Silver Halide Colloid Tanning Process, Composition, Or Product Patents (Class 430/264)
  • Patent number: 5328801
    Abstract: A method for forming an image is disclosed, which comprises processing with a developer having a pH value of 9 to 12 and comprising 0.2 mol/liter or more of a sulfite an imagewise exposed silver halide photographic material comprising a compound represented by formula (I): ##STR1## wherein Het represents a group represented by formula (II) and the remaining terms are as defined in the specification: ##STR2## wherein the terms are as defined in the specification. In a preferred embodiment, the compound represented by formula (I) is a compound represented by formula (III): ##STR3## wherein the terms are as defined in the specification. The light-sensitive material may comprise a hydrazine derivative in addition to the compound represented by formula (I) or (III).
    Type: Grant
    Filed: March 6, 1992
    Date of Patent: July 12, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shoji Yasuda, Kazunobu Katoh, Hisashi Okamura
  • Patent number: 5326683
    Abstract: A silver halide photographic material comprising a support having thereon a previously fogged silver halide emulsion layer and a light-sensitive silver halide emulsion layer comprising at least one silver halide, wherein at least one of said previously fogged silver halide emulsion layer and a hydrophilic colloid layer adjacent thereto contains at least one hydrazine nucleating agent and at least one of said light-sensitive silver halide emulsion layer and a hydrophilic colloid layer adjacent thereto contains at least one redox compound capable of releasing a development restrainer when oxidized, and wherein said nucleating agent and said redox compound are contained in different layers.
    Type: Grant
    Filed: March 30, 1993
    Date of Patent: July 5, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kazunobu Katoh
  • Patent number: 5326667
    Abstract: The present invention provides 6 embodiments of a new image forming method. The image forming method uses a light-sensitive material and an image receiving material. The light-sensitive material comprises a support and a light-sensitive polymerizable layer provided thereon. Some embodiments of the light-sensitive material further have an adhesive layer. The light-sensitive polymerizable layer contains silver halide, a reducing agent and an ethylenically unsaturated polymerizable compound or/and a cross-linkable polymer. Some embodiments of the light-sensitive polymerizable layer further contain a colorant. The image forming method comprises an exposing step, a developing step, a removing step and a transferring step or a laminating step. Some embodiments of the image forming method further contains a peeling step or a toning step. The present invention is characterized in the combination of the removing step with the transferring step or the laminating step.
    Type: Grant
    Filed: May 6, 1992
    Date of Patent: July 5, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroaki Yokoya, Keiji Takeda, Osami Tanabe, Katsuji Kitatani
  • Patent number: 5316889
    Abstract: A silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein at least one of the silver halide emulsion layer and a hydrophilic colloid layer(s) adjacent thereto contains at least one hydrazine compound represented by the following general formula (I) and at least one compound selected from the group consisting of compounds represented by the following general formula (II) and (III): ##STR1## wherein R.sub.1 represents an aliphatic or aromatic group which has a substituent having a moiety of --O(CH.sub.2 CH.sub.2 O).sub.n --, --O--(CH.sub.2 CH(CH.sub.3)O).sub.n -- or --O--(CH.sub.2 CH(OH)CH.sub.2 O).sub.n -- (wherein n is an integer of not smaller than 3) as part of a substituent or having a moiety of a quaternary ammonium cation as part of a substituent group, G.sub.1 represents a bivalent bonding group consisting of at least one of --CO--, --COCO--, --CS--, --C(.dbd.NG.sub.2 R.sub.2)--, --SO--, --SO.sub.2 -- or --P(O)(G.sub.2 R.
    Type: Grant
    Filed: March 31, 1993
    Date of Patent: May 31, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Minoru Sakai
  • Patent number: 5316890
    Abstract: A silver halide light-sensitive material containing a compound selected from compounds represented by formula (I) or (II): ##STR1## wherein L.sup.1 represents --O--, --S--, --SO--, --SO.sub.2 --, --N(R.sup.4)--, --CONR.sup.4 --, --NR.sup.4 CO--, --OCONR.sup.4 --, --NR.sup.4 CONR.sup.4 --, --SO.sub.2 NR.sup.4 --, --NR.sup.4 SO.sub.2 -- or --NR.sup.4 SO.sub.2 NR.sup.4 --, each of which is bonded to the pyridine ring at the right hand side thereof; L.sup.2, L.sup.3, and L.sup.4 each represent a divalent aliphatic group or a divalent aromatic group; G represents --CO--, --SO.sub.2 --, --SO--, --COCO--, a thiocarbonyl group, an iminomethylene group or --P(O)(G.sup.1 R.sup.4)--; G.sup.1 represents a single bond, --O-- or --NR.sup.4 --; R.sup.1 represents an aliphatic group or an aromatic group; R.sup.2 represents a monovalent substituent; n.sup.1 represents 0 or an integer of from 1 to 4; R.sup.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: May 31, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Kazumi Nii, Kazunobu Katoh
  • Patent number: 5306598
    Abstract: A silver halide photographic material, suitable for exposure using Helium/Neon laser or light-emitting diode, contains silver bromide grains capable of forming a surface-latent image, a binder, a dot quality-promoting amount of at least one compound of the Formula I, and an effective amount for sensitizing said grains in the red region of the spectrum only one optical sensitizer compound of the Formula II: ##STR1## wherein all the symbols are as defined in the specification.
    Type: Grant
    Filed: November 30, 1992
    Date of Patent: April 26, 1994
    Assignee: International Paper Company
    Inventor: Clarence D. Kolosick
  • Patent number: 5298362
    Abstract: High contrast graphic arts photographic materials exhibiting improved accuracy in image reproduction are comprised of a support, a silver halide emulsion layer having a chloride content of at least 50 mole percent, and a non-electroconductive hydrophilic colloid layer containing both a vinyl polymer and a hydrophilic colloid interposed between the support and the silver halide emulsion layer. A hydrazine nucleating agent is incorporated in or adjacent to the silver halide emulsion layer and the photographic material preferably also contains an amino compound which functions as a booster.
    Type: Grant
    Filed: April 5, 1993
    Date of Patent: March 29, 1994
    Assignee: Eastman Kodak Company
    Inventors: David Beaumond, Philip J. Coldrick, Nicholas Pightling
  • Patent number: 5288590
    Abstract: A high contrast photographic image is formed by development of a photographic material with an amine-free developer having a low pH value. The photographic material has at least one silver halide emulsion on a support. The silver halide emulsion in the emulsion layer contains an iridium salt and/or a rhodium salt and comprises a gold-sensitized and sulfur-sensitized silver chlorobromide emulsion or silver chloroiodobromide emulsion having a silver chloride content of 50 mol% or more and a silver iodide content of 5 mol% or less. The emulsion layer contains a hydrazine compound represented by formula (I): ##STR1## wherein R.sub.1 represents an aliphatic group or an aromatic group, which contains a partial structure, --O(--CH.sub.2 CH.sub.2 O).sub.n --, --O(--CH.sub.2 CH(CH.sub.3)O).sub.n -- or --O(--CH.sub.2 CH(OH)CH.sub.2 O).sub.n --, wherein n is an integer of 3 or more, as a part of the R.sub.1 substituent, or contains a quaternary ammonium cation as a part of the R.sub.1 substituent; G.sub.
    Type: Grant
    Filed: August 25, 1992
    Date of Patent: February 22, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ken-ichi Kuwabara, Takashi Hoshimiya
  • Patent number: 5286598
    Abstract: Disclosed is a high-sensitive and super-high contrast silver halide photographic material suitable to use in photomechanical process. The material comprises a support having thereon having at least one light-sensitive silver halide emulsion layer and another hydrophilic colloid layer, wherein at least one of the emulsion layer or the other hydrophilic colloid layer contains a hydrazine derivative and a redox compound capable of releasing a development inhibitor by oxidation and further contains at least one hardening agent represented by formula (A): ##STR1## wherein R represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aralkyl group or a substituted or unsubstituted aryl group; and n represents 0 or 1.
    Type: Grant
    Filed: October 28, 1992
    Date of Patent: February 15, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Inoue, Minoru Sakai, Shigeru Ohno, Hisashi Okamura
  • Patent number: 5284732
    Abstract: A silver halide light-sensitive material containing a hydrazine compound represented by formula (I): ##STR1## wherein L.sup.1 represents a single bond, --O--, --S--, --NR.sup.6 --, --CO--, SO.sub.2 --, --P(O) (G.sup.2 R.sup.6)-- or a combination thereof; L.sup.2 represents --SO.sub.2 NR.sup.6 --, --NR.sup.6 SO.sub.2 NR.sup.6 --, --CONR.sup.6 --, --NR.sup.6 CONR.sup.6 -- or --G.sup.2 P(O) (G.sup.2 R.sup.6)NR.sup.6 --; G.sup.1 represents --CO--, --SO.sub.2 --, --SO--, --COCO--, a thiocarbonyl group, an iminomethylene group or --P(O) (G.sup.2 R.sup.6)--; G.sup.2 represents a single bond, --O-- or --NR.sup.6 --; R.sup.1 represents an aliphatic group or an aromatic group; R.sup.2, R.sup.3, and R.sup.4 each represent a divalent aliphatic group or a divalent aromatic group; R.sup.5 represents a hydrogen atom, an aliphatic group, an aromatic group, an alkoxy group, an aryloxy group or an amino group; R.sup.6 represents a hydrogen atom, an aliphatic group or an aromatic group; m represents 0 or 1; and X.sup.
    Type: Grant
    Filed: June 9, 1993
    Date of Patent: February 8, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazumi Nii, Toshihide Ezoe
  • Patent number: 5284733
    Abstract: A silver halide photographic material is disclosed. The photographic material comprises a support having coated thereon one or more hydrophilic colloidal layers, at least one of the hydrophilic colloidal layers being a negative working silver halide emulsion layer, wherein said silver halide emulsion layer or another hydrophilic colloidal layer contains a water-soluble polymer or copolymer having a quaternary ammonium salt in a repeating unit. The process for forming a high contrast negative image using the photographic material is also disclosed.
    Type: Grant
    Filed: October 1, 1991
    Date of Patent: February 8, 1994
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Yasuhiko Kojima, Naoki Obi, Yasuo Shigemitsu, Kiyoshi Suematsu
  • Patent number: 5284739
    Abstract: Photographic materials having incorporated sulphonyhdrazide color developing agents. Such photographic materials have at least two color-forming units, each of which has a silver halide emulsion layer and a photographic coupler. A ballasted heterocyclic sulphonhydrazide color developing agent is present in the material in droplets of a high boiling point solvent. A method of forming a photographic color image using such materials is also provided.
    Type: Grant
    Filed: November 10, 1992
    Date of Patent: February 8, 1994
    Assignee: Eastman Kodak Company
    Inventors: David Clarke, John D. Goddard, Paul L. R. Stanley, Nigel E. Milner
  • Patent number: 5283158
    Abstract: Disclosed is a silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, a hydrazine compound is contained in said silver emulsion layer or at least one of other layers, wherein said material contains at least one compound represented by Formula I or Formula II, ##STR1## wherein R.sub.1 and R.sub.2 each independently represent an alkyl group, an alkenyl group or an alkynyl group respectively; R.sub.1 and R.sub.2 may form a ring; R.sub.3 represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group; L.sub.1 represents a divalent linking group; X represents a --[S--L.sub.2 --Y--(L.sub.3)n]-- group or a [--(L.sub.3)n--Y--L.sub.2 --S--]-- group, L.sub.2 represents an alkylene group or an alkenylene group, Y represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, L.sub.3 represents ##STR2## wherein Z.sub.1, Z.sub.2 and Z.sub.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: February 1, 1994
    Assignee: Konica Corporation
    Inventors: Akira Onodera, Yasushi Usagawa
  • Patent number: 5283140
    Abstract: The invention provides a device for offset and similar printing from a continuous tone original to produce a halftone image on a photosensitive layer comprising means for screening the information via a first array of parallely extending lines of effective minimum optical density and a second array of parallely extending lines of effective maximum optical density, the arrays being interposed to form a composite array of substantially parallel, spaced-apart, alternating lines of effective maximum and minimum optical density, the lines delimiting therebetween zones of effective graduated optical density, the gradient inside each zone progressively varying from low optical density adjacent lines of the first array to high optical density adjacent lines of the second array, the spacing of lines of the first array being between about 100 and 400 lines per inch and wherein the resulting thickness of each reproduced line on a resulting developed photosensitive layer, generated by screening the information via the ar
    Type: Grant
    Filed: November 23, 1992
    Date of Patent: February 1, 1994
    Inventors: Yoel Netz, Arnold Hoffman
  • Patent number: 5283169
    Abstract: A silver halide photographic material is disclosed, comprising a support having thereon at least one silver halide emulsion layer and the other hydrophilic colloid layer, wherein the emulsion layer comprises a silver halide emulsion containing a compound having a nitrosyl ligand or a thionitrosyl ligand per mol of silver and a transition metal selected from the group consisting of the elements belonging to Groups V to X of the periodic table in an amount of 1.times.10.sup.-6 mol or more per mol of silver, and at least one of the silver halide emulsion layer and the other hydrophilic colloid layer contains at least one compound represented by formula (I), (II), (III), (IV) or (V). ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.
    Type: Grant
    Filed: December 6, 1991
    Date of Patent: February 1, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takahiro Goto
  • Patent number: 5279920
    Abstract: There is disclosed a silver halide photographic light-sensitive material containing a compound represented by the following formula. The photographic material provides sufficiently high contrast images using a stable developer having a low pH value. The photographic material also provides a direct-positive type photographic material improved in image quality and storage stability.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: January 18, 1994
    Assignee: Konica Corporation
    Inventors: Akira Onodera, Yasushi Usagawa
  • Patent number: 5279933
    Abstract: A high-contrast room-light-handleable black-and-white silver halide photographic element that is especially useful in the field of graphic arts is comprised of a support, an imaging layer containing doped silver halide grains with a mean grain size of less than 0.12 micrometers, and a print-out layer containing doped silver halide grains with a mean grain size in the range of from 0.14 to 0.4 micrometers. The element utilizes very slow speed emulsions which render it capable of being handled in room light and is able to print-out a visible image on normal exposure and develop to full density upon being processed in conventional developing solutions.
    Type: Grant
    Filed: February 3, 1993
    Date of Patent: January 18, 1994
    Assignee: Eastman Kodak Company
    Inventors: Anthony D. Gingello, Ronald J. Schmidt, Richard J. Kapusniak
  • Patent number: 5279919
    Abstract: A silver halide photographic material which comprises a compound represented by the following general formulae (Ia) or (Ib):R.sup.1 --L.sup.1 --R.sup.2 --L.sup.2 --R.sup.3 --NHNH--G.sup.1 --R.sup.4 (Ia)R.sup.6 --L.sup.3 --R.sup.2 --NHNH--G.sup.1 --R.sup.4 (Ib)wherein the terms are as defined in the specification. The photographic material is capable of producing ultrahigh contrast images and is useful in photomechanical processes. An advantage of the material in comparison to prior materials is that can be developed using a developer having a lower pH value.
    Type: Grant
    Filed: July 28, 1992
    Date of Patent: January 18, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Kazumi Nii, Kazunobu Katoh
  • Patent number: 5278025
    Abstract: A method for forming an image comprising the steps of: (a) imagewise exposing silver halide photographic materials; where said photographic material contains (1) a compound represented by formula (I) ##STR1## wherein R.sub.1 represents an aliphatic group or an aromatic group; R.sub.2 represents a hydrogen atom, an alkyl group, or an aryl group, an alkoxy group, an aryloxy group, an amino group, a carbamoyl group, or an oxycarbonyl group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, ##STR2## or an iminomethylene group; and A.sub.1 and A.sub.2 both represent a hydrogen atom, or one of A.sub.1 or A.sub.
    Type: Grant
    Filed: August 21, 1992
    Date of Patent: January 11, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Kazunobu Katoh, Tetsuro Kojima
  • Patent number: 5275915
    Abstract: A developer for light-sensitive material capable of processing in common a negative-working light-sensitive lithographic printing plate and a positive-working light-sensitive printing plate as well as a developing agent-containing type silver halide photographic material, is disclosed. The developer comprises an alkali agent, an anionic surface active agent, an antifoggant for a silver halide photographic material, and an alkylene oxide addition product (molecular weight of from 130 to 1200) of an aromatic amine or an aralkyl amine, and has pH of the range of from 11.5 to 13.5.
    Type: Grant
    Filed: June 2, 1992
    Date of Patent: January 4, 1994
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Yasuhiko Kojima, Yasuo Shigemitsu
  • Patent number: 5273859
    Abstract: A method for forming an image is disclosed. The method comprises the step of developing an imagewise exposed silver halide photographic material which contains a redox compound, with a developer which contains a silver halide developing agent and at least 0.1 mol/l of a sulfite and has a pH of 9 to 12, wherein the redox compound contains a redox group which is a hydrazine derivative which is capable of releasing a development inhibitor as a result of oxidation with the oxidized developer, and wherein after said oxidation, at least a portion of the development inhibitor is released into a developer where it reacts with a developer component and changes into a compound having little inhibiting effect. A silver halide photographic material used in that method is also disclosed.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: December 28, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunobu Katoh, Hisashi Okamura, Morio Yagihara
  • Patent number: 5272046
    Abstract: There is disclosed a method for rapidly processing a silver halide photographic material with an automatic processing machine for 20 to 60 seconds, the method being excellent fixability and drying characteristics. The fixing solution has:(a) a pH of 5.3 or more,(b) a sulfite ion concentration of 0.05 to 1.0 mole/liter, and(c) a content of an aluminium compound content of 0 to 0.01 mole/liter as a hardener. The coated amount of the gelatin contained in the protective layer provided on the side of the silver halide emulsion layers of the photographic material is 1.0 g/m.sup.2 or less.
    Type: Grant
    Filed: October 24, 1991
    Date of Patent: December 21, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Senzo Sasaoka
  • Patent number: 5272041
    Abstract: The present invention provides a method for obtaining a negative type lithographic printing plate comprising the steps of (i) image-wise exposing a diffusion transfer reversal imaging element comprising a direct positive silver halide emulsion that mainly forms an internal latent image and a layer containing physical development nuclei, (ii) fogging said image-wise exposed imaging element, (iii) developing said imaging element using a surface developer, (iv) transfering the undeveloped silver salts in the non-exposed areas to said layer containing physical development nuclei and (v) image-wise depositing said silver salts on said physical development nuclei in the presence of physical development restraining compound(s).
    Type: Grant
    Filed: October 10, 1991
    Date of Patent: December 21, 1993
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Ludo L. Van Rompuy
  • Patent number: 5264323
    Abstract: An improved photographic developing solution is free of dihydroxybenzene developing agents such as hydroquinone, has a pH in the range of from 9.5 to 11.5 and comprises (1) an ascorbic acid developing agent, (2) an auxiliary super-additive developing agent and (3) a carbonate buffering agent in a concentration of at least 0.5 molar. The developing solution is broadly useful in black-and-white development but is most advantageously employed in a process for forming a high-contrast image utilizing a silver halide photographic element comprising a hydrazine compound which functions as a nucleating agent and an amino compound which functions as an incorporated booster. The developing solution is ecologically advantageous, exhibits excellent stability with respect to seasoning effects, and provides high speed and good upper scale contrast combined with a low level of pepper fog and a moderate degree of chemical spread.
    Type: Grant
    Filed: December 14, 1992
    Date of Patent: November 23, 1993
    Assignee: Eastman Kodak Company
    Inventors: Michael D. Purol, Paul A. Zielinski, Donald L. Kerr
  • Patent number: 5262274
    Abstract: Disclosed is a novel silver halide photographic material which comprises at least one light-sensitive silver halide emulsion layer on a support. The light-sensitive layer or another hydrophilic colloidal layer contains a compound represented by the following general formula (1): ##STR1## wherein X represents a hydroxy, amino or sulfonamide group; A.sub.1 and A.sub.2 each represents a hydrogen atom, an alkylsulfonyl group, an arylsulfonyl group or an acyl group, with the proviso that at least one of A.sub.1 and A.sub.2 is a hydrogen atom; G.sub.1 represents --CO--, --COCO--, --CS--, --C(.dbd.NG.sub.2 R.sub.3)--, --SO--, --SO.sub.2 -- or --P(O)(G.sub.2 R.sub.3)--; G.sub.2 represents a mere bond, --O--, --S-- or --N(R.sub.3)--; R.sub.1 represents a hydrogen atom, an amino group, a sulfonamide group, a halogen atom, a hydroxyl group, an alkoxy group or an alkyl group; L represents a divalent linking group; n represents an integer 0 or 1; R.sub.
    Type: Grant
    Filed: April 30, 1992
    Date of Patent: November 16, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kazunobu Katoh
  • Patent number: 5258259
    Abstract: A method of forming an image comprising the steps of (a) imagewise exposing a silver halide photographic material to light substantially having no wavelengths of less than 370 nm, the silver halide photographic material comprising: (i) a support, (ii) at least one light-sensitive silver halide emulsion layer formed on the support, (iii) at least one other hydrophilic colloid layer, and (iv) a redox compound that releases a development inhibitor when oxidized in at least one of the at least one light-sensitive layer or the at least one hydrophilic colloid layer; and (b) processing the exposed silver halide material from step (a) to produce a .tau. value of at least 10.0. The redox compound is a compound represented by formula (I): ##STR1## wherein A.sub.1 and A.sub.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: November 2, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Inoue, Hisashi Okamura
  • Patent number: 5256519
    Abstract: Silver halide photographic elements which are capable of high contrast development and are especially useful in the field of graphic arts have incorporated therein a hydrazine compound which functions as a nucleator, an amino compound which functions as an incorporated booster, and a 2-substituted-4-hydroxy-1,3,3a,7-tetraazaindene which functions to inhibit pepper fog.
    Type: Grant
    Filed: March 2, 1992
    Date of Patent: October 26, 1993
    Assignee: Eastman Kodak Company
    Inventor: Anthony Adin
  • Patent number: 5254436
    Abstract: The present invention provides a method for image formation which is free from the problems such as uneven development and pepper fog and can give photographic characteristics of extremely high contrast negative tone using a stable developer and which comprises developing a silver halide photographic light-sensitive material in the presence of a compound represented by the following formula (I): ##STR1## wherein R.sub.1 represents an alkyl group of 1-8 carbon atoms or a cycloalkyl group having 4-8 carbon atoms in the ring, R.sub.2, R.sub.3 and R.sub.4 may be identical or different and each represents a hydrogen atom, an alkyl group, an aralkyl group, an aryl group or a heterocyclic group with a proviso that they cannot be simultaneously hydrogen atoms, R.sub.2 and R.sub.3 may link to each other to form a ring structure, and at least one hydroxy group is present in the substituents R.sub.2, R.sub.3 and R.sub.4.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: October 19, 1993
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Masao Koga, Minoru Ohashi
  • Patent number: 5252438
    Abstract: Disclosed is a silver halide photographic material containing a compound of a general formula (1) or (2):ED-(Time).sub.t -Y-L-Z (1)wherein ED represents a group that releases the moiety (Time).sub.t -Y-L-Z by reaction with an oxidation product of a developing agent; Time represents a divalent linking group; t represents 0 or 1; Y represents a divalent group comprising a hetero atom through which Y bonds to the moiety ED-(Time).sub.t ; L represents a divalent group which is capable of being cleaved by reaction with components in a developer; and Z represents a monovalent functional group that expresses a development inhibiting effect; ##STR1## wherein Time, t, L and Z have the same meanings as above; Y represents a divalent group comprising a hetero atom through which Y bonds to the moiety ##STR2## R.sub.1 represents an aliphatic group or an aromatic group; G.sub.1 represents is ##STR3## G.sub.2 represents a mere bond, --O--, --S-- or ##STR4## R.sub.2 has the same meaning as R.sub.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: October 12, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazumi Nii, Hisashi Okamura, Kazunobu Katoh
  • Patent number: 5252426
    Abstract: A novel group of fluoroacetylphenyl hydrazines useful in insuring rapid-access processing of lithographic film elements is described. These hydrazines not only will produce good dot quality under conditions of rapid-access processing, but can be used a lower pH than conventional, prior art elements and will produce lower fog.
    Type: Grant
    Filed: July 29, 1991
    Date of Patent: October 12, 1993
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Dominic M. Chan
  • Patent number: 5244772
    Abstract: The present invention features a negative-type, silver halide photographic emulsion containing hydrazides that has reduced scratch sensitivity (i.e., the emulsion will have a reduced tendency to develop black scratches on non-exposed areas). The emulsion will resist developing black scratches due to the introduction to the emulsion of hydroquinone and ascorbate. The stability of the emulsion is further enhanced by the addition of sodium formaldehyde bisulfite.
    Type: Grant
    Filed: December 6, 1991
    Date of Patent: September 14, 1993
    Assignee: Sun Chemical Corporation
    Inventors: Allan P. Piechowski, Penny M. Mullen, John F. Pilot
  • Patent number: 5244773
    Abstract: A silver halide photographic light sensitive material having high contrast photographic characteristics and excellent antistatic properties is provided by incorporating a hydrazine compound represented by formula 1 or 2 and a nucleation-promoting compound selected from the group consisting of amine compounds and quaternary onium salts; and by coating an electrically conductive layer on a support.
    Type: Grant
    Filed: January 24, 1992
    Date of Patent: September 14, 1993
    Assignee: Konica Corporation
    Inventors: Yasuhiko Muramatsu, Takeshi Sampei
  • Patent number: 5238801
    Abstract: A silver halide photographic material which has at least one silver halide emulsion layer on a support, wherein there is incorporated at least one electrically conductive layer of which the surface resistance is not more than 10.sup.12 .OMEGA. under conditions of 25.degree. C., 25% RH, which photographic material has been dried out at a relative humidity of not more than 50% when the water content is not more than 300 wt% with respect to the total dry weight of the binder included in the silver halide emulsion layers and other hydrophilic layers on the support, which was subjected, after drying, to a heat treatment of duration at least 6 hours at a temperature of at least 30.degree. C. in an atmosphere of absolute humidity not more than 0.01, and which has been stored under conditions of absolute humidity not more than 0.01.
    Type: Grant
    Filed: October 22, 1992
    Date of Patent: August 24, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kunio Ishigaki, Ken-ichi Kuwabara, Akira Hatakeyama
  • Patent number: 5238780
    Abstract: A method for forming images having a contrast of greater than G 8, comprising the step of developing an imagewise exposed silver halide photographic material with a developing solution having a pH of 11.2 or less. The silver halide photographic material comprises a support having thereon a hydrophilic colloid layer containing a redox compound which releases a development inhibitor upon oxidation and at least one photosensitive silver halide emulsion layer containing a hydrazine derivative. The at least one photosensitive silver halide emulsion layer containing a hydrazine derivative is different from the hydrophilic colloid layer containing a redox compound.
    Type: Grant
    Filed: September 10, 1991
    Date of Patent: August 24, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshihiro Takagi, Kazunobu Katoh
  • Patent number: 5238800
    Abstract: Disclosed is a silver halide photographic light-sensitive material that comprises a support having thereon at least one silver halide light-sensitive emulsion layer, wherein emulsion layer is spectrally sensitized; the back coating layer side of said light-sensitive material has a specific surface resistance of 1 10.sup.9 to 1 10.sup.12 .OMEGA.at 25.degree. C. and 25% RH; and said light-sensitive photographic material curls in the direction of said back coating layer side. The silver halide photographic light-sensitive material according to this invention does not undergo jamming even in electrostatic charge adsorption type cameras, and is improved in anti-static property.
    Type: Grant
    Filed: November 21, 1991
    Date of Patent: August 24, 1993
    Assignee: Konica Corporation
    Inventors: Yuji Hosoi, Junichi Fukawa, Akira Kobayashi
  • Patent number: 5238779
    Abstract: Silver halide photographic elements which are capable of high-contrast development and are especially useful in the field of graphic arts comprise surface latent image forming high-chloride silver halide grains and have incorporated therein a hydrazine compound which functions as a nucleator, an amino compound which functions as an incorporated booster, and a benzimidazolocarbocyanine sensitizing dye that provides enhanced photographic sensitivity yet leaves substantially no sensitizing dye stain after rapid access processing.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: August 24, 1993
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, Linda J. Knapp, Steven G. Link
  • Patent number: 5236807
    Abstract: A method for forming an image is disclosed, comprising imagewise exposing a negatively working silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer with light having a wavelength of from 460 to 600 nm and containing substantially no light having a wavelength of 360 nm or less, said emulsion layer containing at least one sensitizing dye having an absorption maximum (.lambda..sub.max) at a wavelength of form 450 nm to 580 nm, and said emulsion layer or other hydrophilic colloidal layer containing at least one hydrazine derivative. The method provides an image having excellent image quality either in enlargement or reduction work without causing reduction in sensitivity or inducing black pepper.
    Type: Grant
    Filed: March 27, 1992
    Date of Patent: August 17, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Inoue, Tetsuo Yoshida, Shuzo Suga, Hiroyuki Goto
  • Patent number: 5232818
    Abstract: Silver halide photographic elements which are capable of high contrast development and are especially useful in the field of graphic arts have incorporated therein a hydrazine compound which functions as a nucleator, an amino compound which functions as an incorporated booster, and a thioether compound which functions to inhibit pepper fog and restrain image spread.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: August 3, 1993
    Assignee: Eastman Kodak Company
    Inventors: Harold I. Machonkin, Donald L. Kerr
  • Patent number: 5230981
    Abstract: An image recording process is disclosed. The process comprises the steps of: imagewise exposing silver halide to light to form a latent image of the silver halide; developing the formed latent image of the silver halide with a reducing agent; and conducting substantially uniform light exposure in the presence of a photopolymerization initiator and an ethylenically unsaturated polymerizable compound to form a polymer image. According to the present invention, the reducing agent forms an oxidation product having a function as a polymerization inhibitor after the development. Thus a polymer image is formed within the area where the oxidation product of the reducing agent has not been formed. The reducing agent has the following formula [I]: ##STR1## in which R.sup.1 is an alkyl group, an aryl group or a heterocyclic group; R.sup.2 is an organic group which is attached to the benzene ring by a hetero-atom having a lone pair of electrons; R.sup.
    Type: Grant
    Filed: February 21, 1990
    Date of Patent: July 27, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoki Saito, Makoto Yamada
  • Patent number: 5230983
    Abstract: A negative-working type silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer containing a hydrazine derivative, wherein the emulsion layer or another hydrophilic colloidal layer provided on the support contains at least one redox compound capable of releasing a development inhibitor upon oxidation, and the silver halide emulsion comprises of monodispersed silver halide grains comprising 50 mol % or more of silver chloride.
    Type: Grant
    Filed: April 12, 1991
    Date of Patent: July 27, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Inoue Nobuaki, Sakai Minoru, Yasuda Shoji
  • Patent number: 5229248
    Abstract: A silver halide photographic light-sensitive material is disclosed, which is capable of forming an extremely high contrast image with high dot quality and is inhibited in formation of pepper spots. The light-sensitive material comprises a support, and provided thereon, a photographic layer including a silver halide emulsion layer, wherein the pH value of the surface of said photographic layer is 5.9 or more and said emulsion layer or a layer adjacent to said emulsion layer contains a specified hydrazine compound, and an amine compound or a quaternary onium compound.
    Type: Grant
    Filed: August 13, 1991
    Date of Patent: July 20, 1993
    Assignee: Konica Corporation
    Inventors: Takeshi Sanpei, Kenji Goto
  • Patent number: 5229249
    Abstract: A silver halide photographic material comprising a support, having thereon one or more hydrophilic colloid layers, wherein at least one of the hydrophilic colloid layers is a silver halide emulsion layer, and wherein the silver halide emulsion layer or another hydrophilic colloid layer contains a compound represented by general formula (I):Y--[(X).sub.n --A.sub.0 --B.sub.0 ].sub.m (I)wherein Y represents a group which is adsorbed on silver halide, X represents a divalent group comprising an atom or group of atoms selected from among a hydrogen atom, a carbon atom, a nitrogen atom, an oxygen atom and a sulfur atom, A.sub.0 represents a divalent linking group which has at least two alkyleneoxy units, B.sub.0 represents an amino group, an ammonium group or a nitrogen containing heterocyclic group, m represents 1, 2 or 3, and n represents 0 or 1, as well as a method for processing a silver halide photographic material in the presence of a compound according to general formula (I).
    Type: Grant
    Filed: September 4, 1991
    Date of Patent: July 20, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunobu Katoh, Tetsuro Kojima
  • Patent number: 5227278
    Abstract: A positive-working, low silver containing, wash-out element comprises a support, a fogged silver halide emulsion layer optionally containing a colorant, a photopolymer layer coated contiguous to silver halide layer and an abrasion layer containing a conventional, wash-out developing agent coated over the photopolymer layer. A process of making a positive image comprises image-wise exposing the above element to actinic radiation, immersing the element in an aqueous alkaline medium, and washing the element with water.
    Type: Grant
    Filed: February 27, 1992
    Date of Patent: July 13, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Robert P. Held
  • Patent number: 5221593
    Abstract: The improved silver halide photographic material contains a novel nucleating compound that is useful either as a contrast increasing agent in light-sensitive material for use in photochemical processes or as a foggant in direct positive light-sensitive materials.
    Type: Grant
    Filed: March 7, 1991
    Date of Patent: June 22, 1993
    Assignee: Konica Corporation
    Inventors: Akira Onodera, Yasushi Usagawa
  • Patent number: 5217842
    Abstract: A process of forming superhigh-contrast negative images is disclosed. The process comprises the steps of imagewise exposing a substantially surface latent image-type silver halide photographic material which is spectrally sensitized with a sensitizing dye and then developing said photographic material with a developer, wherein said photographic material contains a heterocyclic thione compound and said developer comprises (a) an aminophenol derivative developing agent, (b) a reductone compound, (c) a quaternary ammonium salt, and (d) a compound represented by formula (I): ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3, which may be the same or different, each represents a hydrogen atom, a nitro group, a halogen atom, or a cyano group, and wherein said development processing is carried out in the existence of at least one kind of a polyalkylene oxide or a derivative thereof. The process provides negative images of superhigh contrast having gamma over 10 substantially free from appearance of pepper.
    Type: Grant
    Filed: September 18, 1991
    Date of Patent: June 8, 1993
    Assignee: Dainippon Ink and Chemical, Inc.
    Inventors: Yasuhiko Kojima, Naoki Obi, Yasuo Shigemitsu
  • Patent number: 5213944
    Abstract: Silver halide photographic elements which are capable of high-contrast development and are especially useful in the field of graphic arts comprise surface latent image forming high-chloride silver halide grains and have incorporated therein a hydrazine compound which functions as a nucleator, an amino compound which functions as an incorporated booster, and a combination of a gold compound and a thiourea compound which functions as a chemical sensitizer. Thiourea compounds effective for this purpose are substituted thioureas having one or two acyl substituents or having three alkyl substituents or having one aryl substituent and two alkyl substituents.
    Type: Grant
    Filed: January 24, 1992
    Date of Patent: May 25, 1993
    Assignee: Eastman Kodak Company
    Inventor: Anthony Adin
  • Patent number: 5212045
    Abstract: Disclosed is a method for image formation which comprises developing a silver halide photographic photosensitive material in the presence of a compound represented by the following formula [I] or [II]: ##STR1## wherein Ar represents an aryl group, R.sub.1, R.sub.2 and R.sub.3 which may be identical or different each represents a hydrogen atom, an alkyl group, an aralkyl group, an aryl group, or a heterocyclic group, with a proviso that they cannot be simultaneously hydrogen atoms, R.sub.1 and R.sub.2 may link to each other to form a ring, and at least one of R.sub.1, R.sub.2 and R.sub.3 has at least one hydroxyl group as a substituent, ##STR2## wherein Ar.sub.1 and Ar.sub.2 each represents a divalent aromatic group, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group, R.sub. and R.sub.2 may link to each other to form a ring and R.sub.3 and R.sub.
    Type: Grant
    Filed: May 9, 1991
    Date of Patent: May 18, 1993
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Masao Koga, Minoru Ohashi
  • Patent number: 5210002
    Abstract: Silver halide photographic elements which are capable of high-contrast development and are especially useful in the field of graphic arts comprise surface latent image forming high-chloride silver halide grains and have incorporated therein a hydrazine compound which functions as a nucleator, an amino compound which functions as an incorporated booster, and a combination of a gold compound and a urea compound which functions as a chemical sensitizer. Urea compounds effective for this purpose are 1,1,3,3-tetra-substituted middle chalcogen urea compounds in which at least one substituent comprises a nucleophilic center.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: May 11, 1993
    Assignee: Eastman Kodak Company
    Inventor: Anthony Adin
  • Patent number: 5206123
    Abstract: A method for high contrast development of an image-wise exposed photographic element comprising a support and at least one silver halide emulsion layer, which method comprises contacting said exposed element in the presence of a hydrazine compound with an aqueous alkaline developing solution which has a pH between 10 and 13 and contains a dihydroxybenzene developing agent a 3-pyrazolidinone or an aminophenol developing agent sulphite ions and a contrast promoting amount of an amino compound characterized in that said developing solution further contains an aprotic solvent corresponding to general formula (I) or (II) : ##STR1## wherein R.sub.1 represents alkyl, substituted alkyl, alkylamino or substituted alkylamino, andR.sub.2 and R.sub.3 each independently represent alkyl substituted alkyl orwherein R.sub.1 together with R.sub.2 represent the necessary atoms to form together with the carbon and the nitrogen atom respectively to which they are attached, a heterocyclic ring, and R.sub.
    Type: Grant
    Filed: February 18, 1992
    Date of Patent: April 27, 1993
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Richard A. Ooms, Piet Kok
  • Patent number: H1281
    Abstract: The improve silver halide photographic material contains a specified hydrazide compound and a specified polyoxyethylene based compound and is capable of providing high-contrast image with high sensitivity in a rapid and consistent way.
    Type: Grant
    Filed: February 6, 1990
    Date of Patent: January 4, 1994
    Assignee: Konica Corporation
    Inventors: Kazuhiko Hirabayashi, Takeshi Sampei, Yoji Hara, Miho Sai