Silver Halide Colloid Tanning Process, Composition, Or Product Patents (Class 430/264)
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Patent number: 5866313Abstract: A silver halide photographic light-sensitive material having at least one light-sensitive silver halide emulsion layer, on a support, and comprising a reducing agent for color formation of carbamoyl-substituted hydrazine, a dye-forming coupler and at least one photographic stabilizer selected from five groups of compounds.Type: GrantFiled: November 29, 1996Date of Patent: February 2, 1999Assignee: Fuji Photo Film Co., Ltd.Inventor: Katsumi Hirano
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Patent number: 5858610Abstract: An image forming method comprising developing a silver halide photographic light-sensitive material which comprises a support having thereon at least one light-sensitive silver halide emulsion layer: wherein the silver halide photographic light-sensitive material contains at least one kind of hydrazine derivative represented by general formula (NB) in at least one layer of the silver halide emulsion layer(s) and other hydrophilic colloidal layers:A--(B).sub.m (NB)and wherein the development is conducted by using a developing solution having a pH of from not less than 8.5 to less than 11.0, which developing solution does not substantially contain a dihydroxybenzene developing agent, but contains a developing agent represented by general formula (1): ##STR1## The symbols used in the above formulas are defined in the specification.Type: GrantFiled: April 17, 1997Date of Patent: January 12, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshihide Ezoe, Kohzaburoh Yamada
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Patent number: 5858612Abstract: A method for forming a superhigh contrast image which comprises the steps of image-exposing a silver halide photographic material having a silver halide emulsion layer provided on a support, the layer comprising silver halide grains containing 50 mol % or more of silver chloride and 1.times.10.sup.-8 to 1.times.10.sup.-6 mol of a complex of rhodium, ruthenium, rhenium, or osmium per mol of silver halide, being spectrally sensitized so as to have the maximum sensitivity in the wavelength region of 750 nm or more, and further containing a hydrazine compound; and processing with a developer which contains a developing agent of a ascorbic acid type and does not substantially contain that of a dihydroxybenzene type, the silver halide photographic material being processed with the developer which causes less harm to the environment.Type: GrantFiled: May 22, 1997Date of Patent: January 12, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuaki Inoue, Kouta Fukui
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Patent number: 5858589Abstract: A method for making a lithographic printing plate from an original containing multiple tones comprising the steps of frequency modulation screening the multiple image to obtain screened data representing tones of the multiple tone image in terms of halftone dots; reproducing the halftone dots on a lithographic printing plate precursor having a surface capable of being differentiated in ink accepting and ink repellant areas upon scanwise exposure and an optional development step, by means of a scanwise exposure, wherein the scanwise exposure for rendering a halftone dot is intensity modulated.Type: GrantFiled: March 20, 1996Date of Patent: January 12, 1999Assignee: Agfa-Gevaert N.V.Inventors: Rene Govaert, Paul Delabastita, Jacobus Bosschaerts
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Patent number: 5858611Abstract: A development processing method of a silver halide black-and-white photographic material is described, which comprises the steps of (a) exposing a silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, and (b) developing the exposed silver halide photographic material with a developer, wherein at least one layer of the light-sensitive silver halide emulsion layer and a hydrophilic colloid layer contains at least one hydrazine derivative represented by the following formula (I); the developer contains substantially no dihydroxybenzene compound; and the developer contains (1) a developing agent selected from ascorbic acid, erythorbic acid and derivatives thereof, (2) a developing agent represented by the following formula (II), and (3) an auxiliary developing agent exhibiting a superadditive property. ##STR1## The formulae (I) and (II) are described in the specification in detail.Type: GrantFiled: May 9, 1997Date of Patent: January 12, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Kouta Fukui, Shinnichi Morishima
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Patent number: 5853951Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein: the silver halide emulsion layer comprises a silver halide comprising silver chloride or silver chlorobromide having a silver chloride content of not less than 95 mol %; the silver halide emulsion comprises at least one transition metal selected from the group consisting of elements belonging to the groups V to VIII of the periodic table, which has one nitrosyl, thionitrosyl or aquo ligand per molecule; and the silver halide is chemically sensitized with a selenium compound selected from compounds represented by one of formulae SE-1 to SE-8 disclosed in the specification.Type: GrantFiled: October 3, 1996Date of Patent: December 29, 1998Assignee: Fuji Photo Film Co., LTD.Inventors: Shoji Yasuda, Tadashi Ito, Takahiro Goto, Hirotomo Sasaki, Seiichi Yamamoto
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Color-developing agent, silver halide photographic light-sensitive material and image-forming method
Patent number: 5851749Abstract: There is disclosed novel color-developing agents of the formula (I). There is also disclosed silver halide photographic light-sensitive materials and image-forming methods, using the color-developing agent. The color-developing agent is excellent in color-forming property, and the image obtained from the color-developing agent is good in stability of hue and image. ##STR1## wherein Z.sup.1 represents an acyl group, a carbamoyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonyl group, or a carbonimidoyl group, Q.sup.1 represents a group of atoms required to form a 5- or 6-membered aromatic ring together with the C, Q.sup.2 represents a heterocyclic residue, Y.sup.1 represents a group capable of substitution onto the aromatic ring, m is 1 or 2, and n is an integer of 0 to 3.Type: GrantFiled: November 26, 1996Date of Patent: December 22, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Atsuhiro Okawa, Toshiyuki Makuta, Toshiki Taguchi -
Patent number: 5837418Abstract: A silver halide black-and-white photographic light sensitive material is disclosed, comprising a support provided thereon a silver halide emulsion layer and provided farther from the support another higher-sensitive silver halide emulsion layer, wherein both silver halide emulsion layers each have a coating weight of silver of not less than 0.5 g/m.sup.2 and are sensitized substantially to the same spectral region; at least two, different hydrazine compounds being contained in the silver halide emulsion layers or another photographic component layer.Type: GrantFiled: April 23, 1996Date of Patent: November 17, 1998Assignee: Konica CorporationInventors: Takeo Arai, Junichi Fukawa
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Patent number: 5834176Abstract: A silver halide photographic light-sensitive material is disclosed. The light-sensitive material comprises a support, and a silver halide emulsion layer and optionally a hydrophilic colloid layer provided on the support, in which the silver halide layer comprises a silver halide emulsion chemically sensitized in the presence of fine particles of a water-insoluble sulfur sensitizer which are added to the silver halide emulsion in a form of dispersion of solid particles.Type: GrantFiled: July 10, 1997Date of Patent: November 10, 1998Assignee: Konica CorporationInventors: Wataru Ishikawa, Seiji Hidaka
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Patent number: 5834172Abstract: A photographic coating composition comprising an aqueous medium containing a hydrophilic colloid and having dispersed therein solid particles of a yellow filter dye also contains a oxidized developer scavenger of formula III ##STR1## wherein x.sup.1 =hydrogen or a process cleavable group;R.sup.14 =an electron withdrawing and aqueous solubilizing group;R.sup.15 =a substituent group;R.sup.16 =a ballasting group;R.sup.17 =a substituent group;i=1, 2, 3, or 4; andj=1, 2, 3, or 4.The coating composition is stable with regard to crystal growth of the dispersed solid particles of filter dye even when held at coating temperatures (about 45.degree. C.) for several hours.Type: GrantFiled: February 23, 1996Date of Patent: November 10, 1998Assignee: Eastman Kodak CompanyInventors: Paul Leo Zengerle, John Victor Nelson, Mary Christine Brick
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Patent number: 5834169Abstract: The present invention concerns a novel method for developing silver halide photographic products. This method involves processing photographic products that have an incorporated developing agent, and a nucleation agent, by surface application of an activator solution. This method intended for processing graphic arts films having high contrast.Type: GrantFiled: September 18, 1997Date of Patent: November 10, 1998Assignee: Eastman Kodak CompanyInventor: Francoise M. Thomas
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Patent number: 5830626Abstract: A processing composition includes a combination of two different mercapto-substituted anti-sludging agents. The first compound is a conventional mercapto-substituted compound, and the second compound is a mercapto thiadiazole glycerol propoxylate having the formula I: ##STR1## This processing composition can be used to provide black-and-white development of both color reversal and black-and-white photographic elements, and particularly in high contrast graphic arts films.Type: GrantFiled: August 26, 1997Date of Patent: November 3, 1998Assignee: Eastman Kodak CompanyInventors: Hugh G. McGuckin, John S. Badger, Ronald J. Nothnagle, Jerry L. Willer
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Patent number: 5830618Abstract: A silver halide photographic material is provided which comprises a support having thereon at least one light-sensitive silver halide emulsion layer wherein said light-sensitive layer or another hydrophilic colloidal layer provided on the support contains a compound represented by formula (I) and a hydrazine derivative represented by formula (II): ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents a hydroxyl, hydroxylamino, amino, alkylamino, arylamino, aralkylamino, alkoxy, phenoxy, alkyl, aryl, alkylthio, or phenylthio group, ##STR2## wherein R.sup.3 represents an aliphatic or aromatic group; R.sup.4 represents a hydrogen atom, or an alkyl, aryl, alkoxy, aryloxy, amino or hydrazino group; G.sup.1 represents a --CO--, --SO.sub.2 --, --SO--, --P(O)R.sup.4, --CO--CO--, thiocarbonyl or iminomethylene group; and A.sup.1 and A.sup.2 each represents a hydrogen atom, or one of A.sup.1 and A.sup.Type: GrantFiled: August 6, 1996Date of Patent: November 3, 1998Assignee: Fuji Photo Film Co., Ltd.Inventor: Tetsuo Yamaguchi
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Patent number: 5804359Abstract: Photographic elements are disclosed in which exposure to at least one portion of the spectrum is recorded by a silver halide emulsion layer unit as an image having its optical density provided by silver. The layer unit is comprised of a plurality of radiation sensitive silver halide emulsion layers that are responsive to the same region of the spectrum, but differ in sensitivity, including a non-wandering silver halide reducing agent. A molar ratio of reducing agent to silver halide in one of the emulsion layers is less than that stoichiometrically required for complete silver halide reduction to silver. A higher molar ratio of reducing agent to silver halide is contained in a remaining of the two emulsion layers.Type: GrantFiled: May 17, 1996Date of Patent: September 8, 1998Assignee: Eastman Kodak CompanyInventor: Michael John Simons
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Patent number: 5798204Abstract: A development processing method is described, which includes the steps of (a) exposing an ultrahigh-contrast silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer and (b) developing the exposed silver halide photographic material with a developer while the developer is replenished with a development replenisher, wherein the developer and the development replenisher each contains a dihydroxybenzene developing agent and an auxiliary developing agent exhibiting a superadditive property to the dihydroxybenzene developing agent, and both the developer and the development replenisher have such a property that an increase of the pH is 0.25 or less when 0.1 mol of sodium hydroxide is added to 1 liter thereof; the developer has a pH from 9.5 up to but excluding 11.0; and the developer replenisher is added in an amount of 225 ml/m.sup.2 or less.Type: GrantFiled: December 16, 1996Date of Patent: August 25, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Kouta Fukui, Mitsunori Hirano, Nobuaki Inoue
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Patent number: 5789139Abstract: A hydrazide compound represented by the following formula (I), and a silver halide photographic photonsensitive material comprising the hydrazide compound:A--(B).sub.b (I)wherein A represents a heterocyclic group, a condensed polycyclic aromatic group or a group formed by connecting at least two aromatic groups to each other, B represents a group represented by the following formula (I-B) or (II-B), and b represents an integer from 2 to 6;--L.sub.1 --Ar.sub.1 --NHNH--G.sub.1 --R.sub.1 (I-B)--L.sub.3 --Ar.sub.3 --L.sub.2 --Ar.sub.2 --NHNH --G.sub.2 --R.sub.2(II-B)wherein each of G.sub.1 and G.sub.2 represents a carbonyl group, an oxalyl group, a sulfonyl group or a phosphoryl group; each of R.sub.1 and R.sub.2 represents a hydrogen atom or a blocking group; each of Ar.sub.1, Ar.sub.2 and Ar.sub.3 represents an aromatic group or an aromatic heterocyclic group; and each of L.sub.1, L.sub.2 and L.sub.3 represents a linkage group.Type: GrantFiled: December 27, 1996Date of Patent: August 4, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Kohzaburoh Yamada, Hiroyuki Suzuki, Toshihide Ezoe, Koji Kawato
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Patent number: 5783357Abstract: Silver halide recording material for the production of negative images with ultrahigh contrast.Known silver halide recording materials for the production of negative images with ultrahigh contrast contain hydrazine compounds and contrast-increasing compounds (so-called boosters). A material with a new class of such boosters is being presented here, whereby they contain a sulfonyl urea, sulfonyl urethane or sulfuryl diamide group as well as a tertiary amino group in the molecule. The invention also comprises a process for the production of black-and-white negative images with ultrahigh contrast using the material according to the invention. It is especially useful for reproduction in the pre-press stage.Type: GrantFiled: March 15, 1996Date of Patent: July 21, 1998Assignee: E. I. du Pont de Nemours and CompanyInventor: Reinhold Ruger
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Patent number: 5780198Abstract: A silver halide photographic material comprising a plurality of light-sensitive silver halide emulsion layers, wherein (A) at least one of the layers contains a hydrazine nucleating agent represented by formula (II): ##STR1## wherein R.sub.1 represents an aliphatic group or an aromatic group; R.sub.2 represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a hydrazine group, a carbamoyl group, or an oxycarbonyl group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfinyl group, a sulfoxy group, ##STR2## a thiocarbonyl group, or an iminomethylene group; and A.sub.3 and A.sub.4 each represents a hydrogen atom, a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, or a substituted or unsubstituted acyl group, provided that at least one of A.sub.3 and A.sub.Type: GrantFiled: February 15, 1995Date of Patent: July 14, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Takahiro Goto, Kazunobu Katoh, Minoru Sakai
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Color developing agent, silver halide photographic light-sensitive material and image forming method
Patent number: 5780210Abstract: There is disclosed a light-sensitive material comprising, in a hydrophilic colloid provided on a base, a color-developing agent represented by formula (I) or (II): ##STR1## wherein Z.sup.1 represents an acyl group, a carbamoyl group, an alkoxycarbonyl group, or an aryloxycarbonyl group; Z.sup.2 represents a carbamoyl group, an alkoxycarbonyl group, or an aryloxycarbonyl group; X.sup.1, X.sup.2, X.sup.3, X.sup.4, and X.sup.5 each represent a hydrogen atom or a substituent, provided that the sum of the Hammett substituent constant .sigma.p values of X.sup.1, X.sup.3, and X.sup.5 and the Hammett substituent constant .sigma.m values of X.sup.2 and X.sup.4 is 0.80 or more but 3.80 or below; and R.sup.3 represents a heterocyclic group. There is also disclosed a novel color-developing agent that can be built in. By using the color-developing agent, the light-sensitive material can attain a rapid and simple formation of an image.Type: GrantFiled: February 15, 1996Date of Patent: July 14, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Kiyoshi Takeuchi, Koki Nakamura, Toshiki Taguchi, Koichi Nakamura, Toshiyuki Makuta -
Patent number: 5776664Abstract: A silver halide photographic material comprising: (a) a silver chloride-containing emulsion comprising a dispersion medium and a silver halide grain, wherein the silver halide grain contains a tabular grain having an average aspect ratio of not less than 2 accounting for at least 50% of the entire projected area thereof and has a silver chloride content of not less than 20 mol%; (b) a developing agent; and (c) a compound capable of forming a dye image upon development.Type: GrantFiled: June 17, 1996Date of Patent: July 7, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Yamashita, Koki Nakamura, Koichi Nakamura
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Patent number: 5770344Abstract: A silver halide photographic light-sensitive material containing a hydrazide compound represented by the following formula (I), (II), (I') or (II'): ##STR1## wherein the symbols in the above formulae are defined in the specification.Type: GrantFiled: December 27, 1996Date of Patent: June 23, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Kohzaburoh Yamada, Hiroyuki Suzuki, Toshihide Ezoe
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Patent number: 5766821Abstract: A black-and-white silver halide photographic light-sensitive material is disclosed.Type: GrantFiled: March 31, 1997Date of Patent: June 16, 1998Assignee: Konica CorporationInventors: Yasuhiko Muramatsu, Takeshi Sampei
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Patent number: 5766820Abstract: A silver halide photographic light sensitive material is disclosed which comprises a support and provided thereon, a hydrophilic colloid layer comprising at least one silver halide emulsion layer and at least one non-light sensitive layer, the hydrophilic colloid layer being hardened with at least one hardener selected from the group consisting of a carboxyl active hardener, a vinylsulfone type hardener, an epoxy type hardener and a triazine type hardener, wherein a silver halide emulsion layer closest to the support of the silver halide emulsion layers contains a dye in the form of dispersed solid particles or a non-light sensitive layer closest to the support of the non-light sensitive hydrophilic colloid layers contains a dye in the form of dispersed solid particles, and the thickness swell percentage of the photographic component layer is 10 to 100%.Type: GrantFiled: December 12, 1996Date of Patent: June 16, 1998Assignee: Konica CorporationInventors: Junichi Fukawa, Seiji Hidaka, Takeo Arai
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Patent number: 5766822Abstract: A silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide hydrophilic colloid emulsion layer, at least one light-insensitive hydrophilic colloid layer interposed between the support and at least one silver halide emulsion layer, and at least one hydrazine derivative selected from the group consisting of compounds represented by the general formula (1) and (2) contained in the at least one of hydrophilic colloid layers provided in the same side of the support as that coated with the light-sensitive silver halide hydrophilic colloid emulsion layer: ##STR1## wherein their substituents are defined in the specification.Type: GrantFiled: October 18, 1996Date of Patent: June 16, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuaki Inoue, Toshihide Ezoe, Takashi Hoshimiya, Kazumi Nii, Kazunobu Katoh, Tetsuo Yamaguchi, Hisashi Okamura
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Patent number: 5759742Abstract: A masking element is prepared with a photosensitive layer on a suitable support, overcoated with a masking layer containing an infrared absorbing compound and a thermally bleachable dye. The dye is bleached by imagewise laser irradiation, followed by floodwise exposure to produce an image in the photosensitive layer corresponding to the laser produced image. The outermost layers are removed and development provides a suitable negative-working printing plate.Type: GrantFiled: September 25, 1996Date of Patent: June 2, 1998Assignee: Eastman Kodak CompanyInventors: Paul Richard West, Jeffery Allen Gurney
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Patent number: 5753409Abstract: A silver halide black-and-white photographic light sensitive material is disclosed, comprising a support provided on one side thereof photographic component layers comprising at least two, first and second silver halide emulsion layers and optionally a nonlight-sensitive hydrophilic colloidal layer, the first emulsion layer being provided closer to the support than the second emulsion layer, wherein two or more layers of the component layers, each contains a hydrazine compound; and a molar ratio of a total hydrazine content of all layer(s) closer to the support from the first emulsion layer which include the first emulsion layer to that of all layer(s) farther from the support than the first emulsion layer which include the second emulsion layer is 0.2 to 0.8.Type: GrantFiled: October 11, 1996Date of Patent: May 19, 1998Assignee: Konica CorporationInventors: Toshiyuki Takabayashi, Hirohide Ito
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Patent number: 5753411Abstract: A silver halide color photographic light-sensitive material is disclosed, comprising a support having thereon at least one photographic constituent layer, wherein any one of the photographic constituent layer contains at least one reducing agent for color formation represented by formula (I), at least one dye forming coupler and at least one water-insoluble polymer.Type: GrantFiled: November 27, 1996Date of Patent: May 19, 1998Assignee: Fuji Photo Film Co., Ltd.Inventor: Toshiyuki Makuta
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Patent number: 5753410Abstract: Disclosed is a silver halide photographic light-sensitive material comprising a support having thereon a light-sensitive silver halide emulsion layer and a layer adjacent to said light-sensitive silver halide emulsion layer, whereinat least one of said layers contains a dye having a maximum absorption at a wavelength being within the range of .+-.Type: GrantFiled: August 15, 1996Date of Patent: May 19, 1998Assignee: Konica CorporationInventors: Yoshitaka Goto, Takeo Arai
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Patent number: 5744279Abstract: A silver halide photographic material is disclosed, comprising a support having provided thereon at least one silver halide emulsion layer, at least one layer of the emulsion layer and other hydrophilic colloid layers containing at least one hydrazine-type nucleating agent having, in the vicinity of the hydrazine group, an anionic group or a nonionic group which forms an intramolecular hydrogen bond with a hydrogen atom of the hydrazine, and also containing at least one of the onium salt compounds represented by formulae (a), (b) and (c), or at least one of the amine compounds represented by formulae (d), (e), (f), (g), (h), (i) and (j). Also disclosed is a method for processing, after exposure, the silver halide photographic material described above with a developer containing a reductone-type developing agent and having a pH of 12 or less.Type: GrantFiled: February 1, 1996Date of Patent: April 28, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshihide Ezoe, Toshiaki Kubo, Hiroshi Takeuchi, Kazunobu Katoh, Shigeo Hirano, Kazuki Yamazaki, Takashi Hoshimiya, Minoru Sakai, Tetsuo Yoshida
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Patent number: 5738969Abstract: Disclosed is a process for treating a plate surface of a lithographic printing plate, which comprises, after exposing and developing a lithographic printing plate having a support and at least a silver halide emulsion layer and a physical development nuclei layer provided on the support, treating the plate surface of the lithographic printing plate with a plate surface-treating solution containing at least one water-insoluble compound having a mercapto group or a thione group and a compound represented by the following formula (1): ##STR1## wherein A represents a vinyl monomer unit having a carboxyl group, B represents a copolymerizable ethylenic unsaturated monomer unit, M represents a cation, k represents 30 to 90 mole %, m represents 10 to 50 mole %, and n represents 0 to 50 mole %.Type: GrantFiled: March 7, 1997Date of Patent: April 14, 1998Assignee: Mitsubishi Paper Mills LimitedInventors: Hiroyuki Kurokawa, Toshiro Kondo, Yutaka Araki
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Patent number: 5736295Abstract: A density enhancing amine compound is incorporated into a silver halide element containing both spectrally sensitized and non-spectrally sensitized silver halide grains in the emulsion layer.Type: GrantFiled: August 8, 1996Date of Patent: April 7, 1998Assignee: Eastman Kodak CompanyInventors: Allison Hazel Caroline Dale, Roger Hugh Piggin
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Patent number: 5736299Abstract: A silver halide color photographic material is disclosed, wherein it comprises a support having thereon one or more constituent layers including at least one silver halide emulsion layer, wherein at least one hydrophilic colloid layer of said constituent layers contains a coupler represented by the following formula (M) or formula (I) and at least one hydrophilic colloid layer of said constituent layers contains a compound represented by the following formula (H): ##STR1##Type: GrantFiled: January 23, 1996Date of Patent: April 7, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiyuki Watanabe, Hiroshi Fukuzawa, Michio Ono, Takashi Nakamura
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Patent number: 5725998Abstract: A method of developing an exposed black and white silver halide photographic light-sensitive material with developer using an automatic processor is disclosed, the developing comprising supplying replenisher for developer in an amount of not more than 200 ml per m.sup.2 of the material, the material containing a hydrazine derivative and an infectious development nucleation agent, and the developer having a pH value of 10.0 to 11.2 and containing a dihydroxy benzene compound, a 3-pyrazolidone compound or an aminophenol compound, a sulfite of 0.3 to 1.Type: GrantFiled: April 10, 1997Date of Patent: March 10, 1998Assignee: Konica CorporationInventor: Takeshi Sanpei
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Patent number: 5723265Abstract: A color image forming method is disclosed, comprising developing a silver halide photographic material and bleach and/or fixing the photographic material, wherein the color image is formed in the presence of a dextran. The dextran may be incorporated in the photographic material or a processing solution.Type: GrantFiled: October 8, 1996Date of Patent: March 3, 1998Assignee: Konica CorporationInventors: Shinsaku Nagaoka, Takehiko Shoji, Kiyokazu Morita, Tsukasa Ito, Yoshihiko Suda
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Patent number: 5721094Abstract: A method of processing an exposed silver halide photographic light sensitive material is disclosed which comprises the steps of:developing the exposed material with developer, the developer being replenished with developer replenisher and the developer containing no dihydroxy benzene and containing a developing agent represented by the following Formula ?1!: ##STR1## wherein R.sub.1 and R.sub.2 independently represent an alkyl group, an amino group, an alkoxy group or an alkylthio group, or R.sub.1 and R.sub.2 combine with each other to form a ring, k represents 0 or 1, and X represents --CO-- or --CS--;fixing the developed material;stabilizing the fixed material with a washing water which is replenished with water replenisher in a replenishing amount of 0.5 to 2 liter/m.sup.2 or with a rinsing solution which is replenished with a rinsing replenisher in a replenishing amount of 0 to 2 liter/m.sup.2 ; anddrying the stabilized material.Type: GrantFiled: August 14, 1996Date of Patent: February 24, 1998Assignee: Konica CorporationInventors: Hideki Komatsu, Shoji Nishio
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Patent number: 5719007Abstract: A silver halide color photographic material is described, which comprises a support having thereon at least one blue-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer, at least one red-sensitive silver halide emulsion layer and at least one light-insensitive layer, wherein one or more of the above layers contains at least one compound represented by formula (A-I), (A-II), (A-III), (A-IV) or (A-V) and one or more of the above layers contains at least one compound represented by formula (H): ##STR1##Type: GrantFiled: January 29, 1996Date of Patent: February 17, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Mamoru Sakurazawa, Hisashi Mikoshiba, Masakazu Morigaki
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Patent number: 5714302Abstract: The present invention provides a printing method using a silver salt lithographic printing plate obtained by imagewise exposing a silver salt lithographic printing plate precursor comprising a support and, provided thereon, at least a silver halide emulsion layer and a physical development nuclei layer and then subjecting the exposed printing plate precursor to silver complex diffusion transfer development and using a dampening composition containing a nonionic surface-active agent represented by the following formula ?I!: ##STR1## wherein R represents an alkyl group of 1-9 carbon atoms, and n.sub.1 and n.sub.2 are mol numbers necessary for the polymer having an average molecular weight of 250 or more, and n.sub.1 /n.sub.2 is 0.5-2, and a polymer represented by the following formula ?II!: ##STR2## wherein m is a number which provides a number-average molecular weight of 2000-50000 for the polymer.Type: GrantFiled: February 23, 1996Date of Patent: February 3, 1998Assignee: Mitsubishi Paper Mills LimitedInventors: Jun Urasaki, Hideo Kiyoyama, Hiroyuki Kurokawa, Kazuhiko Ibaraki, Akio Yoshida
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Patent number: 5707788Abstract: A method of processing a black and white silver halide photographic light sensitive material, using an automatic developing machine, the method comprising the steps of:exposing the material; anddeveloping the exposed material with developer, the developer being replenished with developer replenisher and the developer containing a dihydroxybenzene developing agent or a developing agent represented by Formula (A): ##STR1## wherein R.sub.5 and R.sub.6 independently represent an alkyl group, an amino group, an alkoxy group or an alkylthio group, or R.sub.5 and R.sub.6 combine with each other to form a ring; M represents a hydrogen atom or an alkali metal atom; k represents 0 or 1; and X represents --CO-- or --CS--,wherein the method satisfies the following inequality:1.1.ltoreq.D.sub.R /D.sub.S .ltoreq.2.5in which D.sub.S represents the developing agent concentration of a fresh developer and D.sub.R represents the developing agent concentration of a running developer in stationary state.Type: GrantFiled: October 2, 1996Date of Patent: January 13, 1998Assignee: Konica CorporationInventor: Shoji Nishio
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Patent number: 5702866Abstract: This subject invention relates to novel dihydrazide compounds useful as dot-promoting agents in photographic image systems, methods for making them, and to photographic materials which comprise these compounds.Type: GrantFiled: October 24, 1996Date of Patent: December 30, 1997Assignee: Ilford A.G.Inventors: Mario Fryberg, Otto Gottel, Thomas Stauner
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Patent number: 5702864Abstract: A hybrid lith photographic film substantially resistant to the formation of scratch-related defects that occur during the manufacturing and handling process having an anti-abrasion coating on the silver halide emulsion layer containing a polyalkylene oxide surfactant.Type: GrantFiled: August 30, 1996Date of Patent: December 30, 1997Assignee: Sun Chemical CorporationInventors: John F. Pilot, Shirley M. Madamba, Penny M. Mullen
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Patent number: 5702865Abstract: Relief images can be formed in photographic elements having a tanning developing agent incorporated therein. The tanning developing agents have the formula: ##STR1## wherein R.sup.1 and R.sup.2 are each an alkyl group of at least 3 carbon atoms, or an aryl group,After exposure, the material is treated with an alkaline solution and unhardened areas are removed.Type: GrantFiled: October 10, 1996Date of Patent: December 30, 1997Assignee: Eastman Kodak CompanyInventor: Michael John Simons
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Patent number: 5700610Abstract: A method for generating a screened reproduction of a multiple tone image comprising the steps of frequency modulation screening the multiple tone image to obtain screened data representing tones of the multiple tone image in terms of halftone dots, reproducing the halftone dots on an imaging element by means of a scanwise exposure, characterized in that the scanwise exposure for rendering a halftone dot is time modulated.Type: GrantFiled: March 20, 1996Date of Patent: December 23, 1997Assignee: Agfa-Gevaert N.V.Inventors: Jacobus Bosschaerts, Rene Govaert, Paul Delabastita
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Patent number: 5698367Abstract: Disclosed is a lithographic printing plate having a silver halide emulsion layer and a layer containing physical development nuclei on a support, the improvement wherein a water-soluble polymer having a structural unit represented by the formula (I): ##STR1## wherein R.sup.1 represents H or alkyl; Q represents divalent linking group; R.sup.2 represents divalent linking group or direct bond; and A represents a functional group represented by the formula: --S--C(.dbd.N--R.sup.4)--NH--R.sup.3, --Z--X(.dbd.Y)--(R.sup.5).sub.m or --W--(SH).sub.n where respective substituents are defined in the specification is contained in the layer containing physical development nuclei.Type: GrantFiled: December 7, 1995Date of Patent: December 16, 1997Assignee: Mitsubishi Paper Mills, LimitedInventors: Akira Furukawa, Motozo Yamano, Satoshi Shimonodan
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Patent number: 5695909Abstract: A silver halide photographic material comprising a support having provided thereon a light-sensitive silver halide emulsion layer, said silver halide photographic material contains at least one spectral sensitizing dye represented by the following formula (I): ##STR1## wherein Z.sub.11 represents a nonmetal atomic group necessary for completing a 5- or 6-membered nitrogen-containing heterocyclic ring; Q.sub.11 represents a nonmetal atomic group necessary for completing a 5-membered nitrogen-containing heterocyclic ring; R.sub.11 represents a substituted or unsubstituted alkyl group; R.sub.12 represents a straight chain or branched alkyl, alkenyl or alkynyl group each of which contains at least one carboxyl group and at least one ester bond, amido bond or ether bond; L.sub.11 and L.sub.12 each represents a methine group; m.sub.11 represents 0 or 1; m.sub.12 represents 0, 1 or 2: X.sub.1 represents a counter ion necessary for neutralizing a charge; and n.sub.Type: GrantFiled: October 25, 1996Date of Patent: December 9, 1997Assignee: Fuji Photo Film Co., Ltd.Inventors: Toyohisa Oya, Kazuki Yamazaki, Harumi Watanabe
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Patent number: 5693450Abstract: There is disclosed a silver halide color photographic light-sensitive material having at least one photographic constitutional layer on a support, wherein at least one reducing agent for color formation, which is a specific hydrazine compound, at least one dye-forming coupler, and at least one high-boiling-point organic solvent whose electron-donative parameter .DELTA..nu..sub.D at 25.degree. C. is 80 or more, are contained in at least one of said photographic constitutional layers. The above light-sensitive material enables low replenishment and reduced discharge of a color developer; can form colors favorably even when the coating film's pH is low; and is reduced in stain due to long-term storage of the light-sensitive material or stain after the processing of the light-sensitive material.Type: GrantFiled: May 24, 1996Date of Patent: December 2, 1997Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiyuki Makuta, Koki Nakamura, Kiyoshi Takeuchi, Hiroo Takizawa
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Patent number: 5691109Abstract: A method for processing silver halide photographic materials comprising the step of: processing imagewise exposed silver halide photographic material using a developer containing at least one compound represented by general formula (X): ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an alkyl group containing from 2 to 8 carbon atoms, an alkenyl group containing from 3 to 8 carbon atoms, or an aralkyl group containing from 7 to 12 carbon atoms; or R.sub.1 and R.sub.2 are combined to form a ring; R.sub.3, R.sub.4, R.sub.5, and R.sub.6 each represents a hydrogen atom, or an alkyl group containing from 1 to 4 carbon atoms: and n represents an integer from 3 to 20. A developer for processing silver halide photographic materials comprising at least one compound represented by general formula (X), described above. A silver halide photographic material comprising: at least one compound represented by general formula (X'): ##STR2## wherein R'.sub.1 and R'.sub.Type: GrantFiled: February 10, 1997Date of Patent: November 25, 1997Assignee: Fuji Photo Film Co., Ltd.Inventors: Tetsuro Kojima, Eiichi Okutsu, Kazunobu Katoh
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Patent number: 5691108Abstract: A process for developing a silver halide photographic light-sensitive material is disclosed, comprising processing, after exposure, a silver halide photographic light-sensitive material which comprises a support having thereon at least one light-sensitive silver halide emulsion layer, the emulsion layer or other hydrophilic colloid layer containing a hydrazine-base nucleating agent having an anionic group in the vicinity of the hydrazine group or a nonionic group of forming an intramolecular hydrogen bond with the hydrogen atom of the hydrazine, or containing at least one hydrazine nucleating agent selected from the compounds represented by formula (I), and a nucleating accelerator, with a developer having a pH of from 9.0 to 11.0 and containing:(1) from 0.2 to 0.75 mol/l of a dihydroxybenzene-base developing agent,(2) from 0.001 to 0.06 mol/l of a 1-phenyl-3-pyrazolidone-base or p-aminophenol-base auxiliary developing agent,(3) from 0.3 to 1.Type: GrantFiled: October 24, 1996Date of Patent: November 25, 1997Assignee: Fuji Photo Film Co., LTD.Inventors: Mitsunori Hirano, Kouta Fukui
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Patent number: 5688630Abstract: A silver halide photographic material comprising a hydrazine compound is described, wherein the hydrazine compound is selected from (a) a hydrazide compound having an acyl group substituted with an anionic group and with an electron-attracting group and (b) a hydrazide compound having an acyl group substituted with an electron-attracting group and with a nonionic group which forms an intramolecular hydrogen bond with a hydrogen atom in hydrazide compound.Type: GrantFiled: November 16, 1995Date of Patent: November 18, 1997Assignee: Fuji Photo Film Co., Ltd.Inventors: Kohzaburoh Yamada, Hiroshi Takeuchi, Takashi Hoshimiya, Toshihide Ezoe, Shigeo Hirano, Minoru Sakai
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Patent number: 5686222Abstract: This subject invention relates to novel dihydrazide compounds useful as dot-promoting agents in photographic image systems, methods for making them, and to photographic materials which comprise these compounds.Type: GrantFiled: December 6, 1996Date of Patent: November 11, 1997Assignee: Ilford A.G.Inventors: Mario Fryberg, Otto Gottel, Thomas Stauner
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Patent number: 5683854Abstract: An image-forming process developing a previously image-exposed silver halide photographic material with an alkaline developer containing a reductone compound as a main developing agent in the presence of a 1,2,5-thiadiazole compound and/or a 2,1,3-benzothiadiazole compound, and the silver halide photographic material and the photographic developer being used for the process are disclosed. In this case, the 1,2,5-thuiadiazole compound and/or the 2,1,3-benzothiadiazole may be contained in the silver halide photographic material and/or the alkaline developer. Super high-contrast images for photomechanical process having a gamma of higher than 15 and having no pepper and less fog can be obtained.Type: GrantFiled: September 12, 1996Date of Patent: November 4, 1997Assignee: Dainippon Ink and Chemicals Inc.Inventors: Kiyoshi Suematsu, Hiroaki Muratake, Haruhiko Kaji, Naoki Obi, Yasuhiko Kojima, Yasuo Shigemitsu