Silver Halide Colloid Tanning Process, Composition, Or Product Patents (Class 430/264)
  • Patent number: 5204214
    Abstract: A silver halide photographic material which provides a negative image is disclosed. The photographic material contains a compound represented by formula (I): ##STR1## wherein R represents an aliphatic group, an aromatic group, or a heterocyclic group; and Z represents an atomic group necessary to form a nitrogen-containing heterocyclic aromatic group, and provides a negative image having high contract, high sensitivity, an satisfactory dot image quality.
    Type: Grant
    Filed: July 17, 1991
    Date of Patent: April 20, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Hiroshi Kawamoto, Kazuhiko Matsumoto, Kazunobu Katoh
  • Patent number: 5204213
    Abstract: A silver halide photographic material comprising at least one silver halide emulsion layer on a support, characterized in that there is contained a compound represented by the general formula ##STR1## wherein R.sup.1 and R.sup.2 each represents a hydrogen atom, aliphatic group, aromatic group or heterocyclic group, with the proviso that R.sup.1 and R.sup.2 may be connected to each other to form a ring; L represents a divalent linking group; V represents a carbonyl group, ##STR2## group, sulfonyl group, sulfoxy group, ##STR3## group (in which R.sub.0 represents an alkoxy group or aryloxy group), iminomethylene group or thiocarbonyl group; Time represents a divalent linking group; m represents an integer 0 or 1; n represents an integer 0 or 1; PUG represents a photographically useful group; and X represents an atomic group required to form a 5- or 6-membered ring with ##STR4## wherein R.sup.1, R.sup.
    Type: Grant
    Filed: February 13, 1991
    Date of Patent: April 20, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Morio Yagihara
  • Patent number: 5200298
    Abstract: A method of forming a black-and-white image of very high contrast having a gamma value of 8 or above is disclosed, using a negative imagewise exposed photosensitive material comprising a support having thereon at least one hydrophilic colloid layer, at least one layer which is a silver halide emulsion layer, at least one of said hydrophilic colloid layer containing a hydrazine derivative represented by formula (I), comprising processing the photosensitive material with a developer having a pH of 11.2 or lower, said developer being substantially free from benzotriazoles to thereby provide a wide exposure latitude and steady image formability: ##STR1## wherein R.sub.1 represents an aliphatic group or an aromatic group; R.sub.2 represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a carbamoyl group or an oxycarbonyl group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, ##STR2## or an iminomethylene group; and each of A.sub.1 and A.
    Type: Grant
    Filed: August 8, 1991
    Date of Patent: April 6, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshihiro Takagi, Mitsunori Hirano, Senzo Sasaoka
  • Patent number: 5198333
    Abstract: A new class of electron-accepting compounds for photographic emulsions is disclosed represented by following general formula (I): ##STR1## wherein: each of Z and Q which may be the same or different represents the atoms necessary to complete an unsubstituted or substituted nitrogen-containing heterocyclic ring;each of T.sub.1 and T.sub.2 which may be the same or different represents alkyl, cycloalkyl, alkoxy, aryl, aryloxy, halogen, cyano, hydroxy, carboxyl, sulfo, carbamoyl, acyl, acylamino, sulfamoyl, sulfonamido or a benzocondensed ring, each of which can be further substituted or not;q=1, 2 or 3, and p and r=0, 1 or 2.In this formula the nitro containing heterocyclic nucleus is preferably nitropyridine or nitrothiazole.In a preferred embodiment of the invention electron-accepting compounds are incorporated in negative or direct positive roomlight emulsions. In the latter case the emulsion layer preferably contains in addition a nitroindazole or nitrobenzimidazole derivative.
    Type: Grant
    Filed: March 13, 1991
    Date of Patent: March 30, 1993
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Jean-Marie O. Dewanckele, Paul R. Callant, Marc H. Van Bockstaele, Marc B. Graindourze
  • Patent number: 5196291
    Abstract: A silver halide photographic material which comprises a support having provided thereon at least one light-sensitive emulsion layer, and which contains in said emulsion layer, or at least one other layer, at least one hydrazine derivative, at least one contrast enhancing agent and at least one redox compound capable of releasing a development inhibitor upon being oxidized. The hydrazine derivative is exemplified by compounds represented by the following formula: ##STR1## wherein R.sub.1 represents an aliphatic group or an aromatic group; R.sub.2 represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a carbamoyl group or an oxycarbonyl group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, ##STR2## or an iminomethylene group; and A.sub.1 and A.sub.2 both represent a hydrogen atom, or, alternatively, one of them represents a hydrogen atom and the other represents an alkylsulfonyl group, an arylsulfonyl group, or an acyl group.
    Type: Grant
    Filed: July 30, 1991
    Date of Patent: March 23, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Kazunobu Katoh
  • Patent number: 5196293
    Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the silver halide photographic material contains at least one compound represented by formula (I): ##STR1## wherein ED represents a group capable of releasing (Time).sub.t -Ind upon a reaction with an oxidation product of a developing agent; Time represents a divalent linking group; t represents 0 to 1; and Ind represents a group represented by formula (II): ##STR2## wherein X represents a monovalent group; and s represents an integer of from 0 to 4.The compound represented by formula (I) is excellent in preservability and rapidly releases a development inhibitor.The silver halide photographic material provides an ultrahigh contrast image using a highly stable developing solution and is particularly suitable for use in photomechanical processes.
    Type: Grant
    Filed: January 15, 1992
    Date of Patent: March 23, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Kazunobu Katoh, Shoji Yasuda, Takashi Hoshimiya
  • Patent number: 5196292
    Abstract: Silver halide photographic elements which are capable of high contrast development and are especially useful in the field of graphic arts have incorporated therein a hydrazine compound which functions as a nucleator, an amino compound which functions as an incorporated booster, and a ballasted thioether isothiourea which functions to inhibit pepper fog and restrain image spread.
    Type: Grant
    Filed: October 17, 1991
    Date of Patent: March 23, 1993
    Assignee: Eastman Kodak Company
    Inventors: Harold I. Machonkin, Donald L. Kerr
  • Patent number: 5190850
    Abstract: A silver halide photographic material having on a support a first light-sensitive layer containing a light-sensitive silver halide emulsion and a second light-sensitive layer containing a light-sensitive silver halide emulsion, wherein the first light-sensitive layer and/or a hydrophilic colloid layer contains a hydrazine compound, the second light-sensitive layer contains a redox compound capable of releasing a development inhibitor by oxidation, and the sensitivity of the first light-sensitive layer is higher by 0.2 to 1.0 than that of the second light-sensitive layer.
    Type: Grant
    Filed: May 14, 1991
    Date of Patent: March 2, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Minoru Sakai, Kazunobu Katoh
  • Patent number: 5190853
    Abstract: A silver halide color photosensitive material is disclosed. The photosensitive material comprises a support and a hydrophilic colloidal layer containing a yellow coupler. According to the present invention, the layer further contains a color image stabilizer in an amount of 10 to 200 mole % based on the amount of the yellow coupler. The color image stabilizer and the yellow coupler are together contained in droplets of a medium which are dispersed in the layer. The color image stabilizer is an organic compound having the following formula [I] or [II]: ##STR1## in which each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently is hydrogen, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, an alkoxycarbonyl group, an aryloxycarbonyl group, an acyl group, a sulfonyl group, a sulfinyl group, a phosphoryl group, a carbamoyl group or a sulfamoyl group; each of R.sup.5 and R.sup.
    Type: Grant
    Filed: November 22, 1989
    Date of Patent: March 2, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuo Seto, Masakazu Morigaki
  • Patent number: 5190847
    Abstract: Photographic silver halide materials containing aryl hydrazides as defined and novel aryl hydrazides with a cationic group in the acyl radical enables the preparation of photographic materials that can be developed rapidly to ultrahigh contrast at a relatively low pH value. The photographic materials are useful in reprography, particularly screening for halftone images.
    Type: Grant
    Filed: February 20, 1991
    Date of Patent: March 2, 1993
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Dominic M. Chan, Reinhold Ruger
  • Patent number: 5187042
    Abstract: A silver halide photographic material comprising a support having thereon at least one sensitive silver halide emulsion layer, wherein said emulsion layer comprises a monodisperse emulsion and said emulsion layer or other hydrophilic colloid layer contains at least one hydrazine derivative and at least one redox compound capable of releasing a development inhibitor when oxidized.
    Type: Grant
    Filed: April 27, 1990
    Date of Patent: February 16, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunobu Katoh, Hisashi Okamura, Hisashi Okada, Nobuaki Inoue, Toshiro Takahashi, Morio Yagihara, Tetsuo Yamaguchi
  • Patent number: 5187058
    Abstract: A negative silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer containing a silver halide emulsion containing regular silver halide grains containing from 0.3 mol % to 3.0 mol % of silver iodide, the silver halide grains being produced by conversion of silver halide host grains using high silver iodide silver halide grains having a silver iodide content of at least 90 mol % in an amount sufficient to provide from 0.1 mol % to 2.5 mol % of silver iodide based on the total silver halide content of the silver halide host grains and the high silver iodide grains.The photographic material containing silver halide grains having a novel structure provides a negative image having excellent photographic characteristics, particularly high sensitivity and ultrahigh contrast.A method of forming an ultrahigh contrast image which is excellent in line image quality using a stable developing solution is also disclosed.
    Type: Grant
    Filed: December 16, 1991
    Date of Patent: February 16, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Nobuaki Inoue
  • Patent number: 5185232
    Abstract: A method of image formation comprising imagewise exposing a silver halide photographic photosensitive material comprising a support having thereon at least two silver halide emulsion layers and which contains a hydrazine compound in the emulsion layers or in another hydrophilic colloid layer wherein the photographic speed of the emulsion layer on the side furthest from the support of the above mentioned silver halide layers is higher by 0.1 to 0.4 logE than the photographic speed of the emulsion layer which is closest to the support, through the support, and developing the imagewise exposed photosensitive material, whereby a high contrast negative image of a gamma at least 8 is obtained.
    Type: Grant
    Filed: November 16, 1990
    Date of Patent: February 9, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Senzo Sasaoka
  • Patent number: 5175074
    Abstract: A silver halide photographic material suitable for photomechanical process is disclosed, which has at least one silver halide photographic emulsion hydrophilic colloid layer and contains at least one redox compound capable of releasing a development inhibitor by oxidation and at least one compound of general formula (I') in the photographic emulsion layer or in at least one other hydrophilic colloid layer: ##STR1## wherein the variable terms are as defined in the specification.
    Type: Grant
    Filed: October 29, 1991
    Date of Patent: December 29, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Kazunobu Katoh
  • Patent number: 5175073
    Abstract: A high-contrast room-light-handleable black-and-white silver halide photographic film especially adapted for use as a dry-dot-etchable contact film in the graphic arts is comprised of a support having in order on one side thereof (1) a radiation-sensitive layer comprising silver halide grains, a hydrophilic colloid and a polymer latex, (2) an interlayer comprising a hydrophilic colloid and a polymer latex, and (3) an overcoat layer comprising a hydrophilic colloid, a matting agent and a light-scattering agent, wherein the interlayer has a refractive index in the range of from about 1.4 to about 1.7 and a thickness which is in the range of from about 0.5 to about 5 microns and is at least twice that of the overcoat layer, and wherein the film contains in the radiation-sensitive layer, or a layer contiguous thereto, a hydrazine compound which functions as a nucleating agent.
    Type: Grant
    Filed: March 26, 1991
    Date of Patent: December 29, 1992
    Assignee: Eastman Kodak Company
    Inventors: Anthony D. Gingello, David F. Jennings, Richard D. Lucitte, Hermano P. Rocha
  • Patent number: 5158856
    Abstract: A silver halide photographic light-sensitive material having a support and provided thereon, at least one silver halide emulsion layer containing Compound [I] or Compound [II] represented by Formula [I] or [II] is disclosed; ##STR1##
    Type: Grant
    Filed: February 18, 1992
    Date of Patent: October 27, 1992
    Assignee: Konica Corporation
    Inventors: Yasushi Usagawa, Fumio Ishii
  • Patent number: 5156939
    Abstract: A heat-developable light-sensitive material is disclosed, comprising a support having thereon at least a surface latent image type silver halide, a binder, an electron transfer agent or a precursor thereof, an electron donor, a reducible dye providing compound capable of releasing a diffusible dye upon being reduced with the electron donor and a hydrazine derivative.The heat-developable light-sensitive material can provide positive images having a sufficiently high image density and a low minimum density in a short period of developing time.
    Type: Grant
    Filed: August 5, 1991
    Date of Patent: October 20, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tomoyuki Koide
  • Patent number: 5155007
    Abstract: An improved silver halide photographic material that has at least one silver halide emulsion layer on a support and that contains a hydrazine derivative in said emulsion layer or an adjacent layer. The improvement is that said emulsion layer or at least one of the other hydrophilic colloidal layers contains at least one of the compounds represented by the following general formulas (I) and (II): ##STR1## wherein R.sub.1 and R.sub.1 ' are each a group selected from among a substituted or unsubstituted alkane residue, an alkene residue, a benzene residue, a cyclohexane residue and a nitrogenous heterocyclic residue; R.sub.2 is a substituted or unsubstituted alkyl group; R.sub.3, R.sub.3 ', R.sub.4 and R.sub.4 ' are each a hydrogen atom or a substituted or unsubstituted methyl group, provided that R.sub.3 and R.sub.4 or R.sub.
    Type: Grant
    Filed: March 22, 1991
    Date of Patent: October 13, 1992
    Assignee: Konica Corporation
    Inventors: Yoji Hara, Akira Kobayashi, Takeshi Sampei, Miho Sai, Akira Ogasawara
  • Patent number: 5155006
    Abstract: A silver halide photographic material comprising;a support; at least one light-sensitive silver halide emulsion layer containing a hydrazine derivative on the support; at least one hydrophilic colloid layer containing a redox compound capable of releasing a development inhibitor upon oxidation; and a developing agent incorporated, at least, into the at least one light-sensitive silver halide emulsion layer or the at least one hydrophilic colloid layer and a method for forming an image which comprises the steps of imagewise exposing to light the silver halide photographic material described above; and developing the exposed material with a developing solution having a sulfite ion concentration of at least about 0.15 mol/l and a pH of from about 10.5 to about 12.3.
    Type: Grant
    Filed: September 19, 1990
    Date of Patent: October 13, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takahiro Goto, Kazunobu Katoh
  • Patent number: 5153098
    Abstract: An image forming method for forming a black-and-white image with a gamma value of at least 8 is disclosed, which comprises processing an imagewise expsed negative type photographic material having at least one silver halide emulsion layer on a support, and containing a hydrazine derivative represented by formula (I) in the emulsion layer or in another hydrophilic colloid layer on the support, with a developer having a pH of 11.2 or less, wherein the silver halide grains are octahedral or tetradecahedral grains: ##STR1## wherein R.sub.1 represents an aliphatic or aromatic group, R.sub.2 represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a carbamoyl group or an oxycarbonyl group, G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group ##STR2## group, or an iminomethylene group, and A.sub.1 and A.sub.
    Type: Grant
    Filed: February 25, 1991
    Date of Patent: October 6, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yoshihiro Takagi
  • Patent number: 5153112
    Abstract: The improved method of processing a silver halide photographic material that has at least one light-sensitive silver halide emulsion layer on one side of a support and which has at least one back coating layer on the other side of the support is characterized in that said silver halide photographic material contains at least one specific dye and at least one anionic surfactant and the development, fixing, washing and/or stabilizing steps are performed within a time period of 40 seconds and at a line speed of at least 1,500 mm/min. The method is capable of processing the silver halide photographic material without producing either substantial or uneven color remnant.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: October 6, 1992
    Assignee: Konica Corporation
    Inventors: Kazuhiro Yoshida, Syoji Nishio
  • Patent number: 5147756
    Abstract: A process for stabilizing aqueous solution of aryl hydrazides is described. These solutions may be made by the addition of a stabilizing amount of ascorbic acid, isoascorbic acid, erythorbic acid, tartaric acid, citric acid. glucose and a cyclodextrin, etc., or mixtures, for example. When aqueous solutions of aryl hydrazides containing these stabilizers/antioxidants are prepared, the solution will have a shelf life of up to 30 days compared to 1-3 hours of solutions without the stabilizer/antioxidant. The stabilized aryl hydrazide is useful in photographic silver halide emulsions, etc.
    Type: Grant
    Filed: April 11, 1991
    Date of Patent: September 15, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Ludovic Fodor
  • Patent number: 5147754
    Abstract: A silver halide photographic material which provides a negative image contains a compound represented by formula (I): ##STR1## wherein R represents an aliphatic group, an aromatic group, or a heterocyclic group; Z represents a development inhibitor group containing an anionic functional group as a partial structure; "Time" represents a divalent group; and n is 0 or 1.
    Type: Grant
    Filed: August 7, 1991
    Date of Patent: September 15, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Hisashi Okada, Morio Yagihara, Kazunobu Katoh
  • Patent number: 5147755
    Abstract: An ultra-high contrast negative type silver halide photographic material is disclosed, wherein at least one hydrazine derivative of formula (I) and at least one compound of formula (IV) are contained in a silver halide emulsion layer or another hydrophilic collide layer of the photographic material: ##STR1## wherein A.sub.1 and A.sub.2 both represent hydrogen atoms, or one represents a hydrogen atom and the other represents a sulfinic acid residual group or an acyl group, R represents an aliphatic group, an aromatic group or a heterocyclic group, and X represents a group as indicated by formulae (II) and (III) ##STR2## wherein X.sub.1 and X.sub.2 each represent a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, and X.sub.1 and X.sub.2 may be joined together to form a ring;--O--X.sub.3 (III)wherein X.sub.3 represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group or a heterocyclic group; andY.sub.0 [(A.sub.0).sub.n B].sub.m (IV)wherein Y.sub.
    Type: Grant
    Filed: August 9, 1991
    Date of Patent: September 15, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunobu Katoh, Hisashi Okada
  • Patent number: 5145765
    Abstract: A silver halide photographic material which contains (a) at least one redox compound capable of releasing a development inhibitor by oxidation and (b) at least one compound represented by the following general formula (I): ##STR1## wherein R.sub.1 represents an aliphatic group, an aromatic group, or a heterocyclyl group; L.sub.1 represents a divalent organic group; X.sub.1 represents a hydrogen atom, an aliphatic group, an aromatic group, or a heterocyclyl group; and Y.sub.1 represents --O--, --SO.sub.2 NH-- or ##STR2## where Y.sub.
    Type: Grant
    Filed: August 14, 1991
    Date of Patent: September 8, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Kazunobu Katoh
  • Patent number: 5139921
    Abstract: A process of forming super high contrast negative photographic materials in a developer having a pH of from 9.6 to 11.0 wherein the photographic material contains a hydrazine compound and a nucleation accelerator. The nucleation accelerator is represented by formula (Ia):Y[(A.sub.1).sub.p A.sub.2 --B].sub.m (Ia)wherein Y represents a group adsorbing onto silver halide; A.sub.1 represents a divalent linkage group composed of an atom or an atomic group selected from hydrogen, carbon, nitrogen, oxygen, and sulfur and selected from ##STR1## with a straight chain or branched alkylene group wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9 and R.sub.10 each represents hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkenyl group or a substituted or unsubstituted aralkyl group; A.sub.
    Type: Grant
    Filed: February 12, 1991
    Date of Patent: August 18, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshihiro Takagi, Hisashi Okada, Morio Yagihara
  • Patent number: 5139920
    Abstract: A reducer and a method for conducting dot etching processing using the reducer, the reducer comprising (1) an amino polycarboxylic acid ferric chelate compound having an oxidation-reduction potential of -100 mV or above, (2) a complexing agent, and (3) at least one member of the compounds represented by the following general formulae (IA) to (VIIA). ##STR1## All symbols are defined in the specification.
    Type: Grant
    Filed: July 3, 1991
    Date of Patent: August 18, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsumi Hayashi, Morio Yagihara, Shinji Ueda, Yoshihiro Fujita, Toshihiko Maekawa, Kiyoshi Morimoto
  • Patent number: 5134055
    Abstract: A silver halide photographic material is disclosed, which has at least one compound represented general formula (1): ##STR1## wherein R represents an aliphatic group, an aromatic group, or a heterocyclic group; both L and Time represent a divalent organic group; t represents 0 or 1; PUG represents a photographically useful group; Y represents --SO.sub.2 --, --Y'--SO.sub.2 --, or ##STR2## and Y' represents --O--, --NH--, or ##STR3## The material has a broad exposure latitude in line image-taking work and has a high resolving power in the work. It can form an ultrahard image having a high gamma value of 10 or more. The material may excellently reproduce a line original to form an ultrahard image having a high background density. It also has a broad exposure latitude in halftone dot image-taking work and can form a halftone dot image having ultrahigh contrast with high image quality.
    Type: Grant
    Filed: April 20, 1990
    Date of Patent: July 28, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Hisashi Okada, Morio Yagihara, Kazunobu Katoh, Keiji Mihayashi
  • Patent number: 5132201
    Abstract: A silver halide photographic material composed of a support having thereon at least one light-sensitive silver halide emulsion layer, at least one layer of the material containing a compound represented by formula (I): ##STR1## wherein X represents hydrogen or a group capable of providing hydrogen upon hydrolysis; Time represents a divalent linking group; t is 0 or 1; PUG represents a photographically useful group; V represents a carbonyl group, a sulfonyl group, a sulfoxy group, an iminomethylene group, ##STR2## wherein W represents an electrophilic group, or V represents ##STR3## wherein R.sub.0 represents an alkoxy group or an aryloxy group; and R represents hydrogen, an aliphatic group, an aromatic group or ##STR4## wherein PUG, Time, t, and W are as defined above. The redox compound is capable of releasing a photographically useful reagent using any conventional developing agent, has excellent storage stability, and provides rapid release of the photographically useful reagent.
    Type: Grant
    Filed: November 12, 1991
    Date of Patent: July 21, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Hisashi Okada
  • Patent number: 5130226
    Abstract: A silver halide photographic light-sensitive material suitable for photomechanical process is disclosed. The light-sensitive material comprises a support and a silver halide emulsion layer and the emulsion layer or a layer adjacent to the emulsion layer contains a compound represented by formula 1, 2 or 3 and a compound represented by formula 4 or 5. ##STR1## The light-sensitive material give extreme high contrast images by processing usung a stable developer and is inhibited from producing pepper fog.
    Type: Grant
    Filed: September 12, 1991
    Date of Patent: July 14, 1992
    Assignee: Konica Corporation
    Inventors: Takeshi Sampei, Akira Ogasawara, Miho Sai, Yoji Hara
  • Patent number: 5126227
    Abstract: Silver halide photographic elements which are capable of high contrast development, when processed in the presence of a hydrazine compound that functions as a nucleating agent, contain both an amino compound which functions as an incorporated booster and a ballasted hydrophobic isothiourea compound comprising a ballasting group, that is attached to the sulfur atom, which serves to restrict the mobility of the compound and thereby aid in retaining it in the photographic element during development. The ballasted hydrophobic isothiourea compound is highly effective in reducing pepper fog and also serves to restrain image spread.
    Type: Grant
    Filed: October 17, 1990
    Date of Patent: June 30, 1992
    Assignee: Eastman Kodak Company
    Inventors: Harold I. Machonkin, Donald L. Kerr
  • Patent number: 5124231
    Abstract: A silver halide photographic material which has at least one photosensitive silver halide emulsion layer containing a hydrazine derivative, and in which said emulsion layer and/or a hydrophilic colloid layer which is different from said emulsion layer contains a redox compound which release a development inhibitor when it is oxidized and an organic compound which is a melting-pointlowering agent which is essentially insoluble in water and which has the effect of lowering the melting point of said redox compound when the former has been mixed with the latter.
    Type: Grant
    Filed: September 25, 1990
    Date of Patent: June 23, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Minoru Sakai, Kazunobu Katoh
  • Patent number: 5124230
    Abstract: The silver halide photographic material capable of providing very high contrast negative images is disclosed, which has at least one silver halide photographic emulsion layer on a support, wherein the silver halide photographic emulsion layer or another hydrophilic colloid layer provided on the support contains a nucleating agent represented by formula (Ia), (Ib) or (Ic): ##STR1## wherein R.sub.11, R.sub.12, R.sub.21, R.sub.31, Y.sub.11, Y.sub.21, A.sub.11, A.sub.12 and G.sub.11 are defined in the specification.
    Type: Grant
    Filed: February 4, 1991
    Date of Patent: June 23, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Kazunobu Katoh, Morio Yagihara
  • Patent number: 5122445
    Abstract: A silver halide photographic material is disclosed, comprising a support having thereon at least one light-sensitive silver halide emulsion layer and at least one light-insensitive upper layer, wherein the light-insensitive upper layer contains porous fine powder particles having a surface area of at least 400 m.sup.2 /g.
    Type: Grant
    Filed: June 19, 1990
    Date of Patent: June 16, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kunio Ishigaki
  • Patent number: 5122434
    Abstract: A halogen acceptor according to general chemical formula (I) is added to a photographic negative roomlight emulsion, consisting of at least 90% of silver chloride, having an average grain size smaller than 0.3 micron, and internally doped with an element of group VIII of the periodic table. ##STR1## In this formula: R.sup.1 =alkyl having at least 4 C-atoms, preferably between 4 and 9.In the coated emulsion layer, the halogen acceptors of the invention provide a clear print-out effect and an improved development latitude when the emulsion layer is developed in a "hard-dot Rapid Access" processing system.In a preferred embodiment R=--C.sub.6 H.sub.13 and the element of group VIII is Rhodium.
    Type: Grant
    Filed: March 13, 1991
    Date of Patent: June 16, 1992
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Marc H. Van Bockstaele, Marc B. Graindourze, Jean-Marie O. Dewanckele
  • Patent number: 5116717
    Abstract: A silver halide photographic material composed of a support having thereon at least one silver halide photosensitive emulsion layer, at least one layer of the material containing a blocked photographic reagent precursor represented by formula (I): ##STR1## wherein X.sub.1 represents a divalent linking group containing a hetero atom bonded to the carbon atom, provided that X.sub.1 is linked to the carbon atom by a group other than ##STR2## PUG represents a photographically useful group containing a hetero atom bonded to X.sub.1 ; W represents .dbd.N-- or ##STR3## Y.sub.1 represents hydrogen or a group capable of being substituted; Z represents an atomic group necessary for forming a heterocyclic ring, provided that when W represents a ##STR4## the group adjacent to W in the heterocyclic ring is a group other than ##STR5## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.
    Type: Grant
    Filed: February 25, 1991
    Date of Patent: May 26, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsunori Matsushita, Morio Yagihara
  • Patent number: 5108880
    Abstract: A water soluble alkaline developer composition useful in the development of exposed silver halide photographic material comprised of a developing agent, a sulfite preservative and a small but effective amount of an amino alcohol compound of the formula ##STR1## wherein each R.sub.1 is a C.sub.2 -C.sub.4 alkyl group and R.sub.2 is a moiety having the structure: (R.sub.1 O).sub.x --R.sub.1 OH wherein x is an integer of from 1 to 3, and R.sub.1 is as defined hereinabove.
    Type: Grant
    Filed: December 20, 1990
    Date of Patent: April 28, 1992
    Assignee: Sun Chemical Corporation
    Inventor: John L. Adkins
  • Patent number: 5108872
    Abstract: A silver halide photographic material comprising a support having thereon at least one light-sensitive layer comprising a silver halide emulsion sensitized by an infrared sensitization dye, wherein the silver halide in the silver halide emulsion contains at least 90 mol % of silver chloride and is constituted by monodisperse grains having a coefficient of variation of not more than 20%; and an image formation method using the above-described silver halide photographic photosensitive material, comprising the steps of imagewise exposing the photographic material and developing the said material in a developing solution containing at least 0.15 mol/l of sulfurous acid ions and a compound having a silver halide-adsorption accelerating group.
    Type: Grant
    Filed: November 15, 1990
    Date of Patent: April 28, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Inoue, Morio Yagihara, Naomi Saeki
  • Patent number: 5104769
    Abstract: Photographic elements and emulsions are described which are capable of providing high contrast images. The elements and emulsions comprise negative working silver halide and contrast enhancing arylhydrazide nucleating agents. A process for utilization of the elements and emulsions is also described.
    Type: Grant
    Filed: March 14, 1988
    Date of Patent: April 14, 1992
    Assignee: Eastman Kodak Company
    Inventors: Jerome J. Looker, Ronald E. Leone, Lee J. Fleckenstein
  • Patent number: 5102779
    Abstract: A method for processing silver halide photographic materials comprising the step of: processing imagewise exposed silver halide photographic material using a developer containing at least one compound represented by general formula (X): ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an alkyl group containing from 2 to 8 carbon atoms, an alkenyl group containing from 3 to 8 carbon atoms, or an aralkyl group containing from 7 to 12 carbon atoms; or R.sub.1 and R.sub.2 are combined to form a ring; R.sub.3, R.sub.4, R.sub.5, and R.sub.6 each represents a hydrogen atom, or an alkyl group containing from 1 to 4 carbon atoms: and n represents an integer from 3 to 20. A developer for processing silver halide photographic materials comprising at least one compound represented by general formula (X), described above. A silver halide photographic material comprising: at least one compound represented by general formula (X'): ##STR2## wherein R'.sub.1 and R'.sub.
    Type: Grant
    Filed: October 12, 1990
    Date of Patent: April 7, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Eiichi Okutsu, Kazunobu Katoh
  • Patent number: 5100761
    Abstract: A silver halide photographic material comprising one or more silver halide emulsion layers and hydrophilic colloid layers, wherein at least one of the layers contains an acylhydrazine compound as described below. The instant photographic materials have high contrast negative-gradation or positive-gradation characteristics, high maximum image density, excellent reversal characteristics and long-term storage stability.
    Type: Grant
    Filed: March 21, 1988
    Date of Patent: March 31, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Hisashi Okada, Kazunobu Katoh, Noriyuki Inoue, Shingo Nishiyama, Tetunori Matushita
  • Patent number: 5093222
    Abstract: A negative silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, wherein said silver halide emulsion layer or another hydrophilic colloid layer provided on the support contains (i) a hydrazine derivative, (ii) at least one cationic dye selected from the group consisting of cyanine dyes, hemicyanine dyes and rhodacyanine dyes, and (iii) a compound represented by formula (I) and having substantially no absorption maximum at the visible region; ##STR1## wherein Z.sup.11, Z.sup.12, R.sup.11, R.sup.12, X and n are defined in the specification.
    Type: Grant
    Filed: October 26, 1988
    Date of Patent: March 3, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kazunobu Katoh
  • Patent number: 5085971
    Abstract: A silver halide photographic material comprising a support having thereon a hydrophilic colloid layer which contains gelatin and wherein the hydrophilic colloid layer contains fine polymer particles which contains a redox compound which is capable of releasing a development inhibitor by oxidation, and a hydrazine compound, which is not the same as the redox compound, is contained in the hydrophilic colloid layer and/or in another hydrophilic colloid layer.
    Type: Grant
    Filed: May 15, 1990
    Date of Patent: February 4, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunobu Katoh, Morio Yagihara
  • Patent number: 5085970
    Abstract: A method for forming an image is disclosed which comprises providing a photosensitive material comprising at least one light-sensitive layer and having a gamma value of not less than 10 and a capability of being handled under bright light, subjecting said light-sensitive layer image-wise exposure to light having substantially exclusive of wavelengths of 370 nm or shorter through originals, for example, a line original and a halftone original arranged in a superposed condition, followed by contrast development processing, whereby excellent quality of images, for example, letter images, can be obtained.
    Type: Grant
    Filed: September 13, 1990
    Date of Patent: February 4, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kimitaka Kameoka, Ken-ichi Kuwabara, Toshiro Takahashi, Shigenori Moriuchi, Morio Yagihara, Yoshio Inagaki, Keiichi Adachi
  • Patent number: 5075198
    Abstract: A negative type silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the silver halide emulsion layer or another hydrophilic colloid layer provided on the support contains (1) a compound represented by formula (I) having substantially no absorption maximum in the visible region of the spectrum and (2) a hydrazine compound represented by formula (II): ##STR1## wherein Z.sup.11 and Z.sup.12 each represents a non-metallic atomic group completing a benzoxazole nucleus, a benzothiazole nucleus, a benzoselenazole nucleus, a naphthoxazole nucleus, a naphthothiazole nucleus, a naphthoselenazole nucleus, a thiazole nucleus, a thiazoline nucleus, an oxazole nucleus, a selenazole nucleus, a selenazoline nucleus, a pyridine nucleus, a benzimidazole nucleus, or a quinoline nucleus; R.sup.11 and R.sup.12 each represents an unsubstituted or substituted alkyl group, at least one of said R.sup.11 and R.sup.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: December 24, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kazunobu Katoh
  • Patent number: 5068167
    Abstract: Pepper fog may be reduced in high contrast photographic materials comprising silver halide emulsion in association with a hydrazine by the presence of at least 0.001 mole per mole of silver halide of a water-soluble bromide and/or water-soluble chloride. Suitable water-soluble bromides and chlorides are alkali metal bromides and chlorides which are advantageously added to the silver halide emulsion after physical ripening and washing.
    Type: Grant
    Filed: March 29, 1988
    Date of Patent: November 26, 1991
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Kevin P. Hall
  • Patent number: H1063
    Abstract: Disclosed is a negative type light-sensitive silver halide photographic material comprising at least one light-sensitive silver halide emulsion provided on a support, wherein the ratio of silver amount to gelatin amount (Ag/Gel) (wherein the silver amount is the total silver amount in one or more layers provided in the same side as the light-sensitive silver halide emulsion layer with respect to the support, and the gelatin amount is the total gelatin amount in one or more gelatin layers provided in the same side as the light-sensitive silver halide emulsion layer with respect to the support) is 1.0 or more, and a hydrophilic colloid layer in the light-sensitive silver halide emulsion contains a hydrazine compound.
    Type: Grant
    Filed: November 6, 1989
    Date of Patent: June 2, 1992
    Inventor: Yuji Hosoi
  • Patent number: H1090
    Abstract: Disclosed is a light-sensitive silver halide photographic material having a hydrophilic colloid layer containing at least one layer of a light-sensitive silver halide emulsion layer provided on a support, wherein a hydrazide derivative is contained in the light-sensitive silver halide emulsion layer, and the above hydrophilic colloid layer contains at least one of the compounds represented by Formulae [II] and [III] shown below: ##STR1## wherein R1, R2 and R3 are as defined in the specification, ##STR2## wherein R1 and R2 are as defined in the specification.
    Type: Grant
    Filed: November 27, 1990
    Date of Patent: August 4, 1992
    Assignee: Konica Corporation
    Inventors: Junichi Fukawa, Takeshi Habu
  • Patent number: H1091
    Abstract: There is disclosed a light-sensitive silver halide photographic material which comprises, in a light-sensitive silver halide photographic material provided by coating at least one layer of hydrophilic colloidal layer including light-sensitive silver halide photographic emulsion layer on a support, containing a specific hydrazide derivative in the light-sensitive silver halide emulsion layer and containing, in the hydrophilic colloidal layer, at least one compound selected from each of the groups A and B consisting of the compounds represented by the formulae (II) to (VII) as specified in the specification.
    Type: Grant
    Filed: December 5, 1990
    Date of Patent: August 4, 1992
    Assignee: Konica Corporation
    Inventors: Yasuhiko Takamuki, Junichi Fukawa, Takeshi Habu
  • Patent number: H1119
    Abstract: Disclosed is a direct positive photographic material having an improved time-dependent storage stability. The material comprises a support having thereon at least one photographic emulsion layer containing previously non-fogged internal latent image type silver halide grains wherein the photographic emulsion layer contains at least one compound of formula (I): ##STR1## where R.sup.11 is an aryl group, R.sup.12 to R.sup.15 each are a hydrogen atom, or an aliphatic or aromatic group, and R.sup.11 to F.sup.15 may have substituent(s) and may form ring(s).
    Type: Grant
    Filed: January 18, 1991
    Date of Patent: December 1, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Noriyuki Inoue