki Inoue, Senzo Sasaoka, Tomoo Murakami
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Patent number: 4777118Abstract: High contrast negative images are obtained by developing a silver halide photographic element, in the presence of a hydrazine compound, with an alkali aqueous developing solution which contains a combination of developing agent comprising hydroquinone or substituted hydroquinone and a superadditive developing agent and an antioxidant, wherein the developing solution has a pH lower than about 12 and wherein the silver halide photographic element comprises an emulsion layer including surface latent image negative type silver halide grains in reactive association with a contrast promoting agent, preferably a diarylcarbinol compound, more preferably a diarylmethanol compound in a quantity useful to increase contrast.Type: GrantFiled: February 4, 1987Date of Patent: October 11, 1988Assignee: Minnesota Mining and Manufacturing CompanyInventors: Jonathan P. Kitchin, Carlo Marchesano
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Patent number: 4772531Abstract: A light-sensitive material comprising a light-sensitive layer which contains silver halide, a reducing agent and a polymerizable compound provided on a support, characterized in that the reducing agent is a hydrazine derivative having the following formula (I) or (II): ##STR1## in which R.sup.1 is a monovalent group selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group and a heterocyclic group, each of which may have one or more substituent groups; each of R.sup.2 and R.sup.3 independently is an aryl group which may have one or more substituent groups, or R.sup.2 and R.sup.3 form, together with the neighboring carbon, a condensed aromatic ring; R.sup.Type: GrantFiled: March 9, 1987Date of Patent: September 20, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Jiro Tsukahara, Kozo Sato
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Patent number: 4767690Abstract: A light-sensitive material comprising a light-sensitive layer which contains silver halide grains, a reducing agent and a polymerizable compound provided on a support (the polymerizable compound is in the form of oil droplets which are dispersed in the light-sensitive layer and the oil droplets contain the silver halide grain), characterized in that the total amount of oil droplets containing at least five silver halide grains is not less than 50 weight % of the total amount of the oil droplets dispersed in the light-sensitive layer.Type: GrantFiled: July 8, 1987Date of Patent: August 30, 1988Assignee: Fuji Photo Film Co., Ltd.Inventor: Soichiro Yamamoto
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Patent number: 4767692Abstract: A novel silver halide photographic material is provided comprising a support and at least one silver halide photographic emulsion layer formed thereon and containing in said photographic emulsion layer or at least one hydrophilic colloid layer a compound represented by formula (I): ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents a hydrogen atom, an aliphatic residual group, an aromatic residual group, or a heterocyclic residual group; R.sup.3 represents a hydrogen atom or an aliphatic residual group; L.sub.1 represents a divalent aliphatic group, a divalent aromatic group, or a divalent heterocyclic group; L.sub.2 represents --O--, --CONR--, --NRCO--, --SO.sub.2 NR--, --NRSO.sub.2 --, --OCO--, --COO--, --S--, --NR--, --CO--, --SO--, --SO.sub.2 --, --OCOO--, --NRCONR'--, --NRCOO--, --OCONR--, or --NRSO.sub.Type: GrantFiled: January 5, 1987Date of Patent: August 30, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshio Inagaki, Morio Yagihara, Shigeo Hirano
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Patent number: 4762769Abstract: A silver halide photographic material which has at least one silver halide emulsion layer comprising silver chloride or silver chlorobromide grains which has a bromide content of 5 mol % or less, and containing a rhodium salt in an amount of from 1.times.10.sup.-6 to 5.times.10.sup.-4 mole per mole of silver in said layer, and contains both a hydrazine derivative and a dye having an absorption peak in the wavelength region of from 400 nm to 550 nm in at least one of said emulsion layer another hydrophilic colloid layer, to thereby control the ratio of sensitivity at 360 nm to sensitivity at 400 nm (S.sub.360 /S.sub.400 ratio) to not less than 30, thereby achieving ultra-high contrast, high sensitivity, and a satisfactory aptitude for safelight.Type: GrantFiled: September 22, 1986Date of Patent: August 9, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiro Takahashi, Ken-ichi Kuwabara, Masahiro Okada
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Patent number: 4761362Abstract: An image forming process capable of providing photographic images having extremely high contrast and high resolution for use in photoengraving is disclosed, which comprises processing an image-wise exposed silver halide light-sensitive material having at least two silver halide emulsion layers on a support, one of said emulsion layers providing a contrasty gradation and the other of said emulsion layers providing a soft tone gradation, with a hydrazine contrast development system, a tetrazolium contrast development system or a lith development system, wherein the gamma (.gamma.) value of the portion having a density (D) from 0.3 to 1.5 on the characteristic curve obtained is less than 10 and the gamma (.gamma.) value of the portion having a density (D) from 1.5 to 3.0 is at least 10.Type: GrantFiled: December 29, 1986Date of Patent: August 2, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Senzo Sasaoka, Shigenori Moriuchi, Kimitaka Kameoka, Kazunobu Katoh, Yoshio Inagaki
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Patent number: 4761360Abstract: A light-sensitive material comprising a light-sensitive layer which contains silver halide, a reducing agent and a polymerizable compound provided on a support, characterized in that the light-sensitive layer further contains a silver diazotate having the following formula:Ar--N.dbd.N--O--Ag(L).sub.nin which Ar is an aryl group or a heterocyclic group, each of which may have one or more substituent groups; L is a ligand; and n is 0, 1 or 2. Image-forming methods utilizing the light-sensitive materials are also disclosed.Type: GrantFiled: February 24, 1987Date of Patent: August 2, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Sato, Soichiro Yamamoto
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Photographic silver halide developer compositions and process for forming photographic silver images
Patent number: 4756997Abstract: An aqueous alkaline photographic silver halide developer composition comprising a dihydroxy benzene developing agent, an auxiliary superadditive developing agent, an antifogging agent, an antioxidant and a buffering agent, characterized by the fact that the composition further comprises a stabilizing amount of an .alpha.-ketocarboxylic acid.The developer composition has a better resistance against air oxidation and can be left in continuous transport automatic processors for several days without undergoing any substantial decrease of its developing properties.The developer composition is particularly useful in a process for the formation of a high contrast silver image by developing silver halide photographic elements including at least a negative acting surface latent image type silver halide emulsion in the presence of a hydrazine compound, preferably in the additional presence of an effective amount of a contrast promoting agent.Type: GrantFiled: July 21, 1987Date of Patent: July 12, 1988Assignee: Minnesota Mining and Manufacturing CompanyInventor: Carlo Marchesano -
Patent number: 4755448Abstract: A negative type silver halide photographic material and a method for forming a super high contrast negative image using the photographic material are disclosed. The photographic material comprises a support, at least one silver halide emulsion layer on the support, and at least one light-insensitive colloid layer on the support, said emulsion layer or light-insensitive hydrophilic colloid layer containing a hydrazine derivative, and further contains the tertiary amine salt of an acid polymer.Type: GrantFiled: September 4, 1986Date of Patent: July 5, 1988Assignee: Fuji Photo Film Co., Ltd.Inventor: Kazunobu Katoh
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Patent number: 4755449Abstract: A negative type silver halide photographic material and a method for processing the photographic material to form a super high contrast negative image are disclosed. The photographic material comprises a support and at least one emulsion layer on the support, said emulsion layer comprising silver halide grains comprising a core of silver halide containing silver iodide and a shell covering the core, said shell consisting essentially of silver bromide, silver chloride, or silver chlorobromide and having a thickness of from 0.01 to 0.08 .mu.m, wherein the emulsion layer or a hydrophilic colloid layer other than the emulsion layer of the photograpic material contains a hydrazine derivative.Type: GrantFiled: September 4, 1986Date of Patent: July 5, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuaki Inoue, Senzo Sasaoka
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Patent number: 4746593Abstract: A negative-acting photographic element comprising a support having coated thereon one or more layers of a radiation-sensitive silver halide emulsion, at least one of the layers containing a hydrazine compound in which the one or more radiation-sensitive silver halide layers contain a first silver halide emulsion having an average grain size of from 0.1 to 0.4 microns and a second silver halide emulsion of particles with an average grain volume of less than one half that of the particles of the first emulsion.Type: GrantFiled: July 2, 1986Date of Patent: May 24, 1988Assignee: Minnesota Mining and Manufacturing CompanyInventors: Jonathan P. Kitchin, Kevin P. Hall
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Patent number: 4746594Abstract: A silver halide photographic material for a photomechanical process is disclosed. The material comprises a support having provided thereon at least one light-sensitive silver halide emulsion layer and at least one light-insensitive upper layer disposed on the upper side of the emulsion layer. The light-sensitive upper layer has a greater melting time than the light-sensitive emulsion layer. The emulsion layer contains starch, modified starch and/or macromolecular polysaccharides produced from starch using a microbial fermentation process. The material has greatly improved reduction processability.Type: GrantFiled: March 2, 1987Date of Patent: May 24, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasuo Kasama, Inoue Nobuaki, Ken-ichi Kuwabara
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Patent number: 4737442Abstract: A silver halide photographic material for use in the field of graphic arts and a process for forming a high-contrast negative image using the same, wherein the silver halide emulsion layer or another layer of the silver halide photographic material provided on the support contains at least one compound represented by the formula (I) and at least one blocked development restrainer compound represented by the formula (II): ##STR1##Type: GrantFiled: April 18, 1986Date of Patent: April 12, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Morio Yagihara, Tetunori Matusita, Nobuaki Inoue
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Patent number: 4737452Abstract: A silver halide photographic material comprising a support having at least one silver halide emulsion layer containing substantially surface latent image type silver halide grains, said emulsion layer or at least one hydrophilic colloid layer adjacent to the emulsion layer containing a compound represented by general formula (III): ##STR1## wherein L.sub.2 represents --CONR--, --SO.sub.2 NR-- or --NRCONR' and Z, L.sub.1, m, Ro, R.sub.1 and M are as herein described. The silver halide photographic material is capable of having high contrast negative images, high sensitive negative images, and good dot images.Type: GrantFiled: November 12, 1986Date of Patent: April 12, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Kimitaka Kameoka, Nobuaki Inoue, Yoshio Inagaki, Hidetoshi Kobayashi, Toshiro Takahashi
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Patent number: 4737441Abstract: A photographic material for tanning development which comprises a photographic support base, at least one tannable binder material, at least one silver halide emulsion and at least one pigment, said material including a 3-pyrazolidone compound and at least two different 1,4-dihydroxybenzene compounds, the first of which is chosen within the group of those having a standard tanning development time (STDT) of one fourth to twice the hydroquinone STDT (STDTHy) and the second of which is chosen within the group of those having a STDT of one fourth to fifteen times the STDTHy.Most preferably, the above photographic material includes hydroquinone in addition to the 3-pyrazolidone compound and the two 1,4-dihydroxybenzene compounds, wherein the first 1,4-dihydroxybenzene compound, other than hydroquinone, is chosen within the group of those having a STDT of one fourth to twice the STDTHy and the second 1,4-dihydroxybenzene compound is chosen within the group of those having a STDT of two to fifteen times the STDTHy.Type: GrantFiled: May 23, 1986Date of Patent: April 12, 1988Assignee: Minnesota Mining and Manufacturing CompanyInventors: Marco Beruto, Antonio Luzzi, Piero Ramello
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Patent number: 4735887Abstract: Sharper edges are obtained in silver halide wash-off films for tanning development when from 5 to 60% of the unhardened gelatin binder in one or more layers is replaced with a synthetic amphoteric polymer consisting essentially of at least one of each of three constituents: (a) carboxylic acid, (b) alkyl primary amine, and (c) secondary and/or tertiary amine, the amphoteric polymer having an isoelectric point of from 4 to 8.Type: GrantFiled: June 27, 1986Date of Patent: April 5, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventors: Robert P. Foss, Daniel R. Fruge
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Patent number: 4729946Abstract: A silver halide photographic light-sensitive material is disclosed, comprising a monodisperse silver halide emulsion of 0.30 .mu.m or less in average silver halide grain size containing at least 75 mol % silver chloride and 2 mol % or less silver iodide, and having incorporated in said emulsion a dye represented by the formula (I) ##STR1## wherein Z represents atoms forming a thiazoline nucleus, a thiazole nucleus, or a benzothiazole nucleus,X represents an oxygen atom or a sulfur atom, andR.sub.1 and R.sub.2 each represents an unsubstituted or substituted aliphatic group or an unsubstituted or substituted aromatic group.Type: GrantFiled: November 19, 1986Date of Patent: March 8, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasuo Kasama, Kiyohiko Yamamuro
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Patent number: 4727017Abstract: Photographic element comprising a support and a silver halide emulsion layer comprising in said emulsion layer and/or in a water-permeable layer coated at the same side of the support as said emulsion layer a compound corresponding to the following general formula: ##STR1## wherein: each of R.sup.1, R.sup.2, and R.sup.3, which may be the same or different, can represent hydrogen, C.sub.1 -C.sub.8 alkyl, or Alk.sub.1 - X - Alk.sub.2 - Y -, wherein: Alk.sub.1 is C.sub.1 -C.sub.8 alkyl, which may be substituted, X is --O-- or --S--, Alk.sub.2 is C.sub.1 -C.sub.8 alkylene, which may be substituted, and Y is a single bond, --O--, --S--, --CONH--, --SO.sub.2 NH--, or --NHCONH--, R.sup.3 can alternatively represent C.sub.1 -C.sub.8 alkyl-thio, the C.sub.1 -C.sub.8 alkyl group of which can be substituted, at least one of R.sup.1, R.sup.2, and R.sup.3, however, being other than hydrogen and other than C.sub.1 -C.sub.8 alkyl.The invention disclosed includes compounds per se, which correspond to said general formula.Type: GrantFiled: January 29, 1986Date of Patent: February 23, 1988Assignee: Agfa-Gevaert, N.V.Inventors: Robert J. Pollet, Antoon L. Vandenberghe, Hendrik E. Kokelenberg, Piet Kok
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Patent number: 4725533Abstract: A silver halide photographic material forming a wash-off relief image comprising a support having provided thereon a layer containing a tanning developing agent such as catechol, hydroquinone or pyrogallol, emulsified and dispersed in a high boiling point solvent such as butyl phthalate, butyl benzoate or tricreryl phosphate, and a layer containing a silver halide direct reversal emulsion.Type: GrantFiled: February 25, 1986Date of Patent: February 16, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Yutaka Oka, Khotarou Endou
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Patent number: 4724196Abstract: A lith-type silver halide photographic material comprising a tetrahydro-1,3,5-triazine-2-thione derivative and a polyalkylene oxide derivative.Type: GrantFiled: March 2, 1987Date of Patent: February 9, 1988Inventors: Tadao Shoji, Yonosuke Tsuka, Naoki Obi, Yasuhiko Kojima, Yasuo Shigemitsu
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Patent number: 4722884Abstract: A negative silver halide photographic light-sensitive material is provided, having a silver halide emulsion layer, which layer comprises silver haloiodide grains prepared in the presence of an iridium salt in an amount of 1.times.10.sup.-8 to 1.times.10.sup.-5 mole per one mole of silver, wherein the silver iodide content in the surface part of said grain is larger than the average silver iodide content in said grain, and additionally containing in said emulsion layer or in some other hydrophilic colloid layer, a compound of formula (I):R.sub.1 --NHNH--CHO (I)wherein R.sub.1 represents an aliphatic group or an aromatic group. Said photographic light-sensitive material is, after being exposed imagewise, developed with a developer containing 0.15 mole/l or more sulfite ion and having a pH value of 9.5-12.3, to form negative images having ultra-high contrast.Type: GrantFiled: July 23, 1985Date of Patent: February 2, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuaki Inoue, Senzo Sasaoka, Kenichi Kuwabara, Kimitaka Kameoka
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Patent number: 4705738Abstract: In a silver halide photographic material for tanning development, comprising a support base coated with a substantially unhardened hydrophilic binder layer including a light-sensitive silver halide emulsion reactively associated with a tanning developer and a dispersion of colloidal silver, the tendency of the hydrophilic binder to become water-insoluble during storage can be prevented by adjusting the pAg of the colloidal silver dispersion to values in the range from 6.5 to 9.5 with a 1-phenyl-5-mercaptotetrazole compound before coating.Type: GrantFiled: March 11, 1986Date of Patent: November 10, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventor: Luciano Balestra
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Patent number: 4699868Abstract: An alkaline aqueous tanning developing solution for photographic image development comprising at least one hydroxylamine derivative. Preferred formulations may also contain at least one water-miscible polyhydroxy aliphatic organic solvent and/or a developing agent which comprises a polyhydroxybenzene compound having at least two hydroxy groups and at least one electron withdrawing and good leaving group suitable for nucleophilic addition.Type: GrantFiled: August 18, 1986Date of Patent: October 13, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventor: Gebran J. Sabongi
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Patent number: 4699873Abstract: A negative silver halide photographic light-sensitive material comprising a support having provided thereon at least one silver halide emulsion layer is disclosed. At least one of the silver halide emulsion layers or another hydrophilic colloidal layer of the material contains a hydrazine derivative and a compound represented by the formula:R.sub.1 --S--S--R.sub.2wherein R.sub.1 and R.sub.2, which may be the same or different, each represents an aliphatic group, an aromatic group or a heterocyclic group, or when R.sub.1 and R.sub.2 are both aliphatic groups they may together form a ring. The material can rapidly form a superhigh contrast image using a stable processing solution.Type: GrantFiled: January 29, 1986Date of Patent: October 13, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiro Takahashi, Shigeo Hirano
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Patent number: 4693956Abstract: A process is disclosed for forming a high-contrast photographic image by developing a silver halide photographic element, including at least a silver halide emulsion layer, with an aqueous alkaline developing solution containing a dihydroxybenzene developing agent, a superadditive developing agent and an antioxidant at a pH of less than 12 in the presence of a hydrazine compound, an organic antifogging and contrast promoting agent selected within the class including a benzotriazole compound and a benzimidazole compound and a non polymeric hydroxymethylidyne group containing compound of formula: ##STR1## wherein R.sub.1 and R.sub.2 each independently represent a hydrogen atom, an aliphatic group, an aromatic group, a heterocyclic group, or R.sub.1 and R.sub.2 together complete a non aromatic cyclic group.Type: GrantFiled: November 15, 1985Date of Patent: September 15, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventor: Carlo Marchesano
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Patent number: 4686167Abstract: Disclosed are novel compounds of the formula: ##STR1## wherein: X=--NR.sub.5 R.sub.6, or --OR.sub.7 ;R.sub.1 and R.sub.2 are independently hydrogen, substituted or unsubstituted alkyl, haloalkyl, hydroxyalkyl alkoxyalkyl, alkylaminoalkyl or arylalkyl having up to 18 carbons; cycloalkyl; phenyl or naphthyl; alkylphenyl, cyanophenyl, halophenyl or alkoxyphenyl substituents.R.sub.3 is hydrogen, benzyl, alkoxybenzyl, halobenzyl or alkylbenzyl, provided that if neither R.sub.1 nor R.sub.2 is hydrogen, then R.sub.3 is hydrogen.R.sub.4 is a divalent aromatic group which is substituted or unsubstituted.R.sub.5, R.sub.6, and R.sub.7 are independently hydrogen, alkyl, hydroxyalkyl, haloalkyl, alkoxyalkyl, alkylaminoalkyl, acylaminoalkyl, aminoalkyl or phenylalkyl having up to 12 carbons; a cycloalkyl substituent; phenyl or naphthyl; an alkylphenyl, cyanophenyl, halophenyl or alkoxyphenyl substituent.Furthermore, either R.sub.1 and R.sub.3 or R.sub.1 and R.sub.Type: GrantFiled: September 26, 1985Date of Patent: August 11, 1987Assignee: Anitec Image CorporationInventors: Bruce M. Resnick, Allan J. Wexler
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Patent number: 4681836Abstract: A silver halide photographic material having at least one silver halide emulsion layer which contains silver halide grains containing from 1.times.10.sup.-8 to 8.times.10.sup.-6 mole of a rhodium salt per mole of silver, and containing in said emulsion layer or another hydrophilic colloidal layer a compound represented by formula (I)R.sup.1 -NHNH-G-R.sup.2 (I)wherein R.sup.1 represents an aliphatic group or an aromatic group; R.sup.2 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group; and G represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or an N-substituted or unsubstituted imino group; is exposed to imagewise pattern of light and then development-processed with a developer containing 0.15 mole/liter or more of sulfite ion and having a pH adjusted to from 9.5 to 12.Type: GrantFiled: November 20, 1986Date of Patent: July 21, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuaki Inoue, Yoshio Inagaki, Kimitaka Kameoka
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Patent number: 4659647Abstract: A photosensitive silver halide material for obtaining black and white half-tone dot or line images comprises a fine grain and high-chloride silver halide emulsion reactively associated with an aqueous latex of a hydrophobic vinyl addition polymer in combination with a stabilizer selected from the group consisting of 4-hydroxy-1,3,3a,7-tetrazaindenes, benzotriazoles and benzimidazoles. The silver halide emulsion has an average grain size lower than or equal to 0.20 micron with at least 60% of its molar halide content consisting of chloride ions.The material allows high-contrast and high resolving power images to be obtained.The material has a good developability in photographic processings and this reduces the development times and increases productivity.Type: GrantFiled: December 10, 1985Date of Patent: April 21, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventors: Alberto Vacca, Angelo Vallarino
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Patent number: 4649098Abstract: An image recording process and image recording material are described, said material comprising a support having provided thereon at least one light-sensitive layer containing in a binder a light-sensitive silver halide, a polymrizable vinyl monomer, a photopolymerization initiator and a reducing agent which has a function as a developing agent for silver halide and a function as a polymerization inhibitor for the polymerizable vinyl monomer, but loses the function as a polymerization inhibitor after development of silver halide, and said process comprising imagewise exposure, heating and uniform light exposure.Type: GrantFiled: September 23, 1985Date of Patent: March 10, 1987Assignee: Fuji Photo Film Co., Ltd.Inventor: Keiji Takeda
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Patent number: 4636457Abstract: Direct positive photographic elements are disclosed employing internal latent image silver halide emulsions associated with developer autoxidation promoter agents constituted by 5 or 6 membered nucleus-containing heterocyclic compounds comprising an azomethine group, whose methine group is substituted with a 5-amino-1,2,4-triazolyl group, and/or copper complex compounds thereof.Preferably said direct positive photographic elements are multi-layer elements comprising internal latent image type type silver halide emulsion layers sensitized to different regions of the visible light and associated with image-dye providing compounds (photographic color couplers).Type: GrantFiled: July 15, 1985Date of Patent: January 13, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventors: Luigi Valbusa, Enzo Coraluppi, Andrea Quaglia, Mario Tavella
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Patent number: 4634661Abstract: A negative working photographic element is disclosed capable of producing a high contrast silver image. The photographic element is comprised of surface latent image forming monodispersed silver halide grains having a mean diameter of less than 0.7 .mu.m, a contrast enhancing arylhydrazide, and, in an amount sufficient to stabilize sensitivity, a carboxyalkyl substituted 3H-thiazoline-2-thione.Type: GrantFiled: July 18, 1985Date of Patent: January 6, 1987Assignee: Eastman Kodak CompanyInventor: Anthony Cavallaro
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Patent number: 4606985Abstract: Lithographic printing plates which have on a support at least one hardened gelatin-containing layer which contains a photographic gelatin and a low molecular-weight gelatin are improved in printing endurance, e.g., resistances against ink-staining and blinding of image areas.Type: GrantFiled: August 27, 1982Date of Patent: August 19, 1986Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Yoshikazu Takaya, Yasuo Tsubai, Hiroshi Nishinoiri
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Patent number: 4588673Abstract: A retouchable mat film comprising a hydrophobic support which has formed thereon a mat layer containing silicon dioxide as a matting agent is disclosed. The mat layer further includes a mixture of poly(methyl methacrylate) or a copolymer containing at least 80 wt % of methyl methacrylate and a hydrophilic polymer as a binder. This mat film withstands several retouching operations in ink.Type: GrantFiled: February 22, 1985Date of Patent: May 13, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Shinzi Kataoka, Yukio Shinagawa, Shinji Sakaguchi
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Patent number: 4576894Abstract: A photoimaging system and method for photoimaging employing said photoimaging system, the latter comprising (i) a photosensitive element having a substrate coated with a photosensitive layer containing dispersed silver halide particles in operative association with a continuous film-forming phase of polymeric coupler, the coupler characterized by the ability to couple with the developing agent of component (ii) to become insoluble in aqueous media; and (ii) an oxidized hydroquinone or aminophenol-type developing agent.Type: GrantFiled: September 24, 1984Date of Patent: March 18, 1986Assignee: E. I. Du Pont De Nemours and CompanyInventor: Dennis S. Donald
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Patent number: 4560637Abstract: A process for forming a polymeric image in a silver halide sensor type polymerizable light-sensitive material having a silver halide photographic emulsion layer is disclosed. The process is comprised of reducing a development nucleus-containing silver halide using at least one phenol compound and at least one hydrazine compound in the presence of at least one non-gaseous ethylenically unsaturated compound capable of undergoing addition polymerization to selectively polymerize the non-gaseous ethylenically unsaturated compound in an area where the development nucleus-containing silver halide is present. The phenol compound is represented by the following general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.2 ', R.sub.3 and R.sub.3 ' are defined within the disclosure. The hydrazine compound is represented by the following general formula (II): ##STR2## wherein R.sub.4, R.sub.5 and R.sub.6 are defined within the disclosure.Type: GrantFiled: December 21, 1982Date of Patent: December 24, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Minoru Maeda, Noriyuki Inoue, Mikio Totsuka
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Patent number: 4560638Abstract: An unballasted arylhydrazide is disclosed the aryl moiety of which is substituted with a group of the formula ##STR1## where one of X and X' represents --NH--, the other represents a divalent chalcogen, and R represents an aliphatic or aromatic residue. The arylhydrazides, when applied to halftone imaging in conjunction with silver halide emulsions, photographic elements, and imaging processes, produce images of improved dot quality and low levels of pepper fog.Type: GrantFiled: October 9, 1984Date of Patent: December 24, 1985Assignee: Eastman Kodak CompanyInventors: James C. Loblaw, Barbara B. Lussier
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Patent number: 4551412Abstract: A silver halide photographic light-sensitive material for photo-mechanical process comprising a support having thereon at least one light-sensitive silver halide emulsion layer and at least one light-insensitive upper layer which is positioned above the light-sensitive silver halide emulsion layer, wherein at least one of the light-insensitive upper layers has a melting time longer than a melting time of the light-sensitive silver halide emulsion layer and the light-insensitive upper layer contains a polymer latex.The silver halide photographic light-sensitive material has excellent aptitude for reduction treatment without increasing the amount of silver per unit area. The occurrence of reticulation is prevented with the silver halide photographic light-sensitive material.Type: GrantFiled: August 17, 1983Date of Patent: November 5, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Masashi Ogawa, Taku Nakamura, Yukihide Urata, Shingo Yamauchi
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Patent number: 4544620Abstract: A photographic element for use in a method of multicolor image formation by tanning development is a layered structure comprising an optionally primed base support, a layer of colloidal silver, a layer of sensitized silver halide emulsion in gelatin free of hardener, and at least one colored pigment or dye dispersed therein which absorbs radiation.Type: GrantFiled: May 25, 1984Date of Patent: October 1, 1985Assignee: Minnesota Mining and Manufacturing CompanyInventor: Michael T. Macioch
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Patent number: 4510229Abstract: A lithographic photosensitive material which comprises a support having thereon at least one silver halide emulsion layer and that, contains as a lithographic development accelerating agent a compound represented by the following general formula (I) in its silver halide emulsion layer or another hydrophilic colloidal layer: ##STR1## wherein R.sub.1 to R.sub.5 may be the same or different, and they each represent hydrogen, a halogen atom, an alkyl group, an alkoxy group, an aryl group, ##STR2## (wherein R.sub.6 and R.sub.7 each represents hydrogen or an alkyl group, or they may combine with each other to form a 5- or 6-membered nitrogen containing saturated hetero ring), --NH--CO--R.sub.8 or --NHSO.sub.2 --R.sub.9 (wherein R.sub.8 and R.sub.9 each represents an alkyl group, an aryl group or an aralkyl group), or R.sub.3 and R.sub.4, or R.sub.4 and R.sub.5 may combine with each other to form a benzene ring and that, it is necessary to said compound that at least one of substituents R.sub.1, R.sub.3 and R.sub.Type: GrantFiled: March 19, 1984Date of Patent: April 9, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Yutaka Oka, Naomi Saeki, Yoshiharu Fuseya
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Patent number: 4504572Abstract: Silver halide photographic elements for tanning development including tanning developers, which can diffuse into the gelatin layer containing them, can be improved if they are associated with non-diffusing hydroquinones. In the case where such tanning developer is hydroquinone or a derivative thereof, said elements include such diffusing hydroquinone associated with a hydroquinone derivative non-diffusing in the gelatin layer containing it. Such non-diffusing hydroquinones preferably are hydroquinones substituted with aliphatic chains containing a total of at least twelve carbon atoms and, more preferably, are dispersed in the layer dissolved in a high-boiling organic solvent.Type: GrantFiled: August 4, 1983Date of Patent: March 12, 1985Assignee: Minnesota Mining and Manufacturing CompanyInventors: Marco Beruto, Antonio Luzzi, Piero Ramello
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Patent number: 4456676Abstract: Amine compounds or metal-ammine complexes incorporated into developer-incorporated wash-off films stabilize against premature gelatin hardening on aging. Preferred additives are two gelatin amino acids, lysine and arginine.Type: GrantFiled: June 10, 1983Date of Patent: June 26, 1984Assignee: E. I. Du Pont de Nemours and CompanyInventor: James M. Ciskowski
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Patent number: 4447522Abstract: A method of forming a photographic image which comprises development processing with an alkaline activator solution a silver halide photographic light-sensitive material comprising a support having thereon at least one surface latent image type silver halide emulsion layer, and containing in at least one layer selected from the silver halide emulsion layer and another hydrophilic colloid layer(1) a developing agents;(2) an acylhydrazine compound represented by formula (I):R.sup.1 NHNHCOR.sup.2 (I)wherein R.sup.1 represents an unsubstituted or substituted aryl group or alkyl group; and R.sup.2 represents a hydrogen atom, or an unsubstituted or substituted aryl group or alkyl group; and(3) at least one compound represented by formula (II): ##STR1## wherein each of W.sup.1 and W.sup.2 can represent a hydrogen atom or an aliphatic group or W.sup.1 and W.sup.2 are bonded each other to form a ring; W.sup.3 represents a divalent aliphatic group; Q.sup.Type: GrantFiled: April 18, 1983Date of Patent: May 8, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeo Hirano, Yoshihiro Takagi
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Patent number: 4444875Abstract: Herein are disclosed a light-sensitive silver halide photographic material comprising a support and, coated thereon, a hydrophilic colloid layer or layers including a silver halide emulsion layer, at least one of said hydrophilic colloid layer or layers containing a 1H-tetrazolium compound, and an image-forming method which comprises processing a light-sensitive silver halide photographic material mentioned above.The light-sensitive silver halide photographic material and the image-forming method according to the present invention can provide a high contrast silver image and a clear dot quality.Type: GrantFiled: March 25, 1983Date of Patent: April 24, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Toshiharu Nagashima, Takeshi Habu
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Patent number: 4444866Abstract: Photographic light-sensitive materials particularly useful in connection with instant photography are disclosed. The disclosed photographic materials include films for instant photography which have a reduced image appearing time, a high Dmax and low Dmin. The disclosed materials include force-oxidized carbon black in liquid phase, which has a dispersibility of at least 4 in water.Type: GrantFiled: March 3, 1983Date of Patent: April 24, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Takeo Sakai, Mitsugu Tanaka, Shigetoshi Ono, Seiji Suzuki, Hirohisa Suzuki